#------------------------------------------------------------------------------
#$Date: 2016-02-14 06:40:26 +0200 (Sun, 14 Feb 2016) $
#$Revision: 176432 $
#$URL: svn://www.crystallography.net/cod/cif/7/00/21/7002193.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7002193
loop_
_publ_author_name
'Bennett, Martin A.'
'Bhargava, Suresh K.'
'Mirzadeh, Nedaossadat'
'Privér, Steven H.'
'Wagler, Jörg'
'Willis, Anthony C.'
_publ_section_title
;
 Synthesis and interconversions of digold(i), tetragold(i), digold(ii),
 gold(i)--gold(iii) and digold(iii) complexes of fluorine-substituted
 aryl carbanions
;
_journal_issue                   36
_journal_name_full               'Dalton Transactions'
_journal_page_first              7537
_journal_page_last               7551
_journal_paper_doi               10.1039/b906769h
_journal_year                    2009
_chemical_formula_moiety         'C36 H20 Au2 Cl4 F8 P2, C H2 Cl2'
_chemical_formula_sum            'C37 H22 Au2 Cl6 F8 P2'
_chemical_formula_weight         1287.12
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                60.9030(10)
_cell_angle_beta                 82.7430(10)
_cell_angle_gamma                88.0100(10)
_cell_formula_units_Z            2
_cell_length_a                   10.7369(2)
_cell_length_b                   14.4038(2)
_cell_length_c                   14.5209(2)
_cell_measurement_reflns_used    99774
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      45.294
_cell_measurement_theta_min      2.546
_cell_volume                     1945.63(6)
_computing_cell_refinement       DENZO-SMN
_computing_data_collection       'Nonius Collect'
_computing_data_reduction        Scalepack
_computing_molecular_graphics    'ORTEP32 for windows (Farugia)'
_computing_publication_material  'Ciftab (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Nonius Kappa CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0631
_diffrn_reflns_av_sigmaI/netI    0.0412
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       24
_diffrn_reflns_limit_k_min       -24
_diffrn_reflns_limit_l_max       25
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_number            80292
_diffrn_reflns_theta_full        38.00
_diffrn_reflns_theta_max         38.00
_diffrn_reflns_theta_min         2.63
_exptl_absorpt_coefficient_mu    8.094
_exptl_absorpt_correction_T_max  0.377
_exptl_absorpt_correction_T_min  0.179
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SORTAV
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    2.197
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       piece
_exptl_crystal_F_000             1212
_exptl_crystal_size_max          0.29
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.12
_refine_diff_density_max         5.374
_refine_diff_density_min         -5.879
_refine_diff_density_rms         0.234
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.020
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     496
_refine_ls_number_reflns         21176
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.020
_refine_ls_R_factor_all          0.0419
_refine_ls_R_factor_gt           0.0338
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0469P)²+2.8162P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0838
_refine_ls_wR_factor_ref         0.0868
_reflns_number_gt                18335
_reflns_number_total             21176
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b906769h.txt
_cod_data_source_block           neda01001
_cod_original_cell_volume        1945.64(6)
_cod_original_sg_symbol_Hall     -P1
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7002193
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 0.706302(8) 0.072265(6) 0.285977(6) 0.01097(2) Uani 1 1 d . . .
Au2 Au 0.802458(8) -0.255239(7) 0.170384(7) 0.01412(2) Uani 1 1 d . . .
P1 P 0.72581(6) 0.25743(5) 0.20069(5) 0.01194(9) Uani 1 1 d . . .
P2 P 0.67161(6) -0.15705(5) 0.22792(5) 0.01205(9) Uani 1 1 d . . .
Cl1 Cl 0.48894(6) 0.05101(5) 0.33187(6) 0.01922(10) Uani 1 1 d . . .
Cl2 Cl 0.92640(7) -0.35056(6) 0.10342(6) 0.02349(12) Uani 1 1 d . . .
Cl3 Cl 0.68779(7) -0.19163(6) 0.03043(5) 0.02312(12) Uani 1 1 d . . .
Cl4 Cl 0.92423(7) -0.30591(7) 0.30393(6) 0.02575(13) Uani 1 1 d . . .
F1 F 1.00451(17) 0.39930(13) 0.10916(14) 0.0195(3) Uani 1 1 d . . .
F2 F 1.22412(16) 0.29562(14) 0.13424(14) 0.0203(3) Uani 1 1 d . . .
F3 F 1.22396(16) 0.08163(15) 0.22967(15) 0.0224(3) Uani 1 1 d . . .
F4 F 1.00828(16) -0.03539(13) 0.29752(14) 0.0198(3) Uani 1 1 d . . .
F5 F 0.65488(17) -0.35877(12) 0.42278(14) 0.0189(3) Uani 1 1 d . . .
F6 F 0.67749(19) -0.40440(14) 0.62251(14) 0.0241(3) Uani 1 1 d . . .
F7 F 0.7300(2) -0.24711(15) 0.66495(13) 0.0237(3) Uani 1 1 d . . .
F8 F 0.75913(18) -0.04484(14) 0.50819(13) 0.0199(3) Uani 1 1 d . . .
C1 C 0.8912(2) 0.23378(18) 0.19070(18) 0.0128(3) Uani 1 1 d . . .
C2 C 1.0026(2) 0.29311(19) 0.15574(19) 0.0144(4) Uani 1 1 d . . .
C3 C 1.1155(2) 0.2412(2) 0.1685(2) 0.0159(4) Uani 1 1 d . . .
C4 C 1.1152(2) 0.1303(2) 0.2176(2) 0.0165(4) Uani 1 1 d . . .
C5 C 1.0026(2) 0.07100(19) 0.25338(19) 0.0147(4) Uani 1 1 d . . .
C6 C 0.8893(2) 0.12174(18) 0.24106(18) 0.0126(3) Uani 1 1 d . . .
C7 C 0.6704(2) 0.34025(18) 0.07530(18) 0.0133(3) Uani 1 1 d . . .
C8 C 0.7509(3) 0.4101(2) -0.0145(2) 0.0175(4) Uani 1 1 d . . .
H8 H 0.8378 0.4151 -0.0102 0.021 Uiso 1 1 calc R . .
C9 C 0.7026(3) 0.4723(2) -0.1104(2) 0.0207(5) Uani 1 1 d . . .
H9 H 0.7564 0.5203 -0.1716 0.025 Uiso 1 1 calc R . .
C10 C 0.5756(3) 0.4640(2) -0.1162(2) 0.0203(5) Uani 1 1 d . . .
H10 H 0.5433 0.5062 -0.1818 0.024 Uiso 1 1 calc R . .
C11 C 0.4950(3) 0.3946(2) -0.0274(2) 0.0191(4) Uani 1 1 d . . .
H11 H 0.4083 0.3900 -0.0325 0.023 Uiso 1 1 calc R . .
C12 C 0.5417(3) 0.3318(2) 0.0690(2) 0.0173(4) Uani 1 1 d . . .
H12 H 0.4874 0.2837 0.1298 0.021 Uiso 1 1 calc R . .
C13 C 0.6858(2) 0.31158(19) 0.28873(18) 0.0138(4) Uani 1 1 d . . .
C14 C 0.6323(2) 0.2448(2) 0.3934(2) 0.0174(4) Uani 1 1 d . . .
H14 H 0.6116 0.1726 0.4162 0.021 Uiso 1 1 calc R . .
C15 C 0.6100(3) 0.2846(2) 0.4635(2) 0.0211(5) Uani 1 1 d . . .
H15 H 0.5740 0.2396 0.5346 0.025 Uiso 1 1 calc R . .
C16 C 0.6397(3) 0.3893(3) 0.4304(3) 0.0247(5) Uani 1 1 d . . .
H16 H 0.6229 0.4161 0.4788 0.030 Uiso 1 1 calc R . .
C17 C 0.6943(3) 0.4567(3) 0.3264(3) 0.0246(5) Uani 1 1 d . . .
H17 H 0.7160 0.5284 0.3047 0.029 Uiso 1 1 calc R . .
C18 C 0.7166(3) 0.4178(2) 0.2548(2) 0.0173(4) Uani 1 1 d . . .
H18 H 0.7524 0.4631 0.1837 0.021 Uiso 1 1 calc R . .
C19 C 0.6962(2) -0.17430(18) 0.35706(18) 0.0129(3) Uani 1 1 d . . .
C20 C 0.6836(2) -0.27871(19) 0.44031(19) 0.0148(4) Uani 1 1 d . . .
C21 C 0.6949(3) -0.3039(2) 0.54348(19) 0.0171(4) Uani 1 1 d . . .
C22 C 0.7211(3) -0.2236(2) 0.56481(19) 0.0172(4) Uani 1 1 d . . .
C23 C 0.7343(2) -0.11999(19) 0.48254(19) 0.0149(4) Uani 1 1 d . . .
C24 C 0.7205(2) -0.09110(18) 0.37813(18) 0.0125(3) Uani 1 1 d . . .
C25 C 0.7130(2) -0.02285(19) 0.12765(18) 0.0140(4) Uani 1 1 d . . .
C26 C 0.8421(3) 0.0033(2) 0.1039(2) 0.0173(4) Uani 1 1 d . . .
H26 H 0.9003 -0.0473 0.1434 0.021 Uiso 1 1 calc R . .
C27 C 0.8846(3) 0.1032(2) 0.0226(2) 0.0202(5) Uani 1 1 d . . .
H27 H 0.9719 0.1212 0.0067 0.024 Uiso 1 1 calc R . .
C28 C 0.7991(3) 0.1769(2) -0.0354(2) 0.0212(5) Uani 1 1 d . . .
H28 H 0.8280 0.2455 -0.0904 0.025 Uiso 1 1 calc R . .
C29 C 0.6713(3) 0.1502(2) -0.0129(2) 0.0211(5) Uani 1 1 d . . .
H29 H 0.6136 0.2006 -0.0534 0.025 Uiso 1 1 calc R . .
C30 C 0.6270(3) 0.0504(2) 0.0685(2) 0.0181(4) Uani 1 1 d . . .
H30 H 0.5398 0.0323 0.0835 0.022 Uiso 1 1 calc R . .
C31 C 0.5093(2) -0.19568(19) 0.24232(18) 0.0137(3) Uani 1 1 d . . .
C32 C 0.4132(2) -0.1306(2) 0.2508(2) 0.0171(4) Uani 1 1 d . . .
H32 H 0.4332 -0.0626 0.2415 0.021 Uiso 1 1 calc R . .
C33 C 0.2886(3) -0.1663(2) 0.2728(2) 0.0211(5) Uani 1 1 d . . .
H33 H 0.2232 -0.1217 0.2766 0.025 Uiso 1 1 calc R . .
C34 C 0.2592(3) -0.2668(2) 0.2891(2) 0.0209(5) Uani 1 1 d . . .
H34 H 0.1741 -0.2912 0.3054 0.025 Uiso 1 1 calc R . .
C35 C 0.3543(3) -0.3317(2) 0.2816(2) 0.0195(4) Uani 1 1 d . . .
H35 H 0.3339 -0.4005 0.2931 0.023 Uiso 1 1 calc R . .
C36 C 0.4787(2) -0.2965(2) 0.2576(2) 0.0169(4) Uani 1 1 d . . .
H36 H 0.5433 -0.3406 0.2514 0.020 Uiso 1 1 calc R . .
Cl5 Cl 0.04677(10) 0.84024(9) 0.54750(8) 0.03798(19) Uani 1 1 d . . .
Cl6 Cl -0.01257(11) 0.61628(10) 0.62744(12) 0.0537(3) Uani 1 1 d . . .
C37 C 0.0449(4) 0.7371(3) 0.5157(3) 0.0337(7) Uani 1 1 d . . .
H37A H 0.1311 0.7276 0.4887 0.040 Uiso 1 1 calc R . .
H37B H -0.0088 0.7566 0.4587 0.040 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C6 Au1 C24 102.01(9) . . ?
C6 Au1 Cl1 168.12(7) . . ?
C24 Au1 Cl1 88.80(7) . . ?
C6 Au1 P1 68.87(7) . . ?
C24 Au1 P1 167.75(7) . . ?
Cl1 Au1 P1 99.70(2) . . ?
Cl4 Au2 Cl3 175.55(3) . . ?
Cl4 Au2 P2 93.44(2) . . ?
Cl3 Au2 P2 85.38(2) . . ?
Cl4 Au2 Cl2 90.26(3) . . ?
Cl3 Au2 Cl2 90.92(3) . . ?
P2 Au2 Cl2 176.30(3) . . ?
C7 P1 C1 113.80(11) . . ?
C7 P1 C13 110.38(11) . . ?
C1 P1 C13 110.52(11) . . ?
C7 P1 Au1 122.26(8) . . ?
C1 P1 Au1 83.72(7) . . ?
C13 P1 Au1 113.32(8) . . ?
C25 P2 C31 114.83(11) . . ?
C25 P2 C19 109.40(11) . . ?
C31 P2 C19 105.16(11) . . ?
C25 P2 Au2 102.63(8) . . ?
C31 P2 Au2 110.62(8) . . ?
C19 P2 Au2 114.50(8) . . ?
C2 C1 C6 121.8(2) . . ?
C2 C1 P1 137.48(19) . . ?
C6 C1 P1 100.58(16) . . ?
F1 C2 C1 121.9(2) . . ?
F1 C2 C3 119.0(2) . . ?
C1 C2 C3 119.1(2) . . ?
F2 C3 C2 120.8(2) . . ?
F2 C3 C4 119.5(2) . . ?
C2 C3 C4 119.8(2) . . ?
F3 C4 C5 120.1(2) . . ?
F3 C4 C3 119.1(2) . . ?
C5 C4 C3 120.8(2) . . ?
F4 C5 C6 121.9(2) . . ?
F4 C5 C4 118.1(2) . . ?
C6 C5 C4 120.1(2) . . ?
C5 C6 C1 118.5(2) . . ?
C5 C6 Au1 134.62(18) . . ?
C1 C6 Au1 106.83(16) . . ?
C8 C7 C12 120.5(2) . . ?
C8 C7 P1 121.96(19) . . ?
C12 C7 P1 117.58(18) . . ?
C9 C8 C7 119.5(2) . . ?
C9 C8 H8 120.3 . . ?
C7 C8 H8 120.3 . . ?
C10 C9 C8 119.9(3) . . ?
C10 C9 H9 120.0 . . ?
C8 C9 H9 120.0 . . ?
C9 C10 C11 120.9(2) . . ?
C9 C10 H10 119.5 . . ?
C11 C10 H10 119.5 . . ?
C10 C11 C12 119.9(3) . . ?
C10 C11 H11 120.1 . . ?
C12 C11 H11 120.1 . . ?
C11 C12 C7 119.3(2) . . ?
C11 C12 H12 120.3 . . ?
C7 C12 H12 120.3 . . ?
C18 C13 C14 120.4(2) . . ?
C18 C13 P1 119.89(18) . . ?
C14 C13 P1 119.54(19) . . ?
C15 C14 C13 119.6(3) . . ?
C15 C14 H14 120.2 . . ?
C13 C14 H14 120.2 . . ?
C16 C15 C14 120.2(3) . . ?
C16 C15 H15 119.9 . . ?
C14 C15 H15 119.9 . . ?
C15 C16 C17 120.8(3) . . ?
C15 C16 H16 119.6 . . ?
C17 C16 H16 119.6 . . ?
C18 C17 C16 119.5(3) . . ?
C18 C17 H17 120.2 . . ?
C16 C17 H17 120.2 . . ?
C17 C18 C13 119.4(2) . . ?
C17 C18 H18 120.3 . . ?
C13 C18 H18 120.3 . . ?
C20 C19 C24 119.5(2) . . ?
C20 C19 P2 115.23(18) . . ?
C24 C19 P2 125.16(17) . . ?
F5 C20 C21 117.5(2) . . ?
F5 C20 C19 120.5(2) . . ?
C21 C20 C19 122.0(2) . . ?
F6 C21 C20 120.7(2) . . ?
F6 C21 C22 120.2(2) . . ?
C20 C21 C22 119.1(2) . . ?
F7 C22 C21 119.5(2) . . ?
F7 C22 C23 121.3(2) . . ?
C21 C22 C23 119.2(2) . . ?
F8 C23 C22 116.6(2) . . ?
F8 C23 C24 120.0(2) . . ?
C22 C23 C24 123.4(2) . . ?
C23 C24 C19 116.7(2) . . ?
C23 C24 Au1 111.64(17) . . ?
C19 C24 Au1 130.50(17) . . ?
C30 C25 C26 120.4(2) . . ?
C30 C25 P2 124.00(19) . . ?
C26 C25 P2 115.40(18) . . ?
C27 C26 C25 119.9(3) . . ?
C27 C26 H26 120.0 . . ?
C25 C26 H26 120.0 . . ?
C26 C27 C28 119.9(3) . . ?
C26 C27 H27 120.1 . . ?
C28 C27 H27 120.1 . . ?
C27 C28 C29 120.1(2) . . ?
C27 C28 H28 119.9 . . ?
C29 C28 H28 119.9 . . ?
C28 C29 C30 120.7(3) . . ?
C28 C29 H29 119.6 . . ?
C30 C29 H29 119.6 . . ?
C29 C30 C25 119.0(3) . . ?
C29 C30 H30 120.5 . . ?
C25 C30 H30 120.5 . . ?
C36 C31 C32 119.7(2) . . ?
C36 C31 P2 119.75(19) . . ?
C32 C31 P2 120.16(19) . . ?
C33 C32 C31 119.6(2) . . ?
C33 C32 H32 120.2 . . ?
C31 C32 H32 120.2 . . ?
C34 C33 C32 120.4(3) . . ?
C34 C33 H33 119.8 . . ?
C32 C33 H33 119.8 . . ?
C35 C34 C33 120.1(2) . . ?
C35 C34 H34 119.9 . . ?
C33 C34 H34 119.9 . . ?
C36 C35 C34 120.3(3) . . ?
C36 C35 H35 119.9 . . ?
C34 C35 H35 119.9 . . ?
C35 C36 C31 120.0(3) . . ?
C35 C36 H36 120.0 . . ?
C31 C36 H36 120.0 . . ?
Cl5 C37 Cl6 111.4(2) . . ?
Cl5 C37 H37A 109.4 . . ?
Cl6 C37 H37A 109.4 . . ?
Cl5 C37 H37B 109.4 . . ?
Cl6 C37 H37B 109.4 . . ?
H37A C37 H37B 108.0 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 C6 2.029(2) . ?
Au1 C24 2.077(2) . ?
Au1 Cl1 2.3329(6) . ?
Au1 P1 2.3348(6) . ?
Au2 Cl4 2.2804(7) . ?
Au2 Cl3 2.2866(7) . ?
Au2 P2 2.3209(6) . ?
Au2 Cl2 2.3337(7) . ?
P1 C7 1.790(2) . ?
P1 C1 1.798(2) . ?
P1 C13 1.799(2) . ?
P2 C25 1.792(2) . ?
P2 C31 1.803(2) . ?
P2 C19 1.821(2) . ?
F1 C2 1.338(3) . ?
F2 C3 1.327(3) . ?
F3 C4 1.327(3) . ?
F4 C5 1.346(3) . ?
F5 C20 1.349(3) . ?
F6 C21 1.340(3) . ?
F7 C22 1.339(3) . ?
F8 C23 1.349(3) . ?
C1 C2 1.384(3) . ?
C1 C6 1.411(3) . ?
C2 C3 1.386(4) . ?
C3 C4 1.397(4) . ?
C4 C5 1.394(4) . ?
C5 C6 1.382(3) . ?
C7 C8 1.400(4) . ?
C7 C12 1.409(4) . ?
C8 C9 1.396(4) . ?
C8 H8 0.9500 . ?
C9 C10 1.390(4) . ?
C9 H9 0.9500 . ?
C10 C11 1.391(4) . ?
C10 H10 0.9500 . ?
C11 C12 1.394(4) . ?
C11 H11 0.9500 . ?
C12 H12 0.9500 . ?
C13 C18 1.398(4) . ?
C13 C14 1.400(3) . ?
C14 C15 1.385(4) . ?
C14 H14 0.9500 . ?
C15 C16 1.377(5) . ?
C15 H15 0.9500 . ?
C16 C17 1.399(5) . ?
C16 H16 0.9500 . ?
C17 C18 1.394(4) . ?
C17 H17 0.9500 . ?
C18 H18 0.9500 . ?
C19 C20 1.395(3) . ?
C19 C24 1.413(3) . ?
C20 C21 1.380(4) . ?
C21 C22 1.380(4) . ?
C22 C23 1.383(4) . ?
C23 C24 1.390(3) . ?
C25 C30 1.398(4) . ?
C25 C26 1.404(4) . ?
C26 C27 1.389(4) . ?
C26 H26 0.9500 . ?
C27 C28 1.392(4) . ?
C27 H27 0.9500 . ?
C28 C29 1.392(4) . ?
C28 H28 0.9500 . ?
C29 C30 1.394(4) . ?
C29 H29 0.9500 . ?
C30 H30 0.9500 . ?
C31 C36 1.403(3) . ?
C31 C32 1.404(4) . ?
C32 C33 1.392(4) . ?
C32 H32 0.9500 . ?
C33 C34 1.390(4) . ?
C33 H33 0.9500 . ?
C34 C35 1.389(4) . ?
C34 H34 0.9500 . ?
C35 C36 1.387(4) . ?
C35 H35 0.9500 . ?
C36 H36 0.9500 . ?
Cl5 C37 1.759(4) . ?
Cl6 C37 1.765(4) . ?
C37 H37A 0.9900 . ?
C37 H37B 0.9900 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C6 Au1 P1 C7 114.23(12) . . . . ?
C24 Au1 P1 C7 157.5(3) . . . . ?
Cl1 Au1 P1 C7 -69.14(10) . . . . ?
C6 Au1 P1 C1 0.00(10) . . . . ?
C24 Au1 P1 C1 43.2(3) . . . . ?
Cl1 Au1 P1 C1 176.62(8) . . . . ?
C6 Au1 P1 C13 -109.67(11) . . . . ?
C24 Au1 P1 C13 -66.5(3) . . . . ?
Cl1 Au1 P1 C13 66.95(9) . . . . ?
Cl4 Au2 P2 C25 109.29(8) . . . . ?
Cl3 Au2 P2 C25 -66.41(8) . . . . ?
Cl4 Au2 P2 C31 -127.75(9) . . . . ?
Cl3 Au2 P2 C31 56.56(8) . . . . ?
Cl4 Au2 P2 C19 -9.15(9) . . . . ?
Cl3 Au2 P2 C19 175.16(9) . . . . ?
C7 P1 C1 C2 62.3(3) . . . . ?
C13 P1 C1 C2 -62.6(3) . . . . ?
Au1 P1 C1 C2 -175.2(3) . . . . ?
C7 P1 C1 C6 -122.56(16) . . . . ?
C13 P1 C1 C6 112.58(16) . . . . ?
Au1 P1 C1 C6 0.01(14) . . . . ?
C6 C1 C2 F1 -179.1(2) . . . . ?
P1 C1 C2 F1 -4.7(4) . . . . ?
C6 C1 C2 C3 1.4(4) . . . . ?
P1 C1 C2 C3 175.8(2) . . . . ?
F1 C2 C3 F2 -0.6(4) . . . . ?
C1 C2 C3 F2 178.8(2) . . . . ?
F1 C2 C3 C4 179.6(2) . . . . ?
C1 C2 C3 C4 -1.0(4) . . . . ?
F2 C3 C4 F3 0.5(4) . . . . ?
C2 C3 C4 F3 -179.7(2) . . . . ?
F2 C3 C4 C5 -179.3(2) . . . . ?
C2 C3 C4 C5 0.5(4) . . . . ?
F3 C4 C5 F4 -1.6(4) . . . . ?
C3 C4 C5 F4 178.3(2) . . . . ?
F3 C4 C5 C6 179.8(2) . . . . ?
C3 C4 C5 C6 -0.4(4) . . . . ?
F4 C5 C6 C1 -177.8(2) . . . . ?
C4 C5 C6 C1 0.8(4) . . . . ?
F4 C5 C6 Au1 5.6(4) . . . . ?
C4 C5 C6 Au1 -175.82(19) . . . . ?
C2 C1 C6 C5 -1.3(4) . . . . ?
P1 C1 C6 C5 -177.47(19) . . . . ?
C2 C1 C6 Au1 176.15(19) . . . . ?
P1 C1 C6 Au1 -0.01(17) . . . . ?
C24 Au1 C6 C5 5.4(3) . . . . ?
Cl1 Au1 C6 C5 160.5(2) . . . . ?
P1 Au1 C6 C5 176.9(3) . . . . ?
C24 Au1 C6 C1 -171.45(16) . . . . ?
Cl1 Au1 C6 C1 -16.4(4) . . . . ?
P1 Au1 C6 C1 0.01(14) . . . . ?
C1 P1 C7 C8 -22.2(2) . . . . ?
C13 P1 C7 C8 102.7(2) . . . . ?
Au1 P1 C7 C8 -120.1(2) . . . . ?
C1 P1 C7 C12 156.72(19) . . . . ?
C13 P1 C7 C12 -78.4(2) . . . . ?
Au1 P1 C7 C12 58.9(2) . . . . ?
C12 C7 C8 C9 0.6(4) . . . . ?
P1 C7 C8 C9 179.6(2) . . . . ?
C7 C8 C9 C10 -0.4(4) . . . . ?
C8 C9 C10 C11 0.3(4) . . . . ?
C9 C10 C11 C12 -0.4(4) . . . . ?
C10 C11 C12 C7 0.6(4) . . . . ?
C8 C7 C12 C11 -0.7(4) . . . . ?
P1 C7 C12 C11 -179.7(2) . . . . ?
C7 P1 C13 C18 -51.7(2) . . . . ?
C1 P1 C13 C18 75.1(2) . . . . ?
Au1 P1 C13 C18 167.06(18) . . . . ?
C7 P1 C13 C14 133.1(2) . . . . ?
C1 P1 C13 C14 -100.1(2) . . . . ?
Au1 P1 C13 C14 -8.2(2) . . . . ?
C18 C13 C14 C15 0.1(4) . . . . ?
P1 C13 C14 C15 175.3(2) . . . . ?
C13 C14 C15 C16 0.2(4) . . . . ?
C14 C15 C16 C17 -0.9(5) . . . . ?
C15 C16 C17 C18 1.3(5) . . . . ?
C16 C17 C18 C13 -1.0(4) . . . . ?
C14 C13 C18 C17 0.3(4) . . . . ?
P1 C13 C18 C17 -174.9(2) . . . . ?
C25 P2 C19 C20 -171.82(19) . . . . ?
C31 P2 C19 C20 64.4(2) . . . . ?
Au2 P2 C19 C20 -57.3(2) . . . . ?
C25 P2 C19 C24 11.2(2) . . . . ?
C31 P2 C19 C24 -112.6(2) . . . . ?
Au2 P2 C19 C24 125.78(19) . . . . ?
C24 C19 C20 F5 177.0(2) . . . . ?
P2 C19 C20 F5 -0.1(3) . . . . ?
C24 C19 C20 C21 -0.4(4) . . . . ?
P2 C19 C20 C21 -177.5(2) . . . . ?
F5 C20 C21 F6 -0.1(4) . . . . ?
C19 C20 C21 F6 177.4(2) . . . . ?
F5 C20 C21 C22 -178.4(2) . . . . ?
C19 C20 C21 C22 -0.9(4) . . . . ?
F6 C21 C22 F7 0.5(4) . . . . ?
C20 C21 C22 F7 178.8(2) . . . . ?
F6 C21 C22 C23 -177.7(2) . . . . ?
C20 C21 C22 C23 0.6(4) . . . . ?
F7 C22 C23 F8 1.4(4) . . . . ?
C21 C22 C23 F8 179.6(2) . . . . ?
F7 C22 C23 C24 -177.1(2) . . . . ?
C21 C22 C23 C24 1.1(4) . . . . ?
F8 C23 C24 C19 179.2(2) . . . . ?
C22 C23 C24 C19 -2.3(4) . . . . ?
F8 C23 C24 Au1 -11.7(3) . . . . ?
C22 C23 C24 Au1 166.8(2) . . . . ?
C20 C19 C24 C23 2.0(3) . . . . ?
P2 C19 C24 C23 178.77(19) . . . . ?
C20 C19 C24 Au1 -164.72(19) . . . . ?
P2 C19 C24 Au1 12.1(3) . . . . ?
C6 Au1 C24 C23 85.10(19) . . . . ?
Cl1 Au1 C24 C23 -89.92(17) . . . . ?
P1 Au1 C24 C23 44.3(4) . . . . ?
C6 Au1 C24 C19 -107.7(2) . . . . ?
Cl1 Au1 C24 C19 77.3(2) . . . . ?
P1 Au1 C24 C19 -148.5(2) . . . . ?
C31 P2 C25 C30 3.9(3) . . . . ?
C19 P2 C25 C30 -114.0(2) . . . . ?
Au2 P2 C25 C30 124.0(2) . . . . ?
C31 P2 C25 C26 -170.38(19) . . . . ?
C19 P2 C25 C26 71.7(2) . . . . ?
Au2 P2 C25 C26 -50.3(2) . . . . ?
C30 C25 C26 C27 1.3(4) . . . . ?
P2 C25 C26 C27 175.9(2) . . . . ?
C25 C26 C27 C28 -0.4(4) . . . . ?
C26 C27 C28 C29 -0.7(4) . . . . ?
C27 C28 C29 C30 0.8(4) . . . . ?
C28 C29 C30 C25 0.2(4) . . . . ?
C26 C25 C30 C29 -1.3(4) . . . . ?
P2 C25 C30 C29 -175.3(2) . . . . ?
C25 P2 C31 C36 138.6(2) . . . . ?
C19 P2 C31 C36 -101.1(2) . . . . ?
Au2 P2 C31 C36 23.0(2) . . . . ?
C25 P2 C31 C32 -48.8(2) . . . . ?
C19 P2 C31 C32 71.5(2) . . . . ?
Au2 P2 C31 C32 -164.39(18) . . . . ?
C36 C31 C32 C33 -0.9(4) . . . . ?
P2 C31 C32 C33 -173.4(2) . . . . ?
C31 C32 C33 C34 1.7(4) . . . . ?
C32 C33 C34 C35 -1.2(4) . . . . ?
C33 C34 C35 C36 -0.2(4) . . . . ?
C34 C35 C36 C31 1.0(4) . . . . ?
C32 C31 C36 C35 -0.5(4) . . . . ?
P2 C31 C36 C35 172.1(2) . . . . ?
