#------------------------------------------------------------------------------
#$Date: 2016-03-25 11:22:20 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179787 $
#$URL: svn://www.crystallography.net/cod/cif/7/00/83/7008355.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7008355
loop_
_publ_author_name
'Yucesan, Gundog'
'Golub, Vladimir'
'O'Connor, C J'
'Zubieta, Jon'
_publ_section_title
;
 Solid state coordination chemistry of the
 copper(ii)-terpyridine/oxovanadium organophosphonate system:
 hydrothermal syntheses, structural characterization and magnetic
 properties.
;
_journal_issue                   13
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              2241
_journal_page_last               2251
_journal_paper_doi               10.1039/b502073e
_journal_year                    2005
_chemical_formula_sum            'C33 H28 Cu N3 O13 P3 V2'
_chemical_formula_weight         932.91
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                98.9510(10)
_cell_angle_beta                 98.0030(10)
_cell_angle_gamma                105.1140(10)
_cell_formula_units_Z            2
_cell_length_a                   8.8819(5)
_cell_length_b                   11.3639(7)
_cell_length_c                   18.4757(11)
_cell_measurement_reflns_used    11381
_cell_measurement_temperature    89(2)
_cell_measurement_theta_max      31.51
_cell_measurement_theta_min      1.89
_cell_volume                     1746.49(18)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL and CrystalMaker 6.x'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      89(2)
_diffrn_detector_area_resol_mean '512 x 512'
_diffrn_measured_fraction_theta_full 0.978
_diffrn_measured_fraction_theta_max 0.978
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'Phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0249
_diffrn_reflns_av_sigmaI/netI    0.0384
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_limit_l_min       -27
_diffrn_reflns_number            22776
_diffrn_reflns_theta_full        31.51
_diffrn_reflns_theta_max         31.51
_diffrn_reflns_theta_min         1.89
_diffrn_standards_decay_%        0.001
_exptl_absorpt_coefficient_mu    1.338
_exptl_absorpt_correction_T_max  0.8245
_exptl_absorpt_correction_T_min  0.5542
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            green
_exptl_crystal_density_diffrn    1.774
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             942
_exptl_crystal_size_max          0.50
_exptl_crystal_size_mid          0.30
_exptl_crystal_size_min          0.15
_refine_diff_density_max         0.638
_refine_diff_density_min         -0.387
_refine_diff_density_rms         0.091
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.051
_refine_ls_hydrogen_treatment    refall
_refine_ls_matrix_type           full
_refine_ls_number_parameters     504
_refine_ls_number_reflns         11381
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.051
_refine_ls_R_factor_all          0.0364
_refine_ls_R_factor_gt           0.0309
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0393P)²+0.7546P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0792
_refine_ls_wR_factor_ref         0.0821
_reflns_number_gt                10017
_reflns_number_total             11381
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b502073e.txt
_cod_data_source_block           compound_1
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7008355
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
O10 O 0.85664(12) 0.81520(10) 0.19569(6) 0.01135(19) Uani 1 1 d . . .
Cu1 Cu 0.43799(2) 0.620592(16) 0.062798(10) 0.00834(4) Uani 1 1 d . . .
V1 V 0.36578(3) 0.79372(2) 0.222059(13) 0.00763(5) Uani 1 1 d . . .
V2 V 0.05764(3) 0.93297(2) 0.199441(13) 0.00785(5) Uani 1 1 d . . .
P1 P 0.70241(4) 0.73315(3) 0.20949(2) 0.00759(7) Uani 1 1 d . . .
P2 P 0.39668(4) 1.08355(3) 0.29799(2) 0.00898(7) Uani 1 1 d . . .
P3 P -0.12188(4) 1.12265(3) 0.27986(2) 0.00855(7) Uani 1 1 d . . .
O1 O 0.61318(12) 0.63753(10) 0.13951(6) 0.01026(19) Uani 1 1 d . . .
O2 O 0.60091(12) 0.81432(9) 0.23902(6) 0.00965(19) Uani 1 1 d . . .
O3 O 0.31674(13) 0.67394(11) 0.26016(7) 0.0158(2) Uani 1 1 d . . .
O4 O 0.33380(12) 0.74617(11) 0.13090(6) 0.0131(2) Uani 1 1 d . . .
O5 O 0.45031(12) 0.96885(10) 0.27365(6) 0.0122(2) Uani 1 1 d . . .
O6 O 0.16302(12) 0.83629(10) 0.22486(6) 0.01117(19) Uani 1 1 d . . .
O7 O 0.50954(13) 1.20064(10) 0.28232(6) 0.0126(2) Uani 1 1 d . . .
O8 O 0.22889(12) 1.07258(10) 0.25845(6) 0.0127(2) Uani 1 1 d . . .
O9 O 0.07196(13) 0.93530(10) 0.11448(6) 0.0138(2) Uani 1 1 d . . .
O11 O -0.06073(12) 1.05870(10) 0.21658(6) 0.01113(19) Uani 1 1 d . . .
O12 O -0.19637(14) 1.02707(11) 0.32725(6) 0.0126(2) Uani 1 1 d . . .
N1 N 0.30973(15) 0.45268(11) 0.07705(7) 0.0106(2) Uani 1 1 d . . .
N2 N 0.27697(14) 0.57204(11) -0.02689(7) 0.0095(2) Uani 1 1 d . . .
N3 N 0.52627(14) 0.75920(12) 0.00893(7) 0.0103(2) Uani 1 1 d . . .
C1 C 0.34024(18) 0.39744(14) 0.13418(8) 0.0130(3) Uani 1 1 d . . .
H1 H 0.4349 0.4353 0.1702 0.016 Uiso 1 1 calc R . .
C2 C 0.23829(19) 0.28682(14) 0.14249(9) 0.0150(3) Uani 1 1 d . . .
H2 H 0.2624 0.2495 0.1835 0.018 Uiso 1 1 calc R . .
C3 C 0.10013(19) 0.23197(14) 0.08934(9) 0.0153(3) Uani 1 1 d . . .
H3 H 0.0276 0.1569 0.0940 0.018 Uiso 1 1 calc R . .
C4 C 0.06875(18) 0.28768(14) 0.02929(9) 0.0134(3) Uani 1 1 d . . .
H4 H -0.0246 0.2510 -0.0077 0.016 Uiso 1 1 calc R . .
C5 C 0.17637(17) 0.39783(13) 0.02449(8) 0.0107(2) Uani 1 1 d . . .
C6 C 0.15991(17) 0.46580(13) -0.03680(8) 0.0101(2) Uani 1 1 d . . .
C7 C 0.04087(17) 0.42918(14) -0.10000(8) 0.0120(3) Uani 1 1 d . . .
H7 H -0.0438 0.3550 -0.1069 0.014 Uiso 1 1 calc R . .
C8 C 0.04914(17) 0.50432(14) -0.15300(8) 0.0126(3) Uani 1 1 d . . .
H8 H -0.0312 0.4813 -0.1966 0.015 Uiso 1 1 calc R . .
C9 C 0.17405(17) 0.61301(14) -0.14279(8) 0.0125(3) Uani 1 1 d . . .
H9 H 0.1815 0.6635 -0.1793 0.015 Uiso 1 1 calc R . .
C10 C 0.28755(17) 0.64529(13) -0.07740(8) 0.0102(2) Uani 1 1 d . . .
C11 C 0.42777(16) 0.75673(13) -0.05501(8) 0.0100(2) Uani 1 1 d . . .
C12 C 0.45825(17) 0.85124(14) -0.09508(8) 0.0122(3) Uani 1 1 d . . .
H12 H 0.3863 0.8489 -0.1388 0.015 Uiso 1 1 calc R . .
C13 C 0.59677(18) 0.94965(14) -0.06975(9) 0.0140(3) Uani 1 1 d . . .
H13 H 0.6210 1.0153 -0.0962 0.017 Uiso 1 1 calc R . .
C14 C 0.69832(18) 0.95063(14) -0.00577(9) 0.0143(3) Uani 1 1 d . . .
H14 H 0.7943 1.0162 0.0117 0.017 Uiso 1 1 calc R . .
C15 C 0.65880(17) 0.85465(14) 0.03299(8) 0.0125(3) Uani 1 1 d . . .
H15 H 0.7277 0.8569 0.0777 0.015 Uiso 1 1 calc R . .
C16 C 0.75401(17) 0.64997(13) 0.27934(8) 0.0103(2) Uani 1 1 d . . .
C17 C 0.63375(18) 0.56679(14) 0.30302(8) 0.0129(3) Uani 1 1 d . . .
H17 H 0.5260 0.5631 0.2870 0.015 Uiso 1 1 calc R . .
C18 C 0.6706(2) 0.48957(14) 0.34962(9) 0.0161(3) Uani 1 1 d . . .
H18 H 0.5882 0.4320 0.3645 0.019 Uiso 1 1 calc R . .
C19 C 0.8283(2) 0.49656(16) 0.37443(10) 0.0193(3) Uani 1 1 d . . .
H19 H 0.8537 0.4422 0.4052 0.023 Uiso 1 1 calc R . .
C20 C 0.9487(2) 0.58294(16) 0.35420(9) 0.0187(3) Uani 1 1 d . . .
H20 H 1.0565 0.5901 0.3730 0.022 Uiso 1 1 calc R . .
C21 C 0.91233(18) 0.65923(15) 0.30651(9) 0.0145(3) Uani 1 1 d . . .
H21 H 0.9952 0.7176 0.2924 0.017 Uiso 1 1 calc R . .
C22 C 0.40299(18) 1.10590(14) 0.39635(8) 0.0126(3) Uani 1 1 d . . .
C23 C 0.2909(2) 1.02549(16) 0.42564(10) 0.0197(3) Uani 1 1 d . . .
H23 H 0.2083 0.9606 0.3930 0.024 Uiso 1 1 calc R . .
C24 C 0.2993(2) 1.0397(2) 0.50230(11) 0.0274(4) Uani 1 1 d . . .
H24 H 0.2227 0.9845 0.5218 0.033 Uiso 1 1 calc R . .
C25 C 0.4190(3) 1.1339(2) 0.55013(10) 0.0288(4) Uani 1 1 d . . .
H25 H 0.4238 1.1441 0.6025 0.035 Uiso 1 1 calc R . .
C26 C 0.5319(2) 1.21342(18) 0.52198(10) 0.0255(4) Uani 1 1 d . . .
H26 H 0.6147 1.2774 0.5551 0.031 Uiso 1 1 calc R . .
C27 C 0.5249(2) 1.20022(15) 0.44544(9) 0.0179(3) Uani 1 1 d . . .
H27 H 0.6027 1.2552 0.4264 0.021 Uiso 1 1 calc R . .
C28 C 0.03717(17) 1.23331(14) 0.34608(8) 0.0113(3) Uani 1 1 d . . .
C29 C 0.07118(19) 1.22380(15) 0.42036(9) 0.0154(3) Uani 1 1 d . . .
H29 H 0.0124 1.1539 0.4370 0.019 Uiso 1 1 calc R . .
C30 C 0.1913(2) 1.31657(16) 0.47052(10) 0.0199(3) Uani 1 1 d . . .
H30 H 0.2140 1.3099 0.5213 0.024 Uiso 1 1 calc R . .
C31 C 0.27776(19) 1.41864(16) 0.44645(10) 0.0201(3) Uani 1 1 d . . .
H31 H 0.3589 1.4821 0.4808 0.024 Uiso 1 1 calc R . .
C32 C 0.24595(19) 1.42830(15) 0.37221(10) 0.0192(3) Uani 1 1 d . . .
H32 H 0.3062 1.4978 0.3557 0.023 Uiso 1 1 calc R . .
C33 C 0.12563(18) 1.33607(15) 0.32200(9) 0.0153(3) Uani 1 1 d . . .
H33 H 0.1035 1.3429 0.2713 0.018 Uiso 1 1 calc R . .
O14 O -0.23559(12) 1.18944(10) 0.25024(6) 0.0119(2) Uani 1 1 d . . .
H102 H 0.597(4) 1.200(3) 0.2746(16) 0.052(9) Uiso 1 1 d . . .
H103 H -0.257(3) 0.981(2) 0.3057(15) 0.034(7) Uiso 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
V V 0.3005 0.5294 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P1 O10 V2 168.35(7) . 1_655 ?
O1 Cu1 N2 166.39(5) . . ?
O1 Cu1 N1 95.28(5) . . ?
N2 Cu1 N1 79.86(5) . . ?
O1 Cu1 N3 102.27(5) . . ?
N2 Cu1 N3 80.32(5) . . ?
N1 Cu1 N3 158.73(5) . . ?
O1 Cu1 O4 94.85(4) . . ?
N2 Cu1 O4 98.53(5) . . ?
N1 Cu1 O4 100.56(5) . . ?
N3 Cu1 O4 89.93(5) . . ?
O3 V1 O4 108.86(6) . . ?
O3 V1 O5 126.82(6) . . ?
O4 V1 O5 124.32(5) . . ?
O3 V1 O6 95.07(5) . . ?
O4 V1 O6 96.03(5) . . ?
O5 V1 O6 80.49(4) . . ?
O3 V1 O2 96.79(5) . . ?
O4 V1 O2 95.99(5) . . ?
O5 V1 O2 78.91(4) . . ?
O6 V1 O2 159.39(4) . . ?
O9 V2 O6 104.79(6) . . ?
O9 V2 O10 105.40(5) . 1_455 ?
O6 V2 O10 93.63(5) . 1_455 ?
O9 V2 O8 105.80(5) . . ?
O6 V2 O8 88.78(5) . . ?
O10 V2 O8 146.94(5) 1_455 . ?
O9 V2 O11 99.41(5) . . ?
O6 V2 O11 155.38(5) . . ?
O10 V2 O11 84.13(4) 1_455 . ?
O8 V2 O11 80.29(4) . . ?
O1 P1 O10 110.92(6) . . ?
O1 P1 O2 112.13(6) . . ?
O10 P1 O2 110.02(6) . . ?
O1 P1 C16 107.47(6) . . ?
O10 P1 C16 107.30(6) . . ?
O2 P1 C16 108.83(6) . . ?
O5 P2 O8 112.97(6) . . ?
O5 P2 O7 110.84(6) . . ?
O8 P2 O7 107.59(6) . . ?
O5 P2 C22 108.49(7) . . ?
O8 P2 C22 109.13(7) . . ?
O7 P2 C22 107.68(7) . . ?
O14 P3 O11 110.62(6) . . ?
O14 P3 O12 112.71(6) . . ?
O11 P3 O12 110.55(6) . . ?
O14 P3 C28 108.37(7) . . ?
O11 P3 C28 111.25(6) . . ?
O12 P3 C28 103.11(7) . . ?
P1 O1 Cu1 136.06(7) . . ?
P1 O2 V1 133.27(6) . . ?
V1 O4 Cu1 129.77(6) . . ?
P2 O5 V1 141.28(7) . . ?
V2 O6 V1 144.39(6) . . ?
P2 O8 V2 132.71(7) . . ?
P3 O11 V2 138.78(7) . . ?
C1 N1 C5 119.17(13) . . ?
C1 N1 Cu1 126.36(10) . . ?
C5 N1 Cu1 114.36(10) . . ?
C6 N2 C10 122.33(13) . . ?
C6 N2 Cu1 118.92(10) . . ?
C10 N2 Cu1 118.74(10) . . ?
C15 N3 C11 118.85(13) . . ?
C15 N3 Cu1 127.37(10) . . ?
C11 N3 Cu1 113.47(9) . . ?
N1 C1 C2 122.31(14) . . ?
C1 C2 C3 118.44(15) . . ?
C2 C3 C4 119.61(14) . . ?
C5 C4 C3 118.73(14) . . ?
N1 C5 C4 121.72(14) . . ?
N1 C5 C6 113.71(12) . . ?
C4 C5 C6 124.57(13) . . ?
N2 C6 C7 120.42(14) . . ?
N2 C6 C5 112.82(12) . . ?
C7 C6 C5 126.76(13) . . ?
C6 C7 C8 118.16(13) . . ?
C7 C8 C9 120.73(14) . . ?
C10 C9 C8 118.00(14) . . ?
N2 C10 C9 120.33(13) . . ?
N2 C10 C11 112.81(12) . . ?
C9 C10 C11 126.86(13) . . ?
N3 C11 C12 122.09(13) . . ?
N3 C11 C10 114.18(13) . . ?
C12 C11 C10 123.73(13) . . ?
C11 C12 C13 118.53(14) . . ?
C14 C13 C12 119.29(14) . . ?
C13 C14 C15 119.37(14) . . ?
N3 C15 C14 121.84(14) . . ?
C21 C16 C17 119.10(14) . . ?
C21 C16 P1 121.17(11) . . ?
C17 C16 P1 119.55(11) . . ?
C18 C17 C16 120.57(14) . . ?
C17 C18 C19 119.88(15) . . ?
C20 C19 C18 119.97(15) . . ?
C19 C20 C21 120.34(15) . . ?
C20 C21 C16 120.03(15) . . ?
C23 C22 C27 118.97(15) . . ?
C23 C22 P2 120.34(12) . . ?
C27 C22 P2 120.61(12) . . ?
C24 C23 C22 120.43(17) . . ?
C25 C24 C23 120.07(18) . . ?
C24 C25 C26 120.15(17) . . ?
C25 C26 C27 120.36(18) . . ?
C26 C27 C22 120.00(17) . . ?
C29 C28 C33 119.46(14) . . ?
C29 C28 P3 122.70(12) . . ?
C33 C28 P3 117.78(12) . . ?
C28 C29 C30 120.20(16) . . ?
C31 C30 C29 120.07(16) . . ?
C30 C31 C32 120.18(15) . . ?
C31 C32 C33 119.92(16) . . ?
C32 C33 C28 120.17(15) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
O10 P1 1.5218(11) . ?
O10 V2 1.9168(10) 1_655 ?
Cu1 O1 1.9005(10) . ?
Cu1 N2 1.9339(12) . ?
Cu1 N1 2.0284(12) . ?
Cu1 N3 2.0365(13) . ?
Cu1 O4 2.2205(11) . ?
V1 O3 1.6163(11) . ?
V1 O4 1.6470(11) . ?
V1 O5 1.9658(11) . ?
V1 O6 1.9881(10) . ?
V1 O2 2.0135(10) . ?
V2 O9 1.5961(11) . ?
V2 O6 1.6965(11) . ?
V2 O10 1.9168(10) 1_455 ?
V2 O8 1.9392(11) . ?
V2 O11 1.9955(11) . ?
P1 O1 1.5194(11) . ?
P1 O2 1.5411(10) . ?
P1 C16 1.7917(15) . ?
P2 O5 1.5262(11) . ?
P2 O8 1.5303(11) . ?
P2 O7 1.5377(11) . ?
P2 C22 1.7862(16) . ?
P3 O14 1.5069(11) . ?
P3 O11 1.5194(11) . ?
P3 O12 1.5706(12) . ?
P3 C28 1.7854(15) . ?
N1 C1 1.3404(19) . ?
N1 C5 1.3568(19) . ?
N2 C6 1.3400(18) . ?
N2 C10 1.3408(19) . ?
N3 C15 1.3410(18) . ?
N3 C11 1.3604(19) . ?
C1 C2 1.389(2) . ?
C2 C3 1.391(2) . ?
C3 C4 1.391(2) . ?
C4 C5 1.387(2) . ?
C5 C6 1.478(2) . ?
C6 C7 1.389(2) . ?
C7 C8 1.393(2) . ?
C8 C9 1.395(2) . ?
C9 C10 1.393(2) . ?
C10 C11 1.482(2) . ?
C11 C12 1.388(2) . ?
C12 C13 1.394(2) . ?
C13 C14 1.380(2) . ?
C14 C15 1.393(2) . ?
C16 C21 1.396(2) . ?
C16 C17 1.399(2) . ?
C17 C18 1.387(2) . ?
C18 C19 1.390(2) . ?
C19 C20 1.387(2) . ?
C20 C21 1.392(2) . ?
C22 C23 1.396(2) . ?
C22 C27 1.401(2) . ?
C23 C24 1.389(3) . ?
C24 C25 1.381(3) . ?
C25 C26 1.382(3) . ?
C26 C27 1.389(2) . ?
C28 C29 1.391(2) . ?
C28 C33 1.400(2) . ?
C29 C30 1.394(2) . ?
C30 C31 1.387(3) . ?
C31 C32 1.389(3) . ?
C32 C33 1.392(2) . ?
