#------------------------------------------------------------------------------
#$Date: 2016-03-25 11:00:33 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179772 $
#$URL: svn://www.crystallography.net/cod/cif/7/00/68/7006854.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7006854
loop_
_publ_author_name
'Gallo, Vito'
'Mastrorilli, Piero'
'Nobile, Cosimo F.'
'Braunstein, Pierre'
'Englert, Ulli'
_publ_section_title
;
 Chelating versus bridging bonding modes of N-substituted
 bis(diphenylphosphanyl)amine ligands in Pt complexes and Co2Pt
 clusters.
;
_journal_issue                   19
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              2342
_journal_page_last               2349
_journal_paper_doi               10.1039/b514787e
_journal_year                    2006
_chemical_formula_sum            'C33 H31 Cl2 N P2 Pt S'
_chemical_formula_weight         801.58
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 111.516(9)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   11.4712(19)
_cell_length_b                   16.585(3)
_cell_length_c                   17.909(3)
_cell_measurement_reflns_used    966
_cell_measurement_temperature    110(2)
_cell_measurement_theta_max      24.94
_cell_measurement_theta_min      2.22
_cell_volume                     3169.8(10)
_computing_cell_refinement       SMART
_computing_data_collection       'SMART (Bruker, 2001)'
_computing_data_reduction        'SAINT (Bruker, 1999)'
_computing_molecular_graphics    'PLATON (Spek, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      110(2)
_diffrn_measured_fraction_theta_full .949
_diffrn_measured_fraction_theta_max .949
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0493
_diffrn_reflns_av_sigmaI/netI    0.0459
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            31456
_diffrn_reflns_theta_full        28.10
_diffrn_reflns_theta_max         28.10
_diffrn_reflns_theta_min         2.44
_exptl_absorpt_coefficient_mu    4.786
_exptl_absorpt_correction_T_max  0.762
_exptl_absorpt_correction_T_min  0.358
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   'SADABS (1996)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.680
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             1576
_exptl_crystal_size_max          0.27
_exptl_crystal_size_mid          0.23
_exptl_crystal_size_min          0.06
_refine_diff_density_max         1.532
_refine_diff_density_min         -.592
_refine_diff_density_rms         .130
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.020
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     361
_refine_ls_number_reflns         7584
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.020
_refine_ls_R_factor_all          0.0370
_refine_ls_R_factor_gt           0.0289
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0310P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0640
_refine_ls_wR_factor_ref         0.0668
_reflns_number_gt                6462
_reflns_number_total             7584
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b514787e.txt
_cod_data_source_block           pm12
_cod_depositor_comments
;
The following automatic conversions were performed:

'_refine_ls_weighting_scheme' value 'calc
w=1/[\s^2^(Fo^2^)+(0.0310P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3' was
changed to 'calc'. New tag '_refine_ls_weighting_details' was
created. The value of the new tag was set to
'w=1/[\s^2^(Fo^2^)+(0.0310P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'.

Automatic conversion script
Id: cif_fix_values 3143 2015-03-26 13:38:13Z robertas 
;
_cod_original_cell_volume        3169.8(9)
_cod_original_sg_symbol_H-M      P21/c
_cod_database_code               7006854
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.362830(12) 0.358621(7) 0.301963(6) 0.01399(5) Uani 1 d . . .
Cl1 Cl 0.40623(9) 0.47702(5) 0.24339(5) 0.0265(2) Uani 1 d . . .
Cl2 Cl 0.15355(8) 0.39839(6) 0.27541(5) 0.0291(2) Uani 1 d . . .
S1 S 0.67712(8) 0.02551(5) 0.52244(5) 0.01731(17) Uani 1 d . . .
P1 P 0.36514(7) 0.24556(5) 0.36812(4) 0.01264(16) Uani 1 d . . .
P2 P 0.55556(8) 0.30997(5) 0.34450(5) 0.01341(17) Uani 1 d . . .
N1 N 0.5198(2) 0.22634(15) 0.38699(14) 0.0133(5) Uani 1 d . . .
C1 C 0.6697(3) 0.36915(18) 0.42370(18) 0.0166(7) Uani 1 d . . .
C2 C 0.7965(4) 0.3715(2) 0.4352(2) 0.0303(9) Uani 1 d . . .
H2 H 0.8271 0.3434 0.3999 0.036 Uiso 1 calc R . .
C3 C 0.8773(4) 0.4157(3) 0.4993(3) 0.0446(12) Uani 1 d . . .
H3 H 0.9637 0.4187 0.5071 0.054 Uiso 1 calc R . .
C4 C 0.8339(4) 0.4551(2) 0.5513(2) 0.0364(10) Uani 1 d . . .
H4 H 0.8907 0.4848 0.5949 0.044 Uiso 1 calc R . .
C5 C 0.7087(4) 0.4522(2) 0.5410(2) 0.0305(9) Uani 1 d . . .
H5 H 0.6794 0.4791 0.5776 0.037 Uiso 1 calc R . .
C6 C 0.6260(4) 0.4095(2) 0.47643(19) 0.0229(8) Uani 1 d . . .
H6 H 0.5395 0.4078 0.4683 0.027 Uiso 1 calc R . .
C7 C 0.6291(3) 0.27795(19) 0.27591(18) 0.0161(7) Uani 1 d . . .
C8 C 0.6418(3) 0.1965(2) 0.26128(18) 0.0179(7) Uani 1 d . . .
H8 H 0.6116 0.1565 0.2876 0.021 Uiso 1 calc R . .
C9 C 0.6987(3) 0.1740(2) 0.20827(19) 0.0218(7) Uani 1 d . . .
H9 H 0.7064 0.1185 0.1979 0.026 Uiso 1 calc R . .
C10 C 0.7441(3) 0.2316(2) 0.1704(2) 0.0272(8) Uani 1 d . . .
H10 H 0.7857 0.2155 0.1357 0.033 Uiso 1 calc R . .
C11 C 0.7296(4) 0.3130(2) 0.1828(2) 0.0277(8) Uani 1 d . . .
H11 H 0.7593 0.3526 0.1559 0.033 Uiso 1 calc R . .
C12 C 0.6708(3) 0.3359(2) 0.2352(2) 0.0221(8) Uani 1 d . . .
H12 H 0.6592 0.3915 0.2432 0.027 Uiso 1 calc R . .
C13 C 0.6087(3) 0.17660(19) 0.45160(18) 0.0153(7) Uani 1 d . . .
H13A H 0.6023 0.1915 0.5035 0.018 Uiso 1 calc R . .
H13B H 0.6952 0.1884 0.4552 0.018 Uiso 1 calc R . .
C14 C 0.5835(3) 0.08656(19) 0.43726(18) 0.0156(7) Uani 1 d . . .
H14A H 0.6017 0.0702 0.3895 0.019 Uiso 1 calc R . .
H14B H 0.4936 0.0760 0.4258 0.019 Uiso 1 calc R . .
C15 C 0.8100(3) -0.0004(2) 0.4936(2) 0.0214(7) Uani 1 d . . .
H15A H 0.8649 -0.0391 0.5330 0.026 Uiso 1 calc R . .
H15B H 0.7786 -0.0271 0.4405 0.026 Uiso 1 calc R . .
C16 C 0.8852(3) 0.0727(2) 0.4898(2) 0.0196(7) Uani 1 d . . .
C17 C 0.8766(3) 0.1035(2) 0.4158(2) 0.0208(7) Uani 1 d . . .
H17 H 0.8280 0.0761 0.3679 0.025 Uiso 1 calc R . .
C18 C 0.9392(3) 0.1747(2) 0.4117(2) 0.0247(8) Uani 1 d . . .
H18 H 0.9305 0.1967 0.3610 0.030 Uiso 1 calc R . .
C19 C 1.0137(3) 0.2133(2) 0.4813(2) 0.0278(8) Uani 1 d . . .
H19 H 1.0570 0.2614 0.4785 0.033 Uiso 1 calc R . .
C20 C 1.0249(3) 0.1815(2) 0.5556(2) 0.0286(8) Uani 1 d . . .
H20 H 1.0769 0.2076 0.6034 0.034 Uiso 1 calc R . .
C21 C 0.9608(3) 0.1118(2) 0.5603(2) 0.0234(8) Uani 1 d . . .
H21 H 0.9682 0.0908 0.6111 0.028 Uiso 1 calc R . .
C22 C 0.3436(3) 0.25498(19) 0.46261(17) 0.0146(6) Uani 1 d . . .
C23 C 0.3156(3) 0.3298(2) 0.48716(19) 0.0194(7) Uani 1 d . . .
H23 H 0.3018 0.3752 0.4526 0.023 Uiso 1 calc R . .
C24 C 0.3078(4) 0.3378(2) 0.5625(2) 0.0250(8) Uani 1 d . . .
H24 H 0.2891 0.3887 0.5796 0.030 Uiso 1 calc R . .
C25 C 0.3275(3) 0.2714(2) 0.61243(19) 0.0232(8) Uani 1 d . . .
H25 H 0.3217 0.2770 0.6637 0.028 Uiso 1 calc R . .
C26 C 0.3556(3) 0.1967(2) 0.58856(19) 0.0202(7) Uani 1 d . . .
H26 H 0.3695 0.1515 0.6234 0.024 Uiso 1 calc R . .
C27 C 0.3633(3) 0.1884(2) 0.51358(18) 0.0179(7) Uani 1 d . . .
H27 H 0.3820 0.1374 0.4967 0.021 Uiso 1 calc R . .
C28 C 0.2763(3) 0.15780(19) 0.31834(18) 0.0147(7) Uani 1 d . . .
C29 C 0.1618(3) 0.1412(2) 0.3254(2) 0.0238(8) Uani 1 d . . .
H29 H 0.1321 0.1747 0.3578 0.029 Uiso 1 calc R . .
C30 C 0.0906(3) 0.0754(2) 0.2850(2) 0.0269(8) Uani 1 d . . .
H30 H 0.0134 0.0633 0.2907 0.032 Uiso 1 calc R . .
C31 C 0.1327(3) 0.0278(2) 0.2365(2) 0.0257(8) Uani 1 d . . .
H31 H 0.0844 -0.0171 0.2091 0.031 Uiso 1 calc R . .
C32 C 0.2451(3) 0.0456(2) 0.22781(19) 0.0197(7) Uani 1 d . . .
H32 H 0.2725 0.0138 0.1933 0.024 Uiso 1 calc R . .
C33 C 0.3175(3) 0.1097(2) 0.26924(18) 0.0162(7) Uani 1 d . . .
H33 H 0.3955 0.1208 0.2642 0.019 Uiso 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C .0033 .0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H .0000 .0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl .1484 .1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N .0061 .0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P .1023 .0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S .1246 .1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P2 Pt1 P1 72.06(3) . . ?
P2 Pt1 Cl1 96.28(3) . . ?
P1 Pt1 Cl1 168.06(3) . . ?
P2 Pt1 Cl2 170.09(3) . . ?
P1 Pt1 Cl2 98.98(3) . . ?
Cl1 Pt1 Cl2 92.44(3) . . ?
C14 S1 C15 101.02(15) . . ?
N1 P1 C22 108.65(13) . . ?
N1 P1 C28 107.65(14) . . ?
C22 P1 C28 106.56(15) . . ?
N1 P1 Pt1 94.11(9) . . ?
C22 P1 Pt1 116.73(11) . . ?
C28 P1 Pt1 121.52(10) . . ?
N1 P1 P2 40.23(9) . . ?
C22 P1 P2 121.92(11) . . ?
C28 P1 P2 127.16(11) . . ?
Pt1 P1 P2 53.91(3) . . ?
N1 P2 C7 108.26(14) . . ?
N1 P2 C1 108.22(13) . . ?
C7 P2 C1 107.84(16) . . ?
N1 P2 Pt1 94.41(9) . . ?
C7 P2 Pt1 122.04(10) . . ?
C1 P2 Pt1 114.43(12) . . ?
N1 P2 P1 40.43(9) . . ?
C7 P2 P1 128.25(11) . . ?
C1 P2 P1 120.03(12) . . ?
Pt1 P2 P1 54.03(3) . . ?
C13 N1 P2 126.4(2) . . ?
C13 N1 P1 128.7(2) . . ?
P2 N1 P1 99.34(13) . . ?
C6 C1 C2 120.2(3) . . ?
C6 C1 P2 116.9(3) . . ?
C2 C1 P2 122.9(3) . . ?
C3 C2 C1 118.7(4) . . ?
C3 C2 H2 120.6 . . ?
C1 C2 H2 120.6 . . ?
C4 C3 C2 120.9(4) . . ?
C4 C3 H3 119.6 . . ?
C2 C3 H3 119.6 . . ?
C3 C4 C5 120.8(4) . . ?
C3 C4 H4 119.6 . . ?
C5 C4 H4 119.6 . . ?
C4 C5 C6 119.2(4) . . ?
C4 C5 H5 120.4 . . ?
C6 C5 H5 120.4 . . ?
C5 C6 C1 120.3(4) . . ?
C5 C6 H6 119.9 . . ?
C1 C6 H6 119.9 . . ?
C12 C7 C8 119.4(3) . . ?
C12 C7 P2 119.3(3) . . ?
C8 C7 P2 121.3(2) . . ?
C9 C8 C7 119.9(3) . . ?
C9 C8 H8 120.1 . . ?
C7 C8 H8 120.1 . . ?
C10 C9 C8 120.5(3) . . ?
C10 C9 H9 119.8 . . ?
C8 C9 H9 119.8 . . ?
C9 C10 C11 120.4(3) . . ?
C9 C10 H10 119.8 . . ?
C11 C10 H10 119.8 . . ?
C10 C11 C12 119.3(3) . . ?
C10 C11 H11 120.3 . . ?
C12 C11 H11 120.3 . . ?
C7 C12 C11 120.5(3) . . ?
C7 C12 H12 119.8 . . ?
C11 C12 H12 119.8 . . ?
N1 C13 C14 112.3(2) . . ?
N1 C13 H13A 109.1 . . ?
C14 C13 H13A 109.1 . . ?
N1 C13 H13B 109.1 . . ?
C14 C13 H13B 109.1 . . ?
H13A C13 H13B 107.9 . . ?
C13 C14 S1 112.8(2) . . ?
C13 C14 H14A 109.0 . . ?
S1 C14 H14A 109.0 . . ?
C13 C14 H14B 109.0 . . ?
S1 C14 H14B 109.0 . . ?
H14A C14 H14B 107.8 . . ?
C16 C15 S1 112.0(2) . . ?
C16 C15 H15A 109.2 . . ?
S1 C15 H15A 109.2 . . ?
C16 C15 H15B 109.2 . . ?
S1 C15 H15B 109.2 . . ?
H15A C15 H15B 107.9 . . ?
C17 C16 C21 119.5(3) . . ?
C17 C16 C15 119.9(3) . . ?
C21 C16 C15 120.6(3) . . ?
C16 C17 C18 120.1(3) . . ?
C16 C17 H17 119.9 . . ?
C18 C17 H17 119.9 . . ?
C19 C18 C17 120.2(3) . . ?
C19 C18 H18 119.9 . . ?
C17 C18 H18 119.9 . . ?
C18 C19 C20 119.7(4) . . ?
C18 C19 H19 120.1 . . ?
C20 C19 H19 120.1 . . ?
C21 C20 C19 120.5(3) . . ?
C21 C20 H20 119.7 . . ?
C19 C20 H20 119.7 . . ?
C20 C21 C16 119.9(3) . . ?
C20 C21 H21 120.1 . . ?
C16 C21 H21 120.1 . . ?
C23 C22 C27 119.9(3) . . ?
C23 C22 P1 120.0(2) . . ?
C27 C22 P1 120.0(2) . . ?
C24 C23 C22 119.7(3) . . ?
C24 C23 H23 120.2 . . ?
C22 C23 H23 120.2 . . ?
C25 C24 C23 119.9(3) . . ?
C25 C24 H24 120.1 . . ?
C23 C24 H24 120.1 . . ?
C24 C25 C26 120.9(3) . . ?
C24 C25 H25 119.6 . . ?
C26 C25 H25 119.6 . . ?
C27 C26 C25 119.5(3) . . ?
C27 C26 H26 120.3 . . ?
C25 C26 H26 120.3 . . ?
C26 C27 C22 120.2(3) . . ?
C26 C27 H27 119.9 . . ?
C22 C27 H27 119.9 . . ?
C33 C28 C29 119.6(3) . . ?
C33 C28 P1 120.7(3) . . ?
C29 C28 P1 119.5(3) . . ?
C28 C29 C30 119.9(3) . . ?
C28 C29 H29 120.0 . . ?
C30 C29 H29 120.0 . . ?
C31 C30 C29 120.0(3) . . ?
C31 C30 H30 120.0 . . ?
C29 C30 H30 120.0 . . ?
C30 C31 C32 120.1(3) . . ?
C30 C31 H31 120.0 . . ?
C32 C31 H31 120.0 . . ?
C33 C32 C31 120.2(3) . . ?
C33 C32 H32 119.9 . . ?
C31 C32 H32 119.9 . . ?
C32 C33 C28 120.2(3) . . ?
C32 C33 H33 119.9 . . ?
C28 C33 H33 119.9 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 P2 2.2099(9) . ?
Pt1 P1 2.2131(9) . ?
Pt1 Cl1 2.3637(9) . ?
Pt1 Cl2 2.3636(10) . ?
S1 C14 1.818(3) . ?
S1 C15 1.830(3) . ?
P1 N1 1.710(3) . ?
P1 C22 1.804(3) . ?
P1 C28 1.813(3) . ?
P1 P2 2.6017(12) . ?
P2 N1 1.703(3) . ?
P2 C7 1.806(3) . ?
P2 C1 1.824(3) . ?
N1 C13 1.481(4) . ?
C1 C6 1.391(5) . ?
C1 C2 1.393(5) . ?
C2 C3 1.391(5) . ?
C2 H2 0.9500 . ?
C3 C4 1.373(6) . ?
C3 H3 0.9500 . ?
C4 C5 1.380(6) . ?
C4 H4 0.9500 . ?
C5 C6 1.391(5) . ?
C5 H5 0.9500 . ?
C6 H6 0.9500 . ?
C7 C12 1.393(4) . ?
C7 C8 1.394(5) . ?
C8 C9 1.386(5) . ?
C8 H8 0.9500 . ?
C9 C10 1.380(5) . ?
C9 H9 0.9500 . ?
C10 C11 1.387(5) . ?
C10 H10 0.9500 . ?
C11 C12 1.394(5) . ?
C11 H11 0.9500 . ?
C12 H12 0.9500 . ?
C13 C14 1.525(4) . ?
C13 H13A 0.9900 . ?
C13 H13B 0.9900 . ?
C14 H14A 0.9900 . ?
C14 H14B 0.9900 . ?
C15 C16 1.504(5) . ?
C15 H15A 0.9900 . ?
C15 H15B 0.9900 . ?
C16 C17 1.390(5) . ?
C16 C21 1.401(5) . ?
C17 C18 1.398(5) . ?
C17 H17 0.9500 . ?
C18 C19 1.383(5) . ?
C18 H18 0.9500 . ?
C19 C20 1.392(5) . ?
C19 H19 0.9500 . ?
C20 C21 1.389(5) . ?
C20 H20 0.9500 . ?
C21 H21 0.9500 . ?
C22 C23 1.394(4) . ?
C22 C27 1.397(4) . ?
C23 C24 1.390(4) . ?
C23 H23 0.9500 . ?
C24 C25 1.385(5) . ?
C24 H24 0.9500 . ?
C25 C26 1.386(5) . ?
C25 H25 0.9500 . ?
C26 C27 1.384(4) . ?
C26 H26 0.9500 . ?
C27 H27 0.9500 . ?
C28 C33 1.393(4) . ?
C28 C29 1.393(5) . ?
C29 C30 1.396(5) . ?
C29 H29 0.9500 . ?
C30 C31 1.386(5) . ?
C30 H30 0.9500 . ?
C31 C32 1.386(5) . ?
C31 H31 0.9500 . ?
C32 C33 1.384(5) . ?
C32 H32 0.9500 . ?
C33 H33 0.9500 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
P2 Pt1 P1 N1 -1.84(9) . . . . ?
Cl1 Pt1 P1 N1 -14.66(18) . . . . ?
Cl2 Pt1 P1 N1 -177.48(9) . . . . ?
P2 Pt1 P1 C22 111.43(12) . . . . ?
Cl1 Pt1 P1 C22 98.61(18) . . . . ?
Cl2 Pt1 P1 C22 -64.21(12) . . . . ?
P2 Pt1 P1 C28 -115.45(13) . . . . ?
Cl1 Pt1 P1 C28 -128.28(18) . . . . ?
Cl2 Pt1 P1 C28 68.91(13) . . . . ?
Cl1 Pt1 P1 P2 -12.82(15) . . . . ?
Cl2 Pt1 P1 P2 -175.64(3) . . . . ?
P1 Pt1 P2 N1 1.85(9) . . . . ?
Cl1 Pt1 P2 N1 179.20(9) . . . . ?
Cl2 Pt1 P2 N1 27.7(2) . . . . ?
P1 Pt1 P2 C7 116.62(13) . . . . ?
Cl1 Pt1 P2 C7 -66.02(13) . . . . ?
Cl2 Pt1 P2 C7 142.5(2) . . . . ?
P1 Pt1 P2 C1 -110.45(12) . . . . ?
Cl1 Pt1 P2 C1 66.90(12) . . . . ?
Cl2 Pt1 P2 C1 -84.6(2) . . . . ?
Cl1 Pt1 P2 P1 177.35(3) . . . . ?
Cl2 Pt1 P2 P1 25.86(18) . . . . ?
C22 P1 P2 N1 81.20(18) . . . . ?
C28 P1 P2 N1 -72.13(18) . . . . ?
Pt1 P1 P2 N1 -177.16(14) . . . . ?
N1 P1 P2 C7 71.94(19) . . . . ?
C22 P1 P2 C7 153.14(18) . . . . ?
C28 P1 P2 C7 -0.18(19) . . . . ?
Pt1 P1 P2 C7 -105.22(14) . . . . ?
N1 P1 P2 C1 -83.01(18) . . . . ?
C22 P1 P2 C1 -1.82(18) . . . . ?
C28 P1 P2 C1 -155.14(17) . . . . ?
Pt1 P1 P2 C1 99.83(12) . . . . ?
N1 P1 P2 Pt1 177.16(14) . . . . ?
C22 P1 P2 Pt1 -101.64(13) . . . . ?
C28 P1 P2 Pt1 105.03(13) . . . . ?
C7 P2 N1 C13 76.6(3) . . . . ?
C1 P2 N1 C13 -40.1(3) . . . . ?
Pt1 P2 N1 C13 -157.6(2) . . . . ?
P1 P2 N1 C13 -155.3(3) . . . . ?
C7 P2 N1 P1 -128.16(14) . . . . ?
C1 P2 N1 P1 115.21(15) . . . . ?
Pt1 P2 N1 P1 -2.30(11) . . . . ?
C22 P1 N1 C13 36.7(3) . . . . ?
C28 P1 N1 C13 -78.3(3) . . . . ?
Pt1 P1 N1 C13 156.7(2) . . . . ?
P2 P1 N1 C13 154.4(3) . . . . ?
C22 P1 N1 P2 -117.71(15) . . . . ?
C28 P1 N1 P2 127.25(14) . . . . ?
Pt1 P1 N1 P2 2.30(11) . . . . ?
N1 P2 C1 C6 -72.2(3) . . . . ?
C7 P2 C1 C6 170.9(3) . . . . ?
Pt1 P2 C1 C6 31.6(3) . . . . ?
P1 P2 C1 C6 -29.6(3) . . . . ?
N1 P2 C1 C2 104.3(3) . . . . ?
C7 P2 C1 C2 -12.6(3) . . . . ?
Pt1 P2 C1 C2 -151.9(3) . . . . ?
P1 P2 C1 C2 146.9(3) . . . . ?
C6 C1 C2 C3 -1.0(6) . . . . ?
P2 C1 C2 C3 -177.4(3) . . . . ?
C1 C2 C3 C4 1.2(7) . . . . ?
C2 C3 C4 C5 -0.4(7) . . . . ?
C3 C4 C5 C6 -0.8(6) . . . . ?
C4 C5 C6 C1 1.0(5) . . . . ?
C2 C1 C6 C5 -0.1(5) . . . . ?
P2 C1 C6 C5 176.5(3) . . . . ?
N1 P2 C7 C12 -178.0(3) . . . . ?
C1 P2 C7 C12 -61.2(3) . . . . ?
Pt1 P2 C7 C12 74.4(3) . . . . ?
P1 P2 C7 C12 141.5(2) . . . . ?
N1 P2 C7 C8 3.7(3) . . . . ?
C1 P2 C7 C8 120.6(3) . . . . ?
Pt1 P2 C7 C8 -103.9(3) . . . . ?
P1 P2 C7 C8 -36.8(3) . . . . ?
C12 C7 C8 C9 1.7(5) . . . . ?
P2 C7 C8 C9 180.0(2) . . . . ?
C7 C8 C9 C10 0.7(5) . . . . ?
C8 C9 C10 C11 -2.3(5) . . . . ?
C9 C10 C11 C12 1.4(6) . . . . ?
C8 C7 C12 C11 -2.7(5) . . . . ?
P2 C7 C12 C11 179.0(3) . . . . ?
C10 C11 C12 C7 1.1(5) . . . . ?
P2 N1 C13 C14 -138.6(2) . . . . ?
P1 N1 C13 C14 73.3(3) . . . . ?
N1 C13 C14 S1 -171.9(2) . . . . ?
C15 S1 C14 C13 -94.9(2) . . . . ?
C14 S1 C15 C16 64.9(3) . . . . ?
S1 C15 C16 C17 -105.9(3) . . . . ?
S1 C15 C16 C21 71.8(4) . . . . ?
C21 C16 C17 C18 -2.4(5) . . . . ?
C15 C16 C17 C18 175.4(3) . . . . ?
C16 C17 C18 C19 2.4(5) . . . . ?
C17 C18 C19 C20 -0.8(5) . . . . ?
C18 C19 C20 C21 -0.8(6) . . . . ?
C19 C20 C21 C16 0.7(6) . . . . ?
C17 C16 C21 C20 0.9(5) . . . . ?
C15 C16 C21 C20 -176.9(3) . . . . ?
N1 P1 C22 C23 110.5(3) . . . . ?
C28 P1 C22 C23 -133.8(3) . . . . ?
Pt1 P1 C22 C23 5.7(3) . . . . ?
P2 P1 C22 C23 68.1(3) . . . . ?
N1 P1 C22 C27 -65.3(3) . . . . ?
C28 P1 C22 C27 50.5(3) . . . . ?
Pt1 P1 C22 C27 -170.0(2) . . . . ?
P2 P1 C22 C27 -107.6(3) . . . . ?
C27 C22 C23 C24 0.2(5) . . . . ?
P1 C22 C23 C24 -175.5(3) . . . . ?
C22 C23 C24 C25 -0.2(5) . . . . ?
C23 C24 C25 C26 0.3(6) . . . . ?
C24 C25 C26 C27 -0.4(5) . . . . ?
C25 C26 C27 C22 0.4(5) . . . . ?
C23 C22 C27 C26 -0.3(5) . . . . ?
P1 C22 C27 C26 175.4(3) . . . . ?
N1 P1 C28 C33 -30.6(3) . . . . ?
C22 P1 C28 C33 -147.0(3) . . . . ?
Pt1 P1 C28 C33 75.8(3) . . . . ?
P2 P1 C28 C33 9.6(3) . . . . ?
N1 P1 C28 C29 153.3(3) . . . . ?
C22 P1 C28 C29 36.9(3) . . . . ?
Pt1 P1 C28 C29 -100.2(3) . . . . ?
P2 P1 C28 C29 -166.5(2) . . . . ?
C33 C28 C29 C30 1.6(5) . . . . ?
P1 C28 C29 C30 177.7(3) . . . . ?
C28 C29 C30 C31 -1.4(5) . . . . ?
C29 C30 C31 C32 -0.3(5) . . . . ?
C30 C31 C32 C33 1.8(5) . . . . ?
C31 C32 C33 C28 -1.6(5) . . . . ?
C29 C28 C33 C32 -0.1(5) . . . . ?
P1 C28 C33 C32 -176.2(2) . . . . ?
