#------------------------------------------------------------------------------
#$Date: 2016-03-25 10:05:59 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179740 $
#$URL: svn://www.crystallography.net/cod/cif/7/00/36/7003669.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7003669
loop_
_publ_author_name
'Bösing, Patrick'
'Willner, Alexander'
'Pape, Tania'
'Hepp, Alexander'
'Mitzel, Norbert W.'
_publ_section_title
;
 Structural diversity in bishydroxylamine complexes of gallium
;
_journal_issue                   19
_journal_name_full               'Dalton Transactions'
_journal_page_first              2549
_journal_page_last               2556
_journal_paper_doi               10.1039/b718268f
_journal_year                    2008
_chemical_formula_sum            'C16 H38 Ga2 N2 O2'
_chemical_formula_weight         429.92
_chemical_name_common
;
N,N'-Bis-oxo-N,N'-dimethylethylenediamine
tetrakis.isopropyldigallate
;
_chemical_name_systematic
;
1,4-Dimethyl-2,2,5,5-Tetrakis-isopropyl-2,5-digalla
-3,6-dioxa-1,4-diazabicyclo[2,2,2]octan
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                104.349(18)
_cell_angle_beta                 109.081(18)
_cell_angle_gamma                101.892(18)
_cell_formula_units_Z            2
_cell_length_a                   9.4306(17)
_cell_length_b                   9.9648(18)
_cell_length_c                   13.183(2)
_cell_measurement_reflns_used    5000
_cell_measurement_temperature    163(2)
_cell_measurement_theta_max      26.90
_cell_measurement_theta_min      4.57
_cell_volume                     1077.1(4)
_computing_cell_refinement       'STOE IPDS 1 software package'
_computing_data_collection       'STOE IPDS 1 software package'
_computing_data_reduction        'STOE IPDS 1 software package'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      163(2)
_diffrn_measured_fraction_theta_full 0.925
_diffrn_measured_fraction_theta_max 0.925
_diffrn_measurement_device_type  'STOE IPDS 1'
_diffrn_measurement_method       'φ scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.1183
_diffrn_reflns_av_sigmaI/netI    0.0705
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            16845
_diffrn_reflns_theta_full        26.90
_diffrn_reflns_theta_max         26.90
_diffrn_reflns_theta_min         4.57
_exptl_absorpt_coefficient_mu    2.509
_exptl_absorpt_correction_T_max  0.478
_exptl_absorpt_correction_T_min  0.166
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details
;
Absorption correction was done with the program ABSCOR from
the IPDS-1 software package. ABSCOR works similar to the
well known DIFABS, but reads and provides Fo² values
instead of Fo ones.
;
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.326
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Plate
_exptl_crystal_F_000             452
_exptl_crystal_size_max          0.6
_exptl_crystal_size_mid          0.4
_exptl_crystal_size_min          0.3
_refine_diff_density_max         2.651
_refine_diff_density_min         -1.389
_refine_diff_density_rms         0.177
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.037
_refine_ls_hydrogen_treatment    noref
_refine_ls_matrix_type           full
_refine_ls_number_parameters     209
_refine_ls_number_reflns         4304
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.037
_refine_ls_R_factor_all          0.0790
_refine_ls_R_factor_gt           0.0689
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0997P)²+8.2187P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1942
_refine_ls_wR_factor_ref         0.2023
_reflns_number_gt                3622
_reflns_number_total             4304
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b718268f.txt
_cod_data_source_block           serrano
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_cell_volume        1077.1(3)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7003669
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ga2 Ga 0.91483(7) 0.83239(7) 0.70043(5) 0.0206(2) Uani 1 1 d . . .
Ga1 Ga 0.68948(7) 0.59833(7) 0.80534(5) 0.0203(2) Uani 1 1 d . . .
O1 O 0.7571(5) 0.6472(4) 0.6192(3) 0.0237(9) Uani 1 1 d . . .
O2 O 0.8708(5) 0.7679(5) 0.8890(4) 0.0235(9) Uani 1 1 d . . .
N1 N 0.7592(6) 0.5369(5) 0.6734(4) 0.0191(10) Uani 1 1 d . . .
N2 N 0.9936(6) 0.7830(5) 0.8482(4) 0.0202(10) Uani 1 1 d . . .
C1 C 0.7089(8) 0.4584(7) 0.8894(6) 0.0305(14) Uani 1 1 d . . .
H1B H 0.8093 0.4354 0.8966 0.037 Uiso 1 1 calc R . .
C11 C 0.5721(11) 0.3141(8) 0.8345(8) 0.048(2) Uani 1 1 d . . .
H11D H 0.5906 0.2534 0.8826 0.071 Uiso 1 1 calc R . .
H11E H 0.5658 0.2624 0.7587 0.071 Uiso 1 1 calc R . .
H11F H 0.4726 0.3346 0.8271 0.071 Uiso 1 1 calc R . .
C12 C 0.7215(10) 0.5364(9) 1.0092(7) 0.0425(18) Uani 1 1 d . . .
H12D H 0.7163 0.4667 1.0499 0.064 Uiso 1 1 calc R . .
H12E H 0.6340 0.5769 1.0032 0.064 Uiso 1 1 calc R . .
H12F H 0.8222 0.6154 1.0511 0.064 Uiso 1 1 calc R . .
C2 C 0.5014(7) 0.6626(7) 0.7532(6) 0.0266(13) Uani 1 1 d . . .
H1A H 0.5103 0.7060 0.6939 0.032 Uiso 1 1 calc R . .
C21 C 0.3457(8) 0.5395(8) 0.6974(7) 0.0363(16) Uani 1 1 d . . .
H12A H 0.2591 0.5774 0.6667 0.054 Uiso 1 1 calc R . .
H12B H 0.3290 0.4981 0.7543 0.054 Uiso 1 1 calc R . .
H12C H 0.3485 0.4635 0.6352 0.054 Uiso 1 1 calc R . .
C22 C 0.5026(8) 0.7833(8) 0.8508(7) 0.0372(17) Uani 1 1 d . . .
H11A H 0.4148 0.8207 0.8219 0.056 Uiso 1 1 calc R . .
H11B H 0.6028 0.8626 0.8833 0.056 Uiso 1 1 calc R . .
H11C H 0.4910 0.7443 0.9100 0.056 Uiso 1 1 calc R . .
C3 C 0.6502(8) 0.4012(7) 0.5815(6) 0.0289(14) Uani 1 1 d . . .
H3A H 0.6810 0.3870 0.5164 0.043 Uiso 1 1 calc R . .
H3B H 0.5424 0.4071 0.5576 0.043 Uiso 1 1 calc R . .
H3C H 0.6543 0.3187 0.6091 0.043 Uiso 1 1 calc R . .
C4 C 0.9219(7) 0.5268(6) 0.7143(5) 0.0239(13) Uani 1 1 d . . .
H4A H 0.9653 0.5339 0.6562 0.029 Uiso 1 1 calc R . .
H4B H 0.9172 0.4301 0.7227 0.029 Uiso 1 1 calc R . .
C5 C 1.0906(8) 0.8411(8) 0.6472(7) 0.0323(15) Uani 1 1 d . . .
H5A H 1.1490 0.7764 0.6767 0.039 Uiso 1 1 calc R . .
C51 C 1.2101(10) 0.9930(9) 0.6919(8) 0.0458(19) Uani 1 1 d . . .
H51A H 1.2950 0.9883 0.6651 0.069 Uiso 1 1 calc R . .
H51B H 1.2547 1.0290 0.7756 0.069 Uiso 1 1 calc R . .
H51C H 1.1572 1.0594 0.6637 0.069 Uiso 1 1 calc R . .
C52 C 1.0275(11) 0.7807(11) 0.5172(8) 0.053(2) Uani 1 1 d . . .
H52A H 1.1161 0.7913 0.4934 0.079 Uiso 1 1 calc R . .
H52B H 0.9594 0.8347 0.4848 0.079 Uiso 1 1 calc R . .
H52C H 0.9663 0.6772 0.4898 0.079 Uiso 1 1 calc R . .
C6 C 0.8043(8) 0.9791(7) 0.7200(6) 0.0292(14) Uani 1 1 d . . .
H6A H 0.7507 0.9598 0.7714 0.035 Uiso 1 1 calc R . .
C61 C 0.9127(10) 1.1364(7) 0.7765(7) 0.0403(18) Uani 1 1 d . . .
H61A H 0.8501 1.2018 0.7870 0.060 Uiso 1 1 calc R . .
H61B H 0.9663 1.1604 0.7279 0.060 Uiso 1 1 calc R . .
H61C H 0.9916 1.1480 0.8509 0.060 Uiso 1 1 calc R . .
C62 C 0.6765(11) 0.9604(9) 0.6082(8) 0.050(2) Uani 1 1 d . . .
H62A H 0.6073 1.0171 0.6226 0.076 Uiso 1 1 calc R . .
H62B H 0.6143 0.8571 0.5692 0.076 Uiso 1 1 calc R . .
H62C H 0.7247 0.9950 0.5600 0.076 Uiso 1 1 calc R . .
C7 C 1.1291(8) 0.8997(7) 0.9419(5) 0.0290(14) Uani 1 1 d . . .
H7A H 1.1587 0.8707 1.0098 0.043 Uiso 1 1 calc R . .
H7B H 1.1005 0.9893 0.9592 0.043 Uiso 1 1 calc R . .
H7C H 1.2186 0.9171 0.9193 0.043 Uiso 1 1 calc R . .
C8 C 1.0331(7) 0.6451(7) 0.8280(5) 0.0235(12) Uani 1 1 d . . .
H8A H 1.0314 0.6074 0.8905 0.028 Uiso 1 1 calc R . .
H8B H 1.1420 0.6662 0.8310 0.028 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ga Ga 0.2307 1.6083 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Ga2 C6 107.1(2) . . ?
O1 Ga2 C5 109.7(2) . . ?
C6 Ga2 C5 127.4(3) . . ?
O1 Ga2 N2 92.71(19) . . ?
C6 Ga2 N2 110.0(3) . . ?
C5 Ga2 N2 104.6(3) . . ?
O2 Ga1 C2 108.2(2) . . ?
O2 Ga1 C1 107.8(2) . . ?
C2 Ga1 C1 124.8(3) . . ?
O2 Ga1 N1 93.08(19) . . ?
C2 Ga1 N1 109.6(2) . . ?
C1 Ga1 N1 108.7(2) . . ?
N1 O1 Ga2 117.9(3) . . ?
N2 O2 Ga1 117.4(3) . . ?
O1 N1 C3 104.4(4) . . ?
O1 N1 C4 108.3(4) . . ?
C3 N1 C4 110.1(5) . . ?
O1 N1 Ga1 107.8(3) . . ?
C3 N1 Ga1 113.9(4) . . ?
C4 N1 Ga1 111.8(4) . . ?
O2 N2 C7 104.9(5) . . ?
O2 N2 C8 108.7(4) . . ?
C7 N2 C8 109.4(5) . . ?
O2 N2 Ga2 108.1(3) . . ?
C7 N2 Ga2 113.6(4) . . ?
C8 N2 Ga2 111.9(4) . . ?
C12 C1 C11 109.2(7) . . ?
C12 C1 Ga1 107.0(5) . . ?
C11 C1 Ga1 115.3(5) . . ?
C12 C1 H1B 108.4 . . ?
C11 C1 H1B 108.4 . . ?
Ga1 C1 H1B 108.4 . . ?
C1 C11 H11D 109.5 . . ?
C1 C11 H11E 109.5 . . ?
H11D C11 H11E 109.5 . . ?
C1 C11 H11F 109.5 . . ?
H11D C11 H11F 109.5 . . ?
H11E C11 H11F 109.5 . . ?
C1 C12 H12D 109.5 . . ?
C1 C12 H12E 109.5 . . ?
H12D C12 H12E 109.5 . . ?
C1 C12 H12F 109.5 . . ?
H12D C12 H12F 109.5 . . ?
H12E C12 H12F 109.5 . . ?
C21 C2 C22 111.3(6) . . ?
C21 C2 Ga1 114.0(5) . . ?
C22 C2 Ga1 110.4(4) . . ?
C21 C2 H1A 106.9 . . ?
C22 C2 H1A 106.9 . . ?
Ga1 C2 H1A 106.9 . . ?
C2 C21 H12A 109.5 . . ?
C2 C21 H12B 109.5 . . ?
H12A C21 H12B 109.5 . . ?
C2 C21 H12C 109.5 . . ?
H12A C21 H12C 109.5 . . ?
H12B C21 H12C 109.5 . . ?
C2 C22 H11A 109.5 . . ?
C2 C22 H11B 109.5 . . ?
H11A C22 H11B 109.5 . . ?
C2 C22 H11C 109.5 . . ?
H11A C22 H11C 109.5 . . ?
H11B C22 H11C 109.5 . . ?
N1 C3 H3A 109.5 . . ?
N1 C3 H3B 109.5 . . ?
H3A C3 H3B 109.5 . . ?
N1 C3 H3C 109.5 . . ?
H3A C3 H3C 109.5 . . ?
H3B C3 H3C 109.5 . . ?
N1 C4 C8 113.2(5) . . ?
N1 C4 H4A 108.9 . . ?
C8 C4 H4A 108.9 . . ?
N1 C4 H4B 108.9 . . ?
C8 C4 H4B 108.9 . . ?
H4A C4 H4B 107.8 . . ?
C52 C5 C51 109.8(7) . . ?
C52 C5 Ga2 111.3(5) . . ?
C51 C5 Ga2 114.0(5) . . ?
C52 C5 H5A 107.1 . . ?
C51 C5 H5A 107.1 . . ?
Ga2 C5 H5A 107.1 . . ?
C5 C51 H51A 109.5 . . ?
C5 C51 H51B 109.5 . . ?
H51A C51 H51B 109.5 . . ?
C5 C51 H51C 109.5 . . ?
H51A C51 H51C 109.5 . . ?
H51B C51 H51C 109.5 . . ?
C5 C52 H52A 109.5 . . ?
C5 C52 H52B 109.5 . . ?
H52A C52 H52B 109.5 . . ?
C5 C52 H52C 109.5 . . ?
H52A C52 H52C 109.5 . . ?
H52B C52 H52C 109.5 . . ?
C62 C6 C61 110.4(6) . . ?
C62 C6 Ga2 111.1(5) . . ?
C61 C6 Ga2 114.4(5) . . ?
C62 C6 H6A 106.8 . . ?
C61 C6 H6A 106.8 . . ?
Ga2 C6 H6A 106.8 . . ?
C6 C61 H61A 109.5 . . ?
C6 C61 H61B 109.5 . . ?
H61A C61 H61B 109.5 . . ?
C6 C61 H61C 109.5 . . ?
H61A C61 H61C 109.5 . . ?
H61B C61 H61C 109.5 . . ?
C6 C62 H62A 109.5 . . ?
C6 C62 H62B 109.5 . . ?
H62A C62 H62B 109.5 . . ?
C6 C62 H62C 109.5 . . ?
H62A C62 H62C 109.5 . . ?
H62B C62 H62C 109.5 . . ?
N2 C7 H7A 109.5 . . ?
N2 C7 H7B 109.5 . . ?
H7A C7 H7B 109.5 . . ?
N2 C7 H7C 109.5 . . ?
H7A C7 H7C 109.5 . . ?
H7B C7 H7C 109.5 . . ?
N2 C8 C4 114.3(5) . . ?
N2 C8 H8A 108.7 . . ?
C4 C8 H8A 108.7 . . ?
N2 C8 H8B 108.7 . . ?
C4 C8 H8B 108.7 . . ?
H8A C8 H8B 107.6 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ga2 O1 1.900(4) . ?
Ga2 C6 1.977(6) . ?
Ga2 C5 1.995(7) . ?
Ga2 N2 2.065(5) . ?
Ga1 O2 1.910(4) . ?
Ga1 C2 1.979(6) . ?
Ga1 C1 1.986(7) . ?
Ga1 N1 2.054(5) . ?
O1 N1 1.453(6) . ?
O2 N2 1.425(7) . ?
N1 C3 1.468(7) . ?
N1 C4 1.484(7) . ?
N2 C7 1.468(7) . ?
N2 C8 1.481(8) . ?
C1 C12 1.531(11) . ?
C1 C11 1.538(10) . ?
C1 H1B 1.0000 . ?
C11 H11D 0.9800 . ?
C11 H11E 0.9800 . ?
C11 H11F 0.9800 . ?
C12 H12D 0.9800 . ?
C12 H12E 0.9800 . ?
C12 H12F 0.9800 . ?
C2 C21 1.518(9) . ?
C2 C22 1.524(9) . ?
C2 H1A 1.0000 . ?
C21 H12A 0.9800 . ?
C21 H12B 0.9800 . ?
C21 H12C 0.9800 . ?
C22 H11A 0.9800 . ?
C22 H11B 0.9800 . ?
C22 H11C 0.9800 . ?
C3 H3A 0.9800 . ?
C3 H3B 0.9800 . ?
C3 H3C 0.9800 . ?
C4 C8 1.524(8) . ?
C4 H4A 0.9900 . ?
C4 H4B 0.9900 . ?
C5 C52 1.526(11) . ?
C5 C51 1.526(10) . ?
C5 H5A 1.0000 . ?
C51 H51A 0.9800 . ?
C51 H51B 0.9800 . ?
C51 H51C 0.9800 . ?
C52 H52A 0.9800 . ?
C52 H52B 0.9800 . ?
C52 H52C 0.9800 . ?
C6 C62 1.507(10) . ?
C6 C61 1.523(9) . ?
C6 H6A 1.0000 . ?
C61 H61A 0.9800 . ?
C61 H61B 0.9800 . ?
C61 H61C 0.9800 . ?
C62 H62A 0.9800 . ?
C62 H62B 0.9800 . ?
C62 H62C 0.9800 . ?
C7 H7A 0.9800 . ?
C7 H7B 0.9800 . ?
C7 H7C 0.9800 . ?
C8 H8A 0.9900 . ?
C8 H8B 0.9900 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C6 Ga2 O1 N1 -120.7(4) . . . . ?
C5 Ga2 O1 N1 97.7(4) . . . . ?
N2 Ga2 O1 N1 -8.8(4) . . . . ?
C2 Ga1 O2 N2 -120.9(4) . . . . ?
C1 Ga1 O2 N2 101.7(4) . . . . ?
N1 Ga1 O2 N2 -9.1(4) . . . . ?
Ga2 O1 N1 C3 -167.4(4) . . . . ?
Ga2 O1 N1 C4 -50.1(5) . . . . ?
Ga2 O1 N1 Ga1 71.1(4) . . . . ?
O2 Ga1 N1 O1 -65.2(3) . . . . ?
C2 Ga1 N1 O1 45.3(4) . . . . ?
C1 Ga1 N1 O1 -175.2(3) . . . . ?
O2 Ga1 N1 C3 179.4(4) . . . . ?
C2 Ga1 N1 C3 -70.0(5) . . . . ?
C1 Ga1 N1 C3 69.4(5) . . . . ?
O2 Ga1 N1 C4 53.8(4) . . . . ?
C2 Ga1 N1 C4 164.4(4) . . . . ?
C1 Ga1 N1 C4 -56.2(4) . . . . ?
Ga1 O2 N2 C7 -166.5(4) . . . . ?
Ga1 O2 N2 C8 -49.6(5) . . . . ?
Ga1 O2 N2 Ga2 72.0(4) . . . . ?
O1 Ga2 N2 O2 -66.1(3) . . . . ?
C6 Ga2 N2 O2 43.2(4) . . . . ?
C5 Ga2 N2 O2 -177.3(3) . . . . ?
O1 Ga2 N2 C7 177.9(4) . . . . ?
C6 Ga2 N2 C7 -72.8(5) . . . . ?
C5 Ga2 N2 C7 66.8(5) . . . . ?
O1 Ga2 N2 C8 53.5(4) . . . . ?
C6 Ga2 N2 C8 162.8(4) . . . . ?
C5 Ga2 N2 C8 -57.6(4) . . . . ?
O2 Ga1 C1 C12 58.1(5) . . . . ?
C2 Ga1 C1 C12 -70.4(6) . . . . ?
N1 Ga1 C1 C12 157.8(5) . . . . ?
O2 Ga1 C1 C11 179.8(5) . . . . ?
C2 Ga1 C1 C11 51.3(7) . . . . ?
N1 Ga1 C1 C11 -80.5(6) . . . . ?
O2 Ga1 C2 C21 -173.1(5) . . . . ?
C1 Ga1 C2 C21 -44.7(6) . . . . ?
N1 Ga1 C2 C21 86.7(6) . . . . ?
O2 Ga1 C2 C22 -46.9(6) . . . . ?
C1 Ga1 C2 C22 81.5(6) . . . . ?
N1 Ga1 C2 C22 -147.1(5) . . . . ?
O1 N1 C4 C8 81.0(6) . . . . ?
C3 N1 C4 C8 -165.4(5) . . . . ?
Ga1 N1 C4 C8 -37.7(6) . . . . ?
O1 Ga2 C5 C52 45.3(6) . . . . ?
C6 Ga2 C5 C52 -86.5(7) . . . . ?
N2 Ga2 C5 C52 143.6(6) . . . . ?
O1 Ga2 C5 C51 170.2(5) . . . . ?
C6 Ga2 C5 C51 38.4(7) . . . . ?
N2 Ga2 C5 C51 -91.5(6) . . . . ?
O1 Ga2 C6 C62 -50.0(6) . . . . ?
C5 Ga2 C6 C62 82.7(7) . . . . ?
N2 Ga2 C6 C62 -149.5(6) . . . . ?
O1 Ga2 C6 C61 -175.9(5) . . . . ?
C5 Ga2 C6 C61 -43.2(7) . . . . ?
N2 Ga2 C6 C61 84.7(6) . . . . ?
O2 N2 C8 C4 81.5(6) . . . . ?
C7 N2 C8 C4 -164.5(5) . . . . ?
Ga2 N2 C8 C4 -37.7(6) . . . . ?
N1 C4 C8 N2 -29.2(8) . . . . ?
