#------------------------------------------------------------------------------
#$Date: 2016-02-14 06:40:26 +0200 (Sun, 14 Feb 2016) $
#$Revision: 176432 $
#$URL: svn://www.crystallography.net/cod/cif/7/00/21/7002188.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7002188
loop_
_publ_author_name
'Bennett, Martin A.'
'Bhargava, Suresh K.'
'Mirzadeh, Nedaossadat'
'Privér, Steven H.'
'Wagler, Jörg'
'Willis, Anthony C.'
_publ_section_title
;
 Synthesis and interconversions of digold(i), tetragold(i), digold(ii),
 gold(i)--gold(iii) and digold(iii) complexes of fluorine-substituted
 aryl carbanions
;
_journal_issue                   36
_journal_name_full               'Dalton Transactions'
_journal_page_first              7537
_journal_page_last               7551
_journal_paper_doi               10.1039/b906769h
_journal_year                    2009
_chemical_formula_moiety         'C36 H20 Au2 F8 P2'
_chemical_formula_sum            'C36 H20 Au2 F8 P2'
_chemical_formula_weight         1060.39
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.4600(10)
_cell_angle_beta                 113.9920(10)
_cell_angle_gamma                98.3480(10)
_cell_formula_units_Z            2
_cell_length_a                   10.7539(2)
_cell_length_b                   12.7320(2)
_cell_length_c                   12.8969(2)
_cell_measurement_reflns_used    40911
_cell_measurement_temperature    110(2)
_cell_measurement_theta_max      35.631
_cell_measurement_theta_min      2.546
_cell_volume                     1591.77(5)
_computing_cell_refinement       DENZO-SMN
_computing_data_collection       'Nonius Collect'
_computing_data_reduction        Scalepack
_computing_molecular_graphics    'ORTEP32 for windows (Farugia)'
_computing_publication_material  'Ciftab (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      110(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Nonius Kappa CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0644
_diffrn_reflns_av_sigmaI/netI    0.0334
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            53442
_diffrn_reflns_theta_full        28.00
_diffrn_reflns_theta_max         28.00
_diffrn_reflns_theta_min         2.78
_exptl_absorpt_coefficient_mu    9.381
_exptl_absorpt_correction_T_max  0.574
_exptl_absorpt_correction_T_min  0.421
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SORTAV
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    2.212
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       polyhedron
_exptl_crystal_F_000             992
_exptl_crystal_size_max          0.11
_exptl_crystal_size_mid          0.06
_exptl_crystal_size_min          0.06
_refine_diff_density_max         2.028
_refine_diff_density_min         -1.030
_refine_diff_density_rms         0.141
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.019
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     433
_refine_ls_number_reflns         7679
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.019
_refine_ls_R_factor_all          0.0470
_refine_ls_R_factor_gt           0.0240
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0247P)²+1.0031P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0537
_refine_ls_wR_factor_ref         0.0591
_reflns_number_gt                5225
_reflns_number_total             7679
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b906769h.txt
_cod_data_source_block           neda00302
_cod_original_sg_symbol_Hall     -P1
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7002188
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 0.854860(15) 0.475202(11) 0.448109(12) 0.01750(5) Uani 1 1 d . . .
Au2 Au 0.145001(15) 0.026134(11) 0.050227(12) 0.01611(5) Uani 1 1 d . . .
P1 P 0.87473(11) 0.32355(8) 0.54244(9) 0.0179(2) Uani 1 1 d . . .
P2 P 0.11528(11) 0.17610(8) 0.12977(9) 0.0174(2) Uani 1 1 d . . .
F1 F 0.9770(3) 0.14656(18) 0.6937(2) 0.0306(6) Uani 1 1 d . . .
F2 F 1.2309(3) 0.13723(19) 0.8497(2) 0.0309(6) Uani 1 1 d . . .
F3 F 1.4450(3) 0.2868(2) 0.8656(2) 0.0383(7) Uani 1 1 d . . .
F4 F 1.4056(2) 0.4486(2) 0.7307(2) 0.0341(6) Uani 1 1 d . . .
F5 F 0.0064(2) 0.34312(17) 0.2232(2) 0.0272(6) Uani 1 1 d . . .
F6 F -0.2529(3) 0.34597(18) 0.2004(2) 0.0298(6) Uani 1 1 d . . .
F7 F -0.4609(2) 0.19399(18) 0.06585(19) 0.0260(5) Uani 1 1 d . . .
F8 F -0.4130(2) 0.04226(18) -0.0531(2) 0.0263(5) Uani 1 1 d . . .
C1 C 1.0533(4) 0.3111(3) 0.6336(3) 0.0187(8) Uani 1 1 d . . .
C2 C 1.0795(4) 0.2261(3) 0.7017(3) 0.0212(9) Uani 1 1 d . . .
C3 C 1.2083(5) 0.2179(3) 0.7801(3) 0.0240(9) Uani 1 1 d . . .
C4 C 1.3181(4) 0.2944(3) 0.7887(4) 0.0260(10) Uani 1 1 d . . .
C5 C 1.2927(4) 0.3769(3) 0.7183(3) 0.0221(9) Uani 1 1 d . . .
C6 C 1.1647(4) 0.3902(3) 0.6409(3) 0.0181(8) Uani 1 1 d . . .
C7 C 0.7907(4) 0.3188(3) 0.6397(3) 0.0195(8) Uani 1 1 d . . .
C8 C 0.7325(4) 0.2250(3) 0.6695(4) 0.0246(9) Uani 1 1 d . . .
H8 H 0.7238 0.1584 0.6313 0.030 Uiso 1 1 calc R . .
C9 C 0.6872(4) 0.2306(4) 0.7564(4) 0.0292(10) Uani 1 1 d . . .
H9 H 0.6487 0.1672 0.7780 0.035 Uiso 1 1 calc R . .
C10 C 0.6980(5) 0.3274(4) 0.8113(4) 0.0312(11) Uani 1 1 d . . .
H10 H 0.6692 0.3301 0.8717 0.037 Uiso 1 1 calc R . .
C11 C 0.7507(5) 0.4200(4) 0.7782(4) 0.0292(10) Uani 1 1 d . . .
H11 H 0.7547 0.4867 0.8141 0.035 Uiso 1 1 calc R . .
C12 C 0.7978(4) 0.4167(3) 0.6932(3) 0.0242(9) Uani 1 1 d . . .
H12 H 0.8348 0.4807 0.6714 0.029 Uiso 1 1 calc R . .
C13 C 0.8003(4) 0.2033(3) 0.4464(3) 0.0190(9) Uani 1 1 d . . .
C14 C 0.8853(5) 0.1458(3) 0.4176(3) 0.0241(9) Uani 1 1 d . . .
H14 H 0.9828 0.1641 0.4544 0.029 Uiso 1 1 calc R . .
C15 C 0.8245(5) 0.0620(3) 0.3347(3) 0.0250(9) Uani 1 1 d . . .
H15 H 0.8810 0.0228 0.3144 0.030 Uiso 1 1 calc R . .
C16 C 0.6829(5) 0.0346(3) 0.2812(3) 0.0271(10) Uani 1 1 d . . .
H16 H 0.6430 -0.0238 0.2255 0.032 Uiso 1 1 calc R . .
C17 C 0.5989(5) 0.0917(3) 0.3081(3) 0.0247(9) Uani 1 1 d . . .
H17 H 0.5014 0.0729 0.2708 0.030 Uiso 1 1 calc R . .
C18 C 0.6578(4) 0.1770(3) 0.3904(3) 0.0213(9) Uani 1 1 d . . .
H18 H 0.6004 0.2172 0.4082 0.026 Uiso 1 1 calc R . .
C19 C -0.0645(4) 0.1827(3) 0.1028(3) 0.0167(8) Uani 1 1 d . . .
C20 C -0.0948(4) 0.2641(3) 0.1561(3) 0.0201(9) Uani 1 1 d . . .
C21 C -0.2267(5) 0.2680(3) 0.1437(3) 0.0219(9) Uani 1 1 d . . .
C22 C -0.3326(4) 0.1916(3) 0.0752(3) 0.0205(9) Uani 1 1 d . . .
C23 C -0.3031(4) 0.1125(3) 0.0179(3) 0.0194(8) Uani 1 1 d . . .
C24 C -0.1722(4) 0.1040(3) 0.0299(3) 0.0176(8) Uani 1 1 d . . .
C25 C 0.1765(4) 0.2933(3) 0.0737(3) 0.0166(8) Uani 1 1 d . . .
C26 C 0.3183(4) 0.3195(3) 0.1034(4) 0.0239(9) Uani 1 1 d . . .
H26 H 0.3809 0.2803 0.1567 0.029 Uiso 1 1 calc R . .
C27 C 0.3666(4) 0.4029(3) 0.0547(4) 0.0248(9) Uani 1 1 d . . .
H27 H 0.4630 0.4216 0.0760 0.030 Uiso 1 1 calc R . .
C28 C 0.2774(5) 0.4592(3) -0.0241(4) 0.0271(10) Uani 1 1 d . . .
H28 H 0.3121 0.5166 -0.0567 0.033 Uiso 1 1 calc R . .
C29 C 0.1368(5) 0.4323(3) -0.0560(4) 0.0280(10) Uani 1 1 d . . .
H29 H 0.0750 0.4704 -0.1115 0.034 Uiso 1 1 calc R . .
C30 C 0.0856(5) 0.3494(3) -0.0070(3) 0.0244(9) Uani 1 1 d . . .
H30 H -0.0109 0.3313 -0.0285 0.029 Uiso 1 1 calc R . .
C31 C 0.2100(4) 0.1889(3) 0.2838(3) 0.0205(9) Uani 1 1 d . . .
C32 C 0.2049(5) 0.0949(3) 0.3387(4) 0.0289(10) Uani 1 1 d . . .
H32 H 0.1565 0.0298 0.2950 0.035 Uiso 1 1 calc R . .
C33 C 0.2692(5) 0.0961(4) 0.4551(4) 0.0360(11) Uani 1 1 d . . .
H33 H 0.2647 0.0320 0.4916 0.043 Uiso 1 1 calc R . .
C34 C 0.3406(5) 0.1902(4) 0.5195(4) 0.0348(11) Uani 1 1 d . . .
H34 H 0.3846 0.1909 0.6001 0.042 Uiso 1 1 calc R . .
C35 C 0.3477(5) 0.2826(4) 0.4665(4) 0.0374(12) Uani 1 1 d . . .
H35 H 0.3973 0.3470 0.5108 0.045 Uiso 1 1 calc R . .
C36 C 0.2828(5) 0.2828(3) 0.3482(4) 0.0277(10) Uani 1 1 d . . .
H36 H 0.2886 0.3470 0.3122 0.033 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C6 Au1 P1 178.54(10) 2_766 . ?
C6 Au1 Au1 93.07(11) 2_766 2_766 ?
P1 Au1 Au1 87.45(3) . 2_766 ?
C24 Au2 P2 176.46(10) 2 . ?
C24 Au2 Au2 93.66(11) 2 2 ?
P2 Au2 Au2 86.54(3) . 2 ?
C7 P1 C13 107.16(18) . . ?
C7 P1 C1 103.93(18) . . ?
C13 P1 C1 107.06(18) . . ?
C7 P1 Au1 112.05(14) . . ?
C13 P1 Au1 112.63(13) . . ?
C1 P1 Au1 113.42(13) . . ?
C25 P2 C31 107.85(18) . . ?
C25 P2 C19 106.65(18) . . ?
C31 P2 C19 105.80(18) . . ?
C25 P2 Au2 109.94(12) . . ?
C31 P2 Au2 111.91(14) . . ?
C19 P2 Au2 114.34(13) . . ?
C2 C1 C6 119.4(4) . . ?
C2 C1 P1 119.4(3) . . ?
C6 C1 P1 121.1(3) . . ?
F1 C2 C3 116.4(3) . . ?
F1 C2 C1 121.3(4) . . ?
C3 C2 C1 122.4(4) . . ?
F2 C3 C2 121.6(4) . . ?
F2 C3 C4 119.4(4) . . ?
C2 C3 C4 119.0(4) . . ?
F3 C4 C5 122.1(4) . . ?
F3 C4 C3 119.3(4) . . ?
C5 C4 C3 118.6(4) . . ?
F4 C5 C6 120.1(4) . . ?
F4 C5 C4 115.4(4) . . ?
C6 C5 C4 124.5(4) . . ?
C5 C6 C1 116.0(4) . . ?
C5 C6 Au1 118.9(3) . 2_766 ?
C1 C6 Au1 125.0(3) . 2_766 ?
C12 C7 C8 120.1(4) . . ?
C12 C7 P1 115.4(3) . . ?
C8 C7 P1 124.3(3) . . ?
C9 C8 C7 118.9(4) . . ?
C9 C8 H8 120.5 . . ?
C7 C8 H8 120.5 . . ?
C10 C9 C8 120.8(4) . . ?
C10 C9 H9 119.6 . . ?
C8 C9 H9 119.6 . . ?
C11 C10 C9 119.8(4) . . ?
C11 C10 H10 120.1 . . ?
C9 C10 H10 120.1 . . ?
C10 C11 C12 120.6(4) . . ?
C10 C11 H11 119.7 . . ?
C12 C11 H11 119.7 . . ?
C11 C12 C7 119.7(4) . . ?
C11 C12 H12 120.1 . . ?
C7 C12 H12 120.1 . . ?
C18 C13 C14 119.9(4) . . ?
C18 C13 P1 119.2(3) . . ?
C14 C13 P1 120.3(3) . . ?
C15 C14 C13 118.9(4) . . ?
C15 C14 H14 120.5 . . ?
C13 C14 H14 120.5 . . ?
C16 C15 C14 120.9(4) . . ?
C16 C15 H15 119.6 . . ?
C14 C15 H15 119.6 . . ?
C15 C16 C17 120.4(4) . . ?
C15 C16 H16 119.8 . . ?
C17 C16 H16 119.8 . . ?
C16 C17 C18 119.6(4) . . ?
C16 C17 H17 120.2 . . ?
C18 C17 H17 120.2 . . ?
C13 C18 C17 120.2(4) . . ?
C13 C18 H18 119.9 . . ?
C17 C18 H18 119.9 . . ?
C20 C19 C24 119.7(4) . . ?
C20 C19 P2 119.9(3) . . ?
C24 C19 P2 120.4(3) . . ?
F5 C20 C21 117.5(3) . . ?
F5 C20 C19 120.8(4) . . ?
C21 C20 C19 121.7(4) . . ?
F6 C21 C22 119.7(4) . . ?
F6 C21 C20 120.6(4) . . ?
C22 C21 C20 119.8(4) . . ?
F7 C22 C21 119.6(4) . . ?
F7 C22 C23 121.8(4) . . ?
C21 C22 C23 118.6(4) . . ?
F8 C23 C24 120.6(3) . . ?
F8 C23 C22 115.8(3) . . ?
C24 C23 C22 123.6(4) . . ?
C23 C24 C19 116.7(3) . . ?
C23 C24 Au2 118.4(3) . 2 ?
C19 C24 Au2 124.8(3) . 2 ?
C30 C25 C26 119.6(4) . . ?
C30 C25 P2 121.7(3) . . ?
C26 C25 P2 118.3(3) . . ?
C27 C26 C25 119.6(4) . . ?
C27 C26 H26 120.2 . . ?
C25 C26 H26 120.2 . . ?
C28 C27 C26 121.0(4) . . ?
C28 C27 H27 119.5 . . ?
C26 C27 H27 119.5 . . ?
C27 C28 C29 119.9(4) . . ?
C27 C28 H28 120.1 . . ?
C29 C28 H28 120.1 . . ?
C28 C29 C30 120.2(4) . . ?
C28 C29 H29 119.9 . . ?
C30 C29 H29 119.9 . . ?
C25 C30 C29 119.7(4) . . ?
C25 C30 H30 120.2 . . ?
C29 C30 H30 120.2 . . ?
C36 C31 C32 119.2(4) . . ?
C36 C31 P2 125.2(3) . . ?
C32 C31 P2 115.6(3) . . ?
C33 C32 C31 120.5(4) . . ?
C33 C32 H32 119.8 . . ?
C31 C32 H32 119.8 . . ?
C32 C33 C34 120.3(4) . . ?
C32 C33 H33 119.9 . . ?
C34 C33 H33 119.9 . . ?
C35 C34 C33 119.7(4) . . ?
C35 C34 H34 120.1 . . ?
C33 C34 H34 120.1 . . ?
C34 C35 C36 120.8(4) . . ?
C34 C35 H35 119.6 . . ?
C36 C35 H35 119.6 . . ?
C31 C36 C35 119.6(4) . . ?
C31 C36 H36 120.2 . . ?
C35 C36 H36 120.2 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 C6 2.058(4) 2_766 ?
Au1 P1 2.2803(10) . ?
Au1 Au1 2.8198(3) 2_766 ?
Au2 C24 2.063(4) 2 ?
Au2 P2 2.2831(10) . ?
Au2 Au2 2.8187(3) 2 ?
P1 C7 1.817(4) . ?
P1 C13 1.823(4) . ?
P1 C1 1.831(4) . ?
P2 C25 1.817(4) . ?
P2 C31 1.820(4) . ?
P2 C19 1.835(4) . ?
F1 C2 1.354(4) . ?
F2 C3 1.353(4) . ?
F3 C4 1.340(5) . ?
F4 C5 1.361(4) . ?
F5 C20 1.359(4) . ?
F6 C21 1.355(4) . ?
F7 C22 1.340(4) . ?
F8 C23 1.354(4) . ?
C1 C2 1.386(5) . ?
C1 C6 1.420(5) . ?
C2 C3 1.362(6) . ?
C3 C4 1.383(6) . ?
C4 C5 1.378(6) . ?
C5 C6 1.369(6) . ?
C6 Au1 2.058(4) 2_766 ?
C7 C12 1.397(6) . ?
C7 C8 1.397(5) . ?
C8 C9 1.396(6) . ?
C8 H8 0.9500 . ?
C9 C10 1.382(6) . ?
C9 H9 0.9500 . ?
C10 C11 1.381(6) . ?
C10 H10 0.9500 . ?
C11 C12 1.384(5) . ?
C11 H11 0.9500 . ?
C12 H12 0.9500 . ?
C13 C18 1.389(6) . ?
C13 C14 1.405(6) . ?
C14 C15 1.386(5) . ?
C14 H14 0.9500 . ?
C15 C16 1.380(6) . ?
C15 H15 0.9500 . ?
C16 C17 1.381(6) . ?
C16 H16 0.9500 . ?
C17 C18 1.393(5) . ?
C17 H17 0.9500 . ?
C18 H18 0.9500 . ?
C19 C20 1.386(5) . ?
C19 C24 1.411(5) . ?
C20 C21 1.370(6) . ?
C21 C22 1.368(6) . ?
C22 C23 1.391(5) . ?
C23 C24 1.373(5) . ?
C24 Au2 2.063(4) 2 ?
C25 C30 1.391(6) . ?
C25 C26 1.400(6) . ?
C26 C27 1.381(6) . ?
C26 H26 0.9500 . ?
C27 C28 1.374(6) . ?
C27 H27 0.9500 . ?
C28 C29 1.383(6) . ?
C28 H28 0.9500 . ?
C29 C30 1.394(5) . ?
C29 H29 0.9500 . ?
C30 H30 0.9500 . ?
C31 C36 1.384(6) . ?
C31 C32 1.402(6) . ?
C32 C33 1.373(6) . ?
C32 H32 0.9500 . ?
C33 C34 1.383(6) . ?
C33 H33 0.9500 . ?
C34 C35 1.373(7) . ?
C34 H34 0.9500 . ?
C35 C36 1.396(6) . ?
C35 H35 0.9500 . ?
C36 H36 0.9500 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Au1 Au1 P1 C7 118.49(14) 2_766 . . . ?
Au1 Au1 P1 C13 -120.60(15) 2_766 . . . ?
Au1 Au1 P1 C1 1.20(13) 2_766 . . . ?
Au2 Au2 P2 C25 -115.02(14) 2 . . . ?
Au2 Au2 P2 C31 125.14(14) 2 . . . ?
Au2 Au2 P2 C19 4.88(13) 2 . . . ?
C7 P1 C1 C2 53.7(3) . . . . ?
C13 P1 C1 C2 -59.5(3) . . . . ?
Au1 P1 C1 C2 175.7(3) . . . . ?
C7 P1 C1 C6 -122.4(3) . . . . ?
C13 P1 C1 C6 124.4(3) . . . . ?
Au1 P1 C1 C6 -0.5(3) . . . . ?
C6 C1 C2 F1 -177.0(3) . . . . ?
P1 C1 C2 F1 6.8(5) . . . . ?
C6 C1 C2 C3 3.2(6) . . . . ?
P1 C1 C2 C3 -173.0(3) . . . . ?
F1 C2 C3 F2 -3.1(6) . . . . ?
C1 C2 C3 F2 176.7(4) . . . . ?
F1 C2 C3 C4 177.3(3) . . . . ?
C1 C2 C3 C4 -3.0(6) . . . . ?
F2 C3 C4 F3 0.4(6) . . . . ?
C2 C3 C4 F3 -180.0(4) . . . . ?
F2 C3 C4 C5 -179.1(4) . . . . ?
C2 C3 C4 C5 0.6(6) . . . . ?
F3 C4 C5 F4 1.2(6) . . . . ?
C3 C4 C5 F4 -179.4(4) . . . . ?
F3 C4 C5 C6 -177.9(4) . . . . ?
C3 C4 C5 C6 1.5(6) . . . . ?
F4 C5 C6 C1 179.7(3) . . . . ?
C4 C5 C6 C1 -1.2(6) . . . . ?
F4 C5 C6 Au1 -3.9(5) . . . 2_766 ?
C4 C5 C6 Au1 175.2(3) . . . 2_766 ?
C2 C1 C6 C5 -1.1(5) . . . . ?
P1 C1 C6 C5 175.1(3) . . . . ?
C2 C1 C6 Au1 -177.3(3) . . . 2_766 ?
P1 C1 C6 Au1 -1.1(5) . . . 2_766 ?
C13 P1 C7 C12 -159.2(3) . . . . ?
C1 P1 C7 C12 87.6(3) . . . . ?
Au1 P1 C7 C12 -35.2(3) . . . . ?
C13 P1 C7 C8 26.4(4) . . . . ?
C1 P1 C7 C8 -86.7(4) . . . . ?
Au1 P1 C7 C8 150.4(3) . . . . ?
C12 C7 C8 C9 -2.6(6) . . . . ?
P1 C7 C8 C9 171.5(3) . . . . ?
C7 C8 C9 C10 0.8(6) . . . . ?
C8 C9 C10 C11 1.7(7) . . . . ?
C9 C10 C11 C12 -2.4(7) . . . . ?
C10 C11 C12 C7 0.7(7) . . . . ?
C8 C7 C12 C11 1.9(6) . . . . ?
P1 C7 C12 C11 -172.7(3) . . . . ?
C7 P1 C13 C18 51.0(4) . . . . ?
C1 P1 C13 C18 162.0(3) . . . . ?
Au1 P1 C13 C18 -72.7(3) . . . . ?
C7 P1 C13 C14 -137.4(3) . . . . ?
C1 P1 C13 C14 -26.4(4) . . . . ?
Au1 P1 C13 C14 98.9(3) . . . . ?
C18 C13 C14 C15 -1.2(6) . . . . ?
P1 C13 C14 C15 -172.8(3) . . . . ?
C13 C14 C15 C16 -0.3(6) . . . . ?
C14 C15 C16 C17 1.1(6) . . . . ?
C15 C16 C17 C18 -0.4(6) . . . . ?
C14 C13 C18 C17 1.9(6) . . . . ?
P1 C13 C18 C17 173.5(3) . . . . ?
C16 C17 C18 C13 -1.1(6) . . . . ?
C25 P2 C19 C20 -65.0(3) . . . . ?
C31 P2 C19 C20 49.7(4) . . . . ?
Au2 P2 C19 C20 173.3(3) . . . . ?
C25 P2 C19 C24 116.4(3) . . . . ?
C31 P2 C19 C24 -129.0(3) . . . . ?
Au2 P2 C19 C24 -5.3(3) . . . . ?
C24 C19 C20 F5 -177.4(3) . . . . ?
P2 C19 C20 F5 3.9(5) . . . . ?
C24 C19 C20 C21 2.8(6) . . . . ?
P2 C19 C20 C21 -175.9(3) . . . . ?
F5 C20 C21 F6 -2.5(6) . . . . ?
C19 C20 C21 F6 177.3(3) . . . . ?
F5 C20 C21 C22 178.6(3) . . . . ?
C19 C20 C21 C22 -1.6(6) . . . . ?
F6 C21 C22 F7 -0.8(6) . . . . ?
C20 C21 C22 F7 178.1(3) . . . . ?
F6 C21 C22 C23 -180.0(3) . . . . ?
C20 C21 C22 C23 -1.1(6) . . . . ?
F7 C22 C23 F8 4.0(5) . . . . ?
C21 C22 C23 F8 -176.8(3) . . . . ?
F7 C22 C23 C24 -176.4(4) . . . . ?
C21 C22 C23 C24 2.8(6) . . . . ?
F8 C23 C24 C19 178.0(3) . . . . ?
C22 C23 C24 C19 -1.6(6) . . . . ?
F8 C23 C24 Au2 -5.9(5) . . . 2 ?
C22 C23 C24 Au2 174.5(3) . . . 2 ?
C20 C19 C24 C23 -1.2(5) . . . . ?
P2 C19 C24 C23 177.4(3) . . . . ?
C20 C19 C24 Au2 -177.0(3) . . . 2 ?
P2 C19 C24 Au2 1.6(5) . . . 2 ?
C31 P2 C25 C30 -133.5(3) . . . . ?
C19 P2 C25 C30 -20.2(4) . . . . ?
Au2 P2 C25 C30 104.3(3) . . . . ?
C31 P2 C25 C26 53.9(3) . . . . ?
C19 P2 C25 C26 167.2(3) . . . . ?
Au2 P2 C25 C26 -68.3(3) . . . . ?
C30 C25 C26 C27 1.9(6) . . . . ?
P2 C25 C26 C27 174.7(3) . . . . ?
C25 C26 C27 C28 -1.3(6) . . . . ?
C26 C27 C28 C29 -0.3(6) . . . . ?
C27 C28 C29 C30 1.1(6) . . . . ?
C26 C25 C30 C29 -1.1(6) . . . . ?
P2 C25 C30 C29 -173.6(3) . . . . ?
C28 C29 C30 C25 -0.4(6) . . . . ?
C25 P2 C31 C36 17.7(4) . . . . ?
C19 P2 C31 C36 -96.1(4) . . . . ?
Au2 P2 C31 C36 138.8(3) . . . . ?
C25 P2 C31 C32 -163.2(3) . . . . ?
C19 P2 C31 C32 83.0(4) . . . . ?
Au2 P2 C31 C32 -42.1(4) . . . . ?
C36 C31 C32 C33 1.1(7) . . . . ?
P2 C31 C32 C33 -178.0(4) . . . . ?
C31 C32 C33 C34 -0.4(7) . . . . ?
C32 C33 C34 C35 -0.4(7) . . . . ?
C33 C34 C35 C36 0.4(7) . . . . ?
C32 C31 C36 C35 -1.1(7) . . . . ?
P2 C31 C36 C35 178.0(3) . . . . ?
C34 C35 C36 C31 0.3(7) . . . . ?
