#------------------------------------------------------------------------------
#$Date: 2016-03-25 11:07:29 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179776 $
#$URL: svn://www.crystallography.net/cod/cif/7/00/72/7007294.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7007294
loop_
_publ_author_name
'Jaganyi, Deogaratius'
'Tiba, Felicia'
'Munro, Orde Q.'
'Petrović, Biljana'
'Bugarcić, Zivadin D'
_publ_section_title
;
 Kinetic and mechanistic study on the reactions of [Pt(bpma)(H2O)]2+
 and [Pd(bpma)(H2O)]2+ with some nucleophiles. Crystal structure of
 [Pd(bpma)(py)](ClO4)2.
;
_journal_issue                   24
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              2943
_journal_page_last               2949
_journal_paper_doi               10.1039/b602950g
_journal_year                    2006
_chemical_formula_moiety         'C17 H18 N4 Pd, 2(Cl O4)'
_chemical_formula_sum            'C17 H18 Cl2 N4 O8 Pd'
_chemical_formula_weight         583.65
_chemical_name_common            '[Pd(pap)py](ClO4)2'
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                89.20(2)
_cell_angle_beta                 81.03(2)
_cell_angle_gamma                60.61(2)
_cell_formula_units_Z            2
_cell_length_a                   8.522(2)
_cell_length_b                   8.627(2)
_cell_length_c                   16.730(4)
_cell_measurement_reflns_used    2149
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      32
_cell_measurement_theta_min      4
_cell_volume                     1055.8(5)
_computing_cell_refinement       'CrysAlis RED 170'
_computing_data_collection       'CrysAlis CCD 170'
_computing_data_reduction        'CrysAlis RED 170'
_computing_molecular_graphics    'WinGX (Farrugia, 1999)'
_computing_publication_material  'ORTEP-3 (Farrugia, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.991
_diffrn_measured_fraction_theta_max 0.887
_diffrn_measurement_device_type  'Oxford Diffraction Xcalibur 2 CCD'
_diffrn_measurement_method       'omega-2theta scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0318
_diffrn_reflns_av_sigmaI/netI    0.0400
_diffrn_reflns_limit_h_max       7
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_number            10217
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         31.61
_diffrn_reflns_theta_min         4.73
_exptl_absorpt_coefficient_mu    1.186
_exptl_absorpt_correction_T_max  0.659
_exptl_absorpt_correction_T_min  0.564
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
[c.f. r.h. blessing, acta cryst. (1995), a51, 33-38]
;
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.836
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       'rectangular block'
_exptl_crystal_F_000             584
_exptl_crystal_size_max          0.45
_exptl_crystal_size_mid          0.40
_exptl_crystal_size_min          0.35
_refine_diff_density_max         1.112
_refine_diff_density_min         -1.141
_refine_diff_density_rms         0.116
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.082
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     330
_refine_ls_number_reflns         6296
_refine_ls_number_restraints     93
_refine_ls_restrained_S_all      1.078
_refine_ls_R_factor_all          0.0701
_refine_ls_R_factor_gt           0.0541
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0723P)²+1.3562P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1365
_refine_ls_wR_factor_ref         0.1475
_reflns_number_gt                5089
_reflns_number_total             6296
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b602950g.txt
_cod_data_source_block           pd_pap
_cod_original_cell_volume        1055.7(5)
_cod_database_code               7007294
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.9559(6) 0.4348(6) 0.7007(3) 0.0499(9) Uani 1 1 d . . .
H1 H 0.9621 0.3587 0.7416 0.060 Uiso 1 1 calc R . .
C2 C 1.1158(7) 0.4168(7) 0.6571(3) 0.0619(13) Uani 1 1 d . . .
H2 H 1.2283 0.3302 0.6687 0.074 Uiso 1 1 calc R . .
C3 C 1.1074(8) 0.5278(9) 0.5965(3) 0.0664(15) Uani 1 1 d . . .
H3 H 1.2143 0.5173 0.5668 0.080 Uiso 1 1 calc R . .
C4 C 0.9386(7) 0.6560(8) 0.5798(3) 0.0592(12) Uani 1 1 d . . .
H4 H 0.9306 0.7325 0.5389 0.071 Uiso 1 1 calc R . .
C5 C 0.7816(6) 0.6675(6) 0.6253(3) 0.0464(9) Uani 1 1 d . . .
C6 C 0.5927(7) 0.8043(7) 0.6137(3) 0.0565(11) Uani 1 1 d . . .
H6A H 0.5548 0.9150 0.6445 0.068 Uiso 1 1 calc R . .
H6B H 0.5921 0.8278 0.5568 0.068 Uiso 1 1 calc R . .
C7 C 0.2699(6) 0.8779(6) 0.6639(3) 0.0541(11) Uani 1 1 d . . .
H7A H 0.2129 0.9091 0.6159 0.065 Uiso 1 1 calc R . .
H7B H 0.2623 0.9841 0.6873 0.065 Uiso 1 1 calc R . .
C8 C 0.1716(5) 0.8109(5) 0.7241(2) 0.0431(8) Uani 1 1 d . . .
C9 C -0.0178(6) 0.8836(6) 0.7380(3) 0.0558(11) Uani 1 1 d . . .
H9 H -0.0891 0.9732 0.7069 0.067 Uiso 1 1 calc R . .
C10 C -0.0981(6) 0.8223(7) 0.7979(3) 0.0601(13) Uani 1 1 d . . .
H10 H -0.2245 0.8714 0.8083 0.072 Uiso 1 1 calc R . .
C11 C 0.0088(7) 0.6884(8) 0.8422(4) 0.0643(13) Uani 1 1 d . . .
H11 H -0.0438 0.6451 0.8829 0.077 Uiso 1 1 calc R . .
C12 C 0.1948(6) 0.6187(7) 0.8258(3) 0.0492(9) Uani 1 1 d . . .
H12 H 0.2675 0.5255 0.8550 0.059 Uiso 1 1 calc R . .
C13 C 0.6671(6) 0.5451(6) 0.8941(2) 0.0442(8) Uani 1 1 d . . .
H13 H 0.6497 0.6594 0.8873 0.053 Uiso 1 1 calc R . .
C14 C 0.7363(6) 0.4591(7) 0.9611(3) 0.0526(10) Uani 1 1 d . . .
H14 H 0.7705 0.5120 0.9979 0.063 Uiso 1 1 calc R . .
C15 C 0.7536(7) 0.2925(7) 0.9724(3) 0.0592(12) Uani 1 1 d . . .
H15 H 0.8003 0.2313 1.0169 0.071 Uiso 1 1 calc R . .
C16 C 0.7010(8) 0.2188(6) 0.9173(3) 0.0595(12) Uani 1 1 d . . .
H16 H 0.7073 0.1090 0.9250 0.071 Uiso 1 1 calc R . .
C17 C 0.6392(6) 0.3082(6) 0.8506(3) 0.0482(9) Uani 1 1 d . . .
H17 H 0.6066 0.2563 0.8127 0.058 Uiso 1 1 calc R . .
N1 N 0.7923(5) 0.5584(5) 0.6860(2) 0.0427(7) Uani 1 1 d . . .
N2 N 0.4640(5) 0.7380(5) 0.6413(2) 0.0428(7) Uani 1 1 d . . .
N3 N 0.2747(4) 0.6802(5) 0.7694(2) 0.0399(7) Uani 1 1 d . . .
N4 N 0.6243(4) 0.4681(4) 0.83865(18) 0.0345(6) Uani 1 1 d . . .
Pd1 Pd 0.54335(4) 0.60015(4) 0.737957(17) 0.03905(11) Uani 1 1 d . . .
Cl1 Cl 0.28713(16) 1.10315(14) 0.87302(8) 0.0529(3) Uani 1 1 d D . .
O1 O 0.4641(16) 0.9846(17) 0.8548(17) 0.207(15) Uani 0.502(19) 1 d PDU A 1
O2 O 0.257(3) 1.208(3) 0.9378(13) 0.221(16) Uani 0.502(19) 1 d PDU A 1
O3 O 0.227(3) 1.197(3) 0.8117(13) 0.254(16) Uani 0.502(19) 1 d PDU A 1
O4 O 0.1992(19) 1.0093(17) 0.8912(11) 0.112(6) Uani 0.502(19) 1 d PDU A 1
Cl2 Cl 0.68023(15) 0.21952(14) 0.58002(6) 0.0465(2) Uani 1 1 d . . .
O5 O 0.6828(13) 0.0908(10) 0.5307(3) 0.144(3) Uani 1 1 d U . .
O6 O 0.5951(8) 0.2243(10) 0.6587(3) 0.114(2) Uani 1 1 d U . .
O7 O 0.6071(13) 0.3799(8) 0.5449(4) 0.159(3) Uani 1 1 d U . .
O8 O 0.8592(9) 0.1767(13) 0.5844(5) 0.157(3) Uani 1 1 d U . .
O4' O 0.1432(15) 1.121(3) 0.8341(12) 0.145(10) Uani 0.498(19) 1 d PU A 2
O1' O 0.338(6) 0.990(4) 0.9183(18) 0.33(2) Uani 0.498(19) 1 d PU A 2
O3' O 0.430(2) 1.058(3) 0.8064(11) 0.145(9) Uani 0.498(19) 1 d PU A 2
O2' O 0.221(3) 1.270(2) 0.9102(16) 0.139(9) Uani 0.498(19) 1 d PU A 2
H100 H 0.482(8) 0.643(8) 0.600(3) 0.064(16) Uiso 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pd Pd -0.9988 1.0072 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 C1 C2 121.8(5) . . ?
N1 C1 H1 119.1 . . ?
C2 C1 H1 119.1 . . ?
C3 C2 C1 119.3(5) . . ?
C3 C2 H2 120.3 . . ?
C1 C2 H2 120.3 . . ?
C2 C3 C4 119.7(5) . . ?
C2 C3 H3 120.2 . . ?
C4 C3 H3 120.2 . . ?
C3 C4 C5 118.6(5) . . ?
C3 C4 H4 120.7 . . ?
C5 C4 H4 120.7 . . ?
N1 C5 C4 121.0(5) . . ?
N1 C5 C6 116.1(4) . . ?
C4 C5 C6 122.8(4) . . ?
N2 C6 C5 109.6(4) . . ?
N2 C6 H6A 109.8 . . ?
C5 C6 H6A 109.8 . . ?
N2 C6 H6B 109.8 . . ?
C5 C6 H6B 109.8 . . ?
H6A C6 H6B 108.2 . . ?
N2 C7 C8 109.7(3) . . ?
N2 C7 H7A 109.7 . . ?
C8 C7 H7A 109.7 . . ?
N2 C7 H7B 109.7 . . ?
C8 C7 H7B 109.7 . . ?
H7A C7 H7B 108.2 . . ?
N3 C8 C9 119.9(4) . . ?
N3 C8 C7 116.7(4) . . ?
C9 C8 C7 123.3(4) . . ?
C10 C9 C8 119.6(4) . . ?
C10 C9 H9 120.2 . . ?
C8 C9 H9 120.2 . . ?
C11 C10 C9 119.5(4) . . ?
C11 C10 H10 120.2 . . ?
C9 C10 H10 120.2 . . ?
C10 C11 C12 119.0(5) . . ?
C10 C11 H11 120.5 . . ?
C12 C11 H11 120.5 . . ?
N3 C12 C11 122.2(5) . . ?
N3 C12 H12 118.9 . . ?
C11 C12 H12 118.9 . . ?
N4 C13 C14 121.7(4) . . ?
N4 C13 H13 119.2 . . ?
C14 C13 H13 119.2 . . ?
C13 C14 C15 118.6(4) . . ?
C13 C14 H14 120.7 . . ?
C15 C14 H14 120.7 . . ?
C16 C15 C14 119.2(4) . . ?
C16 C15 H15 120.4 . . ?
C14 C15 H15 120.4 . . ?
C17 C16 C15 119.4(5) . . ?
C17 C16 H16 120.3 . . ?
C15 C16 H16 120.3 . . ?
N4 C17 C16 121.8(4) . . ?
N4 C17 H17 119.1 . . ?
C16 C17 H17 119.1 . . ?
C1 N1 C5 119.6(4) . . ?
C1 N1 Pd1 128.5(3) . . ?
C5 N1 Pd1 111.8(3) . . ?
C6 N2 C7 115.2(4) . . ?
C6 N2 Pd1 107.5(3) . . ?
C7 N2 Pd1 108.4(3) . . ?
C6 N2 H100 110(3) . . ?
C7 N2 H100 112(3) . . ?
Pd1 N2 H100 103(3) . . ?
C12 N3 C8 119.6(4) . . ?
C12 N3 Pd1 128.3(3) . . ?
C8 N3 Pd1 112.1(3) . . ?
C17 N4 C13 119.3(3) . . ?
C17 N4 Pd1 122.8(3) . . ?
C13 N4 Pd1 117.9(3) . . ?
N2 Pd1 N1 83.57(15) . . ?
N2 Pd1 N3 83.33(14) . . ?
N1 Pd1 N3 166.78(14) . . ?
N2 Pd1 N4 177.67(14) . . ?
N1 Pd1 N4 95.98(13) . . ?
N3 Pd1 N4 97.05(13) . . ?
O1' Cl1 O3 165(2) . . ?
O1' Cl1 O1 66.0(19) . . ?
O3 Cl1 O1 111.5(10) . . ?
O1' Cl1 O2 83(2) . . ?
O3 Cl1 O2 111.1(10) . . ?
O1 Cl1 O2 109.7(10) . . ?
O1' Cl1 O4 60(2) . . ?
O3 Cl1 O4 108.9(10) . . ?
O1 Cl1 O4 106.5(8) . . ?
O2 Cl1 O4 108.9(10) . . ?
O1' Cl1 O2' 112(2) . . ?
O3 Cl1 O2' 81.6(16) . . ?
O1 Cl1 O2' 123.4(13) . . ?
O4 Cl1 O2' 121.0(10) . . ?
O1' Cl1 O3' 108(2) . . ?
O3 Cl1 O3' 68.6(12) . . ?
O2 Cl1 O3' 124.1(12) . . ?
O4 Cl1 O3' 124.4(10) . . ?
O2' Cl1 O3' 113.7(11) . . ?
O1' Cl1 O4' 116(3) . . ?
O3 Cl1 O4' 52.4(12) . . ?
O1 Cl1 O4' 128.2(12) . . ?
O2 Cl1 O4' 122.1(12) . . ?
O4 Cl1 O4' 56.7(10) . . ?
O2' Cl1 O4' 104.0(12) . . ?
O3' Cl1 O4' 101.9(10) . . ?
O7 Cl2 O5 109.7(5) . . ?
O7 Cl2 O6 114.9(5) . . ?
O5 Cl2 O6 110.5(4) . . ?
O7 Cl2 O8 105.0(6) . . ?
O5 Cl2 O8 109.5(6) . . ?
O6 Cl2 O8 106.9(4) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 N1 1.335(6) . ?
C1 C2 1.378(6) . ?
C1 H1 0.9300 . ?
C2 C3 1.370(9) . ?
C2 H2 0.9300 . ?
C3 C4 1.388(9) . ?
C3 H3 0.9300 . ?
C4 C5 1.390(6) . ?
C4 H4 0.9300 . ?
C5 N1 1.357(6) . ?
C5 C6 1.500(7) . ?
C6 N2 1.481(6) . ?
C6 H6A 0.9700 . ?
C6 H6B 0.9700 . ?
C7 N2 1.481(6) . ?
C7 C8 1.499(6) . ?
C7 H7A 0.9700 . ?
C7 H7B 0.9700 . ?
C8 N3 1.352(5) . ?
C8 C9 1.395(6) . ?
C9 C10 1.371(8) . ?
C9 H9 0.9300 . ?
C10 C11 1.366(8) . ?
C10 H10 0.9300 . ?
C11 C12 1.372(6) . ?
C11 H11 0.9300 . ?
C12 N3 1.333(6) . ?
C12 H12 0.9300 . ?
C13 N4 1.339(5) . ?
C13 C14 1.382(6) . ?
C13 H13 0.9300 . ?
C14 C15 1.384(8) . ?
C14 H14 0.9300 . ?
C15 C16 1.372(8) . ?
C15 H15 0.9300 . ?
C16 C17 1.370(6) . ?
C16 H16 0.9300 . ?
C17 N4 1.337(5) . ?
C17 H17 0.9300 . ?
N1 Pd1 2.017(3) . ?
N2 Pd1 1.996(3) . ?
N2 H100 1.02(6) . ?
N3 Pd1 2.019(3) . ?
N4 Pd1 2.037(3) . ?
Cl1 O1' 1.175(15) . ?
Cl1 O3 1.305(12) . ?
Cl1 O1 1.329(10) . ?
Cl1 O2 1.329(12) . ?
Cl1 O4 1.351(8) . ?
Cl1 O2' 1.380(14) . ?
Cl1 O3' 1.416(12) . ?
Cl1 O4' 1.419(11) . ?
Cl2 O7 1.375(6) . ?
Cl2 O5 1.382(5) . ?
Cl2 O6 1.391(5) . ?
Cl2 O8 1.396(6) . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N1 C1 C2 C3 -0.4(7) . . . . ?
C1 C2 C3 C4 -0.2(8) . . . . ?
C2 C3 C4 C5 -0.2(7) . . . . ?
C3 C4 C5 N1 1.3(7) . . . . ?
C3 C4 C5 C6 178.2(4) . . . . ?
N1 C5 C6 N2 -27.9(6) . . . . ?
C4 C5 C6 N2 155.0(4) . . . . ?
N2 C7 C8 N3 24.7(5) . . . . ?
N2 C7 C8 C9 -159.2(4) . . . . ?
N3 C8 C9 C10 0.2(6) . . . . ?
C7 C8 C9 C10 -175.8(4) . . . . ?
C8 C9 C10 C11 -1.2(7) . . . . ?
C9 C10 C11 C12 0.2(8) . . . . ?
C10 C11 C12 N3 1.7(8) . . . . ?
N4 C13 C14 C15 -2.9(7) . . . . ?
C13 C14 C15 C16 -0.3(7) . . . . ?
C14 C15 C16 C17 2.5(8) . . . . ?
C15 C16 C17 N4 -1.6(8) . . . . ?
C2 C1 N1 C5 1.5(7) . . . . ?
C2 C1 N1 Pd1 176.6(3) . . . . ?
C4 C5 N1 C1 -2.0(6) . . . . ?
C6 C5 N1 C1 -179.1(4) . . . . ?
C4 C5 N1 Pd1 -177.8(3) . . . . ?
C6 C5 N1 Pd1 5.0(5) . . . . ?
C5 C6 N2 C7 157.0(4) . . . . ?
C5 C6 N2 Pd1 36.2(4) . . . . ?
C8 C7 N2 C6 -153.9(4) . . . . ?
C8 C7 N2 Pd1 -33.5(4) . . . . ?
C11 C12 N3 C8 -2.6(7) . . . . ?
C11 C12 N3 Pd1 178.6(4) . . . . ?
C9 C8 N3 C12 1.7(6) . . . . ?
C7 C8 N3 C12 177.9(4) . . . . ?
C9 C8 N3 Pd1 -179.4(3) . . . . ?
C7 C8 N3 Pd1 -3.1(4) . . . . ?
C16 C17 N4 C13 -1.5(6) . . . . ?
C16 C17 N4 Pd1 177.3(4) . . . . ?
C14 C13 N4 C17 3.8(6) . . . . ?
C14 C13 N4 Pd1 -175.1(3) . . . . ?
C6 N2 Pd1 N1 -27.3(3) . . . . ?
C7 N2 Pd1 N1 -152.4(3) . . . . ?
C6 N2 Pd1 N3 151.0(3) . . . . ?
C7 N2 Pd1 N3 25.9(3) . . . . ?
C1 N1 Pd1 N2 -162.4(4) . . . . ?
C5 N1 Pd1 N2 13.0(3) . . . . ?
C1 N1 Pd1 N3 -169.8(5) . . . . ?
C5 N1 Pd1 N3 5.6(7) . . . . ?
C1 N1 Pd1 N4 19.9(4) . . . . ?
C5 N1 Pd1 N4 -164.7(3) . . . . ?
C12 N3 Pd1 N2 165.6(4) . . . . ?
C8 N3 Pd1 N2 -13.2(3) . . . . ?
C12 N3 Pd1 N1 173.0(5) . . . . ?
C8 N3 Pd1 N1 -5.8(7) . . . . ?
C12 N3 Pd1 N4 -16.7(4) . . . . ?
C8 N3 Pd1 N4 164.5(3) . . . . ?
C17 N4 Pd1 N1 -106.8(3) . . . . ?
C13 N4 Pd1 N1 72.1(3) . . . . ?
C17 N4 Pd1 N3 75.4(3) . . . . ?
C13 N4 Pd1 N3 -105.7(3) . . . . ?
