#------------------------------------------------------------------------------
#$Date: 2016-03-25 11:16:03 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179782 $
#$URL: svn://www.crystallography.net/cod/cif/7/00/78/7007882.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7007882
loop_
_publ_author_name
'Senanayake, Kanthi'
'Thompson, Amber L.'
'Howard, Judith A. K.'
'Botta, Mauro'
'Parker, David'
_publ_section_title
;
 Synthesis and characterisation of dimeric eight-coordinate
 lanthanide(III) complexes of a macrocyclic tribenzylphosphinate
 ligand.
;
_journal_issue                   45
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              5423
_journal_page_last               5428
_journal_paper_doi               10.1039/b612189f
_journal_year                    2006
_chemical_formula_moiety         'C64 H88 Eu2 N8 O12 P6, 10(O H2)'
_chemical_formula_sum            'C64 H108 Eu2 N8 O22 P6'
_chemical_formula_weight         1831.32
_chemical_melting_point          ?
_chemical_name_common
;
bis((mu!2$-1-4-7-10-tetra-azacyclododecane-1,4,7,10-tetrayl-
methyl-(trimethylene-tris(phenylphosphinato)))-europium(iii))
decahydrate
;
_chemical_name_systematic
;
bis((μ₂-1-4-7-10-tetra-azacyclododecane-1,4,7,10-tetrayl-methyl-
(trimethylene-tris(phenylphosphinato)))-europium(III)) decahydrate
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   difmap
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_cell_angle_alpha                90.00
_cell_angle_beta                 97.0140(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   16.6586(8)
_cell_length_b                   15.1326(7)
_cell_length_c                   30.2862(15)
_cell_measurement_reflns_used    7729
_cell_measurement_temperature    120(2)
_cell_measurement_theta_max      26.084
_cell_measurement_theta_min      2.361
_cell_volume                     7577.6(6)
_computing_cell_refinement       'SMART-NT V6.1 (Bruker, 2000)'
_computing_data_collection       'SMART-NT V6.1 (Bruker, 2000)'
_computing_data_reduction        'SAINT-NT V6.45A (Bruker, 2000)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      120(2)
_diffrn_detector_area_resol_mean 8
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker SMART CCD 1K area detector'
_diffrn_measurement_method       ω-scans
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0865
_diffrn_reflns_av_sigmaI/netI    0.0552
_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_h_min       -20
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       37
_diffrn_reflns_limit_l_min       -37
_diffrn_reflns_number            35450
_diffrn_reflns_theta_full        26.00
_diffrn_reflns_theta_max         26.00
_diffrn_reflns_theta_min         1.35
_exptl_absorpt_coefficient_mu    1.844
_exptl_absorpt_correction_T_max  0.9820
_exptl_absorpt_correction_T_min  0.6675
_exptl_absorpt_correction_type   integration
_exptl_absorpt_process_details   'XPREP (SHELXTL,1997)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.605
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    .
_exptl_crystal_description       plate
_exptl_crystal_F_000             3760
_exptl_crystal_size_max          0.24
_exptl_crystal_size_mid          0.12
_exptl_crystal_size_min          0.01
_refine_diff_density_max         0.862
_refine_diff_density_min         -2.580
_refine_diff_density_rms         0.146
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.420
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     496
_refine_ls_number_reflns         7442
_refine_ls_number_restraints     87
_refine_ls_restrained_S_all      1.411
_refine_ls_R_factor_all          0.0833
_refine_ls_R_factor_gt           0.0689
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0000P)²+88.0228P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1062
_refine_ls_wR_factor_ref         0.1092
_reflns_number_gt                6499
_reflns_number_total             7442
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b612189f.txt
_cod_data_source_block           '[Eu.L^3^]~2~.10H~2~O'
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/adriana/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from
2010-06-29.

'_exptl_absorpt_correction_type' value 'Integration' changed
to 'integration' according to
'/home/adriana/struct/CIF-dictionaries/cif_core.dic' dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1555 2011-01-17 13:19:09Z saulius 

The following automatic conversions were performed:

'_chemical_melting_point' value 'not measured' was changed to '?' -
the value is undefined or not given.

Automatic conversion script
Id: cif_fix_values 1569 2011-02-09 13:29:24Z adriana 
;
_cod_original_sg_symbol_H-M      C2/c
_cod_database_code               7007882
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.309638(19) 0.69866(2) 0.596130(11) 0.01028(9) Uani 1 1 d . . .
P1 P 0.15526(10) 0.68353(10) 0.50970(5) 0.0104(3) Uani 1 1 d . . .
P2 P 0.27703(10) 0.47917(11) 0.61871(6) 0.0130(3) Uani 1 1 d . . .
P3 P 0.50565(10) 0.66891(11) 0.64018(6) 0.0137(4) Uani 1 1 d . . .
N1 N 0.1641(3) 0.7761(3) 0.58899(17) 0.0120(11) Uani 1 1 d . . .
N2 N 0.2165(3) 0.6304(3) 0.65192(17) 0.0112(11) Uani 1 1 d . . .
N3 N 0.3735(3) 0.7182(3) 0.68041(17) 0.0117(11) Uani 1 1 d . . .
N4 N 0.3171(3) 0.8611(3) 0.62181(17) 0.0123(11) Uani 1 1 d . . .
H4C H 0.3596 0.8839 0.6093 0.015 Uiso 1 1 calc R . .
C1 C 0.1066(4) 0.7214(4) 0.6113(2) 0.0152(14) Uani 1 1 d . . .
H1A H 0.0884 0.6721 0.5921 0.018 Uiso 1 1 calc R . .
H1B H 0.0597 0.7568 0.6156 0.018 Uiso 1 1 calc R . .
C2 C 0.1443(4) 0.6861(4) 0.6558(2) 0.0159(14) Uani 1 1 d . . .
H2A H 0.1598 0.7354 0.6755 0.019 Uiso 1 1 calc R . .
H2B H 0.1044 0.6514 0.6690 0.019 Uiso 1 1 calc R . .
C3 C 0.2629(4) 0.6162(4) 0.6967(2) 0.0153(14) Uani 1 1 d . . .
H3A H 0.2971 0.5646 0.6957 0.018 Uiso 1 1 calc R . .
H3B H 0.2252 0.6046 0.7181 0.018 Uiso 1 1 calc R . .
C4 C 0.3153(4) 0.6954(5) 0.7124(2) 0.0170(13) Uani 1 1 d . . .
H4A H 0.2807 0.7459 0.7158 0.020 Uiso 1 1 calc R . .
H4B H 0.3450 0.6823 0.7412 0.020 Uiso 1 1 calc R . .
C5 C 0.4019(4) 0.8108(4) 0.6887(2) 0.0165(14) Uani 1 1 d . . .
H5A H 0.4511 0.8202 0.6752 0.020 Uiso 1 1 calc R . .
H5B H 0.4141 0.8205 0.7205 0.020 Uiso 1 1 calc R . .
C6 C 0.3382(4) 0.8759(4) 0.6697(2) 0.0138(14) Uani 1 1 d . . .
H6A H 0.2903 0.8693 0.6847 0.017 Uiso 1 1 calc R . .
H6B H 0.3583 0.9356 0.6747 0.017 Uiso 1 1 calc R . .
C7 C 0.2469(4) 0.9131(4) 0.6020(2) 0.0151(14) Uani 1 1 d . . .
H7A H 0.2493 0.9203 0.5704 0.018 Uiso 1 1 calc R . .
H7B H 0.2483 0.9712 0.6155 0.018 Uiso 1 1 calc R . .
C8 C 0.1685(4) 0.8663(4) 0.6093(2) 0.0144(14) Uani 1 1 d . . .
H8A H 0.1652 0.8614 0.6410 0.017 Uiso 1 1 calc R . .
H8B H 0.1228 0.9011 0.5962 0.017 Uiso 1 1 calc R . .
C9 C 0.1347(4) 0.7832(4) 0.5412(2) 0.0131(13) Uani 1 1 d . . .
H9A H 0.1604 0.8335 0.5289 0.016 Uiso 1 1 calc R . .
H9B H 0.0769 0.7939 0.5378 0.016 Uiso 1 1 calc R . .
C10 C 0.1898(4) 0.5419(4) 0.6341(2) 0.0148(14) Uani 1 1 d . . .
H10A H 0.1500 0.5491 0.6082 0.018 Uiso 1 1 calc R . .
H10B H 0.1648 0.5095 0.6565 0.018 Uiso 1 1 calc R . .
C11 C 0.4431(4) 0.6564(4) 0.6862(2) 0.0163(14) Uani 1 1 d . . .
H11A H 0.4234 0.5962 0.6869 0.020 Uiso 1 1 calc R . .
H11B H 0.4758 0.6683 0.7143 0.020 Uiso 1 1 calc R . .
C12 C 0.0631(4) 0.6185(5) 0.5011(2) 0.0195(15) Uani 1 1 d . . .
H12A H 0.0608 0.5802 0.5266 0.023 Uiso 1 1 calc R . .
H12B H 0.0169 0.6580 0.4993 0.023 Uiso 1 1 calc R . .
C13 C 0.0567(4) 0.5626(4) 0.4595(2) 0.0174(14) Uani 1 1 d . . .
C14 C 0.0052(4) 0.5883(5) 0.4222(2) 0.0241(17) Uani 1 1 d . . .
H14 H -0.0259 0.6391 0.4231 0.029 Uiso 1 1 calc R . .
C15 C 0.0000(5) 0.5380(6) 0.3832(3) 0.032(2) Uani 1 1 d . . .
H15 H -0.0343 0.5562 0.3584 0.039 Uiso 1 1 calc R . .
C16 C 0.0447(5) 0.4622(5) 0.3810(3) 0.034(2) Uani 1 1 d . . .
H16 H 0.0408 0.4292 0.3549 0.041 Uiso 1 1 calc R . .
C17 C 0.0960(5) 0.4358(5) 0.4186(3) 0.0256(17) Uani 1 1 d . . .
H17 H 0.1263 0.3844 0.4177 0.031 Uiso 1 1 calc R . .
C18 C 0.1019(4) 0.4855(5) 0.4569(2) 0.0215(15) Uani 1 1 d . . .
H18 H 0.1367 0.4673 0.4816 0.026 Uiso 1 1 calc R . .
C19 C 0.2376(4) 0.4250(4) 0.5672(2) 0.0167(14) Uani 1 1 d . . .
H19A H 0.2068 0.3735 0.5741 0.020 Uiso 1 1 calc R . .
H19B H 0.2009 0.4650 0.5498 0.020 Uiso 1 1 calc R . .
C20 C 0.3028(4) 0.3961(4) 0.5392(2) 0.0172(15) Uani 1 1 d . . .
C21 C 0.3249(4) 0.3087(5) 0.5373(2) 0.0255(16) Uani 1 1 d . . .
H21 H 0.3006 0.2671 0.5540 0.031 Uiso 1 1 calc R . .
C22 C 0.3831(5) 0.2811(5) 0.5106(3) 0.034(2) Uani 1 1 d . . .
H22 H 0.3964 0.2216 0.5093 0.041 Uiso 1 1 calc R . .
C23 C 0.4208(5) 0.3419(5) 0.4863(2) 0.0276(18) Uani 1 1 d . . .
H23 H 0.4594 0.3241 0.4684 0.033 Uiso 1 1 calc R . .
C24 C 0.4000(5) 0.4297(5) 0.4891(2) 0.0309(19) Uani 1 1 d . . .
H24 H 0.4258 0.4716 0.4732 0.037 Uiso 1 1 calc R . .
C25 C 0.3416(5) 0.4568(5) 0.5150(2) 0.0272(18) Uani 1 1 d . . .
H25 H 0.3282 0.5163 0.5161 0.033 Uiso 1 1 calc R . .
C26 C 0.5328(4) 0.5577(4) 0.6265(2) 0.0191(15) Uani 1 1 d . . .
H26A H 0.4857 0.5296 0.6103 0.023 Uiso 1 1 calc R . .
H26B H 0.5740 0.5609 0.6065 0.023 Uiso 1 1 calc R . .
C27 C 0.5636(4) 0.4996(4) 0.6650(2) 0.0164(14) Uani 1 1 d . . .
C28 C 0.5195(4) 0.4244(4) 0.6740(2) 0.0218(16) Uani 1 1 d . . .
H28 H 0.4695 0.4138 0.6577 0.026 Uiso 1 1 calc R . .
C29 C 0.5495(5) 0.3655(5) 0.7071(3) 0.0260(18) Uani 1 1 d . . .
H29 H 0.5199 0.3155 0.7126 0.031 Uiso 1 1 calc R . .
C30 C 0.6239(5) 0.3814(5) 0.7321(2) 0.0266(17) Uani 1 1 d . . .
H30 H 0.6443 0.3417 0.7540 0.032 Uiso 1 1 calc R . .
C31 C 0.6673(5) 0.4561(5) 0.7242(2) 0.0227(16) Uani 1 1 d . . .
H31 H 0.7165 0.4674 0.7413 0.027 Uiso 1 1 calc R . .
C32 C 0.6379(4) 0.5144(5) 0.6907(2) 0.0210(15) Uani 1 1 d . . .
H32 H 0.6680 0.5641 0.6853 0.025 Uiso 1 1 calc R . .
O1 O 0.2192(3) 0.6324(3) 0.53867(14) 0.0128(9) Uani 1 1 d . . .
O2 O 0.3376(3) 0.5495(3) 0.60892(14) 0.0131(9) Uani 1 1 d . . .
O3 O 0.4490(3) 0.7047(3) 0.60113(13) 0.0150(9) Uani 1 1 d . . .
O4 O 0.1752(3) 0.7135(3) 0.46490(14) 0.0125(9) Uani 1 1 d . . .
O5 O 0.3042(3) 0.4124(3) 0.65366(16) 0.0202(11) Uani 1 1 d . . .
O6 O 0.5807(3) 0.7223(3) 0.65415(16) 0.0209(11) Uani 1 1 d . . .
O1W O 0.6718(3) 0.8548(3) 0.70195(18) 0.0271(12) Uani 1 1 d D . .
H1WA H 0.646(4) 0.817(4) 0.687(2) 0.041 Uiso 1 1 d D . .
H1WB H 0.711(4) 0.866(5) 0.688(2) 0.041 Uiso 1 1 d D . .
O2W O 0.7103(4) 0.6775(5) 0.6096(2) 0.0468(17) Uani 1 1 d D . .
H2WA H 0.691(5) 0.675(7) 0.5831(13) 0.070 Uiso 1 1 d D . .
H2WB H 0.673(4) 0.695(7) 0.623(3) 0.070 Uiso 1 1 d D . .
O3W O 0.8578(4) 0.7370(4) 0.6571(2) 0.0370(14) Uani 1 1 d D . .
H3WA H 0.813(3) 0.719(5) 0.645(3) 0.055 Uiso 1 1 d D . .
H3WB H 0.854(5) 0.792(2) 0.656(3) 0.055 Uiso 1 1 d D . .
O4W O 0.5748(5) 0.9863(5) 0.7334(2) 0.059(2) Uani 1 1 d D . .
H4WA H 0.606(6) 0.947(6) 0.727(4) 0.088 Uiso 1 1 d D . .
H4WB H 0.558(12) 0.968(10) 0.756(5) 0.088 Uiso 0.50 1 d PD A 1
H4WC H 0.544(11) 0.996(13) 0.710(3) 0.088 Uiso 0.50 1 d PD B 2
O5W O 0.9167(6) 0.6569(6) 0.7372(2) 0.073(3) Uani 1 1 d D . .
H5WA H 0.891(7) 0.676(8) 0.714(3) 0.109 Uiso 1 1 d D . .
H5WB H 0.903(15) 0.604(6) 0.738(7) 0.109 Uiso 0.50 1 d PD C 1
H5WC H 0.965(3) 0.659(18) 0.732(6) 0.109 Uiso 0.50 1 d PD D 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_exptl_crystal_face_index_h
_exptl_crystal_face_index_k
_exptl_crystal_face_index_l
_exptl_crystal_face_perp_dist
0.00 0.00 1.00 0.0050
0.00 0.00 -1.00 0.0050
1.00 -1.00 1.00 0.0600
-1.00 1.00 -1.00 0.0600
1.00 1.00 -1.00 0.1200
-1.00 -1.00 1.00 0.1200
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O3 Eu1 O4 79.82(15) . 7_566 ?
O3 Eu1 O2 81.27(16) . . ?
O4 Eu1 O2 130.60(15) 7_566 . ?
O3 Eu1 O1 127.29(15) . . ?
O4 Eu1 O1 77.22(14) 7_566 . ?
O2 Eu1 O1 79.00(15) . . ?
O3 Eu1 N4 86.10(16) . . ?
O4 Eu1 N4 71.77(15) 7_566 . ?
O2 Eu1 N4 150.89(16) . . ?
O1 Eu1 N4 128.71(16) . . ?
O3 Eu1 N2 129.63(15) . . ?
O4 Eu1 N2 149.93(16) 7_566 . ?
O2 Eu1 N2 68.60(15) . . ?
O1 Eu1 N2 86.25(15) . . ?
N4 Eu1 N2 100.98(16) . . ?
O3 Eu1 N3 69.60(15) . . ?
O4 Eu1 N3 129.23(15) 7_566 . ?
O2 Eu1 N3 84.25(15) . . ?
O1 Eu1 N3 153.17(15) . . ?
N4 Eu1 N3 66.75(16) . . ?
N2 Eu1 N3 68.08(16) . . ?
O3 Eu1 N1 151.75(16) . . ?
O4 Eu1 N1 82.51(15) 7_566 . ?
O2 Eu1 N1 126.78(15) . . ?
O1 Eu1 N1 68.86(15) . . ?
N4 Eu1 N1 67.44(16) . . ?
N2 Eu1 N1 68.05(15) . . ?
N3 Eu1 N1 106.32(15) . . ?
O3 Eu1 P3 21.70(11) . . ?
O4 Eu1 P3 101.31(11) 7_566 . ?
O2 Eu1 P3 69.12(11) . . ?
O1 Eu1 P3 136.25(10) . . ?
N4 Eu1 P3 89.97(13) . . ?
N2 Eu1 P3 107.94(12) . . ?
N3 Eu1 P3 52.13(11) . . ?
N1 Eu1 P3 154.89(11) . . ?
O3 Eu1 P1 134.70(10) . . ?
O4 Eu1 P1 64.89(11) 7_566 . ?
O2 Eu1 P1 100.23(11) . . ?
O1 Eu1 P1 21.46(10) . . ?
N4 Eu1 P1 107.25(12) . . ?
N2 Eu1 P1 91.03(12) . . ?
N3 Eu1 P1 155.59(11) . . ?
N1 Eu1 P1 51.93(11) . . ?
P3 Eu1 P1 151.69(4) . . ?
O3 Eu1 P2 101.91(12) . . ?
O4 Eu1 P2 138.31(10) 7_566 . ?
O2 Eu1 P2 20.91(11) . . ?
O1 Eu1 P2 68.80(10) . . ?
N4 Eu1 P2 149.56(12) . . ?
N2 Eu1 P2 51.46(11) . . ?
N3 Eu1 P2 88.35(11) . . ?
N1 Eu1 P2 105.95(11) . . ?
P3 Eu1 P2 87.81(4) . . ?
P1 Eu1 P2 88.03(4) . . ?
O4 P1 O1 117.4(2) . . ?
O4 P1 C12 108.1(3) . . ?
O1 P1 C12 109.3(3) . . ?
O4 P1 C9 107.3(3) . . ?
O1 P1 C9 106.3(3) . . ?
C12 P1 C9 108.1(3) . . ?
O4 P1 Eu1 115.97(18) . . ?
O1 P1 Eu1 35.25(17) . . ?
C12 P1 Eu1 133.2(2) . . ?
C9 P1 Eu1 73.7(2) . . ?
O5 P2 O2 117.5(3) . . ?
O5 P2 C19 110.5(3) . . ?
O2 P2 C19 109.2(3) . . ?
O5 P2 C10 110.4(3) . . ?
O2 P2 C10 104.5(3) . . ?
C19 P2 C10 103.7(3) . . ?
O5 P2 Eu1 138.7(2) . . ?
O2 P2 Eu1 33.11(16) . . ?
C19 P2 Eu1 108.3(2) . . ?
C10 P2 Eu1 72.7(2) . . ?
O6 P3 O3 116.3(3) . . ?
O6 P3 C26 110.0(3) . . ?
O3 P3 C26 107.6(3) . . ?
O6 P3 C11 111.6(3) . . ?
O3 P3 C11 105.6(3) . . ?
C26 P3 C11 105.0(3) . . ?
O6 P3 Eu1 139.79(19) . . ?
O3 P3 Eu1 34.17(17) . . ?
C26 P3 Eu1 106.8(2) . . ?
C11 P3 Eu1 72.9(2) . . ?
C9 N1 C1 109.3(5) . . ?
C9 N1 C8 109.4(5) . . ?
C1 N1 C8 108.8(5) . . ?
C9 N1 Eu1 107.5(4) . . ?
C1 N1 Eu1 110.2(3) . . ?
C8 N1 Eu1 111.6(4) . . ?
C2 N2 C10 109.2(5) . . ?
C2 N2 C3 110.1(5) . . ?
C10 N2 C3 107.3(5) . . ?
C2 N2 Eu1 111.9(4) . . ?
C10 N2 Eu1 107.0(3) . . ?
C3 N2 Eu1 111.0(4) . . ?
C11 N3 C5 110.2(5) . . ?
C11 N3 C4 109.8(5) . . ?
C5 N3 C4 109.0(5) . . ?
C11 N3 Eu1 105.0(4) . . ?
C5 N3 Eu1 110.4(3) . . ?
C4 N3 Eu1 112.4(4) . . ?
C6 N4 C7 113.8(5) . . ?
C6 N4 Eu1 116.2(4) . . ?
C7 N4 Eu1 112.3(4) . . ?
C6 N4 H4C 104.3 . . ?
C7 N4 H4C 104.3 . . ?
Eu1 N4 H4C 104.3 . . ?
N1 C1 C2 112.4(5) . . ?
N1 C1 H1A 109.1 . . ?
C2 C1 H1A 109.1 . . ?
N1 C1 H1B 109.1 . . ?
C2 C1 H1B 109.1 . . ?
H1A C1 H1B 107.9 . . ?
N2 C2 C1 112.5(5) . . ?
N2 C2 H2A 109.1 . . ?
C1 C2 H2A 109.1 . . ?
N2 C2 H2B 109.1 . . ?
C1 C2 H2B 109.1 . . ?
H2A C2 H2B 107.8 . . ?
N2 C3 C4 112.5(5) . . ?
N2 C3 H3A 109.1 . . ?
C4 C3 H3A 109.1 . . ?
N2 C3 H3B 109.1 . . ?
C4 C3 H3B 109.1 . . ?
H3A C3 H3B 107.8 . . ?
N3 C4 C3 111.9(5) . . ?
N3 C4 H4A 109.2 . . ?
C3 C4 H4A 109.2 . . ?
N3 C4 H4B 109.2 . . ?
C3 C4 H4B 109.2 . . ?
H4A C4 H4B 107.9 . . ?
N3 C5 C6 110.8(5) . . ?
N3 C5 H5A 109.5 . . ?
C6 C5 H5A 109.5 . . ?
N3 C5 H5B 109.5 . . ?
C6 C5 H5B 109.5 . . ?
H5A C5 H5B 108.1 . . ?
N4 C6 C5 110.5(5) . . ?
N4 C6 H6A 109.5 . . ?
C5 C6 H6A 109.5 . . ?
N4 C6 H6B 109.5 . . ?
C5 C6 H6B 109.5 . . ?
H6A C6 H6B 108.1 . . ?
N4 C7 C8 110.1(5) . . ?
N4 C7 H7A 109.6 . . ?
C8 C7 H7A 109.6 . . ?
N4 C7 H7B 109.6 . . ?
C8 C7 H7B 109.6 . . ?
H7A C7 H7B 108.2 . . ?
N1 C8 C7 111.3(5) . . ?
N1 C8 H8A 109.4 . . ?
C7 C8 H8A 109.4 . . ?
N1 C8 H8B 109.4 . . ?
C7 C8 H8B 109.4 . . ?
H8A C8 H8B 108.0 . . ?
N1 C9 P1 112.9(4) . . ?
N1 C9 H9A 109.0 . . ?
P1 C9 H9A 109.0 . . ?
N1 C9 H9B 109.0 . . ?
P1 C9 H9B 109.0 . . ?
H9A C9 H9B 107.8 . . ?
N2 C10 P2 110.2(4) . . ?
N2 C10 H10A 109.6 . . ?
P2 C10 H10A 109.6 . . ?
N2 C10 H10B 109.6 . . ?
P2 C10 H10B 109.6 . . ?
H10A C10 H10B 108.1 . . ?
N3 C11 P3 110.5(4) . . ?
N3 C11 H11A 109.5 . . ?
P3 C11 H11A 109.5 . . ?
N3 C11 H11B 109.5 . . ?
P3 C11 H11B 109.5 . . ?
H11A C11 H11B 108.1 . . ?
C13 C12 P1 113.2(5) . . ?
C13 C12 H12A 108.9 . . ?
P1 C12 H12A 108.9 . . ?
C13 C12 H12B 108.9 . . ?
P1 C12 H12B 108.9 . . ?
H12A C12 H12B 107.7 . . ?
C14 C13 C18 118.2(7) . . ?
C14 C13 C12 119.8(6) . . ?
C18 C13 C12 122.1(6) . . ?
C13 C14 C15 120.2(7) . . ?
C13 C14 H14 119.9 . . ?
C15 C14 H14 119.9 . . ?
C16 C15 C14 121.2(7) . . ?
C16 C15 H15 119.4 . . ?
C14 C15 H15 119.4 . . ?
C15 C16 C17 118.7(7) . . ?
C15 C16 H16 120.7 . . ?
C17 C16 H16 120.7 . . ?
C18 C17 C16 120.4(7) . . ?
C18 C17 H17 119.8 . . ?
C16 C17 H17 119.8 . . ?
C17 C18 C13 121.3(7) . . ?
C17 C18 H18 119.4 . . ?
C13 C18 H18 119.4 . . ?
C20 C19 P2 113.6(5) . . ?
C20 C19 H19A 108.8 . . ?
P2 C19 H19A 108.8 . . ?
C20 C19 H19B 108.8 . . ?
P2 C19 H19B 108.8 . . ?
H19A C19 H19B 107.7 . . ?
C21 C20 C25 118.1(7) . . ?
C21 C20 C19 120.8(6) . . ?
C25 C20 C19 121.1(6) . . ?
C20 C21 C22 121.2(7) . . ?
C20 C21 H21 119.4 . . ?
C22 C21 H21 119.4 . . ?
C23 C22 C21 120.2(7) . . ?
C23 C22 H22 119.9 . . ?
C21 C22 H22 119.9 . . ?
C22 C23 C24 118.6(7) . . ?
C22 C23 H23 120.7 . . ?
C24 C23 H23 120.7 . . ?
C23 C24 C25 121.2(7) . . ?
C23 C24 H24 119.4 . . ?
C25 C24 H24 119.4 . . ?
C20 C25 C24 120.7(7) . . ?
C20 C25 H25 119.7 . . ?
C24 C25 H25 119.7 . . ?
C27 C26 P3 116.0(5) . . ?
C27 C26 H26A 108.3 . . ?
P3 C26 H26A 108.3 . . ?
C27 C26 H26B 108.3 . . ?
P3 C26 H26B 108.3 . . ?
H26A C26 H26B 107.4 . . ?
C32 C27 C28 118.2(6) . . ?
C32 C27 C26 122.3(6) . . ?
C28 C27 C26 119.4(6) . . ?
C29 C28 C27 120.8(7) . . ?
C29 C28 H28 119.6 . . ?
C27 C28 H28 119.6 . . ?
C28 C29 C30 119.9(7) . . ?
C28 C29 H29 120.0 . . ?
C30 C29 H29 120.0 . . ?
C31 C30 C29 120.0(7) . . ?
C31 C30 H30 120.0 . . ?
C29 C30 H30 120.0 . . ?
C30 C31 C32 120.1(7) . . ?
C30 C31 H31 119.9 . . ?
C32 C31 H31 119.9 . . ?
C31 C32 C27 121.0(7) . . ?
C31 C32 H32 119.5 . . ?
C27 C32 H32 119.5 . . ?
P1 O1 Eu1 123.3(2) . . ?
P2 O2 Eu1 126.0(2) . . ?
P3 O3 Eu1 124.1(2) . . ?
P1 O4 Eu1 161.7(3) . 7_566 ?
H1WA O1W H1WB 105(5) . . ?
H2WA O2W H2WB 105(5) . . ?
H3WA O3W H3WB 104(5) . . ?
H4WA O4W H4WB 105(5) . . ?
H4WA O4W H4WC 105(5) . . ?
H4WB O4W H4WC 121(10) . . ?
H5WA O5W H5WB 105(5) . . ?
H5WA O5W H5WC 105(5) . . ?
H5WB O5W H5WC 108(10) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O3 2.309(4) . ?
Eu1 O4 2.316(4) 7_566 ?
Eu1 O2 2.327(4) . ?
Eu1 O1 2.379(4) . ?
Eu1 N4 2.577(5) . ?
Eu1 N2 2.640(5) . ?
Eu1 N3 2.659(5) . ?
Eu1 N1 2.677(5) . ?
Eu1 P3 3.4031(18) . ?
Eu1 P1 3.4460(17) . ?
Eu1 P2 3.4474(16) . ?
P1 O4 1.506(4) . ?
P1 O1 1.508(4) . ?
P1 C12 1.816(7) . ?
P1 C9 1.839(6) . ?
P2 O5 1.493(5) . ?
P2 O2 1.520(5) . ?
P2 C19 1.814(7) . ?
P2 C10 1.843(7) . ?
P3 O6 1.505(5) . ?
P3 O3 1.520(4) . ?
P3 C26 1.805(7) . ?
P3 C11 1.850(7) . ?
N1 C9 1.473(8) . ?
N1 C1 1.490(8) . ?
N1 C8 1.495(8) . ?
N2 C2 1.485(8) . ?
N2 C10 1.491(8) . ?
N2 C3 1.492(8) . ?
N3 C11 1.482(8) . ?
N3 C5 1.490(8) . ?
N3 C4 1.492(8) . ?
N4 C6 1.467(8) . ?
N4 C7 1.474(8) . ?
N4 H4C 0.9100 . ?
C1 C2 1.512(9) . ?
C1 H1A 0.9700 . ?
C1 H1B 0.9700 . ?
C2 H2A 0.9700 . ?
C2 H2B 0.9700 . ?
C3 C4 1.524(9) . ?
C3 H3A 0.9700 . ?
C3 H3B 0.9700 . ?
C4 H4A 0.9700 . ?
C4 H4B 0.9700 . ?
C5 C6 1.510(9) . ?
C5 H5A 0.9700 . ?
C5 H5B 0.9700 . ?
C6 H6A 0.9700 . ?
C6 H6B 0.9700 . ?
C7 C8 1.526(9) . ?
C7 H7A 0.9700 . ?
C7 H7B 0.9700 . ?
C8 H8A 0.9700 . ?
C8 H8B 0.9700 . ?
C9 H9A 0.9700 . ?
C9 H9B 0.9700 . ?
C10 H10A 0.9700 . ?
C10 H10B 0.9700 . ?
C11 H11A 0.9700 . ?
C11 H11B 0.9700 . ?
C12 C13 1.511(9) . ?
C12 H12A 0.9700 . ?
C12 H12B 0.9700 . ?
C13 C14 1.388(10) . ?
C13 C18 1.396(10) . ?
C14 C15 1.397(11) . ?
C14 H14 0.9300 . ?
C15 C16 1.373(12) . ?
C15 H15 0.9300 . ?
C16 C17 1.396(12) . ?
C16 H16 0.9300 . ?
C17 C18 1.377(10) . ?
C17 H17 0.9300 . ?
C18 H18 0.9300 . ?
C19 C20 1.521(9) . ?
C19 H19A 0.9700 . ?
C19 H19B 0.9700 . ?
C20 C21 1.377(10) . ?
C20 C25 1.383(10) . ?
C21 C22 1.400(10) . ?
C21 H21 0.9300 . ?
C22 C23 1.376(11) . ?
C22 H22 0.9300 . ?
C23 C24 1.377(11) . ?
C23 H23 0.9300 . ?
C24 C25 1.386(11) . ?
C24 H24 0.9300 . ?
C25 H25 0.9300 . ?
C26 C27 1.501(9) . ?
C26 H26A 0.9700 . ?
C26 H26B 0.9700 . ?
C27 C32 1.398(10) . ?
C27 C28 1.398(10) . ?
C28 C29 1.389(10) . ?
C28 H28 0.9300 . ?
C29 C30 1.391(11) . ?
C29 H29 0.9300 . ?
C30 C31 1.378(11) . ?
C30 H30 0.9300 . ?
C31 C32 1.387(10) . ?
C31 H31 0.9300 . ?
C32 H32 0.9300 . ?
O4 Eu1 2.316(4) 7_566 ?
O1W H1WA 0.83(3) . ?
O1W H1WB 0.83(3) . ?
O2W H2WA 0.83(3) . ?
O2W H2WB 0.83(3) . ?
O3W H3WA 0.83(3) . ?
O3W H3WB 0.83(3) . ?
O4W H4WA 0.83(3) . ?
O4W H4WB 0.83(3) . ?
O4W H4WC 0.83(3) . ?
O5W H5WA 0.83(3) . ?
O5W H5WB 0.83(3) . ?
O5W H5WC 0.83(3) . ?
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
O1W H1WA O6 0.83(3) 1.98(3) 2.807(7) 176(8) .
O1W H1WB O5 0.83(3) 2.10(3) 2.924(7) 173(8) 3
O2W H2WB O6 0.83(3) 1.94(3) 2.765(8) 173(11) .
O3W H3WA O2W 0.83(3) 2.01(3) 2.838(8) 173(10) .
O3W H3WB O5 0.83(3) 2.00(4) 2.798(7) 160(8) 3
O4W H4WA O1W 0.83(3) 1.98(4) 2.802(8) 172(12) .
O4W H4WB O4W 0.83(3) 2.28(16) 2.800(17) 121(16) 2_656
O5W H5WA O3W 0.83(3) 1.97(5) 2.781(9) 164(13) .
O5W H5WB O4W 0.83(3) 1.99(9) 2.729(11) 147(15) 4_646
O5W H5WC O5W 0.83(3) 2.08(9) 2.79(2) 144(15) 2_756
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O3 Eu1 P1 O4 -22.2(3) . . . . ?
O4 Eu1 P1 O4 20.2(3) 7_566 . . . ?
O2 Eu1 P1 O4 -110.0(2) . . . . ?
O1 Eu1 P1 O4 -101.4(3) . . . . ?
N4 Eu1 P1 O4 79.8(2) . . . . ?
N2 Eu1 P1 O4 -178.4(2) . . . . ?
N3 Eu1 P1 O4 151.3(3) . . . . ?
N1 Eu1 P1 O4 120.9(2) . . . . ?
P3 Eu1 P1 O4 -45.4(2) . . . . ?
P2 Eu1 P1 O4 -127.04(19) . . . . ?
O3 Eu1 P1 O1 79.2(3) . . . . ?
O4 Eu1 P1 O1 121.6(3) 7_566 . . . ?
O2 Eu1 P1 O1 -8.6(3) . . . . ?
N4 Eu1 P1 O1 -178.9(3) . . . . ?
N2 Eu1 P1 O1 -77.0(3) . . . . ?
N3 Eu1 P1 O1 -107.3(4) . . . . ?
N1 Eu1 P1 O1 -137.8(3) . . . . ?
P3 Eu1 P1 O1 56.0(3) . . . . ?
P2 Eu1 P1 O1 -25.7(3) . . . . ?
O3 Eu1 P1 C12 136.4(3) . . . . ?
O4 Eu1 P1 C12 178.8(3) 7_566 . . . ?
O2 Eu1 P1 C12 48.6(3) . . . . ?
O1 Eu1 P1 C12 57.2(4) . . . . ?
N4 Eu1 P1 C12 -121.7(3) . . . . ?
N2 Eu1 P1 C12 -19.9(3) . . . . ?
N3 Eu1 P1 C12 -50.1(4) . . . . ?
N1 Eu1 P1 C12 -80.6(3) . . . . ?
P3 Eu1 P1 C12 113.2(3) . . . . ?
P2 Eu1 P1 C12 31.5(3) . . . . ?
O3 Eu1 P1 C9 -123.8(3) . . . . ?
O4 Eu1 P1 C9 -81.4(2) 7_566 . . . ?
O2 Eu1 P1 C9 148.4(2) . . . . ?
O1 Eu1 P1 C9 157.0(4) . . . . ?
N4 Eu1 P1 C9 -21.9(2) . . . . ?
N2 Eu1 P1 C9 79.9(2) . . . . ?
N3 Eu1 P1 C9 49.7(3) . . . . ?
N1 Eu1 P1 C9 19.2(2) . . . . ?
P3 Eu1 P1 C9 -147.0(2) . . . . ?
P2 Eu1 P1 C9 131.3(2) . . . . ?
O3 Eu1 P2 O5 52.9(3) . . . . ?
O4 Eu1 P2 O5 140.9(3) 7_566 . . . ?
O2 Eu1 P2 O5 62.2(4) . . . . ?
O1 Eu1 P2 O5 178.5(3) . . . . ?
N4 Eu1 P2 O5 -49.9(4) . . . . ?
N2 Eu1 P2 O5 -78.9(3) . . . . ?
N3 Eu1 P2 O5 -15.9(3) . . . . ?
N1 Eu1 P2 O5 -122.4(3) . . . . ?
P3 Eu1 P2 O5 36.3(3) . . . . ?
P1 Eu1 P2 O5 -171.7(3) . . . . ?
O3 Eu1 P2 O2 -9.4(3) . . . . ?
O4 Eu1 P2 O2 78.6(3) 7_566 . . . ?
O1 Eu1 P2 O2 116.2(3) . . . . ?
N4 Eu1 P2 O2 -112.2(4) . . . . ?
N2 Eu1 P2 O2 -141.1(3) . . . . ?
N3 Eu1 P2 O2 -78.1(3) . . . . ?
N1 Eu1 P2 O2 175.4(3) . . . . ?
P3 Eu1 P2 O2 -26.0(3) . . . . ?
P1 Eu1 P2 O2 126.0(3) . . . . ?
O3 Eu1 P2 C19 -106.6(3) . . . . ?
O4 Eu1 P2 C19 -18.5(3) 7_566 . . . ?
O2 Eu1 P2 C19 -97.2(4) . . . . ?
O1 Eu1 P2 C19 19.1(3) . . . . ?
N4 Eu1 P2 C19 150.6(3) . . . . ?
N2 Eu1 P2 C19 121.7(3) . . . . ?
N3 Eu1 P2 C19 -175.3(3) . . . . ?
N1 Eu1 P2 C19 78.2(3) . . . . ?
P3 Eu1 P2 C19 -123.2(2) . . . . ?
P1 Eu1 P2 C19 28.8(2) . . . . ?
O3 Eu1 P2 C10 154.3(2) . . . . ?
O4 Eu1 P2 C10 -117.7(3) 7_566 . . . ?
O2 Eu1 P2 C10 163.7(4) . . . . ?
O1 Eu1 P2 C10 -80.1(2) . . . . ?
N4 Eu1 P2 C10 51.5(3) . . . . ?
N2 Eu1 P2 C10 22.6(3) . . . . ?
N3 Eu1 P2 C10 85.6(2) . . . . ?
N1 Eu1 P2 C10 -20.9(3) . . . . ?
P3 Eu1 P2 C10 137.7(2) . . . . ?
P1 Eu1 P2 C10 -70.3(2) . . . . ?
O3 Eu1 P3 O6 58.8(4) . . . . ?
O4 Eu1 P3 O6 50.7(3) 7_566 . . . ?
O2 Eu1 P3 O6 -180.0(3) . . . . ?
O1 Eu1 P3 O6 134.0(3) . . . . ?
N4 Eu1 P3 O6 -20.7(3) . . . . ?
N2 Eu1 P3 O6 -122.2(3) . . . . ?
N3 Eu1 P3 O6 -80.7(3) . . . . ?
N1 Eu1 P3 O6 -45.8(4) . . . . ?
P1 Eu1 P3 O6 107.9(3) . . . . ?
P2 Eu1 P3 O6 -170.3(3) . . . . ?
O4 Eu1 P3 O3 -8.1(3) 7_566 . . . ?
O2 Eu1 P3 O3 121.3(3) . . . . ?
O1 Eu1 P3 O3 75.2(3) . . . . ?
N4 Eu1 P3 O3 -79.5(3) . . . . ?
N2 Eu1 P3 O3 179.0(3) . . . . ?
N3 Eu1 P3 O3 -139.5(3) . . . . ?
N1 Eu1 P3 O3 -104.6(4) . . . . ?
P1 Eu1 P3 O3 49.2(3) . . . . ?
P2 Eu1 P3 O3 130.9(3) . . . . ?
O3 Eu1 P3 C26 -96.8(4) . . . . ?
O4 Eu1 P3 C26 -104.8(3) 7_566 . . . ?
O2 Eu1 P3 C26 24.5(3) . . . . ?
O1 Eu1 P3 C26 -21.6(3) . . . . ?
N4 Eu1 P3 C26 -176.2(3) . . . . ?
N2 Eu1 P3 C26 82.2(3) . . . . ?
N3 Eu1 P3 C26 123.7(3) . . . . ?
N1 Eu1 P3 C26 158.6(3) . . . . ?
P1 Eu1 P3 C26 -47.6(3) . . . . ?
P2 Eu1 P3 C26 34.1(2) . . . . ?
O3 Eu1 P3 C11 162.3(4) . . . . ?
O4 Eu1 P3 C11 154.2(2) 7_566 . . . ?
O2 Eu1 P3 C11 -76.5(2) . . . . ?
O1 Eu1 P3 C11 -122.5(3) . . . . ?
N4 Eu1 P3 C11 82.8(2) . . . . ?
N2 Eu1 P3 C11 -18.7(3) . . . . ?
N3 Eu1 P3 C11 22.8(3) . . . . ?
N1 Eu1 P3 C11 57.7(3) . . . . ?
P1 Eu1 P3 C11 -148.6(2) . . . . ?
P2 Eu1 P3 C11 -66.8(2) . . . . ?
O3 Eu1 N1 C9 91.0(4) . . . . ?
O4 Eu1 N1 C9 39.4(3) 7_566 . . . ?
O2 Eu1 N1 C9 -96.7(4) . . . . ?
O1 Eu1 N1 C9 -39.7(3) . . . . ?
N4 Eu1 N1 C9 112.7(4) . . . . ?
N2 Eu1 N1 C9 -134.3(4) . . . . ?
N3 Eu1 N1 C9 168.2(3) . . . . ?
P3 Eu1 N1 C9 140.1(3) . . . . ?
P1 Eu1 N1 C9 -24.4(3) . . . . ?
P2 Eu1 N1 C9 -98.8(3) . . . . ?
O3 Eu1 N1 C1 -150.0(4) . . . . ?
O4 Eu1 N1 C1 158.4(4) 7_566 . . . ?
O2 Eu1 N1 C1 22.3(4) . . . . ?
O1 Eu1 N1 C1 79.3(4) . . . . ?
N4 Eu1 N1 C1 -128.2(4) . . . . ?
N2 Eu1 N1 C1 -15.3(4) . . . . ?
N3 Eu1 N1 C1 -72.8(4) . . . . ?
P3 Eu1 N1 C1 -100.8(4) . . . . ?
P1 Eu1 N1 C1 94.6(4) . . . . ?
P2 Eu1 N1 C1 20.2(4) . . . . ?
O3 Eu1 N1 C8 -28.9(6) . . . . ?
O4 Eu1 N1 C8 -80.5(4) 7_566 . . . ?
O2 Eu1 N1 C8 143.3(4) . . . . ?
O1 Eu1 N1 C8 -159.7(4) . . . . ?
N4 Eu1 N1 C8 -7.2(4) . . . . ?
N2 Eu1 N1 C8 105.7(4) . . . . ?
N3 Eu1 N1 C8 48.2(4) . . . . ?
P3 Eu1 N1 C8 20.2(5) . . . . ?
P1 Eu1 N1 C8 -144.4(4) . . . . ?
P2 Eu1 N1 C8 141.3(4) . . . . ?
O3 Eu1 N2 C2 140.6(4) . . . . ?
O4 Eu1 N2 C2 -26.0(6) 7_566 . . . ?
O2 Eu1 N2 C2 -161.8(4) . . . . ?
O1 Eu1 N2 C2 -82.2(4) . . . . ?
N4 Eu1 N2 C2 46.5(4) . . . . ?
N3 Eu1 N2 C2 105.8(4) . . . . ?
N1 Eu1 N2 C2 -13.5(4) . . . . ?
P3 Eu1 N2 C2 140.1(4) . . . . ?
P1 Eu1 N2 C2 -61.3(4) . . . . ?
P2 Eu1 N2 C2 -147.9(4) . . . . ?
O3 Eu1 N2 C10 -99.8(4) . . . . ?
O4 Eu1 N2 C10 93.7(5) 7_566 . . . ?
O2 Eu1 N2 C10 -42.2(4) . . . . ?
O1 Eu1 N2 C10 37.4(4) . . . . ?
N4 Eu1 N2 C10 166.2(4) . . . . ?
N3 Eu1 N2 C10 -134.6(4) . . . . ?
N1 Eu1 N2 C10 106.1(4) . . . . ?
P3 Eu1 N2 C10 -100.3(4) . . . . ?
P1 Eu1 N2 C10 58.4(4) . . . . ?
P2 Eu1 N2 C10 -28.3(3) . . . . ?
O3 Eu1 N2 C3 17.0(5) . . . . ?
O4 Eu1 N2 C3 -149.5(4) 7_566 . . . ?
O2 Eu1 N2 C3 74.6(4) . . . . ?
O1 Eu1 N2 C3 154.3(4) . . . . ?
N4 Eu1 N2 C3 -77.0(4) . . . . ?
N3 Eu1 N2 C3 -17.8(4) . . . . ?
N1 Eu1 N2 C3 -137.0(4) . . . . ?
P3 Eu1 N2 C3 16.6(4) . . . . ?
P1 Eu1 N2 C3 175.2(4) . . . . ?
P2 Eu1 N2 C3 88.5(4) . . . . ?
O3 Eu1 N3 C11 -43.4(3) . . . . ?
O4 Eu1 N3 C11 -100.3(4) 7_566 . . . ?
O2 Eu1 N3 C11 39.4(4) . . . . ?
O1 Eu1 N3 C11 90.8(5) . . . . ?
N4 Eu1 N3 C11 -138.1(4) . . . . ?
N2 Eu1 N3 C11 108.6(4) . . . . ?
N1 Eu1 N3 C11 166.1(3) . . . . ?
P3 Eu1 N3 C11 -28.6(3) . . . . ?
P1 Eu1 N3 C11 141.5(3) . . . . ?
P2 Eu1 N3 C11 59.9(3) . . . . ?
O3 Eu1 N3 C5 75.4(4) . . . . ?
O4 Eu1 N3 C5 18.5(4) 7_566 . . . ?
O2 Eu1 N3 C5 158.2(4) . . . . ?
O1 Eu1 N3 C5 -150.5(4) . . . . ?
N4 Eu1 N3 C5 -19.3(4) . . . . ?
N2 Eu1 N3 C5 -132.6(4) . . . . ?
N1 Eu1 N3 C5 -75.1(4) . . . . ?
P3 Eu1 N3 C5 90.2(4) . . . . ?
P1 Eu1 N3 C5 -99.7(4) . . . . ?
P2 Eu1 N3 C5 178.7(4) . . . . ?
O3 Eu1 N3 C4 -162.7(4) . . . . ?
O4 Eu1 N3 C4 140.5(4) 7_566 . . . ?
O2 Eu1 N3 C4 -79.9(4) . . . . ?
O1 Eu1 N3 C4 -28.5(6) . . . . ?
N4 Eu1 N3 C4 102.7(4) . . . . ?
N2 Eu1 N3 C4 -10.7(4) . . . . ?
N1 Eu1 N3 C4 46.8(4) . . . . ?
P3 Eu1 N3 C4 -147.9(4) . . . . ?
P1 Eu1 N3 C4 22.2(6) . . . . ?
P2 Eu1 N3 C4 -59.4(4) . . . . ?
O3 Eu1 N4 C6 -79.8(4) . . . . ?
O4 Eu1 N4 C6 -160.3(5) 7_566 . . . ?
O2 Eu1 N4 C6 -15.6(6) . . . . ?
O1 Eu1 N4 C6 143.9(4) . . . . ?
N2 Eu1 N4 C6 49.9(4) . . . . ?
N3 Eu1 N4 C6 -10.3(4) . . . . ?
N1 Eu1 N4 C6 110.3(4) . . . . ?
P3 Eu1 N4 C6 -58.4(4) . . . . ?
P1 Eu1 N4 C6 144.4(4) . . . . ?
P2 Eu1 N4 C6 27.2(6) . . . . ?
O3 Eu1 N4 C7 146.8(4) . . . . ?
O4 Eu1 N4 C7 66.2(4) 7_566 . . . ?
O2 Eu1 N4 C7 -149.0(4) . . . . ?
O1 Eu1 N4 C7 10.4(5) . . . . ?
N2 Eu1 N4 C7 -83.6(4) . . . . ?
N3 Eu1 N4 C7 -143.8(4) . . . . ?
N1 Eu1 N4 C7 -23.1(4) . . . . ?
P3 Eu1 N4 C7 168.1(4) . . . . ?
P1 Eu1 N4 C7 11.0(4) . . . . ?
P2 Eu1 N4 C7 -106.2(4) . . . . ?
C9 N1 C1 C2 161.3(5) . . . . ?
C8 N1 C1 C2 -79.4(6) . . . . ?
Eu1 N1 C1 C2 43.3(6) . . . . ?
C10 N2 C2 C1 -76.5(6) . . . . ?
C3 N2 C2 C1 165.9(5) . . . . ?
Eu1 N2 C2 C1 41.8(6) . . . . ?
N1 C1 C2 N2 -59.2(7) . . . . ?
C2 N2 C3 C4 -79.1(6) . . . . ?
C10 N2 C3 C4 162.1(5) . . . . ?
Eu1 N2 C3 C4 45.4(6) . . . . ?
C11 N3 C4 C3 -78.4(6) . . . . ?
C5 N3 C4 C3 160.8(5) . . . . ?
Eu1 N3 C4 C3 38.1(6) . . . . ?
N2 C3 C4 N3 -57.5(7) . . . . ?
C11 N3 C5 C6 162.5(5) . . . . ?
C4 N3 C5 C6 -76.9(6) . . . . ?
Eu1 N3 C5 C6 47.0(6) . . . . ?
C7 N4 C6 C5 171.4(5) . . . . ?
Eu1 N4 C6 C5 38.7(6) . . . . ?
N3 C5 C6 N4 -57.7(7) . . . . ?
C6 N4 C7 C8 -83.0(6) . . . . ?
Eu1 N4 C7 C8 51.6(6) . . . . ?
C9 N1 C8 C7 -82.9(6) . . . . ?
C1 N1 C8 C7 157.8(5) . . . . ?
Eu1 N1 C8 C7 35.9(6) . . . . ?
N4 C7 C8 N1 -59.2(7) . . . . ?
C1 N1 C9 P1 -78.1(5) . . . . ?
C8 N1 C9 P1 162.9(4) . . . . ?
Eu1 N1 C9 P1 41.5(5) . . . . ?
O4 P1 C9 N1 -143.5(4) . . . . ?
O1 P1 C9 N1 -17.1(5) . . . . ?
C12 P1 C9 N1 100.1(5) . . . . ?
Eu1 P1 C9 N1 -30.8(4) . . . . ?
C2 N2 C10 P2 169.0(4) . . . . ?
C3 N2 C10 P2 -71.6(5) . . . . ?
Eu1 N2 C10 P2 47.7(4) . . . . ?
O5 P2 C10 N2 101.8(4) . . . . ?
O2 P2 C10 N2 -25.4(5) . . . . ?
C19 P2 C10 N2 -139.8(4) . . . . ?
Eu1 P2 C10 N2 -34.5(4) . . . . ?
C5 N3 C11 P3 -71.0(6) . . . . ?
C4 N3 C11 P3 168.9(4) . . . . ?
Eu1 N3 C11 P3 47.9(4) . . . . ?
O6 P3 C11 N3 101.7(5) . . . . ?
O3 P3 C11 N3 -25.6(5) . . . . ?
C26 P3 C11 N3 -139.2(5) . . . . ?
Eu1 P3 C11 N3 -35.9(4) . . . . ?
O4 P1 C12 C13 36.2(6) . . . . ?
O1 P1 C12 C13 -92.7(5) . . . . ?
C9 P1 C12 C13 152.0(5) . . . . ?
Eu1 P1 C12 C13 -123.6(4) . . . . ?
P1 C12 C13 C14 -104.3(7) . . . . ?
P1 C12 C13 C18 75.1(7) . . . . ?
C18 C13 C14 C15 -0.6(10) . . . . ?
C12 C13 C14 C15 178.8(6) . . . . ?
C13 C14 C15 C16 0.6(11) . . . . ?
C14 C15 C16 C17 0.0(11) . . . . ?
C15 C16 C17 C18 -0.5(11) . . . . ?
C16 C17 C18 C13 0.5(11) . . . . ?
C14 C13 C18 C17 0.0(10) . . . . ?
C12 C13 C18 C17 -179.4(6) . . . . ?
O5 P2 C19 C20 -82.3(5) . . . . ?
O2 P2 C19 C20 48.3(5) . . . . ?
C10 P2 C19 C20 159.3(5) . . . . ?
Eu1 P2 C19 C20 83.3(5) . . . . ?
P2 C19 C20 C21 104.4(7) . . . . ?
P2 C19 C20 C25 -75.7(8) . . . . ?
C25 C20 C21 C22 -1.8(11) . . . . ?
C19 C20 C21 C22 178.1(7) . . . . ?
C20 C21 C22 C23 1.3(12) . . . . ?
C21 C22 C23 C24 0.3(12) . . . . ?
C22 C23 C24 C25 -1.2(12) . . . . ?
C21 C20 C25 C24 0.9(11) . . . . ?
C19 C20 C25 C24 -179.0(7) . . . . ?
C23 C24 C25 C20 0.7(12) . . . . ?
O6 P3 C26 C27 72.9(6) . . . . ?
O3 P3 C26 C27 -159.4(5) . . . . ?
C11 P3 C26 C27 -47.3(6) . . . . ?
Eu1 P3 C26 C27 -123.6(5) . . . . ?
P3 C26 C27 C32 -68.2(8) . . . . ?
P3 C26 C27 C28 116.2(6) . . . . ?
C32 C27 C28 C29 -1.1(10) . . . . ?
C26 C27 C28 C29 174.7(6) . . . . ?
C27 C28 C29 C30 0.6(10) . . . . ?
C28 C29 C30 C31 0.7(11) . . . . ?
C29 C30 C31 C32 -1.5(10) . . . . ?
C30 C31 C32 C27 1.1(10) . . . . ?
C28 C27 C32 C31 0.2(10) . . . . ?
C26 C27 C32 C31 -175.4(6) . . . . ?
O4 P1 O1 Eu1 97.0(3) . . . . ?
C12 P1 O1 Eu1 -139.5(3) . . . . ?
C9 P1 O1 Eu1 -23.0(4) . . . . ?
O3 Eu1 O1 P1 -118.6(3) . . . . ?
O4 Eu1 O1 P1 -52.2(3) 7_566 . . . ?
O2 Eu1 O1 P1 171.4(3) . . . . ?
N4 Eu1 O1 P1 1.4(4) . . . . ?
N2 Eu1 O1 P1 102.5(3) . . . . ?
N3 Eu1 O1 P1 119.0(3) . . . . ?
N1 Eu1 O1 P1 34.6(3) . . . . ?
P3 Eu1 O1 P1 -145.3(2) . . . . ?
P2 Eu1 O1 P1 152.4(3) . . . . ?
O5 P2 O2 Eu1 -138.8(3) . . . . ?
C19 P2 O2 Eu1 94.4(3) . . . . ?
C10 P2 O2 Eu1 -16.1(4) . . . . ?
O3 Eu1 O2 P2 170.7(3) . . . . ?
O4 Eu1 O2 P2 -120.8(3) 7_566 . . . ?
O1 Eu1 O2 P2 -58.4(3) . . . . ?
N4 Eu1 O2 P2 105.4(4) . . . . ?
N2 Eu1 O2 P2 31.8(3) . . . . ?
N3 Eu1 O2 P2 100.5(3) . . . . ?
N1 Eu1 O2 P2 -5.6(4) . . . . ?
P3 Eu1 O2 P2 152.1(3) . . . . ?
P1 Eu1 O2 P2 -55.2(3) . . . . ?
O6 P3 O3 Eu1 -142.0(3) . . . . ?
C26 P3 O3 Eu1 94.1(4) . . . . ?
C11 P3 O3 Eu1 -17.6(4) . . . . ?
O4 Eu1 O3 P3 172.0(3) 7_566 . . . ?
O2 Eu1 O3 P3 -53.9(3) . . . . ?
O1 Eu1 O3 P3 -122.8(3) . . . . ?
N4 Eu1 O3 P3 99.8(3) . . . . ?
N2 Eu1 O3 P3 -1.2(4) . . . . ?
N3 Eu1 O3 P3 33.2(3) . . . . ?
N1 Eu1 O3 P3 119.8(4) . . . . ?
P1 Eu1 O3 P3 -149.7(2) . . . . ?
P2 Eu1 O3 P3 -50.5(3) . . . . ?
O1 P1 O4 Eu1 -131.3(8) . . . 7_566 ?
C12 P1 O4 Eu1 104.6(9) . . . 7_566 ?
C9 P1 O4 Eu1 -11.8(9) . . . 7_566 ?
Eu1 P1 O4 Eu1 -91.7(8) . . . 7_566 ?
