#------------------------------------------------------------------------------
#$Date: 2016-03-25 09:17:47 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179718 $
#$URL: svn://www.crystallography.net/cod/cif/7/00/20/7002007.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7002007
loop_
_publ_author_name
'Zamora, Matthew T.'
'Ferguson, Michael J.'
'McDonald, Robert'
'Cowie, Martin'
_publ_section_title
;
 Carbene-anchored/pendent-imidazolium species as precursors to
 di-N-heterocyclic carbene-bridged mixed-metal complexes
;
_journal_issue                   35
_journal_name_full               'Dalton Transactions'
_journal_page_first              7269
_journal_paper_doi               10.1039/b906884h
_journal_year                    2009
_chemical_formula_moiety         'C24 H39 Br N4 Rh, 2(C H2 Cl2), Br'
_chemical_formula_sum            'C26 H43 Br2 Cl4 N4 Rh'
_chemical_formula_weight         816.17
_chemical_name_systematic
;
?
;
_space_group_IT_number           4
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  'P 2yb'
_symmetry_space_group_name_H-M   'P 1 21 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 101.093(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   8.5243(10)
_cell_length_b                   13.8891(16)
_cell_length_c                   14.5876(17)
_cell_measurement_reflns_used    5922
_cell_measurement_temperature    193(2)
_cell_measurement_theta_max      27.42
_cell_measurement_theta_min      2.43
_cell_volume                     1694.8(3)
_computing_cell_refinement       'Bruker SAINT (Bruker, 1997)'
_computing_data_collection       'Bruker SMART (Bruker, 1997)'
_computing_data_reduction        'Bruker SAINT (Bruker, 1997)'
_computing_molecular_graphics    'Bruker SHELXTL (Bruker, 1997)'
_computing_publication_material  'Bruker SHELXTL (Bruker, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SIR97 (Altomare et al., 1999)'
_diffrn_ambient_temperature      193(2)
_diffrn_detector_area_resol_mean 8.192
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type
'Bruker PLATFORM diffractometer/SMART 1000 CCD area detector'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0163
_diffrn_reflns_av_sigmaI/netI    0.0273
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            14567
_diffrn_reflns_theta_full        27.44
_diffrn_reflns_theta_max         27.44
_diffrn_reflns_theta_min         2.04
_diffrn_standards_decay_%        0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    3.199
_exptl_absorpt_correction_T_max  0.6455
_exptl_absorpt_correction_T_min  0.3270
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS (Sheldrick, 1996)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.599
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             820
_exptl_crystal_size_max          0.45
_exptl_crystal_size_mid          0.17
_exptl_crystal_size_min          0.15
_refine_diff_density_max         1.989
_refine_diff_density_min         -0.525
_refine_diff_density_rms         0.099
_refine_ls_abs_structure_details
'Flack H D (1983), Acta Cryst. A39, 876-881. 3641 Friedel pairs.'
_refine_ls_abs_structure_Flack   0.364(6)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.071
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     335
_refine_ls_number_reflns         7648
_refine_ls_number_restraints     1
_refine_ls_restrained_S_all      1.071
_refine_ls_R_factor_all          0.0315
_refine_ls_R_factor_gt           0.0294
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0504P)²+0.2277P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0745
_refine_ls_wR_factor_ref         0.0755
_reflns_number_gt                7288
_reflns_number_total             7648
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            b906884h.txt
_cod_data_source_block           2d
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      'P 21'
_cod_database_code               7002007
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh Rh 0.64721(2) 0.553501(17) 0.929564(15) 0.02277(6) Uani 1 1 d . . .
Br1 Br 0.83518(4) 0.62485(2) 0.83264(2) 0.03204(8) Uani 1 1 d . . .
Br2 Br 0.77381(4) 0.12361(3) 0.66496(2) 0.03771(9) Uani 1 1 d . . .
N11 N 0.7577(3) 0.35927(18) 0.87499(16) 0.0223(5) Uani 1 1 d . . .
N12 N 0.8936(3) 0.39169(18) 1.01126(17) 0.0227(5) Uani 1 1 d . . .
N13 N 0.6686(4) 0.4068(2) 0.61991(18) 0.0292(6) Uani 1 1 d . . .
N14 N 0.5423(4) 0.3803(2) 0.47853(19) 0.0309(6) Uani 1 1 d . . .
C1 C 0.5677(5) 0.6959(3) 0.9662(3) 0.0406(8) Uani 1 1 d . . .
H1 H 0.6453 0.7488 0.9613 0.049 Uiso 1 1 calc R . .
C2 C 0.4722(5) 0.6708(3) 0.8819(3) 0.0408(9) Uani 1 1 d . . .
H2 H 0.4938 0.7082 0.8271 0.049 Uiso 1 1 calc R . .
C3 C 0.3015(5) 0.6349(4) 0.8717(3) 0.0496(10) Uani 1 1 d . . .
H3A H 0.2377 0.6589 0.8122 0.060 Uiso 1 1 calc R . .
H3B H 0.2540 0.6611 0.9233 0.060 Uiso 1 1 calc R . .
C4 C 0.2931(5) 0.5241(3) 0.8731(3) 0.0467(10) Uani 1 1 d . . .
H4A H 0.1944 0.5044 0.8944 0.056 Uiso 1 1 calc R . .
H4B H 0.2866 0.4996 0.8088 0.056 Uiso 1 1 calc R . .
C5 C 0.4355(4) 0.4787(3) 0.9362(2) 0.0312(7) Uani 1 1 d . . .
H5 H 0.4437 0.4077 0.9270 0.037 Uiso 1 1 calc R . .
C6 C 0.5042(4) 0.5095(3) 1.0266(2) 0.0310(7) Uani 1 1 d . . .
H6 H 0.5523 0.4563 1.0691 0.037 Uiso 1 1 calc R . .
C7 C 0.4433(5) 0.5937(3) 1.0766(3) 0.0433(9) Uani 1 1 d . . .
H7A H 0.4641 0.5805 1.1446 0.052 Uiso 1 1 calc R . .
H7B H 0.3262 0.5993 1.0552 0.052 Uiso 1 1 calc R . .
C8 C 0.5213(5) 0.6893(3) 1.0595(3) 0.0477(10) Uani 1 1 d . . .
H8A H 0.4461 0.7423 1.0654 0.057 Uiso 1 1 calc R . .
H8B H 0.6179 0.6986 1.1086 0.057 Uiso 1 1 calc R . .
C10 C 0.7765(3) 0.4279(2) 0.94208(19) 0.0207(5) Uani 1 1 d . . .
C11 C 0.8578(4) 0.2821(2) 0.9001(2) 0.0277(6) Uani 1 1 d . . .
H11 H 0.8659 0.2261 0.8639 0.033 Uiso 1 1 calc R . .
C12 C 0.9415(4) 0.3014(2) 0.9858(2) 0.0273(6) Uani 1 1 d . . .
H12 H 1.0192 0.2610 1.0223 0.033 Uiso 1 1 calc R . .
C13 C 0.6579(4) 0.3695(2) 0.7823(2) 0.0245(6) Uani 1 1 d . . .
H13A H 0.5811 0.4230 0.7821 0.029 Uiso 1 1 calc R . .
H13B H 0.5967 0.3096 0.7646 0.029 Uiso 1 1 calc R . .
C14 C 0.7664(4) 0.3901(2) 0.7131(2) 0.0272(6) Uani 1 1 d . . .
H14A H 0.8326 0.4477 0.7334 0.033 Uiso 1 1 calc R . .
H14B H 0.8389 0.3349 0.7109 0.033 Uiso 1 1 calc R . .
C15 C 0.6364(4) 0.3406(2) 0.5533(2) 0.0310(7) Uani 1 1 d . . .
H15 H 0.6736 0.2760 0.5578 0.037 Uiso 1 1 calc R . .
C16 C 0.5949(5) 0.4909(3) 0.5881(2) 0.0384(8) Uani 1 1 d . . .
H16 H 0.5990 0.5497 0.6217 0.046 Uiso 1 1 calc R . .
C17 C 0.5147(5) 0.4750(3) 0.4995(2) 0.0381(8) Uani 1 1 d . . .
H17 H 0.4518 0.5203 0.4596 0.046 Uiso 1 1 calc R . .
C18 C 0.9679(4) 0.4376(2) 1.1021(2) 0.0274(6) Uani 1 1 d . . .
C19 C 0.9434(4) 0.5469(3) 1.0968(2) 0.0410(8) Uani 1 1 d . . .
H19A H 0.9949 0.5734 1.0478 0.062 Uiso 1 1 calc R . .
H19B H 0.9910 0.5759 1.1570 0.062 Uiso 1 1 calc R . .
H19C H 0.8288 0.5613 1.0823 0.062 Uiso 1 1 calc R . .
C20 C 0.8953(5) 0.3935(3) 1.1792(2) 0.0446(10) Uani 1 1 d . . .
H20A H 0.9438 0.4226 1.2392 0.067 Uiso 1 1 calc R . .
H20B H 0.9152 0.3240 1.1817 0.067 Uiso 1 1 calc R . .
H20C H 0.7798 0.4054 1.1667 0.067 Uiso 1 1 calc R . .
C21 C 1.1485(4) 0.4175(3) 1.1198(3) 0.0369(8) Uani 1 1 d . . .
H21A H 1.1951 0.4473 1.0704 0.055 Uiso 1 1 calc R . .
H21B H 1.1667 0.3478 1.1200 0.055 Uiso 1 1 calc R . .
H21C H 1.1988 0.4444 1.1805 0.055 Uiso 1 1 calc R . .
C22 C 0.4794(5) 0.3306(3) 0.3878(2) 0.0413(9) Uani 1 1 d . . .
C23 C 0.5229(5) 0.3903(3) 0.3101(2) 0.0431(9) Uani 1 1 d . . .
H23A H 0.6391 0.3894 0.3147 0.065 Uiso 1 1 calc R . .
H23B H 0.4871 0.4568 0.3154 0.065 Uiso 1 1 calc R . .
H23C H 0.4708 0.3636 0.2497 0.065 Uiso 1 1 calc R . .
C24 C 0.2964(7) 0.3268(5) 0.3777(3) 0.0729(17) Uani 1 1 d . . .
H24A H 0.2685 0.2852 0.4265 0.109 Uiso 1 1 calc R . .
H24B H 0.2488 0.3009 0.3162 0.109 Uiso 1 1 calc R . .
H24C H 0.2553 0.3919 0.3841 0.109 Uiso 1 1 calc R . .
C25 C 0.5545(10) 0.2320(3) 0.3909(3) 0.087(2) Uani 1 1 d . . .
H25A H 0.5253 0.1947 0.4422 0.131 Uiso 1 1 calc R . .
H25B H 0.6710 0.2384 0.4009 0.131 Uiso 1 1 calc R . .
H25C H 0.5158 0.1987 0.3316 0.131 Uiso 1 1 calc R . .
Cl1S Cl 0.9861(3) 0.0880(2) 0.38893(16) 0.1254(9) Uani 1 1 d . . .
Cl2S Cl 1.0523(2) -0.0639(2) 0.52575(17) 0.1326(10) Uani 1 1 d . . .
Cl3S Cl 0.63735(19) 0.67172(12) 0.35268(13) 0.0835(4) Uani 1 1 d . . .
Cl4S Cl 0.8162(2) 0.81654(16) 0.27873(19) 0.1133(8) Uani 1 1 d . . .
C1S C 0.9117(8) 0.0176(6) 0.4651(5) 0.095(3) Uani 1 1 d . . .
H1SA H 0.8193 -0.0189 0.4305 0.114 Uiso 1 1 calc R . .
H1SB H 0.8724 0.0593 0.5109 0.114 Uiso 1 1 calc R . .
C2S C 0.8265(7) 0.7122(6) 0.3474(6) 0.102(3) Uani 1 1 d . . .
H2SA H 0.8852 0.6614 0.3203 0.123 Uiso 1 1 calc R . .
H2SB H 0.8857 0.7262 0.4113 0.123 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Br Br -0.2901 2.4595 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C10 Rh C5 91.57(13) . . ?
C10 Rh C6 93.62(13) . . ?
C5 Rh C6 38.74(13) . . ?
C10 Rh C1 158.71(14) . . ?
C5 Rh C1 97.25(14) . . ?
C6 Rh C1 81.57(14) . . ?
C10 Rh C2 164.80(14) . . ?
C5 Rh C2 81.15(14) . . ?
C6 Rh C2 89.02(14) . . ?
C1 Rh C2 36.46(16) . . ?
C10 Rh Br1 89.74(8) . . ?
C5 Rh Br1 149.33(10) . . ?
C6 Rh Br1 171.25(10) . . ?
C1 Rh Br1 92.39(11) . . ?
C2 Rh Br1 89.85(11) . . ?
C10 N11 C11 112.1(2) . . ?
C10 N11 C13 124.6(2) . . ?
C11 N11 C13 123.0(3) . . ?
C10 N12 C12 110.1(2) . . ?
C10 N12 C18 128.3(3) . . ?
C12 N12 C18 121.7(2) . . ?
C15 N13 C16 109.1(3) . . ?
C15 N13 C14 124.7(3) . . ?
C16 N13 C14 126.2(3) . . ?
C15 N14 C17 108.2(3) . . ?
C15 N14 C22 125.8(3) . . ?
C17 N14 C22 126.0(3) . . ?
C2 C1 C8 125.6(4) . . ?
C2 C1 Rh 73.3(2) . . ?
C8 C1 Rh 108.4(3) . . ?
C1 C2 C3 124.0(4) . . ?
C1 C2 Rh 70.3(2) . . ?
C3 C2 Rh 111.2(3) . . ?
C2 C3 C4 111.9(3) . . ?
C5 C4 C3 113.0(3) . . ?
C6 C5 C4 125.9(3) . . ?
C6 C5 Rh 71.66(19) . . ?
C4 C5 Rh 111.2(3) . . ?
C5 C6 C7 124.4(3) . . ?
C5 C6 Rh 69.60(19) . . ?
C7 C6 Rh 112.9(2) . . ?
C6 C7 C8 113.0(3) . . ?
C1 C8 C7 113.7(3) . . ?
N11 C10 N12 104.0(2) . . ?
N11 C10 Rh 123.2(2) . . ?
N12 C10 Rh 132.8(2) . . ?
C12 C11 N11 106.5(3) . . ?
C11 C12 N12 107.4(3) . . ?
N11 C13 C14 108.2(2) . . ?
N13 C14 C13 109.5(3) . . ?
N13 C15 N14 108.5(3) . . ?
C17 C16 N13 107.4(3) . . ?
C16 C17 N14 106.8(3) . . ?
N12 C18 C20 108.8(3) . . ?
N12 C18 C19 110.3(3) . . ?
C20 C18 C19 111.5(3) . . ?
N12 C18 C21 108.1(3) . . ?
C20 C18 C21 109.9(3) . . ?
C19 C18 C21 108.1(3) . . ?
N14 C22 C23 108.2(3) . . ?
N14 C22 C25 108.4(3) . . ?
C23 C22 C25 111.0(4) . . ?
N14 C22 C24 106.5(4) . . ?
C23 C22 C24 109.8(4) . . ?
C25 C22 C24 112.8(5) . . ?
Cl1S C1S Cl2S 113.4(4) . . ?
Cl3S C2S Cl4S 110.5(3) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Rh C10 2.053(3) . ?
Rh C5 2.101(3) . ?
Rh C6 2.127(3) . ?
Rh C1 2.190(4) . ?
Rh C2 2.229(3) . ?
Rh Br1 2.5338(4) . ?
N11 C10 1.353(4) . ?
N11 C11 1.375(4) . ?
N11 C13 1.460(4) . ?
N12 C10 1.371(4) . ?
N12 C12 1.391(4) . ?
N12 C18 1.497(4) . ?
N13 C15 1.327(4) . ?
N13 C16 1.365(5) . ?
N13 C14 1.470(4) . ?
N14 C15 1.341(4) . ?
N14 C17 1.381(5) . ?
N14 C22 1.497(4) . ?
C1 C2 1.383(6) . ?
C1 C8 1.491(6) . ?
C2 C3 1.518(6) . ?
C3 C4 1.541(7) . ?
C4 C5 1.512(5) . ?
C5 C6 1.403(5) . ?
C6 C7 1.523(5) . ?
C7 C8 1.527(6) . ?
C11 C12 1.342(5) . ?
C13 C14 1.521(4) . ?
C16 C17 1.359(5) . ?
C18 C20 1.514(5) . ?
C18 C19 1.532(5) . ?
C18 C21 1.536(5) . ?
C22 C23 1.508(5) . ?
C22 C25 1.508(7) . ?
C22 C24 1.540(7) . ?
Cl1S C1S 1.692(8) . ?
Cl2S C1S 1.759(8) . ?
Cl3S C2S 1.723(7) . ?
Cl4S C2S 1.755(8) . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C10 Rh C1 C2 -178.1(3) . . . . ?
C5 Rh C1 C2 -64.3(2) . . . . ?
C6 Rh C1 C2 -99.9(2) . . . . ?
Br1 Rh C1 C2 86.5(2) . . . . ?
C10 Rh C1 C8 -55.3(5) . . . . ?
C5 Rh C1 C8 58.4(3) . . . . ?
C6 Rh C1 C8 22.9(3) . . . . ?
C2 Rh C1 C8 122.7(4) . . . . ?
Br1 Rh C1 C8 -150.8(3) . . . . ?
C8 C1 C2 C3 1.8(6) . . . . ?
Rh C1 C2 C3 102.8(4) . . . . ?
C8 C1 C2 Rh -101.0(4) . . . . ?
C10 Rh C2 C1 177.3(4) . . . . ?
C5 Rh C2 C1 115.2(2) . . . . ?
C6 Rh C2 C1 77.1(2) . . . . ?
Br1 Rh C2 C1 -94.2(2) . . . . ?
C10 Rh C2 C3 57.5(6) . . . . ?
C5 Rh C2 C3 -4.7(3) . . . . ?
C6 Rh C2 C3 -42.8(3) . . . . ?
C1 Rh C2 C3 -119.9(4) . . . . ?
Br1 Rh C2 C3 145.9(3) . . . . ?
C1 C2 C3 C4 -93.9(5) . . . . ?
Rh C2 C3 C4 -14.0(5) . . . . ?
C2 C3 C4 C5 33.8(5) . . . . ?
C3 C4 C5 C6 44.4(5) . . . . ?
C3 C4 C5 Rh -37.8(4) . . . . ?
C10 Rh C5 C6 93.8(2) . . . . ?
C1 Rh C5 C6 -66.7(2) . . . . ?
C2 Rh C5 C6 -99.6(2) . . . . ?
Br1 Rh C5 C6 -174.03(16) . . . . ?
C10 Rh C5 C4 -143.9(3) . . . . ?
C6 Rh C5 C4 122.3(4) . . . . ?
C1 Rh C5 C4 55.5(3) . . . . ?
C2 Rh C5 C4 22.7(3) . . . . ?
Br1 Rh C5 C4 -51.8(4) . . . . ?
C4 C5 C6 C7 1.1(6) . . . . ?
Rh C5 C6 C7 104.4(3) . . . . ?
C4 C5 C6 Rh -103.3(4) . . . . ?
C10 Rh C6 C5 -88.0(2) . . . . ?
C1 Rh C6 C5 112.9(2) . . . . ?
C2 Rh C6 C5 77.0(2) . . . . ?
Br1 Rh C6 C5 159.6(5) . . . . ?
C10 Rh C6 C7 152.2(3) . . . . ?
C5 Rh C6 C7 -119.8(4) . . . . ?
C1 Rh C6 C7 -7.0(3) . . . . ?
C2 Rh C6 C7 -42.8(3) . . . . ?
Br1 Rh C6 C7 39.8(8) . . . . ?
C5 C6 C7 C8 -90.5(5) . . . . ?
Rh C6 C7 C8 -10.2(4) . . . . ?
C2 C1 C8 C7 46.9(6) . . . . ?
Rh C1 C8 C7 -35.4(4) . . . . ?
C6 C7 C8 C1 31.0(5) . . . . ?
C11 N11 C10 N12 0.3(3) . . . . ?
C13 N11 C10 N12 -172.9(3) . . . . ?
C11 N11 C10 Rh -179.8(2) . . . . ?
C13 N11 C10 Rh 7.0(4) . . . . ?
C12 N12 C10 N11 -1.1(3) . . . . ?
C18 N12 C10 N11 178.1(3) . . . . ?
C12 N12 C10 Rh 179.1(2) . . . . ?
C18 N12 C10 Rh -1.8(5) . . . . ?
C5 Rh C10 N11 68.0(3) . . . . ?
C6 Rh C10 N11 106.7(3) . . . . ?
C1 Rh C10 N11 -177.3(3) . . . . ?
C2 Rh C10 N11 7.1(6) . . . . ?
Br1 Rh C10 N11 -81.4(2) . . . . ?
C5 Rh C10 N12 -112.2(3) . . . . ?
C6 Rh C10 N12 -73.4(3) . . . . ?
C1 Rh C10 N12 2.5(5) . . . . ?
C2 Rh C10 N12 -173.1(4) . . . . ?
Br1 Rh C10 N12 98.5(3) . . . . ?
C10 N11 C11 C12 0.6(4) . . . . ?
C13 N11 C11 C12 173.9(3) . . . . ?
N11 C11 C12 N12 -1.2(4) . . . . ?
C10 N12 C12 C11 1.5(4) . . . . ?
C18 N12 C12 C11 -177.7(3) . . . . ?
C10 N11 C13 C14 102.3(3) . . . . ?
C11 N11 C13 C14 -70.1(4) . . . . ?
C15 N13 C14 C13 -97.3(4) . . . . ?
C16 N13 C14 C13 81.8(4) . . . . ?
N11 C13 C14 N13 -176.6(2) . . . . ?
C16 N13 C15 N14 -0.2(4) . . . . ?
C14 N13 C15 N14 179.0(3) . . . . ?
C17 N14 C15 N13 -0.1(4) . . . . ?
C22 N14 C15 N13 179.5(3) . . . . ?
C15 N13 C16 C17 0.4(5) . . . . ?
C14 N13 C16 C17 -178.8(3) . . . . ?
N13 C16 C17 N14 -0.4(5) . . . . ?
C15 N14 C17 C16 0.3(4) . . . . ?
C22 N14 C17 C16 -179.2(4) . . . . ?
C10 N12 C18 C20 101.8(4) . . . . ?
C12 N12 C18 C20 -79.2(4) . . . . ?
C10 N12 C18 C19 -20.8(4) . . . . ?
C12 N12 C18 C19 158.2(3) . . . . ?
C10 N12 C18 C21 -138.9(3) . . . . ?
C12 N12 C18 C21 40.2(4) . . . . ?
C15 N14 C22 C23 -126.6(4) . . . . ?
C17 N14 C22 C23 52.8(5) . . . . ?
C15 N14 C22 C25 -6.3(6) . . . . ?
C17 N14 C22 C25 173.2(5) . . . . ?
C15 N14 C22 C24 115.4(4) . . . . ?
C17 N14 C22 C24 -65.1(5) . . . . ?
