#------------------------------------------------------------------------------
#$Date: 2016-03-25 09:20:00 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179719 $
#$URL: svn://www.crystallography.net/cod/cif/7/00/21/7002190.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7002190
loop_
_publ_author_name
'Bennett, Martin A.'
'Bhargava, Suresh K.'
'Mirzadeh, Nedaossadat'
'Privér, Steven H.'
'Wagler, Jörg'
'Willis, Anthony C.'
_publ_section_title
;
 Synthesis and interconversions of digold(i), tetragold(i), digold(ii),
 gold(i)--gold(iii) and digold(iii) complexes of fluorine-substituted
 aryl carbanions
;
_journal_issue                   36
_journal_name_full               'Dalton Transactions'
_journal_page_first              7537
_journal_page_last               7551
_journal_paper_doi               10.1039/b906769h
_journal_year                    2009
_chemical_formula_moiety         'C72 H40 Au4 F16 P4, 0.86(C H2 Cl2)'
_chemical_formula_sum            'C75.44 H46.88 Au4 Cl6.88 F16 P4'
_chemical_formula_weight         2412.93
_chemical_name_systematic
;
?
;
_space_group_IT_number           86
_symmetry_cell_setting           tetragonal
_symmetry_space_group_name_Hall  '-P 4bc'
_symmetry_space_group_name_H-M   'P 42/n :2'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   15.9440(3)
_cell_length_b                   15.9440(3)
_cell_length_c                   14.7921(2)
_cell_measurement_reflns_used    28531
_cell_measurement_temperature    110(2)
_cell_measurement_theta_max      35.631
_cell_measurement_theta_min      2.546
_cell_volume                     3760.32(11)
_computing_cell_refinement       DENZO-SMN
_computing_data_collection       'Nonius Collect'
_computing_data_reduction        Scalepack
_computing_molecular_graphics    'ORTEP32 for windows (Farugia)'
_computing_publication_material  'Ciftab (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      110(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Nonius Kappa CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0415
_diffrn_reflns_av_sigmaI/netI    0.0347
_diffrn_reflns_limit_h_max       25
_diffrn_reflns_limit_h_min       -25
_diffrn_reflns_limit_k_max       25
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            41538
_diffrn_reflns_theta_full        35.00
_diffrn_reflns_theta_max         35.00
_diffrn_reflns_theta_min         2.90
_exptl_absorpt_coefficient_mu    8.192
_exptl_absorpt_correction_T_max  0.484
_exptl_absorpt_correction_T_min  0.374
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SORTAV
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    2.131
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       polyhedron
_exptl_crystal_F_000             2273
_exptl_crystal_size_max          0.17
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.09
_refine_diff_density_max         1.689
_refine_diff_density_min         -1.669
_refine_diff_density_rms         0.147
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.032
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     283
_refine_ls_number_reflns         8284
_refine_ls_number_restraints     25
_refine_ls_restrained_S_all      1.031
_refine_ls_R_factor_all          0.0527
_refine_ls_R_factor_gt           0.0318
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0346P)²+3.9891P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0722
_refine_ls_wR_factor_ref         0.0774
_reflns_number_gt                6147
_reflns_number_total             8284
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b906769h.txt
_cod_data_source_block           neda00402
_cod_original_sg_symbol_H-M      P42/n
_cod_database_code               7002190
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, -y+1/2, z'
'-y, x+1/2, z+1/2'
'y+1/2, -x, z+1/2'
'-x, -y, -z'
'x-1/2, y-1/2, -z'
'y, -x-1/2, -z-1/2'
'-y-1/2, x, -z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 0.278802(6) 0.378055(6) 0.215592(6) 0.01890(4) Uani 1 1 d . A .
P1 P 0.23491(5) 0.45117(5) 0.34001(5) 0.02152(14) Uani 1 1 d D . .
F1 F 0.26177(16) 0.47407(15) 0.55141(13) 0.0479(6) Uani 1 1 d . A .
F2 F 0.20992(16) 0.36970(17) 0.68071(13) 0.0525(6) Uani 1 1 d . . .
F3 F 0.12760(14) 0.22585(17) 0.63800(13) 0.0456(5) Uani 1 1 d . A .
F4 F 0.09754(12) 0.18624(13) 0.46511(12) 0.0329(4) Uani 1 1 d . . .
C1 C 0.20478(17) 0.38526(19) 0.43515(17) 0.0223(5) Uani 1 1 d . A .
C2 C 0.2208(2) 0.4039(2) 0.5253(2) 0.0301(7) Uani 1 1 d . . .
C3 C 0.1948(2) 0.3510(3) 0.5937(2) 0.0346(8) Uani 1 1 d . A .
C4 C 0.1527(2) 0.2784(2) 0.5722(2) 0.0317(7) Uani 1 1 d . . .
C5 C 0.13741(18) 0.2600(2) 0.4826(2) 0.0259(6) Uani 1 1 d . A .
C6 C 0.16169(17) 0.31118(18) 0.41195(17) 0.0207(5) Uani 1 1 d . . .
C7 C 0.30810(19) 0.5315(2) 0.3784(2) 0.0278(6) Uani 1 1 d . A .
C8 C 0.2808(2) 0.6100(2) 0.4060(3) 0.0456(10) Uani 1 1 d . . .
H8 H 0.2228 0.6235 0.4038 0.055 Uiso 1 1 calc R A .
C9 C 0.3382(3) 0.6688(3) 0.4368(4) 0.0553(12) Uani 1 1 d . A .
H9 H 0.3190 0.7220 0.4571 0.066 Uiso 1 1 calc R . .
C10 C 0.4223(2) 0.6509(3) 0.4382(3) 0.0540(12) Uani 1 1 d . . .
H10 H 0.4614 0.6920 0.4580 0.065 Uiso 1 1 calc R A .
C11 C 0.4500(2) 0.5727(3) 0.4105(4) 0.0557(12) Uani 1 1 d . A .
H11 H 0.5082 0.5598 0.4118 0.067 Uiso 1 1 calc R . .
C12 C 0.3929(2) 0.5131(2) 0.3808(3) 0.0403(8) Uani 1 1 d . . .
H12 H 0.4120 0.4594 0.3619 0.048 Uiso 1 1 calc R A .
C13A C 0.1431(8) 0.5128(16) 0.3107(10) 0.0240(13) Uani 0.50 1 d PD A 1
C14A C 0.1448(6) 0.5507(9) 0.2253(9) 0.0288(15) Uani 0.50 1 d PD A 1
H14A H 0.1921 0.5448 0.1869 0.035 Uiso 0.50 1 calc PR A 1
C15A C 0.0755(6) 0.5970(10) 0.1983(11) 0.0364(14) Uani 0.50 1 d PD A 1
H15A H 0.0760 0.6245 0.1413 0.044 Uiso 0.50 1 calc PR A 1
C16A C 0.0056(7) 0.6037(6) 0.2537(5) 0.0364(14) Uani 0.50 1 d PD A 1
H16A H -0.0400 0.6386 0.2368 0.044 Uiso 0.50 1 calc PR A 1
C17A C 0.0030(5) 0.5590(5) 0.3342(6) 0.0364(14) Uani 0.50 1 d PD A 1
H17A H -0.0463 0.5614 0.3702 0.044 Uiso 0.50 1 calc PR A 1
C18A C 0.0703(5) 0.5111(5) 0.3634(5) 0.0288(15) Uani 0.50 1 d PD A 1
H18A H 0.0671 0.4784 0.4170 0.035 Uiso 0.50 1 calc PR A 1
C13B C 0.1385(9) 0.5063(16) 0.3115(8) 0.0240(13) Uani 0.50 1 d PD A 2
C14B C 0.1291(6) 0.5458(10) 0.2277(9) 0.0326(17) Uani 0.50 1 d PD A 2
H14B H 0.1699 0.5351 0.1823 0.039 Uiso 0.50 1 calc PR A 2
C15B C 0.0636(6) 0.5998(10) 0.2071(11) 0.0370(14) Uani 0.50 1 d PD A 2
H15B H 0.0599 0.6252 0.1491 0.044 Uiso 0.50 1 calc PR A 2
C16B C 0.0035(7) 0.6160(6) 0.2727(5) 0.0370(14) Uani 0.50 1 d PD A 2
H16B H -0.0436 0.6502 0.2586 0.044 Uiso 0.50 1 calc PR A 2
C17B C 0.0121(5) 0.5824(5) 0.3587(6) 0.0370(14) Uani 0.50 1 d PD A 2
H17B H -0.0286 0.5935 0.4040 0.044 Uiso 0.50 1 calc PR A 2
C18B C 0.0811(5) 0.5323(5) 0.3774(6) 0.0326(17) Uani 0.50 1 d PD A 2
H18B H 0.0898 0.5147 0.4380 0.039 Uiso 0.50 1 calc PR A 2
Cl1 Cl 0.3292(2) 0.9300(3) 0.6984(3) 0.0775(11) Uani 0.36 1 d PD B 3
C19 C 0.4128(6) 0.8710(8) 0.6669(5) 0.058(3) Uani 0.36 1 d PD B 3
H19A H 0.4639 0.8959 0.6937 0.069 Uiso 0.36 1 calc PR B 3
H19B H 0.4061 0.8142 0.6930 0.069 Uiso 0.36 1 calc PR B 3
Cl2 Cl 0.4276(3) 0.8614(3) 0.5540(3) 0.0611(11) Uani 0.36 1 d PD B 3
Cl3 Cl 0.26876(18) 0.77706(18) 0.6816(2) 0.0799(8) Uani 0.50 1 d PD . 4
C20 C 0.3313(4) 0.8629(5) 0.6758(6) 0.074(3) Uani 0.50 1 d PD C 4
H20A H 0.2957 0.9129 0.6658 0.089 Uiso 0.50 1 calc PR C 4
H20B H 0.3599 0.8701 0.7347 0.089 Uiso 0.50 1 calc PR C 4
Cl4 Cl 0.4049(3) 0.8589(3) 0.5932(3) 0.0842(13) Uani 0.50 1 d PD C 4
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C6 Au1 P1 166.37(8) 7_566 . ?
C6 Au1 Au1 110.07(7) 7_566 8_656 ?
P1 Au1 Au1 75.62(2) . 8_656 ?
C6 Au1 Au1 85.71(8) 7_566 7_566 ?
P1 Au1 Au1 107.468(19) . 7_566 ?
Au1 Au1 Au1 83.927(2) 8_656 7_566 ?
C13A P1 C1 106.5(4) . . ?
C13B P1 C1 103.6(5) . . ?
C13A P1 C7 102.1(9) . . ?
C13B P1 C7 105.9(10) . . ?
C1 P1 C7 109.47(14) . . ?
C13A P1 Au1 109.3(7) . . ?
C13B P1 Au1 108.6(6) . . ?
C1 P1 Au1 114.09(9) . . ?
C7 P1 Au1 114.36(11) . . ?
C2 C1 C6 120.1(3) . . ?
C2 C1 P1 124.8(2) . . ?
C6 C1 P1 115.11(19) . . ?
F1 C2 C3 116.1(3) . . ?
F1 C2 C1 122.6(3) . . ?
C3 C2 C1 121.2(3) . . ?
F2 C3 C4 119.8(3) . . ?
F2 C3 C2 120.9(3) . . ?
C4 C3 C2 119.3(3) . . ?
F3 C4 C3 120.1(3) . . ?
F3 C4 C5 120.7(3) . . ?
C3 C4 C5 119.2(3) . . ?
F4 C5 C4 116.7(3) . . ?
F4 C5 C6 119.9(3) . . ?
C4 C5 C6 123.4(3) . . ?
C5 C6 C1 116.6(3) . . ?
C5 C6 Au1 117.3(2) . 8_656 ?
C1 C6 Au1 125.7(2) . 8_656 ?
C12 C7 C8 119.4(3) . . ?
C12 C7 P1 119.0(2) . . ?
C8 C7 P1 121.7(2) . . ?
C7 C8 C9 120.0(3) . . ?
C7 C8 H8 120.0 . . ?
C9 C8 H8 120.0 . . ?
C10 C9 C8 120.6(4) . . ?
C10 C9 H9 119.7 . . ?
C8 C9 H9 119.7 . . ?
C9 C10 C11 119.6(4) . . ?
C9 C10 H10 120.2 . . ?
C11 C10 H10 120.2 . . ?
C10 C11 C12 120.1(3) . . ?
C10 C11 H11 120.0 . . ?
C12 C11 H11 120.0 . . ?
C7 C12 C11 120.3(3) . . ?
C7 C12 H12 119.9 . . ?
C11 C12 H12 119.9 . . ?
C18A C13A C14A 121.8(7) . . ?
C18A C13A P1 121.6(6) . . ?
C14A C13A P1 115.7(5) . . ?
C15A C14A C13A 118.4(9) . . ?
C15A C14A H14A 120.8 . . ?
C13A C14A H14A 120.8 . . ?
C14A C15A C16A 120.6(11) . . ?
C14A C15A H15A 119.7 . . ?
C16A C15A H15A 119.7 . . ?
C15A C16A C17A 119.5(9) . . ?
C15A C16A H16A 120.3 . . ?
C17A C16A H16A 120.3 . . ?
C18A C17A C16A 121.8(7) . . ?
C18A C17A H17A 119.1 . . ?
C16A C17A H17A 119.1 . . ?
C17A C18A C13A 117.2(7) . . ?
C17A C18A H18A 121.4 . . ?
C13A C18A H18A 121.4 . . ?
C18B C13B C14B 114.5(9) . . ?
C18B C13B P1 122.3(7) . . ?
C14B C13B P1 120.8(6) . . ?
C15B C14B C13B 123.6(10) . . ?
C15B C14B H14B 118.2 . . ?
C13B C14B H14B 118.2 . . ?
C14B C15B C16B 118.9(10) . . ?
C14B C15B H15B 120.6 . . ?
C16B C15B H15B 120.6 . . ?
C17B C16B C15B 120.0(9) . . ?
C17B C16B H16B 120.0 . . ?
C15B C16B H16B 120.0 . . ?
C18B C17B C16B 118.9(8) . . ?
C18B C17B H17B 120.5 . . ?
C16B C17B H17B 120.5 . . ?
C17B C18B C13B 123.4(7) . . ?
C17B C18B H18B 118.3 . . ?
C13B C18B H18B 118.3 . . ?
Cl2 C19 Cl1 115.5(6) . . ?
Cl2 C19 H19A 108.4 . . ?
Cl1 C19 H19A 108.4 . . ?
Cl2 C19 H19B 108.4 . . ?
Cl1 C19 H19B 108.4 . . ?
H19A C19 H19B 107.5 . . ?
Cl3 Cl3 C20 176.8(4) 2_565 . ?
Cl4 C20 Cl3 114.5(5) . . ?
Cl4 C20 H20A 108.6 . . ?
Cl3 C20 H20A 108.6 . . ?
Cl4 C20 H20B 108.6 . . ?
Cl3 C20 H20B 108.6 . . ?
H20A C20 H20B 107.6 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 C6 2.056(3) 7_566 ?
Au1 P1 2.2882(7) . ?
Au1 Au1 3.12972(16) 8_656 ?
Au1 Au1 3.12972(16) 7_566 ?
P1 C13A 1.815(6) . ?
P1 C13B 1.820(6) . ?
P1 C1 1.821(3) . ?
P1 C7 1.823(3) . ?
F1 C2 1.353(4) . ?
F2 C3 1.343(3) . ?
F3 C4 1.345(4) . ?
F4 C5 1.361(4) . ?
C1 C2 1.390(4) . ?
C1 C6 1.409(4) . ?
C2 C3 1.380(5) . ?
C3 C4 1.376(5) . ?
C4 C5 1.379(4) . ?
C5 C6 1.381(4) . ?
C6 Au1 2.056(3) 8_656 ?
C7 C12 1.383(4) . ?
C7 C8 1.387(5) . ?
C8 C9 1.387(5) . ?
C8 H8 0.9500 . ?
C9 C10 1.372(6) . ?
C9 H9 0.9500 . ?
C10 C11 1.385(6) . ?
C10 H10 0.9500 . ?
C11 C12 1.388(5) . ?
C11 H11 0.9500 . ?
C12 H12 0.9500 . ?
C13A C18A 1.399(4) . ?
C13A C14A 1.399(4) . ?
C14A C15A 1.387(4) . ?
C14A H14A 0.9500 . ?
C15A C16A 1.388(4) . ?
C15A H15A 0.9500 . ?
C16A C17A 1.388(4) . ?
C16A H16A 0.9500 . ?
C17A C18A 1.387(4) . ?
C17A H17A 0.9500 . ?
C18A H18A 0.9500 . ?
C13B C18B 1.400(4) . ?
C13B C14B 1.400(4) . ?
C14B C15B 1.388(4) . ?
C14B H14B 0.9500 . ?
C15B C16B 1.388(4) . ?
C15B H15B 0.9500 . ?
C16B C17B 1.388(4) . ?
C16B H16B 0.9500 . ?
C17B C18B 1.387(4) . ?
C17B H17B 0.9500 . ?
C18B H18B 0.9500 . ?
Cl1 C19 1.695(5) . ?
C19 Cl2 1.695(5) . ?
C19 H19A 0.9900 . ?
C19 H19B 0.9900 . ?
Cl3 Cl3 1.050(5) 2_565 ?
Cl3 C20 1.695(5) . ?
C20 Cl4 1.695(5) . ?
C20 H20A 0.9900 . ?
C20 H20B 0.9900 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C6 Au1 P1 C13A 39.8(8) 7_566 . . . ?
Au1 Au1 P1 C13A -76.7(8) 8_656 . . . ?
Au1 Au1 P1 C13A -155.4(8) 7_566 . . . ?
C6 Au1 P1 C13B 44.0(9) 7_566 . . . ?
Au1 Au1 P1 C13B -72.5(8) 8_656 . . . ?
Au1 Au1 P1 C13B -151.2(8) 7_566 . . . ?
C6 Au1 P1 C1 158.9(3) 7_566 . . . ?
Au1 Au1 P1 C1 42.44(10) 8_656 . . . ?
Au1 Au1 P1 C1 -36.31(10) 7_566 . . . ?
C6 Au1 P1 C7 -74.0(4) 7_566 . . . ?
Au1 Au1 P1 C7 169.55(12) 8_656 . . . ?
Au1 Au1 P1 C7 90.81(12) 7_566 . . . ?
C13A P1 C1 C2 -97.3(10) . . . . ?
C13B P1 C1 C2 -100.1(9) . . . . ?
C7 P1 C1 C2 12.5(3) . . . . ?
Au1 P1 C1 C2 142.1(2) . . . . ?
C13A P1 C1 C6 82.2(10) . . . . ?
C13B P1 C1 C6 79.4(9) . . . . ?
C7 P1 C1 C6 -168.1(2) . . . . ?
Au1 P1 C1 C6 -38.5(2) . . . . ?
C6 C1 C2 F1 -179.9(3) . . . . ?
P1 C1 C2 F1 -0.5(5) . . . . ?
C6 C1 C2 C3 -0.3(5) . . . . ?
P1 C1 C2 C3 179.1(3) . . . . ?
F1 C2 C3 F2 0.2(5) . . . . ?
C1 C2 C3 F2 -179.5(3) . . . . ?
F1 C2 C3 C4 180.0(3) . . . . ?
C1 C2 C3 C4 0.3(5) . . . . ?
F2 C3 C4 F3 -0.8(5) . . . . ?
C2 C3 C4 F3 179.4(3) . . . . ?
F2 C3 C4 C5 179.9(3) . . . . ?
C2 C3 C4 C5 0.1(5) . . . . ?
F3 C4 C5 F4 -1.1(4) . . . . ?
C3 C4 C5 F4 178.3(3) . . . . ?
F3 C4 C5 C6 -179.9(3) . . . . ?
C3 C4 C5 C6 -0.5(5) . . . . ?
F4 C5 C6 C1 -178.2(2) . . . . ?
C4 C5 C6 C1 0.5(4) . . . . ?
F4 C5 C6 Au1 7.7(4) . . . 8_656 ?
C4 C5 C6 Au1 -173.6(2) . . . 8_656 ?
C2 C1 C6 C5 -0.1(4) . . . . ?
P1 C1 C6 C5 -179.6(2) . . . . ?
C2 C1 C6 Au1 173.5(2) . . . 8_656 ?
P1 C1 C6 Au1 -6.0(3) . . . 8_656 ?
C13A P1 C7 C12 -160.5(4) . . . . ?
C13B P1 C7 C12 -162.1(4) . . . . ?
C1 P1 C7 C12 86.8(3) . . . . ?
Au1 P1 C7 C12 -42.6(3) . . . . ?
C13A P1 C7 C8 20.1(5) . . . . ?
C13B P1 C7 C8 18.5(5) . . . . ?
C1 P1 C7 C8 -92.6(3) . . . . ?
Au1 P1 C7 C8 138.0(3) . . . . ?
C12 C7 C8 C9 -0.9(7) . . . . ?
P1 C7 C8 C9 178.5(4) . . . . ?
C7 C8 C9 C10 1.7(8) . . . . ?
C8 C9 C10 C11 -1.5(8) . . . . ?
C9 C10 C11 C12 0.6(8) . . . . ?
C8 C7 C12 C11 0.0(6) . . . . ?
P1 C7 C12 C11 -179.4(4) . . . . ?
C10 C11 C12 C7 0.1(7) . . . . ?
C13B P1 C13A C18A 50(13) . . . . ?
C1 P1 C13A C18A 7(2) . . . . ?
C7 P1 C13A C18A -108(2) . . . . ?
Au1 P1 C13A C18A 130.2(19) . . . . ?
C13B P1 C13A C14A -120(16) . . . . ?
C1 P1 C13A C14A -163.4(18) . . . . ?
C7 P1 C13A C14A 82(2) . . . . ?
Au1 P1 C13A C14A -40(2) . . . . ?
C18A C13A C14A C15A 9(3) . . . . ?
P1 C13A C14A C15A 178.6(16) . . . . ?
C13A C14A C15A C16A -2(3) . . . . ?
C14A C15A C16A C17A -4(2) . . . . ?
C15A C16A C17A C18A 3.5(16) . . . . ?
C16A C17A C18A C13A 3.2(19) . . . . ?
C14A C13A C18A C17A -9(3) . . . . ?
P1 C13A C18A C17A -178.7(13) . . . . ?
C13A P1 C13B C18B -102(16) . . . . ?
C1 P1 C13B C18B 36(2) . . . . ?
C7 P1 C13B C18B -79(2) . . . . ?
Au1 P1 C13B C18B 157.5(18) . . . . ?
C13A P1 C13B C14B 60(13) . . . . ?
C1 P1 C13B C14B -163(2) . . . . ?
C7 P1 C13B C14B 82(2) . . . . ?
Au1 P1 C13B C14B -41(2) . . . . ?
C18B C13B C14B C15B -6(3) . . . . ?
P1 C13B C14B C15B -169.3(16) . . . . ?
C13B C14B C15B C16B 0(3) . . . . ?
C14B C15B C16B C17B 4(2) . . . . ?
C15B C16B C17B C18B -0.4(15) . . . . ?
C16B C17B C18B C13B -6.9(19) . . . . ?
C14B C13B C18B C17B 10(3) . . . . ?
P1 C13B C18B C17B 172.6(13) . . . . ?
