#------------------------------------------------------------------------------
#$Date: 2016-03-25 10:09:59 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179742 $
#$URL: svn://www.crystallography.net/cod/cif/7/00/38/7003808.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7003808
loop_
_publ_author_name
'Ge, Qingchun'
'Hor, T. S. Andy'
_publ_section_title
;
 Stepwise assembly of linearly-aligned Ru--M--Ru (M = Pd, Pt)
 heterotrimetallic complexes with σ-4-ethynylpyridine spacer
;
_journal_issue                   22
_journal_name_full               'Dalton Transactions'
_journal_page_first              2929
_journal_page_last               2936
_journal_paper_doi               10.1039/b719820e
_journal_year                    2008
_chemical_formula_sum            'C118 H104 Cl4 N2 O P8 Pt Ru2'
_chemical_formula_weight         2352.82
_chemical_name_systematic
;
?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 97.706(4)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   10.1772(16)
_cell_length_b                   31.291(5)
_cell_length_c                   17.958(3)
_cell_measurement_reflns_used    4281
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      22.28
_cell_measurement_theta_min      2.26
_cell_volume                     5667.2(16)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0585
_diffrn_reflns_av_sigmaI/netI    0.0632
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       37
_diffrn_reflns_limit_k_min       -36
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            32602
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         1.73
_exptl_absorpt_coefficient_mu    1.749
_exptl_absorpt_correction_T_max  0.9023
_exptl_absorpt_correction_T_min  0.7672
_exptl_absorpt_correction_type   'Sadabs, (Sheldrick 2001)'
_exptl_crystal_colour            Yellow
_exptl_crystal_density_diffrn    1.379
_exptl_crystal_density_meas      0
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Rod
_exptl_crystal_F_000             2376
_exptl_crystal_size_max          0.16
_exptl_crystal_size_mid          0.08
_exptl_crystal_size_min          0.06
_refine_diff_density_max         1.106
_refine_diff_density_min         -1.296
_refine_diff_density_rms         0.108
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.097
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     638
_refine_ls_number_reflns         9949
_refine_ls_number_restraints     39
_refine_ls_restrained_S_all      1.107
_refine_ls_R_factor_all          0.0801
_refine_ls_R_factor_gt           0.0593
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0684P)²+2.5576P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1357
_refine_ls_wR_factor_ref         0.1453
_reflns_number_gt                7790
_reflns_number_total             9949
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b719820e.txt
_cod_data_source_block           6101
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_cell_volume        5667.1(15)
_cod_original_sg_symbol_H-M      P2(1)/n
_cod_database_code               7003808
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.5000 0.5000 0.0000 0.04720(14) Uani 1 2 d S . .
Ru1 Ru 0.49980(5) 0.320783(15) 0.41792(3) 0.03446(15) Uani 1 1 d . . .
P1 P 0.70849(17) 0.35062(6) 0.45250(9) 0.0417(4) Uani 1 1 d . . .
P2 P 0.65537(17) 0.27765(5) 0.36756(9) 0.0394(4) Uani 1 1 d . . .
P3 P 0.35197(16) 0.36342(5) 0.47496(9) 0.0370(4) Uani 1 1 d . . .
P4 P 0.28360(17) 0.29481(5) 0.38175(9) 0.0426(4) Uani 1 1 d . . .
Cl1 Cl 0.4799(3) 0.44827(7) -0.09041(11) 0.0996(9) Uani 1 1 d . . .
Cl2 Cl 0.4983(2) 0.27417(7) 0.52784(11) 0.0706(6) Uani 1 1 d . . .
N1 N 0.4826(6) 0.45554(18) 0.0796(3) 0.0496(14) Uani 1 1 d . . .
C1 C 0.4857(6) 0.35408(19) 0.3241(3) 0.0368(14) Uani 1 1 d . . .
C2 C 0.4774(7) 0.3731(2) 0.2645(4) 0.0487(17) Uani 1 1 d . . .
C3 C 0.5615(8) 0.4216(2) 0.0885(4) 0.062(2) Uani 1 1 d . . .
H3 H 0.6203 0.4169 0.0539 0.074 Uiso 1 1 calc R . .
C4 C 0.5599(8) 0.3932(2) 0.1468(4) 0.065(2) Uani 1 1 d . . .
H4 H 0.6163 0.3697 0.1502 0.078 Uiso 1 1 calc R . .
C5 C 0.4755(7) 0.3989(2) 0.2007(3) 0.0490(17) Uani 1 1 d . . .
C6 C 0.3894(8) 0.4336(3) 0.1871(5) 0.075(3) Uani 1 1 d . . .
H6 H 0.3253 0.4382 0.2186 0.090 Uiso 1 1 calc R . .
C7 C 0.3977(8) 0.4608(3) 0.1285(4) 0.073(3) Uani 1 1 d . . .
H7 H 0.3409 0.4842 0.1227 0.088 Uiso 1 1 calc R . .
C8 C 0.8022(6) 0.3098(2) 0.4063(4) 0.0469(16) Uani 1 1 d . . .
H8A H 0.8637 0.2939 0.4419 0.056 Uiso 1 1 calc R . .
H8B H 0.8484 0.3219 0.3673 0.056 Uiso 1 1 calc R . .
C9 C 0.2135(6) 0.3252(2) 0.4548(3) 0.0424(15) Uani 1 1 d . . .
H9A H 0.2016 0.3078 0.4980 0.051 Uiso 1 1 calc R . .
H9B H 0.1308 0.3392 0.4357 0.051 Uiso 1 1 calc R . .
C1A C 0.7924(7) 0.3544(3) 0.5489(4) 0.060(2) Uani 1 1 d . . .
C2A C 0.9249(9) 0.3630(4) 0.5650(5) 0.108(4) Uani 1 1 d . . .
H2A H 0.9758 0.3662 0.5260 0.129 Uiso 1 1 calc R . .
C3A C 0.9832(12) 0.3672(5) 0.6379(7) 0.147(6) Uani 1 1 d . . .
H3A H 1.0731 0.3736 0.6478 0.177 Uiso 1 1 calc R . .
C4A C 0.9121(13) 0.3621(5) 0.6952(6) 0.128(5) Uani 1 1 d . . .
H4A H 0.9530 0.3648 0.7445 0.154 Uiso 1 1 calc R . .
C5A C 0.7821(12) 0.3530(5) 0.6816(5) 0.131(5) Uani 1 1 d . . .
H5A H 0.7333 0.3497 0.7214 0.157 Uiso 1 1 calc R . .
C6A C 0.7202(8) 0.3485(3) 0.6082(4) 0.077(3) Uani 1 1 d . . .
H6A H 0.6306 0.3415 0.5990 0.093 Uiso 1 1 calc R . .
C1B C 0.7448(7) 0.4020(2) 0.4122(4) 0.0521(18) Uani 1 1 d . . .
C2B C 0.7316(9) 0.4387(3) 0.4514(6) 0.088(3) Uani 1 1 d . . .
H2B H 0.7157 0.4369 0.5011 0.105 Uiso 1 1 calc R . .
C3B C 0.7412(12) 0.4781(4) 0.4196(9) 0.114(4) Uani 1 1 d . . .
H3B H 0.7326 0.5028 0.4473 0.137 Uiso 1 1 calc R . .
C4B C 0.7633(13) 0.4804(4) 0.3472(10) 0.127(5) Uani 1 1 d . . .
H4B H 0.7675 0.5072 0.3253 0.152 Uiso 1 1 calc R . .
C5B C 0.7799(10) 0.4446(4) 0.3044(7) 0.103(4) Uani 1 1 d . . .
H5B H 0.7978 0.4469 0.2551 0.124 Uiso 1 1 calc R . .
C6B C 0.7688(9) 0.4050(3) 0.3383(5) 0.076(2) Uani 1 1 d . . .
H6B H 0.7777 0.3802 0.3109 0.091 Uiso 1 1 calc R . .
C1C C 0.6971(6) 0.2233(2) 0.4003(4) 0.0406(15) Uani 1 1 d . . .
C2C C 0.6756(7) 0.1889(2) 0.3536(4) 0.0564(19) Uani 1 1 d . . .
H2C H 0.6422 0.1932 0.3033 0.068 Uiso 1 1 calc R . .
C3C C 0.7022(8) 0.1478(3) 0.3791(5) 0.072(2) Uani 1 1 d . . .
H3C H 0.6868 0.1247 0.3466 0.086 Uiso 1 1 calc R . .
C4C C 0.7525(9) 0.1414(3) 0.4542(6) 0.075(2) Uani 1 1 d . . .
H4C H 0.7710 0.1139 0.4722 0.091 Uiso 1 1 calc R . .
C5C C 0.7746(9) 0.1754(3) 0.5014(5) 0.072(2) Uani 1 1 d . . .
H5C H 0.8078 0.1712 0.5517 0.086 Uiso 1 1 calc R . .
C6C C 0.7477(7) 0.2161(2) 0.4744(4) 0.059(2) Uani 1 1 d . . .
H6C H 0.7639 0.2393 0.5068 0.071 Uiso 1 1 calc R . .
C1D C 0.6550(7) 0.2737(2) 0.2675(4) 0.0491(17) Uani 1 1 d . . .
C2D C 0.7672(9) 0.2760(3) 0.2313(5) 0.074(2) Uani 1 1 d . . .
H2D H 0.8500 0.2804 0.2590 0.089 Uiso 1 1 calc R . .
C3D C 0.7560(12) 0.2717(3) 0.1543(6) 0.091(3) Uani 1 1 d . . .
H3D H 0.8319 0.2729 0.1308 0.109 Uiso 1 1 calc R . .
C4D C 0.6367(13) 0.2658(3) 0.1124(5) 0.091(3) Uani 1 1 d . . .
H4D H 0.6312 0.2632 0.0605 0.110 Uiso 1 1 calc R . .
C5D C 0.5240(11) 0.2635(4) 0.1462(5) 0.101(4) Uani 1 1 d . . .
H5D H 0.4420 0.2589 0.1177 0.121 Uiso 1 1 calc R . .
C6D C 0.5343(9) 0.2683(3) 0.2231(4) 0.072(2) Uani 1 1 d . . .
H6D H 0.4574 0.2678 0.2459 0.086 Uiso 1 1 calc R . .
C1E C 0.3698(6) 0.3737(2) 0.5753(3) 0.0432(15) Uani 1 1 d . . .
C2E C 0.4205(8) 0.4128(3) 0.6033(4) 0.067(2) Uani 1 1 d . . .
H2E H 0.4384 0.4343 0.5703 0.080 Uiso 1 1 calc R . .
C3E C 0.4443(11) 0.4198(3) 0.6798(5) 0.091(3) Uani 1 1 d . . .
H3E H 0.4765 0.4461 0.6980 0.110 Uiso 1 1 calc R . .
C4E C 0.4208(10) 0.3881(3) 0.7293(5) 0.081(3) Uani 1 1 d . . .
H4E H 0.4380 0.3929 0.7807 0.098 Uiso 1 1 calc R . .
C5E C 0.3731(9) 0.3503(3) 0.7035(4) 0.074(2) Uani 1 1 d . . .
H5E H 0.3581 0.3288 0.7372 0.089 Uiso 1 1 calc R . .
C6E C 0.3461(7) 0.3428(3) 0.6271(4) 0.059(2) Uani 1 1 d . . .
H6E H 0.3114 0.3166 0.6101 0.070 Uiso 1 1 calc R . .
C1F C 0.2924(7) 0.4149(2) 0.4361(4) 0.0464(16) Uani 1 1 d . . .
C2F C 0.1692(8) 0.4298(3) 0.4448(6) 0.078(3) Uani 1 1 d . . .
H2F H 0.1139 0.4137 0.4710 0.093 Uiso 1 1 calc R . .
C3F C 0.1263(12) 0.4692(4) 0.4143(8) 0.117(5) Uani 1 1 d . . .
H3F H 0.0407 0.4786 0.4180 0.141 Uiso 1 1 calc R . .
C4F C 0.2083(18) 0.4935(4) 0.3798(7) 0.122(5) Uani 1 1 d . . .
H4F H 0.1804 0.5202 0.3613 0.146 Uiso 1 1 calc R . .
C5F C 0.3321(16) 0.4793(3) 0.3718(6) 0.120(4) Uani 1 1 d . . .
H5F H 0.3883 0.4962 0.3474 0.144 Uiso 1 1 calc R . .
C6F C 0.3739(9) 0.4399(2) 0.3997(5) 0.070(2) Uani 1 1 d . . .
H6F H 0.4583 0.4302 0.3938 0.083 Uiso 1 1 calc R . .
C1G C 0.2350(7) 0.2393(2) 0.3908(4) 0.0566(19) Uani 1 1 d . . .
C2G C 0.1038(8) 0.2272(3) 0.3889(5) 0.066(2) Uani 1 1 d . . .
H2G H 0.0377 0.2479 0.3827 0.080 Uiso 1 1 calc R . .
C3G C 0.0698(10) 0.1856(3) 0.3960(5) 0.084(3) Uani 1 1 d . . .
H3G H -0.0189 0.1780 0.3939 0.101 Uiso 1 1 calc R . .
C4G C 0.1667(12) 0.1545(3) 0.4062(6) 0.096(3) Uani 1 1 d . . .
H4G H 0.1434 0.1261 0.4123 0.115 Uiso 1 1 calc R . .
C5G C 0.2951(12) 0.1653(3) 0.4072(7) 0.103(3) Uani 1 1 d . . .
H5G H 0.3598 0.1441 0.4129 0.124 Uiso 1 1 calc R . .
C6G C 0.3322(9) 0.2084(3) 0.3998(6) 0.083(3) Uani 1 1 d . . .
H6G H 0.4209 0.2158 0.4011 0.099 Uiso 1 1 calc R . .
C1H C 0.1874(7) 0.3117(2) 0.2937(4) 0.0535(18) Uani 1 1 d . . .
C2H C 0.1342(9) 0.3523(3) 0.2844(5) 0.080(3) Uani 1 1 d . . .
H2H H 0.1421 0.3710 0.3250 0.096 Uiso 1 1 calc R . .
C3H C 0.0692(12) 0.3659(4) 0.2151(6) 0.111(4) Uani 1 1 d . . .
H3H H 0.0334 0.3932 0.2098 0.134 Uiso 1 1 calc R . .
C4H C 0.0583(13) 0.3392(5) 0.1559(6) 0.113(4) Uani 1 1 d . . .
H4H H 0.0140 0.3482 0.1099 0.135 Uiso 1 1 calc R . .
C5H C 0.1097(11) 0.3005(4) 0.1622(5) 0.096(4) Uani 1 1 d . . .
H5H H 0.1036 0.2831 0.1199 0.115 Uiso 1 1 calc R . .
C6H C 0.1740(9) 0.2848(3) 0.2316(5) 0.076(3) Uani 1 1 d . . .
H6H H 0.2066 0.2570 0.2355 0.091 Uiso 1 1 calc R . .
O1S O 1.024(4) 0.4910(10) 0.170(2) 0.263(15) Uani 0.50 1 d PDU . .
C1S C 0.904(4) 0.4940(12) 0.124(2) 0.236(19) Uani 0.50 1 d PDU . .
H1S1 H 0.8312 0.4959 0.1534 0.283 Uiso 0.50 1 calc PR . .
H1S2 H 0.8907 0.4694 0.0911 0.283 Uiso 0.50 1 calc PR . .
C2S C 0.916(4) 0.5352(12) 0.078(2) 0.27(2) Uani 0.50 1 d PDU . .
H2S1 H 0.8400 0.5537 0.0812 0.329 Uiso 0.50 1 calc PR . .
H2S2 H 0.9212 0.5287 0.0261 0.329 Uiso 0.50 1 calc PR . .
C3S C 1.050(4) 0.5571(10) 0.118(2) 0.243(19) Uani 0.50 1 d PDU . .
H3S1 H 1.1178 0.5570 0.0845 0.291 Uiso 0.50 1 calc PR . .
H3S2 H 1.0347 0.5863 0.1326 0.291 Uiso 0.50 1 calc PR . .
C4S C 1.091(4) 0.5290(13) 0.186(2) 0.26(2) Uani 0.50 1 d PDU . .
H4S1 H 1.1857 0.5244 0.1938 0.307 Uiso 0.50 1 calc PR . .
H4S2 H 1.0647 0.5420 0.2311 0.307 Uiso 0.50 1 calc PR . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru -1.2594 0.8363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Pt1 N1 180.0(3) 3_665 . ?
N1 Pt1 Cl1 89.58(18) 3_665 . ?
N1 Pt1 Cl1 90.42(18) . . ?
N1 Pt1 Cl1 90.42(18) 3_665 3_665 ?
N1 Pt1 Cl1 89.58(18) . 3_665 ?
Cl1 Pt1 Cl1 180.00(10) . 3_665 ?
C1 Ru1 P1 88.59(18) . . ?
C1 Ru1 P3 95.46(18) . . ?
P1 Ru1 P3 105.73(6) . . ?
C1 Ru1 P2 87.15(18) . . ?
P1 Ru1 P2 72.26(6) . . ?
P3 Ru1 P2 176.70(6) . . ?
C1 Ru1 P4 89.32(17) . . ?
P1 Ru1 P4 176.54(6) . . ?
P3 Ru1 P4 71.73(6) . . ?
P2 Ru1 P4 110.39(6) . . ?
C1 Ru1 Cl2 173.71(18) . . ?
P1 Ru1 Cl2 97.32(7) . . ?
P3 Ru1 Cl2 85.03(6) . . ?
P2 Ru1 Cl2 92.59(6) . . ?
P4 Ru1 Cl2 84.87(7) . . ?
C1B P1 C1A 103.0(4) . . ?
C1B P1 C8 106.6(3) . . ?
C1A P1 C8 105.4(3) . . ?
C1B P1 Ru1 118.3(2) . . ?
C1A P1 Ru1 124.9(3) . . ?
C8 P1 Ru1 96.4(2) . . ?
C1D P2 C1C 103.0(3) . . ?
C1D P2 C8 107.8(3) . . ?
C1C P2 C8 104.1(3) . . ?
C1D P2 Ru1 120.8(2) . . ?
C1C P2 Ru1 123.3(2) . . ?
C8 P2 Ru1 95.4(2) . . ?
C1E P3 C1F 101.9(3) . . ?
C1E P3 C9 106.4(3) . . ?
C1F P3 C9 106.9(3) . . ?
C1E P3 Ru1 123.3(2) . . ?
C1F P3 Ru1 122.3(2) . . ?
C9 P3 Ru1 93.6(2) . . ?
C1G P4 C1H 103.5(3) . . ?
C1G P4 C9 107.1(3) . . ?
C1H P4 C9 104.7(3) . . ?
C1G P4 Ru1 124.1(3) . . ?
C1H P4 Ru1 120.9(2) . . ?
C9 P4 Ru1 93.6(2) . . ?
C7 N1 C3 117.3(6) . . ?
C7 N1 Pt1 120.8(5) . . ?
C3 N1 Pt1 121.8(5) . . ?
C2 C1 Ru1 177.3(6) . . ?
C1 C2 C5 173.3(8) . . ?
N1 C3 C4 122.6(7) . . ?
C3 C4 C5 121.3(7) . . ?
C4 C5 C6 114.2(6) . . ?
C4 C5 C2 123.6(7) . . ?
C6 C5 C2 122.1(7) . . ?
C7 C6 C5 121.2(7) . . ?
N1 C7 C6 123.2(7) . . ?
P1 C8 P2 96.0(3) . . ?
P4 C9 P3 96.7(3) . . ?
C2A C1A C6A 118.3(7) . . ?
C2A C1A P1 122.3(6) . . ?
C6A C1A P1 119.4(6) . . ?
C1A C2A C3A 120.7(10) . . ?
C4A C3A C2A 120.8(11) . . ?
C5A C4A C3A 120.2(10) . . ?
C4A C5A C6A 120.4(10) . . ?
C1A C6A C5A 119.7(9) . . ?
C2B C1B C6B 118.7(8) . . ?
C2B C1B P1 119.9(7) . . ?
C6B C1B P1 120.8(6) . . ?
C1B C2B C3B 121.8(11) . . ?
C4B C3B C2B 118.8(12) . . ?
C3B C4B C5B 122.7(11) . . ?
C4B C5B C6B 117.1(11) . . ?
C1B C6B C5B 120.9(9) . . ?
C2C C1C C6C 118.3(6) . . ?
C2C C1C P2 121.6(5) . . ?
C6C C1C P2 120.1(5) . . ?
C1C C2C C3C 121.5(7) . . ?
C2C C3C C4C 119.0(8) . . ?
C5C C4C C3C 120.1(8) . . ?
C4C C5C C6C 119.7(8) . . ?
C5C C6C C1C 121.4(7) . . ?
C6D C1D C2D 117.3(7) . . ?
C6D C1D P2 117.8(5) . . ?
C2D C1D P2 124.9(6) . . ?
C3D C2D C1D 120.1(9) . . ?
C4D C3D C2D 121.3(9) . . ?
C3D C4D C5D 120.2(8) . . ?
C4D C5D C6D 118.9(9) . . ?
C5D C6D C1D 122.2(8) . . ?
C6E C1E C2E 117.4(6) . . ?
C6E C1E P3 122.6(5) . . ?
C2E C1E P3 119.8(5) . . ?
C3E C2E C1E 120.3(7) . . ?
C4E C3E C2E 120.5(8) . . ?
C5E C4E C3E 120.1(8) . . ?
C4E C5E C6E 120.4(8) . . ?
C5E C6E C1E 121.3(7) . . ?
C2F C1F C6F 118.9(7) . . ?
C2F C1F P3 121.4(6) . . ?
C6F C1F P3 119.7(5) . . ?
C1F C2F C3F 120.1(10) . . ?
C4F C3F C2F 120.0(11) . . ?
C3F C4F C5F 120.5(11) . . ?
C4F C5F C6F 119.9(12) . . ?
C1F C6F C5F 120.5(9) . . ?
C6G C1G C2G 119.0(7) . . ?
C6G C1G P4 118.8(6) . . ?
C2G C1G P4 122.2(6) . . ?
C3G C2G C1G 121.1(9) . . ?
C2G C3G C4G 120.1(9) . . ?
C5G C4G C3G 120.1(9) . . ?
C4G C5G C6G 120.6(10) . . ?
C1G C6G C5G 119.1(8) . . ?
C2H C1H C6H 117.7(8) . . ?
C2H C1H P4 121.8(6) . . ?
C6H C1H P4 120.3(7) . . ?
C1H C2H C3H 121.2(9) . . ?
C4H C3H C2H 119.7(11) . . ?
C5H C4H C3H 120.8(11) . . ?
C4H C5H C6H 121.7(9) . . ?
C1H C6H C5H 118.7(9) . . ?
C4S O1S C1S 116(2) . . ?
O1S C1S C2S 104.7(13) . . ?
C1S C2S C3S 104.0(11) . . ?
C4S C3S C2S 103.4(12) . . ?
O1S C4S C3S 105.0(14) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 N1 2.020(5) 3_665 ?
Pt1 N1 2.020(5) . ?
Pt1 Cl1 2.282(2) . ?
Pt1 Cl1 2.282(2) 3_665 ?
Ru1 C1 1.970(6) . ?
Ru1 P1 2.3269(18) . ?
Ru1 P3 2.3465(17) . ?
Ru1 P2 2.3516(17) . ?
Ru1 P4 2.3538(18) . ?
Ru1 Cl2 2.4560(17) . ?
P1 C1B 1.821(7) . ?
P1 C1A 1.828(7) . ?
P1 C8 1.854(7) . ?
P2 C1D 1.801(7) . ?
P2 C1C 1.831(6) . ?
P2 C8 1.859(6) . ?
P3 C1E 1.816(6) . ?
P3 C1F 1.827(7) . ?
P3 C9 1.846(6) . ?
P4 C1G 1.818(7) . ?
P4 C1H 1.822(8) . ?
P4 C9 1.840(6) . ?
N1 C7 1.321(9) . ?
N1 C3 1.328(9) . ?
C1 C2 1.217(8) . ?
C2 C5 1.399(9) . ?
C3 C4 1.376(9) . ?
C4 C5 1.389(10) . ?
C5 C6 1.396(10) . ?
C6 C7 1.366(10) . ?
C1A C2A 1.368(11) . ?
C1A C6A 1.386(10) . ?
C2A C3A 1.369(13) . ?
C3A C4A 1.346(16) . ?
C4A C5A 1.343(15) . ?
C5A C6A 1.389(12) . ?
C1B C2B 1.363(11) . ?
C1B C6B 1.385(11) . ?
C2B C3B 1.367(14) . ?
C3B C4B 1.351(18) . ?
C4B C5B 1.381(17) . ?
C5B C6B 1.394(12) . ?
C1C C2C 1.365(9) . ?
C1C C6C 1.380(9) . ?
C2C C3C 1.380(10) . ?
C3C C4C 1.391(12) . ?
C4C C5C 1.359(12) . ?
C5C C6C 1.378(10) . ?
C1D C6D 1.382(10) . ?
C1D C2D 1.390(10) . ?
C2D C3D 1.377(12) . ?
C3D C4D 1.353(13) . ?
C4D C5D 1.369(14) . ?
C5D C6D 1.380(11) . ?
C1E C6E 1.385(10) . ?
C1E C2E 1.394(9) . ?
C2E C3E 1.380(11) . ?
C3E C4E 1.373(12) . ?
C4E C5E 1.339(12) . ?
C5E C6E 1.383(10) . ?
C1F C2F 1.365(10) . ?
C1F C6F 1.369(10) . ?
C2F C3F 1.393(14) . ?
C3F C4F 1.340(18) . ?
C4F C5F 1.361(18) . ?
C5F C6F 1.377(12) . ?
C1G C6G 1.378(11) . ?
C1G C2G 1.385(10) . ?
C2G C3G 1.358(11) . ?
C3G C4G 1.379(13) . ?
C4G C5G 1.346(14) . ?
C5G C6G 1.412(11) . ?
C1H C2H 1.384(11) . ?
C1H C6H 1.389(10) . ?
C2H C3H 1.395(12) . ?
C3H C4H 1.343(15) . ?
C4H C5H 1.318(15) . ?
C5H C6H 1.416(13) . ?
O1S C4S 1.377(18) . ?
O1S C1S 1.384(18) . ?
C1S C2S 1.541(17) . ?
C2S C3S 1.608(18) . ?
C3S C4S 1.522(18) . ?
