#------------------------------------------------------------------------------
#$Date: 2016-03-25 10:41:08 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179759 $
#$URL: svn://www.crystallography.net/cod/cif/7/00/55/7005573.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7005573
loop_
_publ_author_name
'Houghton, Jennifer'
'Dyson, Gavin'
'Douthwaite, Richard E.'
'Whitwood, Adrian C.'
'Kariuki, Benson M.'
_publ_section_title
;
 Structural variation, dynamics, and catalytic application of
 palladium(II) complexes of di-N-heterocyclic carbene-amine ligands.
;
_journal_issue                   28
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              3065
_journal_page_last               3073
_journal_paper_doi               10.1039/b703248j
_journal_year                    2007
_chemical_formula_moiety         'C25 H37 Cl2 N5 Pd'
_chemical_formula_sum            'C25 H37 Cl2 N5 Pd'
_chemical_formula_weight         584.90
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                105.876(2)
_cell_angle_beta                 102.093(2)
_cell_angle_gamma                92.241(2)
_cell_formula_units_Z            4
_cell_length_a                   12.9590(11)
_cell_length_b                   13.4961(11)
_cell_length_c                   16.3190(14)
_cell_measurement_reflns_used    2903
_cell_measurement_temperature    273(2)
_cell_measurement_theta_max      26.10
_cell_measurement_theta_min      2.28
_cell_volume                     2670.2(4)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      273(2)
_diffrn_measured_fraction_theta_full 0.986
_diffrn_measured_fraction_theta_max 0.986
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0433
_diffrn_reflns_av_sigmaI/netI    0.1028
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            19413
_diffrn_reflns_theta_full        28.32
_diffrn_reflns_theta_max         28.32
_diffrn_reflns_theta_min         1.33
_exptl_absorpt_coefficient_mu    0.917
_exptl_absorpt_correction_T_max  0.870
_exptl_absorpt_correction_T_min  0.815
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS v2.03; (Sheldrick)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.455
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1208
_exptl_crystal_size_max          0.2
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.15
_refine_diff_density_max         1.322
_refine_diff_density_min         -0.969
_refine_diff_density_rms         0.130
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.965
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     637
_refine_ls_number_reflns         13121
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.965
_refine_ls_R_factor_all          0.1012
_refine_ls_R_factor_gt           0.0474
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0484P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0986
_refine_ls_wR_factor_ref         0.1171
_reflns_number_gt                8171
_reflns_number_total             13121
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b703248j.txt
_cod_data_source_block           compound12
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7005573
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.3276(4) 0.3076(3) 0.1340(3) 0.0216(10) Uani 1 1 d . . .
C2 C 0.4776(3) 0.3574(3) 0.0991(3) 0.0224(10) Uani 1 1 d . . .
H2 H 0.5253 0.3947 0.0806 0.027 Uiso 1 1 calc R . .
C3 C 0.4949(4) 0.2720(4) 0.1254(3) 0.0249(10) Uani 1 1 d . . .
H3 H 0.5567 0.2390 0.1285 0.030 Uiso 1 1 calc R . .
C4 C 0.3908(4) 0.1569(3) 0.1840(3) 0.0235(10) Uani 1 1 d . . .
H4A H 0.3523 0.1781 0.2299 0.028 Uiso 1 1 calc R . .
H4B H 0.4604 0.1418 0.2105 0.028 Uiso 1 1 calc R . .
C5 C 0.3316(4) 0.0580(3) 0.1160(3) 0.0204(10) Uani 1 1 d . . .
H5A H 0.2786 0.0763 0.0725 0.024 Uiso 1 1 calc R . .
H5B H 0.3813 0.0191 0.0863 0.024 Uiso 1 1 calc R . .
C6 C 0.1836(3) 0.0354(3) 0.1821(3) 0.0201(9) Uani 1 1 d . . .
H6A H 0.2014 0.1076 0.2158 0.024 Uiso 1 1 calc R . .
H6B H 0.1609 -0.0013 0.2198 0.024 Uiso 1 1 calc R . .
C7 C 0.0902(3) 0.0281(3) 0.1050(3) 0.0190(9) Uani 1 1 d . . .
H7A H 0.1170 0.0404 0.0570 0.023 Uiso 1 1 calc R . .
H7B H 0.0538 -0.0413 0.0851 0.023 Uiso 1 1 calc R . .
C8 C -0.0841(3) 0.0756(3) 0.1396(3) 0.0212(10) Uani 1 1 d . . .
H8 H -0.1130 0.0092 0.1338 0.025 Uiso 1 1 calc R . .
C9 C -0.1301(4) 0.1634(3) 0.1607(3) 0.0226(10) Uani 1 1 d . . .
H9 H -0.1971 0.1693 0.1725 0.027 Uiso 1 1 calc R . .
C10 C 0.0322(3) 0.2071(3) 0.1422(3) 0.0169(9) Uani 1 1 d . . .
C11 C 0.3298(4) 0.4763(3) 0.0920(3) 0.0218(10) Uani 1 1 d . . .
C12A C 0.2146(7) 0.4538(7) 0.0336(6) 0.022(2) Uani 0.50 1 d P A 1
H12A H 0.1710 0.4153 0.0575 0.034 Uiso 0.50 1 calc PR A 1
H12B H 0.2160 0.4143 -0.0247 0.034 Uiso 0.50 1 calc PR A 1
H12C H 0.1861 0.5181 0.0323 0.034 Uiso 0.50 1 calc PR A 1
C13A C 0.3962(7) 0.5332(7) 0.0502(7) 0.025(2) Uani 0.50 1 d P A 1
H13A H 0.3630 0.5928 0.0411 0.038 Uiso 0.50 1 calc PR A 1
H13B H 0.4023 0.4881 -0.0050 0.038 Uiso 0.50 1 calc PR A 1
H13C H 0.4656 0.5548 0.0880 0.038 Uiso 0.50 1 calc PR A 1
C14A C 0.3295(8) 0.5426(7) 0.1839(6) 0.027(2) Uani 0.50 1 d P A 1
H14A H 0.3114 0.6104 0.1819 0.040 Uiso 0.50 1 calc PR A 1
H14B H 0.3987 0.5483 0.2213 0.040 Uiso 0.50 1 calc PR A 1
H14C H 0.2783 0.5110 0.2063 0.040 Uiso 0.50 1 calc PR A 1
C12B C 0.3078(10) 0.4571(9) -0.0072(7) 0.046(3) Uani 0.50 1 d P A 2
H12D H 0.2509 0.4029 -0.0352 0.070 Uiso 0.50 1 calc PR A 2
H12E H 0.3705 0.4369 -0.0274 0.070 Uiso 0.50 1 calc PR A 2
H12F H 0.2884 0.5194 -0.0213 0.070 Uiso 0.50 1 calc PR A 2
C13B C 0.4106(10) 0.5654(9) 0.1333(9) 0.050(3) Uani 0.50 1 d P A 2
H13D H 0.3802 0.6276 0.1277 0.075 Uiso 0.50 1 calc PR A 2
H13E H 0.4690 0.5562 0.1050 0.075 Uiso 0.50 1 calc PR A 2
H13F H 0.4356 0.5705 0.1941 0.075 Uiso 0.50 1 calc PR A 2
C14B C 0.2327(10) 0.4947(9) 0.1209(10) 0.055(4) Uani 0.50 1 d P A 2
H14D H 0.1786 0.4396 0.0869 0.083 Uiso 0.50 1 calc PR A 2
H14E H 0.2104 0.5593 0.1134 0.083 Uiso 0.50 1 calc PR A 2
H14F H 0.2443 0.4975 0.1816 0.083 Uiso 0.50 1 calc PR A 2
C15 C -0.0845(4) 0.3549(3) 0.1847(3) 0.0216(10) Uani 1 1 d . . .
C16 C -0.0106(4) 0.4217(3) 0.1551(3) 0.0269(11) Uani 1 1 d . . .
H16A H 0.0604 0.4263 0.1890 0.040 Uiso 1 1 calc R . .
H16B H -0.0335 0.4898 0.1633 0.040 Uiso 1 1 calc R . .
H16C H -0.0124 0.3911 0.0943 0.040 Uiso 1 1 calc R . .
C17 C -0.0720(4) 0.3927(4) 0.2838(3) 0.0295(11) Uani 1 1 d . . .
H17A H -0.1184 0.3491 0.3011 0.044 Uiso 1 1 calc R . .
H17B H -0.0898 0.4627 0.3002 0.044 Uiso 1 1 calc R . .
H17C H 0.0001 0.3901 0.3125 0.044 Uiso 1 1 calc R . .
C18 C -0.1993(4) 0.3572(4) 0.1370(3) 0.0288(11) Uani 1 1 d . . .
H18A H -0.2077 0.3252 0.0755 0.043 Uiso 1 1 calc R . .
H18B H -0.2155 0.4277 0.1467 0.043 Uiso 1 1 calc R . .
H18C H -0.2466 0.3202 0.1591 0.043 Uiso 1 1 calc R . .
C19 C 0.2595(4) -0.1148(3) 0.1063(3) 0.0210(10) Uani 1 1 d . . .
H19A H 0.3258 -0.1404 0.0957 0.025 Uiso 1 1 calc R . .
H19B H 0.2129 -0.1200 0.0501 0.025 Uiso 1 1 calc R . .
C20 C 0.2095(4) -0.1812(3) 0.1508(3) 0.0209(10) Uani 1 1 d . . .
C21 C 0.2516(4) -0.1750(4) 0.2379(3) 0.0276(11) Uani 1 1 d . . .
H21 H 0.3136 -0.1320 0.2678 0.033 Uiso 1 1 calc R . .
C22 C 0.2031(4) -0.2313(4) 0.2809(3) 0.0299(12) Uani 1 1 d . . .
H22 H 0.2323 -0.2259 0.3393 0.036 Uiso 1 1 calc R . .
C23 C 0.1111(4) -0.2958(4) 0.2370(3) 0.0288(11) Uani 1 1 d . . .
H23 H 0.0787 -0.3347 0.2655 0.035 Uiso 1 1 calc R . .
C24 C 0.0679(4) -0.3022(4) 0.1509(3) 0.0304(11) Uani 1 1 d . . .
H24 H 0.0055 -0.3447 0.1211 0.037 Uiso 1 1 calc R . .
C25 C 0.1181(4) -0.2448(3) 0.1087(3) 0.0232(10) Uani 1 1 d . . .
H25 H 0.0887 -0.2498 0.0504 0.028 Uiso 1 1 calc R . .
C26 C 0.6979(4) 0.2464(3) 0.4856(3) 0.0190(9) Uani 1 1 d . . .
C27 C 0.6385(4) 0.3717(4) 0.5809(3) 0.0252(10) Uani 1 1 d . . .
H27 H 0.5937 0.4074 0.6137 0.030 Uiso 1 1 calc R . .
C28 C 0.7373(4) 0.4052(3) 0.5832(3) 0.0234(10) Uani 1 1 d . . .
H28 H 0.7744 0.4683 0.6178 0.028 Uiso 1 1 calc R . .
C29 C 0.8744(4) 0.3398(3) 0.4982(3) 0.0218(10) Uani 1 1 d . . .
H29A H 0.9011 0.4126 0.5182 0.026 Uiso 1 1 calc R . .
H29B H 0.8610 0.3180 0.4348 0.026 Uiso 1 1 calc R . .
C30 C 0.9599(3) 0.2779(3) 0.5344(3) 0.0212(10) Uani 1 1 d . . .
H30A H 0.9977 0.3178 0.5928 0.025 Uiso 1 1 calc R . .
H30B H 0.9267 0.2142 0.5385 0.025 Uiso 1 1 calc R . .
C31 C 0.9915(4) 0.1704(3) 0.3960(3) 0.0207(10) Uani 1 1 d . . .
H31A H 1.0395 0.1670 0.3572 0.025 Uiso 1 1 calc R . .
H31B H 0.9242 0.1879 0.3674 0.025 Uiso 1 1 calc R . .
C32 C 0.9743(3) 0.0628(3) 0.4089(3) 0.0201(10) Uani 1 1 d . . .
H32A H 1.0413 0.0329 0.4153 0.024 Uiso 1 1 calc R . .
H32B H 0.9500 0.0701 0.4624 0.024 Uiso 1 1 calc R . .
C33 C 0.9237(4) -0.0922(3) 0.2773(3) 0.0228(10) Uani 1 1 d . . .
H33 H 0.9911 -0.1137 0.2780 0.027 Uiso 1 1 calc R . .
C34 C 0.8330(4) -0.1377(3) 0.2193(3) 0.0235(10) Uani 1 1 d . . .
H34 H 0.8260 -0.1965 0.1720 0.028 Uiso 1 1 calc R . .
C35 C 0.7915(4) 0.0004(3) 0.3159(3) 0.0187(9) Uani 1 1 d . . .
C36 C 0.5051(4) 0.2172(4) 0.4986(3) 0.0261(11) Uani 1 1 d . . .
C37 C 0.4295(5) 0.2832(5) 0.4554(5) 0.0591(19) Uani 1 1 d . . .
H37A H 0.4340 0.3511 0.4953 0.089 Uiso 1 1 calc R . .
H37B H 0.3581 0.2509 0.4406 0.089 Uiso 1 1 calc R . .
H37C H 0.4494 0.2886 0.4032 0.089 Uiso 1 1 calc R . .
C38 C 0.4784(5) 0.2072(6) 0.5820(4) 0.066(2) Uani 1 1 d . . .
H38A H 0.5284 0.1677 0.6082 0.098 Uiso 1 1 calc R . .
H38B H 0.4081 0.1726 0.5688 0.098 Uiso 1 1 calc R . .
H38C H 0.4815 0.2748 0.6220 0.098 Uiso 1 1 calc R . .
C39 C 0.4973(4) 0.1114(4) 0.4326(4) 0.0416(14) Uani 1 1 d . . .
H39A H 0.5172 0.1192 0.3811 0.062 Uiso 1 1 calc R . .
H39B H 0.4257 0.0795 0.4172 0.062 Uiso 1 1 calc R . .
H39C H 0.5440 0.0686 0.4578 0.062 Uiso 1 1 calc R . .
C40 C 0.6401(4) -0.1023(4) 0.1891(3) 0.0243(10) Uani 1 1 d . . .
C41 C 0.6319(4) -0.0483(4) 0.1184(3) 0.0335(12) Uani 1 1 d . . .
H41A H 0.6462 0.0252 0.1449 0.050 Uiso 1 1 calc R . .
H41B H 0.5617 -0.0639 0.0814 0.050 Uiso 1 1 calc R . .
H41C H 0.6826 -0.0718 0.0840 0.050 Uiso 1 1 calc R . .
C42 C 0.5635(4) -0.0653(4) 0.2461(3) 0.0337(12) Uani 1 1 d . . .
H42A H 0.5774 -0.0927 0.2954 0.051 Uiso 1 1 calc R . .
H42B H 0.4921 -0.0886 0.2129 0.051 Uiso 1 1 calc R . .
H42C H 0.5721 0.0090 0.2665 0.051 Uiso 1 1 calc R . .
C43 C 0.6156(5) -0.2191(4) 0.1457(4) 0.0528(18) Uani 1 1 d . . .
H43A H 0.6638 -0.2423 0.1087 0.079 Uiso 1 1 calc R . .
H43B H 0.5441 -0.2338 0.1111 0.079 Uiso 1 1 calc R . .
H43C H 0.6236 -0.2545 0.1900 0.079 Uiso 1 1 calc R . .
C44 C 1.1376(3) 0.2320(3) 0.5239(3) 0.0252(10) Uani 1 1 d . . .
H44A H 1.1763 0.1966 0.4815 0.030 Uiso 1 1 calc R . .
H44B H 1.1254 0.1861 0.5582 0.030 Uiso 1 1 calc R . .
C45 C 1.2047(3) 0.3299(3) 0.5841(3) 0.0211(10) Uani 1 1 d . . .
C46 C 1.2473(4) 0.3387(4) 0.6708(3) 0.0299(12) Uani 1 1 d . . .
H46 H 1.2310 0.2858 0.6939 0.036 Uiso 1 1 calc R . .
C47 C 1.3145(4) 0.4258(4) 0.7245(3) 0.0346(13) Uani 1 1 d . . .
H47 H 1.3422 0.4310 0.7831 0.042 Uiso 1 1 calc R . .
C48 C 1.3396(4) 0.5040(4) 0.6908(3) 0.0310(12) Uani 1 1 d . . .
H48 H 1.3852 0.5617 0.7263 0.037 Uiso 1 1 calc R . .
C49 C 1.2970(4) 0.4967(4) 0.6042(3) 0.0292(11) Uani 1 1 d . . .
H49 H 1.3138 0.5496 0.5813 0.035 Uiso 1 1 calc R . .
C50 C 1.2290(4) 0.4103(3) 0.5512(3) 0.0261(11) Uani 1 1 d . . .
H50 H 1.1994 0.4064 0.4932 0.031 Uiso 1 1 calc R . .
Cl3 Cl 0.68604(9) 0.20989(8) 0.29305(7) 0.0199(2) Uani 1 1 d . . .
Cl4 Cl 0.76130(9) 0.03249(8) 0.50341(7) 0.0223(2) Uani 1 1 d . . .
Cl1 Cl 0.21826(10) 0.33106(9) 0.29138(7) 0.0272(3) Uani 1 1 d . . .
Cl2 Cl 0.13759(9) 0.20314(9) -0.01130(7) 0.0251(3) Uani 1 1 d . . .
N1 N 0.3748(3) 0.3791(3) 0.1048(2) 0.0216(8) Uani 1 1 d . A .
N2 N 0.4035(3) 0.2431(3) 0.1468(3) 0.0218(8) Uani 1 1 d . . .
N3 N 0.2801(3) -0.0062(3) 0.1583(2) 0.0190(8) Uani 1 1 d . . .
N4 N 0.0146(3) 0.1029(3) 0.1282(2) 0.0188(8) Uani 1 1 d . . .
N5 N -0.0591(3) 0.2443(3) 0.1615(2) 0.0176(8) Uani 1 1 d . . .
N6 N 0.6140(3) 0.2737(3) 0.5209(2) 0.0211(8) Uani 1 1 d . . .
N7 N 0.7742(3) 0.3279(3) 0.5240(2) 0.0193(8) Uani 1 1 d . . .
N8 N 1.0349(3) 0.2533(3) 0.4773(2) 0.0212(8) Uani 1 1 d . . .
N9 N 0.8969(3) -0.0072(3) 0.3358(2) 0.0180(8) Uani 1 1 d . . .
N10 N 0.7519(3) -0.0801(3) 0.2434(2) 0.0188(8) Uani 1 1 d . . .
Pd2 Pd 0.73076(3) 0.11950(3) 0.39681(2) 0.01594(9) Uani 1 1 d . . .
Pd1 Pd 0.17656(3) 0.26958(3) 0.13986(2) 0.01671(9) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pd Pd -0.9988 1.0072 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N2 C1 N1 104.1(4) . . ?
N2 C1 Pd1 120.1(3) . . ?
N1 C1 Pd1 134.8(3) . . ?
C3 C2 N1 107.1(4) . . ?
C3 C2 H2 126.5 . . ?
N1 C2 H2 126.5 . . ?
C2 C3 N2 106.6(4) . . ?
C2 C3 H3 126.7 . . ?
N2 C3 H3 126.7 . . ?
N2 C4 C5 113.2(4) . . ?
N2 C4 H4A 108.9 . . ?
C5 C4 H4A 108.9 . . ?
N2 C4 H4B 108.9 . . ?
C5 C4 H4B 108.9 . . ?
H4A C4 H4B 107.8 . . ?
N3 C5 C4 110.4(4) . . ?
N3 C5 H5A 109.6 . . ?
C4 C5 H5A 109.6 . . ?
N3 C5 H5B 109.6 . . ?
C4 C5 H5B 109.6 . . ?
H5A C5 H5B 108.1 . . ?
N3 C6 C7 115.3(4) . . ?
N3 C6 H6A 108.5 . . ?
C7 C6 H6A 108.5 . . ?
N3 C6 H6B 108.5 . . ?
C7 C6 H6B 108.5 . . ?
H6A C6 H6B 107.5 . . ?
N4 C7 C6 112.2(4) . . ?
N4 C7 H7A 109.2 . . ?
C6 C7 H7A 109.2 . . ?
N4 C7 H7B 109.2 . . ?
C6 C7 H7B 109.2 . . ?
H7A C7 H7B 107.9 . . ?
C9 C8 N4 106.7(4) . . ?
C9 C8 H8 126.6 . . ?
N4 C8 H8 126.6 . . ?
C8 C9 N5 107.4(4) . . ?
C8 C9 H9 126.3 . . ?
N5 C9 H9 126.3 . . ?
N4 C10 N5 104.2(3) . . ?
N4 C10 Pd1 119.5(3) . . ?
N5 C10 Pd1 136.0(3) . . ?
C14B C11 C13B 111.6(8) . . ?
C14B C11 N1 113.9(6) . . ?
C13B C11 N1 109.9(6) . . ?
C14B C11 C13A 133.7(6) . . ?
C13B C11 C13A 50.7(6) . . ?
N1 C11 C13A 112.4(5) . . ?
C14B C11 C14A 58.2(7) . . ?
C13B C11 C14A 61.7(6) . . ?
N1 C11 C14A 104.7(5) . . ?
C13A C11 C14A 110.0(6) . . ?
C14B C11 C12B 109.5(8) . . ?
C13B C11 C12B 108.2(7) . . ?
N1 C11 C12B 103.3(5) . . ?
C13A C11 C12B 58.1(6) . . ?
C14A C11 C12B 152.0(6) . . ?
C14B C11 C12A 53.0(7) . . ?
C13B C11 C12A 137.8(6) . . ?
N1 C11 C12A 112.1(4) . . ?
C13A C11 C12A 107.6(6) . . ?
C14A C11 C12A 110.1(6) . . ?
C12B C11 C12A 58.1(6) . . ?
C11 C12A H12A 109.5 . . ?
C11 C12A H12B 109.5 . . ?
C11 C12A H12C 109.5 . . ?
C11 C13A H13A 109.5 . . ?
C11 C13A H13B 109.5 . . ?
C11 C13A H13C 109.5 . . ?
C11 C14A H14A 109.5 . . ?
C11 C14A H14B 109.5 . . ?
C11 C14A H14C 109.5 . . ?
C11 C12B H12D 109.5 . . ?
C11 C12B H12E 109.5 . . ?
H12D C12B H12E 109.5 . . ?
C11 C12B H12F 109.5 . . ?
H12D C12B H12F 109.5 . . ?
H12E C12B H12F 109.5 . . ?
C11 C13B H13D 109.5 . . ?
C11 C13B H13E 109.5 . . ?
H13D C13B H13E 109.5 . . ?
C11 C13B H13F 109.5 . . ?
H13D C13B H13F 109.5 . . ?
H13E C13B H13F 109.5 . . ?
C11 C14B H14D 109.5 . . ?
C11 C14B H14E 109.5 . . ?
H14D C14B H14E 109.5 . . ?
C11 C14B H14F 109.5 . . ?
H14D C14B H14F 109.5 . . ?
H14E C14B H14F 109.5 . . ?
N5 C15 C16 110.4(4) . . ?
N5 C15 C17 107.8(4) . . ?
C16 C15 C17 110.9(4) . . ?
N5 C15 C18 107.9(4) . . ?
C16 C15 C18 109.1(4) . . ?
C17 C15 C18 110.7(4) . . ?
C15 C16 H16A 109.5 . . ?
C15 C16 H16B 109.5 . . ?
H16A C16 H16B 109.5 . . ?
C15 C16 H16C 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
C15 C17 H17A 109.5 . . ?
C15 C17 H17B 109.5 . . ?
H17A C17 H17B 109.5 . . ?
C15 C17 H17C 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
C15 C18 H18A 109.5 . . ?
C15 C18 H18B 109.5 . . ?
H18A C18 H18B 109.5 . . ?
C15 C18 H18C 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
N3 C19 C20 112.3(4) . . ?
N3 C19 H19A 109.1 . . ?
C20 C19 H19A 109.1 . . ?
N3 C19 H19B 109.1 . . ?
C20 C19 H19B 109.1 . . ?
H19A C19 H19B 107.9 . . ?
C25 C20 C21 118.0(4) . . ?
C25 C20 C19 121.2(4) . . ?
C21 C20 C19 120.7(4) . . ?
C22 C21 C20 121.3(5) . . ?
C22 C21 H21 119.4 . . ?
C20 C21 H21 119.4 . . ?
C21 C22 C23 119.9(5) . . ?
C21 C22 H22 120.1 . . ?
C23 C22 H22 120.1 . . ?
C24 C23 C22 119.5(5) . . ?
C24 C23 H23 120.2 . . ?
C22 C23 H23 120.2 . . ?
C23 C24 C25 119.7(5) . . ?
C23 C24 H24 120.2 . . ?
C25 C24 H24 120.2 . . ?
C20 C25 C24 121.6(4) . . ?
C20 C25 H25 119.2 . . ?
C24 C25 H25 119.2 . . ?
N6 C26 N7 105.4(4) . . ?
N6 C26 Pd2 135.7(3) . . ?
N7 C26 Pd2 119.0(3) . . ?
C28 C27 N6 107.9(4) . . ?
C28 C27 H27 126.0 . . ?
N6 C27 H27 126.0 . . ?
C27 C28 N7 106.8(4) . . ?
C27 C28 H28 126.6 . . ?
N7 C28 H28 126.6 . . ?
N7 C29 C30 113.8(3) . . ?
N7 C29 H29A 108.8 . . ?
C30 C29 H29A 108.8 . . ?
N7 C29 H29B 108.8 . . ?
C30 C29 H29B 108.8 . . ?
H29A C29 H29B 107.7 . . ?
N8 C30 C29 110.4(3) . . ?
N8 C30 H30A 109.6 . . ?
C29 C30 H30A 109.6 . . ?
N8 C30 H30B 109.6 . . ?
C29 C30 H30B 109.6 . . ?
H30A C30 H30B 108.1 . . ?
N8 C31 C32 114.3(4) . . ?
N8 C31 H31A 108.7 . . ?
C32 C31 H31A 108.7 . . ?
N8 C31 H31B 108.7 . . ?
C32 C31 H31B 108.7 . . ?
H31A C31 H31B 107.6 . . ?
N9 C32 C31 112.2(4) . . ?
N9 C32 H32A 109.2 . . ?
C31 C32 H32A 109.2 . . ?
N9 C32 H32B 109.2 . . ?
C31 C32 H32B 109.2 . . ?
H32A C32 H32B 107.9 . . ?
C34 C33 N9 106.6(4) . . ?
C34 C33 H33 126.7 . . ?
N9 C33 H33 126.7 . . ?
C33 C34 N10 107.1(4) . . ?
C33 C34 H34 126.4 . . ?
N10 C34 H34 126.4 . . ?
N9 C35 N10 105.2(4) . . ?
N9 C35 Pd2 118.2(3) . . ?
N10 C35 Pd2 136.5(3) . . ?
N6 C36 C38 108.7(4) . . ?
N6 C36 C39 111.9(4) . . ?
C38 C36 C39 110.8(5) . . ?
N6 C36 C37 106.0(4) . . ?
C38 C36 C37 111.8(5) . . ?
C39 C36 C37 107.7(4) . . ?
C36 C37 H37A 109.5 . . ?
C36 C37 H37B 109.5 . . ?
H37A C37 H37B 109.5 . . ?
C36 C37 H37C 109.5 . . ?
H37A C37 H37C 109.5 . . ?
H37B C37 H37C 109.5 . . ?
C36 C38 H38A 109.5 . . ?
C36 C38 H38B 109.5 . . ?
H38A C38 H38B 109.5 . . ?
C36 C38 H38C 109.5 . . ?
H38A C38 H38C 109.5 . . ?
H38B C38 H38C 109.5 . . ?
C36 C39 H39A 109.5 . . ?
C36 C39 H39B 109.5 . . ?
H39A C39 H39B 109.5 . . ?
C36 C39 H39C 109.5 . . ?
H39A C39 H39C 109.5 . . ?
H39B C39 H39C 109.5 . . ?
N10 C40 C42 110.1(4) . . ?
N10 C40 C41 108.1(4) . . ?
C42 C40 C41 111.1(4) . . ?
N10 C40 C43 109.1(4) . . ?
C42 C40 C43 109.6(4) . . ?
C41 C40 C43 108.7(4) . . ?
C40 C41 H41A 109.5 . . ?
C40 C41 H41B 109.5 . . ?
H41A C41 H41B 109.5 . . ?
C40 C41 H41C 109.5 . . ?
H41A C41 H41C 109.5 . . ?
H41B C41 H41C 109.5 . . ?
C40 C42 H42A 109.5 . . ?
C40 C42 H42B 109.5 . . ?
H42A C42 H42B 109.5 . . ?
C40 C42 H42C 109.5 . . ?
H42A C42 H42C 109.5 . . ?
H42B C42 H42C 109.5 . . ?
C40 C43 H43A 109.5 . . ?
C40 C43 H43B 109.5 . . ?
H43A C43 H43B 109.5 . . ?
C40 C43 H43C 109.5 . . ?
H43A C43 H43C 109.5 . . ?
H43B C43 H43C 109.5 . . ?
N8 C44 C45 112.5(4) . . ?
N8 C44 H44A 109.1 . . ?
C45 C44 H44A 109.1 . . ?
N8 C44 H44B 109.1 . . ?
C45 C44 H44B 109.1 . . ?
H44A C44 H44B 107.8 . . ?
C46 C45 C50 118.6(4) . . ?
C46 C45 C44 121.0(4) . . ?
C50 C45 C44 120.3(4) . . ?
C45 C46 C47 120.9(4) . . ?
C45 C46 H46 119.5 . . ?
C47 C46 H46 119.5 . . ?
C48 C47 C46 119.9(4) . . ?
C48 C47 H47 120.0 . . ?
C46 C47 H47 120.0 . . ?
C47 C48 C49 119.9(5) . . ?
C47 C48 H48 120.1 . . ?
C49 C48 H48 120.1 . . ?
C48 C49 C50 120.0(5) . . ?
C48 C49 H49 120.0 . . ?
C50 C49 H49 120.0 . . ?
C45 C50 C49 120.7(4) . . ?
C45 C50 H50 119.7 . . ?
C49 C50 H50 119.7 . . ?
C1 N1 C2 110.5(4) . . ?
C1 N1 C11 125.6(4) . . ?
C2 N1 C11 123.5(4) . . ?
C1 N2 C3 111.7(4) . . ?
C1 N2 C4 123.7(4) . . ?
C3 N2 C4 124.4(4) . . ?
C19 N3 C5 112.2(3) . . ?
C19 N3 C6 111.8(3) . . ?
C5 N3 C6 112.1(3) . . ?
C10 N4 C8 111.4(4) . . ?
C10 N4 C7 125.1(4) . . ?
C8 N4 C7 123.5(4) . . ?
C10 N5 C9 110.2(4) . . ?
C10 N5 C15 128.1(3) . . ?
C9 N5 C15 121.6(4) . . ?
C26 N6 C27 109.8(4) . . ?
C26 N6 C36 128.9(4) . . ?
C27 N6 C36 121.1(4) . . ?
C26 N7 C28 110.2(4) . . ?
C26 N7 C29 125.2(4) . . ?
C28 N7 C29 124.0(4) . . ?
C31 N8 C44 111.6(4) . . ?
C31 N8 C30 113.2(3) . . ?
C44 N8 C30 112.0(4) . . ?
C35 N9 C33 110.9(4) . . ?
C35 N9 C32 125.9(4) . . ?
C33 N9 C32 123.2(4) . . ?
C35 N10 C34 110.1(4) . . ?
C35 N10 C40 127.3(4) . . ?
C34 N10 C40 122.4(4) . . ?
C26 Pd2 C35 170.09(18) . . ?
C26 Pd2 Cl4 90.24(12) . . ?
C35 Pd2 Cl4 88.51(12) . . ?
C26 Pd2 Cl3 86.68(12) . . ?
C35 Pd2 Cl3 95.19(12) . . ?
Cl4 Pd2 Cl3 175.03(4) . . ?
C1 Pd1 C10 170.48(17) . . ?
C1 Pd1 Cl2 87.67(13) . . ?
C10 Pd1 Cl2 89.96(12) . . ?
C1 Pd1 Cl1 91.91(13) . . ?
C10 Pd1 Cl1 90.15(12) . . ?
Cl2 Pd1 Cl1 178.08(5) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 N2 1.360(6) . ?
C1 N1 1.364(5) . ?
C1 Pd1 2.032(4) . ?
C2 C3 1.346(6) . ?
C2 N1 1.391(6) . ?
C2 H2 0.9300 . ?
C3 N2 1.374(6) . ?
C3 H3 0.9300 . ?
C4 N2 1.471(5) . ?
C4 C5 1.535(6) . ?
C4 H4A 0.9700 . ?
C4 H4B 0.9700 . ?
C5 N3 1.466(5) . ?
C5 H5A 0.9700 . ?
C5 H5B 0.9700 . ?
C6 N3 1.474(5) . ?
C6 C7 1.530(6) . ?
C6 H6A 0.9700 . ?
C6 H6B 0.9700 . ?
C7 N4 1.464(5) . ?
C7 H7A 0.9700 . ?
C7 H7B 0.9700 . ?
C8 C9 1.341(6) . ?
C8 N4 1.381(5) . ?
C8 H8 0.9300 . ?
C9 N5 1.395(5) . ?
C9 H9 0.9300 . ?
C10 N4 1.364(5) . ?
C10 N5 1.366(5) . ?
C10 Pd1 2.034(4) . ?
C11 C14B 1.442(12) . ?
C11 C13B 1.470(12) . ?
C11 N1 1.504(5) . ?
C11 C13A 1.508(10) . ?
C11 C14A 1.523(10) . ?
C11 C12B 1.529(12) . ?
C11 C12A 1.561(9) . ?
C12A H12A 0.9600 . ?
C12A H12B 0.9600 . ?
C12A H12C 0.9600 . ?
C13A H13A 0.9600 . ?
C13A H13B 0.9600 . ?
C13A H13C 0.9600 . ?
C14A H14A 0.9600 . ?
C14A H14B 0.9600 . ?
C14A H14C 0.9600 . ?
C12B H12D 0.9600 . ?
C12B H12E 0.9600 . ?
C12B H12F 0.9600 . ?
C13B H13D 0.9600 . ?
C13B H13E 0.9600 . ?
C13B H13F 0.9600 . ?
C14B H14D 0.9600 . ?
C14B H14E 0.9600 . ?
C14B H14F 0.9600 . ?
C15 N5 1.504(5) . ?
C15 C16 1.526(6) . ?
C15 C17 1.528(6) . ?
C15 C18 1.533(6) . ?
C16 H16A 0.9600 . ?
C16 H16B 0.9600 . ?
C16 H16C 0.9600 . ?
C17 H17A 0.9600 . ?
C17 H17B 0.9600 . ?
C17 H17C 0.9600 . ?
C18 H18A 0.9600 . ?
C18 H18B 0.9600 . ?
C18 H18C 0.9600 . ?
C19 N3 1.460(5) . ?
C19 C20 1.503(6) . ?
C19 H19A 0.9700 . ?
C19 H19B 0.9700 . ?
C20 C25 1.367(6) . ?
C20 C21 1.390(6) . ?
C21 C22 1.379(7) . ?
C21 H21 0.9300 . ?
C22 C23 1.383(7) . ?
C22 H22 0.9300 . ?
C23 C24 1.377(7) . ?
C23 H23 0.9300 . ?
C24 C25 1.392(6) . ?
C24 H24 0.9300 . ?
C25 H25 0.9300 . ?
C26 N6 1.352(6) . ?
C26 N7 1.364(5) . ?
C26 Pd2 2.042(4) . ?
C27 C28 1.331(7) . ?
C27 N6 1.391(6) . ?
C27 H27 0.9300 . ?
C28 N7 1.391(6) . ?
C28 H28 0.9300 . ?
C29 N7 1.463(6) . ?
C29 C30 1.531(6) . ?
C29 H29A 0.9700 . ?
C29 H29B 0.9700 . ?
C30 N8 1.470(6) . ?
C30 H30A 0.9700 . ?
C30 H30B 0.9700 . ?
C31 N8 1.468(5) . ?
C31 C32 1.537(6) . ?
C31 H31A 0.9700 . ?
C31 H31B 0.9700 . ?
C32 N9 1.459(5) . ?
C32 H32A 0.9700 . ?
C32 H32B 0.9700 . ?
C33 C34 1.346(6) . ?
C33 N9 1.385(5) . ?
C33 H33 0.9300 . ?
C34 N10 1.390(6) . ?
C34 H34 0.9300 . ?
C35 N9 1.350(6) . ?
C35 N10 1.356(5) . ?
C35 Pd2 2.079(4) . ?
C36 N6 1.501(6) . ?
C36 C38 1.511(7) . ?
C36 C39 1.521(7) . ?
C36 C37 1.541(7) . ?
C37 H37A 0.9600 . ?
C37 H37B 0.9600 . ?
C37 H37C 0.9600 . ?
C38 H38A 0.9600 . ?
C38 H38B 0.9600 . ?
C38 H38C 0.9600 . ?
C39 H39A 0.9600 . ?
C39 H39B 0.9600 . ?
C39 H39C 0.9600 . ?
C40 N10 1.503(6) . ?
C40 C42 1.508(7) . ?
C40 C41 1.514(6) . ?
C40 C43 1.531(7) . ?
C41 H41A 0.9600 . ?
C41 H41B 0.9600 . ?
C41 H41C 0.9600 . ?
C42 H42A 0.9600 . ?
C42 H42B 0.9600 . ?
C42 H42C 0.9600 . ?
C43 H43A 0.9600 . ?
C43 H43B 0.9600 . ?
C43 H43C 0.9600 . ?
C44 N8 1.469(5) . ?
C44 C45 1.520(6) . ?
C44 H44A 0.9700 . ?
C44 H44B 0.9700 . ?
C45 C46 1.378(6) . ?
C45 C50 1.387(6) . ?
C46 C47 1.394(7) . ?
C46 H46 0.9300 . ?
C47 C48 1.374(7) . ?
C47 H47 0.9300 . ?
C48 C49 1.380(7) . ?
C48 H48 0.9300 . ?
C49 C50 1.390(6) . ?
C49 H49 0.9300 . ?
C50 H50 0.9300 . ?
Cl3 Pd2 2.3378(11) . ?
Cl4 Pd2 2.3298(11) . ?
Cl1 Pd1 2.3189(12) . ?
Cl2 Pd1 2.3187(12) . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N1 C2 C3 N2 -0.2(5) . . . . ?
N2 C4 C5 N3 -154.6(4) . . . . ?
N3 C6 C7 N4 -158.1(3) . . . . ?
N4 C8 C9 N5 0.3(5) . . . . ?
N3 C19 C20 C25 127.6(4) . . . . ?
N3 C19 C20 C21 -48.5(6) . . . . ?
C25 C20 C21 C22 0.2(7) . . . . ?
C19 C20 C21 C22 176.4(4) . . . . ?
C20 C21 C22 C23 0.3(8) . . . . ?
C21 C22 C23 C24 -0.8(8) . . . . ?
C22 C23 C24 C25 0.9(8) . . . . ?
C21 C20 C25 C24 -0.2(7) . . . . ?
C19 C20 C25 C24 -176.3(4) . . . . ?
C23 C24 C25 C20 -0.4(8) . . . . ?
N6 C27 C28 N7 0.3(5) . . . . ?
N7 C29 C30 N8 153.7(4) . . . . ?
N8 C31 C32 N9 158.2(4) . . . . ?
N9 C33 C34 N10 -0.3(5) . . . . ?
N8 C44 C45 C46 127.8(5) . . . . ?
N8 C44 C45 C50 -55.7(6) . . . . ?
C50 C45 C46 C47 -0.8(8) . . . . ?
C44 C45 C46 C47 175.8(5) . . . . ?
C45 C46 C47 C48 -0.5(8) . . . . ?
C46 C47 C48 C49 1.0(8) . . . . ?
C47 C48 C49 C50 -0.2(8) . . . . ?
C46 C45 C50 C49 1.6(7) . . . . ?
C44 C45 C50 C49 -175.0(5) . . . . ?
C48 C49 C50 C45 -1.2(8) . . . . ?
N2 C1 N1 C2 0.7(5) . . . . ?
Pd1 C1 N1 C2 -167.3(4) . . . . ?
N2 C1 N1 C11 -171.4(4) . . . . ?
Pd1 C1 N1 C11 20.6(7) . . . . ?
C3 C2 N1 C1 -0.4(5) . . . . ?
C3 C2 N1 C11 172.0(4) . . . . ?
C14B C11 N1 C1 5.2(9) . . . . ?
C13B C11 N1 C1 131.3(7) . . . . ?
C13A C11 N1 C1 -174.1(6) . . . . ?
C14A C11 N1 C1 66.5(6) . . . . ?
C12B C11 N1 C1 -113.4(7) . . . . ?
C12A C11 N1 C1 -52.8(7) . . . . ?
C14B C11 N1 C2 -166.0(8) . . . . ?
C13B C11 N1 C2 -39.9(8) . . . . ?
C13A C11 N1 C2 14.7(7) . . . . ?
C14A C11 N1 C2 -104.7(6) . . . . ?
C12B C11 N1 C2 75.4(7) . . . . ?
C12A C11 N1 C2 136.0(6) . . . . ?
N1 C1 N2 C3 -0.8(5) . . . . ?
Pd1 C1 N2 C3 169.3(3) . . . . ?
N1 C1 N2 C4 175.8(4) . . . . ?
Pd1 C1 N2 C4 -14.0(6) . . . . ?
C2 C3 N2 C1 0.6(5) . . . . ?
C2 C3 N2 C4 -176.0(4) . . . . ?
C5 C4 N2 C1 83.4(5) . . . . ?
C5 C4 N2 C3 -100.3(5) . . . . ?
C20 C19 N3 C5 178.3(4) . . . . ?
C20 C19 N3 C6 -54.7(5) . . . . ?
C4 C5 N3 C19 -157.4(4) . . . . ?
C4 C5 N3 C6 75.7(4) . . . . ?
C7 C6 N3 C19 -57.6(5) . . . . ?
C7 C6 N3 C5 69.5(5) . . . . ?
N5 C10 N4 C8 -0.8(5) . . . . ?
Pd1 C10 N4 C8 174.8(3) . . . . ?
N5 C10 N4 C7 179.9(4) . . . . ?
Pd1 C10 N4 C7 -4.5(6) . . . . ?
C9 C8 N4 C10 0.3(5) . . . . ?
C9 C8 N4 C7 179.6(4) . . . . ?
C6 C7 N4 C10 72.4(5) . . . . ?
C6 C7 N4 C8 -106.9(5) . . . . ?
N4 C10 N5 C9 1.0(5) . . . . ?
Pd1 C10 N5 C9 -173.5(3) . . . . ?
N4 C10 N5 C15 178.6(4) . . . . ?
Pd1 C10 N5 C15 4.2(7) . . . . ?
C8 C9 N5 C10 -0.9(5) . . . . ?
C8 C9 N5 C15 -178.7(4) . . . . ?
C16 C15 N5 C10 19.2(6) . . . . ?
C17 C15 N5 C10 -102.0(5) . . . . ?
C18 C15 N5 C10 138.4(4) . . . . ?
C16 C15 N5 C9 -163.4(4) . . . . ?
C17 C15 N5 C9 75.4(5) . . . . ?
C18 C15 N5 C9 -44.2(5) . . . . ?
N7 C26 N6 C27 0.0(5) . . . . ?
Pd2 C26 N6 C27 178.8(3) . . . . ?
N7 C26 N6 C36 175.3(4) . . . . ?
Pd2 C26 N6 C36 -5.9(7) . . . . ?
C28 C27 N6 C26 -0.2(5) . . . . ?
C28 C27 N6 C36 -175.9(4) . . . . ?
C38 C36 N6 C26 128.4(5) . . . . ?
C39 C36 N6 C26 5.8(6) . . . . ?
C37 C36 N6 C26 -111.3(5) . . . . ?
C38 C36 N6 C27 -56.7(6) . . . . ?
C39 C36 N6 C27 -179.3(4) . . . . ?
C37 C36 N6 C27 63.6(5) . . . . ?
N6 C26 N7 C28 0.2(5) . . . . ?
Pd2 C26 N7 C28 -178.9(3) . . . . ?
N6 C26 N7 C29 -171.5(4) . . . . ?
Pd2 C26 N7 C29 9.5(5) . . . . ?
C27 C28 N7 C26 -0.3(5) . . . . ?
C27 C28 N7 C29 171.5(4) . . . . ?
C30 C29 N7 C26 -80.5(5) . . . . ?
C30 C29 N7 C28 109.0(5) . . . . ?
C32 C31 N8 C44 58.7(5) . . . . ?
C32 C31 N8 C30 -68.7(5) . . . . ?
C45 C44 N8 C31 156.1(4) . . . . ?
C45 C44 N8 C30 -75.8(5) . . . . ?
C29 C30 N8 C31 -75.2(4) . . . . ?
C29 C30 N8 C44 157.5(4) . . . . ?
N10 C35 N9 C33 -0.8(5) . . . . ?
Pd2 C35 N9 C33 178.0(3) . . . . ?
N10 C35 N9 C32 179.7(4) . . . . ?
Pd2 C35 N9 C32 -1.5(5) . . . . ?
C34 C33 N9 C35 0.7(5) . . . . ?
C34 C33 N9 C32 -179.8(4) . . . . ?
C31 C32 N9 C35 -69.8(5) . . . . ?
C31 C32 N9 C33 110.7(4) . . . . ?
N9 C35 N10 C34 0.6(5) . . . . ?
Pd2 C35 N10 C34 -177.9(3) . . . . ?
N9 C35 N10 C40 -174.0(4) . . . . ?
Pd2 C35 N10 C40 7.6(7) . . . . ?
C33 C34 N10 C35 -0.2(5) . . . . ?
C33 C34 N10 C40 174.7(4) . . . . ?
C42 C40 N10 C35 -31.8(6) . . . . ?
C41 C40 N10 C35 89.7(5) . . . . ?
C43 C40 N10 C35 -152.1(5) . . . . ?
C42 C40 N10 C34 154.3(4) . . . . ?
C41 C40 N10 C34 -84.2(5) . . . . ?
C43 C40 N10 C34 33.9(6) . . . . ?
N6 C26 Pd2 Cl4 -78.2(4) . . . . ?
N7 C26 Pd2 Cl4 100.5(3) . . . . ?
N6 C26 Pd2 Cl3 97.9(4) . . . . ?
N7 C26 Pd2 Cl3 -83.4(3) . . . . ?
N9 C35 Pd2 Cl4 -71.5(3) . . . . ?
N10 C35 Pd2 Cl4 106.8(4) . . . . ?
N9 C35 Pd2 Cl3 111.8(3) . . . . ?
N10 C35 Pd2 Cl3 -69.8(4) . . . . ?
N2 C1 Pd1 Cl2 -96.0(4) . . . . ?
N1 C1 Pd1 Cl2 70.5(5) . . . . ?
N2 C1 Pd1 Cl1 82.1(4) . . . . ?
N1 C1 Pd1 Cl1 -111.4(5) . . . . ?
N4 C10 Pd1 Cl2 74.1(3) . . . . ?
N5 C10 Pd1 Cl2 -112.1(4) . . . . ?
N4 C10 Pd1 Cl1 -104.0(3) . . . . ?
N5 C10 Pd1 Cl1 69.8(4) . . . . ?
