#------------------------------------------------------------------------------
#$Date: 2016-03-25 10:09:59 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179742 $
#$URL: svn://www.crystallography.net/cod/cif/7/00/38/7003836.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7003836
loop_
_publ_author_name
'Al-Ktaifani, Mahmoud M.'
'Hitchcock, Peter B.'
'Lappert, Michael F.'
'Nixon, John F.'
'Uiterweerd, Philip'
_publ_section_title
;
 Specific insertion reactions of a germylene, stannylene and plumbylene
 into the unique P--P bond of the hexaphospha-pentaprismane cage,
 P6C4tBu4: Crystal and molecular structures of P6C4tBu4ER2 (E = Ge, Sn,
 R = N(SiMe3)2; E = Pb, R = (C6H3(NMe2)2 -2,6)
;
_journal_issue                   21
_journal_name_full               'Dalton Transactions'
_journal_page_first              2825
_journal_page_last               2831
_journal_paper_doi               10.1039/b800458g
_journal_year                    2008
_chemical_compound_source        'synthesis as described'
_chemical_formula_moiety         'C32 H72 N2 P6 Si4 Sn'
_chemical_formula_sum            'C32 H72 N2 P6 Si4 Sn'
_chemical_formula_weight         901.79
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_conform_dict_location     ftp://ftp.iucr.org/cifdics/cif_core.dic
_audit_conform_dict_name         cif_core.dic
_audit_conform_dict_version      2.1
_audit_creation_date             2000-09-13T16:25:32-00:00
_audit_creation_method           'WinGX routine CIF_UPDATE'
_cell_angle_alpha                114.191(7)
_cell_angle_beta                 93.524(5)
_cell_angle_gamma                94.335(9)
_cell_formula_units_Z            2
_cell_length_a                   11.9453(17)
_cell_length_b                   13.7446(14)
_cell_length_c                   15.126(2)
_cell_measurement_reflns_used    18767
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      22.986
_cell_measurement_theta_min      3.705
_cell_measurement_wavelength     0.71073
_cell_volume                     2247.2(5)
_computing_cell_refinement       'HKL Scalepack (Otwinowski & Minor 1997)'
_computing_data_reduction
'HKL Denzo and Scalepack (Otwinowski & Minor 1997)'
_computing_molecular_graphics    'Ortep-3 for Windows (Farrugia, 1997)'
_computing_publication_material  'WinGX publication routines (Farrugia, 1999)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.987
_diffrn_measured_fraction_theta_max 0.987
_diffrn_measurement_device       KappaCCD
_diffrn_measurement_method       CCD
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0956
_diffrn_reflns_av_unetI/netI     0.1342
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            13494
_diffrn_reflns_theta_full        23.02
_diffrn_reflns_theta_max         23.02
_diffrn_reflns_theta_min         3.76
_exptl_absorpt_coefficient_mu    0.913
_exptl_absorpt_correction_T_max  0.982
_exptl_absorpt_correction_T_min  0.711
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
[c.f. r.h. blessing, acta cryst. (1995), a51, 33-38]
;
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.333
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       'very fine needle'
_exptl_crystal_F_000             948
_exptl_crystal_size_max          0.4
_exptl_crystal_size_mid          0.05
_exptl_crystal_size_min          0.02
_refine_diff_density_max         0.657
_refine_diff_density_min         -1.019
_refine_diff_density_rms         0.114
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.022
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     419
_refine_ls_number_reflns         6186
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.022
_refine_ls_R_factor_all          0.1024
_refine_ls_R_factor_gt           0.0607
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0369P)²+0.9339P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1202
_refine_ls_wR_factor_ref         0.1356
_reflns_number_gt                4261
_reflns_number_total             6186
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b800458g.txt
_cod_data_source_block           sep1700
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7003836
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Sn Sn 0.71186(5) 0.78224(4) 0.71910(4) 0.02472(18) Uani 1 1 d . . .
P1 P 0.66272(18) 0.53905(15) 0.88417(14) 0.0254(5) Uani 1 1 d . . .
P2 P 0.82338(18) 0.57008(16) 0.73552(14) 0.0261(5) Uani 1 1 d . . .
P3 P 0.64921(18) 0.59523(15) 0.70765(14) 0.0255(5) Uani 1 1 d . . .
P4 P 0.88482(19) 0.62001(16) 0.92623(14) 0.0276(5) Uani 1 1 d . . .
P5 P 0.67868(19) 0.75525(15) 0.93855(14) 0.0263(5) Uani 1 1 d . . .
P6 P 0.82202(19) 0.81698(15) 0.88664(14) 0.0273(5) Uani 1 1 d . . .
Si1 Si 0.8516(2) 0.68176(18) 0.51540(15) 0.0313(6) Uani 1 1 d . . .
Si2 Si 0.8772(2) 0.92062(18) 0.64027(17) 0.0375(6) Uani 1 1 d . . .
Si3 Si 0.5499(2) 0.98578(17) 0.80190(16) 0.0326(6) Uani 1 1 d . . .
Si4 Si 0.4857(2) 0.81481(19) 0.59874(17) 0.0378(6) Uani 1 1 d . . .
N1 N 0.8198(6) 0.7904(4) 0.6193(4) 0.0260(16) Uani 1 1 d . . .
N2 N 0.5787(6) 0.8667(5) 0.7063(4) 0.0302(16) Uani 1 1 d . A .
C1 C 0.7949(7) 0.5069(6) 0.8215(5) 0.0266(19) Uani 1 1 d . . .
C2 C 0.6028(6) 0.6302(6) 0.8322(5) 0.0245(18) Uani 1 1 d . . .
C3 C 0.7510(7) 0.6638(6) 0.9811(5) 0.0278(19) Uani 1 1 d . . .
C4 C 0.8990(7) 0.6941(6) 0.8458(5) 0.0266(19) Uani 1 1 d . . .
C5 C 0.8127(7) 0.3864(6) 0.7861(5) 0.029(2) Uani 1 1 d . . .
C6 C 0.7175(7) 0.3186(6) 0.7073(5) 0.036(2) Uani 1 1 d . . .
H6A H 0.7173 0.3403 0.6532 0.054 Uiso 1 1 calc R . .
H6B H 0.6449 0.3293 0.7348 0.054 Uiso 1 1 calc R . .
H6C H 0.7293 0.2426 0.6835 0.054 Uiso 1 1 calc R . .
C7 C 0.8152(8) 0.3542(6) 0.8713(6) 0.038(2) Uani 1 1 d . . .
H7A H 0.8265 0.2781 0.848 0.058 Uiso 1 1 calc R . .
H7B H 0.7435 0.366 0.9002 0.058 Uiso 1 1 calc R . .
H7C H 0.8772 0.3977 0.9205 0.058 Uiso 1 1 calc R . .
C8 C 0.9252(7) 0.3633(6) 0.7420(6) 0.042(2) Uani 1 1 d . . .
H8A H 0.9263 0.3824 0.6863 0.062 Uiso 1 1 calc R . .
H8B H 0.9337 0.2868 0.7202 0.062 Uiso 1 1 calc R . .
H8C H 0.9875 0.4059 0.7912 0.062 Uiso 1 1 calc R . .
C9 C 0.4698(7) 0.6259(6) 0.8323(5) 0.030(2) Uani 1 1 d . . .
C10 C 0.4311(7) 0.6412(6) 0.9311(5) 0.032(2) Uani 1 1 d . . .
H10A H 0.4665 0.7101 0.9812 0.048 Uiso 1 1 calc R . .
H10B H 0.4532 0.5828 0.9474 0.048 Uiso 1 1 calc R . .
H10C H 0.3488 0.6405 0.9282 0.048 Uiso 1 1 calc R . .
C11 C 0.4135(7) 0.5183(6) 0.7570(6) 0.038(2) Uani 1 1 d . . .
H11A H 0.4383 0.4607 0.7732 0.056 Uiso 1 1 calc R . .
H11B H 0.4345 0.5078 0.6924 0.056 Uiso 1 1 calc R . .
H11C H 0.3313 0.5172 0.7571 0.056 Uiso 1 1 calc R . .
C12 C 0.4322(7) 0.7168(7) 0.8090(6) 0.044(2) Uani 1 1 d . . .
H12A H 0.4691 0.7855 0.8582 0.066 Uiso 1 1 calc R . .
H12B H 0.3501 0.7162 0.8093 0.066 Uiso 1 1 calc R . .
H12C H 0.4532 0.7072 0.7446 0.066 Uiso 1 1 calc R . .
C13 C 0.7557(7) 0.6892(6) 1.0914(5) 0.029(2) Uani 1 1 d . . .
C14 C 0.7953(8) 0.5939(6) 1.1079(6) 0.040(2) Uani 1 1 d . . .
H14A H 0.7985 0.6098 1.1774 0.06 Uiso 1 1 calc R . .
H14B H 0.8705 0.5812 1.0859 0.06 Uiso 1 1 calc R . .
H14C H 0.7422 0.5297 1.0709 0.06 Uiso 1 1 calc R . .
C15 C 0.8418(8) 0.7902(6) 1.1464(6) 0.043(2) Uani 1 1 d . . .
H15A H 0.8467 0.8084 1.2165 0.065 Uiso 1 1 calc R . .
H15B H 0.8169 0.8505 1.1345 0.065 Uiso 1 1 calc R . .
H15C H 0.9161 0.7755 1.1232 0.065 Uiso 1 1 calc R . .
C16 C 0.6416(8) 0.7098(7) 1.1302(6) 0.040(2) Uani 1 1 d . . .
H16A H 0.6486 0.7256 1.1997 0.06 Uiso 1 1 calc R . .
H16B H 0.5874 0.646 1.0949 0.06 Uiso 1 1 calc R . .
H16C H 0.615 0.771 1.1209 0.06 Uiso 1 1 calc R . .
C17 C 1.0281(7) 0.7239(6) 0.8403(6) 0.032(2) Uani 1 1 d . . .
C18 C 1.0880(7) 0.7922(6) 0.9429(6) 0.039(2) Uani 1 1 d . . .
H18A H 1.0799 0.7524 0.9836 0.059 Uiso 1 1 calc R . .
H18B H 1.054 0.8595 0.9722 0.059 Uiso 1 1 calc R . .
H18C H 1.1683 0.808 0.9384 0.059 Uiso 1 1 calc R . .
C19 C 1.0877(7) 0.6224(7) 0.7954(6) 0.044(2) Uani 1 1 d . . .
H19A H 1.0783 0.5799 0.8335 0.065 Uiso 1 1 calc R . .
H19B H 1.1682 0.6425 0.7957 0.065 Uiso 1 1 calc R . .
H19C H 1.0546 0.5797 0.7282 0.065 Uiso 1 1 calc R . .
C20 C 1.0430(7) 0.7895(6) 0.7807(6) 0.037(2) Uani 1 1 d . . .
H20A H 1.0053 0.8547 0.8093 0.055 Uiso 1 1 calc R . .
H20B H 1.0098 0.7467 0.7136 0.055 Uiso 1 1 calc R . .
H20C H 1.1236 0.8092 0.7809 0.055 Uiso 1 1 calc R . .
C21 C 0.7604(8) 0.5519(6) 0.4886(6) 0.048(3) Uani 1 1 d . . .
H21A H 0.6807 0.563 0.4835 0.071 Uiso 1 1 calc R . .
H21B H 0.7758 0.5293 0.5413 0.071 Uiso 1 1 calc R . .
H21C H 0.7778 0.4961 0.427 0.071 Uiso 1 1 calc R . .
C22 C 0.9979(8) 0.6455(7) 0.5224(6) 0.048(3) Uani 1 1 d . . .
H22A H 1.0112 0.6292 0.5792 0.073 Uiso 1 1 calc R . .
H22B H 1.0519 0.7059 0.5286 0.073 Uiso 1 1 calc R . .
H22C H 1.0076 0.5825 0.4631 0.073 Uiso 1 1 calc R . .
C23 C 0.8355(8) 0.7107(7) 0.4051(6) 0.047(3) Uani 1 1 d . . .
H23A H 0.7594 0.7301 0.3975 0.071 Uiso 1 1 calc R . .
H23B H 0.8475 0.6469 0.3473 0.071 Uiso 1 1 calc R . .
H23C H 0.8913 0.7704 0.4127 0.071 Uiso 1 1 calc R . .
C24 C 1.0252(8) 0.9253(7) 0.6094(7) 0.052(3) Uani 1 1 d . . .
H24A H 1.0282 0.8768 0.541 0.079 Uiso 1 1 calc R . .
H24B H 1.073 0.903 0.6511 0.079 Uiso 1 1 calc R . .
H24C H 1.0522 0.9987 0.6199 0.079 Uiso 1 1 calc R . .
C25 C 0.7942(9) 0.9800(7) 0.5684(7) 0.059(3) Uani 1 1 d . . .
H25A H 0.7897 0.9326 0.4989 0.088 Uiso 1 1 calc R . .
H25B H 0.8318 1.0506 0.5801 0.088 Uiso 1 1 calc R . .
H25C H 0.7179 0.9875 0.589 0.088 Uiso 1 1 calc R . .
C26 C 0.8815(8) 1.0152(6) 0.7705(6) 0.043(2) Uani 1 1 d . . .
H26A H 0.8052 1.0165 0.7911 0.065 Uiso 1 1 calc R . .
H26B H 0.9107 1.0874 0.7788 0.065 Uiso 1 1 calc R . .
H26C H 0.931 0.9917 0.8103 0.065 Uiso 1 1 calc R . .
C27 C 0.6279(8) 1.0109(6) 0.9199(5) 0.042(2) Uani 1 1 d . . .
H27A H 0.709 1.0119 0.9133 0.063 Uiso 1 1 calc R . .
H27B H 0.6034 0.9539 0.9398 0.063 Uiso 1 1 calc R . .
H27C H 0.6125 1.0803 0.9693 0.063 Uiso 1 1 calc R . .
C28 C 0.5877(8) 1.1056(6) 0.7764(6) 0.051(3) Uani 1 1 d . . .
H28A H 0.5473 1.0957 0.7144 0.076 Uiso 1 1 calc R . .
H28B H 0.6692 1.1141 0.7725 0.076 Uiso 1 1 calc R . .
H28C H 0.5664 1.1699 0.8289 0.076 Uiso 1 1 calc R . .
C29 C 0.3975(7) 0.9866(6) 0.8236(6) 0.039(2) Uani 1 1 d . . .
H29A H 0.3515 0.9736 0.763 0.058 Uiso 1 1 calc R . .
H29B H 0.3855 1.0565 0.874 0.058 Uiso 1 1 calc R . .
H29C H 0.3756 0.9301 0.8449 0.058 Uiso 1 1 calc R . .
C30 C 0.4486(14) 0.9254(11) 0.5647(10) 0.078(5) Uani 0.777(13) 1 d P A 1
H30A H 0.4173 0.9803 0.6194 0.118 Uiso 0.777(13) 1 calc PR A 1
H30B H 0.3924 0.8965 0.5077 0.118 Uiso 0.777(13) 1 calc PR A 1
H30C H 0.5165 0.9575 0.5494 0.118 Uiso 0.777(13) 1 calc PR A 1
C31 C 0.3425(10) 0.7520(11) 0.6079(9) 0.063(5) Uani 0.777(13) 1 d P A 1
H31A H 0.3068 0.8042 0.6611 0.095 Uiso 0.777(13) 1 calc PR A 1
H31B H 0.352 0.6886 0.6208 0.095 Uiso 0.777(13) 1 calc PR A 1
H31C H 0.2948 0.7306 0.5464 0.095 Uiso 0.777(13) 1 calc PR A 1
C32 C 0.5410(14) 0.7096(14) 0.5004(9) 0.106(8) Uani 0.777(13) 1 d P A 1
H32A H 0.5602 0.6535 0.521 0.158 Uiso 0.777(13) 1 calc PR A 1
H32B H 0.6089 0.7392 0.4827 0.158 Uiso 0.777(13) 1 calc PR A 1
H32C H 0.4841 0.6789 0.4439 0.158 Uiso 0.777(13) 1 calc PR A 1
C30A C 0.370(5) 0.884(4) 0.587(4) 0.072(16) Uiso 0.223(13) 1 d P A 2
H30D H 0.3938 0.961 0.6161 0.108 Uiso 0.223(13) 1 calc PR A 2
H30E H 0.3082 0.8676 0.6197 0.108 Uiso 0.223(13) 1 calc PR A 2
H30F H 0.3453 0.8602 0.5175 0.108 Uiso 0.223(13) 1 calc PR A 2
C31A C 0.446(4) 0.668(3) 0.550(3) 0.050(13) Uiso 0.223(13) 1 d P A 2
H31D H 0.5123 0.6325 0.5551 0.076 Uiso 0.223(13) 1 calc PR A 2
H31E H 0.4151 0.6409 0.4817 0.076 Uiso 0.223(13) 1 calc PR A 2
H31F H 0.3883 0.6531 0.5879 0.076 Uiso 0.223(13) 1 calc PR A 2
C32A C 0.567(3) 0.809(3) 0.486(3) 0.038(11) Uiso 0.223(13) 1 d P A 2
H32D H 0.636 0.7743 0.4852 0.057 Uiso 0.223(13) 1 calc PR A 2
H32E H 0.5878 0.8826 0.4926 0.057 Uiso 0.223(13) 1 calc PR A 2
H32F H 0.5186 0.7688 0.4254 0.057 Uiso 0.223(13) 1 calc PR A 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0 0 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sn Sn -0.6537 1.4246 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Sn N2 105.2(2) . . ?
N1 Sn P3 116.57(16) . . ?
N2 Sn P3 113.83(19) . . ?
N1 Sn P6 111.92(18) . . ?
N2 Sn P6 123.18(17) . . ?
P3 Sn P6 86.02(6) . . ?
C1 P1 C2 101.9(3) . . ?
C1 P1 C3 86.8(3) . . ?
C2 P1 C3 87.7(3) . . ?
C1 P2 C4 87.9(3) . . ?
C1 P2 P3 96.3(3) . . ?
C4 P2 P3 110.1(2) . . ?
C2 P3 P2 99.3(2) . . ?
C2 P3 Sn 100.5(2) . . ?
P2 P3 Sn 91.07(9) . . ?
C3 P4 C4 101.9(3) . . ?
C3 P4 C1 87.6(3) . . ?
C4 P4 C1 88.6(3) . . ?
C3 P5 C2 88.2(3) . . ?
C3 P5 P6 99.0(3) . . ?
C2 P5 P6 108.6(2) . . ?
C4 P6 P5 97.9(3) . . ?
C4 P6 Sn 98.8(2) . . ?
P5 P6 Sn 94.09(10) . . ?
N1 Si1 C22 114.7(4) . . ?
N1 Si1 C23 111.0(3) . . ?
C22 Si1 C23 105.8(4) . . ?
N1 Si1 C21 113.5(4) . . ?
C22 Si1 C21 103.4(4) . . ?
C23 Si1 C21 107.9(4) . . ?
N1 Si2 C26 111.8(3) . . ?
N1 Si2 C24 112.6(4) . . ?
C26 Si2 C24 105.7(4) . . ?
N1 Si2 C25 112.8(4) . . ?
C26 Si2 C25 106.5(4) . . ?
C24 Si2 C25 107.0(4) . . ?
N2 Si3 C27 113.1(3) . . ?
N2 Si3 C28 111.5(4) . . ?
C27 Si3 C28 106.9(4) . . ?
N2 Si3 C29 113.0(4) . . ?
C27 Si3 C29 105.7(4) . . ?
C28 Si3 C29 106.2(4) . . ?
N2 Si4 C30A 120.6(16) . . ?
N2 Si4 C32 112.2(5) . . ?
C30A Si4 C32 125.6(17) . . ?
N2 Si4 C31A 113.7(13) . . ?
C30A Si4 C31A 112(2) . . ?
N2 Si4 C30 110.2(5) . . ?
C32 Si4 C30 111.8(8) . . ?
C31A Si4 C30 136.1(13) . . ?
N2 Si4 C31 115.4(4) . . ?
C32 Si4 C31 104.2(8) . . ?
C30 Si4 C31 102.7(7) . . ?
N2 Si4 C32A 110.3(12) . . ?
C30A Si4 C32A 101(2) . . ?
C31A Si4 C32A 95.5(18) . . ?
Si1 N1 Si2 118.6(3) . . ?
Si1 N1 Sn 126.1(3) . . ?
Si2 N1 Sn 115.2(3) . . ?
Si3 N2 Si4 117.7(4) . . ?
Si3 N2 Sn 122.6(3) . . ?
Si4 N2 Sn 119.6(3) . . ?
C5 C1 P2 116.7(5) . . ?
C5 C1 P1 112.2(5) . . ?
P2 C1 P1 116.1(4) . . ?
C5 C1 P4 124.1(5) . . ?
P2 C1 P4 92.2(3) . . ?
P1 C1 P4 92.5(3) . . ?
C9 C2 P3 112.5(5) . . ?
C9 C2 P1 111.8(5) . . ?
P3 C2 P1 109.1(4) . . ?
C9 C2 P5 111.9(5) . . ?
P3 C2 P5 118.2(4) . . ?
P1 C2 P5 91.4(3) . . ?
C13 C3 P5 117.5(5) . . ?
C13 C3 P4 113.9(5) . . ?
P5 C3 P4 115.4(4) . . ?
C13 C3 P1 121.9(5) . . ?
P5 C3 P1 92.0(3) . . ?
P4 C3 P1 92.1(3) . . ?
C17 C4 P6 110.8(5) . . ?
C17 C4 P4 109.9(5) . . ?
P6 C4 P4 112.8(4) . . ?
C17 C4 P2 116.1(5) . . ?
P6 C4 P2 115.3(4) . . ?
P4 C4 P2 90.5(3) . . ?
C7 C5 C6 110.6(7) . . ?
C7 C5 C8 107.2(6) . . ?
C6 C5 C8 108.0(6) . . ?
C7 C5 C1 110.3(6) . . ?
C6 C5 C1 109.1(6) . . ?
C8 C5 C1 111.5(7) . . ?
C12 C9 C11 110.5(6) . . ?
C12 C9 C10 107.8(6) . . ?
C11 C9 C10 107.8(7) . . ?
C12 C9 C2 108.0(6) . . ?
C11 C9 C2 110.3(6) . . ?
C10 C9 C2 112.5(6) . . ?
C16 C13 C14 108.1(7) . . ?
C16 C13 C15 109.8(7) . . ?
C14 C13 C15 109.8(7) . . ?
C16 C13 C3 112.3(7) . . ?
C14 C13 C3 109.3(6) . . ?
C15 C13 C3 107.5(6) . . ?
C20 C17 C19 109.2(7) . . ?
C20 C17 C18 107.2(7) . . ?
C19 C17 C18 107.7(6) . . ?
C20 C17 C4 111.4(6) . . ?
C19 C17 C4 110.7(7) . . ?
C18 C17 C4 110.5(6) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Sn N1 2.077(6) . ?
Sn N2 2.083(6) . ?
Sn P3 2.554(2) . ?
Sn P6 2.624(2) . ?
P1 C1 1.879(8) . ?
P1 C2 1.891(7) . ?
P1 C3 1.918(8) . ?
P2 C1 1.869(7) . ?
P2 C4 1.938(8) . ?
P2 P3 2.179(3) . ?
P3 C2 1.874(7) . ?
P4 C3 1.872(8) . ?
P4 C4 1.886(7) . ?
P4 C1 1.898(8) . ?
P5 C3 1.872(7) . ?
P5 C2 1.919(7) . ?
P5 P6 2.182(3) . ?
P6 C4 1.879(7) . ?
Si1 N1 1.755(6) . ?
Si1 C22 1.861(9) . ?
Si1 C23 1.870(8) . ?
Si1 C21 1.896(9) . ?
Si2 N1 1.760(6) . ?
Si2 C26 1.858(8) . ?
Si2 C24 1.859(9) . ?
Si2 C25 1.883(9) . ?
Si3 N2 1.759(6) . ?
Si3 C27 1.848(8) . ?
Si3 C28 1.870(8) . ?
Si3 C29 1.870(9) . ?
Si4 N2 1.760(6) . ?
Si4 C30A 1.77(5) . ?
Si4 C32 1.801(13) . ?
Si4 C31A 1.85(4) . ?
Si4 C30 1.867(12) . ?
Si4 C31 1.895(12) . ?
Si4 C32A 1.99(4) . ?
C1 C5 1.554(10) . ?
C2 C9 1.586(11) . ?
C3 C13 1.554(10) . ?
C4 C17 1.583(11) . ?
C5 C7 1.525(10) . ?
C5 C6 1.532(11) . ?
C5 C8 1.535(11) . ?
C9 C12 1.520(10) . ?
C9 C11 1.520(10) . ?
C9 C10 1.528(10) . ?
C13 C16 1.518(11) . ?
C13 C14 1.533(10) . ?
C13 C15 1.552(11) . ?
C17 C20 1.521(10) . ?
C17 C19 1.533(10) . ?
C17 C18 1.540(10) . ?
