#------------------------------------------------------------------------------
#$Date: 2016-02-16 03:10:39 +0200 (Tue, 16 Feb 2016) $
#$Revision: 176453 $
#$URL: svn://www.crystallography.net/cod/cif/7/00/83/7008381.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7008381
loop_
_publ_author_name
'Novio, Fernando'
'Mas-Ballesté, Rubén'
'Gallardo, Iluminada'
'González-Duarte, Pilar'
'Lledós, Agustí'
'Vila, Neus'
_publ_section_title
;
 Influence of the terminal ligands on the redox properties of the
 {Pt2(mu-S)2} core in [Pt2(Ph2X(CH2)2XPh2)2(mu-S)2] (X = P or As)
 complexes and on their reactivity towards metal centres, protic acids
 and organic electrophiles.
;
_journal_issue                   16
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              2742
_journal_page_last               2753
_journal_paper_doi               10.1039/b502196k
_journal_year                    2005
_chemical_compound_source        'synthesis as described'
_chemical_formula_moiety         'C27 H26 As2 Pt S2, 0.5(C2 H3 N)'
_chemical_formula_sum            'C28 H27.5 As2 N0.5 Pt S2'
_chemical_formula_weight         780.06
_chemical_name_common
;
(1,2-bis(diphenylarsino)ethane)-(methanedithiolato)-platinum
acetonitrile solvate
;
_chemical_name_systematic
;
(1,2-bis(diphenylarsino)ethane)-(methanedithiolato)-platinum acetonitrile
solvate
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_conform_dict_location     ftp://ftp.iucr.org/pub/cif_core.dic
_audit_conform_dict_name         cif_core.dic
_audit_conform_dict_version      2.2
_audit_creation_date             2003-07-28T11:17:18-00:00
_audit_creation_method           'WinGX routine CIF_UPDATE'
_cell_angle_alpha                90
_cell_angle_beta                 100.732(2)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   9.2640(12)
_cell_length_b                   26.988(4)
_cell_length_c                   12.1334(16)
_cell_measurement_reflns_used    1958
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      26.43
_cell_measurement_theta_min      2.36
_cell_measurement_wavelength     0.7107
_cell_volume                     2980.5(7)
_computing_cell_refinement       "'BRUKER Smart"
_computing_data_collection       "'BRUKER Smart"
_computing_data_reduction        "'BRUKER SAINT"
_computing_molecular_graphics    'Ortep-3 for Windows (Farrugia, 1997)'
_computing_publication_material  'WinGX publication routines (Farrugia, 1999)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'DIRDIF99 (Beurskens et al., 1999)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'Smart-CCD-1000 BRUKER'
_diffrn_measurement_method       'omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_probe          x-ray
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0394
_diffrn_reflns_av_unetI/netI     0.0339
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       33
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       0
_diffrn_reflns_number            25326
_diffrn_reflns_theta_full        26.46
_diffrn_reflns_theta_max         26.46
_diffrn_reflns_theta_min         1.51
_exptl_absorpt_coefficient_mu    7.066
_exptl_absorpt_correction_T_max  0.529
_exptl_absorpt_correction_T_min  0.057
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS - Bruker Nonius'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.738
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             1500
_exptl_crystal_size_max          0.40
_exptl_crystal_size_mid          0.13
_exptl_crystal_size_min          0.09
_refine_diff_density_max         2.315
_refine_diff_density_min         -2.101
_refine_diff_density_rms         0.215
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.235
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     302
_refine_ls_number_reflns         6132
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.235
_refine_ls_R_factor_all          0.0641
_refine_ls_R_factor_gt           0.0473
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0499P)²+17.2882P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1249
_refine_ls_wR_factor_ref         0.1386
_reflns_number_gt                4994
_reflns_number_total             6132
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b502196k.txt
_cod_data_source_block           ub01fb1n
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_original_formula_sum        'C28 H27.5 As2 N0.5 Pt1 S2'
_cod_database_code               7008381
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.12628(4) 0.152317(12) 0.35585(3) 0.03968(12) Uani 1 1 d . . .
As2 As 0.11396(10) 0.23412(3) 0.42557(8) 0.0408(2) Uani 1 1 d . . .
As3 As 0.31170(10) 0.13976(3) 0.51610(8) 0.0442(2) Uani 1 1 d . . .
S4 S -0.0472(3) 0.15805(10) 0.1935(2) 0.0534(6) Uani 1 1 d . . .
S5 S 0.1381(4) 0.07410(11) 0.2847(3) 0.0779(9) Uani 1 1 d . . .
C6 C 0.3687(11) 0.2047(4) 0.5837(9) 0.052(2) Uani 1 1 d . . .
H6A H 0.4162 0.2006 0.6614 0.063 Uiso 1 1 calc R . .
H6B H 0.4373 0.2208 0.5439 0.063 Uiso 1 1 calc R . .
C7 C 0.2328(11) 0.2358(4) 0.5766(8) 0.051(2) Uani 1 1 d . . .
H7A H 0.2605 0.2697 0.5966 0.062 Uiso 1 1 calc R . .
H7B H 0.1750 0.2235 0.6298 0.062 Uiso 1 1 calc R . .
C8 C 0.2023(10) 0.2848(3) 0.3448(7) 0.043(2) Uani 1 1 d . . .
C9 C 0.2410(11) 0.2723(4) 0.2455(9) 0.057(2) Uani 1 1 d . . .
H9 H 0.2256 0.2402 0.2182 0.069 Uiso 1 1 calc R . .
C10 C 0.3027(13) 0.3071(5) 0.1851(10) 0.071(3) Uani 1 1 d . . .
H10 H 0.3272 0.2984 0.1167 0.085 Uiso 1 1 calc R . .
C11 C 0.3280(15) 0.3539(5) 0.2251(12) 0.079(4) Uani 1 1 d . . .
H11 H 0.3717 0.3770 0.1850 0.095 Uiso 1 1 calc R . .
C12 C 0.2895(16) 0.3668(5) 0.3236(12) 0.081(4) Uani 1 1 d . . .
H12 H 0.3064 0.3990 0.3499 0.097 Uiso 1 1 calc R . .
C13 C 0.2245(14) 0.3325(4) 0.3869(10) 0.069(3) Uani 1 1 d . . .
H13 H 0.1975 0.3415 0.4543 0.083 Uiso 1 1 calc R . .
C14 C -0.0706(10) 0.2640(4) 0.4448(8) 0.047(2) Uani 1 1 d . . .
C15 C -0.1975(11) 0.2489(5) 0.3759(9) 0.060(3) Uani 1 1 d . . .
H15 H -0.1944 0.2247 0.3220 0.072 Uiso 1 1 calc R . .
C16 C -0.3316(13) 0.2703(6) 0.3870(11) 0.079(4) Uani 1 1 d . . .
H16 H -0.4175 0.2606 0.3394 0.095 Uiso 1 1 calc R . .
C17 C -0.3369(15) 0.3051(6) 0.4670(13) 0.086(4) Uani 1 1 d . . .
H17 H -0.4266 0.3189 0.4743 0.103 Uiso 1 1 calc R . .
C18 C -0.2112(17) 0.3199(5) 0.5368(13) 0.085(4) Uani 1 1 d . . .
H18 H -0.2159 0.3434 0.5922 0.102 Uiso 1 1 calc R . .
C19 C -0.0760(13) 0.3000(4) 0.5254(10) 0.067(3) Uani 1 1 d . . .
H19 H 0.0099 0.3107 0.5715 0.081 Uiso 1 1 calc R . .
C20 C 0.4932(10) 0.1095(4) 0.4938(9) 0.054(2) Uani 1 1 d . . .
C21 C 0.5645(17) 0.1312(6) 0.4139(14) 0.098(5) Uani 1 1 d . . .
H21 H 0.5252 0.1589 0.3737 0.118 Uiso 1 1 calc R . .
C22 C 0.6966(18) 0.1101(7) 0.3958(17) 0.113(6) Uani 1 1 d . . .
H22 H 0.7503 0.1252 0.3476 0.136 Uiso 1 1 calc R . .
C23 C 0.7461(16) 0.0669(7) 0.4496(17) 0.108(6) Uani 1 1 d . . .
H23 H 0.8296 0.0516 0.4333 0.130 Uiso 1 1 calc R . .
C24 C 0.6743(16) 0.0461(6) 0.5266(15) 0.101(5) Uani 1 1 d . . .
H24 H 0.7122 0.0180 0.5660 0.121 Uiso 1 1 calc R . .
C25 C 0.5468(13) 0.0666(5) 0.5456(11) 0.075(3) Uani 1 1 d . . .
H25 H 0.4953 0.0512 0.5949 0.090 Uiso 1 1 calc R . .
C26 C 0.2534(11) 0.1022(3) 0.6356(9) 0.051(2) Uani 1 1 d . . .
C27 C 0.1420(12) 0.0687(4) 0.6107(10) 0.063(3) Uani 1 1 d . . .
H27 H 0.0954 0.0646 0.5365 0.076 Uiso 1 1 calc R . .
C28 C 0.0966(15) 0.0405(5) 0.6936(13) 0.080(4) Uani 1 1 d . . .
H28 H 0.0234 0.0168 0.6742 0.096 Uiso 1 1 calc R . .
C29 C 0.1572(19) 0.0474(5) 0.8006(14) 0.093(5) Uani 1 1 d . . .
H29 H 0.1237 0.0293 0.8561 0.112 Uiso 1 1 calc R . .
C30 C 0.269(2) 0.0808(6) 0.8296(11) 0.116(6) Uani 1 1 d . . .
H30 H 0.3097 0.0855 0.9048 0.139 Uiso 1 1 calc R . .
C31 C 0.3220(18) 0.1084(5) 0.7465(11) 0.087(4) Uani 1 1 d . . .
H31 H 0.4008 0.1300 0.7657 0.105 Uiso 1 1 calc R . .
C32 C -0.019(2) 0.0915(6) 0.1580(13) 0.120(6) Uani 1 1 d . . .
H32A H 0.0124 0.0882 0.0866 0.144 Uiso 1 1 calc R . .
H32B H -0.1071 0.0719 0.1575 0.144 Uiso 1 1 calc R . .
N40 N 0.472(3) 0.0215(10) 0.186(2) 0.105(8) Uiso 0.50 1 d P . .
C41 C 0.521(4) 0.0461(13) 0.124(3) 0.106(10) Uiso 0.50 1 d P . .
C42 C 0.588(4) 0.0630(14) 0.063(3) 0.123(12) Uiso 0.50 1 d P . .
H42A H 0.6366 0.0371 0.0299 0.184 Uiso 0.50 1 calc PR . .
H42B H 0.6591 0.0856 0.1022 0.184 Uiso 0.50 1 calc PR . .
H42C H 0.5226 0.0805 0.0048 0.184 Uiso 0.50 1 calc PR . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0 0 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
As As 0.0499 2.0058 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
S5 Pt1 S4 79.31(11) . . ?
S5 Pt1 As3 95.69(10) . . ?
S4 Pt1 As3 174.87(7) . . ?
S5 Pt1 As2 178.74(10) . . ?
S4 Pt1 As2 99.78(7) . . ?
As3 Pt1 As2 85.19(3) . . ?
C14 As2 C8 103.4(4) . . ?
C14 As2 C7 103.4(4) . . ?
C8 As2 C7 103.9(4) . . ?
C14 As2 Pt1 122.0(3) . . ?
C8 As2 Pt1 114.9(3) . . ?
C7 As2 Pt1 107.4(3) . . ?
C26 As3 C20 104.8(4) . . ?
C26 As3 C6 104.3(4) . . ?
C20 As3 C6 105.2(4) . . ?
C26 As3 Pt1 115.5(3) . . ?
C20 As3 Pt1 117.6(3) . . ?
C6 As3 Pt1 108.2(3) . . ?
C32 S4 Pt1 91.6(5) . . ?
C32 S5 Pt1 89.6(5) . . ?
C7 C6 As3 108.4(6) . . ?
C7 C6 H6A 110.0 . . ?
As3 C6 H6A 110.0 . . ?
C7 C6 H6B 110.0 . . ?
As3 C6 H6B 110.0 . . ?
H6A C6 H6B 108.4 . . ?
C6 C7 As2 111.1(7) . . ?
C6 C7 H7A 109.4 . . ?
As2 C7 H7A 109.4 . . ?
C6 C7 H7B 109.4 . . ?
As2 C7 H7B 109.4 . . ?
H7A C7 H7B 108.0 . . ?
C9 C8 C13 120.7(9) . . ?
C9 C8 As2 118.5(7) . . ?
C13 C8 As2 120.9(7) . . ?
C8 C9 C10 120.4(11) . . ?
C8 C9 H9 119.8 . . ?
C10 C9 H9 119.8 . . ?
C11 C10 C9 120.3(11) . . ?
C11 C10 H10 119.9 . . ?
C9 C10 H10 119.9 . . ?
C12 C11 C10 119.9(11) . . ?
C12 C11 H11 120.1 . . ?
C10 C11 H11 120.1 . . ?
C11 C12 C13 121.5(12) . . ?
C11 C12 H12 119.2 . . ?
C13 C12 H12 119.2 . . ?
C8 C13 C12 117.2(11) . . ?
C8 C13 H13 121.4 . . ?
C12 C13 H13 121.4 . . ?
C15 C14 C19 119.8(9) . . ?
C15 C14 As2 118.6(7) . . ?
C19 C14 As2 121.6(8) . . ?
C14 C15 C16 119.7(11) . . ?
C14 C15 H15 120.1 . . ?
C16 C15 H15 120.1 . . ?
C17 C16 C15 120.3(13) . . ?
C17 C16 H16 119.8 . . ?
C15 C16 H16 119.8 . . ?
C16 C17 C18 120.4(11) . . ?
C16 C17 H17 119.8 . . ?
C18 C17 H17 119.8 . . ?
C17 C18 C19 120.2(13) . . ?
C17 C18 H18 119.9 . . ?
C19 C18 H18 119.9 . . ?
C14 C19 C18 119.5(12) . . ?
C14 C19 H19 120.3 . . ?
C18 C19 H19 120.3 . . ?
C25 C20 C21 119.7(11) . . ?
C25 C20 As3 123.0(8) . . ?
C21 C20 As3 117.0(9) . . ?
C20 C21 C22 118.4(15) . . ?
C20 C21 H21 120.8 . . ?
C22 C21 H21 120.8 . . ?
C23 C22 C21 119.6(16) . . ?
C23 C22 H22 120.2 . . ?
C21 C22 H22 120.2 . . ?
C24 C23 C22 120.8(14) . . ?
C24 C23 H23 119.6 . . ?
C22 C23 H23 119.6 . . ?
C25 C24 C23 119.8(15) . . ?
C25 C24 H24 120.1 . . ?
C23 C24 H24 120.1 . . ?
C24 C25 C20 121.3(14) . . ?
C24 C25 H25 119.4 . . ?
C20 C25 H25 119.4 . . ?
C27 C26 C31 119.1(11) . . ?
C27 C26 As3 119.3(8) . . ?
C31 C26 As3 121.6(9) . . ?
C26 C27 C28 121.5(12) . . ?
C26 C27 H27 119.3 . . ?
C28 C27 H27 119.3 . . ?
C29 C28 C27 120.2(13) . . ?
C29 C28 H28 119.9 . . ?
C27 C28 H28 119.9 . . ?
C28 C29 C30 120.3(13) . . ?
C28 C29 H29 119.8 . . ?
C30 C29 H29 119.8 . . ?
C29 C30 C31 120.8(14) . . ?
C29 C30 H30 119.6 . . ?
C31 C30 H30 119.6 . . ?
C26 C31 C30 118.0(14) . . ?
C26 C31 H31 121.0 . . ?
C30 C31 H31 121.0 . . ?
S4 C32 S5 99.4(7) . . ?
S4 C32 H32A 111.9 . . ?
S5 C32 H32A 111.9 . . ?
S4 C32 H32B 111.9 . . ?
S5 C32 H32B 111.9 . . ?
H32A C32 H32B 109.6 . . ?
C42 C41 N40 167(5) . . ?
C41 C42 H42A 109.5 . . ?
C41 C42 H42B 109.5 . . ?
H42A C42 H42B 109.5 . . ?
C41 C42 H42C 109.5 . . ?
H42A C42 H42C 109.5 . . ?
H42B C42 H42C 109.5 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 S5 2.291(3) . ?
Pt1 S4 2.304(2) . ?
Pt1 As3 2.3668(10) . ?
Pt1 As2 2.3746(10) . ?
As2 C14 1.943(9) . ?
As2 C8 1.949(8) . ?
As2 C7 1.955(9) . ?
As3 C26 1.927(10) . ?
As3 C20 1.933(10) . ?
As3 C6 1.966(10) . ?
S4 C32 1.875(17) . ?
S5 C32 1.969(17) . ?
C6 C7 1.502(13) . ?
C6 H6A 0.9700 . ?
C6 H6B 0.9700 . ?
C7 H7A 0.9700 . ?
C7 H7B 0.9700 . ?
C8 C9 1.362(13) . ?
C8 C13 1.388(14) . ?
C9 C10 1.378(14) . ?
C9 H9 0.9300 . ?
C10 C11 1.358(17) . ?
C10 H10 0.9300 . ?
C11 C12 1.355(18) . ?
C11 H11 0.9300 . ?
C12 C13 1.407(16) . ?
C12 H12 0.9300 . ?
C13 H13 0.9300 . ?
C14 C15 1.371(14) . ?
C14 C19 1.387(14) . ?
C15 C16 1.399(14) . ?
C15 H15 0.9300 . ?
C16 C17 1.358(19) . ?
C16 H16 0.9300 . ?
C17 C18 1.37(2) . ?
C17 H17 0.9300 . ?
C18 C19 1.393(16) . ?
C18 H18 0.9300 . ?
C19 H19 0.9300 . ?
C20 C25 1.364(15) . ?
C20 C21 1.400(17) . ?
C21 C22 1.40(2) . ?
C21 H21 0.9300 . ?
C22 C23 1.37(2) . ?
C22 H22 0.9300 . ?
C23 C24 1.37(2) . ?
C23 H23 0.9300 . ?
C24 C25 1.362(17) . ?
C24 H24 0.9300 . ?
C25 H25 0.9300 . ?
C26 C27 1.364(14) . ?
C26 C31 1.388(16) . ?
C27 C28 1.386(16) . ?
C27 H27 0.9300 . ?
C28 C29 1.33(2) . ?
C28 H28 0.9300 . ?
C29 C30 1.37(2) . ?
C29 H29 0.9300 . ?
C30 C31 1.41(2) . ?
C30 H30 0.9300 . ?
C31 H31 0.9300 . ?
C32 H32A 0.9700 . ?
C32 H32B 0.9700 . ?
N40 C41 1.15(4) . ?
C41 C42 1.15(4) . ?
C42 H42A 0.9600 . ?
C42 H42B 0.9600 . ?
C42 H42C 0.9600 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
S4 Pt1 As2 C14 52.8(3) . . . . ?
As3 Pt1 As2 C14 -128.4(3) . . . . ?
S4 Pt1 As2 C8 -73.3(3) . . . . ?
As3 Pt1 As2 C8 105.4(3) . . . . ?
S4 Pt1 As2 C7 171.7(3) . . . . ?
As3 Pt1 As2 C7 -9.6(3) . . . . ?
S5 Pt1 As3 C26 -76.8(3) . . . . ?
As2 Pt1 As3 C26 104.1(3) . . . . ?
S5 Pt1 As3 C20 47.8(4) . . . . ?
As2 Pt1 As3 C20 -131.3(3) . . . . ?
S5 Pt1 As3 C6 166.7(3) . . . . ?
As2 Pt1 As3 C6 -12.4(3) . . . . ?
S5 Pt1 S4 C32 1.8(6) . . . . ?
As2 Pt1 S4 C32 -179.1(6) . . . . ?
S4 Pt1 S5 C32 -1.7(6) . . . . ?
As3 Pt1 S5 C32 179.5(6) . . . . ?
C26 As3 C6 C7 -84.3(7) . . . . ?
C20 As3 C6 C7 165.7(7) . . . . ?
Pt1 As3 C6 C7 39.2(7) . . . . ?
As3 C6 C7 As2 -48.5(8) . . . . ?
C14 As2 C7 C6 168.2(7) . . . . ?
C8 As2 C7 C6 -84.1(7) . . . . ?
Pt1 As2 C7 C6 38.0(7) . . . . ?
C14 As2 C8 C9 -124.2(8) . . . . ?
C7 As2 C8 C9 128.1(8) . . . . ?
Pt1 As2 C8 C9 11.1(8) . . . . ?
C14 As2 C8 C13 55.4(9) . . . . ?
C7 As2 C8 C13 -52.4(9) . . . . ?
Pt1 As2 C8 C13 -169.4(8) . . . . ?
C13 C8 C9 C10 -0.1(16) . . . . ?
As2 C8 C9 C10 179.5(8) . . . . ?
C8 C9 C10 C11 1.2(18) . . . . ?
C9 C10 C11 C12 -1(2) . . . . ?
C10 C11 C12 C13 1(2) . . . . ?
C9 C8 C13 C12 -0.7(17) . . . . ?
As2 C8 C13 C12 179.8(9) . . . . ?
C11 C12 C13 C8 0(2) . . . . ?
C8 As2 C14 C15 102.4(8) . . . . ?
C7 As2 C14 C15 -149.6(8) . . . . ?
Pt1 As2 C14 C15 -28.8(9) . . . . ?
C8 As2 C14 C19 -77.2(9) . . . . ?
C7 As2 C14 C19 30.9(9) . . . . ?
Pt1 As2 C14 C19 151.7(7) . . . . ?
C19 C14 C15 C16 0.4(16) . . . . ?
As2 C14 C15 C16 -179.2(9) . . . . ?
C14 C15 C16 C17 -1.2(18) . . . . ?
C15 C16 C17 C18 1(2) . . . . ?
C16 C17 C18 C19 1(2) . . . . ?
C15 C14 C19 C18 1.2(16) . . . . ?
As2 C14 C19 C18 -179.3(9) . . . . ?
C17 C18 C19 C14 -1.9(19) . . . . ?
C26 As3 C20 C25 7.9(11) . . . . ?
C6 As3 C20 C25 117.5(10) . . . . ?
Pt1 As3 C20 C25 -122.0(9) . . . . ?
C26 As3 C20 C21 -177.2(10) . . . . ?
C6 As3 C20 C21 -67.6(11) . . . . ?
Pt1 As3 C20 C21 52.9(11) . . . . ?
C25 C20 C21 C22 -5(2) . . . . ?
As3 C20 C21 C22 180.0(12) . . . . ?
C20 C21 C22 C23 5(2) . . . . ?
C21 C22 C23 C24 -5(3) . . . . ?
C22 C23 C24 C25 4(3) . . . . ?
C23 C24 C25 C20 -4(2) . . . . ?
C21 C20 C25 C24 4(2) . . . . ?
As3 C20 C25 C24 179.1(11) . . . . ?
C20 As3 C26 C27 -104.1(9) . . . . ?
C6 As3 C26 C27 145.6(8) . . . . ?
Pt1 As3 C26 C27 26.9(9) . . . . ?
C20 As3 C26 C31 75.9(10) . . . . ?
C6 As3 C26 C31 -34.4(10) . . . . ?
Pt1 As3 C26 C31 -153.0(9) . . . . ?
C31 C26 C27 C28 -0.4(17) . . . . ?
As3 C26 C27 C28 179.6(9) . . . . ?
C26 C27 C28 C29 3.0(19) . . . . ?
C27 C28 C29 C30 -2(2) . . . . ?
C28 C29 C30 C31 -1(3) . . . . ?
C27 C26 C31 C30 -2.5(19) . . . . ?
As3 C26 C31 C30 177.5(11) . . . . ?
C29 C30 C31 C26 3(2) . . . . ?
Pt1 S4 C32 S5 -2.1(7) . . . . ?
Pt1 S5 C32 S4 2.1(7) . . . . ?
