#------------------------------------------------------------------------------
#$Date: 2016-02-14 06:40:26 +0200 (Sun, 14 Feb 2016) $
#$Revision: 176432 $
#$URL: svn://www.crystallography.net/cod/cif/7/00/77/7007725.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7007725
loop_
_publ_author_name
'Hill, Nicholas J.'
'Reeske, Gregor'
'Moore, Jennifer A.'
'Cowley, Alan H.'
_publ_section_title
;
 Complexes of 1,2-bis(aryl-imino)acenaphthene (Ar-BIAN) ligands with
 some heavy p-block elements.
;
_journal_issue                   40
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              4838
_journal_page_last               4844
_journal_paper_doi               10.1039/b609737e
_journal_year                    2006
_chemical_formula_moiety         'C60 H56 Bi2 Cl6 N4'
_chemical_formula_sum            'C60 H56 Bi2 Cl6 N4'
_chemical_formula_weight         1463.75
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method
;
manual editing of the .cif file
created by SHELXTL Ver. 6.10
;
_cell_angle_alpha                111.60(3)
_cell_angle_beta                 93.99(3)
_cell_angle_gamma                111.21(3)
_cell_formula_units_Z            1
_cell_length_a                   12.035(2)
_cell_length_b                   12.512(3)
_cell_length_c                   12.980(3)
_cell_measurement_temperature    153(2)
_cell_volume                     1647.2(9)
_computing_cell_refinement       'Collect software, Nonius B.V. 1998'
_computing_data_collection       'Collect software, Nonius B.V. 1998'
_computing_data_reduction
;
DENZO and Scalepack (Otwinoski and Minor, 1997)
;
_computing_molecular_graphics    'XP SHELXTL/PC, Siemens Analytical'
_computing_structure_refinement  'XL SHELXTL/PC, Siemens Analytical'
_computing_structure_solution
;
SIR97 - Altomare A., Burla M.C., Camalli M., Cascarano G.L., Giacovazzo C.,
Guagliardi A., Moliterni A.G.G., Polidori G.,Spagna R.
;
_diffrn_ambient_temperature      153(2)
_diffrn_measured_fraction_theta_full 0.985
_diffrn_measured_fraction_theta_max 0.985
_diffrn_measurement_device_type  'Nonius Kappa CCD'
_diffrn_measurement_method       ω-scan
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0271
_diffrn_reflns_av_sigmaI/netI    0.0607
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       14
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            12533
_diffrn_reflns_theta_full        27.45
_diffrn_reflns_theta_max         27.45
_diffrn_reflns_theta_min         1.97
_exptl_absorpt_coefficient_mu    5.614
_exptl_absorpt_correction_T_max  0.852
_exptl_absorpt_correction_T_min  0.779
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
'DENZO and Scalepack (Otwinoski and Minor, 1997)'
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.476
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             712
_exptl_crystal_size_max          0.05
_exptl_crystal_size_mid          0.04
_exptl_crystal_size_min          0.03
_refine_diff_density_max         0.848
_refine_diff_density_min         -0.995
_refine_diff_density_rms         0.116
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.019
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     331
_refine_ls_number_reflns         7423
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.019
_refine_ls_R_factor_all          0.0371
_refine_ls_R_factor_gt           0.0284
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0033P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0500
_refine_ls_wR_factor_ref         0.0517
_reflns_number_gt                6377
_reflns_number_total             7423
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b609737e.txt
_cod_data_source_block           grngr019
_cod_original_sg_symbol_Hall     -p1
_cod_original_sg_symbol_H-M      p-1
_cod_database_code               7007725
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.8120(3) -0.0427(3) 0.2469(3) 0.0193(7) Uani 1 1 d . . .
C2 C 0.9263(3) -0.0153(3) 0.2074(3) 0.0218(7) Uani 1 1 d . . .
C3 C 0.9875(3) 0.0643(3) 0.1600(3) 0.0260(8) Uani 1 1 d . . .
H3 H 0.9566 0.1176 0.1472 0.031 Uiso 1 1 calc R . .
C4 C 1.0988(3) 0.0632(3) 0.1312(3) 0.0308(8) Uani 1 1 d . . .
H4 H 1.1403 0.1161 0.0984 0.037 Uiso 1 1 calc R . .
C5 C 1.1468(3) -0.0140(3) 0.1503(3) 0.0285(8) Uani 1 1 d . . .
H5 H 1.2203 -0.0117 0.1308 0.034 Uiso 1 1 calc R . .
C6 C 1.0875(3) -0.0963(3) 0.1986(3) 0.0242(8) Uani 1 1 d . . .
C7 C 1.1278(3) -0.1774(3) 0.2262(3) 0.0314(9) Uani 1 1 d . . .
H7 H 1.2007 -0.1816 0.2102 0.038 Uiso 1 1 calc R . .
C8 C 1.0603(3) -0.2506(3) 0.2767(3) 0.0321(9) Uani 1 1 d . . .
H8 H 1.0903 -0.3012 0.2961 0.039 Uiso 1 1 calc R . .
C9 C 0.9480(3) -0.2512(3) 0.2997(3) 0.0285(8) Uani 1 1 d . . .
H9 H 0.9031 -0.3029 0.3320 0.034 Uiso 1 1 calc R . .
C10 C 0.9056(3) -0.1736(3) 0.2734(3) 0.0224(7) Uani 1 1 d . . .
C11 C 0.9765(3) -0.0962(3) 0.2254(3) 0.0205(7) Uani 1 1 d . . .
C12 C 0.7957(3) -0.1477(3) 0.2842(3) 0.0220(7) Uani 1 1 d . . .
C13 C 0.7555(3) 0.1065(3) 0.2167(3) 0.0208(7) Uani 1 1 d . . .
C14 C 0.8331(3) 0.2304(3) 0.2939(3) 0.0249(8) Uani 1 1 d . . .
C15 C 0.8572(3) 0.3243(3) 0.2549(3) 0.0289(8) Uani 1 1 d . . .
H15 H 0.9081 0.4076 0.3045 0.035 Uiso 1 1 calc R . .
C16 C 0.8069(3) 0.2967(3) 0.1430(3) 0.0276(8) Uani 1 1 d . . .
C17 C 0.7285(3) 0.1732(3) 0.0711(3) 0.0242(8) Uani 1 1 d . . .
H17 H 0.6929 0.1546 -0.0028 0.029 Uiso 1 1 calc R . .
C18 C 0.7012(3) 0.0753(3) 0.1062(3) 0.0224(7) Uani 1 1 d . . .
C19 C 0.8918(3) 0.2616(3) 0.4140(3) 0.0372(9) Uani 1 1 d . . .
H19A H 0.9321 0.3518 0.4567 0.056 Uiso 1 1 calc R . .
H19B H 0.9506 0.2261 0.4120 0.056 Uiso 1 1 calc R . .
H19C H 0.8298 0.2267 0.4496 0.056 Uiso 1 1 calc R . .
C20 C 0.8394(3) 0.3998(3) 0.1005(3) 0.0391(9) Uani 1 1 d . . .
H20A H 0.9156 0.4120 0.0777 0.059 Uiso 1 1 calc R . .
H20B H 0.8473 0.4772 0.1605 0.059 Uiso 1 1 calc R . .
H20C H 0.7759 0.3751 0.0366 0.059 Uiso 1 1 calc R . .
C21 C 0.6211(3) -0.0594(3) 0.0250(3) 0.0285(8) Uani 1 1 d . . .
H21A H 0.6692 -0.1078 0.0105 0.043 Uiso 1 1 calc R . .
H21B H 0.5866 -0.0620 -0.0452 0.043 Uiso 1 1 calc R . .
H21C H 0.5563 -0.0947 0.0580 0.043 Uiso 1 1 calc R . .
C22 C 0.6804(3) -0.3019(3) 0.3426(3) 0.0216(7) Uani 1 1 d . . .
C23 C 0.6950(3) -0.2808(3) 0.4576(3) 0.0314(8) Uani 1 1 d . . .
C24 C 0.6770(3) -0.3834(4) 0.4822(3) 0.0400(10) Uani 1 1 d . . .
H24 H 0.6869 -0.3708 0.5581 0.048 Uiso 1 1 calc R . .
C25 C 0.6449(3) -0.5034(4) 0.3996(3) 0.0361(9) Uani 1 1 d . . .
C26 C 0.6288(3) -0.5212(3) 0.2863(3) 0.0302(8) Uani 1 1 d . . .
H26 H 0.6058 -0.6021 0.2295 0.036 Uiso 1 1 calc R . .
C27 C 0.6458(3) -0.4225(3) 0.2551(3) 0.0249(7) Uani 1 1 d . . .
C28 C 0.7319(4) -0.1492(4) 0.5504(3) 0.0512(11) Uani 1 1 d . . .
H28A H 0.7345 -0.1526 0.6232 0.077 Uiso 1 1 calc R . .
H28B H 0.6732 -0.1174 0.5375 0.077 Uiso 1 1 calc R . .
H28C H 0.8114 -0.0941 0.5494 0.077 Uiso 1 1 calc R . .
C29 C 0.6249(4) -0.6146(4) 0.4292(4) 0.0625(13) Uani 1 1 d . . .
H29A H 0.6908 -0.5908 0.4907 0.094 Uiso 1 1 calc R . .
H29B H 0.6225 -0.6847 0.3638 0.094 Uiso 1 1 calc R . .
H29C H 0.5486 -0.6385 0.4518 0.094 Uiso 1 1 calc R . .
C30 C 0.6318(3) -0.4425(3) 0.1320(3) 0.0351(9) Uani 1 1 d . . .
H30A H 0.7111 -0.4058 0.1182 0.053 Uiso 1 1 calc R . .
H30B H 0.5817 -0.4030 0.1162 0.053 Uiso 1 1 calc R . .
H30C H 0.5936 -0.5316 0.0834 0.053 Uiso 1 1 calc R . .
N1 N 0.7330(2) 0.0047(2) 0.2519(2) 0.0204(6) Uani 1 1 d . . .
N2 N 0.6982(2) -0.1963(2) 0.3158(2) 0.0219(6) Uani 1 1 d . . .
Cl1 Cl 0.63616(7) 0.15604(9) 0.56334(7) 0.0316(2) Uani 1 1 d . . .
Cl2 Cl 0.42767(7) -0.27142(8) 0.15621(7) 0.0339(2) Uani 1 1 d . . .
Cl3 Cl 0.46315(7) 0.04212(8) 0.26101(7) 0.02888(19) Uani 1 1 d . . .
Bi1 Bi 0.546996(10) -0.077320(12) 0.336769(10) 0.02139(5) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Bi Bi -4.1077 10.2566 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 C1 C2 131.6(3) . . ?
N1 C1 C12 121.4(3) . . ?
C2 C1 C12 107.0(2) . . ?
C3 C2 C11 119.1(3) . . ?
C3 C2 C1 135.1(3) . . ?
C11 C2 C1 105.8(3) . . ?
C2 C3 C4 118.6(3) . . ?
C2 C3 H3 120.7 . . ?
C4 C3 H3 120.7 . . ?
C5 C4 C3 121.7(3) . . ?
C5 C4 H4 119.2 . . ?
C3 C4 H4 119.2 . . ?
C4 C5 C6 121.5(3) . . ?
C4 C5 H5 119.3 . . ?
C6 C5 H5 119.3 . . ?
C5 C6 C11 116.5(3) . . ?
C5 C6 C7 127.6(3) . . ?
C11 C6 C7 115.9(3) . . ?
C8 C7 C6 120.7(3) . . ?
C8 C7 H7 119.6 . . ?
C6 C7 H7 119.6 . . ?
C7 C8 C9 122.2(3) . . ?
C7 C8 H8 118.9 . . ?
C9 C8 H8 118.9 . . ?
C10 C9 C8 118.6(3) . . ?
C10 C9 H9 120.7 . . ?
C8 C9 H9 120.7 . . ?
C9 C10 C11 119.1(3) . . ?
C9 C10 C12 134.7(3) . . ?
C11 C10 C12 106.2(3) . . ?
C6 C11 C10 123.5(3) . . ?
C6 C11 C2 122.6(3) . . ?
C10 C11 C2 114.0(2) . . ?
N2 C12 C10 133.0(3) . . ?
N2 C12 C1 120.2(3) . . ?
C10 C12 C1 106.8(3) . . ?
C18 C13 C14 123.0(3) . . ?
C18 C13 N1 117.8(3) . . ?
C14 C13 N1 119.2(3) . . ?
C15 C14 C13 117.4(3) . . ?
C15 C14 C19 120.8(3) . . ?
C13 C14 C19 121.8(3) . . ?
C14 C15 C16 121.6(3) . . ?
C14 C15 H15 119.2 . . ?
C16 C15 H15 119.2 . . ?
C17 C16 C15 118.6(3) . . ?
C17 C16 C20 120.6(3) . . ?
C15 C16 C20 120.7(3) . . ?
C16 C17 C18 122.0(3) . . ?
C16 C17 H17 119.0 . . ?
C18 C17 H17 119.0 . . ?
C13 C18 C17 117.4(3) . . ?
C13 C18 C21 121.3(3) . . ?
C17 C18 C21 121.2(3) . . ?
C14 C19 H19A 109.5 . . ?
C14 C19 H19B 109.5 . . ?
H19A C19 H19B 109.5 . . ?
C14 C19 H19C 109.5 . . ?
H19A C19 H19C 109.5 . . ?
H19B C19 H19C 109.5 . . ?
C16 C20 H20A 109.5 . . ?
C16 C20 H20B 109.5 . . ?
H20A C20 H20B 109.5 . . ?
C16 C20 H20C 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
C18 C21 H21A 109.5 . . ?
C18 C21 H21B 109.5 . . ?
H21A C21 H21B 109.5 . . ?
C18 C21 H21C 109.5 . . ?
H21A C21 H21C 109.5 . . ?
H21B C21 H21C 109.5 . . ?
C27 C22 C23 121.8(3) . . ?
C27 C22 N2 120.0(3) . . ?
C23 C22 N2 118.1(3) . . ?
C24 C23 C22 117.5(3) . . ?
C24 C23 C28 121.9(3) . . ?
C22 C23 C28 120.6(3) . . ?
C25 C24 C23 122.9(3) . . ?
C25 C24 H24 118.5 . . ?
C23 C24 H24 118.5 . . ?
C24 C25 C26 117.9(3) . . ?
C24 C25 C29 121.8(3) . . ?
C26 C25 C29 120.3(4) . . ?
C27 C26 C25 122.4(3) . . ?
C27 C26 H26 118.8 . . ?
C25 C26 H26 118.8 . . ?
C26 C27 C22 117.4(3) . . ?
C26 C27 C30 121.8(3) . . ?
C22 C27 C30 120.8(3) . . ?
C23 C28 H28A 109.5 . . ?
C23 C28 H28B 109.5 . . ?
H28A C28 H28B 109.5 . . ?
C23 C28 H28C 109.5 . . ?
H28A C28 H28C 109.5 . . ?
H28B C28 H28C 109.5 . . ?
C25 C29 H29A 109.5 . . ?
C25 C29 H29B 109.5 . . ?
H29A C29 H29B 109.5 . . ?
C25 C29 H29C 109.5 . . ?
H29A C29 H29C 109.5 . . ?
H29B C29 H29C 109.5 . . ?
C27 C30 H30A 109.5 . . ?
C27 C30 H30B 109.5 . . ?
H30A C30 H30B 109.5 . . ?
C27 C30 H30C 109.5 . . ?
H30A C30 H30C 109.5 . . ?
H30B C30 H30C 109.5 . . ?
C1 N1 C13 118.4(2) . . ?
C1 N1 Bi1 118.32(19) . . ?
C13 N1 Bi1 123.12(17) . . ?
C12 N2 C22 119.3(2) . . ?
C12 N2 Bi1 115.3(2) . . ?
C22 N2 Bi1 125.36(17) . . ?
Bi1 Cl1 Bi1 99.17(4) 2_656 . ?
Cl3 Bi1 Cl2 88.52(4) . . ?
Cl3 Bi1 N1 84.94(6) . . ?
Cl2 Bi1 N1 94.12(7) . . ?
Cl3 Bi1 Cl1 96.98(3) . 2_656 ?
Cl2 Bi1 Cl1 88.73(4) . 2_656 ?
N1 Bi1 Cl1 176.61(5) . 2_656 ?
Cl3 Bi1 N2 145.86(6) . . ?
Cl2 Bi1 N2 79.74(6) . . ?
N1 Bi1 N2 64.32(7) . . ?
Cl1 Bi1 N2 114.51(6) 2_656 . ?
Cl3 Bi1 Cl1 85.54(4) . . ?
Cl2 Bi1 Cl1 167.26(3) . . ?
N1 Bi1 Cl1 96.57(7) . . ?
Cl1 Bi1 Cl1 80.83(4) 2_656 . ?
N2 Bi1 Cl1 111.21(6) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 N1 1.283(3) . ?
C1 C2 1.470(4) . ?
C1 C12 1.515(4) . ?
C2 C3 1.377(4) . ?
C2 C11 1.427(4) . ?
C3 C4 1.419(4) . ?
C3 H3 0.9300 . ?
C4 C5 1.375(4) . ?
C4 H4 0.9300 . ?
C5 C6 1.403(4) . ?
C5 H5 0.9300 . ?
C6 C11 1.404(4) . ?
C6 C7 1.413(4) . ?
C7 C8 1.380(5) . ?
C7 H7 0.9300 . ?
C8 C9 1.403(4) . ?
C8 H8 0.9300 . ?
C9 C10 1.377(4) . ?
C9 H9 0.9300 . ?
C10 C11 1.405(4) . ?
C10 C12 1.476(4) . ?
C12 N2 1.284(4) . ?
C13 C18 1.382(4) . ?
C13 C14 1.399(5) . ?
C13 N1 1.450(4) . ?
C14 C15 1.390(4) . ?
C14 C19 1.510(4) . ?
C15 C16 1.397(4) . ?
C15 H15 0.9300 . ?
C16 C17 1.382(5) . ?
C16 C20 1.519(4) . ?
C17 C18 1.398(4) . ?
C17 H17 0.9300 . ?
C18 C21 1.502(4) . ?
C19 H19A 0.9600 . ?
C19 H19B 0.9600 . ?
C19 H19C 0.9600 . ?
C20 H20A 0.9600 . ?
C20 H20B 0.9600 . ?
C20 H20C 0.9600 . ?
C21 H21A 0.9600 . ?
C21 H21B 0.9600 . ?
C21 H21C 0.9600 . ?
C22 C27 1.399(4) . ?
C22 C23 1.402(4) . ?
C22 N2 1.434(4) . ?
C23 C24 1.382(5) . ?
C23 C28 1.515(5) . ?
C24 C25 1.375(5) . ?
C24 H24 0.9300 . ?
C25 C26 1.391(5) . ?
C25 C29 1.519(5) . ?
C26 C27 1.389(4) . ?
C26 H26 0.9300 . ?
C27 C30 1.510(4) . ?
C28 H28A 0.9600 . ?
C28 H28B 0.9600 . ?
C28 H28C 0.9600 . ?
C29 H29A 0.9600 . ?
C29 H29B 0.9600 . ?
C29 H29C 0.9600 . ?
C30 H30A 0.9600 . ?
C30 H30B 0.9600 . ?
C30 H30C 0.9600 . ?
N1 Bi1 2.606(2) . ?
N2 Bi1 2.708(2) . ?
Cl1 Bi1 2.6976(11) 2_656 ?
Cl1 Bi1 3.0488(18) . ?
Cl2 Bi1 2.5038(17) . ?
Cl3 Bi1 2.5008(9) . ?
Bi1 Cl1 2.6976(11) 2_656 ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N1 C1 C2 C3 -2.3(6) . . . . ?
C12 C1 C2 C3 176.9(4) . . . . ?
N1 C1 C2 C11 178.4(3) . . . . ?
C12 C1 C2 C11 -2.3(3) . . . . ?
C11 C2 C3 C4 -0.2(5) . . . . ?
C1 C2 C3 C4 -179.4(3) . . . . ?
C2 C3 C4 C5 -0.6(5) . . . . ?
C3 C4 C5 C6 0.5(5) . . . . ?
C4 C5 C6 C11 0.5(5) . . . . ?
C4 C5 C6 C7 -177.9(3) . . . . ?
C5 C6 C7 C8 178.1(3) . . . . ?
C11 C6 C7 C8 -0.2(5) . . . . ?
C6 C7 C8 C9 2.0(5) . . . . ?
C7 C8 C9 C10 -1.6(5) . . . . ?
C8 C9 C10 C11 -0.5(5) . . . . ?
C8 C9 C10 C12 -179.9(3) . . . . ?
C5 C6 C11 C10 179.5(3) . . . . ?
C7 C6 C11 C10 -1.9(5) . . . . ?
C5 C6 C11 C2 -1.3(5) . . . . ?
C7 C6 C11 C2 177.2(3) . . . . ?
C9 C10 C11 C6 2.3(5) . . . . ?
C12 C10 C11 C6 -178.1(3) . . . . ?
C9 C10 C11 C2 -176.9(3) . . . . ?
C12 C10 C11 C2 2.7(4) . . . . ?
C3 C2 C11 C6 1.2(5) . . . . ?
C1 C2 C11 C6 -179.4(3) . . . . ?
C3 C2 C11 C10 -179.6(3) . . . . ?
C1 C2 C11 C10 -0.2(4) . . . . ?
C9 C10 C12 N2 -5.3(6) . . . . ?
C11 C10 C12 N2 175.2(3) . . . . ?
C9 C10 C12 C1 175.5(4) . . . . ?
C11 C10 C12 C1 -3.9(3) . . . . ?
N1 C1 C12 N2 4.0(5) . . . . ?
C2 C1 C12 N2 -175.4(3) . . . . ?
N1 C1 C12 C10 -176.8(3) . . . . ?
C2 C1 C12 C10 3.9(3) . . . . ?
C18 C13 C14 C15 -1.3(4) . . . . ?
N1 C13 C14 C15 176.8(3) . . . . ?
C18 C13 C14 C19 -179.7(3) . . . . ?
N1 C13 C14 C19 -1.6(4) . . . . ?
C13 C14 C15 C16 -0.4(4) . . . . ?
C19 C14 C15 C16 178.0(3) . . . . ?
C14 C15 C16 C17 1.9(4) . . . . ?
C14 C15 C16 C20 -176.9(3) . . . . ?
C15 C16 C17 C18 -1.8(4) . . . . ?
C20 C16 C17 C18 177.1(3) . . . . ?
C14 C13 C18 C17 1.4(4) . . . . ?
N1 C13 C18 C17 -176.7(2) . . . . ?
C14 C13 C18 C21 178.3(3) . . . . ?
N1 C13 C18 C21 0.2(4) . . . . ?
C16 C17 C18 C13 0.2(4) . . . . ?
C16 C17 C18 C21 -176.7(3) . . . . ?
C27 C22 C23 C24 1.6(5) . . . . ?
N2 C22 C23 C24 179.6(3) . . . . ?
C27 C22 C23 C28 -179.7(3) . . . . ?
N2 C22 C23 C28 -1.7(4) . . . . ?
C22 C23 C24 C25 -0.5(5) . . . . ?
C28 C23 C24 C25 -179.2(3) . . . . ?
C23 C24 C25 C26 -0.8(5) . . . . ?
C23 C24 C25 C29 -179.6(4) . . . . ?
C24 C25 C26 C27 1.1(5) . . . . ?
C29 C25 C26 C27 179.8(3) . . . . ?
C25 C26 C27 C22 0.0(5) . . . . ?
C25 C26 C27 C30 178.1(3) . . . . ?
C23 C22 C27 C26 -1.4(4) . . . . ?
N2 C22 C27 C26 -179.4(3) . . . . ?
C23 C22 C27 C30 -179.5(3) . . . . ?
N2 C22 C27 C30 2.6(4) . . . . ?
C2 C1 N1 C13 -1.9(5) . . . . ?
C12 C1 N1 C13 178.9(3) . . . . ?
C2 C1 N1 Bi1 -178.2(3) . . . . ?
C12 C1 N1 Bi1 2.6(4) . . . . ?
C18 C13 N1 C1 95.8(3) . . . . ?
C14 C13 N1 C1 -82.4(4) . . . . ?
C18 C13 N1 Bi1 -88.2(3) . . . . ?
C14 C13 N1 Bi1 93.7(3) . . . . ?
C10 C12 N2 C22 -3.7(5) . . . . ?
C1 C12 N2 C22 175.4(3) . . . . ?
C10 C12 N2 Bi1 173.1(3) . . . . ?
C1 C12 N2 Bi1 -7.9(4) . . . . ?
C27 C22 N2 C12 -75.5(4) . . . . ?
C23 C22 N2 C12 106.4(3) . . . . ?
C27 C22 N2 Bi1 108.1(3) . . . . ?
C23 C22 N2 Bi1 -70.0(3) . . . . ?
C1 N1 Bi1 Cl3 -169.1(2) . . . . ?
C13 N1 Bi1 Cl3 14.8(2) . . . . ?
C1 N1 Bi1 Cl2 -81.0(2) . . . . ?
C13 N1 Bi1 Cl2 103.0(2) . . . . ?
C1 N1 Bi1 N2 -4.4(2) . . . . ?
C13 N1 Bi1 N2 179.5(2) . . . . ?
C1 N1 Bi1 Cl1 106.0(2) . . . . ?
C13 N1 Bi1 Cl1 -70.1(2) . . . . ?
C12 N2 Bi1 Cl3 34.3(3) . . . . ?
C22 N2 Bi1 Cl3 -149.18(19) . . . . ?
C12 N2 Bi1 Cl2 106.0(2) . . . . ?
C22 N2 Bi1 Cl2 -77.5(2) . . . . ?
C12 N2 Bi1 N1 6.4(2) . . . . ?
C22 N2 Bi1 N1 -177.1(3) . . . . ?
C12 N2 Bi1 Cl1 -170.1(2) . . . 2_656 ?
C22 N2 Bi1 Cl1 6.4(2) . . . 2_656 ?
C12 N2 Bi1 Cl1 -80.8(2) . . . . ?
C22 N2 Bi1 Cl1 95.8(2) . . . . ?
Bi1 Cl1 Bi1 Cl3 97.82(3) 2_656 . . . ?
Bi1 Cl1 Bi1 Cl2 35.39(12) 2_656 . . . ?
Bi1 Cl1 Bi1 N1 -177.80(5) 2_656 . . . ?
Bi1 Cl1 Bi1 Cl1 0.0 2_656 . . 2_656 ?
Bi1 Cl1 Bi1 N2 -112.84(6) 2_656 . . . ?
