#------------------------------------------------------------------------------
#$Date: 2016-03-25 08:53:21 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179710 $
#$URL: svn://www.crystallography.net/cod/cif/7/00/13/7001350.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7001350
loop_
_publ_author_name
'Hounjet, Lindsay J.'
'Bierenstiel, Matthias'
'Ferguson, Michael J.'
'McDonald, Robert'
'Cowie, Martin'
_publ_section_title
;
 Mono- and binuclear complexes of rhodium involving a new series of
 hemilabile o-phosphinoaniline ligands
;
_journal_issue                   21
_journal_name_full               'Dalton Transactions'
_journal_page_first              4213
_journal_page_last               4226
_journal_paper_doi               10.1039/b822170g
_journal_year                    2009
_chemical_formula_moiety         'C31 H34 Cl2 N4 O2 P2 Rh2 0.75(C H2 Cl2)'
_chemical_formula_sum            'C31.75 H35.5 Cl3.5 N4 O2 P2 Rh2'
_chemical_formula_weight         896.98
_chemical_name_systematic
;
?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 104.6430(11)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   11.6270(8)
_cell_length_b                   18.1593(12)
_cell_length_c                   17.4024(12)
_cell_measurement_reflns_used    7195
_cell_measurement_temperature    193(2)
_cell_measurement_theta_max      25.53
_cell_measurement_theta_min      2.21
_cell_volume                     3555.0(4)
_computing_cell_refinement       'Bruker SAINT (Bruker, 1997)'
_computing_data_collection       'Bruker SMART (Bruker, 1997)'
_computing_data_reduction        'Bruker SAINT (Bruker, 1997)'
_computing_molecular_graphics    'Bruker SHELXTL (Bruker, 1997)'
_computing_publication_material  'Bruker SHELXTL (Bruker, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      193(2)
_diffrn_detector_area_resol_mean 8.192
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type
'Bruker PLATFORM diffractometer/SMART 1000 CCD area detector'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0394
_diffrn_reflns_av_sigmaI/netI    0.0366
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_k_min       -22
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            25488
_diffrn_reflns_theta_full        26.40
_diffrn_reflns_theta_max         26.40
_diffrn_reflns_theta_min         1.65
_diffrn_standards_decay_%        0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    1.317
_exptl_absorpt_correction_T_max  0.8907
_exptl_absorpt_correction_T_min  0.6704
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS (Sheldrick, 1996)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.676
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             1798
_exptl_crystal_size_max          0.33
_exptl_crystal_size_mid          0.21
_exptl_crystal_size_min          0.09
_refine_diff_density_max         0.670
_refine_diff_density_min         -0.603
_refine_diff_density_rms         0.083
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.036
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     388
_refine_ls_number_reflns         7269
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.036
_refine_ls_R_factor_all          0.0504
_refine_ls_R_factor_gt           0.0355
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0477P)²+0.2493P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0824
_refine_ls_wR_factor_ref         0.0871
_reflns_number_gt                5696
_reflns_number_total             7269
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            b822170g.txt
_cod_data_source_block           compound(10)
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               7001350
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh1 Rh 0.35769(2) 0.134845(14) 0.104032(15) 0.02982(8) Uani 1 1 d . . .
Rh2 Rh 0.18752(2) 0.065878(14) 0.223692(19) 0.04019(9) Uani 1 1 d . . .
Cl1 Cl 0.27501(8) 0.05470(5) -0.00410(6) 0.0482(2) Uani 1 1 d . . .
Cl2 Cl 0.20637(10) -0.05867(5) 0.18369(9) 0.0735(4) Uani 1 1 d . . .
P1 P 0.42900(7) 0.19490(4) 0.21542(5) 0.02763(18) Uani 1 1 d . . .
P2 P 0.17798(7) 0.18437(4) 0.24334(5) 0.02841(18) Uani 1 1 d . . .
O1 O 0.2578(2) 0.26858(16) 0.01444(17) 0.0595(7) Uani 1 1 d . . .
O2 O 0.3147(3) 0.0417(2) 0.3920(2) 0.0807(10) Uani 1 1 d . . .
N1 N 0.4452(2) 0.04109(14) 0.16726(16) 0.0341(6) Uani 1 1 d . . .
H1N H 0.3880 0.0045 0.1634 0.041 Uiso 1 1 calc R . .
N2 N 0.6387(2) 0.19678(18) 0.14257(18) 0.0465(8) Uani 1 1 d . . .
H2N H 0.5838 0.1626 0.1379 0.056 Uiso 1 1 calc R . .
N3 N 0.0766(2) 0.08963(16) 0.10658(19) 0.0449(8) Uani 1 1 d . . .
H3N H 0.1204 0.0754 0.0712 0.054 Uiso 1 1 calc R . .
N4 N -0.0465(2) 0.12677(16) 0.2828(2) 0.0454(8) Uani 1 1 d . . .
H4N H -0.0104 0.1086 0.2482 0.054 Uiso 1 1 calc R . .
C1 C 0.2945(3) 0.2167(2) 0.0499(2) 0.0370(8) Uani 1 1 d . . .
C2 C 0.2677(4) 0.0501(2) 0.3261(3) 0.0522(10) Uani 1 1 d . . .
C10 C 0.3186(2) 0.23531(17) 0.26265(19) 0.0295(7) Uani 1 1 d . . .
H10A H 0.3533 0.2375 0.3207 0.035 Uiso 1 1 calc R . .
H10B H 0.3019 0.2865 0.2434 0.035 Uiso 1 1 calc R . .
C11 C 0.5037(3) 0.12306(17) 0.28262(19) 0.0309(7) Uani 1 1 d . . .
C12 C 0.5000(3) 0.05231(18) 0.2521(2) 0.0347(8) Uani 1 1 d . . .
C13 C 0.5493(3) -0.0059(2) 0.3010(2) 0.0463(9) Uani 1 1 d . . .
H13 H 0.5439 -0.0547 0.2808 0.056 Uiso 1 1 calc R . .
C14 C 0.6067(3) 0.0082(2) 0.3796(2) 0.0529(10) Uani 1 1 d . . .
H14 H 0.6410 -0.0315 0.4132 0.064 Uiso 1 1 calc R . .
C15 C 0.6148(3) 0.0789(2) 0.4101(2) 0.0503(10) Uani 1 1 d . . .
H15 H 0.6553 0.0879 0.4640 0.060 Uiso 1 1 calc R . .
C16 C 0.5638(3) 0.1355(2) 0.3617(2) 0.0394(8) Uani 1 1 d . . .
H16 H 0.5693 0.1842 0.3822 0.047 Uiso 1 1 calc R . .
C17 C 0.5370(3) 0.0121(2) 0.1269(2) 0.0436(9) Uani 1 1 d . . .
H17A H 0.4996 0.0037 0.0705 0.052 Uiso 1 1 calc R . .
H17B H 0.5697 -0.0343 0.1519 0.052 Uiso 1 1 calc R . .
H17C H 0.6011 0.0482 0.1323 0.052 Uiso 1 1 calc R . .
C21 C 0.5416(3) 0.26603(18) 0.2275(2) 0.0337(7) Uani 1 1 d . . .
C22 C 0.6357(3) 0.2563(2) 0.1896(2) 0.0420(8) Uani 1 1 d . . .
C23 C 0.7271(4) 0.3086(3) 0.2053(3) 0.0671(13) Uani 1 1 d . . .
H23 H 0.7911 0.3038 0.1809 0.080 Uiso 1 1 calc R . .
C24 C 0.7258(4) 0.3668(3) 0.2555(3) 0.0856(17) Uani 1 1 d . . .
H24 H 0.7893 0.4013 0.2654 0.103 Uiso 1 1 calc R . .
C25 C 0.6351(4) 0.3763(3) 0.2917(3) 0.0748(15) Uani 1 1 d . . .
H25 H 0.6354 0.4170 0.3261 0.090 Uiso 1 1 calc R . .
C26 C 0.5432(3) 0.3260(2) 0.2772(2) 0.0516(10) Uani 1 1 d . . .
H26 H 0.4798 0.3325 0.3019 0.062 Uiso 1 1 calc R . .
C27 C 0.7306(3) 0.1883(3) 0.0998(3) 0.0664(13) Uani 1 1 d . . .
H27A H 0.7166 0.1429 0.0685 0.080 Uiso 1 1 calc R . .
H27B H 0.8086 0.1859 0.1379 0.080 Uiso 1 1 calc R . .
H27C H 0.7284 0.2305 0.0644 0.080 Uiso 1 1 calc R . .
C31 C 0.0900(3) 0.21794(19) 0.14828(19) 0.0336(7) Uani 1 1 d . . .
C32 C 0.0475(3) 0.1666(2) 0.0899(2) 0.0377(8) Uani 1 1 d . . .
C33 C -0.0254(3) 0.1900(3) 0.0166(2) 0.0533(11) Uani 1 1 d . . .
H33 H -0.0565 0.1552 -0.0241 0.064 Uiso 1 1 calc R . .
C34 C -0.0513(3) 0.2635(3) 0.0044(2) 0.0593(12) Uani 1 1 d . . .
H34 H -0.1008 0.2788 -0.0451 0.071 Uiso 1 1 calc R . .
C35 C -0.0081(3) 0.3151(2) 0.0612(2) 0.0526(10) Uani 1 1 d . . .
H35 H -0.0268 0.3657 0.0509 0.063 Uiso 1 1 calc R . .
C36 C 0.0638(3) 0.2931(2) 0.1346(2) 0.0388(8) Uani 1 1 d . . .
H36 H 0.0946 0.3285 0.1748 0.047 Uiso 1 1 calc R . .
C37 C -0.0324(3) 0.0417(2) 0.0883(3) 0.0631(13) Uani 1 1 d . . .
H37A H -0.0090 -0.0098 0.0999 0.076 Uiso 1 1 calc R . .
H37B H -0.0739 0.0466 0.0321 0.076 Uiso 1 1 calc R . .
H37C H -0.0854 0.0570 0.1212 0.076 Uiso 1 1 calc R . .
C41 C 0.1020(3) 0.22345(17) 0.31320(18) 0.0304(7) Uani 1 1 d . . .
C42 C -0.0045(3) 0.19074(19) 0.3218(2) 0.0383(8) Uani 1 1 d . . .
C43 C -0.0694(4) 0.2279(2) 0.3683(3) 0.0546(11) Uani 1 1 d . . .
H43 H -0.1412 0.2071 0.3751 0.066 Uiso 1 1 calc R . .
C44 C -0.0301(4) 0.2934(2) 0.4037(3) 0.0561(11) Uani 1 1 d . . .
H44 H -0.0770 0.3186 0.4329 0.067 Uiso 1 1 calc R . .
C45 C 0.0762(3) 0.3240(2) 0.3980(2) 0.0479(9) Uani 1 1 d . . .
H45 H 0.1044 0.3684 0.4252 0.057 Uiso 1 1 calc R . .
C46 C 0.1408(3) 0.28900(18) 0.3522(2) 0.0366(8) Uani 1 1 d . . .
H46 H 0.2133 0.3102 0.3473 0.044 Uiso 1 1 calc R . .
C47 C -0.1494(4) 0.0878(2) 0.2970(3) 0.0624(12) Uani 1 1 d . . .
H47A H -0.1661 0.0442 0.2627 0.075 Uiso 1 1 calc R . .
H47B H -0.2187 0.1205 0.2849 0.075 Uiso 1 1 calc R . .
H47C H -0.1323 0.0726 0.3527 0.075 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 Rh1 N1 175.65(12) . . ?
C1 Rh1 P1 93.68(11) . . ?
N1 Rh1 P1 85.23(8) . . ?
C1 Rh1 Cl1 93.51(11) . . ?
N1 Rh1 Cl1 87.97(8) . . ?
P1 Rh1 Cl1 171.19(4) . . ?
C2 Rh2 N3 173.77(14) . . ?
C2 Rh2 P2 92.03(13) . . ?
N3 Rh2 P2 84.79(8) . . ?
C2 Rh2 Cl2 94.28(13) . . ?
N3 Rh2 Cl2 89.49(9) . . ?
P2 Rh2 Cl2 171.10(4) . . ?
C21 P1 C11 102.88(14) . . ?
C21 P1 C10 103.23(14) . . ?
C11 P1 C10 105.80(15) . . ?
C21 P1 Rh1 123.79(11) . . ?
C11 P1 Rh1 102.93(11) . . ?
C10 P1 Rh1 116.20(10) . . ?
C31 P2 C41 102.79(14) . . ?
C31 P2 C10 105.55(15) . . ?
C41 P2 C10 103.99(14) . . ?
C31 P2 Rh2 103.13(11) . . ?
C41 P2 Rh2 122.78(11) . . ?
C10 P2 Rh2 116.55(10) . . ?
C12 N1 C17 109.7(2) . . ?
C12 N1 Rh1 115.86(19) . . ?
C17 N1 Rh1 109.7(2) . . ?
C22 N2 C27 121.6(3) . . ?
C32 N3 C37 112.0(3) . . ?
C32 N3 Rh2 115.8(2) . . ?
C37 N3 Rh2 110.7(3) . . ?
C42 N4 C47 122.0(3) . . ?
O1 C1 Rh1 177.6(3) . . ?
O2 C2 Rh2 177.1(4) . . ?
P2 C10 P1 113.99(16) . . ?
C12 C11 C16 119.1(3) . . ?
C12 C11 P1 117.1(2) . . ?
C16 C11 P1 123.8(3) . . ?
C13 C12 C11 120.3(3) . . ?
C13 C12 N1 121.2(3) . . ?
C11 C12 N1 118.5(3) . . ?
C12 C13 C14 119.0(4) . . ?
C15 C14 C13 121.3(4) . . ?
C16 C15 C14 119.0(4) . . ?
C15 C16 C11 121.2(3) . . ?
C26 C21 C22 119.7(3) . . ?
C26 C21 P1 121.7(3) . . ?
C22 C21 P1 118.4(2) . . ?
N2 C22 C23 121.5(3) . . ?
N2 C22 C21 121.1(3) . . ?
C23 C22 C21 117.4(3) . . ?
C24 C23 C22 121.1(4) . . ?
C25 C24 C23 121.6(4) . . ?
C24 C25 C26 118.9(4) . . ?
C25 C26 C21 121.4(4) . . ?
C32 C31 C36 120.7(3) . . ?
C32 C31 P2 117.4(3) . . ?
C36 C31 P2 121.9(3) . . ?
C31 C32 C33 119.1(4) . . ?
C31 C32 N3 118.9(3) . . ?
C33 C32 N3 122.0(3) . . ?
C34 C33 C32 119.5(4) . . ?
C35 C34 C33 122.1(4) . . ?
C34 C35 C36 119.4(4) . . ?
C35 C36 C31 119.1(3) . . ?
C46 C41 C42 119.5(3) . . ?
C46 C41 P2 120.6(2) . . ?
C42 C41 P2 119.5(2) . . ?
N4 C42 C43 120.9(3) . . ?
N4 C42 C41 121.0(3) . . ?
C43 C42 C41 118.0(3) . . ?
C44 C43 C42 120.6(3) . . ?
C43 C44 C45 121.5(3) . . ?
C46 C45 C44 118.9(4) . . ?
C45 C46 C41 121.4(3) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Rh1 C1 1.813(4) . ?
Rh1 N1 2.140(3) . ?
Rh1 P1 2.1958(8) . ?
Rh1 Cl1 2.3810(9) . ?
Rh2 C2 1.813(5) . ?
Rh2 N3 2.162(3) . ?
Rh2 P2 2.1859(8) . ?
Rh2 Cl2 2.3927(10) . ?
P1 C21 1.814(3) . ?
P1 C11 1.819(3) . ?
P1 C10 1.842(3) . ?
P2 C31 1.816(3) . ?
P2 C41 1.818(3) . ?
P2 C10 1.834(3) . ?
O1 C1 1.147(4) . ?
O2 C2 1.149(5) . ?
N1 C12 1.467(4) . ?
N1 C17 1.512(4) . ?
N2 C22 1.362(5) . ?
N2 C27 1.456(4) . ?
N3 C32 1.449(5) . ?
N3 C37 1.503(4) . ?
N4 C42 1.372(4) . ?
N4 C47 1.464(4) . ?
C11 C12 1.387(5) . ?
C11 C16 1.395(5) . ?
C12 C13 1.386(5) . ?
C13 C14 1.387(6) . ?
C14 C15 1.383(6) . ?
C15 C16 1.366(5) . ?
C21 C26 1.388(5) . ?
C21 C22 1.423(5) . ?
C22 C23 1.400(5) . ?
C23 C24 1.373(6) . ?
C24 C25 1.369(6) . ?
C25 C26 1.380(5) . ?
C31 C32 1.376(5) . ?
C31 C36 1.406(5) . ?
C32 C33 1.407(5) . ?
C33 C34 1.373(6) . ?
C34 C35 1.362(6) . ?
C35 C36 1.397(5) . ?
C41 C46 1.388(5) . ?
C41 C42 1.415(4) . ?
C42 C43 1.410(5) . ?
C43 C44 1.365(6) . ?
C44 C45 1.382(5) . ?
C45 C46 1.382(5) . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C1 Rh1 P1 C21 -63.20(16) . . . . ?
N1 Rh1 P1 C21 112.58(15) . . . . ?
Cl1 Rh1 P1 C21 152.2(2) . . . . ?
C1 Rh1 P1 C11 -178.58(14) . . . . ?
N1 Rh1 P1 C11 -2.81(12) . . . . ?
Cl1 Rh1 P1 C11 36.8(2) . . . . ?
C1 Rh1 P1 C10 66.32(15) . . . . ?
N1 Rh1 P1 C10 -117.91(14) . . . . ?
Cl1 Rh1 P1 C10 -78.3(2) . . . . ?
C2 Rh2 P2 C31 -176.53(15) . . . . ?
N3 Rh2 P2 C31 -1.90(12) . . . . ?
Cl2 Rh2 P2 C31 48.3(3) . . . . ?
C2 Rh2 P2 C41 -61.66(17) . . . . ?
N3 Rh2 P2 C41 112.97(14) . . . . ?
Cl2 Rh2 P2 C41 163.2(3) . . . . ?
C2 Rh2 P2 C10 68.37(17) . . . . ?
N3 Rh2 P2 C10 -117.00(14) . . . . ?
Cl2 Rh2 P2 C10 -66.8(3) . . . . ?
C1 Rh1 N1 C12 81.4(17) . . . . ?
P1 Rh1 N1 C12 5.73(19) . . . . ?
Cl1 Rh1 N1 C12 -168.7(2) . . . . ?
C1 Rh1 N1 C17 -43.5(17) . . . . ?
P1 Rh1 N1 C17 -119.2(2) . . . . ?
Cl1 Rh1 N1 C17 66.4(2) . . . . ?
C2 Rh2 N3 C32 61.3(14) . . . . ?
P2 Rh2 N3 C32 1.7(2) . . . . ?
Cl2 Rh2 N3 C32 -171.4(2) . . . . ?
C2 Rh2 N3 C37 -67.5(14) . . . . ?
P2 Rh2 N3 C37 -127.1(2) . . . . ?
Cl2 Rh2 N3 C37 59.8(2) . . . . ?
N1 Rh1 C1 O1 28(9) . . . . ?
P1 Rh1 C1 O1 103(8) . . . . ?
Cl1 Rh1 C1 O1 -82(8) . . . . ?
N3 Rh2 C2 O2 -5(9) . . . . ?
P2 Rh2 C2 O2 54(8) . . . . ?
Cl2 Rh2 C2 O2 -132(8) . . . . ?
C31 P2 C10 P1 -84.4(2) . . . . ?
C41 P2 C10 P1 167.81(17) . . . . ?
Rh2 P2 C10 P1 29.4(2) . . . . ?
C21 P1 C10 P2 168.53(17) . . . . ?
C11 P1 C10 P2 -83.7(2) . . . . ?
Rh1 P1 C10 P2 29.7(2) . . . . ?
C21 P1 C11 C12 -129.7(2) . . . . ?
C10 P1 C11 C12 122.3(2) . . . . ?
Rh1 P1 C11 C12 -0.1(3) . . . . ?
C21 P1 C11 C16 50.0(3) . . . . ?
C10 P1 C11 C16 -57.9(3) . . . . ?
Rh1 P1 C11 C16 179.7(2) . . . . ?
C16 C11 C12 C13 3.8(5) . . . . ?
P1 C11 C12 C13 -176.4(2) . . . . ?
C16 C11 C12 N1 -175.0(3) . . . . ?
P1 C11 C12 N1 4.8(4) . . . . ?
C17 N1 C12 C13 -61.3(4) . . . . ?
Rh1 N1 C12 C13 173.8(2) . . . . ?
C17 N1 C12 C11 117.5(3) . . . . ?
Rh1 N1 C12 C11 -7.4(3) . . . . ?
C11 C12 C13 C14 -2.8(5) . . . . ?
N1 C12 C13 C14 176.0(3) . . . . ?
C12 C13 C14 C15 0.4(5) . . . . ?
C13 C14 C15 C16 0.9(6) . . . . ?
C14 C15 C16 C11 0.2(5) . . . . ?
C12 C11 C16 C15 -2.5(5) . . . . ?
P1 C11 C16 C15 177.7(3) . . . . ?
C11 P1 C21 C26 -98.0(3) . . . . ?
C10 P1 C21 C26 11.9(4) . . . . ?
Rh1 P1 C21 C26 146.6(3) . . . . ?
C11 P1 C21 C22 76.9(3) . . . . ?
C10 P1 C21 C22 -173.2(3) . . . . ?
Rh1 P1 C21 C22 -38.5(3) . . . . ?
C27 N2 C22 C23 -6.4(6) . . . . ?
C27 N2 C22 C21 176.4(4) . . . . ?
C26 C21 C22 N2 177.8(4) . . . . ?
P1 C21 C22 N2 2.8(5) . . . . ?
C26 C21 C22 C23 0.4(6) . . . . ?
P1 C21 C22 C23 -174.5(3) . . . . ?
N2 C22 C23 C24 -177.2(5) . . . . ?
C21 C22 C23 C24 0.1(7) . . . . ?
C22 C23 C24 C25 -0.4(9) . . . . ?
C23 C24 C25 C26 0.2(9) . . . . ?
C24 C25 C26 C21 0.4(8) . . . . ?
C22 C21 C26 C25 -0.7(6) . . . . ?
P1 C21 C26 C25 174.1(4) . . . . ?
C41 P2 C31 C32 -126.3(3) . . . . ?
C10 P2 C31 C32 125.0(2) . . . . ?
Rh2 P2 C31 C32 2.3(3) . . . . ?
C41 P2 C31 C36 52.5(3) . . . . ?
C10 P2 C31 C36 -56.2(3) . . . . ?
Rh2 P2 C31 C36 -179.0(2) . . . . ?
C36 C31 C32 C33 -1.6(5) . . . . ?
P2 C31 C32 C33 177.2(2) . . . . ?
C36 C31 C32 N3 -179.9(3) . . . . ?
P2 C31 C32 N3 -1.1(4) . . . . ?
C37 N3 C32 C31 127.5(3) . . . . ?
Rh2 N3 C32 C31 -0.7(4) . . . . ?
C37 N3 C32 C33 -50.8(4) . . . . ?
Rh2 N3 C32 C33 -179.0(2) . . . . ?
C31 C32 C33 C34 0.9(5) . . . . ?
N3 C32 C33 C34 179.1(3) . . . . ?
C32 C33 C34 C35 0.3(6) . . . . ?
C33 C34 C35 C36 -0.7(6) . . . . ?
C34 C35 C36 C31 0.0(5) . . . . ?
C32 C31 C36 C35 1.2(5) . . . . ?
P2 C31 C36 C35 -177.6(2) . . . . ?
C31 P2 C41 C46 -95.7(3) . . . . ?
C10 P2 C41 C46 14.2(3) . . . . ?
Rh2 P2 C41 C46 149.3(2) . . . . ?
C31 P2 C41 C42 77.9(3) . . . . ?
C10 P2 C41 C42 -172.2(3) . . . . ?
Rh2 P2 C41 C42 -37.1(3) . . . . ?
C47 N4 C42 C43 -9.8(5) . . . . ?
C47 N4 C42 C41 173.6(3) . . . . ?
C46 C41 C42 N4 178.7(3) . . . . ?
P2 C41 C42 N4 5.0(4) . . . . ?
C46 C41 C42 C43 2.0(5) . . . . ?
P2 C41 C42 C43 -171.7(3) . . . . ?
N4 C42 C43 C44 -176.7(4) . . . . ?
C41 C42 C43 C44 0.0(6) . . . . ?
C42 C43 C44 C45 -2.7(7) . . . . ?
C43 C44 C45 C46 3.2(6) . . . . ?
C44 C45 C46 C41 -1.1(5) . . . . ?
C42 C41 C46 C45 -1.4(5) . . . . ?
P2 C41 C46 C45 172.1(3) . . . . ?
