#------------------------------------------------------------------------------
#$Date: 2016-03-25 10:37:47 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179757 $
#$URL: svn://www.crystallography.net/cod/cif/7/00/53/7005343.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7005343
loop_
_publ_author_name
'Kühnert, Janett'
'Dusek, Michal'
'Demel, Jan'
'Lang, Heinrich'
'Stepnicka, Petr'
_publ_section_title
;
 Synthesis, coordination and catalytic use of
 1-(diphenylphosphino)-1'-carbamoylferrocenes with pyridyl-containing
 N-substituents.
;
_journal_issue                   26
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              2802
_journal_page_last               2811
_journal_paper_doi               10.1039/b701012e
_journal_year                    2007
_chemical_formula_moiety         'C29 H25 Fe N2 O P'
_chemical_formula_sum            'C29 H25 Fe N2 O P'
_chemical_formula_weight         504.33
_chemical_name_common
;N-((pyrid-2yl)methyl) 1'-
(diphenylphosphino)ferrocenecarboxamide
;
_chemical_name_systematic
;
N-{(pyrid-2yl)methyl} 1'-(diphenylphosphino)ferrocenecarboxamide
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                81.11(2)
_cell_angle_beta                 73.58(4)
_cell_angle_gamma                80.57(3)
_cell_formula_units_Z            2
_cell_length_a                   8.217(4)
_cell_length_b                   11.453(2)
_cell_length_c                   13.079(4)
_cell_measurement_reflns_used    8814
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      26.50
_cell_measurement_theta_min      2.57
_cell_volume                     1157.1(7)
_computing_cell_refinement
;
CrysAlis RED, Oxford Diffraction Ltd.,
Version 1.171.29.5 (release 22-02-2006 CrysAlis171 .NET)
;
_computing_data_collection
;
CrysAlis CCD, Oxford Diffraction Ltd.,
Version 1.171.29.5 (release 22-02-2006 CrysAlis171 .NET)
;
_computing_data_reduction
;
CrysAlis RED, Oxford Diffraction Ltd.,
Version 1.171.29.5 (release 22-02-2006 CrysAlis171 .NET)
;
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SIR-97 (Altomare et al., 1999)'
_diffrn_ambient_temperature      150(2)
_diffrn_detector_area_resol_mean 8.3438
_diffrn_measured_fraction_theta_full 0.987
_diffrn_measured_fraction_theta_max 0.987
_diffrn_measurement_device_type  'Oxford KM4 CCD diffractometer'
_diffrn_measurement_method       'ω and π scans to fill the Ewald sphere'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'Enhance (Mo) X-ray Source'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0428
_diffrn_reflns_av_sigmaI/netI    0.0487
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            15853
_diffrn_reflns_theta_full        26.65
_diffrn_reflns_theta_max         26.65
_diffrn_reflns_theta_min         2.61
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    0.747
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            plate
_exptl_crystal_density_diffrn    1.448
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       orange
_exptl_crystal_F_000             524
_exptl_crystal_size_max          0.35
_exptl_crystal_size_mid          0.17
_exptl_crystal_size_min          0.03
_refine_diff_density_max         0.427
_refine_diff_density_min         -0.266
_refine_diff_density_rms         0.053
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.991
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     311
_refine_ls_number_reflns         4825
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.991
_refine_ls_R_factor_all          0.0424
_refine_ls_R_factor_gt           0.0291
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0396P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0705
_refine_ls_wR_factor_ref         0.0724
_reflns_number_gt                3607
_reflns_number_total             4825
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b701012e.txt
_cod_data_source_block           jk6
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7005343
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Fe Fe 0.43253(3) 0.19524(2) 0.724221(19) 0.02033(9) Uani 1 1 d . . .
P P 0.39633(6) 0.22072(4) 0.46631(3) 0.01987(11) Uani 1 1 d . . .
O O 0.38954(16) 0.19395(11) 1.01492(10) 0.0312(3) Uani 1 1 d . . .
N1 N 0.23719(19) 0.05102(13) 1.00521(12) 0.0242(3) Uani 1 1 d . . .
N2 N -0.14978(19) 0.16501(13) 1.06319(11) 0.0264(3) Uani 1 1 d . . .
H1N H 0.227(2) -0.0015(16) 0.9724(15) 0.031(6) Uiso 1 1 d . . .
C1 C 0.3420(2) 0.27386(14) 0.59665(13) 0.0206(4) Uani 1 1 d . . .
C2 C 0.4178(2) 0.35586(14) 0.63453(14) 0.0257(4) Uani 1 1 d . . .
H2 H 0.5097 0.3954 0.5944 0.031 Uiso 1 1 calc R . .
C3 C 0.3308(3) 0.36735(16) 0.74312(15) 0.0323(5) Uani 1 1 d . . .
H3 H 0.3554 0.4154 0.7865 0.039 Uiso 1 1 calc R . .
C4 C 0.2001(2) 0.29326(16) 0.77410(15) 0.0326(5) Uani 1 1 d . . .
H4 H 0.1233 0.2840 0.8415 0.039 Uiso 1 1 calc R . .
C5 C 0.2063(2) 0.23493(16) 0.68394(14) 0.0265(4) Uani 1 1 d . . .
H5 H 0.1343 0.1809 0.6824 0.032 Uiso 1 1 calc R . .
C6 C 0.4787(2) 0.09666(14) 0.85790(13) 0.0209(4) Uani 1 1 d . . .
C7 C 0.4644(2) 0.02010(14) 0.78566(13) 0.0223(4) Uani 1 1 d . . .
H7 H 0.3851 -0.0336 0.7997 0.027 Uiso 1 1 calc R . .
C8 C 0.5919(2) 0.04015(14) 0.68895(13) 0.0248(4) Uani 1 1 d . . .
H8 H 0.6113 0.0016 0.6282 0.030 Uiso 1 1 calc R . .
C9 C 0.6849(2) 0.12851(15) 0.69995(14) 0.0268(4) Uani 1 1 d . . .
H9 H 0.7756 0.1585 0.6476 0.032 Uiso 1 1 calc R . .
C10 C 0.6165(2) 0.16355(15) 0.80418(14) 0.0246(4) Uani 1 1 d . . .
H10 H 0.6547 0.2202 0.8327 0.030 Uiso 1 1 calc R . .
C11 C 0.3660(2) 0.11784(15) 0.96542(14) 0.0237(4) Uani 1 1 d . . .
C12 C 0.3306(2) 0.35296(14) 0.38159(13) 0.0206(4) Uani 1 1 d . . .
C13 C 0.2322(2) 0.45515(15) 0.42093(14) 0.0245(4) Uani 1 1 d . . .
H13 H 0.2048 0.4620 0.4939 0.029 Uiso 1 1 calc R . .
C14 C 0.1745(2) 0.54700(15) 0.35226(16) 0.0318(5) Uani 1 1 d . . .
H14 H 0.1093 0.6153 0.3793 0.038 Uiso 1 1 calc R . .
C15 C 0.2134(2) 0.53728(17) 0.24418(16) 0.0347(5) Uani 1 1 d . . .
H15 H 0.1743 0.5988 0.1982 0.042 Uiso 1 1 calc R . .
C16 C 0.3106(2) 0.43601(17) 0.20413(15) 0.0338(5) Uani 1 1 d . . .
H16 H 0.3377 0.4294 0.1311 0.041 Uiso 1 1 calc R . .
C17 C 0.3676(2) 0.34460(17) 0.27261(14) 0.0300(4) Uani 1 1 d . . .
H17 H 0.4319 0.2762 0.2452 0.036 Uiso 1 1 calc R . .
C18 C 0.6295(2) 0.21332(14) 0.42384(12) 0.0193(4) Uani 1 1 d . . .
C19 C 0.7187(2) 0.31177(15) 0.40270(14) 0.0257(4) Uani 1 1 d . . .
H19 H 0.6590 0.3881 0.4031 0.031 Uiso 1 1 calc R . .
C20 C 0.8943(2) 0.29693(16) 0.38120(15) 0.0310(4) Uani 1 1 d . . .
H20 H 0.9524 0.3631 0.3680 0.037 Uiso 1 1 calc R . .
C21 C 0.9846(2) 0.18364(17) 0.37914(14) 0.0309(4) Uani 1 1 d . . .
H21 H 1.1029 0.1738 0.3667 0.037 Uiso 1 1 calc R . .
C22 C 0.8996(2) 0.08606(16) 0.39548(14) 0.0282(4) Uani 1 1 d . . .
H22 H 0.9605 0.0102 0.3920 0.034 Uiso 1 1 calc R . .
C23 C 0.7228(2) 0.10073(14) 0.41718(13) 0.0222(4) Uani 1 1 d . . .
H23 H 0.6658 0.0343 0.4274 0.027 Uiso 1 1 calc R . .
C24 C 0.1127(2) 0.07133(15) 1.10672(14) 0.0292(4) Uani 1 1 d . . .
H24A H 0.1717 0.0813 1.1588 0.035 Uiso 1 1 calc R . .
H24B H 0.0520 0.0024 1.1335 0.035 Uiso 1 1 calc R . .
C25 C -0.0137(2) 0.18030(15) 1.09447(13) 0.0227(4) Uani 1 1 d . . .
C26 C -0.2599(2) 0.26187(17) 1.04754(14) 0.0315(4) Uani 1 1 d . . .
H26 H -0.3545 0.2526 1.0253 0.038 Uiso 1 1 calc R . .
C27 C -0.2396(2) 0.37483(16) 1.06280(14) 0.0319(5) Uani 1 1 d . . .
H27 H -0.3188 0.4400 1.0512 0.038 Uiso 1 1 calc R . .
C28 C -0.1004(3) 0.38822(17) 1.09532(16) 0.0363(5) Uani 1 1 d . . .
H28 H -0.0834 0.4630 1.1065 0.044 Uiso 1 1 calc R . .
C29 C 0.0137(2) 0.29031(16) 1.11130(15) 0.0308(4) Uani 1 1 d . . .
H29 H 0.1091 0.2981 1.1334 0.037 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Fe Fe 0.3463 0.8444 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C6 Fe C10 41.20(7) . . ?
C6 Fe C2 149.00(7) . . ?
C10 Fe C2 115.78(8) . . ?
C6 Fe C3 114.84(7) . . ?
C10 Fe C3 104.32(8) . . ?
C2 Fe C3 40.72(7) . . ?
C6 Fe C5 127.83(8) . . ?
C10 Fe C5 164.49(7) . . ?
C2 Fe C5 68.52(8) . . ?
C3 Fe C5 68.62(8) . . ?
C6 Fe C4 105.64(8) . . ?
C10 Fe C4 124.88(8) . . ?
C2 Fe C4 68.34(8) . . ?
C3 Fe C4 40.46(8) . . ?
C5 Fe C4 41.03(7) . . ?
C6 Fe C1 167.47(6) . . ?
C10 Fe C1 151.14(7) . . ?
C2 Fe C1 40.94(7) . . ?
C3 Fe C1 68.98(7) . . ?
C5 Fe C1 40.93(7) . . ?
C4 Fe C1 69.02(8) . . ?
C6 Fe C9 68.69(8) . . ?
C10 Fe C9 40.65(7) . . ?
C2 Fe C9 107.89(8) . . ?
C3 Fe C9 126.15(8) . . ?
C5 Fe C9 154.47(7) . . ?
C4 Fe C9 163.20(8) . . ?
C1 Fe C9 119.63(8) . . ?
C6 Fe C7 40.95(7) . . ?
C10 Fe C7 68.74(7) . . ?
C2 Fe C7 168.53(7) . . ?
C3 Fe C7 150.37(7) . . ?
C5 Fe C7 110.13(8) . . ?
C4 Fe C7 118.67(8) . . ?
C1 Fe C7 130.68(7) . . ?
C9 Fe C7 68.11(8) . . ?
C6 Fe C8 68.29(7) . . ?
C10 Fe C8 68.14(7) . . ?
C2 Fe C8 130.00(7) . . ?
C3 Fe C8 165.49(8) . . ?
C5 Fe C8 121.70(8) . . ?
C4 Fe C8 153.99(8) . . ?
C1 Fe C8 111.23(7) . . ?
C9 Fe C8 40.26(7) . . ?
C7 Fe C8 40.21(7) . . ?
C1 P C18 102.87(9) . . ?
C1 P C12 102.46(8) . . ?
C18 P C12 101.97(8) . . ?
C11 N1 C24 120.68(16) . . ?
C11 N1 H1N 120.7(14) . . ?
C24 N1 H1N 118.6(14) . . ?
C25 N2 C26 117.49(15) . . ?
C2 C1 C5 106.86(16) . . ?
C2 C1 P 130.20(13) . . ?
C5 C1 P 122.94(14) . . ?
C2 C1 Fe 69.06(9) . . ?
C5 C1 Fe 69.32(10) . . ?
P C1 Fe 126.00(9) . . ?
C3 C2 C1 108.88(16) . . ?
C3 C2 Fe 69.87(10) . . ?
C1 C2 Fe 70.00(9) . . ?
C3 C2 H2 125.6 . . ?
C1 C2 H2 125.6 . . ?
Fe C2 H2 126.1 . . ?
C4 C3 C2 108.06(17) . . ?
C4 C3 Fe 69.89(11) . . ?
C2 C3 Fe 69.41(10) . . ?
C4 C3 H3 126.0 . . ?
C2 C3 H3 126.0 . . ?
Fe C3 H3 126.3 . . ?
C3 C4 C5 108.00(17) . . ?
C3 C4 Fe 69.65(11) . . ?
C5 C4 Fe 69.39(11) . . ?
C3 C4 H4 126.0 . . ?
C5 C4 H4 126.0 . . ?
Fe C4 H4 126.5 . . ?
C1 C5 C4 108.20(17) . . ?
C1 C5 Fe 69.76(10) . . ?
C4 C5 Fe 69.58(11) . . ?
C1 C5 H5 125.9 . . ?
C4 C5 H5 125.9 . . ?
Fe C5 H5 126.3 . . ?
C7 C6 C10 107.60(15) . . ?
C7 C6 C11 129.14(16) . . ?
C10 C6 C11 122.97(15) . . ?
C7 C6 Fe 70.33(9) . . ?
C10 C6 Fe 69.48(10) . . ?
C11 C6 Fe 120.79(12) . . ?
C8 C7 C6 107.87(15) . . ?
C8 C7 Fe 70.32(10) . . ?
C6 C7 Fe 68.72(9) . . ?
C8 C7 H7 126.1 . . ?
C6 C7 H7 126.1 . . ?
Fe C7 H7 126.5 . . ?
C7 C8 C9 108.46(16) . . ?
C7 C8 Fe 69.47(10) . . ?
C9 C8 Fe 69.29(10) . . ?
C7 C8 H8 125.8 . . ?
C9 C8 H8 125.8 . . ?
Fe C8 H8 127.1 . . ?
C8 C9 C10 108.23(16) . . ?
C8 C9 Fe 70.46(10) . . ?
C10 C9 Fe 69.11(10) . . ?
C8 C9 H9 125.9 . . ?
C10 C9 H9 125.9 . . ?
Fe C9 H9 126.1 . . ?
C9 C10 C6 107.83(15) . . ?
C9 C10 Fe 70.24(10) . . ?
C6 C10 Fe 69.32(10) . . ?
C9 C10 H10 126.1 . . ?
C6 C10 H10 126.1 . . ?
Fe C10 H10 125.9 . . ?
O C11 N1 122.19(17) . . ?
O C11 C6 121.03(16) . . ?
N1 C11 C6 116.78(16) . . ?
C17 C12 C13 118.41(16) . . ?
C17 C12 P 117.13(13) . . ?
C13 C12 P 124.13(13) . . ?
C14 C13 C12 120.57(17) . . ?
C14 C13 H13 119.7 . . ?
C12 C13 H13 119.7 . . ?
C15 C14 C13 120.14(18) . . ?
C15 C14 H14 119.9 . . ?
C13 C14 H14 119.9 . . ?
C14 C15 C16 119.86(17) . . ?
C14 C15 H15 120.1 . . ?
C16 C15 H15 120.1 . . ?
C17 C16 C15 119.92(19) . . ?
C17 C16 H16 120.0 . . ?
C15 C16 H16 120.0 . . ?
C16 C17 C12 121.10(18) . . ?
C16 C17 H17 119.5 . . ?
C12 C17 H17 119.5 . . ?
C23 C18 C19 118.35(16) . . ?
C23 C18 P 117.02(13) . . ?
C19 C18 P 124.57(13) . . ?
C20 C19 C18 120.58(17) . . ?
C20 C19 H19 119.7 . . ?
C18 C19 H19 119.7 . . ?
C19 C20 C21 120.18(17) . . ?
C19 C20 H20 119.9 . . ?
C21 C20 H20 119.9 . . ?
C22 C21 C20 120.02(17) . . ?
C22 C21 H21 120.0 . . ?
C20 C21 H21 120.0 . . ?
C21 C22 C23 119.89(17) . . ?
C21 C22 H22 120.1 . . ?
C23 C22 H22 120.1 . . ?
C22 C23 C18 120.87(16) . . ?
C22 C23 H23 119.6 . . ?
C18 C23 H23 119.6 . . ?
N1 C24 C25 111.37(14) . . ?
N1 C24 H24A 109.4 . . ?
C25 C24 H24A 109.4 . . ?
N1 C24 H24B 109.4 . . ?
C25 C24 H24B 109.4 . . ?
H24A C24 H24B 108.0 . . ?
N2 C25 C29 122.15(17) . . ?
N2 C25 C24 116.69(15) . . ?
C29 C25 C24 121.13(17) . . ?
N2 C26 C27 123.22(18) . . ?
N2 C26 H26 118.4 . . ?
C27 C26 H26 118.4 . . ?
C28 C27 C26 118.28(18) . . ?
C28 C27 H27 120.9 . . ?
C26 C27 H27 120.9 . . ?
C27 C28 C29 119.29(18) . . ?
C27 C28 H28 120.4 . . ?
C29 C28 H28 120.4 . . ?
C28 C29 C25 119.56(18) . . ?
C28 C29 H29 120.2 . . ?
C25 C29 H29 120.2 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Fe C6 2.0247(17) . ?
Fe C10 2.0269(19) . ?
Fe C2 2.0285(17) . ?
Fe C3 2.0346(18) . ?
Fe C5 2.035(2) . ?
Fe C4 2.038(2) . ?
Fe C1 2.0411(17) . ?
Fe C9 2.042(2) . ?
Fe C7 2.0461(17) . ?
Fe C8 2.0571(18) . ?
P C1 1.8102(18) . ?
P C18 1.8296(19) . ?
P C12 1.8344(17) . ?
O C11 1.232(2) . ?
N1 C11 1.344(2) . ?
N1 C24 1.454(2) . ?
N1 H1N 0.819(18) . ?
N2 C25 1.339(2) . ?
N2 C26 1.340(2) . ?
C1 C2 1.423(2) . ?
C1 C5 1.425(2) . ?
C2 C3 1.414(3) . ?
C2 H2 0.9300 . ?
C3 C4 1.408(3) . ?
C3 H3 0.9300 . ?
C4 C5 1.427(3) . ?
C4 H4 0.9300 . ?
C5 H5 0.9300 . ?
C6 C7 1.424(2) . ?
C6 C10 1.425(2) . ?
C6 C11 1.480(2) . ?
C7 C8 1.411(2) . ?
C7 H7 0.9300 . ?
C8 C9 1.411(2) . ?
C8 H8 0.9300 . ?
C9 C10 1.413(2) . ?
C9 H9 0.9300 . ?
C10 H10 0.9300 . ?
C12 C17 1.386(2) . ?
C12 C13 1.389(2) . ?
C13 C14 1.387(2) . ?
C13 H13 0.9300 . ?
C14 C15 1.376(3) . ?
C14 H14 0.9300 . ?
C15 C16 1.380(3) . ?
C15 H15 0.9300 . ?
C16 C17 1.380(2) . ?
C16 H16 0.9300 . ?
C17 H17 0.9300 . ?
C18 C23 1.389(2) . ?
C18 C19 1.394(2) . ?
C19 C20 1.377(3) . ?
C19 H19 0.9300 . ?
C20 C21 1.385(3) . ?
C20 H20 0.9300 . ?
C21 C22 1.371(3) . ?
C21 H21 0.9300 . ?
C22 C23 1.386(3) . ?
C22 H22 0.9300 . ?
C23 H23 0.9300 . ?
C24 C25 1.506(2) . ?
C24 H24A 0.9700 . ?
C24 H24B 0.9700 . ?
C25 C29 1.376(2) . ?
C26 C27 1.382(3) . ?
C26 H26 0.9300 . ?
C27 C28 1.366(3) . ?
C27 H27 0.9300 . ?
C28 C29 1.369(3) . ?
C28 H28 0.9300 . ?
C29 H29 0.9300 . ?
