#------------------------------------------------------------------------------
#$Date: 2016-03-25 10:51:43 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179767 $
#$URL: svn://www.crystallography.net/cod/cif/7/00/63/7006379.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7006379
loop_
_publ_author_name
'Adams, Harry'
'Alsindi, Wassim Z.'
'Davies, Graham M.'
'Duriska, Martin B.'
'Easun, Timothy L.'
'Fenton, Hazel E.'
'Herrera, Juan-Manuel'
'George, Michael W.'
'Ronayne, Kate L.'
'Sun, Xue-Zhong'
'Towrie, Michael'
'Ward, Michael D.'
_publ_section_title
;
 New members of the [Ru(diimine)(CN)(4)](2-) family: structural,
 electrochemical and photophysical properties.
;
_journal_issue                   1
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              39
_journal_page_last               50
_journal_paper_doi               10.1039/b509042c
_journal_year                    2006
_chemical_formula_sum            'C48 H70 Eu2 K2 N28 O21 Ru4'
_chemical_formula_weight         2161.72
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                113.599(2)
_cell_angle_beta                 103.578(2)
_cell_angle_gamma                91.274(2)
_cell_formula_units_Z            2
_cell_length_a                   14.0042(16)
_cell_length_b                   16.3639(19)
_cell_length_c                   18.520(2)
_cell_measurement_reflns_used    6381
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      55.020
_cell_measurement_theta_min      4.333
_cell_volume                     3748.2(7)
_computing_cell_refinement       'Bruker smart'
_computing_data_collection       'Bruker smart'
_computing_data_reduction        'Bruker SHELXTL'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      150(2)
_diffrn_detector_area_resol_mean 100
_diffrn_measured_fraction_theta_full 0.963
_diffrn_measured_fraction_theta_max 0.963
_diffrn_measurement_device_type  'Bruker smart1000'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0360
_diffrn_reflns_av_sigmaI/netI    0.0469
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_number            42204
_diffrn_reflns_theta_full        27.54
_diffrn_reflns_theta_max         27.54
_diffrn_reflns_theta_min         1.24
_diffrn_standards_decay_%        0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    2.630
_exptl_absorpt_correction_T_max  0.6783
_exptl_absorpt_correction_T_min  0.4047
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.915
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Block
_exptl_crystal_F_000             2124
_exptl_crystal_size_max          0.42
_exptl_crystal_size_mid          0.22
_exptl_crystal_size_min          0.16
_refine_diff_density_max         2.191
_refine_diff_density_min         -0.967
_refine_diff_density_rms         0.167
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.102
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     946
_refine_ls_number_reflns         16650
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.102
_refine_ls_R_factor_all          0.0512
_refine_ls_R_factor_gt           0.0396
_refine_ls_shift/su_max          0.032
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0313P)²+15.7530P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0907
_refine_ls_wR_factor_ref         0.0952
_reflns_number_gt                13752
_reflns_number_total             16650
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b509042c.txt
_cod_data_source_block           imw123m
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7006379
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.475171(18) 0.694456(16) 0.454203(15) 0.01479(6) Uani 1 1 d . . .
Eu2 Eu 0.535154(18) 0.251561(16) 0.061549(15) 0.01396(6) Uani 1 1 d . . .
Ru1 Ru 0.75015(3) 0.85392(3) 0.35926(2) 0.01302(8) Uani 1 1 d . . .
Ru2 Ru 0.76315(3) 0.33877(3) 0.37120(2) 0.01315(8) Uani 1 1 d . . .
Ru3 Ru 0.25654(3) 0.48141(3) 0.14606(2) 0.01335(8) Uani 1 1 d . . .
Ru4 Ru 0.75802(3) 0.05022(3) -0.12752(2) 0.01581(9) Uani 1 1 d . . .
N1 N 0.8622(3) 0.8523(3) 0.4599(3) 0.0169(9) Uani 1 1 d . . .
N2 N 0.9109(3) 0.9250(3) 0.2918(3) 0.0196(9) Uani 1 1 d . . .
H2N H 0.8695 0.9324 0.2517 0.024 Uiso 1 1 calc R . .
N3 N 0.8832(3) 0.9043(3) 0.3476(3) 0.0170(9) Uani 1 1 d . . .
N4 N 0.6953(4) 1.0466(3) 0.4612(3) 0.0272(11) Uani 1 1 d . . .
N5 N 0.7876(3) 0.6644(3) 0.2344(3) 0.0235(10) Uani 1 1 d . . .
N6 N 0.6018(3) 0.8665(3) 0.2100(3) 0.0262(10) Uani 1 1 d . . .
N7 N 0.5837(3) 0.7639(3) 0.4012(3) 0.0258(10) Uani 1 1 d . . .
N8 N 0.8833(3) 0.3434(3) 0.4699(3) 0.0158(8) Uani 1 1 d . . .
N9 N 0.9079(3) 0.4195(3) 0.2969(3) 0.0179(9) Uani 1 1 d . . .
H9N H 0.8623 0.4239 0.2573 0.021 Uiso 1 1 calc R . .
N10 N 0.8887(3) 0.3943(3) 0.3534(2) 0.0157(8) Uani 1 1 d . . .
N11 N 0.7790(4) 0.1413(3) 0.2459(3) 0.0276(11) Uani 1 1 d . . .
N12 N 0.7040(3) 0.5221(3) 0.4867(3) 0.0222(10) Uani 1 1 d . . .
N13 N 0.6092(3) 0.2600(3) 0.4325(3) 0.0187(9) Uani 1 1 d . . .
N14 N 0.6189(3) 0.3302(3) 0.2107(3) 0.0192(9) Uani 1 1 d . . .
N15 N 0.1558(3) 0.3788(3) 0.0399(3) 0.0177(9) Uani 1 1 d . . .
N16 N 0.0807(3) 0.5921(3) 0.2017(3) 0.0202(9) Uani 1 1 d . . .
H16N H 0.1175 0.6372 0.2455 0.024 Uiso 1 1 calc R . .
N17 N 0.1165(3) 0.5245(3) 0.1503(3) 0.0187(9) Uani 1 1 d . . .
N18 N 0.2447(4) 0.3890(3) 0.2669(3) 0.0257(10) Uani 1 1 d . . .
N19 N 0.2914(3) 0.5906(3) 0.0435(3) 0.0270(10) Uani 1 1 d . . .
N20 N 0.4387(3) 0.3795(3) 0.1126(3) 0.0215(9) Uani 1 1 d . . .
N21 N 0.3846(3) 0.6399(3) 0.3061(3) 0.0176(9) Uani 1 1 d . . .
N22 N 0.8800(3) 0.1339(3) -0.0276(3) 0.0197(9) Uani 1 1 d . . .
N23 N 0.8981(3) -0.0941(3) -0.2090(3) 0.0223(10) Uani 1 1 d . . .
H23N H 0.8518 -0.1334 -0.2504 0.027 Uiso 1 1 calc R . .
N24 N 0.8811(3) -0.0187(3) -0.1508(3) 0.0191(9) Uani 1 1 d . . .
N25 N 0.7101(4) -0.0480(4) -0.0210(3) 0.0328(12) Uani 1 1 d . . .
N26 N 0.7774(4) 0.1428(3) -0.2466(3) 0.0310(11) Uani 1 1 d . . .
N27 N 0.6080(3) 0.1765(3) -0.0560(3) 0.0206(9) Uani 1 1 d . . .
N28 N 0.5884(4) -0.0823(4) -0.2765(3) 0.0365(13) Uani 1 1 d . . .
O1 O 0.3953(3) 0.8183(3) 0.4451(3) 0.0317(10) Uani 1 1 d . . .
H1A H 0.4218 0.8484 0.4247 0.038 Uiso 1 1 d R . .
H1B H 0.3406 0.8361 0.4506 0.038 Uiso 1 1 d R . .
O2 O 0.5954(3) 0.8106(3) 0.5692(2) 0.0352(10) Uani 1 1 d . . .
H2A H 0.5913 0.8163 0.6155 0.042 Uiso 1 1 d R . .
H2B H 0.6163 0.8628 0.5737 0.042 Uiso 1 1 d R . .
O3 O 0.5512(3) 0.6271(3) 0.5456(2) 0.0334(10) Uani 1 1 d . . .
H3A H 0.6140 0.6266 0.5544 0.040 Uiso 1 1 d R . .
H3B H 0.5354 0.6301 0.5876 0.040 Uiso 1 1 d R . .
O4 O 0.5552(3) 0.5723(3) 0.3861(3) 0.0359(10) Uani 1 1 d . . .
H4A H 0.5357 0.5224 0.3858 0.043 Uiso 1 1 d R . .
H4B H 0.5916 0.5612 0.3533 0.043 Uiso 1 1 d R . .
O5 O 0.3419(3) 0.5736(2) 0.4160(2) 0.0277(9) Uani 1 1 d . . .
H5A H 0.3033 0.5476 0.3644 0.033 Uiso 1 1 d R . .
H5B H 0.3316 0.5549 0.4535 0.033 Uiso 1 1 d R . .
O6 N 0.4389(3) 0.2022(3) 0.1364(2) 0.0141(8) Uani 1 1 d . . .
H6A1 H 0.4845 0.1964 0.1826 0.017 Uiso 1 1 d R . .
H6A3 H 0.3951 0.2468 0.1566 0.017 Uiso 1 1 d R . .
O7 O 0.4423(3) 0.1063(3) -0.0222(3) 0.0351(10) Uani 1 1 d . . .
H7AA H 0.3964 0.0986 -0.0016 0.042 Uiso 1 1 d R . .
H7AB H 0.4169 0.1027 -0.0699 0.042 Uiso 1 1 d R . .
O8 O 0.6505(3) 0.1512(2) 0.0971(2) 0.0235(8) Uani 1 1 d . . .
H8AB H 0.6314 0.0973 0.0620 0.028 Uiso 1 1 d R . .
H8AC H 0.7086 0.1674 0.0970 0.028 Uiso 1 1 d R . .
O9 O 0.6615(3) 0.3556(3) 0.0704(2) 0.0273(9) Uani 1 1 d . . .
H9A H 0.7024 0.3881 0.1155 0.033 Uiso 1 1 d R . .
H9B H 0.6765 0.3671 0.0332 0.033 Uiso 1 1 d R . .
O10 O 0.4302(4) 0.2668(3) -0.0505(2) 0.0435(12) Uani 1 1 d . . .
H10A H 0.3691 0.2711 -0.0573 0.052 Uiso 1 1 d R . .
H10B H 0.4523 0.2904 -0.0778 0.052 Uiso 1 1 d R . .
O11 O 0.5308(3) 0.0383(3) 0.1490(2) 0.0274(9) Uani 1 1 d . . .
H11A H 0.4587 0.0266 0.1379 0.033 Uiso 1 1 d R . .
H11C H 0.5475 0.0904 0.1388 0.033 Uiso 1 1 d R . .
O12 O 0.4671(3) 0.9154(3) 0.3708(3) 0.0462(12) Uani 1 1 d . . .
H12A H 0.5304 0.9498 0.3802 0.055 Uiso 1 1 d R . .
H12C H 0.4153 0.9550 0.3754 0.055 Uiso 1 1 d R . .
O13 O 0.5073(4) 0.6244(3) 0.1525(3) 0.0511(13) Uani 1 1 d . . .
H13A H 0.4740 0.5759 0.1077 0.061 Uiso 1 1 d R . .
H13B H 0.5706 0.6236 0.1773 0.061 Uiso 1 1 d R . .
O14 O 0.5844(3) 0.5314(3) 0.2418(3) 0.0323(9) Uani 1 1 d . . .
O15 O 0.7633(3) 0.4879(2) 0.2153(2) 0.0217(8) Uani 1 1 d . . .
O16 O 0.4433(3) 0.3367(3) 0.2916(3) 0.0315(9) Uani 1 1 d . . .
O17 O 0.1927(3) 0.7454(3) 0.3236(3) 0.0296(9) Uani 1 1 d . . .
O18 O 0.7726(3) 0.7532(3) 0.6738(3) 0.0360(10) Uani 1 1 d . . .
O19 O 0.3160(3) 0.0213(3) 0.4061(3) 0.0357(10) Uani 1 1 d . . .
O20 O 0.7702(3) 0.9507(3) 0.1753(3) 0.0312(9) Uani 1 1 d . . .
O21 O 0.3424(3) 0.4049(3) 0.9243(3) 0.0354(10) Uani 1 1 d . . .
K1 K 0.61772(10) 0.07312(9) 0.30881(8) 0.0309(3) Uani 1 1 d . . .
K2 K 0.41746(12) 0.77423(11) 0.21308(12) 0.0482(4) Uani 1 1 d . . .
C1 C 0.8465(4) 0.8293(4) 0.5182(3) 0.0226(11) Uani 1 1 d . . .
H1 H 0.7804 0.8115 0.5158 0.027 Uiso 1 1 calc R . .
C2 C 0.9223(5) 0.8305(4) 0.5818(3) 0.0276(13) Uani 1 1 d . . .
H2 H 0.9083 0.8130 0.6218 0.033 Uiso 1 1 calc R . .
C3 C 1.0186(4) 0.8572(4) 0.5865(3) 0.0275(13) Uani 1 1 d . . .
H3 H 1.0718 0.8597 0.6303 0.033 Uiso 1 1 calc R . .
C4 C 1.0361(4) 0.8802(3) 0.5265(3) 0.0242(12) Uani 1 1 d . . .
H4 H 1.1017 0.8980 0.5279 0.029 Uiso 1 1 calc R . .
C5 C 0.9564(4) 0.8770(3) 0.4637(3) 0.0195(11) Uani 1 1 d . . .
C6 C 0.9674(4) 0.9001(3) 0.3975(3) 0.0191(11) Uani 1 1 d . . .
C7 C 1.0499(4) 0.9178(4) 0.3727(4) 0.0255(12) Uani 1 1 d . . .
H7 H 1.1178 0.9190 0.3975 0.031 Uiso 1 1 calc R . .
C8 C 1.0105(4) 0.9329(3) 0.3048(3) 0.0236(12) Uani 1 1 d . . .
H8 H 1.0466 0.9466 0.2727 0.028 Uiso 1 1 calc R . .
C9 C 0.7201(4) 0.9779(4) 0.4281(3) 0.0179(10) Uani 1 1 d . . .
C10 C 0.7742(4) 0.7314(3) 0.2820(3) 0.0172(10) Uani 1 1 d . . .
C11 C 0.6570(4) 0.8606(3) 0.2647(3) 0.0161(10) Uani 1 1 d . . .
C12 C 0.6429(4) 0.7972(3) 0.3836(3) 0.0181(10) Uani 1 1 d . . .
C13 C 0.8770(4) 0.3220(3) 0.5317(3) 0.0197(11) Uani 1 1 d . . .
H13 H 0.8135 0.3025 0.5334 0.024 Uiso 1 1 calc R . .
C14 C 0.9585(4) 0.3271(3) 0.5926(3) 0.0219(11) Uani 1 1 d . . .
H14 H 0.9509 0.3112 0.6351 0.026 Uiso 1 1 calc R . .
C15 C 1.0520(4) 0.3558(3) 0.5911(3) 0.0250(12) Uani 1 1 d . . .
H15 H 1.1092 0.3595 0.6324 0.030 Uiso 1 1 calc R . .
C16 C 1.0598(4) 0.3786(3) 0.5290(3) 0.0205(11) Uani 1 1 d . . .
H16 H 1.1227 0.3990 0.5269 0.025 Uiso 1 1 calc R . .
C17 C 0.9755(4) 0.3716(3) 0.4695(3) 0.0184(10) Uani 1 1 d . . .
C18 C 0.9769(3) 0.3947(3) 0.4013(3) 0.0153(10) Uani 1 1 d . . .
C19 C 1.0530(4) 0.4206(3) 0.3744(3) 0.0221(11) Uani 1 1 d . . .
H19 H 1.1223 0.4257 0.3970 0.027 Uiso 1 1 calc R . .
C20 C 1.0064(4) 0.4371(3) 0.3090(3) 0.0216(11) Uani 1 1 d . . .
H20 H 1.0376 0.4572 0.2777 0.026 Uiso 1 1 calc R . .
C21 C 0.7806(4) 0.2131(3) 0.2944(3) 0.0160(10) Uani 1 1 d . . .
C22 C 0.7308(4) 0.4589(3) 0.4434(3) 0.0172(10) Uani 1 1 d . . .
C23 C 0.6625(4) 0.2869(3) 0.4052(3) 0.0164(10) Uani 1 1 d . . .
C24 C 0.6682(3) 0.3366(3) 0.2728(3) 0.0150(10) Uani 1 1 d . . .
C25 C 0.1799(4) 0.3071(4) -0.0167(3) 0.0229(11) Uani 1 1 d . . .
H25 H 0.2474 0.2971 -0.0087 0.027 Uiso 1 1 calc R . .
C26 C 0.1120(5) 0.2471(4) -0.0860(3) 0.0296(13) Uani 1 1 d . . .
H26 H 0.1325 0.1972 -0.1247 0.036 Uiso 1 1 calc R . .
C27 C 0.0137(4) 0.2607(4) -0.0984(4) 0.0294(13) Uani 1 1 d . . .
H27 H -0.0345 0.2208 -0.1462 0.035 Uiso 1 1 calc R . .
C28 C -0.0132(4) 0.3330(4) -0.0402(3) 0.0258(12) Uani 1 1 d . . .
H28 H -0.0807 0.3431 -0.0468 0.031 Uiso 1 1 calc R . .
C29 C 0.0587(4) 0.3909(3) 0.0281(3) 0.0199(11) Uani 1 1 d . . .
C30 C 0.0378(4) 0.4696(4) 0.0920(3) 0.0199(11) Uani 1 1 d . . .
C31 C -0.0500(4) 0.5046(4) 0.1082(4) 0.0269(12) Uani 1 1 d . . .
H31 H -0.1162 0.4794 0.0772 0.032 Uiso 1 1 calc R . .
C32 C -0.0193(4) 0.5824(4) 0.1779(4) 0.0284(13) Uani 1 1 d . . .
H32 H -0.0608 0.6223 0.2047 0.034 Uiso 1 1 calc R . .
C33 C 0.2444(4) 0.4189(3) 0.2200(3) 0.0175(10) Uani 1 1 d . . .
C34 C 0.2761(4) 0.5498(3) 0.0788(3) 0.0180(10) Uani 1 1 d . . .
C35 C 0.3735(4) 0.4202(3) 0.1264(3) 0.0173(10) Uani 1 1 d . . .
C36 C 0.3381(3) 0.5824(3) 0.2455(3) 0.0154(10) Uani 1 1 d . . .
C37 C 0.8748(4) 0.2082(4) 0.0368(3) 0.0254(12) Uani 1 1 d . . .
H37 H 0.8123 0.2290 0.0385 0.031 Uiso 1 1 calc R . .
C38 C 0.9559(5) 0.2555(4) 0.1005(4) 0.0306(13) Uani 1 1 d . . .
H38 H 0.9489 0.3074 0.1456 0.037 Uiso 1 1 calc R . .
C39 C 1.0479(5) 0.2271(4) 0.0986(4) 0.0336(14) Uani 1 1 d . . .
H39 H 1.1049 0.2598 0.1419 0.040 Uiso 1 1 calc R . .
C40 C 1.0560(4) 0.1510(4) 0.0333(4) 0.0274(12) Uani 1 1 d . . .
H40 H 1.1183 0.1299 0.0309 0.033 Uiso 1 1 calc R . .
C41 C 0.9710(4) 0.1053(4) -0.0293(3) 0.0217(11) Uani 1 1 d . . .
C42 C 0.9698(4) 0.0226(4) -0.0998(3) 0.0211(11) Uani 1 1 d . . .
C43 C 1.0451(4) -0.0269(4) -0.1262(4) 0.0270(12) Uani 1 1 d . . .
H43 H 1.1144 -0.0124 -0.1016 0.032 Uiso 1 1 calc R . .
C44 C 0.9962(4) -0.1010(4) -0.1953(4) 0.0271(12) Uani 1 1 d . . .
H44 H 1.0261 -0.1487 -0.2277 0.033 Uiso 1 1 calc R . .
C45 C 0.7310(4) -0.0139(4) -0.0596(3) 0.0208(11) Uani 1 1 d . . .
C46 C 0.7750(4) 0.1125(4) -0.2001(3) 0.0203(11) Uani 1 1 d . . .
C47 C 0.6526(4) -0.0347(4) -0.2221(3) 0.0228(11) Uani 1 1 d . . .
C48 C 0.6612(4) 0.1296(3) -0.0865(3) 0.0178(10) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
K K 0.2009 0.2494 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru -1.2594 0.8363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O4 Eu1 O1 144.61(14) . . ?
O4 Eu1 O3 69.60(14) . . ?
O1 Eu1 O3 145.04(14) . . ?
O4 Eu1 O2 110.03(16) . . ?
O1 Eu1 O2 83.96(15) . . ?
O3 Eu1 O2 72.81(15) . . ?
O4 Eu1 O5 82.17(15) . . ?
O1 Eu1 O5 105.81(15) . . ?
O3 Eu1 O5 80.87(15) . . ?
O2 Eu1 O5 144.02(13) . . ?
O4 Eu1 N7 78.05(16) . . ?
O1 Eu1 N7 76.16(15) . . ?
O3 Eu1 N7 118.33(16) . . ?
O2 Eu1 N7 71.23(15) . . ?
O5 Eu1 N7 144.43(14) . . ?
O4 Eu1 N21 75.44(14) . . ?
O1 Eu1 N21 75.44(14) . . ?
O3 Eu1 N21 136.69(14) . . ?
O2 Eu1 N21 145.38(14) . . ?
O5 Eu1 N21 69.59(13) . . ?
N7 Eu1 N21 76.94(14) . . ?
O4 Eu1 N13 137.57(15) . 2_666 ?
O1 Eu1 N13 76.42(14) . 2_666 ?
O3 Eu1 N13 72.97(14) . 2_666 ?
O2 Eu1 N13 76.31(14) . 2_666 ?
O5 Eu1 N13 72.76(13) . 2_666 ?
N7 Eu1 N13 139.17(15) . 2_666 ?
N21 Eu1 N13 123.69(14) . 2_666 ?
O10 Eu2 O9 91.59(16) . . ?
O10 Eu2 O7 74.74(16) . . ?
O9 Eu2 O7 143.86(14) . . ?
O10 Eu2 O6 111.22(16) . . ?
O9 Eu2 O6 146.56(13) . . ?
O7 Eu2 O6 68.35(13) . . ?
O10 Eu2 O8 142.09(13) . . ?
O9 Eu2 O8 94.88(14) . . ?
O7 Eu2 O8 78.25(14) . . ?
O6 Eu2 O8 82.10(13) . . ?
O10 Eu2 N14 144.59(14) . . ?
O9 Eu2 N14 75.61(13) . . ?
O7 Eu2 N14 133.05(14) . . ?
O6 Eu2 N14 71.68(14) . . ?
O8 Eu2 N14 72.78(13) . . ?
O10 Eu2 N20 70.78(15) . . ?
O9 Eu2 N20 88.31(15) . . ?
O7 Eu2 N20 116.89(15) . . ?
O6 Eu2 N20 77.28(14) . . ?
O8 Eu2 N20 146.58(13) . . ?
N14 Eu2 N20 75.88(14) . . ?
O10 Eu2 N27 74.11(15) . . ?
O9 Eu2 N27 72.25(14) . . ?
O7 Eu2 N27 71.85(14) . . ?
O6 Eu2 N27 136.20(13) . . ?
O8 Eu2 N27 72.50(13) . . ?
N14 Eu2 N27 129.63(14) . . ?
N20 Eu2 N27 139.11(14) . . ?
O10 Eu2 H7AA 78.8 . . ?
O9 Eu2 H7AA 160.4 . . ?
O7 Eu2 H7AA 16.7 . . ?
O6 Eu2 H7AA 52.7 . . ?
O8 Eu2 H7AA 83.0 . . ?
N14 Eu2 H7AA 121.7 . . ?
N20 Eu2 H7AA 104.3 . . ?
N27 Eu2 H7AA 88.6 . . ?
O10 Eu2 H7AB 58.9 . . ?
O9 Eu2 H7AB 132.2 . . ?
O7 Eu2 H7AB 16.7 . . ?
O6 Eu2 H7AB 81.2 . . ?
O8 Eu2 H7AB 90.3 . . ?
N14 Eu2 H7AB 149.5 . . ?
N20 Eu2 H7AB 111.9 . . ?
N27 Eu2 H7AB 64.2 . . ?
H7AA Eu2 H7AB 28.8 . . ?
C11 Ru1 C12 91.5(2) . . ?
C11 Ru1 C9 87.38(19) . . ?
C12 Ru1 C9 90.2(2) . . ?
C11 Ru1 C10 87.9(2) . . ?
C12 Ru1 C10 90.9(2) . . ?
C9 Ru1 C10 175.2(2) . . ?
C11 Ru1 N3 99.10(18) . . ?
C12 Ru1 N3 168.79(18) . . ?
C9 Ru1 N3 93.84(18) . . ?
C10 Ru1 N3 85.97(18) . . ?
C11 Ru1 N1 174.81(18) . . ?
C12 Ru1 N1 93.67(19) . . ?
C9 Ru1 N1 92.55(17) . . ?
C10 Ru1 N1 92.04(18) . . ?
N3 Ru1 N1 75.72(16) . . ?
C23 Ru2 C24 94.2(2) . . ?
C23 Ru2 C22 85.2(2) . . ?
C24 Ru2 C22 92.4(2) . . ?
C23 Ru2 C21 90.4(2) . . ?
C24 Ru2 C21 83.99(19) . . ?
C22 Ru2 C21 174.11(19) . . ?
C23 Ru2 N10 169.84(18) . . ?
C24 Ru2 N10 95.97(18) . . ?
C22 Ru2 N10 94.49(18) . . ?
C21 Ru2 N10 90.53(18) . . ?
C23 Ru2 N8 93.96(18) . . ?
C24 Ru2 N8 171.49(18) . . ?
C22 Ru2 N8 90.74(18) . . ?
C21 Ru2 N8 93.48(17) . . ?
N10 Ru2 N8 75.89(16) . . ?
C35 Ru3 C36 91.8(2) . . ?
C35 Ru3 C34 91.2(2) . . ?
C36 Ru3 C34 89.4(2) . . ?
C35 Ru3 C33 88.0(2) . . ?
C36 Ru3 C33 86.84(19) . . ?
C34 Ru3 C33 176.1(2) . . ?
C35 Ru3 N17 169.44(18) . . ?
C36 Ru3 N17 98.60(18) . . ?
C34 Ru3 N17 90.85(18) . . ?
C33 Ru3 N17 90.57(18) . . ?
C35 Ru3 N15 93.79(18) . . ?
C36 Ru3 N15 174.42(18) . . ?
C34 Ru3 N15 90.20(18) . . ?
C33 Ru3 N15 93.65(18) . . ?
N17 Ru3 N15 75.85(16) . . ?
C48 Ru4 C47 91.4(2) . . ?
C48 Ru4 C45 86.9(2) . . ?
C47 Ru4 C45 89.9(2) . . ?
C48 Ru4 C46 91.1(2) . . ?
C47 Ru4 C46 86.8(2) . . ?
C45 Ru4 C46 176.0(2) . . ?
C48 Ru4 N24 169.22(19) . . ?
C47 Ru4 N24 99.32(19) . . ?
C45 Ru4 N24 91.85(19) . . ?
C46 Ru4 N24 90.76(18) . . ?
C48 Ru4 N22 93.17(19) . . ?
C47 Ru4 N22 175.3(2) . . ?
C45 Ru4 N22 89.44(18) . . ?
C46 Ru4 N22 94.09(19) . . ?
N24 Ru4 N22 76.11(17) . . ?
C1 N1 C5 118.0(4) . . ?
C1 N1 Ru1 125.9(4) . . ?
C5 N1 Ru1 116.1(3) . . ?
N3 N2 C8 111.4(4) . . ?
N3 N2 H2N 124.3 . . ?
C8 N2 H2N 124.3 . . ?
C6 N3 N2 105.6(4) . . ?
C6 N3 Ru1 116.6(3) . . ?
N2 N3 Ru1 136.2(3) . . ?
C9 N4 K1 94.3(4) . 1_565 ?
C11 N6 K2 99.2(4) . . ?
C11 N6 K1 90.6(3) . 1_565 ?
K2 N6 K1 110.41(15) . 1_565 ?
C12 N7 Eu1 172.5(4) . . ?
C13 N8 C17 117.0(4) . . ?
C13 N8 Ru2 127.0(3) . . ?
C17 N8 Ru2 116.0(3) . . ?
N10 N9 C20 110.9(4) . . ?
N10 N9 H9N 124.6 . . ?
C20 N9 H9N 124.6 . . ?
C18 N10 N9 106.2(4) . . ?
C18 N10 Ru2 116.6(3) . . ?
N9 N10 Ru2 136.4(3) . . ?
C21 N11 K1 89.0(4) . . ?
C23 N13 Eu1 143.5(4) . 2_666 ?
C23 N13 K1 87.5(3) . . ?
Eu1 N13 K1 128.73(16) 2_666 . ?
C24 N14 Eu2 155.4(4) . . ?
C25 N15 C29 117.4(5) . . ?
C25 N15 Ru3 126.5(4) . . ?
C29 N15 Ru3 116.0(3) . . ?
N17 N16 C32 111.3(5) . . ?
N17 N16 H16N 124.4 . . ?
C32 N16 H16N 124.4 . . ?
N16 N17 C30 106.6(4) . . ?
N16 N17 Ru3 136.3(3) . . ?
C30 N17 Ru3 116.8(3) . . ?
C34 N19 K2 95.1(4) . . ?
C35 N20 Eu2 161.7(4) . . ?
C36 N21 Eu1 149.6(4) . . ?
C36 N21 K2 92.9(3) . . ?
Eu1 N21 K2 116.98(15) . . ?
C37 N22 C41 117.7(5) . . ?
C37 N22 Ru4 126.4(4) . . ?
C41 N22 Ru4 115.8(3) . . ?
N24 N23 C44 110.6(5) . . ?
N24 N23 H23N 124.7 . . ?
C44 N23 H23N 124.7 . . ?
C42 N24 N23 106.3(4) . . ?
C42 N24 Ru4 116.5(3) . . ?
N23 N24 Ru4 137.0(3) . . ?
C46 N26 K2 87.9(4) . 2_665 ?
C48 N27 Eu2 151.4(4) . . ?
C48 N27 K2 82.6(3) . 2_665 ?
Eu2 N27 K2 125.50(16) . 2_665 ?
C47 N28 K1 129.8(4) . 2_655 ?
Eu1 O1 H1A 116.2 . . ?
Eu1 O1 H1B 134.7 . . ?
H1A O1 H1B 108.3 . . ?
Eu1 O2 H2A 115.0 . . ?
Eu1 O2 H2B 127.7 . . ?
H2A O2 H2B 107.6 . . ?
Eu1 O3 H3A 116.6 . . ?
Eu1 O3 H3B 126.7 . . ?
H3A O3 H3B 107.9 . . ?
Eu1 O4 H4A 114.7 . . ?
Eu1 O4 H4B 136.7 . . ?
H4A O4 H4B 107.4 . . ?
Eu1 O5 H5A 119.9 . . ?
Eu1 O5 H5B 120.1 . . ?
H5A O5 H5B 120.0 . . ?
Eu2 O6 H6A1 109.4 . . ?
Eu2 O6 H6A3 109.4 . . ?
H6A1 O6 H6A3 109.5 . . ?
Eu2 O7 H7AA 109.3 . . ?
Eu2 O7 H7AB 109.4 . . ?
H7AA O7 H7AB 109.5 . . ?
Eu2 O8 H8AB 109.4 . . ?
Eu2 O8 H8AC 109.3 . . ?
H8AB O8 H8AC 109.5 . . ?
Eu2 O9 H9A 121.4 . . ?
Eu2 O9 H9B 130.4 . . ?
H9A O9 H9B 108.2 . . ?
Eu2 O10 H10A 125.6 . . ?
Eu2 O10 H10B 121.6 . . ?
H10A O10 H10B 108.2 . . ?
K1 O11 H11A 109.4 . . ?
K1 O11 H11C 109.4 . . ?
H11A O11 H11C 109.5 . . ?
K2 O12 H12A 109.4 . . ?
K2 O12 H12C 109.4 . . ?
H12A O12 H12C 109.5 . . ?
K2 O13 H13A 120.3 . . ?
K2 O13 H13B 119.8 . . ?
H13A O13 H13B 120.0 . . ?
O11 K1 N28 66.93(14) . 2_655 ?
O11 K1 N4 161.34(13) . 1_545 ?
N28 K1 N4 111.78(15) 2_655 1_545 ?
O11 K1 N13 115.62(12) . . ?
N28 K1 N13 78.14(14) 2_655 . ?
N4 K1 N13 81.23(13) 1_545 . ?
O11 K1 N6 73.47(12) . 1_545 ?
N28 K1 N6 96.26(15) 2_655 1_545 ?
N4 K1 N6 88.43(13) 1_545 1_545 ?
N13 K1 N6 165.30(13) . 1_545 ?
O11 K1 N11 73.71(12) . . ?
N28 K1 N11 130.16(15) 2_655 . ?
N4 K1 N11 115.17(14) 1_545 . ?
N13 K1 N11 93.15(12) . . ?
N6 K1 N11 100.73(13) 1_545 . ?
O11 K1 C23 106.21(13) . . ?
N28 K1 C23 90.66(15) 2_655 . ?
N4 K1 C23 92.34(13) 1_545 . ?
N13 K1 C23 21.31(12) . . ?
N6 K1 C23 172.21(14) 1_545 . ?
N11 K1 C23 71.94(13) . . ?
O11 K1 C9 142.72(13) . 1_545 ?
N28 K1 C9 119.82(15) 2_655 1_545 ?
N4 K1 C9 20.52(13) 1_545 1_545 ?
N13 K1 C9 101.39(13) . 1_545 ?
N6 K1 C9 69.38(13) 1_545 1_545 ?
N11 K1 C9 110.02(13) . 1_545 ?
C23 K1 C9 110.15(13) . 1_545 ?
O11 K1 C21 83.94(12) . . ?
N28 K1 C21 123.84(15) 2_655 . ?
N4 K1 C21 109.93(13) 1_545 . ?
N13 K1 C21 72.87(12) . . ?
N6 K1 C21 120.84(13) 1_545 . ?
N11 K1 C21 20.30(12) . . ?
C23 K1 C21 51.72(13) . . ?
C9 K1 C21 112.50(12) 1_545 . ?
O11 K1 C11 93.25(12) . 1_545 ?
N28 K1 C11 109.26(15) 2_655 1_545 ?
N4 K1 C11 69.23(13) 1_545 1_545 ?
N13 K1 C11 150.27(13) . 1_545 ?
N6 K1 C11 20.41(12) 1_545 1_545 ?
N11 K1 C11 102.14(12) . 1_545 ?
C23 K1 C11 156.56(13) . 1_545 ?
C9 K1 C11 49.47(13) 1_545 1_545 ?
C21 K1 C11 119.76(13) . 1_545 ?
O11 K1 K2 78.94(9) . 1_545 ?
N28 K1 K2 67.30(12) 2_655 1_545 ?
N4 K1 K2 83.50(10) 1_545 1_545 ?
N13 K1 K2 133.35(9) . 1_545 ?
N6 K1 K2 34.00(9) 1_545 1_545 ?
N11 K1 K2 133.03(10) . 1_545 ?
C23 K1 K2 153.77(10) . 1_545 ?
C9 K1 K2 72.20(9) 1_545 1_545 ?
C21 K1 K2 153.21(10) . 1_545 ?
C11 K1 K2 42.01(9) 1_545 1_545 ?
O13 K2 O12 129.31(16) . . ?
O13 K2 N6 82.74(15) . . ?
O12 K2 N6 79.83(14) . . ?
O13 K2 N26 148.28(16) . 2_665 ?
O12 K2 N26 71.78(14) . 2_665 ?
N6 K2 N26 127.81(14) . 2_665 ?
O13 K2 N27 96.00(14) . 2_665 ?
O12 K2 N27 118.69(13) . 2_665 ?
N6 K2 N27 65.98(12) . 2_665 ?
N26 K2 N27 90.60(13) 2_665 2_665 ?
O13 K2 C48 115.57(15) . 2_665 ?
O12 K2 C48 105.41(14) . 2_665 ?
N6 K2 C48 75.55(13) . 2_665 ?
N26 K2 C48 71.29(13) 2_665 2_665 ?
N27 K2 C48 20.23(11) 2_665 2_665 ?
O13 K2 C46 150.69(16) . 2_665 ?
O12 K2 C46 79.18(14) . 2_665 ?
N6 K2 C46 112.94(14) . 2_665 ?
N26 K2 C46 20.42(13) 2_665 2_665 ?
N27 K2 C46 70.62(13) 2_665 2_665 ?
C48 K2 C46 50.98(13) 2_665 2_665 ?
O13 K2 N21 71.06(13) . . ?
O12 K2 N21 85.75(13) . . ?
N6 K2 N21 131.00(13) . . ?
N26 K2 N21 90.00(12) 2_665 . ?
N27 K2 N21 154.34(12) 2_665 . ?
C48 K2 N21 153.21(12) 2_665 . ?
C46 K2 N21 109.78(12) 2_665 . ?
O13 K2 C11 77.46(14) . . ?
O12 K2 C11 70.26(13) . . ?
N6 K2 C11 19.87(12) . . ?
N26 K2 C11 134.09(13) 2_665 . ?
N27 K2 C11 85.72(12) 2_665 . ?
C48 K2 C11 95.02(13) 2_665 . ?
C46 K2 C11 125.37(13) 2_665 . ?
N21 K2 C11 111.74(12) . . ?
O13 K2 N19 59.72(14) . . ?
O12 K2 N19 160.89(14) . . ?
N6 K2 N19 119.25(13) . . ?
N26 K2 N19 93.43(13) 2_665 . ?
N27 K2 N19 72.23(12) 2_665 . ?
C48 K2 N19 80.12(12) 2_665 . ?
C46 K2 N19 91.07(13) 2_665 . ?
N21 K2 N19 82.13(11) . . ?
C11 K2 N19 128.14(12) . . ?
O13 K2 K1 117.39(12) . 1_565 ?
O12 K2 K1 52.19(10) . 1_565 ?
N6 K2 K1 35.59(9) . 1_565 ?
N26 K2 K1 94.18(10) 2_665 1_565 ?
N27 K2 K1 72.30(8) 2_665 1_565 ?
C48 K2 K1 69.01(9) 2_665 1_565 ?
C46 K2 K1 84.15(10) 2_665 1_565 ?
N21 K2 K1 133.22(9) . 1_565 ?
C11 K2 K1 41.36(8) . 1_565 ?
N19 K2 K1 143.74(9) . 1_565 ?
N1 C1 C2 122.8(5) . . ?
N1 C1 H1 118.6 . . ?
C2 C1 H1 118.6 . . ?
C3 C2 C1 119.2(5) . . ?
C3 C2 H2 120.4 . . ?
C1 C2 H2 120.4 . . ?
C4 C3 C2 118.7(5) . . ?
C4 C3 H3 120.7 . . ?
C2 C3 H3 120.7 . . ?
C3 C4 C5 119.3(5) . . ?
C3 C4 H4 120.4 . . ?
C5 C4 H4 120.4 . . ?
N1 C5 C4 122.0(5) . . ?
N1 C5 C6 114.7(4) . . ?
C4 C5 C6 123.3(5) . . ?
N3 C6 C7 110.8(5) . . ?
N3 C6 C5 116.0(4) . . ?
C7 C6 C5 133.2(5) . . ?
C8 C7 C6 104.6(5) . . ?
C8 C7 H7 127.7 . . ?
C6 C7 H7 127.7 . . ?
N2 C8 C7 107.6(5) . . ?
N2 C8 H8 126.2 . . ?
C7 C8 H8 126.2 . . ?
N4 C9 Ru1 173.5(5) . . ?
N4 C9 K1 65.2(3) . 1_565 ?
Ru1 C9 K1 109.60(19) . 1_565 ?
N5 C10 Ru1 175.4(4) . . ?
N6 C11 Ru1 178.6(5) . . ?
N6 C11 K1 69.0(3) . 1_565 ?
Ru1 C11 K1 109.62(19) . 1_565 ?
N6 C11 K2 61.0(3) . . ?
Ru1 C11 K2 119.3(2) . . ?
K1 C11 K2 96.63(13) 1_565 . ?
N7 C12 Ru1 176.4(5) . . ?
N8 C13 C14 122.9(5) . . ?
N8 C13 H13 118.5 . . ?
C14 C13 H13 118.5 . . ?
C13 C14 C15 119.3(5) . . ?
C13 C14 H14 120.3 . . ?
C15 C14 H14 120.3 . . ?
C16 C15 C14 118.6(5) . . ?
C16 C15 H15 120.7 . . ?
C14 C15 H15 120.7 . . ?
C15 C16 C17 119.4(5) . . ?
C15 C16 H16 120.3 . . ?
C17 C16 H16 120.3 . . ?
N8 C17 C16 122.7(5) . . ?
N8 C17 C18 114.2(4) . . ?
C16 C17 C18 123.1(5) . . ?
N10 C18 C19 109.9(4) . . ?
N10 C18 C17 116.5(4) . . ?
C19 C18 C17 133.5(5) . . ?
C20 C19 C18 105.4(5) . . ?
C20 C19 H19 127.3 . . ?
C18 C19 H19 127.3 . . ?
N9 C20 C19 107.6(5) . . ?
N9 C20 H20 126.2 . . ?
C19 C20 H20 126.2 . . ?
N11 C21 Ru2 171.9(4) . . ?
N11 C21 K1 70.7(3) . . ?
Ru2 C21 K1 105.55(18) . . ?
N12 C22 Ru2 171.8(4) . . ?
N13 C23 Ru2 173.6(4) . . ?
N13 C23 K1 71.1(3) . . ?
Ru2 C23 K1 112.24(19) . . ?
N14 C24 Ru2 173.0(4) . . ?
N15 C25 C26 123.4(5) . . ?
N15 C25 H25 118.3 . . ?
C26 C25 H25 118.3 . . ?
C25 C26 C27 118.9(5) . . ?
C25 C26 H26 120.5 . . ?
C27 C26 H26 120.5 . . ?
C26 C27 C28 118.7(5) . . ?
C26 C27 H27 120.6 . . ?
C28 C27 H27 120.6 . . ?
C27 C28 C29 119.4(5) . . ?
C27 C28 H28 120.3 . . ?
C29 C28 H28 120.3 . . ?
N15 C29 C28 122.1(5) . . ?
N15 C29 C30 114.4(4) . . ?
C28 C29 C30 123.5(5) . . ?
N17 C30 C31 109.3(5) . . ?
N17 C30 C29 116.6(5) . . ?
C31 C30 C29 134.1(5) . . ?
C32 C31 C30 105.3(5) . . ?
C32 C31 H31 127.3 . . ?
C30 C31 H31 127.3 . . ?
N16 C32 C31 107.5(5) . . ?
N16 C32 H32 126.2 . . ?
C31 C32 H32 126.2 . . ?
N18 C33 Ru3 173.8(4) . . ?
N19 C34 Ru3 176.7(5) . . ?
N20 C35 Ru3 176.0(4) . . ?
N21 C36 Ru3 176.9(4) . . ?
N22 C37 C38 122.8(5) . . ?
N22 C37 H37 118.6 . . ?
C38 C37 H37 118.6 . . ?
C37 C38 C39 119.5(6) . . ?
C37 C38 H38 120.2 . . ?
C39 C38 H38 120.2 . . ?
C40 C39 C38 119.2(5) . . ?
C40 C39 H39 120.4 . . ?
C38 C39 H39 120.4 . . ?
C39 C40 C41 118.7(6) . . ?
C39 C40 H40 120.6 . . ?
C41 C40 H40 120.6 . . ?
N22 C41 C40 122.0(5) . . ?
N22 C41 C42 114.3(5) . . ?
C40 C41 C42 123.6(5) . . ?
N24 C42 C43 110.4(5) . . ?
N24 C42 C41 116.9(5) . . ?
C43 C42 C41 132.7(5) . . ?
C44 C43 C42 104.7(5) . . ?
C44 C43 H43 127.6 . . ?
C42 C43 H43 127.6 . . ?
N23 C44 C43 108.0(5) . . ?
N23 C44 H44 126.0 . . ?
C43 C44 H44 126.0 . . ?
N25 C45 Ru4 175.6(5) . . ?
N26 C46 Ru4 173.9(5) . . ?
N26 C46 K2 71.6(4) . 2_665 ?
Ru4 C46 K2 106.16(19) . 2_665 ?
N28 C47 Ru4 177.5(5) . . ?
N27 C48 Ru4 174.3(5) . . ?
N27 C48 K2 77.2(3) . 2_665 ?
Ru4 C48 K2 108.07(19) . 2_665 ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O4 2.363(4) . ?
Eu1 O1 2.382(4) . ?
Eu1 O3 2.431(4) . ?
Eu1 O2 2.432(4) . ?
Eu1 O5 2.448(4) . ?
Eu1 N7 2.467(5) . ?
Eu1 N21 2.507(4) . ?
Eu1 N13 2.511(4) 2_666 ?
Eu2 O10 2.351(4) . ?
Eu2 O9 2.359(4) . ?
Eu2 O7 2.390(4) . ?
Eu2 O6 2.473(4) . ?
Eu2 O8 2.495(4) . ?
Eu2 N14 2.496(4) . ?
Eu2 N20 2.498(4) . ?
Eu2 N27 2.499(4) . ?
Eu2 H7AA 2.7894 . ?
Eu2 H7AB 2.7894 . ?
Ru1 C11 1.966(5) . ?
Ru1 C12 1.977(5) . ?
Ru1 C9 2.035(5) . ?
Ru1 C10 2.034(5) . ?
Ru1 N3 2.112(4) . ?
Ru1 N1 2.146(4) . ?
Ru2 C23 1.973(5) . ?
Ru2 C24 1.974(5) . ?
Ru2 C22 2.019(5) . ?
Ru2 C21 2.038(5) . ?
Ru2 N10 2.114(4) . ?
Ru2 N8 2.149(4) . ?
Ru3 C35 1.969(5) . ?
Ru3 C36 1.980(5) . ?
Ru3 C34 2.036(5) . ?
Ru3 C33 2.043(5) . ?
Ru3 N17 2.107(4) . ?
Ru3 N15 2.150(4) . ?
Ru4 C48 1.968(5) . ?
Ru4 C47 1.981(5) . ?
Ru4 C45 2.022(5) . ?
Ru4 C46 2.033(5) . ?
Ru4 N24 2.115(4) . ?
Ru4 N22 2.145(4) . ?
N1 C1 1.337(7) . ?
N1 C5 1.350(7) . ?
N2 N3 1.341(6) . ?
N2 C8 1.353(7) . ?
N2 H2N 0.8800 . ?
N3 C6 1.339(6) . ?
N4 C9 1.151(7) . ?
N4 K1 2.981(5) 1_565 ?
N5 C10 1.153(7) . ?
N6 C11 1.161(7) . ?
N6 K2 2.986(5) . ?
N6 K1 3.107(5) 1_565 ?
N7 C12 1.158(7) . ?
N8 C13 1.343(6) . ?
N8 C17 1.365(7) . ?
N9 N10 1.345(6) . ?
N9 C20 1.350(7) . ?
N9 H9N 0.8800 . ?
N10 C18 1.338(6) . ?
N11 C21 1.154(7) . ?
N11 K1 3.141(5) . ?
N12 C22 1.160(7) . ?
N13 C23 1.162(6) . ?
N13 Eu1 2.511(4) 2_666 ?
N13 K1 3.025(4) . ?
N14 C24 1.157(6) . ?
N15 C25 1.338(7) . ?
N15 C29 1.358(7) . ?
N16 N17 1.338(6) . ?
N16 C32 1.351(7) . ?
N16 H16N 0.8800 . ?
N17 C30 1.344(7) . ?
N18 C33 1.156(7) . ?
N19 C34 1.151(7) . ?
N19 K2 3.408(5) . ?
N20 C35 1.160(7) . ?
N21 C36 1.163(6) . ?
N21 K2 3.371(4) . ?
N22 C37 1.338(7) . ?
N22 C41 1.370(7) . ?
N23 N24 1.345(6) . ?
N23 C44 1.354(7) . ?
N23 H23N 0.8800 . ?
N24 C42 1.339(7) . ?
N25 C45 1.148(7) . ?
N26 C46 1.160(7) . ?
N26 K2 3.155(5) 2_665 ?
N27 C48 1.157(7) . ?
N27 K2 3.263(5) 2_665 ?
N28 C47 1.160(7) . ?
N28 K1 2.827(5) 2_655 ?
O1 H1A 0.8533 . ?
O1 H1B 0.8399 . ?
O2 H2A 0.8406 . ?
O2 H2B 0.8607 . ?
O3 H3A 0.8564 . ?
O3 H3B 0.8413 . ?
O4 H4A 0.8533 . ?
O4 H4B 0.8506 . ?
O5 H5A 0.9000 . ?
O5 H5B 0.9001 . ?
O6 H6A1 0.9800 . ?
O6 H6A3 0.9800 . ?
O7 H7AA 0.8500 . ?
O7 H7AB 0.8500 . ?
O8 H8AB 0.8502 . ?
O8 H8AC 0.8501 . ?
O9 H9A 0.8454 . ?
O9 H9B 0.8497 . ?
O10 H10A 0.8438 . ?
O10 H10B 0.8510 . ?
O11 K1 2.737(4) . ?
O11 H11A 0.9800 . ?
O11 H11C 0.9800 . ?
O12 K2 2.815(6) . ?
O12 H12A 0.9800 . ?
O12 H12C 0.9801 . ?
O13 K2 2.730(5) . ?
O13 H13A 0.9000 . ?
O13 H13B 0.9001 . ?
K1 N28 2.827(5) 2_655 ?
K1 N4 2.981(5) 1_545 ?
K1 N6 3.107(5) 1_545 ?
K1 C23 3.193(5) . ?
K1 C9 3.276(5) 1_545 ?
K1 C21 3.327(5) . ?
K1 C11 3.329(5) 1_545 ?
K1 K2 5.004(2) 1_545 ?
K2 N26 3.155(5) 2_665 ?
K2 N27 3.263(5) 2_665 ?
K2 C48 3.318(5) 2_665 ?
K2 C46 3.322(5) 2_665 ?
K2 C11 3.372(5) . ?
K2 K1 5.004(2) 1_565 ?
C1 C2 1.381(8) . ?
C1 H1 0.9500 . ?
C2 C3 1.381(9) . ?
C2 H2 0.9500 . ?
C3 C4 1.376(8) . ?
C3 H3 0.9500 . ?
C4 C5 1.392(7) . ?
C4 H4 0.9500 . ?
C5 C6 1.458(8) . ?
C6 C7 1.403(7) . ?
C7 C8 1.370(8) . ?
C7 H7 0.9500 . ?
C8 H8 0.9500 . ?
C9 K1 3.276(5) 1_565 ?
C11 K1 3.329(5) 1_565 ?
C13 C14 1.378(7) . ?
C13 H13 0.9500 . ?
C14 C15 1.390(8) . ?
C14 H14 0.9500 . ?
C15 C16 1.371(8) . ?
C15 H15 0.9500 . ?
C16 C17 1.380(7) . ?
C16 H16 0.9500 . ?
C17 C18 1.461(7) . ?
C18 C19 1.400(7) . ?
C19 C20 1.365(8) . ?
C19 H19 0.9500 . ?
C20 H20 0.9500 . ?
C25 C26 1.375(8) . ?
C25 H25 0.9500 . ?
C26 C27 1.379(9) . ?
C26 H26 0.9500 . ?
C27 C28 1.377(8) . ?
C27 H27 0.9500 . ?
C28 C29 1.382(7) . ?
C28 H28 0.9500 . ?
C29 C30 1.450(8) . ?
C30 C31 1.413(7) . ?
C31 C32 1.368(9) . ?
C31 H31 0.9500 . ?
C32 H32 0.9500 . ?
C37 C38 1.372(8) . ?
C37 H37 0.9500 . ?
C38 C39 1.382(9) . ?
C38 H38 0.9500 . ?
C39 C40 1.377(9) . ?
C39 H39 0.9500 . ?
C40 C41 1.392(8) . ?
C40 H40 0.9500 . ?
C41 C42 1.453(8) . ?
C42 C43 1.403(7) . ?
C43 C44 1.373(8) . ?
C43 H43 0.9500 . ?
C44 H44 0.9500 . ?
C46 K2 3.322(5) 2_665 ?
C48 K2 3.318(5) 2_665 ?
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
N2 H2N O20 0.88 1.86 2.735(6) 172.5 .
N9 H9N O15 0.88 1.96 2.766(6) 152.1 .
N16 H16N O17 0.88 1.87 2.733(6) 167.8 .
N23 H23N O18 0.88 1.93 2.778(6) 160.4 1_544
O1 H1A O12 0.85 1.94 2.785(6) 173.6 .
O1 H1B N4 0.84 2.13 2.755(6) 131.5 2_676
O1 H1B O17 0.84 2.61 3.040(6) 113.3 .
O2 H2B O19 0.86 1.95 2.808(6) 170.9 2_666
O3 H3A N12 0.86 2.28 2.912(6) 130.5 .
O3 H3B O16 0.84 2.02 2.812(6) 155.8 2_666
O4 H4B O14 0.85 1.90 2.616(6) 141.3 .
O5 H5A N18 0.90 2.48 3.159(6) 132.9 .
O5 H5B N12 0.90 2.10 2.978(6) 164.5 2_666
O7 H7AA N25 0.85 1.90 2.725(6) 163.8 2_655
O8 H8AB O11 0.85 2.79 3.032(5) 98.6 .
O9 H9A O15 0.85 1.90 2.709(5) 161.0 .
O9 H9B N19 0.85 1.94 2.788(6) 172.7 2_665
O10 H10B O13 0.85 2.46 3.302(7) 169.9 2_665
O11 H11C O8 0.98 2.18 3.032(5) 145.0 .
O12 H12C O19 0.98 1.84 2.797(6) 165.0 1_565
O12 H12A N4 0.98 2.53 3.453(7) 157.2 .
O13 H13A N19 0.90 2.61 3.112(7) 115.7 .
O13 H13B O14 0.90 2.26 2.732(7) 112.7 .
