#------------------------------------------------------------------------------
#$Date: 2016-03-25 10:01:37 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179737 $
#$URL: svn://www.crystallography.net/cod/cif/7/00/33/7003393.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7003393
loop_
_publ_author_name
'Jones, Cameron'
'Mills, David P.'
'Rose, Richard P.'
'Stasch, Andreas'
_publ_section_title
;
 Synthesis and structural characterisation of group 10 metal(ii) gallyl
 complexes: analogies with platinum diboration catalysts?
;
_journal_issue                   33
_journal_name_full               'Dalton Transactions'
_journal_page_first              4395
_journal_page_last               4408
_journal_paper_doi               10.1039/b715895e
_journal_year                    2008
_chemical_formula_sum            'C56 H94 Cl Ga N2 O P2 Pt'
_chemical_formula_weight         1173.53
_chemical_name_systematic
;
?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 104.11(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   12.893(3)
_cell_length_b                   21.811(4)
_cell_length_c                   20.656(4)
_cell_measurement_temperature    150(2)
_cell_volume                     5633(2)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      150(2)
_diffrn_measured_fraction_theta_full 0.994
_diffrn_measured_fraction_theta_max 0.994
_diffrn_measurement_device_type  'Nonius Kappa CCD'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0306
_diffrn_reflns_av_sigmaI/netI    0.0417
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       27
_diffrn_reflns_limit_k_min       -27
_diffrn_reflns_limit_l_max       25
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_number            22427
_diffrn_reflns_theta_full        26.50
_diffrn_reflns_theta_max         26.50
_diffrn_reflns_theta_min         2.94
_exptl_absorpt_coefficient_mu    3.101
_exptl_absorpt_correction_T_max  0.550
_exptl_absorpt_correction_T_min  0.409
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Sortav (Blessing, 1995)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.384
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             2432
_exptl_crystal_size_max          0.35
_exptl_crystal_size_mid          0.25
_exptl_crystal_size_min          0.20
_refine_diff_density_max         1.450
_refine_diff_density_min         -0.868
_refine_diff_density_rms         0.105
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.019
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     562
_refine_ls_number_reflns         11617
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.019
_refine_ls_R_factor_all          0.0413
_refine_ls_R_factor_gt           0.0310
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0240P)²+12.5707P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0669
_refine_ls_wR_factor_ref         0.0706
_reflns_number_gt                9916
_reflns_number_total             11617
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b715895e.txt
_cod_data_source_block           compound11
_cod_original_sg_symbol_H-M      P2(1)/n
_cod_database_code               7003393
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.605679(10) 0.188700(6) 0.438073(6) 0.01300(4) Uani 1 1 d . . .
Ga1 Ga 0.76830(3) 0.240094(16) 0.494977(18) 0.01458(8) Uani 1 1 d . . .
Cl1 Cl 0.66422(7) 0.11582(4) 0.52452(4) 0.02327(19) Uani 1 1 d . . .
P1 P 0.55906(7) 0.25703(4) 0.35767(4) 0.01602(18) Uani 1 1 d . . .
P2 P 0.45395(7) 0.13380(4) 0.38809(4) 0.01493(18) Uani 1 1 d . . .
O1 O 0.5173(3) 0.46877(16) 0.27053(18) 0.0553(9) Uiso 1 1 d . . .
N1 N 0.8092(2) 0.28397(13) 0.57653(14) 0.0172(6) Uani 1 1 d . . .
N2 N 0.9158(2) 0.22920(13) 0.49889(14) 0.0172(6) Uani 1 1 d . . .
C1 C 0.9208(3) 0.27861(16) 0.60044(17) 0.0190(7) Uani 1 1 d . . .
H1 H 0.9568 0.2943 0.6429 0.023 Uiso 1 1 calc R . .
C2 C 0.9739(3) 0.25041(15) 0.56074(17) 0.0180(7) Uani 1 1 d . . .
H2 H 1.0492 0.2450 0.5744 0.022 Uiso 1 1 calc R . .
C3 C 0.7593(3) 0.33244(16) 0.60361(17) 0.0196(7) Uani 1 1 d . . .
C4 C 0.6711(3) 0.31994(17) 0.63127(18) 0.0216(8) Uani 1 1 d . . .
C5 C 0.6279(3) 0.36808(18) 0.66084(19) 0.0280(9) Uani 1 1 d . . .
H5 H 0.5691 0.3601 0.6798 0.034 Uiso 1 1 calc R . .
C6 C 0.6683(3) 0.42678(19) 0.6633(2) 0.0320(9) Uani 1 1 d . . .
H6 H 0.6398 0.4584 0.6855 0.038 Uiso 1 1 calc R . .
C7 C 0.7508(3) 0.43941(17) 0.6330(2) 0.0277(9) Uani 1 1 d . . .
H7 H 0.7772 0.4801 0.6337 0.033 Uiso 1 1 calc R . .
C8 C 0.7957(3) 0.39342(16) 0.60173(19) 0.0233(8) Uani 1 1 d . . .
C9 C 0.6265(3) 0.25546(17) 0.6296(2) 0.0256(8) Uani 1 1 d . . .
H9 H 0.6278 0.2375 0.5852 0.031 Uiso 1 1 calc R . .
C10 C 0.6971(4) 0.2155(2) 0.6825(2) 0.0460(12) Uani 1 1 d . . .
H10A H 0.7704 0.2161 0.6768 0.069 Uiso 1 1 calc R . .
H10B H 0.6700 0.1733 0.6780 0.069 Uiso 1 1 calc R . .
H10C H 0.6966 0.2312 0.7268 0.069 Uiso 1 1 calc R . .
C11 C 0.5111(3) 0.2534(2) 0.6352(2) 0.0420(12) Uani 1 1 d . . .
H11A H 0.5079 0.2657 0.6803 0.063 Uiso 1 1 calc R . .
H11B H 0.4832 0.2117 0.6263 0.063 Uiso 1 1 calc R . .
H11C H 0.4678 0.2817 0.6026 0.063 Uiso 1 1 calc R . .
C12 C 0.8760(3) 0.41120(17) 0.5616(2) 0.0271(9) Uani 1 1 d . . .
H12 H 0.8879 0.3741 0.5358 0.033 Uiso 1 1 calc R . .
C13 C 0.9845(3) 0.4306(2) 0.6045(2) 0.0402(11) Uani 1 1 d . . .
H13A H 0.9761 0.4675 0.6298 0.060 Uiso 1 1 calc R . .
H13B H 1.0330 0.4394 0.5757 0.060 Uiso 1 1 calc R . .
H13C H 1.0143 0.3975 0.6355 0.060 Uiso 1 1 calc R . .
C14 C 0.8304(4) 0.4617(2) 0.5106(2) 0.0419(11) Uani 1 1 d . . .
H14A H 0.8204 0.4994 0.5342 0.063 Uiso 1 1 calc R . .
H14B H 0.7615 0.4484 0.4824 0.063 Uiso 1 1 calc R . .
H14C H 0.8803 0.4696 0.4825 0.063 Uiso 1 1 calc R . .
C15 C 0.9712(3) 0.21589(16) 0.44862(17) 0.0170(7) Uani 1 1 d . . .
C16 C 0.9616(3) 0.15646(16) 0.41996(18) 0.0188(7) Uani 1 1 d . . .
C17 C 1.0159(3) 0.14380(18) 0.37089(19) 0.0258(8) Uani 1 1 d . . .
H17 H 1.0086 0.1045 0.3505 0.031 Uiso 1 1 calc R . .
C18 C 1.0806(3) 0.18752(18) 0.35096(19) 0.0262(8) Uani 1 1 d . . .
H18 H 1.1181 0.1778 0.3180 0.031 Uiso 1 1 calc R . .
C19 C 1.0898(3) 0.24505(17) 0.37947(19) 0.0241(8) Uani 1 1 d . . .
H19 H 1.1339 0.2748 0.3658 0.029 Uiso 1 1 calc R . .
C20 C 1.0356(3) 0.26045(16) 0.42795(18) 0.0200(8) Uani 1 1 d . . .
C21 C 0.8962(3) 0.10758(16) 0.44458(19) 0.0223(8) Uani 1 1 d . . .
H21 H 0.8288 0.1274 0.4499 0.027 Uiso 1 1 calc R . .
C22 C 0.9561(3) 0.08428(18) 0.5130(2) 0.0325(10) Uani 1 1 d . . .
H22A H 1.0212 0.0630 0.5091 0.049 Uiso 1 1 calc R . .
H22B H 0.9104 0.0559 0.5302 0.049 Uiso 1 1 calc R . .
H22C H 0.9753 0.1190 0.5437 0.049 Uiso 1 1 calc R . .
C23 C 0.8643(3) 0.05439(18) 0.3956(2) 0.0357(10) Uani 1 1 d . . .
H23A H 0.8301 0.0705 0.3512 0.054 Uiso 1 1 calc R . .
H23B H 0.8141 0.0275 0.4108 0.054 Uiso 1 1 calc R . .
H23C H 0.9282 0.0310 0.3933 0.054 Uiso 1 1 calc R . .
C24 C 1.0453(3) 0.32530(17) 0.4549(2) 0.0270(9) Uani 1 1 d . . .
H24 H 0.9947 0.3294 0.4845 0.032 Uiso 1 1 calc R . .
C25 C 1.1583(3) 0.3383(2) 0.4977(2) 0.0383(11) Uani 1 1 d . . .
H25A H 1.1731 0.3116 0.5371 0.057 Uiso 1 1 calc R . .
H25B H 1.1632 0.3813 0.5120 0.057 Uiso 1 1 calc R . .
H25C H 1.2106 0.3304 0.4714 0.057 Uiso 1 1 calc R . .
C26 C 1.0133(4) 0.3730(2) 0.3992(3) 0.0460(12) Uani 1 1 d . . .
H26A H 1.0629 0.3710 0.3701 0.069 Uiso 1 1 calc R . .
H26B H 1.0159 0.4141 0.4188 0.069 Uiso 1 1 calc R . .
H26C H 0.9405 0.3645 0.3729 0.069 Uiso 1 1 calc R . .
C27 C 0.4540(3) 0.22232(16) 0.29085(17) 0.0208(8) Uani 1 1 d . . .
H27A H 0.4113 0.2554 0.2641 0.025 Uiso 1 1 calc R . .
H27B H 0.4881 0.1984 0.2609 0.025 Uiso 1 1 calc R . .
C28 C 0.3793(3) 0.18028(16) 0.31767(18) 0.0197(8) Uani 1 1 d . . .
H28A H 0.3410 0.1528 0.2815 0.024 Uiso 1 1 calc R . .
H28B H 0.3254 0.2054 0.3325 0.024 Uiso 1 1 calc R . .
C29 C 0.5065(3) 0.33110(16) 0.37963(19) 0.0205(8) Uani 1 1 d . . .
H29 H 0.5182 0.3621 0.3464 0.025 Uiso 1 1 calc R . .
C30 C 0.5682(3) 0.35315(17) 0.4488(2) 0.0280(9) Uani 1 1 d . . .
H30A H 0.5599 0.3227 0.4827 0.034 Uiso 1 1 calc R . .
H30B H 0.6453 0.3559 0.4498 0.034 Uiso 1 1 calc R . .
C31 C 0.5291(3) 0.41577(18) 0.4666(2) 0.0342(10) Uani 1 1 d . . .
H31A H 0.5678 0.4270 0.5126 0.041 Uiso 1 1 calc R . .
H31B H 0.5450 0.4473 0.4358 0.041 Uiso 1 1 calc R . .
C32 C 0.4095(3) 0.41459(18) 0.4617(2) 0.0339(10) Uani 1 1 d . . .
H32A H 0.3851 0.4561 0.4706 0.041 Uiso 1 1 calc R . .
H32B H 0.3944 0.3863 0.4958 0.041 Uiso 1 1 calc R . .
C33 C 0.3487(3) 0.39361(17) 0.3925(2) 0.0304(9) Uani 1 1 d . . .
H33A H 0.3600 0.4235 0.3587 0.036 Uiso 1 1 calc R . .
H33B H 0.2712 0.3923 0.3904 0.036 Uiso 1 1 calc R . .
C34 C 0.3861(3) 0.33013(16) 0.3763(2) 0.0245(8) Uani 1 1 d . . .
H34A H 0.3461 0.3177 0.3310 0.029 Uiso 1 1 calc R . .
H34B H 0.3714 0.2998 0.4085 0.029 Uiso 1 1 calc R . .
C35 C 0.6624(3) 0.27861(18) 0.3136(2) 0.0287(9) Uani 1 1 d . . .
H35 H 0.7169 0.3031 0.3461 0.034 Uiso 1 1 calc R . .
C36 C 0.6254(4) 0.3180(2) 0.2541(2) 0.0452(12) Uani 1 1 d . . .
H36A H 0.5916 0.3554 0.2668 0.054 Uiso 1 1 calc R . .
H36B H 0.5707 0.2957 0.2203 0.054 Uiso 1 1 calc R . .
C37 C 0.7188(5) 0.3364(3) 0.2235(3) 0.075(2) Uani 1 1 d . . .
H37A H 0.6917 0.3618 0.1831 0.090 Uiso 1 1 calc R . .
H37B H 0.7718 0.3609 0.2560 0.090 Uiso 1 1 calc R . .
C38 C 0.7720(5) 0.2780(3) 0.2049(3) 0.074(2) Uani 1 1 d . . .
H38A H 0.7196 0.2549 0.1706 0.089 Uiso 1 1 calc R . .
H38B H 0.8326 0.2895 0.1857 0.089 Uiso 1 1 calc R . .
C39 C 0.8110(4) 0.2391(3) 0.2634(3) 0.0584(15) Uani 1 1 d . . .
H39A H 0.8678 0.2610 0.2960 0.070 Uiso 1 1 calc R . .
H39B H 0.8426 0.2013 0.2497 0.070 Uiso 1 1 calc R . .
C40 C 0.7211(3) 0.2214(2) 0.2969(2) 0.0333(10) Uani 1 1 d . . .
H40A H 0.7518 0.1984 0.3384 0.040 Uiso 1 1 calc R . .
H40B H 0.6694 0.1944 0.2667 0.040 Uiso 1 1 calc R . .
C41 C 0.3561(3) 0.11762(15) 0.43778(17) 0.0174(7) Uani 1 1 d . . .
H41 H 0.2857 0.1087 0.4061 0.021 Uiso 1 1 calc R . .
C42 C 0.3422(3) 0.17440(16) 0.47896(19) 0.0218(8) Uani 1 1 d . . .
H42A H 0.4119 0.1853 0.5091 0.026 Uiso 1 1 calc R . .
H42B H 0.3184 0.2094 0.4485 0.026 Uiso 1 1 calc R . .
C43 C 0.2602(3) 0.16316(17) 0.5206(2) 0.0256(8) Uani 1 1 d . . .
H43A H 0.2585 0.1992 0.5495 0.031 Uiso 1 1 calc R . .
H43B H 0.1882 0.1585 0.4902 0.031 Uiso 1 1 calc R . .
C44 C 0.2867(3) 0.10605(17) 0.56386(19) 0.0258(8) Uani 1 1 d . . .
H44A H 0.2285 0.0981 0.5864 0.031 Uiso 1 1 calc R . .
H44B H 0.3535 0.1129 0.5987 0.031 Uiso 1 1 calc R . .
C45 C 0.3002(3) 0.05052(17) 0.52183(19) 0.0244(8) Uani 1 1 d . . .
H45A H 0.2315 0.0415 0.4895 0.029 Uiso 1 1 calc R . .
H45B H 0.3202 0.0143 0.5512 0.029 Uiso 1 1 calc R . .
C46 C 0.3867(3) 0.06228(16) 0.48409(18) 0.0213(8) Uani 1 1 d . . .
H46A H 0.3948 0.0256 0.4575 0.026 Uiso 1 1 calc R . .
H46B H 0.4559 0.0701 0.5163 0.026 Uiso 1 1 calc R . .
C47 C 0.4826(3) 0.05926(16) 0.35477(18) 0.0197(7) Uani 1 1 d . . .
H47 H 0.5231 0.0349 0.3938 0.024 Uiso 1 1 calc R . .
C48 C 0.5566(3) 0.06537(17) 0.30714(19) 0.0256(8) Uani 1 1 d . . .
H48A H 0.5185 0.0871 0.2662 0.031 Uiso 1 1 calc R . .
H48B H 0.6201 0.0900 0.3288 0.031 Uiso 1 1 calc R . .
C49 C 0.5929(3) 0.00234(18) 0.2885(2) 0.0297(9) Uani 1 1 d . . .
H49A H 0.6355 0.0075 0.2549 0.036 Uiso 1 1 calc R . .
H49B H 0.6394 -0.0169 0.3286 0.036 Uiso 1 1 calc R . .
C50 C 0.4980(4) -0.03986(19) 0.2602(2) 0.0386(11) Uani 1 1 d . . .
H50A H 0.4590 -0.0245 0.2158 0.046 Uiso 1 1 calc R . .
H50B H 0.5248 -0.0815 0.2542 0.046 Uiso 1 1 calc R . .
C51 C 0.4219(3) -0.04336(18) 0.3054(2) 0.0339(10) Uani 1 1 d . . .
H51A H 0.4578 -0.0642 0.3475 0.041 Uiso 1 1 calc R . .
H51B H 0.3586 -0.0680 0.2835 0.041 Uiso 1 1 calc R . .
C52 C 0.3851(3) 0.02079(17) 0.3216(2) 0.0274(9) Uani 1 1 d . . .
H52A H 0.3455 0.0410 0.2800 0.033 Uiso 1 1 calc R . .
H52B H 0.3367 0.0171 0.3519 0.033 Uiso 1 1 calc R . .
C53 C 0.6021(6) 0.5111(3) 0.2762(4) 0.087(2) Uiso 1 1 d . . .
H53A H 0.5726 0.5513 0.2583 0.105 Uiso 1 1 calc R . .
H53B H 0.6507 0.4967 0.2489 0.105 Uiso 1 1 calc R . .
C54 C 0.6613(8) 0.5187(5) 0.3431(5) 0.145(4) Uiso 1 1 d . . .
H54A H 0.6123 0.5283 0.3713 0.217 Uiso 1 1 calc R . .
H54B H 0.7125 0.5524 0.3455 0.217 Uiso 1 1 calc R . .
H54C H 0.6999 0.4808 0.3588 0.217 Uiso 1 1 calc R . .
C55 C 0.4572(5) 0.4634(3) 0.2043(3) 0.0642(15) Uiso 1 1 d . . .
H55A H 0.5048 0.4509 0.1756 0.077 Uiso 1 1 calc R . .
H55B H 0.4260 0.5038 0.1885 0.077 Uiso 1 1 calc R . .
C56 C 0.3720(5) 0.4187(3) 0.1984(3) 0.0696(17) Uiso 1 1 d . . .
H56A H 0.4030 0.3775 0.2068 0.104 Uiso 1 1 calc R . .
H56B H 0.3251 0.4203 0.1533 0.104 Uiso 1 1 calc R . .
H56C H 0.3305 0.4279 0.2311 0.104 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ga Ga 0.2307 1.6083 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P1 Pt1 P2 88.17(4) . . ?
P1 Pt1 Cl1 177.36(3) . . ?
P2 Pt1 Cl1 93.92(4) . . ?
P1 Pt1 Ga1 95.62(3) . . ?
P2 Pt1 Ga1 176.13(2) . . ?
Cl1 Pt1 Ga1 82.27(3) . . ?
N1 Ga1 N2 88.09(12) . . ?
N1 Ga1 Pt1 133.37(9) . . ?
N2 Ga1 Pt1 134.78(9) . . ?
C27 P1 C35 102.83(18) . . ?
C27 P1 C29 107.22(17) . . ?
C35 P1 C29 104.42(17) . . ?
C27 P1 Pt1 107.58(12) . . ?
C35 P1 Pt1 116.53(13) . . ?
C29 P1 Pt1 117.04(12) . . ?
C47 P2 C28 107.79(16) . . ?
C47 P2 C41 105.45(16) . . ?
C28 P2 C41 104.38(16) . . ?
C47 P2 Pt1 113.57(11) . . ?
C28 P2 Pt1 106.88(12) . . ?
C41 P2 Pt1 118.03(12) . . ?
C55 O1 C53 111.5(5) . . ?
C1 N1 C3 116.5(3) . . ?
C1 N1 Ga1 108.0(2) . . ?
C3 N1 Ga1 132.1(2) . . ?
C2 N2 C15 118.8(3) . . ?
C2 N2 Ga1 107.9(2) . . ?
C15 N2 Ga1 132.0(2) . . ?
C2 C1 N1 117.1(3) . . ?
C1 C2 N2 118.2(3) . . ?
C8 C3 C4 119.8(3) . . ?
C8 C3 N1 120.2(3) . . ?
C4 C3 N1 120.0(3) . . ?
C5 C4 C3 118.4(3) . . ?
C5 C4 C9 121.2(3) . . ?
C3 C4 C9 120.4(3) . . ?
C6 C5 C4 121.8(3) . . ?
C5 C6 C7 119.5(3) . . ?
C6 C7 C8 121.2(4) . . ?
C7 C8 C3 119.1(3) . . ?
C7 C8 C12 118.9(3) . . ?
C3 C8 C12 121.9(3) . . ?
C10 C9 C4 111.0(3) . . ?
C10 C9 C11 110.8(4) . . ?
C4 C9 C11 113.4(3) . . ?
C13 C12 C8 113.8(3) . . ?
C13 C12 C14 110.0(3) . . ?
C8 C12 C14 111.0(3) . . ?
C20 C15 C16 120.1(3) . . ?
C20 C15 N2 121.1(3) . . ?
C16 C15 N2 118.8(3) . . ?
C17 C16 C15 118.5(3) . . ?
C17 C16 C21 121.5(3) . . ?
C15 C16 C21 120.0(3) . . ?
C16 C17 C18 121.5(4) . . ?
C19 C18 C17 119.5(3) . . ?
C18 C19 C20 121.3(3) . . ?
C19 C20 C15 119.1(3) . . ?
C19 C20 C24 118.6(3) . . ?
C15 C20 C24 122.3(3) . . ?
C16 C21 C22 110.3(3) . . ?
C16 C21 C23 113.0(3) . . ?
C22 C21 C23 110.8(3) . . ?
C20 C24 C26 112.0(3) . . ?
C20 C24 C25 111.5(3) . . ?
C26 C24 C25 110.5(3) . . ?
C28 C27 P1 112.8(2) . . ?
C27 C28 P2 111.3(2) . . ?
C30 C29 C34 109.6(3) . . ?
C30 C29 P1 111.4(2) . . ?
C34 C29 P1 113.7(2) . . ?
C31 C30 C29 112.2(3) . . ?
C32 C31 C30 110.9(3) . . ?
C31 C32 C33 110.4(3) . . ?
C32 C33 C34 111.1(3) . . ?
C33 C34 C29 110.3(3) . . ?
C36 C35 C40 111.1(4) . . ?
C36 C35 P1 115.6(3) . . ?
C40 C35 P1 110.9(3) . . ?
C35 C36 C37 111.5(4) . . ?
C38 C37 C36 109.0(5) . . ?
C39 C38 C37 111.0(5) . . ?
C38 C39 C40 111.9(4) . . ?
C39 C40 C35 111.3(4) . . ?
C46 C41 C42 109.6(3) . . ?
C46 C41 P2 113.1(2) . . ?
C42 C41 P2 110.0(2) . . ?
C43 C42 C41 111.7(3) . . ?
C44 C43 C42 111.9(3) . . ?
C43 C44 C45 110.8(3) . . ?
C44 C45 C46 110.9(3) . . ?
C45 C46 C41 110.0(3) . . ?
C52 C47 C48 109.4(3) . . ?
C52 C47 P2 115.8(2) . . ?
C48 C47 P2 112.1(2) . . ?
C49 C48 C47 111.0(3) . . ?
C50 C49 C48 111.9(3) . . ?
C51 C50 C49 111.9(3) . . ?
C50 C51 C52 111.6(3) . . ?
C47 C52 C51 109.5(3) . . ?
O1 C53 C54 112.3(7) . . ?
O1 C55 C56 111.4(5) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 P1 2.2031(10) . ?
Pt1 P2 2.3112(10) . ?
Pt1 Cl1 2.3723(10) . ?
Pt1 Ga1 2.4151(7) . ?
Ga1 N1 1.897(3) . ?
Ga1 N2 1.898(3) . ?
P1 C27 1.844(4) . ?
P1 C35 1.848(4) . ?
P1 C29 1.850(4) . ?
P2 C47 1.838(4) . ?
P2 C28 1.840(4) . ?
P2 C41 1.844(3) . ?
O1 C55 1.403(6) . ?
O1 C53 1.414(7) . ?
N1 C1 1.408(4) . ?
N1 C3 1.421(4) . ?
N2 C2 1.393(4) . ?
N2 C15 1.427(4) . ?
C1 C2 1.340(5) . ?
C3 C8 1.414(5) . ?
C3 C4 1.417(5) . ?
C4 C5 1.397(5) . ?
C4 C9 1.516(5) . ?
C5 C6 1.379(6) . ?
C6 C7 1.386(5) . ?
C7 C8 1.394(5) . ?
C8 C12 1.525(5) . ?
C9 C10 1.516(6) . ?
C9 C11 1.522(5) . ?
C12 C13 1.522(6) . ?
C12 C14 1.540(6) . ?
C15 C20 1.410(5) . ?
C15 C16 1.418(5) . ?
C16 C17 1.392(5) . ?
C16 C21 1.522(5) . ?
C17 C18 1.394(5) . ?
C18 C19 1.379(5) . ?
C19 C20 1.395(5) . ?
C20 C24 1.515(5) . ?
C21 C22 1.523(5) . ?
C21 C23 1.529(5) . ?
C24 C26 1.533(6) . ?
C24 C25 1.535(6) . ?
C27 C28 1.528(5) . ?
C29 C30 1.533(5) . ?
C29 C34 1.537(5) . ?
C30 C31 1.531(5) . ?
C31 C32 1.522(6) . ?
C32 C33 1.523(6) . ?
C33 C34 1.530(5) . ?
C35 C36 1.479(6) . ?
C35 C40 1.541(5) . ?
C36 C37 1.545(6) . ?
C37 C38 1.540(8) . ?
C38 C39 1.462(7) . ?
C39 C40 1.536(6) . ?
C41 C46 1.531(5) . ?
C41 C42 1.538(5) . ?
C42 C43 1.536(5) . ?
C43 C44 1.523(5) . ?
C44 C45 1.525(5) . ?
C45 C46 1.529(5) . ?
C47 C52 1.528(5) . ?
C47 C48 1.534(5) . ?
C48 C49 1.531(5) . ?
C49 C50 1.528(6) . ?
C50 C51 1.513(6) . ?
C51 C52 1.540(5) . ?
C53 C54 1.416(11) . ?
C55 C56 1.452(8) . ?
