#------------------------------------------------------------------------------
#$Date: 2016-03-25 10:09:59 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179742 $
#$URL: svn://www.crystallography.net/cod/cif/7/00/38/7003835.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7003835
loop_
_publ_author_name
'Al-Ktaifani, Mahmoud M.'
'Hitchcock, Peter B.'
'Lappert, Michael F.'
'Nixon, John F.'
'Uiterweerd, Philip'
_publ_section_title
;
 Specific insertion reactions of a germylene, stannylene and plumbylene
 into the unique P--P bond of the hexaphospha-pentaprismane cage,
 P6C4tBu4: Crystal and molecular structures of P6C4tBu4ER2 (E = Ge, Sn,
 R = N(SiMe3)2; E = Pb, R = (C6H3(NMe2)2 -2,6)
;
_journal_issue                   21
_journal_name_full               'Dalton Transactions'
_journal_page_first              2825
_journal_page_last               2831
_journal_paper_doi               10.1039/b800458g
_journal_year                    2008
_chemical_compound_source        'synthesis as described'
_chemical_formula_moiety         'C40 H66 N4 P6 Pb1'
_chemical_formula_structural     'C40 H66 N4 P6 PB'
_chemical_formula_sum            'C40 H66 N4 P6 Pb'
_chemical_formula_weight         995.98
_chemical_name_common            '[Pb{P6(CtBu)4}{C6H3(NMe2)2}2]'
_chemical_name_systematic
;
?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_conform_dict_location     ftp://ftp.iucr.org/cifdics/cif_core.dic
_audit_conform_dict_name         cif_core.dic
_audit_conform_dict_version      2.1
_audit_creation_date             2001-03-05T10:44:55-00:00
_audit_creation_method           'WinGX routine CIF_UPDATE'
_cell_angle_alpha                90
_cell_angle_beta                 112.074(2)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   11.2177(3)
_cell_length_b                   33.3392(11)
_cell_length_c                   13.1175(4)
_cell_measurement_reflns_used    33423
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      27.878
_cell_measurement_theta_min      3.705
_cell_measurement_wavelength     0.71073
_cell_volume                     4546.2(2)
_computing_cell_refinement       'HKL Scalepack (Otwinowski & Minor 1997)'
_computing_data_reduction
'HKL Denzo and Scalepack (Otwinowski & Minor 1997)'
_computing_molecular_graphics    'Ortep-3 for Windows (Farrugia, 1997)'
_computing_publication_material  'WinGX publication routines (Farrugia, 1999)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldri8ck, 1997)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.972
_diffrn_measured_fraction_theta_max 0.972
_diffrn_measurement_device       KappaCCD
_diffrn_measurement_method       CCD
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0697
_diffrn_reflns_av_unetI/netI     0.0844
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       29
_diffrn_reflns_limit_k_min       -43
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            23962
_diffrn_reflns_theta_full        27.88
_diffrn_reflns_theta_max         27.88
_diffrn_reflns_theta_min         3.82
_exptl_absorpt_coefficient_mu    3.954
_exptl_absorpt_correction_T_max  0.558
_exptl_absorpt_correction_T_min  0.455
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
[c.f. r.h. blessing, acta cryst. (1995), a51, 33-38]
;
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.455
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             2024
_exptl_crystal_size_max          0.2
_exptl_crystal_size_mid          0.2
_exptl_crystal_size_min          0.1
_refine_diff_density_max         1.344
_refine_diff_density_min         -1.844
_refine_diff_density_rms         0.158
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.024
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     460
_refine_ls_number_reflns         10524
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.024
_refine_ls_R_factor_all          0.075
_refine_ls_R_factor_gt           0.0461
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0419P)²+0.6017P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.093
_refine_ls_wR_factor_ref         0.1034
_reflns_number_gt                7750
_reflns_number_total             10524
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b800458g.txt
_cod_data_source_block           mar401
_cod_original_sg_symbol_H-M      P2(1)/n
_cod_database_code               7003835
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pb Pb 0.257109(18) 0.104479(6) 0.700176(15) 0.01999(7) Uani 1 1 d . . .
P1 P 0.08931(14) 0.20057(5) 0.38639(11) 0.0288(3) Uani 1 1 d . . .
P2 P 0.35732(13) 0.15809(4) 0.51637(11) 0.0239(3) Uani 1 1 d . . .
P3 P 0.26162(13) 0.17711(4) 0.62429(11) 0.0237(3) Uani 1 1 d . . .
P4 P 0.19036(15) 0.13749(4) 0.31060(11) 0.0268(3) Uani 1 1 d . . .
P5 P 0.01601(13) 0.12986(5) 0.45138(11) 0.0269(3) Uani 1 1 d . . .
P6 P 0.16195(13) 0.08377(4) 0.49118(11) 0.0228(3) Uani 1 1 d . . .
N1 N 0.3253(4) 0.01411(13) 0.7696(3) 0.0238(10) Uani 1 1 d . . .
N2 N 0.5598(4) 0.13838(14) 0.7866(4) 0.0298(11) Uani 1 1 d . . .
N3 N 0.3188(5) 0.12514(15) 0.9575(4) 0.0322(11) Uani 1 1 d . . .
N4 N -0.0317(4) 0.06559(16) 0.6486(4) 0.0339(12) Uani 1 1 d . . .
C1 C 0.2529(5) 0.18586(16) 0.3893(4) 0.0285(12) Uani 1 1 d . . .
C2 C 0.0938(5) 0.17983(17) 0.5220(4) 0.0281(12) Uani 1 1 d . . .
C3 C 0.0329(5) 0.14897(17) 0.3234(4) 0.0275(12) Uani 1 1 d . . .
C4 C 0.2784(5) 0.10932(15) 0.4413(4) 0.0219(11) Uani 1 1 d . . .
C5 C 0.3196(6) 0.21898(17) 0.3469(5) 0.0346(14) Uani 1 1 d . . .
C6 C 0.3514(6) 0.25413(17) 0.4291(5) 0.0397(15) Uani 1 1 d . . .
H6A H 0.2722 0.2636 0.4363 0.06 Uiso 1 1 calc R . .
H6B H 0.3901 0.276 0.4024 0.06 Uiso 1 1 calc R . .
H6C H 0.412 0.2451 0.501 0.06 Uiso 1 1 calc R . .
C7 C 0.2291(6) 0.23373(18) 0.2330(5) 0.0409(15) Uani 1 1 d . . .
H7A H 0.1487 0.2434 0.2374 0.061 Uiso 1 1 calc R . .
H7B H 0.2105 0.2116 0.1801 0.061 Uiso 1 1 calc R . .
H7C H 0.2705 0.2556 0.2087 0.061 Uiso 1 1 calc R . .
C8 C 0.4439(6) 0.20404(19) 0.3380(5) 0.0430(16) Uani 1 1 d . . .
H8A H 0.4832 0.2258 0.3112 0.064 Uiso 1 1 calc R . .
H8B H 0.4247 0.1814 0.2866 0.064 Uiso 1 1 calc R . .
H8C H 0.5035 0.1953 0.4106 0.064 Uiso 1 1 calc R . .
C9 C 0.0054(6) 0.20430(18) 0.5698(5) 0.0349(14) Uani 1 1 d . . .
C10 C -0.1337(6) 0.2075(2) 0.4863(5) 0.0510(19) Uani 1 1 d . . .
H10A H -0.1346 0.2215 0.4203 0.077 Uiso 1 1 calc R . .
H10B H -0.1854 0.2226 0.5191 0.077 Uiso 1 1 calc R . .
H10C H -0.1698 0.1806 0.4663 0.077 Uiso 1 1 calc R . .
C11 C 0.0605(7) 0.24648(19) 0.6017(5) 0.0486(18) Uani 1 1 d . . .
H11A H 0.0623 0.2604 0.5364 0.073 Uiso 1 1 calc R . .
H11B H 0.1481 0.2446 0.657 0.073 Uiso 1 1 calc R . .
H11C H 0.0065 0.2615 0.6322 0.073 Uiso 1 1 calc R . .
C12 C 0.0025(6) 0.18242(19) 0.6724(5) 0.0425(16) Uani 1 1 d . . .
H12A H 0.0904 0.1799 0.727 0.064 Uiso 1 1 calc R . .
H12B H -0.0347 0.1556 0.6515 0.064 Uiso 1 1 calc R . .
H12C H -0.0499 0.1978 0.7039 0.064 Uiso 1 1 calc R . .
C13 C -0.0850(6) 0.14324(19) 0.2150(5) 0.0380(15) Uani 1 1 d . . .
C14 C -0.0657(7) 0.1654(2) 0.1189(5) 0.0518(18) Uani 1 1 d . . .
H14A H 0.0118 0.1552 0.1101 0.078 Uiso 1 1 calc R . .
H14B H -0.056 0.1942 0.1347 0.078 Uiso 1 1 calc R . .
H14C H -0.1405 0.1608 0.0509 0.078 Uiso 1 1 calc R . .
C15 C -0.1023(7) 0.0985(2) 0.1881(5) 0.0530(19) Uani 1 1 d . . .
H15A H -0.0243 0.0879 0.1812 0.08 Uiso 1 1 calc R . .
H15B H -0.1757 0.0947 0.1187 0.08 Uiso 1 1 calc R . .
H15C H -0.1182 0.0844 0.2472 0.08 Uiso 1 1 calc R . .
C16 C -0.2070(6) 0.1600(3) 0.2252(6) 0.065(2) Uani 1 1 d . . .
H16A H -0.2801 0.1562 0.1555 0.097 Uiso 1 1 calc R . .
H16B H -0.1955 0.1886 0.2428 0.097 Uiso 1 1 calc R . .
H16C H -0.2236 0.1458 0.284 0.097 Uiso 1 1 calc R . .
C17 C 0.3788(5) 0.07849(17) 0.4279(4) 0.0275(12) Uani 1 1 d . . .
C18 C 0.3091(6) 0.04507(18) 0.3475(5) 0.0405(15) Uani 1 1 d . . .
H18A H 0.2576 0.0568 0.276 0.061 Uiso 1 1 calc R . .
H18B H 0.2527 0.0304 0.3762 0.061 Uiso 1 1 calc R . .
H18C H 0.3726 0.0266 0.3388 0.061 Uiso 1 1 calc R . .
C19 C 0.4729(6) 0.09959(18) 0.3843(5) 0.0412(16) Uani 1 1 d . . .
H19A H 0.4244 0.1118 0.3126 0.062 Uiso 1 1 calc R . .
H19B H 0.5337 0.0799 0.3763 0.062 Uiso 1 1 calc R . .
H19C H 0.5204 0.1205 0.4363 0.062 Uiso 1 1 calc R . .
C20 C 0.4586(5) 0.06006(18) 0.5383(4) 0.0355(14) Uani 1 1 d . . .
H20A H 0.5034 0.0813 0.59 0.053 Uiso 1 1 calc R . .
H20B H 0.5218 0.0416 0.5292 0.053 Uiso 1 1 calc R . .
H20C H 0.4022 0.0454 0.5669 0.053 Uiso 1 1 calc R . .
C21 C 0.4477(5) 0.07605(15) 0.7881(4) 0.0194(11) Uani 1 1 d . . .
C22 C 0.5646(5) 0.09684(16) 0.8153(4) 0.0235(11) Uani 1 1 d . . .
C23 C 0.6789(5) 0.07594(19) 0.8624(4) 0.0311(13) Uani 1 1 d . . .
H23 H 0.7585 0.0898 0.883 0.037 Uiso 1 1 calc R . .
C24 C 0.6781(5) 0.03509(19) 0.8795(4) 0.0336(14) Uani 1 1 d . . .
H24 H 0.7574 0.0211 0.9117 0.04 Uiso 1 1 calc R . .
C25 C 0.5641(5) 0.01422(18) 0.8507(4) 0.0309(13) Uani 1 1 d . . .
H25 H 0.5644 -0.014 0.8616 0.037 Uiso 1 1 calc R . .
C26 C 0.4481(5) 0.03505(16) 0.8054(4) 0.0225(11) Uani 1 1 d . . .
C27 C 0.3192(6) -0.02019(18) 0.6972(5) 0.0372(14) Uani 1 1 d . . .
H27A H 0.2347 -0.033 0.6754 0.056 Uiso 1 1 calc R . .
H27B H 0.3863 -0.0396 0.7366 0.056 Uiso 1 1 calc R . .
H27C H 0.3326 -0.0108 0.6315 0.056 Uiso 1 1 calc R . .
C28 C 0.2959(5) 0.00080(17) 0.8640(4) 0.0315(13) Uani 1 1 d . . .
H28A H 0.2128 -0.0131 0.8378 0.047 Uiso 1 1 calc R . .
H28B H 0.2919 0.0241 0.9081 0.047 Uiso 1 1 calc R . .
H28C H 0.3633 -0.0175 0.9093 0.047 Uiso 1 1 calc R . .
C29 C 0.5398(5) 0.16540(18) 0.8659(5) 0.0343(14) Uani 1 1 d . . .
H29A H 0.5375 0.1931 0.8405 0.051 Uiso 1 1 calc R . .
H29B H 0.6105 0.1623 0.9374 0.051 Uiso 1 1 calc R . .
H29C H 0.4581 0.1589 0.8731 0.051 Uiso 1 1 calc R . .
C30 C 0.6677(6) 0.15214(19) 0.7580(5) 0.0439(16) Uani 1 1 d . . .
H30A H 0.6572 0.1807 0.7395 0.066 Uiso 1 1 calc R . .
H30B H 0.6691 0.1369 0.6946 0.066 Uiso 1 1 calc R . .
H30C H 0.7487 0.148 0.8207 0.066 Uiso 1 1 calc R . .
C31 C 0.1456(5) 0.09198(16) 0.8071(4) 0.0248(12) Uani 1 1 d . . .
C32 C 0.2027(5) 0.10088(17) 0.9182(4) 0.0282(12) Uani 1 1 d . . .
C33 C 0.1450(6) 0.0873(2) 0.9900(5) 0.0418(16) Uani 1 1 d . . .
H33 H 0.1831 0.0932 1.0664 0.05 Uiso 1 1 calc R . .
C34 C 0.0324(6) 0.0654(2) 0.9487(5) 0.053(2) Uani 1 1 d . . .
H34 H -0.0053 0.0554 0.9975 0.064 Uiso 1 1 calc R . .
C35 C -0.0262(6) 0.0579(2) 0.8372(5) 0.0461(18) Uani 1 1 d . . .
H35 H -0.1049 0.0434 0.8093 0.055 Uiso 1 1 calc R . .
C36 C 0.0303(5) 0.07154(18) 0.7664(4) 0.0294(13) Uani 1 1 d . . .
C37 C 0.2935(7) 0.1646(2) 0.9901(6) 0.060(2) Uani 1 1 d . . .
H37A H 0.3731 0.1803 1.0154 0.091 Uiso 1 1 calc R . .
H37B H 0.2616 0.1622 1.0498 0.091 Uiso 1 1 calc R . .
H37C H 0.2287 0.178 0.9271 0.091 Uiso 1 1 calc R . .
C38 C 0.4262(6) 0.1051(2) 1.0454(5) 0.0482(18) Uani 1 1 d . . .
H38A H 0.5019 0.1226 1.069 0.072 Uiso 1 1 calc R . .
H38B H 0.4467 0.0799 1.0175 0.072 Uiso 1 1 calc R . .
H38C H 0.4013 0.0996 1.1081 0.072 Uiso 1 1 calc R . .
C39 C -0.0114(6) 0.0247(2) 0.6175(5) 0.0477(18) Uani 1 1 d . . .
H39A H -0.054 0.0216 0.5377 0.072 Uiso 1 1 calc R . .
H39B H -0.0476 0.0055 0.6546 0.072 Uiso 1 1 calc R . .
H39C H 0.081 0.0198 0.6395 0.072 Uiso 1 1 calc R . .
C40 C -0.1686(5) 0.0756(2) 0.6029(5) 0.0436(16) Uani 1 1 d . . .
H40A H -0.2031 0.0709 0.5234 0.065 Uiso 1 1 calc R . .
H40B H -0.1799 0.1039 0.6174 0.065 Uiso 1 1 calc R . .
H40C H -0.2146 0.0588 0.6374 0.065 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0 0 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pb Pb -3.3944 10.1111 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C21 Pb C31 104.48(18) . . ?
C21 Pb P3 115.97(13) . . ?
C31 Pb P3 120.23(14) . . ?
C21 Pb P6 111.28(12) . . ?
C31 Pb P6 119.96(14) . . ?
P3 Pb P6 84.55(4) . . ?
C1 P1 C2 101.8(2) . . ?
C1 P1 C3 86.4(2) . . ?
C2 P1 C3 88.0(2) . . ?
C1 P2 C4 87.1(2) . . ?
C1 P2 P3 97.95(17) . . ?
C4 P2 P3 109.53(15) . . ?
C2 P3 P2 99.13(16) . . ?
C2 P3 Pb 99.21(19) . . ?
P2 P3 Pb 93.59(6) . . ?
C4 P4 C3 102.1(2) . . ?
C4 P4 C1 88.2(2) . . ?
C3 P4 C1 86.9(2) . . ?
C3 P5 C2 87.5(2) . . ?
C3 P5 P6 97.82(18) . . ?
C2 P5 P6 109.29(17) . . ?
C4 P6 P5 99.04(17) . . ?
C4 P6 Pb 100.47(16) . . ?
P5 P6 Pb 92.23(6) . . ?
C26 N1 C28 111.0(4) . . ?
C26 N1 C27 113.0(4) . . ?
C28 N1 C27 109.8(4) . . ?
C22 N2 C29 114.3(4) . . ?
C22 N2 C30 114.6(5) . . ?
C29 N2 C30 110.6(5) . . ?
C32 N3 C37 111.3(5) . . ?
C32 N3 C38 112.6(5) . . ?
C37 N3 C38 111.9(5) . . ?
C36 N4 C40 114.5(4) . . ?
C36 N4 C39 111.2(5) . . ?
C40 N4 C39 110.4(5) . . ?
C5 C1 P2 116.4(4) . . ?
C5 C1 P1 113.9(4) . . ?
P2 C1 P1 115.0(3) . . ?
C5 C1 P4 122.6(4) . . ?
P2 C1 P4 92.5(2) . . ?
P1 C1 P4 93.0(2) . . ?
C9 C2 P3 110.7(4) . . ?
C9 C2 P1 112.6(4) . . ?
P3 C2 P1 111.0(3) . . ?
C9 C2 P5 113.2(4) . . ?
P3 C2 P5 116.9(3) . . ?
P1 C2 P5 91.0(2) . . ?
C13 C3 P5 116.3(4) . . ?
C13 C3 P4 113.6(4) . . ?
P5 C3 P4 115.3(3) . . ?
C13 C3 P1 122.6(4) . . ?
P5 C3 P1 92.7(2) . . ?
P4 C3 P1 93.0(2) . . ?
C17 C4 P6 111.2(3) . . ?
C17 C4 P4 112.1(3) . . ?
P6 C4 P4 110.5(3) . . ?
C17 C4 P2 113.2(4) . . ?
P6 C4 P2 116.8(2) . . ?
P4 C4 P2 91.6(2) . . ?
C8 C5 C7 108.6(4) . . ?
C8 C5 C6 108.9(5) . . ?
C7 C5 C6 109.4(5) . . ?
C8 C5 C1 111.9(5) . . ?
C7 C5 C1 110.2(5) . . ?
C6 C5 C1 107.8(4) . . ?
C12 C9 C10 107.9(5) . . ?
C12 C9 C11 109.6(5) . . ?
C10 C9 C11 109.2(5) . . ?
C12 C9 C2 108.9(4) . . ?
C10 C9 C2 111.9(5) . . ?
C11 C9 C2 109.5(5) . . ?
C15 C13 C16 109.6(6) . . ?
C15 C13 C3 108.9(5) . . ?
C16 C13 C3 110.9(5) . . ?
C15 C13 C14 108.9(5) . . ?
C16 C13 C14 107.6(5) . . ?
C3 C13 C14 111.0(5) . . ?
C20 C17 C18 109.2(5) . . ?
C20 C17 C19 107.3(5) . . ?
C18 C17 C19 108.6(4) . . ?
C20 C17 C4 110.3(4) . . ?
C18 C17 C4 110.4(4) . . ?
C19 C17 C4 111.0(4) . . ?
C26 C21 C22 120.0(5) . . ?
C26 C21 Pb 116.7(4) . . ?
C22 C21 Pb 123.0(4) . . ?
C23 C22 C21 119.0(5) . . ?
C23 C22 N2 122.8(5) . . ?
C21 C22 N2 118.1(5) . . ?
C24 C23 C22 120.5(5) . . ?
C25 C24 C23 121.0(5) . . ?
C24 C25 C26 119.1(5) . . ?
C21 C26 C25 120.4(5) . . ?
C21 C26 N1 118.4(4) . . ?
C25 C26 N1 121.1(5) . . ?
C36 C31 C32 120.5(5) . . ?
C36 C31 Pb 120.8(4) . . ?
C32 C31 Pb 118.2(4) . . ?
C31 C32 C33 119.3(5) . . ?
C31 C32 N3 119.4(5) . . ?
C33 C32 N3 121.3(5) . . ?
C34 C33 C32 119.4(5) . . ?
C33 C34 C35 120.8(6) . . ?
C36 C35 C34 119.6(6) . . ?
C35 C36 C31 120.2(5) . . ?
C35 C36 N4 120.8(5) . . ?
C31 C36 N4 118.9(5) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pb C21 2.224(5) . ?
Pb C31 2.241(5) . ?
Pb P3 2.6257(14) . ?
Pb P6 2.6330(13) . ?
P1 C1 1.886(5) . ?
P1 C2 1.891(5) . ?
P1 C3 1.910(6) . ?
P2 C1 1.881(6) . ?
P2 C4 1.935(5) . ?
P2 P3 2.1682(18) . ?
P3 C2 1.859(6) . ?
P4 C4 1.877(5) . ?
P4 C3 1.876(5) . ?
P4 C1 1.901(6) . ?
P5 C3 1.870(5) . ?
P5 C2 1.946(6) . ?
P5 P6 2.161(2) . ?
P6 C4 1.872(5) . ?
N1 C26 1.456(6) . ?
N1 C28 1.466(6) . ?
N1 C27 1.471(6) . ?
N2 C22 1.431(7) . ?
N2 C29 1.455(7) . ?
N2 C30 1.469(7) . ?
N3 C32 1.452(7) . ?
N3 C37 1.443(8) . ?
N3 C38 1.478(8) . ?
N4 C36 1.450(7) . ?
N4 C40 1.462(7) . ?
N4 C39 1.465(8) . ?
C1 C5 1.550(7) . ?
C2 C9 1.584(7) . ?
C3 C13 1.548(8) . ?
C4 C17 1.582(7) . ?
C5 C8 1.525(8) . ?
C5 C7 1.538(8) . ?
C5 C6 1.541(8) . ?
C9 C12 1.541(7) . ?
C9 C10 1.537(8) . ?
C9 C11 1.530(8) . ?
C13 C15 1.527(9) . ?
C13 C16 1.531(8) . ?
C13 C14 1.545(8) . ?
C17 C20 1.517(7) . ?
C17 C18 1.531(8) . ?
C17 C19 1.547(7) . ?
C21 C26 1.385(7) . ?
C21 C22 1.405(7) . ?
C22 C23 1.385(7) . ?
C23 C24 1.381(8) . ?
C24 C25 1.379(8) . ?
C25 C26 1.395(7) . ?
C31 C36 1.380(7) . ?
C31 C32 1.387(7) . ?
C32 C33 1.403(8) . ?
C33 C34 1.382(9) . ?
C34 C35 1.384(8) . ?
C35 C36 1.383(7) . ?
