#------------------------------------------------------------------------------
#$Date: 2016-03-25 10:27:13 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179750 $
#$URL: svn://www.crystallography.net/cod/cif/7/00/46/7004604.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7004604
loop_
_publ_author_name
'Cadierno, Victorio'
'Díez, Josefina'
'García-Álvarez, Joaquín'
'Gimeno, José'
'Rubio-García, Javier'
_publ_section_title
;
 Novel ruthenium(ii) complexes containing the N-phosphorylated
 iminophosphorane-phosphine ligand
 Ph2PCH2P{NP(O)(OEt)2}Ph2: a new coordination mode of
 its methanide anion
;
_journal_issue                   42
_journal_name_full               'Dalton Transactions'
_journal_page_first              5737
_journal_page_last               5748
_journal_paper_doi               10.1039/b809166h
_journal_year                    2008
_chemical_compound_source        synthesis
_chemical_formula_moiety         'C49 H48 N5 O3 P3 Ru, 2(F6 Sb), 2(C H2 Cl2)'
_chemical_formula_sum            'C51 H52 Cl4 F12 N5 O3 P3 Ru Sb2'
_chemical_formula_weight         1590.26
_chemical_name_systematic
;
?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 120.276(1)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   12.4217(2)
_cell_length_b                   34.9367(6)
_cell_length_c                   15.9704(3)
_cell_measurement_reflns_used    9887
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      25.350
_cell_measurement_theta_min      0.407
_cell_volume                     5985.42(19)
_computing_cell_refinement       'HKL Scalepack (Otwinowki & Minor 1997)'
_computing_data_collection       'Collet (Nonius BV, 1997-2000)'
_computing_data_reduction
'HKL Denzo and scalepack (Otwinowski & Minor 1997)'
_computing_molecular_graphics    'PLATON (Spek, 2007)'
_computing_publication_material  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SIR 92 (Altomare A., 1993)'
_diffrn_ambient_temperature      150(2)
_diffrn_detector_area_resol_mean 9
_diffrn_measured_fraction_theta_full 0.982
_diffrn_measured_fraction_theta_max 0.982
_diffrn_measurement_device       '95 mm CCD camera on κ-goniostat'
_diffrn_measurement_device_type  KappaCCD
_diffrn_measurement_method       'φ and ω scan'
_diffrn_radiation_monochromator  'horizontally mounted graphite crystal'
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.042
_diffrn_reflns_av_sigmaI/netI    0.0668
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       0
_diffrn_reflns_limit_k_min       -41
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            39556
_diffrn_reflns_theta_full        25.08
_diffrn_reflns_theta_max         25.08
_diffrn_reflns_theta_min         1.17
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    1.487
_exptl_absorpt_correction_T_max  0.772
_exptl_absorpt_correction_T_min  0.665
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
multi-scan from symmetry-related measurements
Sortav (Blessing 1995)
;
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.765
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             3136
_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.25
_exptl_crystal_size_min          0.2
_refine_diff_density_max         1.132
_refine_diff_density_min         -1.268
_refine_diff_density_rms         0.240
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.020
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     732
_refine_ls_number_reflns         10433
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.020
_refine_ls_R_factor_all          0.0551
_refine_ls_R_factor_gt           0.0390
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0857P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1185
_refine_ls_wR_factor_ref         0.1448
_reflns_number_gt                8145
_reflns_number_total             10433
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b809166h.txt
_cod_data_source_block           8a
_cod_depositor_comments
;
The following automatic conversions were performed:
'_exptl_absorpt_correction_type' value 'Multi scan' changed to
'multi-scan' according to
'/home/saulius/struct/CIF-dictionaries/cif_core.dic' dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_cell_volume        5985.42(18)
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               7004604
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.6004(5) 0.67638(15) 0.9708(4) 0.0194(11) Uani 1 1 d . . .
C2 C 0.4932(5) 0.66123(16) 0.8935(4) 0.0229(12) Uani 1 1 d . . .
H2 H 0.4954 0.6368 0.8714 0.027 Uiso 1 1 calc R . .
C3 C 0.3815(5) 0.68212(18) 0.8478(4) 0.0296(14) Uani 1 1 d . . .
H3 H 0.3104 0.6716 0.7958 0.035 Uiso 1 1 calc R . .
C4 C 0.3779(6) 0.71836(18) 0.8808(4) 0.0325(14) Uani 1 1 d . . .
H4 H 0.3044 0.7324 0.8508 0.039 Uiso 1 1 calc R . .
C5 C 0.4835(6) 0.73360(17) 0.9582(4) 0.0327(14) Uani 1 1 d . . .
H5 H 0.4812 0.7581 0.9800 0.039 Uiso 1 1 calc R . .
C6 C 0.5934(6) 0.71264(16) 1.0039(4) 0.0282(13) Uani 1 1 d . . .
H6 H 0.6633 0.7230 1.0574 0.034 Uiso 1 1 calc R . .
C7 C 0.7670(5) 0.64543(14) 1.1550(4) 0.0178(11) Uani 1 1 d . . .
C8 C 0.6623(5) 0.63764(16) 1.1639(4) 0.0240(12) Uani 1 1 d . . .
H8 H 0.5834 0.6371 1.1089 0.029 Uiso 1 1 calc R . .
C9 C 0.6760(6) 0.63073(17) 1.2545(5) 0.0325(14) Uani 1 1 d . . .
H9 H 0.6066 0.6255 1.2602 0.039 Uiso 1 1 calc R . .
C10 C 0.7930(7) 0.63172(18) 1.3359(4) 0.0361(16) Uani 1 1 d . . .
H10 H 0.8021 0.6269 1.3964 0.043 Uiso 1 1 calc R . .
C11 C 0.8971(6) 0.63973(17) 1.3286(4) 0.0325(15) Uani 1 1 d . . .
H11 H 0.9757 0.6404 1.3840 0.039 Uiso 1 1 calc R . .
C12 C 0.8840(5) 0.64670(15) 1.2391(4) 0.0242(12) Uani 1 1 d . . .
H12 H 0.9541 0.6523 1.2345 0.029 Uiso 1 1 calc R . .
C13 C 0.8709(5) 0.68237(15) 1.0532(4) 0.0200(11) Uani 1 1 d . . .
H13A H 0.8606 0.7047 1.0845 0.024 Uiso 1 1 calc R . .
H13B H 0.9494 0.6706 1.0997 0.024 Uiso 1 1 calc R . .
C14 C 0.7579(5) 0.72894(16) 0.8728(4) 0.0222(12) Uani 1 1 d . . .
C15 C 0.7266(6) 0.76088(17) 0.9079(5) 0.0355(15) Uani 1 1 d . . .
H15 H 0.7724 0.7666 0.9736 0.043 Uiso 1 1 calc R . .
C16 C 0.6281(7) 0.7843(2) 0.8461(6) 0.0473(19) Uani 1 1 d . . .
H16 H 0.6082 0.8057 0.8704 0.057 Uiso 1 1 calc R . .
C17 C 0.5611(6) 0.7760(2) 0.7504(6) 0.0480(19) Uani 1 1 d . . .
H17 H 0.4946 0.7915 0.7090 0.058 Uiso 1 1 calc R . .
C18 C 0.5907(6) 0.7446(2) 0.7139(5) 0.048(2) Uani 1 1 d . . .
H18 H 0.5439 0.7393 0.6479 0.058 Uiso 1 1 calc R . .
C19 C 0.6902(6) 0.72061(18) 0.7744(4) 0.0334(15) Uani 1 1 d . . .
H19 H 0.7105 0.6996 0.7493 0.040 Uiso 1 1 calc R . .
C20 C 1.0225(5) 0.73114(16) 1.0071(4) 0.0254(13) Uani 1 1 d . . .
C21 C 1.1271(5) 0.72297(17) 1.0963(4) 0.0294(14) Uani 1 1 d . . .
H21 H 1.1271 0.7018 1.1314 0.035 Uiso 1 1 calc R . .
C22 C 1.2302(6) 0.7461(2) 1.1326(5) 0.0420(17) Uani 1 1 d . . .
H22 H 1.2994 0.7406 1.1927 0.050 Uiso 1 1 calc R . .
C23 C 1.2320(7) 0.7767(2) 1.0816(6) 0.060(2) Uani 1 1 d . . .
H23 H 1.3014 0.7926 1.1076 0.071 Uiso 1 1 calc R . .
C24 C 1.1324(8) 0.7843(3) 0.9923(8) 0.096(4) Uani 1 1 d . . .
H24 H 1.1363 0.8046 0.9561 0.116 Uiso 1 1 calc R . .
C25 C 1.0268(7) 0.7625(2) 0.9555(6) 0.072(3) Uani 1 1 d . . .
H25 H 0.9578 0.7687 0.8958 0.086 Uiso 1 1 calc R . .
C26 C 0.9463(6) 0.56823(17) 0.8060(4) 0.0298(14) Uani 1 1 d . . .
H26A H 0.9225 0.5511 0.8418 0.036 Uiso 1 1 calc R . .
H26B H 1.0354 0.5659 0.8322 0.036 Uiso 1 1 calc R . .
C27 C 0.8782(7) 0.5579(2) 0.7012(5) 0.0463(18) Uani 1 1 d . . .
H27A H 0.9007 0.5753 0.6661 0.069 Uiso 1 1 calc R . .
H27B H 0.7900 0.5593 0.6765 0.069 Uiso 1 1 calc R . .
H27C H 0.9000 0.5323 0.6935 0.069 Uiso 1 1 calc R . .
C28 C 1.1808(5) 0.64785(17) 0.9490(4) 0.0276(13) Uani 1 1 d . . .
H28A H 1.1474 0.6736 0.9324 0.033 Uiso 1 1 calc R . .
H28B H 1.1804 0.6367 0.8933 0.033 Uiso 1 1 calc R . .
C29 C 1.3106(6) 0.6488(2) 1.0340(5) 0.0404(17) Uani 1 1 d . . .
H29A H 1.3436 0.6232 1.0484 0.061 Uiso 1 1 calc R . .
H29B H 1.3094 0.6591 1.0892 0.061 Uiso 1 1 calc R . .
H29C H 1.3619 0.6645 1.0189 0.061 Uiso 1 1 calc R . .
C30 C 0.8413(5) 0.50301(15) 0.9804(4) 0.0214(12) Uani 1 1 d . . .
H30 H 0.8967 0.5072 1.0460 0.026 Uiso 1 1 calc R . .
C31 C 0.8371(5) 0.46724(16) 0.9419(4) 0.0255(13) Uani 1 1 d . . .
H31 H 0.8896 0.4478 0.9811 0.031 Uiso 1 1 calc R . .
C32 C 0.7551(5) 0.46056(16) 0.8456(4) 0.0278(13) Uani 1 1 d . . .
H32 H 0.7494 0.4364 0.8191 0.033 Uiso 1 1 calc R . .
C33 C 0.6810(5) 0.49021(16) 0.7886(4) 0.0255(13) Uani 1 1 d . . .
H33 H 0.6254 0.4864 0.7229 0.031 Uiso 1 1 calc R . .
C34 C 0.6905(5) 0.52589(15) 0.8303(4) 0.0193(11) Uani 1 1 d . . .
C35 C 0.6264(5) 0.56056(16) 0.7738(4) 0.0203(12) Uani 1 1 d . . .
C36 C 0.5534(5) 0.56020(17) 0.6748(4) 0.0287(13) Uani 1 1 d . . .
H36 H 0.5353 0.5370 0.6417 0.034 Uiso 1 1 calc R . .
C37 C 0.5061(6) 0.59398(18) 0.6232(4) 0.0336(15) Uani 1 1 d . . .
H37 H 0.4543 0.5938 0.5562 0.040 Uiso 1 1 calc R . .
C38 C 0.5385(5) 0.62790(17) 0.6748(4) 0.0278(13) Uani 1 1 d . . .
H38 H 0.5125 0.6513 0.6429 0.033 Uiso 1 1 calc R . .
C39 C 0.6106(5) 0.62641(16) 0.7753(4) 0.0219(12) Uani 1 1 d . . .
H39 H 0.6310 0.6494 0.8094 0.026 Uiso 1 1 calc R . .
C40 C 0.4972(5) 0.56419(15) 0.9318(4) 0.0202(12) Uani 1 1 d . . .
H40 H 0.4712 0.5723 0.8690 0.024 Uiso 1 1 calc R . .
C41 C 0.4092(5) 0.55065(16) 0.9524(4) 0.0275(13) Uani 1 1 d . . .
H41 H 0.3254 0.5499 0.9047 0.033 Uiso 1 1 calc R . .
C42 C 0.4482(5) 0.53805(17) 1.0463(4) 0.0295(14) Uani 1 1 d . . .
H42 H 0.3908 0.5293 1.0629 0.035 Uiso 1 1 calc R . .
C43 C 0.5727(5) 0.53886(16) 1.1134(4) 0.0263(13) Uani 1 1 d . . .
H43 H 0.6007 0.5299 1.1758 0.032 Uiso 1 1 calc R . .
C44 C 0.6569(5) 0.55293(15) 1.0889(4) 0.0194(11) Uani 1 1 d . . .
C45 C 0.7918(5) 0.55407(14) 1.1571(4) 0.0176(11) Uani 1 1 d . . .
C46 C 0.8506(5) 0.54033(16) 1.2510(4) 0.0242(12) Uani 1 1 d . . .
H46 H 0.8040 0.5293 1.2755 0.029 Uiso 1 1 calc R . .
C47 C 0.9778(5) 0.54294(17) 1.3082(4) 0.0281(14) Uani 1 1 d . . .
H47 H 1.0177 0.5337 1.3715 0.034 Uiso 1 1 calc R . .
C48 C 1.0463(5) 0.55953(16) 1.2708(4) 0.0257(13) Uani 1 1 d . . .
H48 H 1.1325 0.5620 1.3086 0.031 Uiso 1 1 calc R . .
C49 C 0.9838(5) 0.57221(15) 1.1770(4) 0.0198(11) Uani 1 1 d . . .
H49 H 1.0296 0.5829 1.1514 0.024 Uiso 1 1 calc R . .
C50 C 0.2805(7) 0.4816(2) 0.5291(5) 0.056(2) Uani 1 1 d . . .
H50A H 0.2738 0.4979 0.5755 0.067 Uiso 1 1 calc R . .
H50B H 0.1984 0.4713 0.4851 0.067 Uiso 1 1 calc R . .
C51 C 0.0816(10) 0.1737(3) -0.1630(8) 0.085(3) Uani 1 1 d . . .
H51A H 0.0523 0.1574 -0.2196 0.102 Uiso 1 1 calc R . .
H51B H 0.0401 0.1656 -0.1283 0.102 Uiso 1 1 calc R . .
F1 F 0.6539(4) 0.09473(12) 0.1428(3) 0.0582(12) Uani 1 1 d . . .
F2 F 0.5942(5) 0.1521(2) 0.2190(4) 0.112(3) Uani 1 1 d . . .
F3 F 0.5484(5) 0.15788(14) 0.0397(3) 0.0772(17) Uani 1 1 d . . .
F4 F 0.7248(7) 0.19828(13) 0.1785(4) 0.116(3) Uani 1 1 d . . .
F5 F 0.7842(5) 0.14091(15) 0.1025(4) 0.0788(16) Uani 1 1 d . . .
F6 F 0.8266(4) 0.13664(11) 0.2802(3) 0.0535(11) Uani 1 1 d . . .
F7 F 0.2914(4) 0.53593(14) 0.7041(3) 0.0645(13) Uani 1 1 d . . .
F8 F 0.1565(4) 0.5790(2) 0.7527(3) 0.090(2) Uani 1 1 d . . .
F9 F 0.0482(5) 0.53854(16) 0.5902(4) 0.0799(16) Uani 1 1 d . . .
F10 F 0.0554(5) 0.61421(17) 0.5854(4) 0.0886(18) Uani 1 1 d . . .
F11 F 0.1913(4) 0.57182(13) 0.5351(3) 0.0562(12) Uani 1 1 d . . .
F12 F 0.3037(5) 0.61006(15) 0.7016(4) 0.0788(16) Uani 1 1 d . . .
N1 N 0.9013(4) 0.66634(13) 0.8914(3) 0.0242(10) Uani 1 1 d . . .
N2 N 0.7678(4) 0.53207(12) 0.9263(3) 0.0166(9) Uani 1 1 d . . .
N3 N 0.6527(4) 0.59366(12) 0.8262(3) 0.0179(9) Uani 1 1 d . . .
N4 N 0.6190(4) 0.56628(11) 0.9983(3) 0.0151(9) Uani 1 1 d . . .
N5 N 0.8589(4) 0.56990(11) 1.1198(3) 0.0154(9) Uani 1 1 d . . .
O1 O 0.9255(3) 0.60001(10) 0.9781(3) 0.0199(8) Uani 1 1 d . . .
O2 O 0.9149(4) 0.60722(11) 0.8152(3) 0.0291(9) Uani 1 1 d . . .
O3 O 1.1048(3) 0.62451(11) 0.9767(3) 0.0249(9) Uani 1 1 d . . .
P1 P 0.74445(13) 0.64791(4) 1.03219(10) 0.0164(3) Uani 1 1 d . . .
P2 P 0.88834(13) 0.69946(4) 0.95333(10) 0.0195(3) Uani 1 1 d . . .
P3 P 0.95782(13) 0.62512(4) 0.91812(10) 0.0183(3) Uani 1 1 d . . .
Ru1 Ru 0.75812(4) 0.586971(11) 0.97733(3) 0.01357(12) Uani 1 1 d . . .
Sb1 Sb 0.68629(4) 0.146764(12) 0.15929(3) 0.03206(14) Uani 1 1 d . . .
Sb2 Sb 0.17229(4) 0.575749(14) 0.64252(3) 0.03438(14) Uani 1 1 d . . .
Cl1 Cl 0.33031(18) 0.50952(6) 0.46267(13) 0.0538(5) Uani 1 1 d . . .
Cl2 Cl 0.3816(3) 0.44444(8) 0.5899(2) 0.1124(12) Uani 1 1 d . . .
Cl3 Cl 0.2429(3) 0.16696(8) -0.08780(17) 0.0824(7) Uani 1 1 d . . .
Cl4 Cl 0.0389(3) 0.22050(8) -0.2012(2) 0.1030(10) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru -1.2594 0.8363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C2 C1 C6 118.0(5) . . ?
C2 C1 P1 120.5(4) . . ?
C6 C1 P1 121.3(4) . . ?
C1 C2 C3 121.2(5) . . ?
C1 C2 H2 119.4 . . ?
C3 C2 H2 119.4 . . ?
C4 C3 C2 119.5(6) . . ?
C4 C3 H3 120.3 . . ?
C2 C3 H3 120.3 . . ?
C5 C4 C3 119.9(6) . . ?
C5 C4 H4 120.1 . . ?
C3 C4 H4 120.1 . . ?
C4 C5 C6 120.5(6) . . ?
C4 C5 H5 119.8 . . ?
C6 C5 H5 119.8 . . ?
C5 C6 C1 120.9(6) . . ?
C5 C6 H6 119.6 . . ?
C1 C6 H6 119.6 . . ?
C12 C7 C8 118.5(5) . . ?
C12 C7 P1 123.3(4) . . ?
C8 C7 P1 117.8(4) . . ?
C9 C8 C7 120.3(6) . . ?
C9 C8 H8 119.8 . . ?
C7 C8 H8 119.8 . . ?
C10 C9 C8 119.7(6) . . ?
C10 C9 H9 120.1 . . ?
C8 C9 H9 120.1 . . ?
C9 C10 C11 120.7(6) . . ?
C9 C10 H10 119.6 . . ?
C11 C10 H10 119.6 . . ?
C12 C11 C10 119.8(6) . . ?
C12 C11 H11 120.1 . . ?
C10 C11 H11 120.1 . . ?
C11 C12 C7 120.9(6) . . ?
C11 C12 H12 119.5 . . ?
C7 C12 H12 119.5 . . ?
P2 C13 P1 121.1(3) . . ?
P2 C13 H13A 107.1 . . ?
P1 C13 H13A 107.1 . . ?
P2 C13 H13B 107.1 . . ?
P1 C13 H13B 107.1 . . ?
H13A C13 H13B 106.8 . . ?
C15 C14 C19 119.5(5) . . ?
C15 C14 P2 120.4(4) . . ?
C19 C14 P2 120.1(5) . . ?
C16 C15 C14 120.9(6) . . ?
C16 C15 H15 119.6 . . ?
C14 C15 H15 119.6 . . ?
C17 C16 C15 119.7(7) . . ?
C17 C16 H16 120.1 . . ?
C15 C16 H16 120.1 . . ?
C16 C17 C18 120.4(6) . . ?
C16 C17 H17 119.8 . . ?
C18 C17 H17 119.8 . . ?
C17 C18 C19 121.1(6) . . ?
C17 C18 H18 119.5 . . ?
C19 C18 H18 119.5 . . ?
C14 C19 C18 118.4(6) . . ?
C14 C19 H19 120.8 . . ?
C18 C19 H19 120.8 . . ?
C25 C20 C21 118.3(6) . . ?
C25 C20 P2 120.1(5) . . ?
C21 C20 P2 121.4(4) . . ?
C22 C21 C20 120.3(6) . . ?
C22 C21 H21 119.9 . . ?
C20 C21 H21 119.9 . . ?
C23 C22 C21 120.5(6) . . ?
C23 C22 H22 119.8 . . ?
C21 C22 H22 119.8 . . ?
C22 C23 C24 120.3(7) . . ?
C22 C23 H23 119.9 . . ?
C24 C23 H23 119.9 . . ?
C23 C24 C25 120.6(8) . . ?
C23 C24 H24 119.7 . . ?
C25 C24 H24 119.7 . . ?
C24 C25 C20 120.0(7) . . ?
C24 C25 H25 120.0 . . ?
C20 C25 H25 120.0 . . ?
O2 C26 C27 108.3(5) . . ?
O2 C26 H26A 110.0 . . ?
C27 C26 H26A 110.0 . . ?
O2 C26 H26B 110.0 . . ?
C27 C26 H26B 110.0 . . ?
H26A C26 H26B 108.4 . . ?
C26 C27 H27A 109.5 . . ?
C26 C27 H27B 109.5 . . ?
H27A C27 H27B 109.5 . . ?
C26 C27 H27C 109.5 . . ?
H27A C27 H27C 109.5 . . ?
H27B C27 H27C 109.5 . . ?
O3 C28 C29 107.5(5) . . ?
O3 C28 H28A 110.2 . . ?
C29 C28 H28A 110.2 . . ?
O3 C28 H28B 110.2 . . ?
C29 C28 H28B 110.2 . . ?
H28A C28 H28B 108.5 . . ?
C28 C29 H29A 109.5 . . ?
C28 C29 H29B 109.5 . . ?
H29A C29 H29B 109.5 . . ?
C28 C29 H29C 109.5 . . ?
H29A C29 H29C 109.5 . . ?
H29B C29 H29C 109.5 . . ?
N2 C30 C31 122.3(5) . . ?
N2 C30 H30 118.8 . . ?
C31 C30 H30 118.8 . . ?
C32 C31 C30 119.5(5) . . ?
C32 C31 H31 120.2 . . ?
C30 C31 H31 120.2 . . ?
C31 C32 C33 118.9(5) . . ?
C31 C32 H32 120.5 . . ?
C33 C32 H32 120.5 . . ?
C32 C33 C34 119.3(5) . . ?
C32 C33 H33 120.3 . . ?
C34 C33 H33 120.3 . . ?
N2 C34 C33 121.7(5) . . ?
N2 C34 C35 114.6(5) . . ?
C33 C34 C35 123.5(5) . . ?
N3 C35 C36 122.0(5) . . ?
N3 C35 C34 115.5(5) . . ?
C36 C35 C34 122.4(5) . . ?
C35 C36 C37 120.8(6) . . ?
C35 C36 H36 119.6 . . ?
C37 C36 H36 119.6 . . ?
C38 C37 C36 117.8(5) . . ?
C38 C37 H37 121.1 . . ?
C36 C37 H37 121.1 . . ?
C37 C38 C39 118.7(5) . . ?
C37 C38 H38 120.6 . . ?
C39 C38 H38 120.6 . . ?
N3 C39 C38 123.8(5) . . ?
N3 C39 H39 118.1 . . ?
C38 C39 H39 118.1 . . ?
N4 C40 C41 123.0(5) . . ?
N4 C40 H40 118.5 . . ?
C41 C40 H40 118.5 . . ?
C40 C41 C42 118.6(5) . . ?
C40 C41 H41 120.7 . . ?
C42 C41 H41 120.7 . . ?
C43 C42 C41 118.6(5) . . ?
C43 C42 H42 120.7 . . ?
C41 C42 H42 120.7 . . ?
C42 C43 C44 120.3(5) . . ?
C42 C43 H43 119.8 . . ?
C44 C43 H43 119.8 . . ?
N4 C44 C43 121.3(5) . . ?
N4 C44 C45 115.7(4) . . ?
C43 C44 C45 123.0(5) . . ?
N5 C45 C46 120.7(5) . . ?
N5 C45 C44 114.1(4) . . ?
C46 C45 C44 125.2(5) . . ?
C47 C46 C45 120.1(5) . . ?
C47 C46 H46 120.0 . . ?
C45 C46 H46 120.0 . . ?
C46 C47 C48 119.4(5) . . ?
C46 C47 H47 120.3 . . ?
C48 C47 H47 120.3 . . ?
C49 C48 C47 118.3(5) . . ?
C49 C48 H48 120.9 . . ?
C47 C48 H48 120.9 . . ?
N5 C49 C48 123.1(5) . . ?
N5 C49 H49 118.5 . . ?
C48 C49 H49 118.5 . . ?
Cl2 C50 Cl1 112.2(4) . . ?
Cl2 C50 H50A 109.2 . . ?
Cl1 C50 H50A 109.2 . . ?
Cl2 C50 H50B 109.2 . . ?
Cl1 C50 H50B 109.2 . . ?
H50A C50 H50B 107.9 . . ?
Cl4 C51 Cl3 114.1(6) . . ?
Cl4 C51 H51A 108.7 . . ?
Cl3 C51 H51A 108.7 . . ?
Cl4 C51 H51B 108.7 . . ?
Cl3 C51 H51B 108.7 . . ?
H51A C51 H51B 107.6 . . ?
P3 N1 P2 132.5(3) . . ?
C30 N2 C34 118.1(5) . . ?
C30 N2 Ru1 126.1(4) . . ?
C34 N2 Ru1 115.8(3) . . ?
C39 N3 C35 116.7(4) . . ?
C39 N3 Ru1 128.0(4) . . ?
C35 N3 Ru1 115.3(3) . . ?
C40 N4 C44 118.1(4) . . ?
C40 N4 Ru1 126.6(3) . . ?
C44 N4 Ru1 115.3(3) . . ?
C49 N5 C45 118.5(4) . . ?
C49 N5 Ru1 125.6(3) . . ?
C45 N5 Ru1 115.9(3) . . ?
P3 O1 Ru1 134.5(2) . . ?
C26 O2 P3 120.9(3) . . ?
C28 O3 P3 122.6(3) . . ?
C7 P1 C1 100.2(2) . . ?
C7 P1 C13 100.2(2) . . ?
C1 P1 C13 104.5(2) . . ?
C7 P1 Ru1 110.83(16) . . ?
C1 P1 Ru1 121.81(18) . . ?
C13 P1 Ru1 116.08(18) . . ?
N1 P2 C14 108.1(3) . . ?
N1 P2 C13 113.8(2) . . ?
C14 P2 C13 110.7(3) . . ?
N1 P2 C20 112.5(3) . . ?
C14 P2 C20 105.7(3) . . ?
C13 P2 C20 105.8(3) . . ?
O1 P3 N1 119.1(2) . . ?
O1 P3 O3 102.5(2) . . ?
N1 P3 O3 113.6(2) . . ?
O1 P3 O2 112.1(2) . . ?
N1 P3 O2 102.2(2) . . ?
O3 P3 O2 107.2(2) . . ?
N4 Ru1 N5 79.06(16) . . ?
N4 Ru1 N3 97.97(16) . . ?
N5 Ru1 N3 169.52(16) . . ?
N4 Ru1 N2 87.69(16) . . ?
N5 Ru1 N2 92.44(16) . . ?
N3 Ru1 N2 77.35(16) . . ?
N4 Ru1 O1 168.08(15) . . ?
N5 Ru1 O1 90.42(15) . . ?
N3 Ru1 O1 91.39(15) . . ?
N2 Ru1 O1 87.17(15) . . ?
N4 Ru1 P1 91.92(12) . . ?
N5 Ru1 P1 88.18(12) . . ?
N3 Ru1 P1 102.02(12) . . ?
N2 Ru1 P1 179.20(13) . . ?
O1 Ru1 P1 93.34(10) . . ?
F2 Sb1 F4 89.5(3) . . ?
F2 Sb1 F1 91.5(3) . . ?
F4 Sb1 F1 177.9(3) . . ?
F2 Sb1 F3 91.1(2) . . ?
F4 Sb1 F3 89.7(2) . . ?
F1 Sb1 F3 92.1(2) . . ?
F2 Sb1 F5 178.2(2) . . ?
F4 Sb1 F5 90.6(3) . . ?
F1 Sb1 F5 88.3(2) . . ?
F3 Sb1 F5 90.7(2) . . ?
F2 Sb1 F6 89.1(2) . . ?
F4 Sb1 F6 89.1(2) . . ?
F1 Sb1 F6 89.07(18) . . ?
F3 Sb1 F6 178.8(2) . . ?
F5 Sb1 F6 89.1(2) . . ?
F10 Sb2 F11 91.9(2) . . ?
F10 Sb2 F12 93.0(3) . . ?
F11 Sb2 F12 91.6(2) . . ?
F10 Sb2 F9 91.1(3) . . ?
F11 Sb2 F9 89.8(2) . . ?
F12 Sb2 F9 175.6(3) . . ?
F10 Sb2 F8 89.5(3) . . ?
F11 Sb2 F8 178.6(2) . . ?
F12 Sb2 F8 88.0(2) . . ?
F9 Sb2 F8 90.5(2) . . ?
F10 Sb2 F7 178.4(2) . . ?
F11 Sb2 F7 89.7(2) . . ?
F12 Sb2 F7 87.3(2) . . ?
F9 Sb2 F7 88.5(2) . . ?
F8 Sb2 F7 89.0(2) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 C2 1.386(8) . ?
C1 C6 1.392(8) . ?
C1 P1 1.839(5) . ?
C2 C3 1.404(8) . ?
C2 H2 0.9300 . ?
C3 C4 1.381(9) . ?
C3 H3 0.9300 . ?
C4 C5 1.378(9) . ?
C4 H4 0.9300 . ?
C5 C6 1.388(8) . ?
C5 H5 0.9300 . ?
C6 H6 0.9300 . ?
C7 C12 1.397(8) . ?
C7 C8 1.404(8) . ?
C7 P1 1.838(5) . ?
C8 C9 1.391(8) . ?
C8 H8 0.9300 . ?
C9 C10 1.377(9) . ?
C9 H9 0.9300 . ?
C10 C11 1.385(9) . ?
C10 H10 0.9300 . ?
C11 C12 1.377(8) . ?
C11 H11 0.9300 . ?
C12 H12 0.9300 . ?
C13 P2 1.815(5) . ?
C13 P1 1.870(5) . ?
C13 H13A 0.9700 . ?
C13 H13B 0.9700 . ?
C14 C15 1.389(8) . ?
C14 C19 1.389(8) . ?
C14 P2 1.800(5) . ?
C15 C16 1.387(9) . ?
C15 H15 0.9300 . ?
C16 C17 1.354(10) . ?
C16 H16 0.9300 . ?
C17 C18 1.375(11) . ?
C17 H17 0.9300 . ?
C18 C19 1.400(9) . ?
C18 H18 0.9300 . ?
C19 H19 0.9300 . ?
C20 C25 1.388(8) . ?
C20 C21 1.390(8) . ?
C20 P2 1.815(6) . ?
C21 C22 1.371(8) . ?
C21 H21 0.9300 . ?
C22 C23 1.35(1) . ?
C22 H22 0.9300 . ?
C23 C24 1.363(12) . ?
C23 H23 0.9300 . ?
C24 C25 1.368(10) . ?
C24 H24 0.9300 . ?
C25 H25 0.9300 . ?
C26 O2 1.445(7) . ?
C26 C27 1.490(8) . ?
C26 H26A 0.9700 . ?
C26 H26B 0.9700 . ?
C27 H27A 0.9600 . ?
C27 H27B 0.9600 . ?
C27 H27C 0.9600 . ?
C28 O3 1.474(6) . ?
C28 C29 1.495(8) . ?
C28 H28A 0.9700 . ?
C28 H28B 0.9700 . ?
C29 H29A 0.9600 . ?
C29 H29B 0.9600 . ?
C29 H29C 0.9600 . ?
C30 N2 1.347(7) . ?
C30 C31 1.382(8) . ?
C30 H30 0.9300 . ?
C31 C32 1.371(8) . ?
C31 H31 0.9300 . ?
C32 C33 1.380(8) . ?
C32 H32 0.9300 . ?
C33 C34 1.390(8) . ?
C33 H33 0.9300 . ?
C34 N2 1.354(6) . ?
C34 C35 1.480(7) . ?
C35 N3 1.367(7) . ?
C35 C36 1.370(7) . ?
C36 C37 1.389(8) . ?
C36 H36 0.9300 . ?
C37 C38 1.382(9) . ?
C37 H37 0.9300 . ?
C38 C39 1.390(7) . ?
C38 H38 0.9300 . ?
C39 N3 1.347(7) . ?
C39 H39 0.9300 . ?
C40 N4 1.342(7) . ?
C40 C41 1.375(7) . ?
C40 H40 0.9300 . ?
C41 C42 1.394(8) . ?
C41 H41 0.9300 . ?
C42 C43 1.367(8) . ?
C42 H42 0.9300 . ?
C43 C44 1.378(7) . ?
C43 H43 0.9300 . ?
C44 N4 1.359(7) . ?
C44 C45 1.468(7) . ?
C45 N5 1.362(7) . ?
C45 C46 1.382(7) . ?
C46 C47 1.372(8) . ?
C46 H46 0.9300 . ?
C47 C48 1.390(8) . ?
C47 H47 0.9300 . ?
C48 C49 1.368(7) . ?
C48 H48 0.9300 . ?
C49 N5 1.349(7) . ?
C49 H49 0.9300 . ?
C50 Cl2 1.726(8) . ?
C50 Cl1 1.766(8) . ?
C50 H50A 0.9700 . ?
C50 H50B 0.9700 . ?
C51 Cl4 1.733(10) . ?
C51 Cl3 1.757(10) . ?
C51 H51A 0.9700 . ?
C51 H51B 0.9700 . ?
F1 Sb1 1.852(4) . ?
F2 Sb1 1.830(5) . ?
F3 Sb1 1.853(4) . ?
F4 Sb1 1.848(5) . ?
F5 Sb1 1.859(5) . ?
F6 Sb1 1.870(4) . ?
F7 Sb2 1.904(4) . ?
F8 Sb2 1.869(4) . ?
F9 Sb2 1.861(4) . ?
F10 Sb2 1.847(5) . ?
F11 Sb2 1.852(4) . ?
F12 Sb2 1.855(4) . ?
N1 P3 1.564(5) . ?
N1 P2 1.583(5) . ?
N2 Ru1 2.112(4) . ?
N3 Ru1 2.099(4) . ?
N4 Ru1 2.050(4) . ?
N5 Ru1 2.056(4) . ?
O1 P3 1.496(4) . ?
O1 Ru1 2.122(3) . ?
O2 P3 1.578(4) . ?
O3 P3 1.577(4) . ?
P1 Ru1 2.3407(14) . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C6 C1 C2 C3 1.7(8) . . . . ?
P1 C1 C2 C3 178.0(4) . . . . ?
C1 C2 C3 C4 -0.3(9) . . . . ?
C2 C3 C4 C5 -0.3(9) . . . . ?
C3 C4 C5 C6 -0.6(9) . . . . ?
C4 C5 C6 C1 2.0(9) . . . . ?
C2 C1 C6 C5 -2.5(8) . . . . ?
P1 C1 C6 C5 -178.8(4) . . . . ?
C12 C7 C8 C9 -1.1(8) . . . . ?
P1 C7 C8 C9 172.0(4) . . . . ?
C7 C8 C9 C10 0.3(9) . . . . ?
C8 C9 C10 C11 0.4(9) . . . . ?
C9 C10 C11 C12 -0.2(9) . . . . ?
C10 C11 C12 C7 -0.7(9) . . . . ?
C8 C7 C12 C11 1.3(8) . . . . ?
P1 C7 C12 C11 -171.4(4) . . . . ?
C19 C14 C15 C16 0.6(9) . . . . ?
P2 C14 C15 C16 178.5(5) . . . . ?
C14 C15 C16 C17 0.2(10) . . . . ?
C15 C16 C17 C18 -0.5(11) . . . . ?
C16 C17 C18 C19 0.1(11) . . . . ?
C15 C14 C19 C18 -1.0(9) . . . . ?
P2 C14 C19 C18 -178.9(5) . . . . ?
C17 C18 C19 C14 0.7(10) . . . . ?
C25 C20 C21 C22 1.6(10) . . . . ?
P2 C20 C21 C22 175.9(5) . . . . ?
C20 C21 C22 C23 -0.9(11) . . . . ?
C21 C22 C23 C24 -1.8(13) . . . . ?
C22 C23 C24 C25 3.8(17) . . . . ?
C23 C24 C25 C20 -3.1(17) . . . . ?
C21 C20 C25 C24 0.4(14) . . . . ?
P2 C20 C25 C24 -174.0(8) . . . . ?
N2 C30 C31 C32 -0.6(8) . . . . ?
C30 C31 C32 C33 1.9(8) . . . . ?
C31 C32 C33 C34 -0.7(9) . . . . ?
C32 C33 C34 N2 -2.1(8) . . . . ?
C32 C33 C34 C35 172.7(5) . . . . ?
N2 C34 C35 N3 -0.8(7) . . . . ?
C33 C34 C35 N3 -176.0(5) . . . . ?
N2 C34 C35 C36 174.2(5) . . . . ?
C33 C34 C35 C36 -0.9(9) . . . . ?
N3 C35 C36 C37 2.0(9) . . . . ?
C34 C35 C36 C37 -172.7(5) . . . . ?
C35 C36 C37 C38 2.1(9) . . . . ?
C36 C37 C38 C39 -3.4(9) . . . . ?
C37 C38 C39 N3 0.9(9) . . . . ?
N4 C40 C41 C42 -0.8(8) . . . . ?
C40 C41 C42 C43 -1.5(9) . . . . ?
C41 C42 C43 C44 1.9(9) . . . . ?
C42 C43 C44 N4 0.0(8) . . . . ?
C42 C43 C44 C45 -179.1(5) . . . . ?
N4 C44 C45 N5 2.4(6) . . . . ?
C43 C44 C45 N5 -178.4(5) . . . . ?
N4 C44 C45 C46 -176.8(5) . . . . ?
C43 C44 C45 C46 2.3(8) . . . . ?
N5 C45 C46 C47 0.7(8) . . . . ?
C44 C45 C46 C47 180.0(5) . . . . ?
C45 C46 C47 C48 0.1(9) . . . . ?
C46 C47 C48 C49 -1.0(8) . . . . ?
C47 C48 C49 N5 1.1(8) . . . . ?
C31 C30 N2 C34 -2.1(8) . . . . ?
C31 C30 N2 Ru1 176.5(4) . . . . ?
C33 C34 N2 C30 3.4(7) . . . . ?
C35 C34 N2 C30 -171.8(4) . . . . ?
C33 C34 N2 Ru1 -175.3(4) . . . . ?
C35 C34 N2 Ru1 9.4(6) . . . . ?
C38 C39 N3 C35 3.1(8) . . . . ?
C38 C39 N3 Ru1 -178.3(4) . . . . ?
C36 C35 N3 C39 -4.5(8) . . . . ?
C34 C35 N3 C39 170.5(5) . . . . ?
C36 C35 N3 Ru1 176.8(4) . . . . ?
C34 C35 N3 Ru1 -8.2(6) . . . . ?
C41 C40 N4 C44 2.7(8) . . . . ?
C41 C40 N4 Ru1 -178.5(4) . . . . ?
C43 C44 N4 C40 -2.2(7) . . . . ?
C45 C44 N4 C40 176.9(4) . . . . ?
C43 C44 N4 Ru1 178.8(4) . . . . ?
C45 C44 N4 Ru1 -2.1(6) . . . . ?
C48 C49 N5 C45 -0.3(8) . . . . ?
C48 C49 N5 Ru1 -178.4(4) . . . . ?
C46 C45 N5 C49 -0.6(7) . . . . ?
C44 C45 N5 C49 -179.9(4) . . . . ?
C46 C45 N5 Ru1 177.6(4) . . . . ?
C44 C45 N5 Ru1 -1.7(5) . . . . ?
C27 C26 O2 P3 171.9(4) . . . . ?
C29 C28 O3 P3 164.1(4) . . . . ?
C12 C7 P1 C1 -143.2(4) . . . . ?
C8 C7 P1 C1 44.0(4) . . . . ?
C12 C7 P1 C13 -36.3(5) . . . . ?
C8 C7 P1 C13 150.9(4) . . . . ?
C12 C7 P1 Ru1 86.8(4) . . . . ?
C8 C7 P1 Ru1 -85.9(4) . . . . ?
C2 C1 P1 C7 -118.5(5) . . . . ?
C6 C1 P1 C7 57.7(5) . . . . ?
C2 C1 P1 C13 138.1(4) . . . . ?
C6 C1 P1 C13 -45.8(5) . . . . ?
C2 C1 P1 Ru1 4.0(5) . . . . ?
C6 C1 P1 Ru1 -179.8(4) . . . . ?
P2 C13 P1 C7 -175.2(3) . . . . ?
P2 C13 P1 C1 -71.7(4) . . . . ?
P2 C13 P1 Ru1 65.4(4) . . . . ?
P3 N1 P2 C14 -154.1(4) . . . . ?
P3 N1 P2 C13 -30.8(5) . . . . ?
P3 N1 P2 C20 89.6(4) . . . . ?
C15 C14 P2 N1 -178.6(5) . . . . ?
C19 C14 P2 N1 -0.8(5) . . . . ?
C15 C14 P2 C13 56.1(5) . . . . ?
C19 C14 P2 C13 -126.0(5) . . . . ?
C15 C14 P2 C20 -58.0(5) . . . . ?
C19 C14 P2 C20 119.9(5) . . . . ?
P1 C13 P2 N1 -55.0(4) . . . . ?
P1 C13 P2 C14 67.0(4) . . . . ?
P1 C13 P2 C20 -179.0(3) . . . . ?
C25 C20 P2 N1 87.7(7) . . . . ?
C21 C20 P2 N1 -86.6(5) . . . . ?
C25 C20 P2 C14 -30.1(7) . . . . ?
C21 C20 P2 C14 155.6(5) . . . . ?
C25 C20 P2 C13 -147.5(6) . . . . ?
C21 C20 P2 C13 38.2(6) . . . . ?
Ru1 O1 P3 N1 44.0(4) . . . . ?
Ru1 O1 P3 O3 170.4(3) . . . . ?
Ru1 O1 P3 O2 -75.1(4) . . . . ?
P2 N1 P3 O1 46.3(5) . . . . ?
P2 N1 P3 O3 -74.6(5) . . . . ?
P2 N1 P3 O2 170.3(4) . . . . ?
C28 O3 P3 O1 -175.4(4) . . . . ?
C28 O3 P3 N1 -45.6(5) . . . . ?
C28 O3 P3 O2 66.5(5) . . . . ?
C26 O2 P3 O1 -50.4(5) . . . . ?
C26 O2 P3 N1 -179.1(4) . . . . ?
C26 O2 P3 O3 61.2(5) . . . . ?
C40 N4 Ru1 N5 -178.0(4) . . . . ?
C44 N4 Ru1 N5 0.9(3) . . . . ?
C40 N4 Ru1 N3 -8.1(4) . . . . ?
C44 N4 Ru1 N3 170.7(3) . . . . ?
C40 N4 Ru1 N2 -85.0(4) . . . . ?
C44 N4 Ru1 N2 93.8(4) . . . . ?
C40 N4 Ru1 O1 -149.6(6) . . . . ?
C44 N4 Ru1 O1 29.3(9) . . . . ?
C40 N4 Ru1 P1 94.3(4) . . . . ?
C44 N4 Ru1 P1 -86.9(3) . . . . ?
C49 N5 Ru1 N4 178.6(4) . . . . ?
C45 N5 Ru1 N4 0.5(3) . . . . ?
C49 N5 Ru1 N3 104.2(9) . . . . ?
C45 N5 Ru1 N3 -73.9(10) . . . . ?
C49 N5 Ru1 N2 91.4(4) . . . . ?
C45 N5 Ru1 N2 -86.7(4) . . . . ?
C49 N5 Ru1 O1 4.3(4) . . . . ?
C45 N5 Ru1 O1 -173.9(3) . . . . ?
C49 N5 Ru1 P1 -89.1(4) . . . . ?
C45 N5 Ru1 P1 92.8(3) . . . . ?
C39 N3 Ru1 N4 105.6(4) . . . . ?
C35 N3 Ru1 N4 -75.8(4) . . . . ?
C39 N3 Ru1 N5 178.3(8) . . . . ?
C35 N3 Ru1 N5 -3.1(11) . . . . ?
C39 N3 Ru1 N2 -168.6(5) . . . . ?
C35 N3 Ru1 N2 10.0(4) . . . . ?
C39 N3 Ru1 O1 -81.8(4) . . . . ?
C35 N3 Ru1 O1 96.8(4) . . . . ?
C39 N3 Ru1 P1 11.9(4) . . . . ?
C35 N3 Ru1 P1 -169.5(3) . . . . ?
C30 N2 Ru1 N4 -90.5(4) . . . . ?
C34 N2 Ru1 N4 88.1(4) . . . . ?
C30 N2 Ru1 N5 -11.6(4) . . . . ?
C34 N2 Ru1 N5 167.1(4) . . . . ?
C30 N2 Ru1 N3 170.8(4) . . . . ?
C34 N2 Ru1 N3 -10.6(3) . . . . ?
C30 N2 Ru1 O1 78.7(4) . . . . ?
C34 N2 Ru1 O1 -102.6(4) . . . . ?
C30 N2 Ru1 P1 -151(8) . . . . ?
C34 N2 Ru1 P1 27(9) . . . . ?
P3 O1 Ru1 N4 173.7(6) . . . . ?
P3 O1 Ru1 N5 -158.4(3) . . . . ?
P3 O1 Ru1 N3 31.9(3) . . . . ?
P3 O1 Ru1 N2 109.1(3) . . . . ?
P3 O1 Ru1 P1 -70.2(3) . . . . ?
C7 P1 Ru1 N4 56.5(2) . . . . ?
C1 P1 Ru1 N4 -60.9(2) . . . . ?
C13 P1 Ru1 N4 169.9(2) . . . . ?
C7 P1 Ru1 N5 -22.5(2) . . . . ?
C1 P1 Ru1 N5 -139.8(2) . . . . ?
C13 P1 Ru1 N5 90.9(2) . . . . ?
C7 P1 Ru1 N3 155.1(2) . . . . ?
C1 P1 Ru1 N3 37.7(2) . . . . ?
C13 P1 Ru1 N3 -91.5(2) . . . . ?
C7 P1 Ru1 N2 117(9) . . . . ?
C1 P1 Ru1 N2 0(9) . . . . ?
C13 P1 Ru1 N2 -129(9) . . . . ?
C7 P1 Ru1 O1 -112.8(2) . . . . ?
C1 P1 Ru1 O1 129.8(2) . . . . ?
C13 P1 Ru1 O1 0.6(2) . . . . ?
