#------------------------------------------------------------------------------
#$Date: 2016-03-25 11:10:05 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179778 $
#$URL: svn://www.crystallography.net/cod/cif/7/00/74/7007400.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7007400
loop_
_publ_author_name
'Aldridge, Simon'
'Baker, Robert J.'
'Coombs, Natalie D.'
'Jones, Cameron'
'Rose, Richard P.'
'Rossin, Andrea'
'Willock, David J.'
_publ_section_title
;
 Complexes of a gallium heterocycle with transition metal
 dicyclopentadienyl and cyclopentadienylcarbonyl fragments, and with a
 dialkylmanganese compound.
;
_journal_issue                   27
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              3313
_journal_page_last               3320
_journal_paper_doi               10.1039/b604640a
_journal_year                    2006
_chemical_formula_sum            'C38 H50 Ga N2 V'
_chemical_formula_weight         655.46
_chemical_name_systematic
;
?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 93.39(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   13.340(3)
_cell_length_b                   16.734(3)
_cell_length_c                   15.496(3)
_cell_measurement_temperature    150(2)
_cell_volume                     3453.1(12)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      150(2)
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'Nonius Kappa CCD'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0941
_diffrn_reflns_av_sigmaI/netI    0.0947
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            18418
_diffrn_reflns_theta_full        25.31
_diffrn_reflns_theta_max         25.31
_diffrn_reflns_theta_min         2.97
_exptl_absorpt_coefficient_mu    1.078
_exptl_absorpt_correction_T_max  0.909
_exptl_absorpt_correction_T_min  0.713
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Sortav (Blessing, 1995)'
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.261
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1384
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.10
_refine_diff_density_max         0.665
_refine_diff_density_min         -0.505
_refine_diff_density_rms         0.085
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.019
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     390
_refine_ls_number_reflns         6267
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.019
_refine_ls_R_factor_all          0.0997
_refine_ls_R_factor_gt           0.0588
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0479P)²+3.0801P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1184
_refine_ls_wR_factor_ref         0.1360
_reflns_number_gt                4238
_reflns_number_total             6267
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b604640a.txt
_cod_data_source_block           compound13
_cod_original_sg_symbol_H-M      P2(1)/c
_cod_database_code               7007400
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ga1 Ga 0.26997(3) 0.01678(3) 0.76996(3) 0.02199(16) Uani 1 1 d . . .
V1 V 0.27570(5) -0.13426(4) 0.77602(4) 0.0237(2) Uani 1 1 d . . .
N1 N 0.3613(3) 0.09943(19) 0.7447(2) 0.0249(8) Uani 1 1 d . . .
N2 N 0.1783(2) 0.09967(19) 0.7941(2) 0.0225(8) Uani 1 1 d . . .
C1 C 0.3183(3) 0.1739(2) 0.7565(3) 0.0281(10) Uani 1 1 d . . .
H1 H 0.3537 0.2220 0.7469 0.034 Uiso 1 1 calc R . .
C2 C 0.2238(3) 0.1742(2) 0.7823(3) 0.0269(10) Uani 1 1 d . . .
H2 H 0.1894 0.2228 0.7921 0.032 Uiso 1 1 calc R . .
C3 C 0.4570(3) 0.0932(2) 0.7084(3) 0.0235(9) Uani 1 1 d . . .
C4 C 0.4695(3) 0.1194(2) 0.6233(3) 0.0266(10) Uani 1 1 d . . .
C5 C 0.5635(3) 0.1109(3) 0.5896(3) 0.0319(11) Uani 1 1 d . . .
H5 H 0.5733 0.1296 0.5329 0.038 Uiso 1 1 calc R . .
C6 C 0.6430(3) 0.0757(3) 0.6371(3) 0.0356(11) Uani 1 1 d . . .
H6 H 0.7064 0.0696 0.6129 0.043 Uiso 1 1 calc R . .
C7 C 0.6290(3) 0.0497(3) 0.7199(3) 0.0327(11) Uani 1 1 d . . .
H7 H 0.6835 0.0255 0.7523 0.039 Uiso 1 1 calc R . .
C8 C 0.5374(3) 0.0577(3) 0.7574(3) 0.0293(10) Uani 1 1 d . . .
C9 C 0.3841(3) 0.1550(3) 0.5662(3) 0.0324(11) Uani 1 1 d . . .
H9 H 0.3229 0.1566 0.6005 0.039 Uiso 1 1 calc R . .
C10 C 0.4080(4) 0.2405(3) 0.5396(4) 0.0622(17) Uani 1 1 d . . .
H10A H 0.4168 0.2741 0.5913 0.093 Uiso 1 1 calc R . .
H10B H 0.3525 0.2614 0.5018 0.093 Uiso 1 1 calc R . .
H10C H 0.4699 0.2408 0.5085 0.093 Uiso 1 1 calc R . .
C11 C 0.3606(4) 0.1024(4) 0.4871(3) 0.0601(16) Uani 1 1 d . . .
H11A H 0.4197 0.0997 0.4525 0.090 Uiso 1 1 calc R . .
H11B H 0.3041 0.1253 0.4522 0.090 Uiso 1 1 calc R . .
H11C H 0.3431 0.0486 0.5059 0.090 Uiso 1 1 calc R . .
C12 C 0.5283(4) 0.0335(3) 0.8520(3) 0.0380(12) Uani 1 1 d . . .
H12 H 0.4617 0.0068 0.8564 0.046 Uiso 1 1 calc R . .
C13 C 0.6090(4) -0.0245(3) 0.8867(4) 0.0519(14) Uani 1 1 d . . .
H13A H 0.6067 -0.0731 0.8514 0.078 Uiso 1 1 calc R . .
H13B H 0.5971 -0.0382 0.9467 0.078 Uiso 1 1 calc R . .
H13C H 0.6752 0.0006 0.8844 0.078 Uiso 1 1 calc R . .
C14 C 0.5286(4) 0.1094(3) 0.9084(3) 0.0490(14) Uani 1 1 d . . .
H14A H 0.5234 0.0943 0.9690 0.073 Uiso 1 1 calc R . .
H14B H 0.4715 0.1432 0.8897 0.073 Uiso 1 1 calc R . .
H14C H 0.5913 0.1388 0.9022 0.073 Uiso 1 1 calc R . .
C15 C 0.0785(3) 0.0987(2) 0.8203(2) 0.0205(9) Uani 1 1 d . . .
C16 C 0.0554(3) 0.1306(2) 0.9009(3) 0.0238(9) Uani 1 1 d . . .
C17 C -0.0446(3) 0.1312(2) 0.9236(3) 0.0280(10) Uani 1 1 d . . .
H17 H -0.0608 0.1540 0.9772 0.034 Uiso 1 1 calc R . .
C18 C -0.1200(3) 0.0992(3) 0.8694(3) 0.0325(11) Uani 1 1 d . . .
H18 H -0.1877 0.1004 0.8852 0.039 Uiso 1 1 calc R . .
C19 C -0.0965(3) 0.0655(3) 0.7922(3) 0.0308(10) Uani 1 1 d . . .
H19 H -0.1489 0.0428 0.7558 0.037 Uiso 1 1 calc R . .
C20 C 0.0009(3) 0.0634(2) 0.7656(3) 0.0245(9) Uani 1 1 d . . .
C21 C 0.1353(3) 0.1616(3) 0.9659(3) 0.0333(11) Uani 1 1 d . . .
H21 H 0.2019 0.1560 0.9402 0.040 Uiso 1 1 calc R . .
C22 C 0.1378(4) 0.1119(4) 1.0492(3) 0.0520(14) Uani 1 1 d . . .
H22A H 0.0731 0.1164 1.0756 0.078 Uiso 1 1 calc R . .
H22B H 0.1914 0.1317 1.0896 0.078 Uiso 1 1 calc R . .
H22C H 0.1506 0.0558 1.0355 0.078 Uiso 1 1 calc R . .
C23 C 0.1191(4) 0.2496(3) 0.9854(4) 0.0519(14) Uani 1 1 d . . .
H23A H 0.1225 0.2807 0.9321 0.078 Uiso 1 1 calc R . .
H23B H 0.1714 0.2679 1.0279 0.078 Uiso 1 1 calc R . .
H23C H 0.0531 0.2568 1.0088 0.078 Uiso 1 1 calc R . .
C24 C 0.0237(3) 0.0282(3) 0.6792(3) 0.0346(11) Uani 1 1 d . . .
H24 H 0.0846 -0.0062 0.6889 0.041 Uiso 1 1 calc R . .
C25 C -0.0602(4) -0.0249(3) 0.6389(3) 0.0478(13) Uani 1 1 d . . .
H25A H -0.0825 -0.0623 0.6825 0.072 Uiso 1 1 calc R . .
H25B H -0.0350 -0.0549 0.5904 0.072 Uiso 1 1 calc R . .
H25C H -0.1169 0.0086 0.6180 0.072 Uiso 1 1 calc R . .
C26 C 0.0499(4) 0.0934(3) 0.6154(3) 0.0542(15) Uani 1 1 d . . .
H26A H -0.0085 0.1282 0.6037 0.081 Uiso 1 1 calc R . .
H26B H 0.0687 0.0688 0.5613 0.081 Uiso 1 1 calc R . .
H26C H 0.1063 0.1252 0.6401 0.081 Uiso 1 1 calc R . .
C27 C 0.2781(4) -0.1538(3) 0.6296(3) 0.0355(11) Uani 1 1 d . . .
C28 C 0.3595(4) -0.1022(3) 0.6556(3) 0.0378(12) Uani 1 1 d . . .
H28 H 0.3678 -0.0486 0.6371 0.045 Uiso 1 1 calc R . .
C29 C 0.4255(4) -0.1444(3) 0.7137(3) 0.0461(13) Uani 1 1 d . . .
H29 H 0.4861 -0.1244 0.7409 0.055 Uiso 1 1 calc R . .
C30 C 0.3856(4) -0.2211(3) 0.7243(3) 0.0432(13) Uani 1 1 d . . .
H30 H 0.4144 -0.2623 0.7599 0.052 Uiso 1 1 calc R . .
C31 C 0.2952(4) -0.2262(3) 0.6726(3) 0.0366(12) Uani 1 1 d . . .
H31 H 0.2527 -0.2717 0.6679 0.044 Uiso 1 1 calc R . .
C32 C 0.1924(4) -0.1349(4) 0.5664(3) 0.0590(16) Uani 1 1 d . . .
H32A H 0.2046 -0.1589 0.5103 0.089 Uiso 1 1 calc R . .
H32B H 0.1862 -0.0768 0.5599 0.089 Uiso 1 1 calc R . .
H32C H 0.1301 -0.1566 0.5875 0.089 Uiso 1 1 calc R . .
C33 C 0.1309(3) -0.1851(3) 0.8276(3) 0.0282(10) Uani 1 1 d . . .
C34 C 0.1474(3) -0.1087(3) 0.8641(3) 0.0326(11) Uani 1 1 d . . .
H34 H 0.1046 -0.0637 0.8556 0.039 Uiso 1 1 calc R . .
C35 C 0.2392(4) -0.1105(3) 0.9159(3) 0.0377(12) Uani 1 1 d . . .
H35 H 0.2683 -0.0671 0.9480 0.045 Uiso 1 1 calc R . .
C36 C 0.2788(4) -0.1876(3) 0.9112(3) 0.0421(12) Uani 1 1 d . . .
H36 H 0.3392 -0.2063 0.9399 0.051 Uiso 1 1 calc R . .
C37 C 0.2126(4) -0.2325(3) 0.8561(3) 0.0354(11) Uani 1 1 d . . .
H37 H 0.2221 -0.2868 0.8406 0.043 Uiso 1 1 calc R . .
C38 C 0.0420(4) -0.2107(3) 0.7701(3) 0.0447(13) Uani 1 1 d . . .
H38A H 0.0621 -0.2537 0.7318 0.067 Uiso 1 1 calc R . .
H38B H 0.0172 -0.1651 0.7353 0.067 Uiso 1 1 calc R . .
H38C H -0.0113 -0.2299 0.8057 0.067 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
V V 0.3005 0.5294 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ga Ga 0.2307 1.6083 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Ga1 N2 86.39(14) . . ?
N1 Ga1 V1 135.78(10) . . ?
N2 Ga1 V1 137.74(10) . . ?
C30 V1 C31 36.58(17) . . ?
C30 V1 C37 89.86(18) . . ?
C31 V1 C37 87.48(17) . . ?
C30 V1 C36 95.66(19) . . ?
C31 V1 C36 113.05(18) . . ?
C37 V1 C36 36.24(17) . . ?
C30 V1 C29 36.15(17) . . ?
C31 V1 C29 60.34(18) . . ?
C37 V1 C29 123.05(19) . . ?
C36 V1 C29 113.1(2) . . ?
C30 V1 C35 129.17(19) . . ?
C31 V1 C35 146.69(18) . . ?
C37 V1 C35 59.77(17) . . ?
C36 V1 C35 35.67(17) . . ?
C29 V1 C35 131.08(19) . . ?
C30 V1 C34 149.28(18) . . ?
C31 V1 C34 132.40(17) . . ?
C37 V1 C34 59.43(16) . . ?
C36 V1 C34 59.87(17) . . ?
C29 V1 C34 166.35(18) . . ?
C35 V1 C34 36.28(16) . . ?
C30 V1 C28 60.09(18) . . ?
C31 V1 C28 59.86(17) . . ?
C37 V1 C28 146.56(17) . . ?
C36 V1 C28 149.02(19) . . ?
C29 V1 C28 35.94(18) . . ?
C35 V1 C28 150.72(17) . . ?
C34 V1 C28 149.05(17) . . ?
C30 V1 C27 60.47(18) . . ?
C31 V1 C27 35.76(16) . . ?
C37 V1 C27 117.94(17) . . ?
C36 V1 C27 148.67(19) . . ?
C29 V1 C27 60.39(18) . . ?
C35 V1 C27 168.34(18) . . ?
C34 V1 C27 132.08(17) . . ?
C28 V1 C27 36.22(17) . . ?
C30 V1 C33 117.67(18) . . ?
C31 V1 C33 97.45(16) . . ?
C37 V1 C33 35.76(16) . . ?
C36 V1 C33 60.25(17) . . ?
C29 V1 C33 153.80(18) . . ?
C35 V1 C33 60.22(16) . . ?
C34 V1 C33 35.79(15) . . ?
C28 V1 C33 146.08(17) . . ?
C27 V1 C33 110.66(16) . . ?
C30 V1 Ga1 130.70(14) . . ?
C31 V1 Ga1 131.44(13) . . ?
C37 V1 Ga1 137.56(12) . . ?
C36 V1 Ga1 115.13(13) . . ?
C29 V1 Ga1 94.81(14) . . ?
C35 V1 Ga1 81.60(13) . . ?
C34 V1 Ga1 79.27(11) . . ?
C28 V1 Ga1 75.60(12) . . ?
C27 V1 Ga1 96.18(12) . . ?
C33 V1 Ga1 111.03(11) . . ?
C1 N1 C3 120.2(3) . . ?
C1 N1 Ga1 110.6(3) . . ?
C3 N1 Ga1 128.8(3) . . ?
C2 N2 C15 118.0(3) . . ?
C2 N2 Ga1 109.6(3) . . ?
C15 N2 Ga1 132.4(3) . . ?
C2 C1 N1 116.4(4) . . ?
C1 C2 N2 117.1(4) . . ?
C8 C3 C4 120.4(4) . . ?
C8 C3 N1 119.3(4) . . ?
C4 C3 N1 120.2(4) . . ?
C5 C4 C3 118.5(4) . . ?
C5 C4 C9 118.8(4) . . ?
C3 C4 C9 122.6(4) . . ?
C6 C5 C4 121.5(4) . . ?
C7 C6 C5 119.1(4) . . ?
C6 C7 C8 122.0(4) . . ?
C7 C8 C3 118.4(4) . . ?
C7 C8 C12 119.7(4) . . ?
C3 C8 C12 121.7(4) . . ?
C4 C9 C11 110.6(4) . . ?
C4 C9 C10 111.3(4) . . ?
C11 C9 C10 111.0(4) . . ?
C13 C12 C8 114.3(4) . . ?
C13 C12 C14 110.3(4) . . ?
C8 C12 C14 109.1(4) . . ?
C16 C15 N2 120.5(3) . . ?
C16 C15 C20 119.7(4) . . ?
N2 C15 C20 119.8(3) . . ?
C17 C16 C15 119.1(4) . . ?
C17 C16 C21 118.3(4) . . ?
C15 C16 C21 122.5(4) . . ?
C18 C17 C16 121.0(4) . . ?
C19 C18 C17 119.6(4) . . ?
C18 C19 C20 122.3(4) . . ?
C19 C20 C15 118.2(4) . . ?
C19 C20 C24 121.0(4) . . ?
C15 C20 C24 120.7(4) . . ?
C16 C21 C23 111.2(4) . . ?
C16 C21 C22 110.7(4) . . ?
C23 C21 C22 110.7(4) . . ?
C20 C24 C26 111.2(4) . . ?
C20 C24 C25 114.0(4) . . ?
C26 C24 C25 109.9(4) . . ?
C31 C27 C28 106.9(4) . . ?
C31 C27 C32 126.4(5) . . ?
C28 C27 C32 126.7(5) . . ?
C31 C27 V1 70.3(2) . . ?
C28 C27 V1 71.9(2) . . ?
C32 C27 V1 124.2(3) . . ?
C29 C28 C27 108.3(4) . . ?
C29 C28 V1 71.3(3) . . ?
C27 C28 V1 71.9(2) . . ?
C30 C29 C28 107.8(5) . . ?
C30 C29 V1 70.8(3) . . ?
C28 C29 V1 72.7(3) . . ?
C29 C30 C31 107.8(5) . . ?
C29 C30 V1 73.1(3) . . ?
C31 C30 V1 71.8(3) . . ?
C27 C31 C30 109.2(4) . . ?
C27 C31 V1 74.0(2) . . ?
C30 C31 V1 71.6(3) . . ?
C37 C33 C34 106.7(4) . . ?
C37 C33 C38 126.8(4) . . ?
C34 C33 C38 126.5(4) . . ?
C37 C33 V1 70.4(3) . . ?
C34 C33 V1 71.9(2) . . ?
C38 C33 V1 123.3(3) . . ?
C33 C34 C35 108.4(4) . . ?
C33 C34 V1 72.3(2) . . ?
C35 C34 V1 71.6(3) . . ?
C36 C35 C34 107.8(4) . . ?
C36 C35 V1 71.8(3) . . ?
C34 C35 V1 72.1(3) . . ?
C35 C36 C37 107.4(4) . . ?
C35 C36 V1 72.5(3) . . ?
C37 C36 V1 71.0(3) . . ?
C33 C37 C36 109.7(4) . . ?
C33 C37 V1 73.9(2) . . ?
C36 C37 V1 72.8(3) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ga1 N1 1.899(3) . ?
Ga1 N2 1.901(3) . ?
Ga1 V1 2.5303(9) . ?
V1 C30 2.246(5) . ?
V1 C31 2.248(4) . ?
V1 C37 2.253(4) . ?
V1 C36 2.275(4) . ?
V1 C29 2.276(5) . ?
V1 C35 2.285(4) . ?
V1 C34 2.292(4) . ?
V1 C28 2.294(4) . ?
V1 C27 2.295(4) . ?
V1 C33 2.297(4) . ?
N1 C1 1.389(5) . ?
N1 C3 1.428(5) . ?
N2 C2 1.404(5) . ?
N2 C15 1.416(5) . ?
C1 C2 1.344(5) . ?
C3 C8 1.408(6) . ?
C3 C4 1.410(6) . ?
C4 C5 1.393(6) . ?
C4 C9 1.522(6) . ?
C5 C6 1.386(6) . ?
C6 C7 1.378(6) . ?
C7 C8 1.390(6) . ?
C8 C12 1.533(6) . ?
C9 C11 1.526(7) . ?
C9 C10 1.528(6) . ?
C12 C13 1.524(7) . ?
C12 C14 1.540(7) . ?
C15 C16 1.410(5) . ?
C15 C20 1.426(6) . ?
C16 C17 1.399(6) . ?
C16 C21 1.514(6) . ?
C17 C18 1.381(6) . ?
C18 C19 1.375(6) . ?
C19 C20 1.387(6) . ?
C20 C24 1.511(6) . ?
C21 C23 1.521(6) . ?
C21 C22 1.533(7) . ?
C24 C26 1.527(7) . ?
C24 C25 1.534(6) . ?
C27 C31 1.395(6) . ?
C27 C28 1.427(7) . ?
C27 C32 1.495(7) . ?
C28 C29 1.410(7) . ?
C29 C30 1.403(7) . ?
C30 C31 1.410(7) . ?
C33 C37 1.398(6) . ?
C33 C34 1.410(6) . ?
C33 C38 1.504(6) . ?
C34 C35 1.425(6) . ?
C35 C36 1.397(7) . ?
C36 C37 1.409(6) . ?
