#------------------------------------------------------------------------------
#$Date: 2016-03-25 11:04:14 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179774 $
#$URL: svn://www.crystallography.net/cod/cif/7/00/70/7007094.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7007094
loop_
_publ_author_name
'Ainscough, Eric W.'
'Brodie, Andrew M.'
'Chaplin, Adrian B.'
'O'Connor, Joy M'
'Otter, Carl A.'
_publ_section_title
;
 Gold(I) and platinum(II) complexes with a new diphosphine ligand based
 on the cyclotriphosphazene platform.
;
_journal_issue                   10
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              1264
_journal_page_last               1266
_journal_paper_doi               10.1039/b517309b
_journal_year                    2006
_chemical_formula_sum            'C62.7 H46.7 Au2 Cl10.1 N3 O6 P5'
_chemical_formula_weight         1845.06
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                93.237(1)
_cell_angle_beta                 104.527(1)
_cell_angle_gamma                100.185(1)
_cell_formula_units_Z            2
_cell_length_a                   13.8387(2)
_cell_length_b                   14.0919(1)
_cell_length_c                   18.3886(1)
_cell_measurement_temperature    83(2)
_cell_volume                     3397.49(6)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      356(2)
_diffrn_measured_fraction_theta_full 0.980
_diffrn_measured_fraction_theta_max 0.980
_diffrn_measurement_device_type  'Brucker P4'
_diffrn_measurement_method       'Area detector /w scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0627
_diffrn_reflns_av_sigmaI/netI    0.0831
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            30919
_diffrn_reflns_theta_full        25.86
_diffrn_reflns_theta_max         25.86
_diffrn_reflns_theta_min         1.15
_exptl_absorpt_coefficient_mu    4.880
_exptl_absorpt_correction_T_max  0.4088
_exptl_absorpt_correction_T_min  0.2358
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Blessing, Acta Cryst., 1995, A51, 33-38'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.803
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1485
_exptl_crystal_size_max          0.28
_exptl_crystal_size_mid          0.28
_exptl_crystal_size_min          0.24
_refine_diff_density_max         3.690
_refine_diff_density_min         -3.577
_refine_diff_density_rms         0.195
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.950
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     703
_refine_ls_number_reflns         12898
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.950
_refine_ls_R_factor_all          0.0667
_refine_ls_R_factor_gt           0.0498
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0715P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1213
_refine_ls_wR_factor_ref         0.1295
_reflns_number_gt                9596
_reflns_number_total             12898
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b517309b.txt
_cod_data_source_block           cao376
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7007094
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 0.62966(2) 0.70085(2) 0.849120(14) 0.02719(9) Uani 1 1 d . . .
Au2 Au 0.33405(2) 0.834691(19) 0.464693(13) 0.02522(9) Uani 1 1 d . . .
Cl1 Cl 0.72930(15) 0.85189(14) 0.88402(12) 0.0436(5) Uani 1 1 d . . .
Cl2 Cl 0.35992(15) 0.70518(13) 0.39627(10) 0.0345(4) Uani 1 1 d . . .
P1 P 0.33349(13) 0.75493(12) 0.70863(9) 0.0204(4) Uani 1 1 d . . .
P2 P 0.26637(13) 0.78859(13) 0.83338(9) 0.0208(4) Uani 1 1 d . . .
P3 P 0.14271(13) 0.66569(13) 0.71041(9) 0.0222(4) Uani 1 1 d . . .
P4 P 0.52594(14) 0.55765(13) 0.80896(9) 0.0244(4) Uani 1 1 d . . .
P5 P 0.31292(14) 0.95703(13) 0.53716(10) 0.0252(4) Uani 1 1 d . . .
N1 N 0.3481(4) 0.8140(4) 0.7870(3) 0.0216(12) Uani 1 1 d . . .
N2 N 0.1683(4) 0.7087(4) 0.7959(3) 0.0228(12) Uani 1 1 d . . .
N3 N 0.2268(4) 0.6907(4) 0.6668(3) 0.0232(12) Uani 1 1 d . . .
O1 O 0.4203(3) 0.6910(3) 0.7228(2) 0.0232(10) Uani 1 1 d . . .
O2 O 0.3646(3) 0.8252(3) 0.6507(2) 0.0236(10) Uani 1 1 d . . .
O3 O 0.3150(4) 0.7550(3) 0.9125(2) 0.0229(10) Uani 1 1 d . . .
O4 O 0.2385(3) 0.8889(3) 0.8558(2) 0.0228(10) Uani 1 1 d . . .
O5 O 0.1089(3) 0.5525(3) 0.7106(2) 0.0243(10) Uani 1 1 d . . .
O6 O 0.0438(3) 0.6954(3) 0.6604(2) 0.0227(10) Uani 1 1 d . . .
C1 C 0.4269(5) 0.6148(5) 0.6739(3) 0.0216(14) Uani 1 1 d . . .
C2 C 0.3895(5) 0.6109(5) 0.5950(4) 0.0274(16) Uani 1 1 d . . .
H2 H 0.3572 0.6589 0.5732 0.033 Uiso 1 1 calc R . .
C3 C 0.4019(6) 0.5343(6) 0.5509(4) 0.0316(17) Uani 1 1 d . . .
H3 H 0.3775 0.5301 0.4986 0.038 Uiso 1 1 calc R . .
C4 C 0.4503(5) 0.4635(5) 0.5835(4) 0.0286(16) Uani 1 1 d . . .
H4 H 0.4589 0.4127 0.5528 0.034 Uiso 1 1 calc R . .
C5 C 0.4860(5) 0.4669(5) 0.6610(4) 0.0268(15) Uani 1 1 d . . .
H5 H 0.5172 0.4181 0.6824 0.032 Uiso 1 1 calc R . .
C6 C 0.4749(5) 0.5439(5) 0.7068(3) 0.0218(14) Uani 1 1 d . . .
C7 C 0.5856(5) 0.4528(5) 0.8289(3) 0.0248(15) Uani 1 1 d . . .
C8 C 0.5268(7) 0.3626(6) 0.8262(5) 0.047(2) Uani 1 1 d . . .
H8 H 0.4563 0.3544 0.8154 0.057 Uiso 1 1 calc R . .
C9 C 0.5736(8) 0.2854(7) 0.8398(5) 0.056(3) Uani 1 1 d . . .
H9 H 0.5339 0.2239 0.8364 0.067 Uiso 1 1 calc R . .
C10 C 0.6768(8) 0.2961(7) 0.8580(5) 0.054(3) Uani 1 1 d . . .
H10 H 0.7077 0.2431 0.8685 0.065 Uiso 1 1 calc R . .
C11 C 0.7340(7) 0.3863(8) 0.8604(5) 0.057(3) Uani 1 1 d . . .
H11 H 0.8044 0.3938 0.8711 0.068 Uiso 1 1 calc R . .
C12 C 0.6904(6) 0.4670(6) 0.8474(4) 0.0386(19) Uani 1 1 d . . .
H12 H 0.7302 0.5285 0.8510 0.046 Uiso 1 1 calc R . .
C13 C 0.4206(6) 0.5364(6) 0.8508(4) 0.0330(18) Uani 1 1 d . . .
C14 C 0.3236(6) 0.4883(7) 0.8108(5) 0.051(2) Uani 1 1 d . . .
H14 H 0.3097 0.4703 0.7592 0.061 Uiso 1 1 calc R . .
C15 C 0.2476(7) 0.4670(9) 0.8475(6) 0.075(4) Uani 1 1 d . . .
H15 H 0.1824 0.4350 0.8211 0.090 Uiso 1 1 calc R . .
C16 C 0.2714(8) 0.4948(9) 0.9255(6) 0.071(4) Uani 1 1 d . . .
H16 H 0.2210 0.4803 0.9507 0.085 Uiso 1 1 calc R . .
C17 C 0.3631(8) 0.5410(7) 0.9642(5) 0.048(2) Uani 1 1 d . . .
H17 H 0.3768 0.5586 1.0158 0.057 Uiso 1 1 calc R . .
C18 C 0.4379(7) 0.5626(6) 0.9277(4) 0.0371(19) Uani 1 1 d . . .
H18 H 0.5021 0.5958 0.9551 0.045 Uiso 1 1 calc R . .
C19 C 0.4357(5) 0.9120(5) 0.6700(4) 0.0265(15) Uani 1 1 d . . .
C20 C 0.5228(5) 0.9237(6) 0.7299(4) 0.0286(16) Uani 1 1 d . . .
H20 H 0.5351 0.8737 0.7597 0.034 Uiso 1 1 calc R . .
C21 C 0.5898(5) 1.0109(6) 0.7439(4) 0.0329(18) Uani 1 1 d . . .
H21 H 0.6488 1.0195 0.7834 0.039 Uiso 1 1 calc R . .
C22 C 0.5721(7) 1.0857(6) 0.7010(4) 0.041(2) Uani 1 1 d . . .
H22 H 0.6177 1.1449 0.7124 0.049 Uiso 1 1 calc R . .
C23 C 0.4850(6) 1.0727(5) 0.6401(4) 0.0327(17) Uani 1 1 d . . .
H23 H 0.4729 1.1233 0.6109 0.039 Uiso 1 1 calc R . .
C24 C 0.4170(5) 0.9849(5) 0.6232(4) 0.0241(15) Uani 1 1 d . . .
C25 C 0.3155(6) 1.0717(5) 0.4974(4) 0.0324(17) Uani 1 1 d . . .
C26 C 0.3657(8) 1.0902(6) 0.4407(4) 0.048(2) Uani 1 1 d . . .
H26 H 0.3914 1.0417 0.4198 0.057 Uiso 1 1 calc R . .
C27 C 0.3768(9) 1.1831(7) 0.4158(5) 0.065(3) Uani 1 1 d . . .
H27 H 0.4121 1.1969 0.3796 0.078 Uiso 1 1 calc R . .
C28 C 0.3366(7) 1.2518(6) 0.4440(5) 0.055(3) Uani 1 1 d . . .
H28 H 0.3430 1.3124 0.4260 0.066 Uiso 1 1 calc R . .
C29 C 0.2849(6) 1.2344(6) 0.5002(6) 0.048(2) Uani 1 1 d . . .
H29 H 0.2585 1.2829 0.5203 0.058 Uiso 1 1 calc R . .
C30 C 0.2742(6) 1.1423(6) 0.5250(5) 0.047(2) Uani 1 1 d . . .
H30 H 0.2383 1.1288 0.5609 0.056 Uiso 1 1 calc R . .
C31 C 0.1937(6) 0.9345(5) 0.5639(4) 0.0318(17) Uani 1 1 d . . .
C32 C 0.1068(6) 0.8979(5) 0.5076(5) 0.0396(19) Uani 1 1 d . . .
H32 H 0.1116 0.8806 0.4593 0.048 Uiso 1 1 calc R . .
C33 C 0.0123(7) 0.8863(6) 0.5218(6) 0.049(2) Uani 1 1 d . . .
H33 H -0.0466 0.8641 0.4829 0.058 Uiso 1 1 calc R . .
C34 C 0.0066(8) 0.9083(6) 0.5951(7) 0.059(3) Uani 1 1 d . . .
H34 H -0.0566 0.9001 0.6055 0.070 Uiso 1 1 calc R . .
C35 C 0.0946(8) 0.9427(7) 0.6530(6) 0.056(3) Uani 1 1 d . . .
H35 H 0.0903 0.9569 0.7019 0.067 Uiso 1 1 calc R . .
C36 C 0.1881(6) 0.9555(6) 0.6378(5) 0.042(2) Uani 1 1 d . . .
H36 H 0.2472 0.9779 0.6764 0.050 Uiso 1 1 calc R . .
C37 C 0.1862(5) 0.8928(5) 0.9121(4) 0.0266(15) Uani 1 1 d . . .
C38 C 0.0844(6) 0.8959(6) 0.8909(4) 0.039(2) Uani 1 1 d . . .
H38 H 0.0506 0.8924 0.8400 0.047 Uiso 1 1 calc R . .
C39 C 0.0322(6) 0.9041(7) 0.9449(5) 0.046(2) Uani 1 1 d . . .
H39 H -0.0369 0.9052 0.9307 0.055 Uiso 1 1 calc R . .
C40 C 0.0843(6) 0.9108(6) 1.0207(4) 0.0394(19) Uani 1 1 d . . .
H40 H 0.0500 0.9184 1.0575 0.047 Uiso 1 1 calc R . .
C41 C 0.1867(6) 0.9063(5) 1.0423(4) 0.0311(17) Uani 1 1 d . . .
H41 H 0.2203 0.9101 1.0933 0.037 Uiso 1 1 calc R . .
C42 C 0.2400(5) 0.8960(5) 0.9874(4) 0.0223(14) Uani 1 1 d . . .
C43 C 0.3488(5) 0.8892(5) 1.0096(3) 0.0238(15) Uani 1 1 d . . .
C44 C 0.4202(5) 0.9508(5) 1.0687(3) 0.0252(15) Uani 1 1 d . . .
H44 H 0.3990 0.9968 1.0961 0.030 Uiso 1 1 calc R . .
C45 C 0.5216(5) 0.9439(5) 1.0867(4) 0.0283(16) Uani 1 1 d . . .
H45 H 0.5678 0.9838 1.1271 0.034 Uiso 1 1 calc R . .
C46 C 0.5544(6) 0.8783(6) 1.0453(4) 0.0323(17) Uani 1 1 d . . .
H46 H 0.6232 0.8754 1.0574 0.039 Uiso 1 1 calc R . .
C47 C 0.4869(5) 0.8163(5) 0.9858(4) 0.0238(15) Uani 1 1 d . . .
H47 H 0.5093 0.7723 0.9575 0.029 Uiso 1 1 calc R . .
C48 C 0.3857(5) 0.8221(5) 0.9700(3) 0.0219(14) Uani 1 1 d . . .
C49 C 0.0502(5) 0.4926(5) 0.6430(4) 0.0268(16) Uani 1 1 d . . .
C50 C 0.0973(6) 0.4315(5) 0.6113(4) 0.0332(18) Uani 1 1 d . . .
H50 H 0.1663 0.4320 0.6305 0.040 Uiso 1 1 calc R . .
C51 C 0.0384(7) 0.3676(6) 0.5487(4) 0.0386(19) Uani 1 1 d . . .
H51 H 0.0685 0.3242 0.5263 0.046 Uiso 1 1 calc R . .
C52 C -0.0623(7) 0.3676(6) 0.5201(4) 0.041(2) Uani 1 1 d . . .
H52 H -0.1009 0.3242 0.4787 0.050 Uiso 1 1 calc R . .
C53 C -0.1068(6) 0.4325(5) 0.5530(4) 0.0335(18) Uani 1 1 d . . .
H53 H -0.1753 0.4331 0.5326 0.040 Uiso 1 1 calc R . .
C54 C -0.0518(5) 0.4972(5) 0.6160(4) 0.0283(16) Uani 1 1 d . . .
C55 C -0.0992(5) 0.5674(5) 0.6522(4) 0.0292(16) Uani 1 1 d . . .
C56 C -0.1972(6) 0.5383(6) 0.6640(4) 0.0355(19) Uani 1 1 d . . .
H56 H -0.2338 0.4756 0.6470 0.043 Uiso 1 1 calc R . .
C57 C -0.2377(6) 0.6019(7) 0.7001(4) 0.047(2) Uani 1 1 d . . .
H57 H -0.3011 0.5816 0.7087 0.056 Uiso 1 1 calc R . .
C58 C -0.1857(6) 0.6964(6) 0.7241(4) 0.0369(19) Uani 1 1 d . . .
H58 H -0.2141 0.7391 0.7489 0.044 Uiso 1 1 calc R . .
C59 C -0.0916(6) 0.7269(6) 0.7110(4) 0.0325(17) Uani 1 1 d . . .
H59 H -0.0567 0.7906 0.7258 0.039 Uiso 1 1 calc R . .
C60 C -0.0509(5) 0.6623(5) 0.6762(4) 0.0268(16) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P4 Au1 Cl1 176.21(7) . . ?
P5 Au2 Cl2 176.73(6) . . ?
N1 P1 N3 119.8(3) . . ?
N1 P1 O2 110.1(3) . . ?
N3 P1 O2 106.6(3) . . ?
N1 P1 O1 105.3(3) . . ?
N3 P1 O1 110.9(3) . . ?
O2 P1 O1 103.0(2) . . ?
N2 P2 O3 105.7(3) . . ?
N2 P2 N1 118.0(3) . . ?
O3 P2 N1 111.6(3) . . ?
N2 P2 O4 111.9(3) . . ?
O3 P2 O4 102.9(2) . . ?
N1 P2 O4 105.7(3) . . ?
N3 P3 O5 111.7(3) . . ?
N3 P3 N2 118.2(3) . . ?
O5 P3 N2 105.1(3) . . ?
N3 P3 O6 105.8(3) . . ?
O5 P3 O6 103.2(3) . . ?
N2 P3 O6 112.1(3) . . ?
C13 P4 C6 108.1(3) . . ?
C13 P4 C7 103.6(3) . . ?
C6 P4 C7 104.6(3) . . ?
C13 P4 Au1 113.7(3) . . ?
C6 P4 Au1 111.1(2) . . ?
C7 P4 Au1 114.9(2) . . ?
C25 P5 C31 104.5(4) . . ?
C25 P5 C24 103.4(3) . . ?
C31 P5 C24 108.2(3) . . ?
C25 P5 Au2 115.9(3) . . ?
C31 P5 Au2 113.9(3) . . ?
C24 P5 Au2 110.1(2) . . ?
P1 N1 P2 119.8(3) . . ?
P2 N2 P3 121.7(3) . . ?
P1 N3 P3 120.1(3) . . ?
C1 O1 P1 126.3(4) . . ?
C19 O2 P1 125.3(4) . . ?
C48 O3 P2 120.4(4) . . ?
C37 O4 P2 118.3(4) . . ?
C49 O5 P3 121.0(4) . . ?
C60 O6 P3 118.8(4) . . ?
C6 C1 O1 116.4(5) . . ?
C6 C1 C2 121.4(6) . . ?
O1 C1 C2 122.1(6) . . ?
C3 C2 C1 118.2(7) . . ?
C2 C3 C4 120.6(7) . . ?
C3 C4 C5 121.1(7) . . ?
C4 C5 C6 119.5(7) . . ?
C1 C6 C5 119.2(6) . . ?
C1 C6 P4 118.4(5) . . ?
C5 C6 P4 122.3(5) . . ?
C8 C7 C12 121.3(7) . . ?
C8 C7 P4 120.3(6) . . ?
C12 C7 P4 118.3(6) . . ?
C9 C8 C7 118.9(8) . . ?
C10 C9 C8 121.7(9) . . ?
C9 C10 C11 118.5(8) . . ?
C10 C11 C12 122.1(9) . . ?
C7 C12 C11 117.4(8) . . ?
C14 C13 C18 118.0(7) . . ?
C14 C13 P4 122.8(6) . . ?
C18 C13 P4 119.1(6) . . ?
C15 C14 C13 120.2(9) . . ?
C14 C15 C16 118.4(10) . . ?
C17 C16 C15 122.0(8) . . ?
C16 C17 C18 119.4(8) . . ?
C17 C18 C13 121.9(9) . . ?
C20 C19 C24 122.0(7) . . ?
C20 C19 O2 122.1(6) . . ?
C24 C19 O2 115.9(6) . . ?
C21 C20 C19 118.2(7) . . ?
C20 C21 C22 121.6(7) . . ?
C21 C22 C23 119.8(7) . . ?
C24 C23 C22 120.2(7) . . ?
C23 C24 C19 118.2(6) . . ?
C23 C24 P5 122.4(5) . . ?
C19 C24 P5 119.1(5) . . ?
C30 C25 C26 119.7(7) . . ?
C30 C25 P5 120.7(6) . . ?
C26 C25 P5 119.6(6) . . ?
C25 C26 C27 119.2(8) . . ?
C28 C27 C26 120.3(9) . . ?
C27 C28 C29 121.5(8) . . ?
C30 C29 C28 118.2(8) . . ?
C25 C30 C29 121.1(8) . . ?
C32 C31 C36 120.1(7) . . ?
C32 C31 P5 117.2(6) . . ?
C36 C31 P5 122.7(6) . . ?
C31 C32 C33 120.9(8) . . ?
C32 C33 C34 118.9(9) . . ?
C35 C34 C33 120.4(9) . . ?
C36 C35 C34 120.0(9) . . ?
C35 C36 C31 119.6(9) . . ?
C38 C37 C42 122.4(6) . . ?
C38 C37 O4 118.8(6) . . ?
C42 C37 O4 118.8(6) . . ?
C37 C38 C39 120.2(7) . . ?
C38 C39 C40 119.1(7) . . ?
C41 C40 C39 120.9(7) . . ?
C40 C41 C42 120.3(7) . . ?
C37 C42 C41 117.1(6) . . ?
C37 C42 C43 122.0(6) . . ?
C41 C42 C43 120.9(6) . . ?
C44 C43 C48 116.8(6) . . ?
C44 C43 C42 122.3(6) . . ?
C48 C43 C42 120.9(6) . . ?
C45 C44 C43 120.8(7) . . ?
C46 C45 C44 120.3(7) . . ?
C45 C46 C47 121.1(7) . . ?
C48 C47 C46 117.8(7) . . ?
C47 C48 C43 123.1(6) . . ?
C47 C48 O3 118.3(6) . . ?
C43 C48 O3 118.5(6) . . ?
C50 C49 C54 124.1(7) . . ?
C50 C49 O5 117.4(6) . . ?
C54 C49 O5 118.4(6) . . ?
C49 C50 C51 117.6(8) . . ?
C52 C51 C50 121.2(8) . . ?
C51 C52 C53 119.4(7) . . ?
C52 C53 C54 121.9(7) . . ?
C49 C54 C53 115.9(7) . . ?
C49 C54 C55 121.9(6) . . ?
C53 C54 C55 122.3(7) . . ?
C60 C55 C56 116.9(7) . . ?
C60 C55 C54 122.4(6) . . ?
C56 C55 C54 120.7(7) . . ?
C57 C56 C55 120.1(8) . . ?
C56 C57 C58 121.0(8) . . ?
C59 C58 C57 119.6(8) . . ?
C60 C59 C58 118.9(7) . . ?
C59 C60 C55 123.3(7) . . ?
C59 C60 O6 118.4(6) . . ?
C55 C60 O6 118.1(6) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 P4 2.2256(19) . ?
Au1 Cl1 2.282(2) . ?
Au2 P5 2.2244(19) . ?
Au2 Cl2 2.2890(18) . ?
P1 N1 1.571(5) . ?
P1 N3 1.572(6) . ?
P1 O2 1.580(4) . ?
P1 O1 1.604(5) . ?
P2 N2 1.577(6) . ?
P2 O3 1.580(4) . ?
P2 N1 1.584(5) . ?
P2 O4 1.589(5) . ?
P3 N3 1.573(5) . ?
P3 O5 1.581(5) . ?
P3 N2 1.582(5) . ?
P3 O6 1.585(5) . ?
P4 C13 1.800(7) . ?
P4 C6 1.819(6) . ?
P4 C7 1.828(7) . ?
P5 C25 1.809(7) . ?
P5 C31 1.817(7) . ?
P5 C24 1.822(7) . ?
O1 C1 1.392(8) . ?
O2 C19 1.394(8) . ?
O3 C48 1.418(8) . ?
O4 C37 1.409(7) . ?
O5 C49 1.432(8) . ?
O6 C60 1.416(8) . ?
C1 C6 1.380(9) . ?
C1 C2 1.408(9) . ?
C2 C3 1.375(10) . ?
C3 C4 1.380(10) . ?
C4 C5 1.383(9) . ?
C5 C6 1.390(9) . ?
C7 C8 1.373(11) . ?
C7 C12 1.378(10) . ?
C8 C9 1.366(12) . ?
C9 C10 1.362(13) . ?
C10 C11 1.366(13) . ?
C11 C12 1.384(12) . ?
C13 C14 1.389(11) . ?
C13 C18 1.390(9) . ?
C14 C15 1.386(12) . ?
C15 C16 1.405(14) . ?
C16 C17 1.320(14) . ?
C17 C18 1.369(11) . ?
C19 C20 1.391(9) . ?
C19 C24 1.394(10) . ?
C20 C21 1.370(10) . ?
C21 C22 1.371(11) . ?
C22 C23 1.401(11) . ?
C23 C24 1.383(10) . ?
C25 C30 1.365(11) . ?
C25 C26 1.404(11) . ?
C26 C27 1.407(11) . ?
C27 C28 1.339(13) . ?
C28 C29 1.407(13) . ?
C29 C30 1.395(11) . ?
C31 C32 1.371(11) . ?
C31 C36 1.399(11) . ?
C32 C33 1.379(11) . ?
C33 C34 1.392(14) . ?
C34 C35 1.391(14) . ?
C35 C36 1.373(12) . ?
C37 C38 1.373(10) . ?
C37 C42 1.392(9) . ?
C38 C39 1.376(11) . ?
C39 C40 1.389(10) . ?
C40 C41 1.386(11) . ?
C41 C42 1.407(9) . ?
C42 C43 1.479(10) . ?
C43 C44 1.401(9) . ?
C43 C48 1.401(9) . ?
C44 C45 1.381(10) . ?
C45 C46 1.372(10) . ?
C46 C47 1.387(10) . ?
C47 C48 1.376(9) . ?
C49 C50 1.356(10) . ?
C49 C54 1.388(10) . ?
C50 C51 1.397(10) . ?
C51 C52 1.360(12) . ?
C52 C53 1.380(11) . ?
C53 C54 1.395(9) . ?
C54 C55 1.493(10) . ?
C55 C60 1.378(10) . ?
C55 C56 1.420(10) . ?
C56 C57 1.362(12) . ?
C57 C58 1.386(12) . ?
C58 C59 1.382(10) . ?
C59 C60 1.362(10) . ?
