#------------------------------------------------------------------------------
#$Date: 2016-03-25 11:22:20 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179787 $
#$URL: svn://www.crystallography.net/cod/cif/7/00/83/7008383.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7008383
loop_
_publ_author_name
'Novio, Fernando'
'Mas-Ballesté, Rubén'
'Gallardo, Iluminada'
'González-Duarte, Pilar'
'Lledós, Agustí'
'Vila, Neus'
_publ_section_title
;
 Influence of the terminal ligands on the redox properties of the
 {Pt2(mu-S)2} core in [Pt2(Ph2X(CH2)2XPh2)2(mu-S)2] (X = P or As)
 complexes and on their reactivity towards metal centres, protic acids
 and organic electrophiles.
;
_journal_issue                   16
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              2742
_journal_page_last               2753
_journal_paper_doi               10.1039/b502196k
_journal_year                    2005
_chemical_compound_source        'synthesis as described'
_chemical_formula_moiety
'C78 H72 As6 Pt3 S2, 2(C24 H20 B), 2(C2 H6 O S)'
_chemical_formula_sum            'C130 H124 As6 B2 O2 Pt3 S4'
_chemical_formula_weight         2902.96
_chemical_name_systematic
;
bis(μ₃-Sulfido)-tris((1,2-bis(diphenylarsino)ethane)-platinum)
bis(tetraphenylborate) dimethylsulfoxide solvate
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_date             2005-02-08T17:31:40-00:00
_audit_creation_method           'WinGX routine CIF_UPDATE'
_cell_angle_alpha                91.679(4)
_cell_angle_beta                 99.603(4)
_cell_angle_gamma                116.255(3)
_cell_formula_units_Z            2
_cell_length_a                   14.306(3)
_cell_length_b                   15.391(3)
_cell_length_c                   29.884(6)
_cell_measurement_reflns_used    1002
_cell_measurement_temperature    120.0(1)
_cell_measurement_theta_max      28.39
_cell_measurement_theta_min      2.61
_cell_measurement_wavelength     0.71073
_cell_volume                     5779(2)
_computing_cell_refinement       "'BRUKER Smart"
_computing_data_collection       "'BRUKER Smart"
_computing_data_reduction        "'BRUKER Saint"
_computing_molecular_graphics    'Ortep-3 for Windows (Farrugia, 1997)'
_computing_publication_material  'WinGX publication routines (Farrugia, 1999)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'DIRDIF96 (bEURSKENS et all, 1996)'
_diffrn_ambient_temperature      120.0(1)
_diffrn_measured_fraction_theta_full 0.956
_diffrn_measured_fraction_theta_max 0.956
_diffrn_measurement_device_type  'Smart-CCD-1000 BRUKER'
_diffrn_measurement_method       'omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0346
_diffrn_reflns_av_unetI/netI     0.0416
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_k_min       -20
_diffrn_reflns_limit_l_max       39
_diffrn_reflns_limit_l_min       0
_diffrn_reflns_number            72691
_diffrn_reflns_theta_full        28.28
_diffrn_reflns_theta_max         28.28
_diffrn_reflns_theta_min         1.49
_exptl_absorpt_coefficient_mu    5.451
_exptl_absorpt_correction_T_max  0.148
_exptl_absorpt_correction_T_min  0.076
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'BRUKER SADABS'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.668
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             2852
_exptl_crystal_size_max          0.59
_exptl_crystal_size_mid          0.46
_exptl_crystal_size_min          0.35
_refine_diff_density_max         1.83
_refine_diff_density_min         -2.146
_refine_diff_density_rms         0.139
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.04
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1328
_refine_ls_number_reflns         27405
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.04
_refine_ls_R_factor_all          0.0502
_refine_ls_R_factor_gt           0.032
_refine_ls_shift/su_max          0.006
_refine_ls_shift/su_mean         0
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0228P)²+18.6061P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0665
_refine_ls_wR_factor_ref         0.0729
_reflns_number_gt                21917
_reflns_number_total             27405
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b502196k.txt
_cod_data_source_block           ub05fb1n
_cod_database_code               7008383
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.530688(13) 0.229414(12) 0.299067(5) 0.01597(4) Uani 1 1 d . . .
As2 As 0.47564(4) 0.21797(3) 0.369453(14) 0.01855(9) Uani 1 1 d . . .
C3 C 0.5585(4) 0.1711(4) 0.41112(15) 0.0238(10) Uani 1 1 d . . .
H3A H 0.6292 0.2234 0.423 0.029 Uiso 1 1 calc R . .
H3B H 0.5241 0.1466 0.4366 0.029 Uiso 1 1 calc R . .
C4 C 0.5650(4) 0.0896(4) 0.38365(15) 0.0247(10) Uani 1 1 d . . .
H4A H 0.4951 0.0342 0.3749 0.03 Uiso 1 1 calc R . .
H4B H 0.6121 0.0684 0.4019 0.03 Uiso 1 1 calc R . .
As5 As 0.61951(4) 0.13989(3) 0.329284(14) 0.01870(9) Uani 1 1 d . . .
C6 C 0.6118(4) 0.0314(3) 0.29251(15) 0.0238(10) Uani 1 1 d . . .
C7 C 0.6390(5) 0.0449(4) 0.25046(18) 0.0392(13) Uani 1 1 d . . .
H7 H 0.6677 0.1071 0.2414 0.047 Uiso 1 1 calc R . .
C8 C 0.6239(6) -0.0344(5) 0.2213(2) 0.0529(18) Uani 1 1 d . . .
H8 H 0.642 -0.0248 0.1928 0.063 Uiso 1 1 calc R . .
C9 C 0.5831(5) -0.1256(5) 0.2343(2) 0.0492(16) Uani 1 1 d . . .
H9 H 0.5749 -0.1778 0.2147 0.059 Uiso 1 1 calc R . .
C10 C 0.5539(5) -0.1415(4) 0.2756(2) 0.0490(16) Uani 1 1 d . . .
H10 H 0.5244 -0.2043 0.284 0.059 Uiso 1 1 calc R . .
C11 C 0.5687(4) -0.0619(4) 0.3055(2) 0.0386(13) Uani 1 1 d . . .
H11 H 0.5496 -0.072 0.3338 0.046 Uiso 1 1 calc R . .
C12 C 0.7667(4) 0.2296(4) 0.35529(16) 0.0258(10) Uani 1 1 d . . .
C13 C 0.8071(4) 0.3219(4) 0.34225(18) 0.0335(12) Uani 1 1 d . . .
H13 H 0.7678 0.3369 0.3185 0.04 Uiso 1 1 calc R . .
C14 C 0.9068(4) 0.3929(4) 0.3646(2) 0.0411(13) Uani 1 1 d . . .
H14 H 0.9342 0.4554 0.3556 0.049 Uiso 1 1 calc R . .
C15 C 0.9650(4) 0.3711(4) 0.39978(18) 0.0356(12) Uani 1 1 d . . .
H15 H 1.0316 0.4187 0.4147 0.043 Uiso 1 1 calc R . .
C16 C 0.9246(4) 0.2786(4) 0.41288(17) 0.0342(12) Uani 1 1 d . . .
H16 H 0.9641 0.2639 0.4367 0.041 Uiso 1 1 calc R . .
C17 C 0.8252(4) 0.2072(4) 0.39075(17) 0.0313(11) Uani 1 1 d . . .
H17 H 0.798 0.1447 0.3996 0.038 Uiso 1 1 calc R . .
C18 C 0.3313(4) 0.1190(3) 0.36353(15) 0.0224(9) Uani 1 1 d . . .
C19 C 0.2600(4) 0.1019(3) 0.32271(16) 0.0260(10) Uani 1 1 d . . .
H19 H 0.2818 0.1401 0.2994 0.031 Uiso 1 1 calc R . .
C20 C 0.1572(4) 0.0289(4) 0.31644(17) 0.0333(12) Uani 1 1 d . . .
H20 H 0.1094 0.0188 0.2893 0.04 Uiso 1 1 calc R . .
C21 C 0.1252(4) -0.0295(4) 0.35085(18) 0.0355(12) Uani 1 1 d . . .
H21 H 0.0563 -0.0798 0.3465 0.043 Uiso 1 1 calc R . .
C22 C 0.1955(4) -0.0132(4) 0.39159(17) 0.0341(12) Uani 1 1 d . . .
H22 H 0.174 -0.0524 0.4147 0.041 Uiso 1 1 calc R . .
C23 C 0.2970(4) 0.0609(4) 0.39790(16) 0.0285(11) Uani 1 1 d . . .
H23 H 0.3437 0.0725 0.4256 0.034 Uiso 1 1 calc R . .
C24 C 0.4810(4) 0.3357(3) 0.39579(15) 0.0221(9) Uani 1 1 d . . .
C25 C 0.3891(4) 0.3474(4) 0.38536(17) 0.0320(11) Uani 1 1 d . . .
H25 H 0.3265 0.2967 0.3689 0.038 Uiso 1 1 calc R . .
C26 C 0.3910(4) 0.4350(4) 0.39953(19) 0.0365(12) Uani 1 1 d . . .
H26 H 0.3296 0.4431 0.3927 0.044 Uiso 1 1 calc R . .
C27 C 0.4844(5) 0.5101(4) 0.42376(18) 0.0391(13) Uani 1 1 d . . .
H27 H 0.4853 0.568 0.4342 0.047 Uiso 1 1 calc R . .
C28 C 0.5748(5) 0.4995(4) 0.4324(2) 0.0466(15) Uani 1 1 d . . .
H28 H 0.6377 0.5514 0.4479 0.056 Uiso 1 1 calc R . .
C29 C 0.5751(4) 0.4122(4) 0.41851(19) 0.0374(13) Uani 1 1 d . . .
H29 H 0.6374 0.4056 0.4244 0.045 Uiso 1 1 calc R . .
Pt30 Pt 0.389249(12) 0.215187(12) 0.207938(5) 0.01528(4) Uani 1 1 d . . .
As31 As 0.22233(3) 0.21375(3) 0.189224(15) 0.01694(9) Uani 1 1 d . . .
C32 C 0.1255(3) 0.0940(3) 0.14968(16) 0.0242(10) Uani 1 1 d . . .
H32A H 0.1 0.0401 0.1679 0.029 Uiso 1 1 calc R . .
H32B H 0.0647 0.1004 0.1335 0.029 Uiso 1 1 calc R . .
C33 C 0.1841(4) 0.0738(3) 0.11555(16) 0.0246(10) Uani 1 1 d . . .
H33A H 0.1937 0.1187 0.0926 0.03 Uiso 1 1 calc R . .
H33B H 0.1419 0.0079 0.1002 0.03 Uiso 1 1 calc R . .
As34 As 0.32304(3) 0.08916(3) 0.146933(15) 0.01825(9) Uani 1 1 d . . .
C35 C 0.3998(4) 0.0943(3) 0.09904(16) 0.0227(9) Uani 1 1 d . . .
C36 C 0.3534(4) 0.0827(4) 0.05295(17) 0.0316(11) Uani 1 1 d . . .
H36 H 0.2832 0.0717 0.0445 0.038 Uiso 1 1 calc R . .
C37 C 0.4119(5) 0.0875(4) 0.01994(17) 0.0362(12) Uani 1 1 d . . .
H37 H 0.3806 0.079 -0.0108 0.043 Uiso 1 1 calc R . .
C38 C 0.5162(5) 0.1047(4) 0.03225(18) 0.0371(13) Uani 1 1 d . . .
H38 H 0.5553 0.1086 0.0098 0.045 Uiso 1 1 calc R . .
C39 C 0.5633(4) 0.1162(4) 0.07788(18) 0.0321(11) Uani 1 1 d . . .
H39 H 0.6336 0.1274 0.0861 0.038 Uiso 1 1 calc R . .
C40 C 0.5048(4) 0.1109(3) 0.11126(17) 0.0261(10) Uani 1 1 d . . .
H40 H 0.5361 0.1185 0.1419 0.031 Uiso 1 1 calc R . .
C41 C 0.2940(4) -0.0368(3) 0.16713(18) 0.0276(11) Uani 1 1 d . . .
C42 C 0.2483(5) -0.1191(4) 0.1350(2) 0.0429(14) Uani 1 1 d . . .
H42 H 0.233 -0.1136 0.1041 0.051 Uiso 1 1 calc R . .
C43 C 0.2260(5) -0.2093(4) 0.1498(3) 0.0541(18) Uani 1 1 d . . .
H43 H 0.1937 -0.2648 0.1286 0.065 Uiso 1 1 calc R . .
C44 C 0.2502(6) -0.2181(5) 0.1943(4) 0.074(3) Uani 1 1 d . . .
H44 H 0.2351 -0.2794 0.2034 0.089 Uiso 1 1 calc R . .
C45 C 0.2974(6) -0.1367(5) 0.2268(3) 0.072(2) Uani 1 1 d . . .
H45 H 0.3146 -0.1429 0.2575 0.086 Uiso 1 1 calc R . .
C46 C 0.3189(5) -0.0449(4) 0.2124(2) 0.0445(14) Uani 1 1 d . . .
H46 H 0.35 0.0104 0.2337 0.053 Uiso 1 1 calc R . .
C47 C 0.2351(4) 0.3176(3) 0.15188(15) 0.0215(9) Uani 1 1 d . . .
C48 C 0.3271(4) 0.3658(3) 0.13484(15) 0.0232(10) Uani 1 1 d . . .
H48 H 0.3824 0.3491 0.1421 0.028 Uiso 1 1 calc R . .
C49 C 0.3369(4) 0.4390(4) 0.10696(16) 0.0301(11) Uani 1 1 d . . .
H49 H 0.3984 0.4713 0.0955 0.036 Uiso 1 1 calc R . .
C50 C 0.2544(5) 0.4629(4) 0.09662(17) 0.0369(13) Uani 1 1 d . . .
H50 H 0.2608 0.5122 0.0782 0.044 Uiso 1 1 calc R . .
C51 C 0.1621(5) 0.4149(4) 0.11321(18) 0.0368(13) Uani 1 1 d . . .
H51 H 0.107 0.4319 0.1058 0.044 Uiso 1 1 calc R . .
C52 C 0.1511(4) 0.3412(4) 0.14095(16) 0.0283(11) Uani 1 1 d . . .
H52 H 0.089 0.3083 0.152 0.034 Uiso 1 1 calc R . .
C53 C 0.1481(3) 0.2274(3) 0.23519(15) 0.0206(9) Uani 1 1 d . . .
C54 C 0.1916(4) 0.3129(4) 0.26431(16) 0.0278(10) Uani 1 1 d . . .
H54 H 0.2555 0.3643 0.2611 0.033 Uiso 1 1 calc R . .
C55 C 0.1403(4) 0.3224(4) 0.29830(17) 0.0338(12) Uani 1 1 d . . .
H55 H 0.1698 0.3802 0.3178 0.041 Uiso 1 1 calc R . .
C56 C 0.0456(5) 0.2461(4) 0.30311(18) 0.0374(13) Uani 1 1 d . . .
H56 H 0.0118 0.252 0.3262 0.045 Uiso 1 1 calc R . .
C57 C 0.0012(4) 0.1615(4) 0.27374(19) 0.0379(13) Uani 1 1 d . . .
H57 H -0.0633 0.1106 0.2767 0.045 Uiso 1 1 calc R . .
C58 C 0.0520(4) 0.1511(4) 0.23959(18) 0.0304(11) Uani 1 1 d . . .
H58 H 0.0219 0.0935 0.2199 0.036 Uiso 1 1 calc R . .
Pt59 Pt 0.594314(12) 0.405399(12) 0.239016(5) 0.01541(4) Uani 1 1 d . . .
As60 As 0.61407(3) 0.56113(3) 0.262270(15) 0.01933(9) Uani 1 1 d . . .
C61 C 0.6815(4) 0.6470(3) 0.21856(16) 0.0228(9) Uani 1 1 d . . .
H61A H 0.6306 0.634 0.1903 0.027 Uiso 1 1 calc R . .
H61B H 0.7081 0.7146 0.2307 0.027 Uiso 1 1 calc R . .
C62 C 0.7727(4) 0.6280(3) 0.20982(16) 0.0239(10) Uani 1 1 d . . .
H62A H 0.8289 0.6514 0.2369 0.029 Uiso 1 1 calc R . .
H62B H 0.8016 0.6629 0.1849 0.029 Uiso 1 1 calc R . .
As63 As 0.72134(3) 0.48823(3) 0.194196(15) 0.01826(9) Uani 1 1 d . . .
C64 C 0.6600(3) 0.4662(3) 0.12951(15) 0.0204(9) Uani 1 1 d . . .
C65 C 0.5865(4) 0.3713(4) 0.11054(16) 0.0283(11) Uani 1 1 d . . .
H65 H 0.5683 0.321 0.129 0.034 Uiso 1 1 calc R . .
C66 C 0.5407(4) 0.3518(4) 0.06455(18) 0.0356(12) Uani 1 1 d . . .
H66 H 0.4931 0.2882 0.0521 0.043 Uiso 1 1 calc R . .
C67 C 0.5654(4) 0.4262(4) 0.03699(18) 0.0356(12) Uani 1 1 d . . .
H67 H 0.5333 0.4133 0.0062 0.043 Uiso 1 1 calc R . .
C68 C 0.6381(5) 0.5199(4) 0.05554(18) 0.0386(13) Uani 1 1 d . . .
H68 H 0.6555 0.57 0.037 0.046 Uiso 1 1 calc R . .
C69 C 0.6857(4) 0.5403(4) 0.10174(17) 0.0302(11) Uani 1 1 d . . .
H69 H 0.7347 0.6037 0.1139 0.036 Uiso 1 1 calc R . .
C70 C 0.8471(3) 0.4708(3) 0.19803(15) 0.0222(9) Uani 1 1 d . . .
C71 C 0.9276(4) 0.5281(4) 0.17576(18) 0.0329(12) Uani 1 1 d . . .
H71 H 0.9207 0.5749 0.1584 0.04 Uiso 1 1 calc R . .
C72 C 1.0183(4) 0.5147(4) 0.1797(2) 0.0390(13) Uani 1 1 d . . .
H72 H 1.0716 0.5514 0.1642 0.047 Uiso 1 1 calc R . .
C73 C 1.0295(4) 0.4470(4) 0.20643(18) 0.0345(12) Uani 1 1 d . . .
H73 H 1.0912 0.4395 0.2096 0.041 Uiso 1 1 calc R . .
C74 C 0.9498(4) 0.3905(4) 0.22838(18) 0.0327(12) Uani 1 1 d . . .
H74 H 0.9573 0.3442 0.2459 0.039 Uiso 1 1 calc R . .
C75 C 0.8588(4) 0.4023(3) 0.22455(17) 0.0266(10) Uani 1 1 d . . .
H75 H 0.8053 0.3645 0.2397 0.032 Uiso 1 1 calc R . .
C76 C 0.4893(4) 0.5759(3) 0.26673(16) 0.0222(9) Uani 1 1 d . . .
C77 C 0.4235(4) 0.5746(4) 0.22643(17) 0.0288(11) Uani 1 1 d . . .
H77 H 0.4408 0.5676 0.1984 0.035 Uiso 1 1 calc R . .
C78 C 0.3321(4) 0.5838(4) 0.2283(2) 0.0366(12) Uani 1 1 d . . .
H78 H 0.2883 0.5833 0.2014 0.044 Uiso 1 1 calc R . .
C79 C 0.3061(4) 0.5936(4) 0.26997(19) 0.0334(12) Uani 1 1 d . . .
H79 H 0.2447 0.5999 0.2711 0.04 Uiso 1 1 calc R . .
C80 C 0.3704(4) 0.5942(4) 0.30980(19) 0.0347(12) Uani 1 1 d . . .
H80 H 0.3526 0.601 0.3378 0.042 Uiso 1 1 calc R . .
C81 C 0.4622(4) 0.5847(4) 0.30820(17) 0.0294(11) Uani 1 1 d . . .
H81 H 0.5052 0.5842 0.3351 0.035 Uiso 1 1 calc R . .
C82 C 0.7165(4) 0.6262(3) 0.31809(16) 0.0259(10) Uani 1 1 d . . .
C83 C 0.7309(4) 0.7157(4) 0.3368(2) 0.0372(13) Uani 1 1 d . . .
H83 H 0.6868 0.742 0.3238 0.045 Uiso 1 1 calc R . .
C84 C 0.8104(5) 0.7660(4) 0.3745(2) 0.0473(16) Uani 1 1 d . . .
H84 H 0.8191 0.8256 0.3872 0.057 Uiso 1 1 calc R . .
C85 C 0.8766(5) 0.7281(5) 0.3932(2) 0.0553(18) Uani 1 1 d . . .
H85 H 0.9303 0.7622 0.4186 0.066 Uiso 1 1 calc R . .
C86 C 0.8638(7) 0.6398(5) 0.3746(2) 0.073(3) Uani 1 1 d . . .
H86 H 0.9097 0.6147 0.3869 0.088 Uiso 1 1 calc R . .
C87 C 0.7830(5) 0.5887(5) 0.33770(19) 0.0492(17) Uani 1 1 d . . .
H87 H 0.773 0.528 0.3258 0.059 Uiso 1 1 calc R . .
S88 S 0.56820(8) 0.24342(8) 0.22472(3) 0.0162(2) Uani 1 1 d . . .
S89 S 0.44965(8) 0.32653(8) 0.27388(3) 0.0164(2) Uani 1 1 d . . .
B90 B 0.7190(4) 0.2829(4) 0.55752(18) 0.0247(11) Uani 1 1 d . . .
C91 C 0.5921(4) 0.2528(3) 0.55621(16) 0.0242(10) Uani 1 1 d . . .
C92 C 0.5305(4) 0.2627(3) 0.51681(17) 0.0267(10) Uani 1 1 d . . .
H92 H 0.5618 0.2835 0.4917 0.032 Uiso 1 1 calc R . .
C93 C 0.4250(4) 0.2429(4) 0.51361(18) 0.0313(11) Uani 1 1 d . . .
H93 H 0.3869 0.2495 0.4866 0.038 Uiso 1 1 calc R . .
C94 C 0.3765(4) 0.2134(4) 0.55037(19) 0.0336(12) Uani 1 1 d . . .
H94 H 0.3062 0.2015 0.5486 0.04 Uiso 1 1 calc R . .
C95 C 0.4326(4) 0.2018(4) 0.58957(19) 0.0345(12) Uani 1 1 d . . .
H95 H 0.4001 0.181 0.6144 0.041 Uiso 1 1 calc R . .
C96 C 0.5394(4) 0.2212(4) 0.59241(17) 0.0311(11) Uani 1 1 d . . .
H96 H 0.5762 0.2128 0.6193 0.037 Uiso 1 1 calc R . .
C97 C 0.7841(4) 0.2992(4) 0.61111(16) 0.0315(12) Uani 1 1 d . . .
C98 C 0.8498(4) 0.3876(5) 0.63663(18) 0.0423(14) Uani 1 1 d . . .
H98 H 0.8588 0.4444 0.6238 0.051 Uiso 1 1 calc R . .
C99 C 0.9040(5) 0.3952(6) 0.6815(2) 0.061(2) Uani 1 1 d . . .
H99 H 0.9486 0.4566 0.6973 0.074 Uiso 1 1 calc R . .
C100 C 0.8925(6) 0.3151(7) 0.7019(2) 0.065(2) Uani 1 1 d . . .
H100 H 0.9293 0.3206 0.7314 0.078 Uiso 1 1 calc R . .
C101 C 0.8242(7) 0.2239(6) 0.6778(2) 0.071(2) Uani 1 1 d . . .
H101 H 0.8135 0.1674 0.6912 0.085 Uiso 1 1 calc R . .
C102 C 0.7723(6) 0.2182(5) 0.63339(18) 0.0546(19) Uani 1 1 d . . .
H102 H 0.7272 0.1567 0.6177 0.066 Uiso 1 1 calc R . .
C103 C 0.7332(4) 0.1959(3) 0.53104(14) 0.0210(9) Uani 1 1 d . . .
C104 C 0.8350(4) 0.2073(3) 0.52814(15) 0.0230(9) Uani 1 1 d . . .
H104 H 0.8937 0.2653 0.5414 0.028 Uiso 1 1 calc R . .
C105 C 0.8521(4) 0.1362(4) 0.50650(16) 0.0259(10) Uani 1 1 d . . .
H105 H 0.9208 0.1475 0.5049 0.031 Uiso 1 1 calc R . .
C106 C 0.7658(4) 0.0479(3) 0.48717(15) 0.0258(10) Uani 1 1 d . . .
H106 H 0.7765 -0.0003 0.4726 0.031 Uiso 1 1 calc R . .
C107 C 0.6639(4) 0.0322(3) 0.48977(15) 0.0251(10) Uani 1 1 d . . .
H107 H 0.6057 -0.0267 0.4772 0.03 Uiso 1 1 calc R . .
C108 C 0.6491(4) 0.1057(3) 0.51149(14) 0.0228(9) Uani 1 1 d . . .
H108 H 0.5802 0.0939 0.513 0.027 Uiso 1 1 calc R . .
C109 C 0.7677(4) 0.3845(3) 0.53342(16) 0.0254(10) Uani 1 1 d . . .
C110 C 0.8283(4) 0.4028(4) 0.49959(17) 0.0305(11) Uani 1 1 d . . .
H110 H 0.844 0.3544 0.4889 0.037 Uiso 1 1 calc R . .
C111 C 0.8661(4) 0.4918(4) 0.48122(19) 0.0366(12) Uani 1 1 d . . .
H111 H 0.9074 0.5016 0.4591 0.044 Uiso 1 1 calc R . .
C112 C 0.8434(4) 0.5652(4) 0.4954(2) 0.0377(13) Uani 1 1 d . . .
H112 H 0.8689 0.6244 0.4831 0.045 Uiso 1 1 calc R . .
C113 C 0.7819(4) 0.5484(4) 0.5281(2) 0.0370(13) Uani 1 1 d . . .
H113 H 0.7646 0.5964 0.5378 0.044 Uiso 1 1 calc R . .
C114 C 0.7454(4) 0.4604(4) 0.54668(18) 0.0320(11) Uani 1 1 d . . .
H114 H 0.7045 0.4515 0.5689 0.038 Uiso 1 1 calc R . .
B115 B 0.2110(4) 0.0952(4) 0.89658(17) 0.0210(10) Uani 1 1 d . . .
C116 C 0.1416(3) 0.1188(3) 0.85259(15) 0.0213(9) Uani 1 1 d . . .
C117 C 0.1563(4) 0.1090(3) 0.80765(16) 0.0259(10) Uani 1 1 d . . .
H117 H 0.2096 0.0926 0.8031 0.031 Uiso 1 1 calc R . .
C118 C 0.0955(4) 0.1225(4) 0.76989(17) 0.0328(12) Uani 1 1 d . . .
H118 H 0.1068 0.113 0.7408 0.039 Uiso 1 1 calc R . .
C119 C 0.0181(4) 0.1501(4) 0.77554(19) 0.0351(12) Uani 1 1 d . . .
H119 H -0.023 0.1592 0.7503 0.042 Uiso 1 1 calc R . .
C120 C 0.0026(4) 0.1637(4) 0.81872(18) 0.0309(11) Uani 1 1 d . . .
H120 H -0.049 0.1826 0.8229 0.037 Uiso 1 1 calc R . .
C121 C 0.0634(4) 0.1494(3) 0.85612(17) 0.0266(10) Uani 1 1 d . . .
H121 H 0.0522 0.1605 0.885 0.032 Uiso 1 1 calc R . .
C122 C 0.1951(4) 0.1379(3) 0.94405(15) 0.0209(9) Uani 1 1 d . . .
C123 C 0.0971(4) 0.0949(4) 0.95815(16) 0.0254(10) Uani 1 1 d . . .
H123 H 0.0429 0.0383 0.941 0.03 Uiso 1 1 calc R . .
C124 C 0.0764(4) 0.1319(4) 0.99630(17) 0.0309(11) Uani 1 1 d . . .
H124 H 0.0095 0.1013 1.0037 0.037 Uiso 1 1 calc R . .
C125 C 0.1561(4) 0.2146(4) 1.02322(17) 0.0312(11) Uani 1 1 d . . .
H125 H 0.1434 0.2404 1.0488 0.037 Uiso 1 1 calc R . .
C126 C 0.2551(4) 0.2584(4) 1.01146(16) 0.0297(11) Uani 1 1 d . . .
H126 H 0.3096 0.3137 1.0294 0.036 Uiso 1 1 calc R . .
C127 C 0.2732(4) 0.2202(3) 0.97305(15) 0.0240(10) Uani 1 1 d . . .
H127 H 0.3407 0.2507 0.9662 0.029 Uiso 1 1 calc R . .
C128 C 0.3374(3) 0.1493(3) 0.89283(14) 0.0205(9) Uani 1 1 d . . .
C129 C 0.3861(4) 0.2463(3) 0.88354(16) 0.0277(10) Uani 1 1 d . . .
H129 H 0.3448 0.2789 0.8779 0.033 Uiso 1 1 calc R . .
C130 C 0.4932(4) 0.2957(4) 0.88238(17) 0.0324(12) Uani 1 1 d . . .
H130 H 0.5222 0.3601 0.8761 0.039 Uiso 1 1 calc R . .
C131 C 0.5573(4) 0.2497(4) 0.89051(19) 0.0383(13) Uani 1 1 d . . .
H131 H 0.6294 0.2829 0.8899 0.046 Uiso 1 1 calc R . .
C132 C 0.5128(4) 0.1541(4) 0.89947(19) 0.0369(13) Uani 1 1 d . . .
H132 H 0.5549 0.122 0.9048 0.044 Uiso 1 1 calc R . .
C133 C 0.4051(4) 0.1052(4) 0.90063(16) 0.0255(10) Uani 1 1 d . . .
H133 H 0.3769 0.0407 0.9068 0.031 Uiso 1 1 calc R . .
C134 C 0.1729(3) -0.0234(3) 0.89508(16) 0.0228(9) Uani 1 1 d . . .
C135 C 0.1622(4) -0.0720(4) 0.93403(19) 0.0349(12) Uani 1 1 d . . .
H135 H 0.1694 -0.038 0.9616 0.042 Uiso 1 1 calc R . .
C136 C 0.1412(5) -0.1698(4) 0.9332(2) 0.0462(15) Uani 1 1 d . . .
H136 H 0.1352 -0.1991 0.96 0.055 Uiso 1 1 calc R . .
C137 C 0.1293(4) -0.2231(4) 0.8931(2) 0.0465(16) Uani 1 1 d . . .
H137 H 0.1146 -0.2885 0.8923 0.056 Uiso 1 1 calc R . .
C138 C 0.1398(5) -0.1776(4) 0.8542(2) 0.0463(15) Uani 1 1 d . . .
H138 H 0.1334 -0.212 0.8268 0.056 Uiso 1 1 calc R . .
C139 C 0.1597(4) -0.0805(4) 0.85511(18) 0.0356(12) Uani 1 1 d . . .
H139 H 0.1645 -0.0523 0.8279 0.043 Uiso 1 1 calc R . .
S140 S 0.10841(12) 0.10419(12) 0.46050(5) 0.0437(3) Uani 1 1 d . . .
O141 O 0.0972(4) 0.1537(4) 0.50147(16) 0.0643(14) Uani 1 1 d . . .
C142 C 0.1475(5) 0.1914(4) 0.4213(2) 0.0509(16) Uani 1 1 d . . .
H14A H 0.0986 0.2189 0.4162 0.076 Uiso 1 1 calc R . .
H14B H 0.1473 0.1604 0.393 0.076 Uiso 1 1 calc R . .
H14C H 0.2178 0.2422 0.4336 0.076 Uiso 1 1 calc R . .
C143 C -0.0237(5) 0.0302(5) 0.4292(2) 0.064(2) Uani 1 1 d . . .
H14D H -0.0591 -0.0243 0.4453 0.096 Uiso 1 1 calc R . .
H14E H -0.0209 0.007 0.3995 0.096 Uiso 1 1 calc R . .
H14F H -0.062 0.0682 0.4259 0.096 Uiso 1 1 calc R . .
S144 S 0.9593(3) 0.5653(3) 0.06264(9) 0.1291(14) Uani 1 1 d . . .
O145 O 1.0649(7) 0.5606(7) 0.0676(2) 0.133(3) Uani 1 1 d . . .
C146 C 0.8541(7) 0.4497(7) 0.0411(4) 0.099(3) Uani 1 1 d . . .
H14G H 0.8518 0.4369 0.0092 0.148 Uiso 1 1 calc R . .
H14H H 0.7882 0.4482 0.045 0.148 Uiso 1 1 calc R . .
H14I H 0.8649 0.4009 0.0573 0.148 Uiso 1 1 calc R . .
C147 C 0.9441(13) 0.6247(11) 0.0164(4) 0.186(8) Uani 1 1 d . . .
H14J H 0.9911 0.6932 0.0236 0.279 Uiso 1 1 calc R . .
H14K H 0.8719 0.6146 0.0089 0.279 Uiso 1 1 calc R . .
H14L H 0.961 0.5995 -0.0092 0.279 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0 0 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
As As 0.0499 2.0058 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0013 0.0007 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.006 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
S89 Pt1 As2 93.04(3) . . ?
S89 Pt1 As5 175.78(3) . . ?
As2 Pt1 As5 84.592(18) . . ?
S89 Pt1 S88 80.96(4) . . ?
As2 Pt1 S88 173.24(3) . . ?
As5 Pt1 S88 101.58(3) . . ?
S89 Pt1 Pt30 49.45(3) . . ?
As2 Pt1 Pt30 123.718(19) . . ?
As5 Pt1 Pt30 134.714(14) . . ?
S88 Pt1 Pt30 49.75(3) . . ?
S89 Pt1 Pt59 47.08(3) . . ?
As2 Pt1 Pt59 128.988(15) . . ?
As5 Pt1 Pt59 132.656(16) . . ?
S88 Pt1 Pt59 47.98(3) . . ?
Pt30 Pt1 Pt59 58.974(10) . . ?
C24 As2 C18 106.26(19) . . ?
C24 As2 C3 111.74(19) . . ?
C18 As2 C3 104.1(2) . . ?
C24 As2 Pt1 114.66(14) . . ?
C18 As2 Pt1 111.07(13) . . ?
C3 As2 Pt1 108.48(13) . . ?
C4 C3 As2 106.7(3) . . ?
C4 C3 H3A 110.4 . . ?
As2 C3 H3A 110.4 . . ?
C4 C3 H3B 110.4 . . ?
As2 C3 H3B 110.4 . . ?
H3A C3 H3B 108.6 . . ?
C3 C4 As5 108.2(3) . . ?
C3 C4 H4A 110.1 . . ?
As5 C4 H4A 110.1 . . ?
C3 C4 H4B 110.1 . . ?
As5 C4 H4B 110.1 . . ?
H4A C4 H4B 108.4 . . ?
C6 As5 C12 110.2(2) . . ?
C6 As5 C4 106.7(2) . . ?
C12 As5 C4 101.7(2) . . ?
C6 As5 Pt1 120.30(14) . . ?
C12 As5 Pt1 109.04(14) . . ?
C4 As5 Pt1 107.21(13) . . ?
C7 C6 C11 119.2(5) . . ?
C7 C6 As5 119.1(4) . . ?
C11 C6 As5 121.2(4) . . ?
C6 C7 C8 120.2(5) . . ?
C6 C7 H7 119.9 . . ?
C8 C7 H7 119.9 . . ?
C9 C8 C7 120.6(6) . . ?
C9 C8 H8 119.7 . . ?
C7 C8 H8 119.7 . . ?
C8 C9 C10 120.6(5) . . ?
C8 C9 H9 119.7 . . ?
C10 C9 H9 119.7 . . ?
C9 C10 C11 119.5(6) . . ?
C9 C10 H10 120.3 . . ?
C11 C10 H10 120.3 . . ?
C6 C11 C10 119.9(5) . . ?
C6 C11 H11 120 . . ?
C10 C11 H11 120 . . ?
C13 C12 C17 120.0(5) . . ?
C13 C12 As5 117.9(4) . . ?
C17 C12 As5 121.4(4) . . ?
C12 C13 C14 120.0(5) . . ?
C12 C13 H13 120 . . ?
C14 C13 H13 120 . . ?
C15 C14 C13 120.1(5) . . ?
C15 C14 H14 119.9 . . ?
C13 C14 H14 119.9 . . ?
C16 C15 C14 119.9(5) . . ?
C16 C15 H15 120.1 . . ?
C14 C15 H15 120.1 . . ?
C15 C16 C17 120.4(5) . . ?
C15 C16 H16 119.8 . . ?
C17 C16 H16 119.8 . . ?
C12 C17 C16 119.5(5) . . ?
C12 C17 H17 120.2 . . ?
C16 C17 H17 120.2 . . ?
C19 C18 C23 118.7(4) . . ?
C19 C18 As2 118.9(3) . . ?
C23 C18 As2 122.3(4) . . ?
C20 C19 C18 120.7(5) . . ?
C20 C19 H19 119.7 . . ?
C18 C19 H19 119.7 . . ?
C19 C20 C21 119.7(5) . . ?
C19 C20 H20 120.2 . . ?
C21 C20 H20 120.2 . . ?
C22 C21 C20 120.2(5) . . ?
C22 C21 H21 119.9 . . ?
C20 C21 H21 119.9 . . ?
C23 C22 C21 119.8(5) . . ?
C23 C22 H22 120.1 . . ?
C21 C22 H22 120.1 . . ?
C22 C23 C18 121.0(5) . . ?
C22 C23 H23 119.5 . . ?
C18 C23 H23 119.5 . . ?
C29 C24 C25 120.2(4) . . ?
C29 C24 As2 121.9(4) . . ?
C25 C24 As2 117.2(3) . . ?
C26 C25 C24 119.9(5) . . ?
C26 C25 H25 120.1 . . ?
C24 C25 H25 120.1 . . ?
C27 C26 C25 119.7(5) . . ?
C27 C26 H26 120.2 . . ?
C25 C26 H26 120.2 . . ?
C28 C27 C26 120.2(5) . . ?
C28 C27 H27 119.9 . . ?
C26 C27 H27 119.9 . . ?
C27 C28 C29 121.2(5) . . ?
C27 C28 H28 119.4 . . ?
C29 C28 H28 119.4 . . ?
C24 C29 C28 118.7(5) . . ?
C24 C29 H29 120.6 . . ?
C28 C29 H29 120.6 . . ?
S89 Pt30 As31 95.10(3) . . ?
S89 Pt30 S88 80.91(3) . . ?
As31 Pt30 S88 170.73(3) . . ?
S89 Pt30 As34 173.60(3) . . ?
As31 Pt30 As34 85.675(17) . . ?
S88 Pt30 As34 99.23(3) . . ?
S89 Pt30 Pt1 49.22(3) . . ?
As31 Pt30 Pt1 132.389(14) . . ?
S88 Pt30 Pt1 49.90(3) . . ?
As34 Pt30 Pt1 126.348(16) . . ?
S89 Pt30 Pt59 48.80(3) . . ?
As31 Pt30 Pt59 121.659(18) . . ?
S88 Pt30 Pt59 49.71(3) . . ?
As34 Pt30 Pt59 135.533(15) . . ?
Pt1 Pt30 Pt59 62.455(10) . . ?
C53 As31 C47 104.82(18) . . ?
C53 As31 C32 106.84(19) . . ?
C47 As31 C32 105.08(19) . . ?
C53 As31 Pt30 122.34(13) . . ?
C47 As31 Pt30 108.46(14) . . ?
C32 As31 Pt30 108.06(14) . . ?
C33 C32 As31 109.2(3) . . ?
C33 C32 H32A 109.8 . . ?
As31 C32 H32A 109.8 . . ?
C33 C32 H32B 109.8 . . ?
As31 C32 H32B 109.8 . . ?
H32A C32 H32B 108.3 . . ?
C32 C33 As34 110.4(3) . . ?
C32 C33 H33A 109.6 . . ?
As34 C33 H33A 109.6 . . ?
C32 C33 H33B 109.6 . . ?
As34 C33 H33B 109.6 . . ?
H33A C33 H33B 108.1 . . ?
C35 As34 C41 102.6(2) . . ?
C35 As34 C33 105.1(2) . . ?
C41 As34 C33 104.4(2) . . ?
C35 As34 Pt30 122.15(14) . . ?
C41 As34 Pt30 113.02(16) . . ?
C33 As34 Pt30 107.98(13) . . ?
C40 C35 C36 119.5(4) . . ?
C40 C35 As34 118.4(3) . . ?
C36 C35 As34 122.1(4) . . ?
C37 C36 C35 119.9(5) . . ?
C37 C36 H36 120 . . ?
C35 C36 H36 120 . . ?
C38 C37 C36 120.4(5) . . ?
C38 C37 H37 119.8 . . ?
C36 C37 H37 119.8 . . ?
C37 C38 C39 120.4(5) . . ?
C37 C38 H38 119.8 . . ?
C39 C38 H38 119.8 . . ?
C38 C39 C40 119.6(5) . . ?
C38 C39 H39 120.2 . . ?
C40 C39 H39 120.2 . . ?
C39 C40 C35 120.2(5) . . ?
C39 C40 H40 119.9 . . ?
C35 C40 H40 119.9 . . ?
C46 C41 C42 120.3(5) . . ?
C46 C41 As34 120.3(4) . . ?
C42 C41 As34 119.4(4) . . ?
C43 C42 C41 119.1(6) . . ?
C43 C42 H42 120.4 . . ?
C41 C42 H42 120.4 . . ?
C44 C43 C42 121.1(7) . . ?
C44 C43 H43 119.5 . . ?
C42 C43 H43 119.5 . . ?
C43 C44 C45 120.7(6) . . ?
C43 C44 H44 119.6 . . ?
C45 C44 H44 119.6 . . ?
C44 C45 C46 118.8(7) . . ?
C44 C45 H45 120.6 . . ?
C46 C45 H45 120.6 . . ?
C41 C46 C45 119.9(6) . . ?
C41 C46 H46 120 . . ?
C45 C46 H46 120 . . ?
C48 C47 C52 120.5(4) . . ?
C48 C47 As31 119.3(3) . . ?
C52 C47 As31 120.2(4) . . ?
C47 C48 C49 120.2(5) . . ?
C47 C48 H48 119.9 . . ?
C49 C48 H48 119.9 . . ?
C50 C49 C48 119.2(5) . . ?
C50 C49 H49 120.4 . . ?
C48 C49 H49 120.4 . . ?
C49 C50 C51 121.0(5) . . ?
C49 C50 H50 119.5 . . ?
C51 C50 H50 119.5 . . ?
C50 C51 C52 120.3(5) . . ?
C50 C51 H51 119.9 . . ?
C52 C51 H51 119.9 . . ?
C47 C52 C51 118.8(5) . . ?
C47 C52 H52 120.6 . . ?
C51 C52 H52 120.6 . . ?
C54 C53 C58 119.8(4) . . ?
C54 C53 As31 119.8(4) . . ?
C58 C53 As31 120.4(4) . . ?
C53 C54 C55 120.2(5) . . ?
C53 C54 H54 119.9 . . ?
C55 C54 H54 119.9 . . ?
C56 C55 C54 120.0(5) . . ?
C56 C55 H55 120 . . ?
C54 C55 H55 120 . . ?
C57 C56 C55 119.9(5) . . ?
C57 C56 H56 120 . . ?
C55 C56 H56 120 . . ?
C56 C57 C58 120.6(5) . . ?
C56 C57 H57 119.7 . . ?
C58 C57 H57 119.7 . . ?
C53 C58 C57 119.5(5) . . ?
C53 C58 H58 120.3 . . ?
C57 C58 H58 120.3 . . ?
S89 Pt59 As60 92.95(3) . . ?
S89 Pt59 As63 170.71(3) . . ?
As60 Pt59 As63 85.125(19) . . ?
S89 Pt59 S88 81.12(4) . . ?
As60 Pt59 S88 172.68(3) . . ?
As63 Pt59 S88 101.41(3) . . ?
S89 Pt59 Pt30 49.27(3) . . ?
As60 Pt59 Pt30 128.686(17) . . ?
As63 Pt59 Pt30 126.132(16) . . ?
S88 Pt59 Pt30 49.54(3) . . ?
S89 Pt59 Pt1 47.31(3) . . ?
As60 Pt59 Pt1 124.719(18) . . ?
As63 Pt59 Pt1 140.081(14) . . ?
S88 Pt59 Pt1 47.96(3) . . ?
Pt30 Pt59 Pt1 58.571(11) . . ?
C76 As60 C82 106.82(19) . . ?
C76 As60 C61 106.42(19) . . ?
C82 As60 C61 100.8(2) . . ?
C76 As60 Pt59 118.87(13) . . ?
C82 As60 Pt59 114.84(15) . . ?
C61 As60 Pt59 107.28(13) . . ?
C62 C61 As60 107.8(3) . . ?
C62 C61 H61A 110.2 . . ?
As60 C61 H61A 110.2 . . ?
C62 C61 H61B 110.2 . . ?
As60 C61 H61B 110.2 . . ?
H61A C61 H61B 108.5 . . ?
C61 C62 As63 109.5(3) . . ?
C61 C62 H62A 109.8 . . ?
As63 C62 H62A 109.8 . . ?
C61 C62 H62B 109.8 . . ?
As63 C62 H62B 109.8 . . ?
H62A C62 H62B 108.2 . . ?
C70 As63 C64 104.97(18) . . ?
C70 As63 C62 105.24(19) . . ?
C64 As63 C62 103.77(19) . . ?
C70 As63 Pt59 120.89(14) . . ?
C64 As63 Pt59 112.85(13) . . ?
C62 As63 Pt59 107.63(13) . . ?
C69 C64 C65 119.2(4) . . ?
C69 C64 As63 122.7(4) . . ?
C65 C64 As63 118.2(3) . . ?
C66 C65 C64 120.4(5) . . ?
C66 C65 H65 119.8 . . ?
C64 C65 H65 119.8 . . ?
C65 C66 C67 120.4(5) . . ?
C65 C66 H66 119.8 . . ?
C67 C66 H66 119.8 . . ?
C68 C67 C66 119.4(5) . . ?
C68 C67 H67 120.3 . . ?
C66 C67 H67 120.3 . . ?
C67 C68 C69 120.7(5) . . ?
C67 C68 H68 119.6 . . ?
C69 C68 H68 119.6 . . ?
C64 C69 C68 119.9(5) . . ?
C64 C69 H69 120 . . ?
C68 C69 H69 120 . . ?
C75 C70 C71 120.1(4) . . ?
C75 C70 As63 119.2(3) . . ?
C71 C70 As63 120.7(4) . . ?
C72 C71 C70 119.4(5) . . ?
C72 C71 H71 120.3 . . ?
C70 C71 H71 120.3 . . ?
C73 C72 C71 120.1(5) . . ?
C73 C72 H72 119.9 . . ?
C71 C72 H72 119.9 . . ?
C74 C73 C72 120.3(5) . . ?
C74 C73 H73 119.8 . . ?
C72 C73 H73 119.8 . . ?
C73 C74 C75 120.3(5) . . ?
C73 C74 H74 119.9 . . ?
C75 C74 H74 119.9 . . ?
C74 C75 C70 119.8(5) . . ?
C74 C75 H75 120.1 . . ?
C70 C75 H75 120.1 . . ?
C81 C76 C77 119.8(4) . . ?
C81 C76 As60 121.9(4) . . ?
C77 C76 As60 118.2(3) . . ?
C78 C77 C76 119.8(5) . . ?
C78 C77 H77 120.1 . . ?
C76 C77 H77 120.1 . . ?
C79 C78 C77 120.1(5) . . ?
C79 C78 H78 120 . . ?
C77 C78 H78 120 . . ?
C80 C79 C78 120.3(5) . . ?
C80 C79 H79 119.9 . . ?
C78 C79 H79 119.9 . . ?
C79 C80 C81 120.0(5) . . ?
C79 C80 H80 120 . . ?
C81 C80 H80 120 . . ?
C76 C81 C80 120.0(5) . . ?
C76 C81 H81 120 . . ?
C80 C81 H81 120 . . ?
C87 C82 C83 118.9(5) . . ?
C87 C82 As60 120.5(4) . . ?
C83 C82 As60 120.4(4) . . ?
C84 C83 C82 120.3(5) . . ?
C84 C83 H83 119.9 . . ?
C82 C83 H83 119.9 . . ?
C85 C84 C83 120.0(6) . . ?
C85 C84 H84 120 . . ?
C83 C84 H84 120 . . ?
C84 C85 C86 120.2(6) . . ?
C84 C85 H85 119.9 . . ?
C86 C85 H85 119.9 . . ?
C85 C86 C87 119.7(6) . . ?
C85 C86 H86 120.1 . . ?
C87 C86 H86 120.1 . . ?
C86 C87 C82 120.9(6) . . ?
C86 C87 H87 119.5 . . ?
C82 C87 H87 119.5 . . ?
Pt30 S88 Pt1 80.35(3) . . ?
Pt30 S88 Pt59 80.75(3) . . ?
Pt1 S88 Pt59 84.06(3) . . ?
Pt59 S89 Pt1 85.61(4) . . ?
Pt59 S89 Pt30 81.93(3) . . ?
Pt1 S89 Pt30 81.33(3) . . ?
C103 B90 C109 111.4(4) . . ?
C103 B90 C91 111.7(4) . . ?
C109 B90 C91 106.7(4) . . ?
C103 B90 C97 105.9(4) . . ?
C109 B90 C97 110.8(4) . . ?
C91 B90 C97 110.5(4) . . ?
C96 C91 C92 115.1(4) . . ?
C96 C91 B90 125.4(4) . . ?
C92 C91 B90 119.4(4) . . ?
C93 C92 C91 123.0(5) . . ?
C93 C92 H92 118.5 . . ?
C91 C92 H92 118.5 . . ?
C94 C93 C92 120.1(5) . . ?
C94 C93 H93 120 . . ?
C92 C93 H93 120 . . ?
C95 C94 C93 119.4(5) . . ?
C95 C94 H94 120.3 . . ?
C93 C94 H94 120.3 . . ?
C94 C95 C96 120.1(5) . . ?
C94 C95 H95 119.9 . . ?
C96 C95 H95 119.9 . . ?
C91 C96 C95 122.3(5) . . ?
C91 C96 H96 118.9 . . ?
C95 C96 H96 118.9 . . ?
C98 C97 C102 115.1(5) . . ?
C98 C97 B90 125.8(5) . . ?
C102 C97 B90 119.1(5) . . ?
C97 C98 C99 122.3(6) . . ?
C97 C98 H98 118.8 . . ?
C99 C98 H98 118.8 . . ?
C100 C99 C98 121.2(6) . . ?
C100 C99 H99 119.4 . . ?
C98 C99 H99 119.4 . . ?
C99 C100 C101 118.4(6) . . ?
C99 C100 H100 120.8 . . ?
C101 C100 H100 120.8 . . ?
C102 C101 C100 119.3(7) . . ?
C102 C101 H101 120.4 . . ?
C100 C101 H101 120.4 . . ?
C101 C102 C97 123.6(7) . . ?
C101 C102 H102 118.2 . . ?
C97 C102 H102 118.2 . . ?
C108 C103 C104 115.1(4) . . ?
C108 C103 B90 124.3(4) . . ?
C104 C103 B90 120.6(4) . . ?
C105 C104 C103 123.2(4) . . ?
C105 C104 H104 118.4 . . ?
C103 C104 H104 118.4 . . ?
C104 C105 C106 119.7(4) . . ?
C104 C105 H105 120.2 . . ?
C106 C105 H105 120.2 . . ?
C107 C106 C105 119.4(4) . . ?
C107 C106 H106 120.3 . . ?
C105 C106 H106 120.3 . . ?
C106 C107 C108 119.6(4) . . ?
C106 C107 H107 120.2 . . ?
C108 C107 H107 120.2 . . ?
C107 C108 C103 123.1(4) . . ?
C107 C108 H108 118.5 . . ?
C103 C108 H108 118.5 . . ?
C110 C109 C114 115.2(5) . . ?
C110 C109 B90 126.3(4) . . ?
C114 C109 B90 118.5(4) . . ?
C109 C110 C111 122.0(5) . . ?
C109 C110 H110 119 . . ?
C111 C110 H110 119 . . ?
C112 C111 C110 121.2(5) . . ?
C112 C111 H111 119.4 . . ?
C110 C111 H111 119.4 . . ?
C113 C112 C111 118.1(5) . . ?
C113 C112 H112 121 . . ?
C111 C112 H112 121 . . ?
C112 C113 C114 120.7(5) . . ?
C112 C113 H113 119.7 . . ?
C114 C113 H113 119.7 . . ?
C113 C114 C109 122.8(5) . . ?
C113 C114 H114 118.6 . . ?
C109 C114 H114 118.6 . . ?
C122 B115 C128 110.2(4) . . ?
C122 B115 C134 110.8(4) . . ?
C128 B115 C134 108.0(4) . . ?
C122 B115 C116 108.9(4) . . ?
C128 B115 C116 108.3(4) . . ?
C134 B115 C116 110.7(4) . . ?
C117 C116 C121 113.9(4) . . ?
C117 C116 B115 121.8(4) . . ?
C121 C116 B115 124.3(4) . . ?
C118 C117 C116 123.3(5) . . ?
C118 C117 H117 118.3 . . ?
C116 C117 H117 118.3 . . ?
C119 C118 C117 119.9(5) . . ?
C119 C118 H118 120 . . ?
C117 C118 H118 120 . . ?
C120 C119 C118 119.2(5) . . ?
C120 C119 H119 120.4 . . ?
C118 C119 H119 120.4 . . ?
C119 C120 C121 120.2(5) . . ?
C119 C120 H120 119.9 . . ?
C121 C120 H120 119.9 . . ?
C120 C121 C116 123.3(5) . . ?
C120 C121 H121 118.3 . . ?
C116 C121 H121 118.3 . . ?
C127 C122 C123 114.1(4) . . ?
C127 C122 B115 124.8(4) . . ?
C123 C122 B115 121.1(4) . . ?
C124 C123 C122 123.7(5) . . ?
C124 C123 H123 118.1 . . ?
C122 C123 H123 118.1 . . ?
C125 C124 C123 119.6(5) . . ?
C125 C124 H124 120.2 . . ?
C123 C124 H124 120.2 . . ?
C124 C125 C126 118.9(5) . . ?
C124 C125 H125 120.6 . . ?
C126 C125 H125 120.6 . . ?
C125 C126 C127 120.2(5) . . ?
C125 C126 H126 119.9 . . ?
C127 C126 H126 119.9 . . ?
C126 C127 C122 123.4(5) . . ?
C126 C127 H127 118.3 . . ?
C122 C127 H127 118.3 . . ?
C129 C128 C133 115.0(4) . . ?
C129 C128 B115 121.1(4) . . ?
C133 C128 B115 123.8(4) . . ?
C130 C129 C128 122.8(5) . . ?
C130 C129 H129 118.6 . . ?
C128 C129 H129 118.6 . . ?
C131 C130 C129 120.4(5) . . ?
C131 C130 H130 119.8 . . ?
C129 C130 H130 119.8 . . ?
C132 C131 C130 119.0(5) . . ?
C132 C131 H131 120.5 . . ?
C130 C131 H131 120.5 . . ?
C131 C132 C133 120.1(5) . . ?
C131 C132 H132 119.9 . . ?
C133 C132 H132 119.9 . . ?
C132 C133 C128 122.7(5) . . ?
C132 C133 H133 118.6 . . ?
C128 C133 H133 118.6 . . ?
C135 C134 C139 114.7(4) . . ?
C135 C134 B115 123.1(4) . . ?
C139 C134 B115 121.9(4) . . ?
C134 C135 C136 122.6(5) . . ?
C134 C135 H135 118.7 . . ?
C136 C135 H135 118.7 . . ?
C137 C136 C135 120.7(6) . . ?
C137 C136 H136 119.7 . . ?
C135 C136 H136 119.7 . . ?
C138 C137 C136 118.3(5) . . ?
C138 C137 H137 120.9 . . ?
C136 C137 H137 120.9 . . ?
C137 C138 C139 120.8(6) . . ?
C137 C138 H138 119.6 . . ?
C139 C138 H138 119.6 . . ?
C138 C139 C134 122.9(5) . . ?
C138 C139 H139 118.6 . . ?
C134 C139 H139 118.6 . . ?
O141 S140 C142 106.8(3) . . ?
O141 S140 C143 105.9(3) . . ?
C142 S140 C143 96.7(3) . . ?
S140 C142 H14A 109.5 . . ?
S140 C142 H14B 109.5 . . ?
H14A C142 H14B 109.5 . . ?
S140 C142 H14C 109.5 . . ?
H14A C142 H14C 109.5 . . ?
H14B C142 H14C 109.5 . . ?
S140 C143 H14D 109.5 . . ?
S140 C143 H14E 109.5 . . ?
H14D C143 H14E 109.5 . . ?
S140 C143 H14F 109.5 . . ?
H14D C143 H14F 109.5 . . ?
H14E C143 H14F 109.5 . . ?
O145 S144 C147 109.4(6) . . ?
O145 S144 C146 109.5(5) . . ?
C147 S144 C146 97.6(7) . . ?
S144 C146 H14G 109.5 . . ?
S144 C146 H14H 109.5 . . ?
H14G C146 H14H 109.5 . . ?
S144 C146 H14I 109.5 . . ?
H14G C146 H14I 109.5 . . ?
H14H C146 H14I 109.5 . . ?
S144 C147 H14J 109.5 . . ?
S144 C147 H14K 109.5 . . ?
H14J C147 H14K 109.5 . . ?
S144 C147 H14L 109.5 . . ?
H14J C147 H14L 109.5 . . ?
H14K C147 H14L 109.5 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 S89 2.3351(11) . ?
Pt1 As2 2.3510(6) . ?
Pt1 As5 2.3596(6) . ?
Pt1 S88 2.3653(11) . ?
Pt1 Pt30 3.0485(5) . ?
Pt1 Pt59 3.1677(5) . ?
As2 C24 1.919(4) . ?
As2 C18 1.922(5) . ?
As2 C3 1.948(4) . ?
C3 C4 1.524(6) . ?
C3 H3A 0.97 . ?
C3 H3B 0.97 . ?
C4 As5 1.952(5) . ?
C4 H4A 0.97 . ?
C4 H4B 0.97 . ?
As5 C6 1.922(4) . ?
As5 C12 1.940(5) . ?
C6 C7 1.372(7) . ?
C6 C11 1.386(7) . ?
C7 C8 1.391(8) . ?
C7 H7 0.93 . ?
C8 C9 1.358(9) . ?
C8 H8 0.93 . ?
C9 C10 1.364(9) . ?
C9 H9 0.93 . ?
C10 C11 1.408(7) . ?
C10 H10 0.93 . ?
C11 H11 0.93 . ?
C12 C13 1.372(7) . ?
C12 C17 1.387(7) . ?
C13 C14 1.391(7) . ?
C13 H13 0.93 . ?
C14 C15 1.375(7) . ?
C14 H14 0.93 . ?
C15 C16 1.375(8) . ?
C15 H15 0.93 . ?
C16 C17 1.389(7) . ?
C16 H16 0.93 . ?
C17 H17 0.93 . ?
C18 C19 1.389(6) . ?
C18 C23 1.389(6) . ?
C19 C20 1.376(7) . ?
C19 H19 0.93 . ?
C20 C21 1.386(7) . ?
C20 H20 0.93 . ?
C21 C22 1.381(7) . ?
C21 H21 0.93 . ?
C22 C23 1.370(7) . ?
C22 H22 0.93 . ?
C23 H23 0.93 . ?
C24 C29 1.380(7) . ?
C24 C25 1.391(7) . ?
C25 C26 1.388(7) . ?
C25 H25 0.93 . ?
C26 C27 1.381(8) . ?
C26 H26 0.93 . ?
C27 C28 1.358(8) . ?
C27 H27 0.93 . ?
C28 C29 1.397(7) . ?
C28 H28 0.93 . ?
C29 H29 0.93 . ?
Pt30 S89 2.3432(11) . ?
Pt30 As31 2.3500(7) . ?
Pt30 S88 2.3599(12) . ?
Pt30 As34 2.3610(6) . ?
Pt30 Pt59 3.0615(5) . ?
As31 C53 1.930(4) . ?
As31 C47 1.936(5) . ?
As31 C32 1.944(4) . ?
C32 C33 1.528(6) . ?
C32 H32A 0.97 . ?
C32 H32B 0.97 . ?
C33 As34 1.959(4) . ?
C33 H33A 0.97 . ?
C33 H33B 0.97 . ?
As34 C35 1.927(5) . ?
As34 C41 1.932(5) . ?
C35 C40 1.389(6) . ?
C35 C36 1.394(7) . ?
C36 C37 1.380(7) . ?
C36 H36 0.93 . ?
C37 C38 1.376(8) . ?
C37 H37 0.93 . ?
C38 C39 1.385(7) . ?
C38 H38 0.93 . ?
C39 C40 1.387(7) . ?
C39 H39 0.93 . ?
C40 H40 0.93 . ?
C41 C46 1.363(8) . ?
C41 C42 1.393(7) . ?
C42 C43 1.384(8) . ?
C42 H42 0.93 . ?
C43 C44 1.342(11) . ?
C43 H43 0.93 . ?
C44 C45 1.390(11) . ?
C44 H44 0.93 . ?
C45 C46 1.405(8) . ?
C45 H45 0.93 . ?
C46 H46 0.93 . ?
C47 C48 1.386(6) . ?
C47 C52 1.394(6) . ?
C48 C49 1.392(7) . ?
C48 H48 0.93 . ?
C49 C50 1.376(7) . ?
C49 H49 0.93 . ?
C50 C51 1.383(8) . ?
C50 H50 0.93 . ?
C51 C52 1.393(7) . ?
C51 H51 0.93 . ?
C52 H52 0.93 . ?
C53 C54 1.380(6) . ?
C53 C58 1.388(6) . ?
C54 C55 1.388(7) . ?
C54 H54 0.93 . ?
C55 C56 1.379(8) . ?
C55 H55 0.93 . ?
C56 C57 1.374(8) . ?
C56 H56 0.93 . ?
C57 C58 1.391(7) . ?
C57 H57 0.93 . ?
C58 H58 0.93 . ?
Pt59 S89 2.3265(11) . ?
Pt59 As60 2.3548(6) . ?
Pt59 As63 2.3631(6) . ?
Pt59 S88 2.3660(11) . ?
As60 C76 1.922(4) . ?
As60 C82 1.929(5) . ?
As60 C61 1.944(4) . ?
C61 C62 1.517(6) . ?
C61 H61A 0.97 . ?
C61 H61B 0.97 . ?
C62 As63 1.953(4) . ?
C62 H62A 0.97 . ?
C62 H62B 0.97 . ?
As63 C70 1.919(4) . ?
As63 C64 1.938(4) . ?
C64 C69 1.382(6) . ?
C64 C65 1.398(6) . ?
C65 C66 1.382(7) . ?
C65 H65 0.93 . ?
C66 C67 1.382(7) . ?
C66 H66 0.93 . ?
C67 C68 1.379(8) . ?
C67 H67 0.93 . ?
C68 C69 1.393(7) . ?
C68 H68 0.93 . ?
C69 H69 0.93 . ?
C70 C75 1.389(7) . ?
C70 C71 1.393(7) . ?
C71 C72 1.388(7) . ?
C71 H71 0.93 . ?
C72 C73 1.381(8) . ?
C72 H72 0.93 . ?
C73 C74 1.375(7) . ?
C73 H73 0.93 . ?
C74 C75 1.380(7) . ?
C74 H74 0.93 . ?
C75 H75 0.93 . ?
C76 C81 1.379(6) . ?
C76 C77 1.393(7) . ?
C77 C78 1.385(7) . ?
C77 H77 0.93 . ?
C78 C79 1.381(8) . ?
C78 H78 0.93 . ?
C79 C80 1.375(8) . ?
C79 H79 0.93 . ?
C80 C81 1.393(7) . ?
C80 H80 0.93 . ?
C81 H81 0.93 . ?
C82 C87 1.379(7) . ?
C82 C83 1.384(7) . ?
C83 C84 1.382(7) . ?
C83 H83 0.93 . ?
C84 C85 1.372(9) . ?
C84 H84 0.93 . ?
C85 C86 1.376(9) . ?
C85 H85 0.93 . ?
C86 C87 1.376(8) . ?
C86 H86 0.93 . ?
C87 H87 0.93 . ?
B90 C103 1.641(7) . ?
B90 C109 1.649(8) . ?
B90 C91 1.656(7) . ?
B90 C97 1.663(7) . ?
C91 C96 1.398(7) . ?
C91 C92 1.403(7) . ?
C92 C93 1.386(7) . ?
C92 H92 0.93 . ?
C93 C94 1.378(7) . ?
C93 H93 0.93 . ?
C94 C95 1.369(7) . ?
C94 H94 0.93 . ?
C95 C96 1.408(7) . ?
C95 H95 0.93 . ?
C96 H96 0.93 . ?
C97 C98 1.372(7) . ?
C97 C102 1.388(8) . ?
C98 C99 1.405(9) . ?
C98 H98 0.93 . ?
C99 C100 1.349(11) . ?
C99 H99 0.93 . ?
C100 C101 1.391(11) . ?
C100 H100 0.93 . ?
C101 C102 1.387(8) . ?
C101 H101 0.93 . ?
C102 H102 0.93 . ?
C103 C108 1.399(6) . ?
C103 C104 1.405(6) . ?
C104 C105 1.387(6) . ?
C104 H104 0.93 . ?
C105 C106 1.392(7) . ?
C105 H105 0.93 . ?
C106 C107 1.385(7) . ?
C106 H106 0.93 . ?
C107 C108 1.399(6) . ?
C107 H107 0.93 . ?
C108 H108 0.93 . ?
C109 C110 1.395(7) . ?
C109 C114 1.403(7) . ?
C110 C111 1.399(7) . ?
C110 H110 0.93 . ?
C111 C112 1.380(7) . ?
C111 H111 0.93 . ?
C112 C113 1.378(8) . ?
C112 H112 0.93 . ?
C113 C114 1.389(7) . ?
C113 H113 0.93 . ?
C114 H114 0.93 . ?
B115 C122 1.638(7) . ?
B115 C128 1.648(7) . ?
B115 C134 1.655(7) . ?
B115 C116 1.660(7) . ?
C116 C117 1.408(6) . ?
C116 C121 1.409(6) . ?
C117 C118 1.385(7) . ?
C117 H117 0.93 . ?
C118 C119 1.382(8) . ?
C118 H118 0.93 . ?
C119 C120 1.371(8) . ?
C119 H119 0.93 . ?
C120 C121 1.384(7) . ?
C120 H120 0.93 . ?
C121 H121 0.93 . ?
C122 C127 1.401(6) . ?
C122 C123 1.405(6) . ?
C123 C124 1.391(7) . ?
C123 H123 0.93 . ?
C124 C125 1.385(7) . ?
C124 H124 0.93 . ?
C125 C126 1.385(7) . ?
C125 H125 0.93 . ?
C126 C127 1.388(6) . ?
C126 H126 0.93 . ?
C127 H127 0.93 . ?
C128 C129 1.400(6) . ?
C128 C133 1.404(6) . ?
C129 C130 1.384(7) . ?
C129 H129 0.93 . ?
C130 C131 1.382(8) . ?
C130 H130 0.93 . ?
C131 C132 1.376(8) . ?
C131 H131 0.93 . ?
C132 C133 1.391(7) . ?
C132 H132 0.93 . ?
C133 H133 0.93 . ?
C134 C135 1.395(7) . ?
C134 C139 1.397(7) . ?
C135 C136 1.397(8) . ?
C135 H135 0.93 . ?
C136 C137 1.376(9) . ?
C136 H136 0.93 . ?
C137 C138 1.370(9) . ?
C137 H137 0.93 . ?
C138 C139 1.391(7) . ?
C138 H138 0.93 . ?
C139 H139 0.93 . ?
S140 O141 1.492(4) . ?
S140 C142 1.769(6) . ?
S140 C143 1.785(7) . ?
C142 H14A 0.96 . ?
C142 H14B 0.96 . ?
C142 H14C 0.96 . ?
C143 H14D 0.96 . ?
C143 H14E 0.96 . ?
C143 H14F 0.96 . ?
S144 O145 1.526(7) . ?
S144 C147 1.716(10) . ?
S144 C146 1.756(10) . ?
C146 H14G 0.96 . ?
C146 H14H 0.96 . ?
C146 H14I 0.96 . ?
C147 H14J 0.96 . ?
C147 H14K 0.96 . ?
C147 H14L 0.96 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
S89 Pt1 As2 C24 -38.71(15) . . . . ?
As5 Pt1 As2 C24 137.78(15) . . . . ?
S88 Pt1 As2 C24 -66.1(3) . . . . ?
Pt30 Pt1 As2 C24 -80.36(15) . . . . ?
Pt59 Pt1 As2 C24 -5.26(15) . . . . ?
S89 Pt1 As2 C18 81.76(14) . . . . ?
As5 Pt1 As2 C18 -101.75(14) . . . . ?
S88 Pt1 As2 C18 54.4(3) . . . . ?
Pt30 Pt1 As2 C18 40.11(14) . . . . ?
Pt59 Pt1 As2 C18 115.21(14) . . . . ?
S89 Pt1 As2 C3 -164.39(16) . . . . ?
As5 Pt1 As2 C3 12.10(16) . . . . ?
S88 Pt1 As2 C3 168.2(3) . . . . ?
Pt30 Pt1 As2 C3 153.96(16) . . . . ?
Pt59 Pt1 As2 C3 -130.94(16) . . . . ?
C24 As2 C3 C4 -169.8(3) . . . . ?
C18 As2 C3 C4 75.9(3) . . . . ?
Pt1 As2 C3 C4 -42.5(3) . . . . ?
As2 C3 C4 As5 53.5(4) . . . . ?
C3 C4 As5 C6 -173.9(3) . . . . ?
C3 C4 As5 C12 70.6(3) . . . . ?
C3 C4 As5 Pt1 -43.8(3) . . . . ?
S89 Pt1 As5 C6 -169.0(4) . . . . ?
As2 Pt1 As5 C6 134.93(17) . . . . ?
S88 Pt1 As5 C6 -42.28(17) . . . . ?
Pt30 Pt1 As5 C6 1.23(17) . . . . ?
Pt59 Pt1 As5 C6 -84.52(17) . . . . ?
S89 Pt1 As5 C12 -40.4(4) . . . . ?
As2 Pt1 As5 C12 -96.41(15) . . . . ?
S88 Pt1 As5 C12 86.38(15) . . . . ?
Pt30 Pt1 As5 C12 129.89(14) . . . . ?
Pt59 Pt1 As5 C12 44.13(15) . . . . ?
S89 Pt1 As5 C4 69.0(4) . . . . ?
As2 Pt1 As5 C4 12.95(15) . . . . ?
S88 Pt1 As5 C4 -164.26(15) . . . . ?
Pt30 Pt1 As5 C4 -120.76(15) . . . . ?
Pt59 Pt1 As5 C4 153.49(15) . . . . ?
C12 As5 C6 C7 -74.5(5) . . . . ?
C4 As5 C6 C7 175.9(4) . . . . ?
Pt1 As5 C6 C7 53.6(5) . . . . ?
C12 As5 C6 C11 112.5(4) . . . . ?
C4 As5 C6 C11 2.8(5) . . . . ?
Pt1 As5 C6 C11 -119.4(4) . . . . ?
C11 C6 C7 C8 -0.3(8) . . . . ?
As5 C6 C7 C8 -173.5(5) . . . . ?
C6 C7 C8 C9 -0.6(10) . . . . ?
C7 C8 C9 C10 1.5(10) . . . . ?
C8 C9 C10 C11 -1.5(10) . . . . ?
C7 C6 C11 C10 0.3(8) . . . . ?
As5 C6 C11 C10 173.3(4) . . . . ?
C9 C10 C11 C6 0.6(9) . . . . ?
C6 As5 C12 C13 115.9(4) . . . . ?
C4 As5 C12 C13 -131.1(4) . . . . ?
Pt1 As5 C12 C13 -18.1(4) . . . . ?
C6 As5 C12 C17 -73.3(4) . . . . ?
C4 As5 C12 C17 39.6(4) . . . . ?
Pt1 As5 C12 C17 152.7(4) . . . . ?
C17 C12 C13 C14 0.0(8) . . . . ?
As5 C12 C13 C14 171.0(4) . . . . ?
C12 C13 C14 C15 -0.2(9) . . . . ?
C13 C14 C15 C16 0.2(9) . . . . ?
C14 C15 C16 C17 -0.1(8) . . . . ?
C13 C12 C17 C16 0.1(8) . . . . ?
As5 C12 C17 C16 -170.5(4) . . . . ?
C15 C16 C17 C12 -0.1(8) . . . . ?
C24 As2 C18 C19 92.7(4) . . . . ?
C3 As2 C18 C19 -149.2(4) . . . . ?
Pt1 As2 C18 C19 -32.6(4) . . . . ?
C24 As2 C18 C23 -90.3(4) . . . . ?
C3 As2 C18 C23 27.9(4) . . . . ?
Pt1 As2 C18 C23 144.4(3) . . . . ?
C23 C18 C19 C20 0.1(7) . . . . ?
As2 C18 C19 C20 177.2(4) . . . . ?
C18 C19 C20 C21 -1.4(8) . . . . ?
C19 C20 C21 C22 1.4(8) . . . . ?
C20 C21 C22 C23 -0.1(8) . . . . ?
C21 C22 C23 C18 -1.3(8) . . . . ?
C19 C18 C23 C22 1.2(7) . . . . ?
As2 C18 C23 C22 -175.8(4) . . . . ?
C18 As2 C24 C29 158.3(4) . . . . ?
C3 As2 C24 C29 45.3(5) . . . . ?
Pt1 As2 C24 C29 -78.6(4) . . . . ?
C18 As2 C24 C25 -31.1(4) . . . . ?
C3 As2 C24 C25 -144.0(4) . . . . ?
Pt1 As2 C24 C25 92.0(4) . . . . ?
C29 C24 C25 C26 -2.7(8) . . . . ?
As2 C24 C25 C26 -173.5(4) . . . . ?
C24 C25 C26 C27 0.3(8) . . . . ?
C25 C26 C27 C28 2.1(9) . . . . ?
C26 C27 C28 C29 -2.1(10) . . . . ?
C25 C24 C29 C28 2.7(8) . . . . ?
As2 C24 C29 C28 173.1(4) . . . . ?
C27 C28 C29 C24 -0.4(9) . . . . ?
As2 Pt1 Pt30 S89 60.85(4) . . . . ?
As5 Pt1 Pt30 S89 -179.06(4) . . . . ?
S88 Pt1 Pt30 S89 -116.96(5) . . . . ?
Pt59 Pt1 Pt30 S89 -57.91(4) . . . . ?
S89 Pt1 Pt30 As31 -51.08(4) . . . . ?
As2 Pt1 Pt30 As31 9.78(2) . . . . ?
As5 Pt1 Pt30 As31 129.86(2) . . . . ?
S88 Pt1 Pt30 As31 -168.04(4) . . . . ?
Pt59 Pt1 Pt30 As31 -108.99(2) . . . . ?
S89 Pt1 Pt30 S88 116.96(5) . . . . ?
As2 Pt1 Pt30 S88 177.82(4) . . . . ?
As5 Pt1 Pt30 S88 -62.09(4) . . . . ?
Pt59 Pt1 Pt30 S88 59.05(3) . . . . ?
S89 Pt1 Pt30 As34 -174.10(4) . . . . ?
As2 Pt1 Pt30 As34 -113.24(2) . . . . ?
As5 Pt1 Pt30 As34 6.85(3) . . . . ?
S88 Pt1 Pt30 As34 68.94(4) . . . . ?
Pt59 Pt1 Pt30 As34 127.99(2) . . . . ?
S89 Pt1 Pt30 Pt59 57.91(4) . . . . ?
As2 Pt1 Pt30 Pt59 118.768(18) . . . . ?
As5 Pt1 Pt30 Pt59 -121.14(2) . . . . ?
S88 Pt1 Pt30 Pt59 -59.05(3) . . . . ?
S89 Pt30 As31 C53 -33.92(17) . . . . ?
S88 Pt30 As31 C53 -97.9(2) . . . . ?
As34 Pt30 As31 C53 139.71(16) . . . . ?
Pt1 Pt30 As31 C53 2.35(17) . . . . ?
Pt59 Pt30 As31 C53 -77.71(16) . . . . ?
S89 Pt30 As31 C47 88.12(14) . . . . ?
S88 Pt30 As31 C47 24.1(2) . . . . ?
As34 Pt30 As31 C47 -98.24(13) . . . . ?
Pt1 Pt30 As31 C47 124.39(13) . . . . ?
Pt59 Pt30 As31 C47 44.33(13) . . . . ?
S89 Pt30 As31 C32 -158.47(16) . . . . ?
S88 Pt30 As31 C32 137.5(2) . . . . ?
As34 Pt30 As31 C32 15.16(15) . . . . ?
Pt1 Pt30 As31 C32 -122.20(15) . . . . ?
Pt59 Pt30 As31 C32 157.74(15) . . . . ?
C53 As31 C32 C33 -174.2(3) . . . . ?
C47 As31 C32 C33 74.8(3) . . . . ?
Pt30 As31 C32 C33 -40.8(3) . . . . ?
As31 C32 C33 As34 47.0(4) . . . . ?
C32 C33 As34 C35 -165.9(3) . . . . ?
C32 C33 As34 C41 86.5(3) . . . . ?
C32 C33 As34 Pt30 -34.1(3) . . . . ?
S89 Pt30 As34 C35 -134.3(3) . . . . ?
As31 Pt30 As34 C35 128.44(16) . . . . ?
S88 Pt30 As34 C35 -43.63(17) . . . . ?
Pt1 Pt30 As34 C35 -89.95(16) . . . . ?
Pt59 Pt30 As34 C35 -3.97(16) . . . . ?
S89 Pt30 As34 C41 -11.2(3) . . . . ?
As31 Pt30 As34 C41 -108.43(15) . . . . ?
S88 Pt30 As34 C41 79.49(15) . . . . ?
Pt1 Pt30 As34 C41 33.17(15) . . . . ?
Pt59 Pt30 As34 C41 119.16(15) . . . . ?
S89 Pt30 As34 C33 103.8(3) . . . . ?
As31 Pt30 As34 C33 6.58(16) . . . . ?
S88 Pt30 As34 C33 -165.50(16) . . . . ?
Pt1 Pt30 As34 C33 148.18(15) . . . . ?
Pt59 Pt30 As34 C33 -125.83(16) . . . . ?
C41 As34 C35 C40 -74.8(4) . . . . ?
C33 As34 C35 C40 176.2(4) . . . . ?
Pt30 As34 C35 C40 53.0(4) . . . . ?
C41 As34 C35 C36 105.7(4) . . . . ?
C33 As34 C35 C36 -3.3(4) . . . . ?
Pt30 As34 C35 C36 -126.5(4) . . . . ?
C40 C35 C36 C37 0.2(7) . . . . ?
As34 C35 C36 C37 179.7(4) . . . . ?
C35 C36 C37 C38 -0.7(8) . . . . ?
C36 C37 C38 C39 0.8(8) . . . . ?
C37 C38 C39 C40 -0.4(8) . . . . ?
C38 C39 C40 C35 -0.1(7) . . . . ?
C36 C35 C40 C39 0.2(7) . . . . ?
As34 C35 C40 C39 -179.3(4) . . . . ?
C35 As34 C41 C46 128.8(4) . . . . ?
C33 As34 C41 C46 -121.7(4) . . . . ?
Pt30 As34 C41 C46 -4.6(5) . . . . ?
C35 As34 C41 C42 -50.6(4) . . . . ?
C33 As34 C41 C42 58.9(4) . . . . ?
Pt30 As34 C41 C42 176.0(3) . . . . ?
C46 C41 C42 C43 1.7(8) . . . . ?
As34 C41 C42 C43 -178.9(4) . . . . ?
C41 C42 C43 C44 -1.7(9) . . . . ?
C42 C43 C44 C45 0.7(11) . . . . ?
C43 C44 C45 C46 0.4(11) . . . . ?
C42 C41 C46 C45 -0.6(9) . . . . ?
As34 C41 C46 C45 179.9(5) . . . . ?
C44 C45 C46 C41 -0.5(10) . . . . ?
C53 As31 C47 C48 142.8(3) . . . . ?
C32 As31 C47 C48 -104.7(4) . . . . ?
Pt30 As31 C47 C48 10.6(4) . . . . ?
C53 As31 C47 C52 -39.4(4) . . . . ?
C32 As31 C47 C52 73.0(4) . . . . ?
Pt30 As31 C47 C52 -171.6(3) . . . . ?
C52 C47 C48 C49 0.6(7) . . . . ?
As31 C47 C48 C49 178.4(3) . . . . ?
C47 C48 C49 C50 0.1(7) . . . . ?
C48 C49 C50 C51 -0.5(8) . . . . ?
C49 C50 C51 C52 0.2(8) . . . . ?
C48 C47 C52 C51 -0.9(7) . . . . ?
As31 C47 C52 C51 -178.7(4) . . . . ?
C50 C51 C52 C47 0.5(8) . . . . ?
C47 As31 C53 C54 -59.7(4) . . . . ?
C32 As31 C53 C54 -170.9(4) . . . . ?
Pt30 As31 C53 C54 64.0(4) . . . . ?
C47 As31 C53 C58 121.3(4) . . . . ?
C32 As31 C53 C58 10.1(4) . . . . ?
Pt30 As31 C53 C58 -115.0(3) . . . . ?
C58 C53 C54 C55 0.8(7) . . . . ?
As31 C53 C54 C55 -178.2(4) . . . . ?
C53 C54 C55 C56 0.1(7) . . . . ?
C54 C55 C56 C57 -1.1(8) . . . . ?
C55 C56 C57 C58 1.2(8) . . . . ?
C54 C53 C58 C57 -0.7(7) . . . . ?
As31 C53 C58 C57 178.3(4) . . . . ?
C56 C57 C58 C53 -0.3(8) . . . . ?
As31 Pt30 Pt59 S89 66.36(4) . . . . ?
S88 Pt30 Pt59 S89 -117.83(5) . . . . ?
As34 Pt30 Pt59 S89 -173.52(4) . . . . ?
Pt1 Pt30 Pt59 S89 -58.50(4) . . . . ?
S89 Pt30 Pt59 As60 -52.95(4) . . . . ?
As31 Pt30 Pt59 As60 13.41(2) . . . . ?
S88 Pt30 Pt59 As60 -170.78(4) . . . . ?
As34 Pt30 Pt59 As60 133.53(2) . . . . ?
Pt1 Pt30 Pt59 As60 -111.454(19) . . . . ?
S89 Pt30 Pt59 As63 -169.68(4) . . . . ?
As31 Pt30 Pt59 As63 -103.32(2) . . . . ?
S88 Pt30 Pt59 As63 72.49(4) . . . . ?
As34 Pt30 Pt59 As63 16.80(2) . . . . ?
Pt1 Pt30 Pt59 As63 131.815(19) . . . . ?
S89 Pt30 Pt59 S88 117.83(5) . . . . ?
As31 Pt30 Pt59 S88 -175.81(4) . . . . ?
As34 Pt30 Pt59 S88 -55.70(4) . . . . ?
Pt1 Pt30 Pt59 S88 59.32(3) . . . . ?
S89 Pt30 Pt59 Pt1 58.50(4) . . . . ?
As31 Pt30 Pt59 Pt1 124.867(16) . . . . ?
S88 Pt30 Pt59 Pt1 -59.32(3) . . . . ?
As34 Pt30 Pt59 Pt1 -115.02(2) . . . . ?
As2 Pt1 Pt59 S89 -48.74(4) . . . . ?
As5 Pt1 Pt59 S89 -174.25(4) . . . . ?
S88 Pt1 Pt59 S89 123.30(5) . . . . ?
Pt30 Pt1 Pt59 S89 61.54(4) . . . . ?
S89 Pt1 Pt59 As60 56.35(4) . . . . ?
As2 Pt1 Pt59 As60 7.61(2) . . . . ?
As5 Pt1 Pt59 As60 -117.90(2) . . . . ?
S88 Pt1 Pt59 As60 179.66(4) . . . . ?
Pt30 Pt1 Pt59 As60 117.89(2) . . . . ?
S89 Pt1 Pt59 As63 -171.81(4) . . . . ?
As2 Pt1 Pt59 As63 139.45(2) . . . . ?
As5 Pt1 Pt59 As63 13.94(3) . . . . ?
S88 Pt1 Pt59 As63 -48.50(4) . . . . ?
Pt30 Pt1 Pt59 As63 -110.27(2) . . . . ?
S89 Pt1 Pt59 S88 -123.30(5) . . . . ?
As2 Pt1 Pt59 S88 -172.04(4) . . . . ?
As5 Pt1 Pt59 S88 62.44(4) . . . . ?
Pt30 Pt1 Pt59 S88 -61.77(4) . . . . ?
S89 Pt1 Pt59 Pt30 -61.54(4) . . . . ?
As2 Pt1 Pt59 Pt30 -110.28(2) . . . . ?
As5 Pt1 Pt59 Pt30 124.21(2) . . . . ?
S88 Pt1 Pt59 Pt30 61.77(4) . . . . ?
S89 Pt59 As60 C76 -33.21(16) . . . . ?
As63 Pt59 As60 C76 137.68(16) . . . . ?
S88 Pt59 As60 C76 -69.0(3) . . . . ?
Pt30 Pt59 As60 C76 4.06(16) . . . . ?
Pt1 Pt59 As60 C76 -71.00(16) . . . . ?
S89 Pt59 As60 C82 95.06(16) . . . . ?
As63 Pt59 As60 C82 -94.05(16) . . . . ?
S88 Pt59 As60 C82 59.3(3) . . . . ?
Pt30 Pt59 As60 C82 132.33(15) . . . . ?
Pt1 Pt59 As60 C82 57.28(16) . . . . ?
S89 Pt59 As60 C61 -153.85(15) . . . . ?
As63 Pt59 As60 C61 17.04(15) . . . . ?
S88 Pt59 As60 C61 170.4(3) . . . . ?
Pt30 Pt59 As60 C61 -116.57(15) . . . . ?
Pt1 Pt59 As60 C61 168.37(15) . . . . ?
C76 As60 C61 C62 -173.2(3) . . . . ?
C82 As60 C61 C62 75.5(3) . . . . ?
Pt59 As60 C61 C62 -44.9(3) . . . . ?
As60 C61 C62 As63 51.3(4) . . . . ?
C61 C62 As63 C70 -167.0(3) . . . . ?
C61 C62 As63 C64 83.0(3) . . . . ?
C61 C62 As63 Pt59 -36.8(3) . . . . ?
S89 Pt59 As63 C70 -154.3(2) . . . . ?
As60 Pt59 As63 C70 127.32(15) . . . . ?
S88 Pt59 As63 C70 -49.33(16) . . . . ?
Pt30 Pt59 As63 C70 -97.08(15) . . . . ?
Pt1 Pt59 As63 C70 -14.75(16) . . . . ?
S89 Pt59 As63 C64 -29.0(2) . . . . ?
As60 Pt59 As63 C64 -107.32(14) . . . . ?
S88 Pt59 As63 C64 76.02(14) . . . . ?
Pt30 Pt59 As63 C64 28.27(14) . . . . ?
Pt1 Pt59 As63 C64 110.60(14) . . . . ?
S89 Pt59 As63 C62 84.9(2) . . . . ?
As60 Pt59 As63 C62 6.56(15) . . . . ?
S88 Pt59 As63 C62 -170.09(15) . . . . ?
Pt30 Pt59 As63 C62 142.16(15) . . . . ?
Pt1 Pt59 As63 C62 -135.52(15) . . . . ?
C70 As63 C64 C69 -90.1(4) . . . . ?
C62 As63 C64 C69 20.2(4) . . . . ?
Pt59 As63 C64 C69 136.4(4) . . . . ?
C70 As63 C64 C65 90.2(4) . . . . ?
C62 As63 C64 C65 -159.5(4) . . . . ?
Pt59 As63 C64 C65 -43.3(4) . . . . ?
C69 C64 C65 C66 0.5(7) . . . . ?
As63 C64 C65 C66 -179.8(4) . . . . ?
C64 C65 C66 C67 -1.4(8) . . . . ?
C65 C66 C67 C68 1.5(8) . . . . ?
C66 C67 C68 C69 -0.8(9) . . . . ?
C65 C64 C69 C68 0.3(7) . . . . ?
As63 C64 C69 C68 -179.4(4) . . . . ?
C67 C68 C69 C64 -0.1(8) . . . . ?
C64 As63 C70 C75 -123.4(4) . . . . ?
C62 As63 C70 C75 127.5(4) . . . . ?
Pt59 As63 C70 C75 5.6(4) . . . . ?
C64 As63 C70 C71 58.7(4) . . . . ?
C62 As63 C70 C71 -50.5(4) . . . . ?
Pt59 As63 C70 C71 -172.4(3) . . . . ?
C75 C70 C71 C72 1.2(7) . . . . ?
As63 C70 C71 C72 179.1(4) . . . . ?
C70 C71 C72 C73 -1.8(8) . . . . ?
C71 C72 C73 C74 1.8(8) . . . . ?
C72 C73 C74 C75 -1.2(8) . . . . ?
C73 C74 C75 C70 0.7(7) . . . . ?
C71 C70 C75 C74 -0.7(7) . . . . ?
As63 C70 C75 C74 -178.6(4) . . . . ?
C82 As60 C76 C81 -29.1(4) . . . . ?
C61 As60 C76 C81 -136.1(4) . . . . ?
Pt59 As60 C76 C81 102.8(4) . . . . ?
C82 As60 C76 C77 152.9(4) . . . . ?
C61 As60 C76 C77 45.9(4) . . . . ?
Pt59 As60 C76 C77 -75.2(4) . . . . ?
C81 C76 C77 C78 1.1(7) . . . . ?
As60 C76 C77 C78 179.2(4) . . . . ?
C76 C77 C78 C79 -0.4(8) . . . . ?
C77 C78 C79 C80 -0.1(8) . . . . ?
C78 C79 C80 C81 -0.2(8) . . . . ?
C77 C76 C81 C80 -1.4(7) . . . . ?
As60 C76 C81 C80 -179.3(4) . . . . ?
C79 C80 C81 C76 0.9(8) . . . . ?
C76 As60 C82 C87 143.7(5) . . . . ?
C61 As60 C82 C87 -105.3(5) . . . . ?
Pt59 As60 C82 C87 9.6(5) . . . . ?
C76 As60 C82 C83 -42.2(5) . . . . ?
C61 As60 C82 C83 68.8(4) . . . . ?
Pt59 As60 C82 C83 -176.3(4) . . . . ?
C87 C82 C83 C84 -0.3(8) . . . . ?
As60 C82 C83 C84 -174.5(4) . . . . ?
C82 C83 C84 C85 1.0(9) . . . . ?
C83 C84 C85 C86 -0.2(11) . . . . ?
C84 C85 C86 C87 -1.4(12) . . . . ?
C85 C86 C87 C82 2.1(12) . . . . ?
C83 C82 C87 C86 -1.3(10) . . . . ?
As60 C82 C87 C86 172.9(6) . . . . ?
S89 Pt30 S88 Pt1 43.12(3) . . . . ?
As31 Pt30 S88 Pt1 108.19(16) . . . . ?
As34 Pt30 S88 Pt1 -130.40(2) . . . . ?
Pt59 Pt30 S88 Pt1 85.49(3) . . . . ?
S89 Pt30 S88 Pt59 -42.37(3) . . . . ?
As31 Pt30 S88 Pt59 22.71(18) . . . . ?
As34 Pt30 S88 Pt59 144.11(2) . . . . ?
Pt1 Pt30 S88 Pt59 -85.49(3) . . . . ?
S89 Pt1 S88 Pt30 -43.30(3) . . . . ?
As2 Pt1 S88 Pt30 -15.6(3) . . . . ?
As5 Pt1 S88 Pt30 140.13(2) . . . . ?
Pt59 Pt1 S88 Pt30 -81.59(3) . . . . ?
S89 Pt1 S88 Pt59 38.30(3) . . . . ?
As2 Pt1 S88 Pt59 66.0(3) . . . . ?
As5 Pt1 S88 Pt59 -138.28(2) . . . . ?
Pt30 Pt1 S88 Pt59 81.59(3) . . . . ?
S89 Pt59 S88 Pt30 42.71(3) . . . . ?
As60 Pt59 S88 Pt30 78.9(2) . . . . ?
As63 Pt59 S88 Pt30 -128.21(2) . . . . ?
Pt1 Pt59 S88 Pt30 81.15(3) . . . . ?
S89 Pt59 S88 Pt1 -38.44(3) . . . . ?
As60 Pt59 S88 Pt1 -2.2(2) . . . . ?
As63 Pt59 S88 Pt1 150.64(2) . . . . ?
Pt30 Pt59 S88 Pt1 -81.15(3) . . . . ?
As60 Pt59 S89 Pt1 -136.75(3) . . . . ?
As63 Pt59 S89 Pt1 145.51(16) . . . . ?
S88 Pt59 S89 Pt1 38.92(3) . . . . ?
Pt30 Pt59 S89 Pt1 81.84(3) . . . . ?
As60 Pt59 S89 Pt30 141.40(2) . . . . ?
As63 Pt59 S89 Pt30 63.66(18) . . . . ?
S88 Pt59 S89 Pt30 -42.92(3) . . . . ?
Pt1 Pt59 S89 Pt30 -81.84(3) . . . . ?
As2 Pt1 S89 Pt59 144.19(3) . . . . ?
As5 Pt1 S89 Pt59 88.4(4) . . . . ?
S88 Pt1 S89 Pt59 -38.95(3) . . . . ?
Pt30 Pt1 S89 Pt59 -82.49(3) . . . . ?
As2 Pt1 S89 Pt30 -133.32(3) . . . . ?
As5 Pt1 S89 Pt30 170.9(4) . . . . ?
S88 Pt1 S89 Pt30 43.53(3) . . . . ?
Pt59 Pt1 S89 Pt30 82.49(3) . . . . ?
As31 Pt30 S89 Pt59 -128.48(3) . . . . ?
S88 Pt30 S89 Pt59 43.09(3) . . . . ?
As34 Pt30 S89 Pt59 134.8(2) . . . . ?
Pt1 Pt30 S89 Pt59 86.76(3) . . . . ?
As31 Pt30 S89 Pt1 144.77(2) . . . . ?
S88 Pt30 S89 Pt1 -43.67(3) . . . . ?
As34 Pt30 S89 Pt1 48.1(3) . . . . ?
Pt59 Pt30 S89 Pt1 -86.76(3) . . . . ?
C103 B90 C91 C96 102.5(5) . . . . ?
C109 B90 C91 C96 -135.7(5) . . . . ?
C97 B90 C91 C96 -15.1(6) . . . . ?
C103 B90 C91 C92 -80.4(5) . . . . ?
C109 B90 C91 C92 41.4(5) . . . . ?
C97 B90 C91 C92 162.0(4) . . . . ?
C96 C91 C92 C93 0.0(7) . . . . ?
B90 C91 C92 C93 -177.4(4) . . . . ?
C91 C92 C93 C94 1.0(7) . . . . ?
C92 C93 C94 C95 -1.5(7) . . . . ?
C93 C94 C95 C96 0.9(8) . . . . ?
C92 C91 C96 C95 -0.6(7) . . . . ?
B90 C91 C96 C95 176.6(4) . . . . ?
C94 C95 C96 C91 0.2(8) . . . . ?
C103 B90 C97 C98 136.7(5) . . . . ?
C109 B90 C97 C98 15.8(7) . . . . ?
C91 B90 C97 C98 -102.2(6) . . . . ?
C103 B90 C97 C102 -44.0(6) . . . . ?
C109 B90 C97 C102 -164.9(5) . . . . ?
C91 B90 C97 C102 77.1(6) . . . . ?
C102 C97 C98 C99 2.1(8) . . . . ?
B90 C97 C98 C99 -178.5(5) . . . . ?
C97 C98 C99 C100 -1.0(10) . . . . ?
C98 C99 C100 C101 -0.9(10) . . . . ?
C99 C100 C101 C102 1.4(11) . . . . ?
C100 C101 C102 C97 -0.2(11) . . . . ?
C98 C97 C102 C101 -1.6(9) . . . . ?
B90 C97 C102 C101 179.0(6) . . . . ?
C109 B90 C103 C108 -121.8(5) . . . . ?
C91 B90 C103 C108 -2.7(6) . . . . ?
C97 B90 C103 C108 117.7(5) . . . . ?
C109 B90 C103 C104 60.6(5) . . . . ?
C91 B90 C103 C104 179.7(4) . . . . ?
C97 B90 C103 C104 -59.9(6) . . . . ?
C108 C103 C104 C105 1.8(7) . . . . ?
B90 C103 C104 C105 179.6(4) . . . . ?
C103 C104 C105 C106 -1.3(7) . . . . ?
C104 C105 C106 C107 0.1(7) . . . . ?
C105 C106 C107 C108 0.4(7) . . . . ?
C106 C107 C108 C103 0.2(7) . . . . ?
C104 C103 C108 C107 -1.2(6) . . . . ?
B90 C103 C108 C107 -178.9(4) . . . . ?
C103 B90 C109 C110 -9.4(7) . . . . ?
C91 B90 C109 C110 -131.5(5) . . . . ?
C97 B90 C109 C110 108.2(5) . . . . ?
C103 B90 C109 C114 169.0(4) . . . . ?
C91 B90 C109 C114 46.9(5) . . . . ?
C97 B90 C109 C114 -73.4(5) . . . . ?
C114 C109 C110 C111 1.6(7) . . . . ?
B90 C109 C110 C111 -180.0(5) . . . . ?
C109 C110 C111 C112 -1.1(8) . . . . ?
C110 C111 C112 C113 -0.2(8) . . . . ?
C111 C112 C113 C114 1.0(8) . . . . ?
C112 C113 C114 C109 -0.5(8) . . . . ?
C110 C109 C114 C113 -0.8(7) . . . . ?
B90 C109 C114 C113 -179.4(5) . . . . ?
C122 B115 C116 C117 166.8(4) . . . . ?
C128 B115 C116 C117 47.1(5) . . . . ?
C134 B115 C116 C117 -71.2(5) . . . . ?
C122 B115 C116 C121 -13.5(6) . . . . ?
C128 B115 C116 C121 -133.3(4) . . . . ?
C134 B115 C116 C121 108.5(5) . . . . ?
C121 C116 C117 C118 -3.6(7) . . . . ?
B115 C116 C117 C118 176.1(4) . . . . ?
C116 C117 C118 C119 2.1(7) . . . . ?
C117 C118 C119 C120 0.0(7) . . . . ?
C118 C119 C120 C121 -0.4(7) . . . . ?
C119 C120 C121 C116 -1.3(7) . . . . ?
C117 C116 C121 C120 3.2(7) . . . . ?
B115 C116 C121 C120 -176.5(4) . . . . ?
C128 B115 C122 C127 10.7(6) . . . . ?
C134 B115 C122 C127 130.1(5) . . . . ?
C116 B115 C122 C127 -107.9(5) . . . . ?
C128 B115 C122 C123 -171.6(4) . . . . ?
C134 B115 C122 C123 -52.2(5) . . . . ?
C116 B115 C122 C123 69.8(5) . . . . ?
C127 C122 C123 C124 2.7(7) . . . . ?
B115 C122 C123 C124 -175.2(4) . . . . ?
C122 C123 C124 C125 -1.6(8) . . . . ?
C123 C124 C125 C126 -0.2(7) . . . . ?
C124 C125 C126 C127 0.6(7) . . . . ?
C125 C126 C127 C122 0.7(8) . . . . ?
C123 C122 C127 C126 -2.3(7) . . . . ?
B115 C122 C127 C126 175.6(4) . . . . ?
C122 B115 C128 C129 -72.5(5) . . . . ?
C134 B115 C128 C129 166.4(4) . . . . ?
C116 B115 C128 C129 46.4(5) . . . . ?
C122 B115 C128 C133 104.3(5) . . . . ?
C134 B115 C128 C133 -16.8(6) . . . . ?
C116 B115 C128 C133 -136.8(4) . . . . ?
C133 C128 C129 C130 -0.4(7) . . . . ?
B115 C128 C129 C130 176.7(4) . . . . ?
C128 C129 C130 C131 0.1(8) . . . . ?
C129 C130 C131 C132 0.4(8) . . . . ?
C130 C131 C132 C133 -0.5(8) . . . . ?
C131 C132 C133 C128 0.2(8) . . . . ?
C129 C128 C133 C132 0.3(7) . . . . ?
B115 C128 C133 C132 -176.7(4) . . . . ?
C122 B115 C134 C135 -19.0(6) . . . . ?
C128 B115 C134 C135 101.7(5) . . . . ?
C116 B115 C134 C135 -139.9(5) . . . . ?
C122 B115 C134 C139 167.9(4) . . . . ?
C128 B115 C134 C139 -71.4(5) . . . . ?
C116 B115 C134 C139 47.0(6) . . . . ?
C139 C134 C135 C136 0.7(7) . . . . ?
B115 C134 C135 C136 -172.9(5) . . . . ?
C134 C135 C136 C137 -0.4(9) . . . . ?
C135 C136 C137 C138 0.7(9) . . . . ?
C136 C137 C138 C139 -1.3(9) . . . . ?
C137 C138 C139 C134 1.7(9) . . . . ?
C135 C134 C139 C138 -1.3(8) . . . . ?
B115 C134 C139 C138 172.4(5) . . . . ?
