#------------------------------------------------------------------------------
#$Date: 2016-03-25 11:14:35 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179781 $
#$URL: svn://www.crystallography.net/cod/cif/7/00/77/7007740.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7007740
loop_
_publ_author_name
'Antonioli, Bianca'
'Bray, David J.'
'Clegg, Jack K.'
'Gloe, Kerstin'
'Gloe, Karsten'
'Kataeva, Olga'
'Lindoy, Leonard F.'
'McMurtrie, John C.'
'Steel, Peter J.'
'Sumby, Christopher J.'
'Wenzel, Marco'
_publ_section_title
;
 Silver(I) complexation of linked 2,2'-dipyridylamine derivatives.
 Synthetic, solvent extraction, membrane transport and X-ray structural
 studies.
;
_journal_issue                   40
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              4783
_journal_page_last               4794
_journal_paper_doi               10.1039/b609738c
_journal_year                    2006
_chemical_absolute_configuration unk
_chemical_formula_moiety         'C28 H24 N6'
_chemical_formula_sum            'C28 H24 N6'
_chemical_formula_weight         444.53
_chemical_name_systematic
;
?
;
_space_group_IT_number           5
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  'C 2y'
_symmetry_space_group_name_H-M   'C 1 2 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.094(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   14.635(3)
_cell_length_b                   9.2483(19)
_cell_length_c                   16.571(3)
_cell_measurement_reflns_used    10633
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      28.1135
_cell_measurement_theta_min      2.458
_cell_volume                     2242.9(8)
_computing_cell_refinement       'SAINT (Siemens, 1995)'
_computing_data_collection       'SMART (Siemens, 1995)'
_computing_data_reduction        'SAINT and XPREP (Siemens, 1995)'
_computing_molecular_graphics
;ORTEP-3 (Farrugia, 1997)
WINGX-32 (Farrugia, 1999)
;
_computing_publication_material  'enCIFer 1.0 (CCDC, 2003)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SIR97 (Altomare, et. al. 1997)'
_diffrn_ambient_temperature      150(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.953
_diffrn_measurement_device_type  'Bruker SMART 1000 CCD'
_diffrn_measurement_method       /w
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0268
_diffrn_reflns_av_sigmaI/netI    0.0277
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            10605
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         28.29
_diffrn_reflns_theta_min         1.23
_diffrn_standards_decay_%        0.44
_diffrn_standards_number         105
_exptl_absorpt_coefficient_mu    0.081
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.316
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       multi-face
_exptl_crystal_F_000             936
_exptl_crystal_size_max          0.39
_exptl_crystal_size_mid          0.31
_exptl_crystal_size_min          0.21
_refine_diff_density_max         0.147
_refine_diff_density_min         -0.177
_refine_diff_density_rms         0.034
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.987
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     310
_refine_ls_number_reflns         2821
_refine_ls_number_restraints     1
_refine_ls_restrained_S_all      0.987
_refine_ls_R_factor_all          0.0361
_refine_ls_R_factor_gt           0.0313
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0446P)²+0.4092P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0692
_refine_ls_wR_factor_ref         0.0800
_reflns_number_gt                2684
_reflns_number_total             2821
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b609738c.txt
_cod_data_source_block           lj64
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_cell_volume        2243.0(8)
_cod_original_sg_symbol_H-M      C2
_cod_database_code               7007740
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.5000 -0.1533(4) 0.5000 0.0308(10) Uani 1 2 d S . .
H1 H 0.5000 -0.2560 0.5000 0.037 Uiso 1 2 calc SR . .
C2 C 0.5098(2) -0.0801(3) 0.42831(19) 0.0280(6) Uani 1 1 d . . .
H2 H 0.5167 -0.1323 0.3793 0.034 Uiso 1 1 calc R . .
C3 C 0.50952(18) 0.0707(3) 0.42740(17) 0.0221(6) Uani 1 1 d . . .
C4 C 0.5000 0.1446(5) 0.5000 0.0220(8) Uani 1 2 d S . .
H4 H 0.5000 0.2473 0.5000 0.026 Uiso 1 2 calc SR . .
C5 C 0.5159(2) 0.1486(3) 0.34771(16) 0.0266(6) Uani 1 1 d . . .
H5A H 0.5706 0.1127 0.3189 0.032 Uiso 1 1 calc R . .
H5B H 0.4618 0.1225 0.3149 0.032 Uiso 1 1 calc R . .
C6 C 0.44415(19) 0.3886(3) 0.32723(16) 0.0236(6) Uani 1 1 d . . .
C7 C 0.3630(2) 0.3782(5) 0.3689(2) 0.0421(9) Uani 1 1 d . . .
H7 H 0.3579 0.3173 0.4148 0.050 Uiso 1 1 calc R . .
C8 C 0.2887(2) 0.4593(5) 0.3421(2) 0.0475(9) Uani 1 1 d . . .
H8 H 0.2320 0.4546 0.3699 0.057 Uiso 1 1 calc R . .
C9 C 0.2977(2) 0.5453(4) 0.2759(2) 0.0359(8) Uani 1 1 d . . .
H9 H 0.2480 0.6016 0.2565 0.043 Uiso 1 1 calc R . .
C10 C 0.3812(2) 0.5475(4) 0.2384(2) 0.0395(8) Uani 1 1 d . . .
H10 H 0.3878 0.6075 0.1923 0.047 Uiso 1 1 calc R . .
C11 C 0.6013(2) 0.3720(3) 0.37816(16) 0.0267(6) Uani 1 1 d . . .
C12 C 0.6070(2) 0.5219(3) 0.38858(18) 0.0301(7) Uani 1 1 d . . .
H12 H 0.5574 0.5829 0.3742 0.036 Uiso 1 1 calc R . .
C13 C 0.6865(2) 0.5787(4) 0.4202(2) 0.0398(8) Uani 1 1 d . . .
H13 H 0.6913 0.6800 0.4289 0.048 Uiso 1 1 calc R . .
C14 C 0.7591(2) 0.4895(5) 0.4395(2) 0.0412(8) Uani 1 1 d . . .
H14 H 0.8137 0.5270 0.4623 0.049 Uiso 1 1 calc R . .
C15 C 0.7487(2) 0.3430(4) 0.4240(2) 0.0382(8) Uani 1 1 d . . .
H15 H 0.7990 0.2809 0.4349 0.046 Uiso 1 1 calc R . .
C16 C 0.5000 0.5056(4) 0.0000 0.0314(10) Uani 1 2 d S . .
H16 H 0.5000 0.4029 0.0000 0.038 Uiso 1 2 calc SR . .
C17 C 0.5247(2) 0.5786(3) 0.06972(19) 0.0292(6) Uani 1 1 d . . .
H17 H 0.5405 0.5264 0.1171 0.035 Uiso 1 1 calc R . .
C18 C 0.52603(18) 0.7298(3) 0.06968(18) 0.0237(6) Uani 1 1 d . . .
C19 C 0.5000 0.8032(4) 0.0000 0.0235(8) Uani 1 2 d S . .
H19 H 0.5000 0.9059 0.0000 0.028 Uiso 1 2 calc SR . .
C20 C 0.5574(2) 0.8086(3) 0.14503(17) 0.0270(6) Uani 1 1 d . . .
H20A H 0.5259 0.7665 0.1923 0.032 Uiso 1 1 calc R . .
H20B H 0.6238 0.7924 0.1522 0.032 Uiso 1 1 calc R . .
C21 C 0.45063(19) 1.0128(3) 0.16070(16) 0.0243(6) Uani 1 1 d . . .
C22 C 0.4130(2) 1.1354(4) 0.12551(18) 0.0307(7) Uani 1 1 d . . .
H22 H 0.4454 1.1875 0.0853 0.037 Uiso 1 1 calc R . .
C23 C 0.3273(2) 1.1802(4) 0.1503(2) 0.0370(7) Uani 1 1 d . . .
H23 H 0.3007 1.2655 0.1285 0.044 Uiso 1 1 calc R . .
C24 C 0.2806(2) 1.0993(4) 0.2071(2) 0.0377(8) Uani 1 1 d . . .
H24 H 0.2229 1.1294 0.2270 0.045 Uiso 1 1 calc R . .
C25 C 0.3206(2) 0.9747(4) 0.23348(18) 0.0351(7) Uani 1 1 d . . .
H25 H 0.2869 0.9159 0.2699 0.042 Uiso 1 1 calc R . .
C26 C 0.60933(19) 1.0569(3) 0.11625(17) 0.0240(6) Uani 1 1 d . . .
C27 C 0.6120(2) 1.2038(3) 0.13512(18) 0.0274(6) Uani 1 1 d . . .
H27 H 0.5657 1.2466 0.1673 0.033 Uiso 1 1 calc R . .
C28 C 0.6837(2) 1.2853(3) 0.10587(19) 0.0312(7) Uani 1 1 d . . .
H28 H 0.6860 1.3863 0.1162 0.037 Uiso 1 1 calc R . .
C29 C 0.7522(2) 1.2201(4) 0.0617(2) 0.0368(8) Uani 1 1 d . . .
H29 H 0.8020 1.2743 0.0409 0.044 Uiso 1 1 calc R . .
C30 C 0.7453(2) 1.0732(4) 0.0489(2) 0.0352(8) Uani 1 1 d . . .
H30 H 0.7931 1.0269 0.0201 0.042 Uiso 1 1 calc R . .
N1 N 0.52137(16) 0.3057(3) 0.35190(14) 0.0248(5) Uani 1 1 d . . .
N2 N 0.45381(17) 0.4711(3) 0.26243(15) 0.0334(6) Uani 1 1 d . . .
N3 N 0.67148(17) 0.2834(3) 0.39446(16) 0.0320(6) Uani 1 1 d . . .
N4 N 0.54000(16) 0.9648(3) 0.14329(14) 0.0242(5) Uani 1 1 d . . .
N5 N 0.40408(17) 0.9292(3) 0.21171(16) 0.0301(6) Uani 1 1 d . . .
N6 N 0.67571(17) 0.9919(3) 0.07440(16) 0.0304(5) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C2 C1 C2 121.0(4) 2_656 . ?
C2 C1 H1 119.5 2_656 . ?
C2 C1 H1 119.5 . . ?
C1 C2 C3 120.1(3) . . ?
C1 C2 H2 120.0 . . ?
C3 C2 H2 120.0 . . ?
C4 C3 C2 118.8(3) . . ?
C4 C3 C5 122.0(2) . . ?
C2 C3 C5 119.2(3) . . ?
C3 C4 C3 121.1(4) . 2_656 ?
C3 C4 H4 119.4 . . ?
C3 C4 H4 119.4 2_656 . ?
N1 C5 C3 116.0(2) . . ?
N1 C5 H5A 108.3 . . ?
C3 C5 H5A 108.3 . . ?
N1 C5 H5B 108.3 . . ?
C3 C5 H5B 108.3 . . ?
H5A C5 H5B 107.4 . . ?
N2 C6 C7 122.6(3) . . ?
N2 C6 N1 117.2(3) . . ?
C7 C6 N1 120.2(3) . . ?
C6 C7 C8 118.5(3) . . ?
C6 C7 H7 120.8 . . ?
C8 C7 H7 120.8 . . ?
C9 C8 C7 119.6(3) . . ?
C9 C8 H8 120.2 . . ?
C7 C8 H8 120.2 . . ?
C8 C9 C10 117.5(3) . . ?
C8 C9 H9 121.3 . . ?
C10 C9 H9 121.3 . . ?
N2 C10 C9 124.5(3) . . ?
N2 C10 H10 117.8 . . ?
C9 C10 H10 117.8 . . ?
N3 C11 N1 116.0(3) . . ?
N3 C11 C12 122.3(3) . . ?
N1 C11 C12 121.7(3) . . ?
C13 C12 C11 118.3(3) . . ?
C13 C12 H12 120.8 . . ?
C11 C12 H12 120.8 . . ?
C14 C13 C12 120.5(3) . . ?
C14 C13 H13 119.7 . . ?
C12 C13 H13 119.7 . . ?
C13 C14 C15 117.2(3) . . ?
C13 C14 H14 121.4 . . ?
C15 C14 H14 121.4 . . ?
N3 C15 C14 123.8(3) . . ?
N3 C15 H15 118.1 . . ?
C14 C15 H15 118.1 . . ?
C17 C16 C17 121.7(4) 2_655 . ?
C17 C16 H16 119.2 2_655 . ?
C17 C16 H16 119.2 . . ?
C16 C17 C18 119.4(3) . . ?
C16 C17 H17 120.3 . . ?
C18 C17 H17 120.3 . . ?
C19 C18 C17 119.0(3) . . ?
C19 C18 C20 122.1(3) . . ?
C17 C18 C20 119.0(3) . . ?
C18 C19 C18 121.6(4) . 2_655 ?
C18 C19 H19 119.2 . . ?
C18 C19 H19 119.2 2_655 . ?
N4 C20 C18 113.9(2) . . ?
N4 C20 H20A 108.8 . . ?
C18 C20 H20A 108.8 . . ?
N4 C20 H20B 108.8 . . ?
C18 C20 H20B 108.8 . . ?
H20A C20 H20B 107.7 . . ?
N5 C21 C22 122.5(3) . . ?
N5 C21 N4 114.9(2) . . ?
C22 C21 N4 122.6(3) . . ?
C23 C22 C21 118.6(3) . . ?
C23 C22 H22 120.7 . . ?
C21 C22 H22 120.7 . . ?
C22 C23 C24 119.2(3) . . ?
C22 C23 H23 120.4 . . ?
C24 C23 H23 120.4 . . ?
C25 C24 C23 117.6(3) . . ?
C25 C24 H24 121.2 . . ?
C23 C24 H24 121.2 . . ?
N5 C25 C24 124.6(3) . . ?
N5 C25 H25 117.7 . . ?
C24 C25 H25 117.7 . . ?
N6 C26 C27 122.3(3) . . ?
N6 C26 N4 114.8(3) . . ?
C27 C26 N4 122.8(3) . . ?
C28 C27 C26 118.3(3) . . ?
C28 C27 H27 120.8 . . ?
C26 C27 H27 120.8 . . ?
C29 C28 C27 120.0(3) . . ?
C29 C28 H28 120.0 . . ?
C27 C28 H28 120.0 . . ?
C28 C29 C30 117.3(3) . . ?
C28 C29 H29 121.3 . . ?
C30 C29 H29 121.3 . . ?
N6 C30 C29 124.2(3) . . ?
N6 C30 H30 117.9 . . ?
C29 C30 H30 117.9 . . ?
C11 N1 C6 121.3(2) . . ?
C11 N1 C5 120.1(2) . . ?
C6 N1 C5 118.6(2) . . ?
C6 N2 C10 117.4(3) . . ?
C11 N3 C15 117.7(3) . . ?
C26 N4 C21 123.2(2) . . ?
C26 N4 C20 118.7(2) . . ?
C21 N4 C20 117.8(2) . . ?
C21 N5 C25 117.0(3) . . ?
C30 N6 C26 117.7(3) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 C2 1.375(4) 2_656 ?
C1 C2 1.375(4) . ?
C1 H1 0.9500 . ?
C2 C3 1.395(4) . ?
C2 H2 0.9500 . ?
C3 C4 1.391(3) . ?
C3 C5 1.508(4) . ?
C4 C3 1.391(3) 2_656 ?
C4 H4 0.9500 . ?
C5 N1 1.456(4) . ?
C5 H5A 0.9900 . ?
C5 H5B 0.9900 . ?
C6 N2 1.325(4) . ?
C6 C7 1.378(4) . ?
C6 N1 1.425(4) . ?
C7 C8 1.393(5) . ?
C7 H7 0.9500 . ?
C8 C9 1.361(5) . ?
C8 H8 0.9500 . ?
C9 C10 1.373(5) . ?
C9 H9 0.9500 . ?
C10 N2 1.336(4) . ?
C10 H10 0.9500 . ?
C11 N3 1.340(4) . ?
C11 N1 1.390(4) . ?
C11 C12 1.399(5) . ?
C12 C13 1.379(5) . ?
C12 H12 0.9500 . ?
C13 C14 1.382(5) . ?
C13 H13 0.9500 . ?
C14 C15 1.388(6) . ?
C14 H14 0.9500 . ?
C15 N3 1.348(4) . ?
C15 H15 0.9500 . ?
C16 C17 1.385(4) 2_655 ?
C16 C17 1.385(4) . ?
C16 H16 0.9500 . ?
C17 C18 1.398(4) . ?
C17 H17 0.9500 . ?
C18 C19 1.392(4) . ?
C18 C20 1.516(4) . ?
C19 C18 1.392(4) 2_655 ?
C19 H19 0.9500 . ?
C20 N4 1.467(4) . ?
C20 H20A 0.9900 . ?
C20 H20B 0.9900 . ?
C21 N5 1.334(4) . ?
C21 C22 1.389(4) . ?
C21 N4 1.411(3) . ?
C22 C23 1.384(5) . ?
C22 H22 0.9500 . ?
C23 C24 1.384(5) . ?
C23 H23 0.9500 . ?
C24 C25 1.364(5) . ?
C24 H24 0.9500 . ?
C25 N5 1.343(4) . ?
C25 H25 0.9500 . ?
C26 N6 1.338(4) . ?
C26 C27 1.394(4) . ?
C26 N4 1.399(4) . ?
C27 C28 1.381(4) . ?
C27 H27 0.9500 . ?
C28 C29 1.380(5) . ?
C28 H28 0.9500 . ?
C29 C30 1.378(5) . ?
C29 H29 0.9500 . ?
C30 N6 1.335(4) . ?
C30 H30 0.9500 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C2 C1 C2 C3 -0.3(2) 2_656 . . . ?
C1 C2 C3 C4 0.5(4) . . . . ?
C1 C2 C3 C5 -177.2(2) . . . . ?
C2 C3 C4 C3 -0.3(2) . . . 2_656 ?
C5 C3 C4 C3 177.4(3) . . . 2_656 ?
C4 C3 C5 N1 6.3(4) . . . . ?
C2 C3 C5 N1 -176.1(3) . . . . ?
N2 C6 C7 C8 -0.7(6) . . . . ?
N1 C6 C7 C8 -179.0(3) . . . . ?
C6 C7 C8 C9 0.3(6) . . . . ?
C7 C8 C9 C10 0.0(6) . . . . ?
C8 C9 C10 N2 0.1(6) . . . . ?
N3 C11 C12 C13 -3.0(5) . . . . ?
N1 C11 C12 C13 175.5(3) . . . . ?
C11 C12 C13 C14 1.3(5) . . . . ?
C12 C13 C14 C15 1.3(5) . . . . ?
C13 C14 C15 N3 -2.5(5) . . . . ?
C17 C16 C17 C18 -0.90(19) 2_655 . . . ?
C16 C17 C18 C19 1.8(4) . . . . ?
C16 C17 C18 C20 -177.2(2) . . . . ?
C17 C18 C19 C18 -0.89(19) . . . 2_655 ?
C20 C18 C19 C18 178.0(3) . . . 2_655 ?
C19 C18 C20 N4 11.8(4) . . . . ?
C17 C18 C20 N4 -169.3(2) . . . . ?
N5 C21 C22 C23 6.4(4) . . . . ?
N4 C21 C22 C23 -175.6(3) . . . . ?
C21 C22 C23 C24 -2.1(5) . . . . ?
C22 C23 C24 C25 -2.8(5) . . . . ?
C23 C24 C25 N5 4.0(5) . . . . ?
N6 C26 C27 C28 3.3(4) . . . . ?
N4 C26 C27 C28 179.6(3) . . . . ?
C26 C27 C28 C29 -2.4(5) . . . . ?
C27 C28 C29 C30 -0.1(5) . . . . ?
C28 C29 C30 N6 2.0(5) . . . . ?
N3 C11 N1 C6 -175.5(2) . . . . ?
C12 C11 N1 C6 5.9(4) . . . . ?
N3 C11 N1 C5 3.3(4) . . . . ?
C12 C11 N1 C5 -175.3(3) . . . . ?
N2 C6 N1 C11 64.4(4) . . . . ?
C7 C6 N1 C11 -117.3(3) . . . . ?
N2 C6 N1 C5 -114.4(3) . . . . ?
C7 C6 N1 C5 63.9(4) . . . . ?
C3 C5 N1 C11 72.8(3) . . . . ?
C3 C5 N1 C6 -108.3(3) . . . . ?
C7 C6 N2 C10 0.8(5) . . . . ?
N1 C6 N2 C10 179.1(3) . . . . ?
C9 C10 N2 C6 -0.5(5) . . . . ?
N1 C11 N3 C15 -176.7(3) . . . . ?
C12 C11 N3 C15 1.9(4) . . . . ?
C14 C15 N3 C11 0.9(5) . . . . ?
N6 C26 N4 C21 -155.6(3) . . . . ?
C27 C26 N4 C21 27.9(4) . . . . ?
N6 C26 N4 C20 17.3(4) . . . . ?
C27 C26 N4 C20 -159.3(3) . . . . ?
N5 C21 N4 C26 -156.6(3) . . . . ?
C22 C21 N4 C26 25.2(4) . . . . ?
N5 C21 N4 C20 30.5(3) . . . . ?
C22 C21 N4 C20 -147.7(3) . . . . ?
C18 C20 N4 C26 -93.8(3) . . . . ?
C18 C20 N4 C21 79.4(3) . . . . ?
C22 C21 N5 C25 -5.4(4) . . . . ?
N4 C21 N5 C25 176.5(2) . . . . ?
C24 C25 N5 C21 0.1(4) . . . . ?
C29 C30 N6 C26 -1.2(5) . . . . ?
C27 C26 N6 C30 -1.5(4) . . . . ?
N4 C26 N6 C30 -178.1(3) . . . . ?
