#------------------------------------------------------------------------------
#$Date: 2017-03-05 21:59:09 +0200 (Sun, 05 Mar 2017) $
#$Revision: 193981 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/00/91/7009165.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7009165
loop_
_publ_author_name
'Zhang, Jian-Jun'
'Luo, Qin-Hui'
'Long, De-Liang'
'Chen, Jiu-Tong'
'Li, Feng-Mei'
'Liu, An-Dong'
_publ_section_title
;
 A superoxide dismutase mimic with high activity: crystal structure,
 solution equilibrium and pulse radiolysis
;
_journal_issue                   12
_journal_name_full
'Journal of the Chemical Society, Dalton Transactions'
_journal_page_first              1893
_journal_paper_doi               10.1039/a909018e
_journal_year                    2000
_chemical_formula_sum            'C18 H54 Cu2 N8 O14'
_chemical_formula_weight         733.77
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL
_cell_angle_alpha                86.308(2)
_cell_angle_beta                 86.622(2)
_cell_angle_gamma                78.476(2)
_cell_formula_units_Z            1
_cell_length_a                   8.4837(2)
_cell_length_b                   8.7611(3)
_cell_length_c                   11.12710(10)
_cell_measurement_reflns_used    2930
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      25.05
_cell_measurement_theta_min      1.84
_cell_volume                     807.79(3)
_computing_cell_refinement       'Siemens SMART & SAINT'
_computing_data_collection       'Siemens SMART'
_computing_data_reduction        'Siemens XPREP'
_computing_molecular_graphics    'Siemens SHELXTL'
_computing_publication_material  'Siemens SHELXTL'
_computing_structure_refinement  'Siemens SHELXTL'
_computing_structure_solution    'Siemens SHELXTL'
_diffrn_ambient_temperature      293(2)
_diffrn_measurement_device       'Siemens SMART CCD'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0211
_diffrn_reflns_av_sigmaI/netI    0.0452
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_k_max       8
_diffrn_reflns_limit_k_min       -10
_diffrn_reflns_limit_l_max       12
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_number            4045
_diffrn_reflns_theta_max         25.05
_diffrn_reflns_theta_min         1.84
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  .
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    1.388
_exptl_absorpt_correction_T_max  0.9010
_exptl_absorpt_correction_T_min  0.6404
_exptl_absorpt_correction_type   'empirical (SADABS: Sheldrick, 1996)'
_exptl_crystal_colour            blue
_exptl_crystal_density_diffrn    1.508
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    .
_exptl_crystal_description       block
_exptl_crystal_F_000             388
_exptl_crystal_size_max          0.45
_exptl_crystal_size_mid          0.30
_exptl_crystal_size_min          0.25
_refine_diff_density_max         0.810
_refine_diff_density_min         -0.774
_refine_diff_density_rms         0.079
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_all   1.053
_refine_ls_goodness_of_fit_obs   1.084
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     230
_refine_ls_number_reflns         2773
_refine_ls_number_restraints     10
_refine_ls_restrained_S_all      1.051
_refine_ls_restrained_S_obs      1.082
_refine_ls_R_factor_all          0.0566
_refine_ls_R_factor_obs          0.0475
_refine_ls_shift/esd_max         0.000
_refine_ls_shift/esd_mean        0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0487P)²+1.3200P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_all         0.1175
_refine_ls_wR_factor_obs         0.1121
_reflns_number_observed          2409
_reflns_number_total             2773
_reflns_observed_criterion       >2sigma(I)
_cod_data_source_file            a909018e.txt
_cod_data_source_block           1
_cod_depositor_comments
;
The following automatic conversions were performed:

'_refine_ls_weighting_scheme' value 'calc
w=1/[\s^2^(Fo^2^)+(0.0487P)^2^+1.3200P] where P=(Fo^2^+2Fc^2^)/3' was
changed to 'calc'. New tag '_refine_ls_weighting_details' was
created. The value of the new tag was set to
'w=1/[\s^2^(Fo^2^)+(0.0487P)^2^+1.3200P] where P=(Fo^2^+2Fc^2^)/3'.

Automatic conversion script
Id: cif_fix_values 3143 2015-03-26 13:38:13Z robertas 

The following automatic conversions were performed:
data name '_geom_bond_atom_site_label_D' replaced with
'_geom_hbond_atom_site_label_D' as specified in the replacement file
'/home/antanas/src/cod-tools/trunk/data/replacement-values/replacement_tags.lst'.

data
name '_geom_bond_atom_site_label_H' replaced with
'_geom_hbond_atom_site_label_H' as specified in the replacement file
'/home/antanas/src/cod-tools/trunk/data/replacement-values/replacement_tags.lst'.

data
name '_geom_contact_atom_site_label_a' replaced with
'_geom_hbond_atom_site_label_A' as specified in the replacement file
'/home/antanas/src/cod-tools/trunk/data/replacement-values/replacement_tags.lst'.

data
name '_geom_bond_distance_DH' replaced with '_geom_hbond_distance_DH'
as specified in the replacement file
'/home/antanas/src/cod-tools/trunk/data/replacement-values/replacement_tags.lst'.

data
name '_geom_contact_distance_DA' replaced with
'_geom_hbond_distance_DA' as specified in the replacement file
'/home/antanas/src/cod-tools/trunk/data/replacement-values/replacement_tags.lst'.

data
name '_geom_angle_DHA' replaced with '_geom_hbond_angle_DHA' as
specified in the replacement file
'/home/antanas/src/cod-tools/trunk/data/replacement-values/replacement_tags.lst'.

data
name '_geom_contact_site_symmetry_A' replaced with
'_geom_hbond_site_symmetry_A' as specified in the replacement file
'/home/antanas/src/cod-tools/trunk/data/replacement-values/replacement_tags.lst'.

Automatic conversion script
Id: cif_correct_tags 5005 2017-03-03 11:38:54Z antanas 
;
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7009165
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_thermal_displace_type
_atom_site_occupancy
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_group
Cu Cu 0.27992(6) 0.49409(6) 0.21868(4) 0.0330(2) Uani 1 d . .
O1 O 0.0816(4) 0.1826(3) 0.0511(2) 0.0432(7) Uani 1 d . .
O2 O 0.2480(3) 0.5855(3) -0.1442(2) 0.0407(7) Uani 1 d . .
O3 O 0.0655(4) 0.6931(4) 0.3280(3) 0.0532(8) Uani 1 d . .
O4 O 0.2857(6) 0.6988(5) 0.5042(3) 0.0735(11) Uani 1 d . .
O5 O 0.1900(5) 0.4632(5) -0.3514(3) 0.0636(10) Uani 1 d . .
O6 O 0.3003(5) 0.8428(5) -0.2825(3) 0.0609(9) Uani 1 d . .
O7 O 0.0447(4) 0.0628(4) -0.1637(3) 0.0508(8) Uani 1 d . .
N1 N 0.1640(4) 0.3343(4) 0.1834(3) 0.0345(7) Uani 1 d . .
N2 N 0.3332(5) 0.3572(5) 0.3708(3) 0.0537(10) Uani 1 d . .
H2A H 0.4371(5) 0.3082(5) 0.3659(3) 0.064 Uiso 1 calc R .
H2D H 0.3186(5) 0.4166(5) 0.4350(3) 0.064 Uiso 1 calc R .
N3 N 0.2648(4) 0.5999(4) 0.0589(3) 0.0336(7) Uani 1 d . .
N4 N 0.4347(4) 0.6318(5) 0.2442(3) 0.0460(9) Uani 1 d . .
H4A H 0.4216(4) 0.6641(5) 0.3199(3) 0.055 Uiso 1 calc R .
H4E H 0.5365(4) 0.5790(5) 0.2332(3) 0.055 Uiso 1 calc R .
C C 0.0836(4) 0.4471(4) -0.0152(3) 0.0299(8) Uani 1 d . .
H0A H 0.0748(4) 0.4028(4) -0.0926(3) 0.036 Uiso 1 calc R .
C1 C 0.1145(4) 0.3100(4) 0.0782(3) 0.0313(8) Uani 1 d . .
C2 C 0.1757(6) 0.2056(5) 0.2749(4) 0.0428(10) Uani 1 d . .
H2B H 0.0704(6) 0.1798(5) 0.2921(4) 0.051 Uiso 1 calc R .
H2C H 0.2477(6) 0.1142(5) 0.2448(4) 0.051 Uiso 1 calc R .
C3 C 0.2363(12) 0.2493(9) 0.3850(6) 0.122(4) Uani 1 d . .
H3A H 0.1381(12) 0.3122(9) 0.4205(6) 0.147 Uiso 1 calc R .
C4 C 0.2723(8) 0.1185(6) 0.4814(5) 0.074(2) Uani 1 d . .
H4B H 0.3115(8) 0.1570(6) 0.5504(5) 0.112 Uiso 1 calc R .
H4C H 0.3525(8) 0.0352(6) 0.4503(5) 0.112 Uiso 1 calc R .
H4D H 0.1757(8) 0.0806(6) 0.5045(5) 0.112 Uiso 1 calc R .
C5 C 0.2103(4) 0.5497(4) -0.0355(3) 0.0310(8) Uani 1 d . .
C6 C 0.3699(5) 0.7135(5) 0.0378(4) 0.0406(10) Uani 1 d . .
H6A H 0.3174(5) 0.8024(5) -0.0115(4) 0.049 Uiso 1 calc R .
H6B H 0.4695(5) 0.6664(5) -0.0041(4) 0.049 Uiso 1 calc R .
C7 C 0.4048(6) 0.7653(6) 0.1584(4) 0.0549(12) Uani 1 d . .
H7A H 0.3061(6) 0.8339(6) 0.1877(4) 0.066 Uiso 1 calc R .
C8 C 0.5372(7) 0.8614(6) 0.1499(5) 0.0638(14) Uani 1 d . .
H8A H 0.5545(7) 0.8913(6) 0.2288(5) 0.096 Uiso 1 calc R .
H8B H 0.5051(7) 0.9533(6) 0.0983(5) 0.096 Uiso 1 calc R .
H8C H 0.6350(7) 0.8002(6) 0.1172(5) 0.096 Uiso 1 calc R .
H7B H 0.0509(60) 0.1070(54) -0.1013(32) 0.059(16) Uiso 1 d . .
H7C H -0.0006(53) -0.0105(44) -0.1357(40) 0.050(14) Uiso 1 d . .
H6C H 0.2803(63) 0.7710(49) -0.2342(41) 0.066(17) Uiso 1 d . .
H3C H 0.0335(72) 0.7825(43) 0.2961(53) 0.087(22) Uiso 1 d . .
H4F H 0.2838(71) 0.7629(56) 0.5562(42) 0.073(19) Uiso 1 d . .
H6D H 0.2348(49) 0.9176(45) -0.2578(43) 0.049(15) Uiso 1 d . .
H5A H 0.1127(87) 0.4137(107) -0.3503(91) 0.183(45) Uiso 1 d . .
H4G H 0.2508(113) 0.6248(79) 0.5400(78) 0.164(41) Uiso 1 d . .
H3D H 0.1113(86) 0.7142(92) 0.3873(49) 0.126(30) Uiso 1 d . .
H5B H 0.1905(80) 0.5159(68) -0.2906(41) 0.096(22) Uiso 1 d . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Cu N3 95.74(12) . . ?
N1 Cu N4 169.6(2) . . ?
N3 Cu N4 84.13(13) . . ?
N1 Cu N2 83.42(13) . . ?
N3 Cu N2 169.0(2) . . ?
N4 Cu N2 94.72(14) . . ?
N1 Cu O3 103.34(13) . . ?
N3 Cu O3 97.36(13) . . ?
N4 Cu O3 86.99(14) . . ?
N2 Cu O3 93.46(15) . . ?
C1 O1 O7 132.9(2) . . ?
C5 O2 O5 130.3(2) . . ?
C5 O2 O6 138.7(3) . . ?
O5 O2 O6 87.28(13) . . ?
Cu O3 O7 107.97(14) . 2_565 ?
Cu O3 O4 88.83(15) . . ?
O7 O3 O4 125.3(2) 2_565 . ?
Cu O3 H3C 120.4(44) . . ?
O7 O3 H3C 17.1(44) 2_565 . ?
O4 O3 H3C 111.2(44) . . ?
Cu O3 H3D 104.4(56) . . ?
O7 O3 H3D 117.1(56) 2_565 . ?
O4 O3 H3D 15.6(55) . . ?
H3C O3 H3D 101.1(66) . . ?
O5 O4 O6 85.78(15) 1_556 1_556 ?
O5 O4 O3 94.3(2) 1_556 . ?
O6 O4 O3 139.0(3) 1_556 . ?
O5 O4 N4 119.9(2) 1_556 . ?
O6 O4 N4 147.2(2) 1_556 . ?
O3 O4 N4 64.26(12) . . ?
O5 O4 H4F 98.8(41) 1_556 . ?
O6 O4 H4F 15.2(41) 1_556 . ?
O3 O4 H4F 129.5(42) . . ?
N4 O4 H4F 139.1(41) . . ?
O5 O4 H4G 7.6(67) 1_556 . ?
O6 O4 H4G 92.6(67) 1_556 . ?
O3 O4 H4G 87.0(69) . . ?
N4 O4 H4G 114.6(68) . . ?
H4F O4 H4G 105.1(74) . . ?
O2 O5 O3 113.5(2) . 2_565 ?
O2 O5 H5A 118.1(68) . . ?
O3 O5 H5A 4.7(68) 2_565 . ?
O2 O5 H5B 12.3(46) . . ?
O3 O5 H5B 110.1(45) 2_565 . ?
H5A O5 H5B 114.6(78) . . ?
O2 O6 O7 95.57(14) . 1_565 ?
O2 O6 H6C 6.4(37) . . ?
O7 O6 H6C 89.9(38) 1_565 . ?
O2 O6 H6D 106.7(35) . . ?
O7 O6 H6D 11.1(35) 1_565 . ?
H6C O6 H6D 101.0(50) . . ?
O1 O7 O1 92.49(12) . 2 ?
O1 O7 H7B 5.4(35) . . ?
O1 O7 H7B 95.7(35) 2 . ?
O1 O7 H7C 97.4(32) . . ?
O1 O7 H7C 6.2(31) 2 . ?
H7B O7 H7C 100.2(46) . . ?
C1 N1 C2 116.8(3) . . ?
C1 N1 Cu 126.7(3) . . ?
C2 N1 Cu 114.0(2) . . ?
C3 N2 Cu 110.0(3) . . ?
C3 N2 H2A 109.7(5) . . ?
Cu N2 H2A 109.66(12) . . ?
C3 N2 H2D 109.7(4) . . ?
Cu N2 H2D 109.66(12) . . ?
H2A N2 H2D 108.2 . . ?
C5 N3 C6 117.5(3) . . ?
C5 N3 Cu 125.7(3) . . ?
C6 N3 Cu 113.7(2) . . ?
C7 N4 Cu 108.5(3) . . ?
C7 N4 O4 114.3(3) . . ?
Cu N4 O4 91.43(15) . . ?
C7 N4 O2 105.5(3) . 2_665 ?
Cu N4 O2 98.30(15) . 2_665 ?
O4 N4 O2 133.4(2) . 2_665 ?
C7 N4 H4A 110.0(2) . . ?
Cu N4 H4A 109.99(10) . . ?
O4 N4 H4A 18.99(10) . . ?
O2 N4 H4A 123.38(8) 2_665 . ?
C7 N4 H4E 110.0(3) . . ?
Cu N4 H4E 109.99(12) . . ?
O4 N4 H4E 120.57(11) . . ?
O2 N4 H4E 15.72(8) 2_665 . ?
H4A N4 H4E 108.4 . . ?
C1 C C5 118.1(3) . . ?
C1 C C 109.3(4) . 2_565 ?
C5 C C 109.0(4) . 2_565 ?
C1 C H0A 106.6(2) . . ?
C5 C H0A 106.6(2) . . ?
C C H0A 106.6(2) 2_565 . ?
O1 C1 N1 124.1(3) . . ?
O1 C1 C 117.5(3) . . ?
N1 C1 C 118.2(3) . . ?
C3 C2 N1 110.1(4) . . ?
C3 C2 H2B 109.6(4) . . ?
N1 C2 H2B 109.6(2) . . ?
C3 C2 H2C 109.6(4) . . ?
N1 C2 H2C 109.6(2) . . ?
H2B C2 H2C 108.2 . . ?
N2 C3 C2 116.0(5) . . ?
N2 C3 C4 119.1(5) . . ?
C2 C3 C4 114.9(5) . . ?
N2 C3 H3A 100.7(5) . . ?
C2 C3 H3A 100.7(5) . . ?
C4 C3 H3A 100.7(5) . . ?
C3 C4 H4B 109.5(3) . . ?
C3 C4 H4C 109.5(5) . . ?
H4B C4 H4C 109.5 . . ?
C3 C4 H4D 109.5(4) . . ?
H4B C4 H4D 109.5 . . ?
H4C C4 H4D 109.5 . . ?
O2 C5 N3 125.1(3) . . ?
O2 C5 C 116.6(3) . . ?
N3 C5 C 118.2(3) . . ?
N3 C6 C7 108.1(3) . . ?
N3 C6 H6A 110.1(2) . . ?
C7 C6 H6A 110.1(3) . . ?
N3 C6 H6B 110.1(2) . . ?
C7 C6 H6B 110.1(3) . . ?
H6A C6 H6B 108.4 . . ?
N4 C7 C6 109.8(4) . . ?
N4 C7 C8 113.6(4) . . ?
C6 C7 C8 112.9(4) . . ?
N4 C7 H7A 106.7(3) . . ?
C6 C7 H7A 106.7(3) . . ?
C8 C7 H7A 106.7(3) . . ?
C7 C8 H8A 109.5(3) . . ?
C7 C8 H8B 109.5(3) . . ?
H8A C8 H8B 109.5 . . ?
C7 C8 H8C 109.5(3) . . ?
H8A C8 H8C 109.5 . . ?
H8B C8 H8C 109.5 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Cu N1 1.936(3) . ?
Cu N3 1.950(3) . ?
Cu N4 1.996(3) . ?
Cu N2 2.029(4) . ?
Cu O3 2.564(4) . ?
Cu Cu 5.9655(9) 2_665 ?
Cu Cu 6.9798(9) 2_565 ?
Cu Cu 7.4926(9) 2_666 ?
O1 C1 1.261(4) . ?
O1 O7 2.731(4) . ?
O2 C5 1.269(4) . ?
O2 O5 2.714(4) . ?
O2 O6 2.743(4) . ?
O3 O7 2.773(5) 2_565 ?
O3 O4 2.796(6) . ?
O3 H3C 0.84(3) . ?
O3 H3D 0.83(3) . ?
O4 O5 2.755(6) 1_556 ?
O4 O6 2.779(5) 1_556 ?
O4 N4 3.132(5) . ?
O4 H4F 0.83(3) . ?
O4 H4G 0.83(3) . ?
O5 O3 2.778(5) 2_565 ?
O5 H5A 0.86(3) . ?
O5 H5B 0.84(3) . ?
O6 O7 2.913(5) 1_565 ?
O6 H6C 0.84(3) . ?
O6 H6D 0.82(3) . ?
O7 O1 2.785(4) 2 ?
O7 H7B 0.83(3) . ?
O7 H7C 0.85(3) . ?
N1 C1 1.311(5) . ?
N1 C2 1.462(5) . ?
N2 C3 1.367(7) . ?
N2 H2A 0.90 . ?
N2 H2D 0.90 . ?
N3 C5 1.308(5) . ?
N3 C6 1.463(5) . ?
N4 C7 1.452(6) . ?
N4 O2 3.159(5) 2_665 ?
N4 H4A 0.90 . ?
N4 H4E 0.90 . ?
C C1 1.529(5) . ?
C C5 1.531(5) . ?
C C 1.563(7) 2_565 ?
C H0A 0.98 . ?
C2 C3 1.458(7) . ?
C2 H2B 0.97 . ?
C2 H2C 0.97 . ?
C3 C4 1.515(7) . ?
C3 H3A 0.98 . ?
C4 H4B 0.96 . ?
C4 H4C 0.96 . ?
C4 H4D 0.96 . ?
C6 C7 1.508(6) . ?
C6 H6A 0.97 . ?
C6 H6B 0.97 . ?
C7 C8 1.528(6) . ?
C7 H7A 0.98 . ?
C8 H8A 0.96 . ?
C8 H8B 0.96 . ?
C8 H8C 0.96 . ?
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
O3 H3D O4 0.83 2.796(6) 158 ?
O3 H3C O7 0.84 2.773(5) 156 2_565
O4 H4G O5 0.83 2.755(6) 169 1_556
O4 H4F O6 0.83 2.779(5) 159 1_556
O5 H5B O2 0.84 2.714(4) 162 ?
O5 H5A O3 0.86 2.778(5) 173 2_565
O6 H6C O2 0.84 2.743(4) 171 ?
O6 H6D O7 0.82 2.913(5) 165 1_565
O7 H7B O1 0.83 2.731(4) 172 ?
O7 H7C O1 0.85 2.785(4) 171 2_555
N4 H4E O2 0.90 3.159(5) 158 2_665
N4 H4A O4 0.90 3.132(5) 154 ?
