#------------------------------------------------------------------------------
#$Date: 2016-03-25 08:46:33 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179708 $
#$URL: svn://www.crystallography.net/cod/cif/7/00/11/7001140.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7001140
loop_
_publ_author_name
'Wu, Hua'
'Dong, Xian-Wu'
'Ma, Jian-Fang'
'Liu, Hai-Yan'
'Yang, Jin'
'Bai, Hong-Ye'
_publ_section_title
;
 Influence of anionic sulfonate-containing and nitrogen-containing
 mixed-ligands on the structures of silver coordination polymers
;
_journal_issue                   17
_journal_name_full               'Dalton Transactions'
_journal_page_first              3162
_journal_page_last               3174
_journal_paper_doi               10.1039/b814942a
_journal_year                    2009
_chemical_formula_moiety
'C46 H38 Ag2 N5 O9 S2, C20 H18 Ag N2, 5(H2 O) '
_chemical_formula_sum            'C66 H66 Ag3 N7 O14 S2'
_chemical_formula_weight         1568.99
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                88.53(5)
_cell_angle_beta                 89.12(3)
_cell_angle_gamma                79.84(4)
_cell_formula_units_Z            2
_cell_length_a                   13.328(3)
_cell_length_b                   13.863(3)
_cell_length_c                   17.612(4)
_cell_measurement_reflns_used    14269
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      3.0
_cell_volume                     3201.8(13)
_computing_cell_refinement       PROCESS-AUTO
_computing_data_collection       PROCESS-AUTO
_computing_data_reduction        PROCESS-AUTO
_computing_molecular_graphics    'SHELXTL-PLUS (Sheldrick, 1990)'
_computing_publication_material  SHELXL-97
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      293(2)
_diffrn_detector_area_resol_mean 10.0
_diffrn_measured_fraction_theta_full 0.989
_diffrn_measured_fraction_theta_max 0.974
_diffrn_measurement_device_type  'Rigaku RAXIS-RAPID'
_diffrn_measurement_method       'ω scan'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0983
_diffrn_reflns_av_sigmaI/netI    0.1414
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            31184
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         27.47
_diffrn_reflns_theta_min         2.99
_exptl_absorpt_coefficient_mu    1.045
_exptl_absorpt_correction_T_max  0.798
_exptl_absorpt_correction_T_min  0.742
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'ABSCOR (Higashi, 1995)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.627
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1592
_exptl_crystal_size_max          0.286
_exptl_crystal_size_mid          0.234
_exptl_crystal_size_min          0.223
_refine_diff_density_max         0.868
_refine_diff_density_min         -0.797
_refine_diff_density_rms         0.089
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.975
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     859
_refine_ls_number_reflns         14269
_refine_ls_number_restraints     16
_refine_ls_restrained_S_all      0.975
_refine_ls_R_factor_all          0.2022
_refine_ls_R_factor_gt           0.0729
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0819P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1504
_refine_ls_wR_factor_ref         0.1986
_reflns_number_gt                5686
_reflns_number_total             14269
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b814942a.txt
_cod_data_source_block           compound6
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_cell_volume        3201.8(11)
_cod_original_sg_symbol_H-M      'P -1 '
_cod_database_code               7001140
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.35273(4) 0.26575(4) 0.41768(4) 0.0684(2) Uani 1 1 d . . .
Ag2 Ag 0.68409(5) 0.24717(4) 0.10377(4) 0.0755(2) Uani 1 1 d . . .
Ag3 Ag 0.96935(5) 0.24696(5) 0.72747(4) 0.0835(3) Uani 1 1 d . . .
C1 C 0.0041(6) 0.3109(5) 0.1358(4) 0.058(2) Uani 1 1 d . . .
C2 C -0.0970(6) 0.3256(5) 0.1715(4) 0.057(2) Uani 1 1 d . . .
C3 C -0.0950(5) 0.2832(4) 0.2468(4) 0.0517(18) Uani 1 1 d . . .
C4 C -0.0077(5) 0.2317(5) 0.2794(4) 0.0512(18) Uani 1 1 d . . .
H4 H -0.0108 0.2059 0.3285 0.061 Uiso 1 1 calc R . .
C5 C 0.0866(5) 0.2173(5) 0.2398(5) 0.060(2) Uani 1 1 d . . .
C6 C 0.0899(6) 0.2578(5) 0.1694(4) 0.0582(19) Uani 1 1 d . . .
H6 H 0.1516 0.2496 0.1429 0.070 Uiso 1 1 calc R . .
C7 C 0.4548(6) 0.0562(6) 0.3855(5) 0.065(2) Uani 1 1 d . . .
H7 H 0.3909 0.0583 0.3644 0.078 Uiso 1 1 calc R . .
C8 C 0.5202(6) -0.0327(5) 0.3852(4) 0.059(2) Uani 1 1 d . . .
C9 C 0.4977(6) -0.1161(6) 0.3518(5) 0.078(2) Uani 1 1 d . . .
H9 H 0.4347 -0.1138 0.3291 0.093 Uiso 1 1 calc R . .
C10 C 0.5673(7) -0.2013(6) 0.3520(5) 0.083(3) Uani 1 1 d . . .
H10 H 0.5513 -0.2566 0.3296 0.100 Uiso 1 1 calc R . .
C11 C 0.6616(7) -0.2057(7) 0.3855(6) 0.088(3) Uani 1 1 d . . .
H11 H 0.7087 -0.2638 0.3850 0.105 Uiso 1 1 calc R . .
C12 C 0.6855(6) -0.1265(6) 0.4188(5) 0.073(2) Uani 1 1 d . . .
H12 H 0.7486 -0.1311 0.4418 0.087 Uiso 1 1 calc R . .
C13 C 0.6167(6) -0.0366(6) 0.4194(4) 0.063(2) Uani 1 1 d . . .
C14 C 0.6360(6) 0.0514(6) 0.4473(4) 0.066(2) Uani 1 1 d . . .
H14 H 0.6991 0.0516 0.4691 0.079 Uiso 1 1 calc R . .
C16 C 0.5695(5) 0.1351(6) 0.4447(4) 0.062(2) Uani 1 1 d . . .
C17 C 0.5899(6) 0.2322(6) 0.4723(5) 0.081(3) Uani 1 1 d . . .
H17A H 0.5306 0.2817 0.4643 0.121 Uiso 1 1 calc R . .
H17B H 0.6467 0.2500 0.4446 0.121 Uiso 1 1 calc R . .
H17C H 0.6052 0.2264 0.5255 0.121 Uiso 1 1 calc R . .
C18 C 0.2663(5) 0.4723(5) 0.4882(4) 0.0528(18) Uani 1 1 d . . .
C19 C 0.1990(5) 0.5569(5) 0.4958(4) 0.0566(19) Uani 1 1 d . . .
H19 H 0.2152 0.6047 0.5272 0.068 Uiso 1 1 calc R . .
C20 C 0.1063(5) 0.5746(5) 0.4581(4) 0.0525(18) Uani 1 1 d . . .
C21 C 0.0330(6) 0.6617(5) 0.4630(5) 0.065(2) Uani 1 1 d . . .
H21 H 0.0450 0.7124 0.4933 0.077 Uiso 1 1 calc R . .
C22 C -0.0550(6) 0.6710(6) 0.4232(5) 0.077(3) Uani 1 1 d . . .
H22 H -0.1012 0.7296 0.4257 0.092 Uiso 1 1 calc R . .
C23 C -0.0789(6) 0.5963(6) 0.3788(5) 0.071(2) Uani 1 1 d . . .
H23 H -0.1406 0.6042 0.3535 0.085 Uiso 1 1 calc R . .
C24 C -0.0095(5) 0.5112(5) 0.3733(4) 0.061(2) Uani 1 1 d . . .
H24 H -0.0241 0.4614 0.3433 0.074 Uiso 1 1 calc R . .
C25 C 0.0833(5) 0.4977(5) 0.4122(4) 0.0502(18) Uani 1 1 d . . .
C26 C 0.1556(5) 0.4124(5) 0.4077(4) 0.0483(17) Uani 1 1 d . . .
H26 H 0.1409 0.3622 0.3781 0.058 Uiso 1 1 calc R . .
C27 C 0.3670(6) 0.4522(6) 0.5279(5) 0.075(2) Uani 1 1 d . . .
H27A H 0.4030 0.3886 0.5145 0.113 Uiso 1 1 calc R . .
H27B H 0.3557 0.4540 0.5818 0.113 Uiso 1 1 calc R . .
H27C H 0.4066 0.5010 0.5127 0.113 Uiso 1 1 calc R . .
C28 C 0.4663(6) 0.3693(6) 0.0641(4) 0.068(2) Uani 1 1 d . . .
C29 C 0.3929(6) 0.4524(6) 0.0603(4) 0.067(2) Uani 1 1 d . . .
H29 H 0.3327 0.4506 0.0348 0.080 Uiso 1 1 calc R . .
C30 C 0.4065(6) 0.5395(6) 0.0938(4) 0.062(2) Uani 1 1 d . . .
C31 C 0.3303(7) 0.6247(7) 0.0926(5) 0.080(3) Uani 1 1 d . . .
H31 H 0.2700 0.6268 0.0663 0.096 Uiso 1 1 calc R . .
C32 C 0.3483(8) 0.7026(7) 0.1309(6) 0.097(3) Uani 1 1 d . . .
H32 H 0.2987 0.7590 0.1310 0.117 Uiso 1 1 calc R . .
C33 C 0.4407(8) 0.7024(6) 0.1715(6) 0.097(3) Uani 1 1 d . . .
H33 H 0.4494 0.7572 0.1983 0.117 Uiso 1 1 calc R . .
C34 C 0.5140(7) 0.6238(6) 0.1708(5) 0.086(3) Uani 1 1 d . . .
H34 H 0.5750 0.6244 0.1955 0.103 Uiso 1 1 calc R . .
C35 C 0.4985(6) 0.5381(6) 0.1317(5) 0.068(2) Uani 1 1 d . . .
C36 C 0.5714(6) 0.4503(6) 0.1316(4) 0.064(2) Uani 1 1 d . . .
H36 H 0.6330 0.4502 0.1556 0.077 Uiso 1 1 calc R . .
C37 C 0.4531(7) 0.2732(7) 0.0321(5) 0.103(3) Uani 1 1 d . . .
H37A H 0.5136 0.2255 0.0408 0.155 Uiso 1 1 calc R . .
H37B H 0.4413 0.2812 -0.0215 0.155 Uiso 1 1 calc R . .
H37C H 0.3959 0.2513 0.0564 0.155 Uiso 1 1 calc R . .
C38 C 0.7601(7) 0.3776(6) 0.7046(5) 0.075(2) Uani 1 1 d . . .
H38 H 0.7471 0.3257 0.6760 0.090 Uiso 1 1 calc RD . .
C39 C 0.6828(7) 0.4640(6) 0.7071(4) 0.065(2) Uani 1 1 d . . .
C40 C 0.5908(7) 0.4721(7) 0.6725(5) 0.083(3) Uani 1 1 d . . .
H40 H 0.5769 0.4205 0.6441 0.100 Uiso 1 1 calc R . .
C41 C 0.5204(7) 0.5529(7) 0.6788(5) 0.080(3) Uani 1 1 d . . .
H41 H 0.4567 0.5544 0.6576 0.096 Uiso 1 1 calc R . .
C42 C 0.5391(7) 0.6335(6) 0.7156(5) 0.069(2) Uani 1 1 d . . .
H42 H 0.4888 0.6893 0.7167 0.083 Uiso 1 1 calc R . .
C43 C 0.6309(7) 0.6347(6) 0.7514(4) 0.071(2) Uani 1 1 d . . .
H43 H 0.6444 0.6897 0.7756 0.086 Uiso 1 1 calc R . .
C44 C 0.7039(6) 0.5446(6) 0.7484(4) 0.062(2) Uani 1 1 d . . .
C45 C 0.7967(7) 0.5311(6) 0.7872(5) 0.075(2) Uani 1 1 d . . .
H45 H 0.8112 0.5814 0.8168 0.090 Uiso 1 1 calc R . .
C46 C 0.8659(7) 0.4468(6) 0.7829(5) 0.070(2) Uani 1 1 d . . .
C47 C 0.9726(7) 0.4265(6) 0.8262(5) 0.082(3) Uani 1 1 d . . .
H47A H 1.0085 0.3622 0.8145 0.123 Uiso 1 1 calc R . .
H47B H 0.9605 0.4305 0.8800 0.123 Uiso 1 1 calc R . .
H47C H 1.0128 0.4745 0.8101 0.123 Uiso 1 1 calc R . .
C49 C 1.1848(6) 0.1761(5) 0.7840(4) 0.064(2) Uani 1 1 d . . .
H49 H 1.1721 0.2385 0.8041 0.077 Uiso 1 1 calc R . .
C50 C 1.2771(6) 0.1152(6) 0.8019(4) 0.064(2) Uani 1 1 d . . .
C51 C 1.3512(8) 0.1443(7) 0.8497(5) 0.092(3) Uani 1 1 d . . .
H51 H 1.3385 0.2056 0.8718 0.110 Uiso 1 1 calc R . .
C52 C 1.4403(8) 0.0823(9) 0.8629(7) 0.111(4) Uani 1 1 d . . .
H52 H 1.4888 0.1016 0.8938 0.133 Uiso 1 1 calc R . .
C53 C 1.4598(7) -0.0088(9) 0.8311(7) 0.102(4) Uani 1 1 d . . .
H53 H 1.5223 -0.0491 0.8397 0.122 Uiso 1 1 calc R . .
C54 C 1.3908(7) -0.0412(6) 0.7877(5) 0.077(3) Uani 1 1 d . . .
H54 H 1.4047 -0.1042 0.7687 0.092 Uiso 1 1 calc R . .
C55 C 1.2967(6) 0.0211(6) 0.7713(4) 0.0554(19) Uani 1 1 d . . .
C56 C 1.2223(6) -0.0038(5) 0.7250(4) 0.0529(19) Uani 1 1 d . . .
H56 H 1.2335 -0.0657 0.7040 0.064 Uiso 1 1 calc R . .
C57 C 1.0531(6) 0.0349(6) 0.6595(4) 0.077(2) Uani 1 1 d . . .
H57A H 0.9987 0.0903 0.6564 0.116 Uiso 1 1 calc R . .
H57B H 1.0275 -0.0208 0.6803 0.116 Uiso 1 1 calc R . .
H57C H 1.0808 0.0203 0.6096 0.116 Uiso 1 1 calc R . .
C58 C 1.1342(6) 0.0580(5) 0.7091(4) 0.0521(18) Uani 1 1 d . . .
C59 C 0.8710(6) 0.0913(5) 0.1154(4) 0.0571(19) Uani 1 1 d . . .
H59 H 0.8847 0.1390 0.1480 0.069 Uiso 1 1 calc R . .
C60 C 0.9437(5) 0.0044(5) 0.1098(4) 0.0518(18) Uani 1 1 d . . .
C61 C 1.0357(6) -0.0113(6) 0.1504(4) 0.066(2) Uani 1 1 d . . .
H61 H 1.0509 0.0368 0.1819 0.080 Uiso 1 1 calc R . .
C62 C 1.1019(6) -0.0968(6) 0.1432(5) 0.075(2) Uani 1 1 d . . .
H62 H 1.1624 -0.1071 0.1702 0.090 Uiso 1 1 calc R . .
C63 C 1.0801(7) -0.1701(6) 0.0956(5) 0.084(3) Uani 1 1 d . . .
H63 H 1.1261 -0.2285 0.0911 0.101 Uiso 1 1 calc R . .
C64 C 0.9924(8) -0.1556(6) 0.0565(5) 0.083(3) Uani 1 1 d . . .
H64 H 0.9783 -0.2051 0.0259 0.100 Uiso 1 1 calc R . .
C65 C 0.9213(6) -0.0675(5) 0.0607(4) 0.062(2) Uani 1 1 d . . .
C66 C 0.8299(7) -0.0469(6) 0.0210(4) 0.072(2) Uani 1 1 d . . .
H66 H 0.8131 -0.0929 -0.0119 0.087 Uiso 1 1 calc R . .
C67 C 0.7657(6) 0.0388(6) 0.0299(4) 0.067(2) Uani 1 1 d . . .
C68 C 0.6673(7) 0.0611(6) -0.0135(5) 0.092(3) Uani 1 1 d . . .
H68A H 0.6312 0.1248 -0.0005 0.138 Uiso 1 1 calc R . .
H68B H 0.6260 0.0128 -0.0007 0.138 Uiso 1 1 calc R . .
H68C H 0.6820 0.0600 -0.0671 0.138 Uiso 1 1 calc R . .
N1 N 0.4741(5) 0.1385(5) 0.4128(4) 0.0628(17) Uani 1 1 d . . .
N2 N 0.2455(4) 0.3982(4) 0.4434(3) 0.0505(15) Uani 1 1 d . . .
N3 N 0.5578(5) 0.3698(5) 0.1001(4) 0.0632(17) Uani 1 1 d . . .
N4 N 0.7855(5) 0.1091(4) 0.0777(4) 0.0601(16) Uani 1 1 d . . .
N5 N 1.1151(4) 0.1510(4) 0.7408(3) 0.0528(15) Uani 1 1 d . . .
N6 N 0.8436(5) 0.3671(5) 0.7380(4) 0.0700(19) Uani 1 1 d . . .
N7 N 0.0176(8) 0.3524(5) 0.0606(4) 0.081(2) Uani 1 1 d . . .
O1 O 0.2800(4) 0.1528(5) 0.2304(4) 0.115(2) Uani 1 1 d . . .
O2 O 0.2069(4) 0.1869(4) 0.3555(4) 0.096(2) Uani 1 1 d . . .
O3 O 0.1758(4) 0.0465(4) 0.2910(3) 0.0857(18) Uani 1 1 d . . .
O4 O -0.1877(4) 0.2370(4) 0.3690(3) 0.0700(15) Uani 1 1 d . . .
O5 O -0.2488(4) 0.3960(3) 0.3109(3) 0.0782(16) Uani 1 1 d . . .
O6 O -0.2807(4) 0.2473(3) 0.2512(3) 0.0630(13) Uani 1 1 d . . .
O7 O -0.1781(4) 0.3683(4) 0.1413(3) 0.0746(16) Uani 1 1 d . . .
O8 O -0.0551(6) 0.3885(5) 0.0225(4) 0.116(3) Uani 1 1 d . . .
O9 O 0.1057(6) 0.3463(6) 0.0367(4) 0.118(3) Uani 1 1 d . . .
O1W O 0.8839(5) 0.1216(4) 0.4968(3) 0.0838(18) Uani 1 1 d D . .
O2W O 0.0957(6) 0.0890(5) 0.4734(4) 0.097(2) Uani 1 1 d D . .
O3W O 0.7899(5) 0.5630(6) 0.0859(4) 0.113(2) Uani 1 1 d D . .
O4W O 0.7511(7) 0.5854(5) 0.2440(5) 0.130(3) Uani 1 1 d D . .
S1 S 0.19626(15) 0.14556(14) 0.28223(13) 0.0661(6) Uani 1 1 d . . .
S2 S -0.21248(14) 0.29248(13) 0.29788(11) 0.0557(5) Uani 1 1 d . . .
O5W O 0.8026(7) 0.1543(6) 0.6514(5) 0.130(3) Uani 1 1 d D . .
H1B H 0.947(6) 0.109(9) 0.479(7) 0.195 Uiso 1 1 d D . .
H1A H 0.856(8) 0.157(8) 0.454(6) 0.195 Uiso 1 1 d D . .
H2A H 0.122(10) 0.029(6) 0.477(8) 0.195 Uiso 1 1 d D . .
H2B H 0.124(10) 0.120(9) 0.443(7) 0.195 Uiso 1 1 d D . .
H3A H 0.795(10) 0.518(8) 0.045(6) 0.195 Uiso 1 1 d D . .
H4B H 0.772(11) 0.536(7) 0.260(6) 0.195 Uiso 1 1 d D . .
H4A H 0.774(10) 0.572(10) 0.193(4) 0.195 Uiso 1 1 d D . .
H3B H 0.849(6) 0.572(9) 0.082(5) 0.195 Uiso 1 1 d D . .
H5A H 0.732(5) 0.175(3) 0.649(7) 0.195 Uiso 1 1 d D . .
H5B H 0.811(9) 0.154(10) 0.596(4) 0.195 Uiso 1 1 d D . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N2 Ag1 N1 168.7(2) . . ?
N3 Ag2 N4 162.0(2) . . ?
N6 Ag3 N5 163.1(3) . . ?
C6 C1 N7 116.6(8) . . ?
C6 C1 C2 123.5(7) . . ?
N7 C1 C2 119.9(7) . . ?
O7 C2 C3 122.2(8) . . ?
O7 C2 C1 125.7(7) . . ?
C3 C2 C1 112.1(6) . . ?
C4 C3 C2 123.0(7) . . ?
C4 C3 S2 118.9(5) . . ?
C2 C3 S2 118.0(5) . . ?
C3 C4 C5 121.3(7) . . ?
C3 C4 H4 119.3 . . ?
C5 C4 H4 119.3 . . ?
C6 C5 C4 118.3(7) . . ?
C6 C5 S1 121.8(6) . . ?
C4 C5 S1 119.9(6) . . ?
C5 C6 C1 121.7(7) . . ?
C5 C6 H6 119.2 . . ?
C1 C6 H6 119.2 . . ?
N1 C7 C8 126.2(7) . . ?
N1 C7 H7 116.9 . . ?
C8 C7 H7 116.9 . . ?
C7 C8 C9 123.7(8) . . ?
C7 C8 C13 116.9(8) . . ?
C9 C8 C13 119.4(7) . . ?
C10 C9 C8 120.6(8) . . ?
C10 C9 H9 119.7 . . ?
C8 C9 H9 119.7 . . ?
C9 C10 C11 120.3(9) . . ?
C9 C10 H10 119.8 . . ?
C11 C10 H10 119.8 . . ?
C12 C11 C10 120.6(9) . . ?
C12 C11 H11 119.7 . . ?
C10 C11 H11 119.7 . . ?
C11 C12 C13 121.3(8) . . ?
C11 C12 H12 119.4 . . ?
C13 C12 H12 119.4 . . ?
C14 C13 C12 126.1(8) . . ?
C14 C13 C8 115.9(7) . . ?
C12 C13 C8 117.9(8) . . ?
C16 C14 C13 123.9(8) . . ?
C16 C14 H14 118.1 . . ?
C13 C14 H14 118.1 . . ?
C14 C16 N1 120.3(8) . . ?
C14 C16 C17 124.8(7) . . ?
N1 C16 C17 114.9(6) . . ?
C16 C17 H17A 109.5 . . ?
C16 C17 H17B 109.5 . . ?
H17A C17 H17B 109.5 . . ?
C16 C17 H17C 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
C19 C18 N2 121.4(6) . . ?
C19 C18 C27 122.9(7) . . ?
N2 C18 C27 115.7(6) . . ?
C18 C19 C20 122.1(7) . . ?
C18 C19 H19 118.9 . . ?
C20 C19 H19 118.9 . . ?
C19 C20 C21 124.9(7) . . ?
C19 C20 C25 117.0(6) . . ?
C21 C20 C25 118.1(6) . . ?
C22 C21 C20 119.7(8) . . ?
C22 C21 H21 120.1 . . ?
C20 C21 H21 120.1 . . ?
C21 C22 C23 122.8(7) . . ?
C21 C22 H22 118.6 . . ?
C23 C22 H22 118.6 . . ?
C24 C23 C22 118.6(7) . . ?
C24 C23 H23 120.7 . . ?
C22 C23 H23 120.7 . . ?
C23 C24 C25 121.3(8) . . ?
C23 C24 H24 119.3 . . ?
C25 C24 H24 119.3 . . ?
C26 C25 C24 122.9(7) . . ?
C26 C25 C20 117.7(6) . . ?
C24 C25 C20 119.4(6) . . ?
N2 C26 C25 124.1(7) . . ?
N2 C26 H26 118.0 . . ?
C25 C26 H26 118.0 . . ?
C18 C27 H27A 109.5 . . ?
C18 C27 H27B 109.5 . . ?
H27A C27 H27B 109.5 . . ?
C18 C27 H27C 109.5 . . ?
H27A C27 H27C 109.5 . . ?
H27B C27 H27C 109.5 . . ?
C29 C28 N3 120.8(8) . . ?
C29 C28 C37 123.4(8) . . ?
N3 C28 C37 115.7(7) . . ?
C28 C29 C30 121.7(7) . . ?
C28 C29 H29 119.2 . . ?
C30 C29 H29 119.2 . . ?
C29 C30 C35 116.8(7) . . ?
C29 C30 C31 122.4(8) . . ?
C35 C30 C31 120.7(8) . . ?
C32 C31 C30 117.7(9) . . ?
C32 C31 H31 121.2 . . ?
C30 C31 H31 121.2 . . ?
C31 C32 C33 122.7(9) . . ?
C31 C32 H32 118.6 . . ?
C33 C32 H32 118.6 . . ?
C34 C33 C32 120.0(10) . . ?
C34 C33 H33 120.0 . . ?
C32 C33 H33 120.0 . . ?
C33 C34 C35 119.7(9) . . ?
C33 C34 H34 120.2 . . ?
C35 C34 H34 120.2 . . ?
C30 C35 C36 118.1(8) . . ?
C30 C35 C34 119.2(8) . . ?
C36 C35 C34 122.7(8) . . ?
N3 C36 C35 124.4(8) . . ?
N3 C36 H36 117.8 . . ?
C35 C36 H36 117.8 . . ?
C28 C37 H37A 109.5 . . ?
C28 C37 H37B 109.5 . . ?
H37A C37 H37B 109.5 . . ?
C28 C37 H37C 109.5 . . ?
H37A C37 H37C 109.5 . . ?
H37B C37 H37C 109.5 . . ?
N6 C38 C39 124.7(9) . . ?
N6 C38 H38 117.6 . . ?
C39 C38 H38 117.6 . . ?
C40 C39 C44 118.8(8) . . ?
C40 C39 C38 123.5(9) . . ?
C44 C39 C38 117.7(8) . . ?
C41 C40 C39 121.1(9) . . ?
C41 C40 H40 119.5 . . ?
C39 C40 H40 119.5 . . ?
C40 C41 C42 121.9(9) . . ?
C40 C41 H41 119.0 . . ?
C42 C41 H41 119.0 . . ?
C41 C42 C43 122.0(8) . . ?
C41 C42 H42 119.0 . . ?
C43 C42 H42 119.0 . . ?
C42 C43 C44 115.4(8) . . ?
C42 C43 H43 122.3 . . ?
C44 C43 H43 122.3 . . ?
C45 C44 C39 117.0(8) . . ?
C45 C44 C43 122.3(9) . . ?
C39 C44 C43 120.6(7) . . ?
C46 C45 C44 122.0(9) . . ?
C46 C45 H45 119.0 . . ?
C44 C45 H45 119.0 . . ?
C45 C46 N6 119.7(8) . . ?
C45 C46 C47 124.5(8) . . ?
N6 C46 C47 115.8(7) . . ?
C46 C47 H47A 109.5 . . ?
C46 C47 H47B 109.5 . . ?
H47A C47 H47B 109.5 . . ?
C46 C47 H47C 109.5 . . ?
H47A C47 H47C 109.5 . . ?
H47B C47 H47C 109.5 . . ?
N5 C49 C50 124.3(7) . . ?
N5 C49 H49 117.9 . . ?
C50 C49 H49 117.9 . . ?
C49 C50 C55 118.0(7) . . ?
C49 C50 C51 123.0(8) . . ?
C55 C50 C51 119.1(8) . . ?
C52 C51 C50 119.7(10) . . ?
C52 C51 H51 120.2 . . ?
C50 C51 H51 120.2 . . ?
C51 C52 C53 120.8(10) . . ?
C51 C52 H52 119.6 . . ?
C53 C52 H52 119.6 . . ?
C54 C53 C52 121.8(9) . . ?
C54 C53 H53 119.1 . . ?
C52 C53 H53 119.1 . . ?
C53 C54 C55 119.8(9) . . ?
C53 C54 H54 120.1 . . ?
C55 C54 H54 120.1 . . ?
C56 C55 C50 116.9(7) . . ?
C56 C55 C54 124.3(8) . . ?
C50 C55 C54 118.8(8) . . ?
C58 C56 C55 122.9(7) . . ?
C58 C56 H56 118.5 . . ?
C55 C56 H56 118.5 . . ?
C58 C57 H57A 109.5 . . ?
C58 C57 H57B 109.5 . . ?
H57A C57 H57B 109.5 . . ?
C58 C57 H57C 109.5 . . ?
H57A C57 H57C 109.5 . . ?
H57B C57 H57C 109.5 . . ?
C56 C58 N5 119.6(7) . . ?
C56 C58 C57 124.8(7) . . ?
N5 C58 C57 115.6(7) . . ?
N4 C59 C60 124.2(7) . . ?
N4 C59 H59 117.9 . . ?
C60 C59 H59 117.9 . . ?
C65 C60 C61 120.3(7) . . ?
C65 C60 C59 117.2(7) . . ?
C61 C60 C59 122.5(7) . . ?
C62 C61 C60 119.7(8) . . ?
C62 C61 H61 120.1 . . ?
C60 C61 H61 120.1 . . ?
C61 C62 C63 120.8(8) . . ?
C61 C62 H62 119.6 . . ?
C63 C62 H62 119.6 . . ?
C64 C63 C62 119.9(8) . . ?
C64 C63 H63 120.1 . . ?
C62 C63 H63 120.1 . . ?
C63 C64 C65 121.9(8) . . ?
C63 C64 H64 119.1 . . ?
C65 C64 H64 119.1 . . ?
C66 C65 C60 117.6(7) . . ?
C66 C65 C64 125.0(8) . . ?
C60 C65 C64 117.4(8) . . ?
C67 C66 C65 120.7(8) . . ?
C67 C66 H66 119.6 . . ?
C65 C66 H66 119.6 . . ?
C66 C67 N4 122.5(7) . . ?
C66 C67 C68 120.6(8) . . ?
N4 C67 C68 116.9(8) . . ?
C67 C68 H68A 109.5 . . ?
C67 C68 H68B 109.5 . . ?
H68A C68 H68B 109.5 . . ?
C67 C68 H68C 109.5 . . ?
H68A C68 H68C 109.5 . . ?
H68B C68 H68C 109.5 . . ?
C7 N1 C16 116.8(6) . . ?
C7 N1 Ag1 119.4(5) . . ?
C16 N1 Ag1 123.5(6) . . ?
C26 N2 C18 117.7(6) . . ?
C26 N2 Ag1 117.2(5) . . ?
C18 N2 Ag1 124.8(4) . . ?
C36 N3 C28 118.1(7) . . ?
C36 N3 Ag2 117.1(5) . . ?
C28 N3 Ag2 124.7(6) . . ?
C59 N4 C67 117.8(7) . . ?
C59 N4 Ag2 115.5(5) . . ?
C67 N4 Ag2 126.6(5) . . ?
C49 N5 C58 118.3(6) . . ?
C49 N5 Ag3 120.2(5) . . ?
C58 N5 Ag3 121.3(5) . . ?
C38 N6 C46 118.8(7) . . ?
C38 N6 Ag3 126.9(7) . . ?
C46 N6 Ag3 114.0(5) . . ?
O8 N7 O9 121.9(8) . . ?
O8 N7 C1 121.1(9) . . ?
O9 N7 C1 116.9(8) . . ?
H1B O1W H1A 96(8) . . ?
H2A O2W H2B 114(10) . . ?
H3A O3W H3B 95(8) . . ?
H4B O4W H4A 96(9) . . ?
O2 S1 O1 113.6(4) . . ?
O2 S1 O3 110.6(4) . . ?
O1 S1 O3 113.0(4) . . ?
O2 S1 C5 106.5(3) . . ?
O1 S1 C5 105.7(4) . . ?
O3 S1 C5 106.8(3) . . ?
O5 S2 O4 111.9(3) . . ?
O5 S2 O6 113.7(3) . . ?
O4 S2 O6 111.6(3) . . ?
O5 S2 C3 107.1(3) . . ?
O4 S2 C3 105.4(3) . . ?
O6 S2 C3 106.6(3) . . ?
H5A O5W H5B 94(6) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 N2 2.171(6) . ?
Ag1 N1 2.176(6) . ?
Ag2 N3 2.171(6) . ?
Ag2 N4 2.194(6) . ?
Ag3 N6 2.153(6) . ?
Ag3 N5 2.164(6) . ?
C1 C6 1.379(10) . ?
C1 N7 1.452(9) . ?
C1 C2 1.461(10) . ?
C2 O7 1.257(8) . ?
C2 C3 1.436(9) . ?
C3 C4 1.379(9) . ?
C3 S2 1.780(7) . ?
C4 C5 1.413(10) . ?
C4 H4 0.9300 . ?
C5 C6 1.351(9) . ?
C5 S1 1.779(7) . ?
C6 H6 0.9300 . ?
C7 N1 1.317(9) . ?
C7 C8 1.379(10) . ?
C7 H7 0.9300 . ?
C8 C9 1.391(11) . ?
C8 C13 1.420(11) . ?
C9 C10 1.368(10) . ?
C9 H9 0.9300 . ?
C10 C11 1.388(12) . ?
C10 H10 0.9300 . ?
C11 C12 1.346(12) . ?
C11 H11 0.9300 . ?
C12 C13 1.411(10) . ?
C12 H12 0.9300 . ?
C13 C14 1.393(11) . ?
C14 C16 1.330(9) . ?
C14 H14 0.9300 . ?
C16 N1 1.391(9) . ?
C16 C17 1.513(10) . ?
C17 H17A 0.9600 . ?
C17 H17B 0.9600 . ?
C17 H17C 0.9600 . ?
C18 C19 1.353(9) . ?
C18 N2 1.381(9) . ?
C18 C27 1.500(9) . ?
C19 C20 1.392(9) . ?
C19 H19 0.9300 . ?
C20 C21 1.417(9) . ?
C20 C25 1.433(10) . ?
C21 C22 1.361(11) . ?
C21 H21 0.9300 . ?
C22 C23 1.396(11) . ?
C22 H22 0.9300 . ?
C23 C24 1.369(10) . ?
C23 H23 0.9300 . ?
C24 C25 1.403(9) . ?
C24 H24 0.9300 . ?
C25 C26 1.390(8) . ?
C26 N2 1.343(8) . ?
C26 H26 0.9300 . ?
C27 H27A 0.9600 . ?
C27 H27B 0.9600 . ?
C27 H27C 0.9600 . ?
C28 C29 1.374(10) . ?
C28 N3 1.384(10) . ?
C28 C37 1.500(11) . ?
C29 C30 1.399(11) . ?
C29 H29 0.9300 . ?
C30 C35 1.402(11) . ?
C30 C31 1.415(10) . ?
C31 C32 1.347(12) . ?
C31 H31 0.9300 . ?
C32 C33 1.432(13) . ?
C32 H32 0.9300 . ?
C33 C34 1.329(11) . ?
C33 H33 0.9300 . ?
C34 C35 1.436(12) . ?
C34 H34 0.9300 . ?
C35 C36 1.417(10) . ?
C36 N3 1.301(9) . ?
C36 H36 0.9300 . ?
C37 H37A 0.9600 . ?
C37 H37B 0.9600 . ?
C37 H37C 0.9600 . ?
C38 N6 1.251(10) . ?
C38 C39 1.438(10) . ?
C38 H38 0.9300 . ?
C39 C40 1.362(12) . ?
C39 C44 1.419(11) . ?
C40 C41 1.334(11) . ?
C40 H40 0.9300 . ?
C41 C42 1.368(11) . ?
C41 H41 0.9300 . ?
C42 C43 1.387(11) . ?
C42 H42 0.9300 . ?
C43 C44 1.443(11) . ?
C43 H43 0.9300 . ?
C44 C45 1.403(11) . ?
C45 C46 1.358(10) . ?
C45 H45 0.9300 . ?
C46 N6 1.450(10) . ?
C46 C47 1.602(11) . ?
C47 H47A 0.9600 . ?
C47 H47B 0.9600 . ?
C47 H47C 0.9600 . ?
C49 N5 1.308(9) . ?
C49 C50 1.400(10) . ?
C49 H49 0.9300 . ?
C50 C55 1.404(10) . ?
C50 C51 1.425(11) . ?
C51 C52 1.357(13) . ?
C51 H51 0.9300 . ?
C52 C53 1.376(14) . ?
C52 H52 0.9300 . ?
C53 C54 1.347(13) . ?
C53 H53 0.9300 . ?
C54 C55 1.421(10) . ?
C54 H54 0.9300 . ?
C55 C56 1.387(10) . ?
C56 C58 1.355(9) . ?
C56 H56 0.9300 . ?
C57 C58 1.483(10) . ?
C57 H57A 0.9600 . ?
C57 H57B 0.9600 . ?
C57 H57C 0.9600 . ?
C58 N5 1.398(9) . ?
C59 N4 1.311(9) . ?
C59 C60 1.411(9) . ?
C59 H59 0.9300 . ?
C60 C65 1.409(10) . ?
C60 C61 1.410(10) . ?
C61 C62 1.353(10) . ?
C61 H61 0.9300 . ?
C62 C63 1.406(12) . ?
C62 H62 0.9300 . ?
C63 C64 1.348(12) . ?
C63 H63 0.9300 . ?
C64 C65 1.410(10) . ?
C64 H64 0.9300 . ?
C65 C66 1.396(11) . ?
C66 C67 1.348(11) . ?
C66 H66 0.9300 . ?
C67 N4 1.366(10) . ?
C67 C68 1.508(11) . ?
C68 H68A 0.9600 . ?
C68 H68B 0.9600 . ?
C68 H68C 0.9600 . ?
N7 O8 1.213(9) . ?
N7 O9 1.231(9) . ?
O1 S1 1.446(6) . ?
O2 S1 1.444(6) . ?
O3 S1 1.450(5) . ?
O4 S2 1.464(5) . ?
O5 S2 1.453(5) . ?
O6 S2 1.465(5) . ?
O1W H1B 0.88(7) . ?
O1W H1A 0.93(7) . ?
O2W H2A 0.85(7) . ?
O2W H2B 0.80(8) . ?
O3W H3A 0.97(7) . ?
O3W H3B 0.82(7) . ?
O4W H4B 0.74(7) . ?
O4W H4A 0.95(7) . ?
O5W H5A 0.94(7) . ?
O5W H5B 0.98(7) . ?
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
O1W H1A O4 0.93(7) 1.88(7) 2.807(7) 174(11) 1_655
O1W H1B O2W 0.88(7) 1.95(8) 2.805(10) 161(12) 1_655
O2W H2A O1W 0.85(7) 2.14(9) 2.919(9) 153(13) 2_656
O2W H2B O2 0.80(8) 2.18(8) 2.970(10) 173(14) .
O3W H3A O8 0.97(7) 2.47(12) 3.110(10) 123(10) 1_655
O3W H3B O9 0.82(7) 2.47(9) 2.927(10) 116(9) 2_665
O4W H4B O5 0.74(7) 2.18(9) 2.850(9) 151(16) 1_655
O4W H4A O3W 0.95(7) 1.91(7) 2.839(12) 166(12) .
O5W H5B O1W 0.98(7) 2.01(7) 2.932(11) 156(11) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C6 C1 C2 O7 -175.4(7) . . . . ?
N7 C1 C2 O7 3.7(11) . . . . ?
C6 C1 C2 C3 3.3(10) . . . . ?
N7 C1 C2 C3 -177.5(6) . . . . ?
O7 C2 C3 C4 176.6(6) . . . . ?
C1 C2 C3 C4 -2.3(9) . . . . ?
O7 C2 C3 S2 -0.1(9) . . . . ?
C1 C2 C3 S2 -178.9(5) . . . . ?
C2 C3 C4 C5 -0.1(10) . . . . ?
S2 C3 C4 C5 176.5(5) . . . . ?
C3 C4 C5 C6 1.8(10) . . . . ?
C3 C4 C5 S1 -177.0(5) . . . . ?
C4 C5 C6 C1 -0.7(10) . . . . ?
S1 C5 C6 C1 178.0(5) . . . . ?
N7 C1 C6 C5 178.8(6) . . . . ?
C2 C1 C6 C5 -2.0(11) . . . . ?
N1 C7 C8 C9 -176.3(8) . . . . ?
N1 C7 C8 C13 1.8(12) . . . . ?
C7 C8 C9 C10 178.4(8) . . . . ?
C13 C8 C9 C10 0.3(12) . . . . ?
C8 C9 C10 C11 -0.1(13) . . . . ?
C9 C10 C11 C12 0.6(14) . . . . ?
C10 C11 C12 C13 -1.2(13) . . . . ?
C11 C12 C13 C14 -175.2(8) . . . . ?
C11 C12 C13 C8 1.3(12) . . . . ?
C7 C8 C13 C14 -2.2(10) . . . . ?
C9 C8 C13 C14 176.0(7) . . . . ?
C7 C8 C13 C12 -179.1(7) . . . . ?
C9 C8 C13 C12 -0.9(11) . . . . ?
C12 C13 C14 C16 178.0(7) . . . . ?
C8 C13 C14 C16 1.4(11) . . . . ?
C13 C14 C16 N1 0.1(12) . . . . ?
C13 C14 C16 C17 -178.0(7) . . . . ?
N2 C18 C19 C20 -1.1(11) . . . . ?
C27 C18 C19 C20 179.5(7) . . . . ?
C18 C19 C20 C21 -179.4(7) . . . . ?
C18 C19 C20 C25 1.9(10) . . . . ?
C19 C20 C21 C22 179.8(7) . . . . ?
C25 C20 C21 C22 -1.6(10) . . . . ?
C20 C21 C22 C23 2.2(12) . . . . ?
C21 C22 C23 C24 -1.9(12) . . . . ?
C22 C23 C24 C25 1.0(11) . . . . ?
C23 C24 C25 C26 -179.7(7) . . . . ?
C23 C24 C25 C20 -0.4(11) . . . . ?
C19 C20 C25 C26 -1.2(9) . . . . ?
C21 C20 C25 C26 -180.0(6) . . . . ?
C19 C20 C25 C24 179.4(7) . . . . ?
C21 C20 C25 C24 0.7(10) . . . . ?
C24 C25 C26 N2 179.1(7) . . . . ?
C20 C25 C26 N2 -0.3(10) . . . . ?
N3 C28 C29 C30 -1.5(12) . . . . ?
C37 C28 C29 C30 177.2(8) . . . . ?
C28 C29 C30 C35 -0.2(11) . . . . ?
C28 C29 C30 C31 -177.8(7) . . . . ?
C29 C30 C31 C32 175.6(8) . . . . ?
C35 C30 C31 C32 -1.9(12) . . . . ?
C30 C31 C32 C33 0.6(14) . . . . ?
C31 C32 C33 C34 1.6(15) . . . . ?
C32 C33 C34 C35 -2.4(14) . . . . ?
C29 C30 C35 C36 1.7(11) . . . . ?
C31 C30 C35 C36 179.4(7) . . . . ?
C29 C30 C35 C34 -176.5(7) . . . . ?
C31 C30 C35 C34 1.1(12) . . . . ?
C33 C34 C35 C30 1.1(13) . . . . ?
C33 C34 C35 C36 -177.1(8) . . . . ?
C30 C35 C36 N3 -1.7(12) . . . . ?
C34 C35 C36 N3 176.4(8) . . . . ?
N6 C38 C39 C40 -177.4(8) . . . . ?
N6 C38 C39 C44 2.2(12) . . . . ?
C44 C39 C40 C41 -1.8(13) . . . . ?
C38 C39 C40 C41 177.7(8) . . . . ?
C39 C40 C41 C42 4.4(14) . . . . ?
C40 C41 C42 C43 -2.8(13) . . . . ?
C41 C42 C43 C44 -1.3(11) . . . . ?
C40 C39 C44 C45 176.0(8) . . . . ?
C38 C39 C44 C45 -3.6(10) . . . . ?
C40 C39 C44 C43 -2.3(11) . . . . ?
C38 C39 C44 C43 178.1(7) . . . . ?
C42 C43 C44 C45 -174.5(7) . . . . ?
C42 C43 C44 C39 3.7(10) . . . . ?
C39 C44 C45 C46 3.1(11) . . . . ?
C43 C44 C45 C46 -178.6(7) . . . . ?
C44 C45 C46 N6 -1.1(12) . . . . ?
C44 C45 C46 C47 -179.4(7) . . . . ?
N5 C49 C50 C55 0.4(12) . . . . ?
N5 C49 C50 C51 -179.4(8) . . . . ?
C49 C50 C51 C52 -178.1(8) . . . . ?
C55 C50 C51 C52 2.1(13) . . . . ?
C50 C51 C52 C53 -0.5(16) . . . . ?
C51 C52 C53 C54 -2.0(17) . . . . ?
C52 C53 C54 C55 2.8(15) . . . . ?
C49 C50 C55 C56 0.3(11) . . . . ?
C51 C50 C55 C56 -179.9(7) . . . . ?
C49 C50 C55 C54 178.9(7) . . . . ?
C51 C50 C55 C54 -1.3(11) . . . . ?
C53 C54 C55 C56 177.4(8) . . . . ?
C53 C54 C55 C50 -1.1(12) . . . . ?
C50 C55 C56 C58 -0.1(11) . . . . ?
C54 C55 C56 C58 -178.6(7) . . . . ?
C55 C56 C58 N5 -0.7(10) . . . . ?
C55 C56 C58 C57 179.4(7) . . . . ?
N4 C59 C60 C65 -0.5(11) . . . . ?
N4 C59 C60 C61 178.9(7) . . . . ?
C65 C60 C61 C62 -1.4(11) . . . . ?
C59 C60 C61 C62 179.2(7) . . . . ?
C60 C61 C62 C63 0.2(12) . . . . ?
C61 C62 C63 C64 -0.1(14) . . . . ?
C62 C63 C64 C65 1.1(14) . . . . ?
C61 C60 C65 C66 -178.8(7) . . . . ?
C59 C60 C65 C66 0.6(10) . . . . ?
C61 C60 C65 C64 2.3(11) . . . . ?
C59 C60 C65 C64 -178.3(7) . . . . ?
C63 C64 C65 C66 179.0(9) . . . . ?
C63 C64 C65 C60 -2.2(13) . . . . ?
C60 C65 C66 C67 -0.2(12) . . . . ?
C64 C65 C66 C67 178.7(8) . . . . ?
C65 C66 C67 N4 -0.5(12) . . . . ?
C65 C66 C67 C68 179.6(7) . . . . ?
C8 C7 N1 C16 -0.4(12) . . . . ?
C8 C7 N1 Ag1 -173.5(6) . . . . ?
C14 C16 N1 C7 -0.6(10) . . . . ?
C17 C16 N1 C7 177.6(7) . . . . ?
C14 C16 N1 Ag1 172.2(5) . . . . ?
C17 C16 N1 Ag1 -9.6(9) . . . . ?
N2 Ag1 N1 C7 143.4(10) . . . . ?
N2 Ag1 N1 C16 -29.2(14) . . . . ?
C25 C26 N2 C18 1.1(10) . . . . ?
C25 C26 N2 Ag1 -173.4(5) . . . . ?
C19 C18 N2 C26 -0.4(10) . . . . ?
C27 C18 N2 C26 179.1(6) . . . . ?
C19 C18 N2 Ag1 173.6(5) . . . . ?
C27 C18 N2 Ag1 -7.0(8) . . . . ?
N1 Ag1 N2 C26 -161.1(10) . . . . ?
N1 Ag1 N2 C18 24.9(14) . . . . ?
C35 C36 N3 C28 0.1(11) . . . . ?
C35 C36 N3 Ag2 177.5(6) . . . . ?
C29 C28 N3 C36 1.5(11) . . . . ?
C37 C28 N3 C36 -177.2(7) . . . . ?
C29 C28 N3 Ag2 -175.7(5) . . . . ?
C37 C28 N3 Ag2 5.5(10) . . . . ?
N4 Ag2 N3 C36 -159.4(6) . . . . ?
N4 Ag2 N3 C28 17.9(11) . . . . ?
C60 C59 N4 C67 -0.1(11) . . . . ?
C60 C59 N4 Ag2 176.5(5) . . . . ?
C66 C67 N4 C59 0.6(11) . . . . ?
C68 C67 N4 C59 -179.5(7) . . . . ?
C66 C67 N4 Ag2 -175.6(6) . . . . ?
C68 C67 N4 Ag2 4.4(10) . . . . ?
N3 Ag2 N4 C59 173.4(6) . . . . ?
N3 Ag2 N4 C67 -10.4(11) . . . . ?
C50 C49 N5 C58 -1.2(11) . . . . ?
C50 C49 N5 Ag3 173.6(6) . . . . ?
C56 C58 N5 C49 1.3(10) . . . . ?
C57 C58 N5 C49 -178.8(7) . . . . ?
C56 C58 N5 Ag3 -173.3(5) . . . . ?
C57 C58 N5 Ag3 6.5(8) . . . . ?
N6 Ag3 N5 C49 -3.3(11) . . . . ?
N6 Ag3 N5 C58 171.3(7) . . . . ?
C39 C38 N6 C46 -0.1(12) . . . . ?
C39 C38 N6 Ag3 -172.9(5) . . . . ?
C45 C46 N6 C38 -0.6(11) . . . . ?
C47 C46 N6 C38 178.0(7) . . . . ?
C45 C46 N6 Ag3 173.2(6) . . . . ?
C47 C46 N6 Ag3 -8.3(8) . . . . ?
N5 Ag3 N6 C38 -179.7(6) . . . . ?
N5 Ag3 N6 C46 7.2(11) . . . . ?
C6 C1 N7 O8 169.8(7) . . . . ?
C2 C1 N7 O8 -9.5(11) . . . . ?
C6 C1 N7 O9 -7.9(11) . . . . ?
C2 C1 N7 O9 172.8(7) . . . . ?
C6 C5 S1 O2 127.3(6) . . . . ?
C4 C5 S1 O2 -54.0(7) . . . . ?
C6 C5 S1 O1 6.1(7) . . . . ?
C4 C5 S1 O1 -175.1(6) . . . . ?
C6 C5 S1 O3 -114.5(6) . . . . ?
C4 C5 S1 O3 64.3(7) . . . . ?
C4 C3 S2 O5 118.4(5) . . . . ?
C2 C3 S2 O5 -64.8(6) . . . . ?
C4 C3 S2 O4 -0.9(6) . . . . ?
C2 C3 S2 O4 175.8(5) . . . . ?
C4 C3 S2 O6 -119.6(5) . . . . ?
C2 C3 S2 O6 57.2(6) . . . . ?
