#------------------------------------------------------------------------------
#$Date: 2016-03-25 11:40:51 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179802 $
#$URL: svn://www.crystallography.net/cod/cif/7/00/98/7009816.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7009816
loop_
_publ_author_name
'Durran, Sean E.'
'Smith, Martin B.'
'Slawin, Alexandra M. Z.'
'Steed, Jonathan W.'
_publ_section_title
;
 The synthesis and co-ordination chemistry of new functionalised
 pyridylphosphines derived from Ph2PCH2OH †
;
_journal_issue                   16
_journal_name_full
'Journal of the Chemical Society, Dalton Transactions'
_journal_page_first              2771
_journal_paper_doi               10.1039/b003759l
_journal_year                    2000
_chemical_formula_sum            'C51 H57 Cl7 N2 O P2 Rh2'
_chemical_formula_weight         1229.90
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                99.178(3)
_cell_angle_beta                 91.764(3)
_cell_angle_gamma                92.281(3)
_cell_formula_units_Z            2
_cell_length_a                   9.6851(3)
_cell_length_b                   16.4272(7)
_cell_length_c                   16.6831(8)
_cell_measurement_temperature    293(2)
_cell_volume                     2616.35(19)
_computing_cell_refinement       DENZO-SMN
_computing_data_collection       'Nonius Collect'
_computing_data_reduction        DENZO-SMN
_computing_molecular_graphics    'XSeed (Barbour, 1999)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.987
_diffrn_measured_fraction_theta_max 0.987
_diffrn_measurement_device_type  KappaCCD
_diffrn_measurement_method       '1.9o phi + omega frames'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0388
_diffrn_reflns_av_sigmaI/netI    0.0607
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            19114
_diffrn_reflns_theta_full        27.50
_diffrn_reflns_theta_max         27.50
_diffrn_reflns_theta_min         2.51
_diffrn_standards_decay_%        0
_exptl_absorpt_coefficient_mu    1.089
_exptl_absorpt_correction_type   Scalepack
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.561
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1248
_exptl_crystal_size_max          0.2
_exptl_crystal_size_mid          0.05
_exptl_crystal_size_min          0.05
_refine_diff_density_max         0.870
_refine_diff_density_min         -1.505
_refine_diff_density_rms         0.165
_refine_ls_extinction_coef       0.0012(2)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.039
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     605
_refine_ls_number_reflns         11885
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.039
_refine_ls_R_factor_all          0.0563
_refine_ls_R_factor_gt           0.0404
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0099P)²+5.6081P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0801
_refine_ls_wR_factor_ref         0.0858
_reflns_number_gt                9858
_reflns_number_total             11885
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b003759l.txt
_cod_data_source_block           ms1376
_cod_original_cell_volume        2616.4(9)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7009816
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh1 Rh 0.37913(2) 0.642792(14) 0.263158(14) 0.01641(7) Uani 1 1 d . . .
Cl1 Cl 0.42690(8) 0.75158(5) 0.18604(5) 0.02454(17) Uani 1 1 d . . .
P1 P 0.39521(8) 0.74071(4) 0.37805(5) 0.01635(16) Uani 1 1 d . . .
O1 O 0.3651(2) 0.70903(12) 0.46459(12) 0.0177(4) Uani 1 1 d . . .
N1 N 0.3698(3) 0.65973(15) 0.60833(15) 0.0182(5) Uani 1 1 d . . .
C1 C 0.4804(3) 0.54942(18) 0.32043(19) 0.0222(7) Uani 1 1 d . . .
Rh2 Rh 0.48598(2) 0.826783(13) 0.817493(14) 0.01681(7) Uani 1 1 d . . .
Cl2 Cl 0.13461(8) 0.65156(5) 0.22954(5) 0.02308(16) Uani 1 1 d . . .
P2 P 0.31648(8) 0.72521(4) 0.77223(5) 0.01565(15) Uani 1 1 d . . .
N2 N 0.1408(3) 0.60765(16) 0.59032(16) 0.0223(6) Uani 1 1 d . . .
C2 C 0.5713(3) 0.57967(18) 0.26412(19) 0.0209(6) Uani 1 1 d . . .
Cl3 Cl 0.55701(7) 0.81748(4) 0.67887(4) 0.02021(15) Uani 1 1 d . . .
C3 C 0.5088(3) 0.55618(18) 0.18360(19) 0.0201(6) Uani 1 1 d . . .
Cl4 Cl 0.62490(8) 0.71494(4) 0.84053(5) 0.02357(16) Uani 1 1 d . . .
C4 C 0.3791(3) 0.51581(18) 0.19021(19) 0.0206(6) Uani 1 1 d . . .
C5 C 0.3586(3) 0.51352(18) 0.2761(2) 0.0228(7) Uani 1 1 d . . .
C6 C 0.5144(4) 0.5468(2) 0.40833(19) 0.0290(8) Uani 1 1 d . . .
H6A H 0.4319 0.5537 0.4387 0.044 Uiso 1 1 calc R . .
H6B H 0.5812 0.5904 0.4290 0.044 Uiso 1 1 calc R . .
H6C H 0.5517 0.4945 0.4136 0.044 Uiso 1 1 calc R . .
C7 C 0.7168(3) 0.6149(2) 0.2829(2) 0.0283(7) Uani 1 1 d . . .
H7A H 0.7798 0.5708 0.2775 0.042 Uiso 1 1 calc R . .
H7B H 0.7237 0.6443 0.3376 0.042 Uiso 1 1 calc R . .
H7C H 0.7397 0.6519 0.2458 0.042 Uiso 1 1 calc R . .
C8 C 0.5718(4) 0.5721(2) 0.1068(2) 0.0283(7) Uani 1 1 d . . .
H8A H 0.6256 0.5263 0.0854 0.042 Uiso 1 1 calc R . .
H8B H 0.6305 0.6214 0.1176 0.042 Uiso 1 1 calc R . .
H8C H 0.5000 0.5789 0.0678 0.042 Uiso 1 1 calc R . .
C9 C 0.2809(4) 0.4789(2) 0.1221(2) 0.0281(7) Uani 1 1 d . . .
H9A H 0.3232 0.4814 0.0712 0.042 Uiso 1 1 calc R . .
H9B H 0.1981 0.5093 0.1248 0.042 Uiso 1 1 calc R . .
H9C H 0.2584 0.4224 0.1266 0.042 Uiso 1 1 calc R . .
C10 C 0.2390(4) 0.4708(2) 0.3083(2) 0.0315(8) Uani 1 1 d . . .
H10A H 0.2508 0.4124 0.2992 0.047 Uiso 1 1 calc R . .
H10B H 0.1552 0.4825 0.2809 0.047 Uiso 1 1 calc R . .
H10C H 0.2338 0.4901 0.3655 0.047 Uiso 1 1 calc R . .
C11 C 0.5731(3) 0.77740(17) 0.40365(18) 0.0182(6) Uani 1 1 d . . .
C12 C 0.6472(3) 0.75658(19) 0.47039(19) 0.0226(6) Uani 1 1 d . . .
H12 H 0.6026 0.7275 0.5063 0.027 Uiso 1 1 calc R . .
C13 C 0.7864(3) 0.7791(2) 0.4832(2) 0.0263(7) Uani 1 1 d . . .
H13 H 0.8353 0.7639 0.5270 0.032 Uiso 1 1 calc R . .
C14 C 0.8530(4) 0.8239(2) 0.4313(2) 0.0294(7) Uani 1 1 d . . .
H14 H 0.9465 0.8388 0.4399 0.035 Uiso 1 1 calc R . .
C15 C 0.7795(4) 0.8466(2) 0.3661(2) 0.0299(8) Uani 1 1 d . . .
H15 H 0.8240 0.8776 0.3316 0.036 Uiso 1 1 calc R . .
C16 C 0.6407(3) 0.82363(19) 0.3519(2) 0.0243(7) Uani 1 1 d . . .
H16 H 0.5925 0.8389 0.3080 0.029 Uiso 1 1 calc R . .
C17 C 0.3026(3) 0.83554(18) 0.39016(19) 0.0202(6) Uani 1 1 d . . .
C18 C 0.2077(3) 0.85511(18) 0.3322(2) 0.0214(6) Uani 1 1 d . . .
H18 H 0.1912 0.8198 0.2832 0.026 Uiso 1 1 calc R . .
C19 C 0.1381(3) 0.9282(2) 0.3487(2) 0.0283(7) Uani 1 1 d . . .
H19 H 0.0754 0.9419 0.3102 0.034 Uiso 1 1 calc R . .
C20 C 0.1615(4) 0.9803(2) 0.4217(2) 0.0317(8) Uani 1 1 d . . .
H20 H 0.1135 1.0286 0.4323 0.038 Uiso 1 1 calc R . .
C21 C 0.2559(4) 0.9614(2) 0.4795(2) 0.0351(8) Uani 1 1 d . . .
H21 H 0.2719 0.9970 0.5284 0.042 Uiso 1 1 calc R . .
C22 C 0.3262(4) 0.8892(2) 0.4636(2) 0.0294(7) Uani 1 1 d . . .
H22 H 0.3896 0.8763 0.5021 0.035 Uiso 1 1 calc R . .
C23 C 0.2421(3) 0.67190(17) 0.48514(19) 0.0186(6) Uani 1 1 d . . .
C24 C 0.2483(3) 0.64620(17) 0.56198(18) 0.0169(6) Uani 1 1 d . . .
C25 C 0.1225(3) 0.66034(19) 0.4381(2) 0.0222(6) Uani 1 1 d . . .
H25 H 0.1164 0.6779 0.3879 0.027 Uiso 1 1 calc R . .
C26 C 0.0093(3) 0.6207(2) 0.4690(2) 0.0263(7) Uani 1 1 d . . .
H26 H -0.0745 0.6116 0.4395 0.032 Uiso 1 1 calc R . .
C27 C 0.0244(3) 0.5958(2) 0.5434(2) 0.0270(7) Uani 1 1 d . . .
H27 H -0.0511 0.5689 0.5625 0.032 Uiso 1 1 calc R . .
C28 C 0.3768(3) 0.64400(17) 0.69115(17) 0.0182(6) Uani 1 1 d . . .
H28A H 0.4721 0.6340 0.7046 0.022 Uiso 1 1 calc R . .
H28B H 0.3229 0.5934 0.6932 0.022 Uiso 1 1 calc R . .
C29 C 0.4126(4) 0.9504(2) 0.8354(2) 0.0319(8) Uani 1 1 d . . .
C30 C 0.3677(4) 0.9095(2) 0.8998(2) 0.0388(10) Uani 1 1 d . . .
C31 C 0.4874(5) 0.8888(2) 0.9422(2) 0.0441(11) Uani 1 1 d . . .
C32 C 0.6067(4) 0.9198(2) 0.9052(3) 0.0388(9) Uani 1 1 d . . .
C33 C 0.5604(4) 0.95841(19) 0.8417(2) 0.0331(8) Uani 1 1 d . . .
C34 C 0.3275(7) 0.9910(3) 0.7784(3) 0.083(2) Uani 1 1 d . . .
H34A H 0.2325 0.9723 0.7794 0.124 Uiso 1 1 calc R . .
H34B H 0.3600 0.9771 0.7244 0.124 Uiso 1 1 calc R . .
H34C H 0.3353 1.0498 0.7949 0.124 Uiso 1 1 calc R . .
C35 C 0.2209(6) 0.8963(3) 0.9222(5) 0.110(3) Uani 1 1 d . . .
H35A H 0.1954 0.9422 0.9612 0.164 Uiso 1 1 calc R . .
H35B H 0.2118 0.8465 0.9452 0.164 Uiso 1 1 calc R . .
H35C H 0.1614 0.8917 0.8744 0.164 Uiso 1 1 calc R . .
C36 C 0.4939(10) 0.8518(3) 1.0186(3) 0.113(3) Uani 1 1 d . . .
H36A H 0.5200 0.8940 1.0638 0.169 Uiso 1 1 calc R . .
H36B H 0.5612 0.8100 1.0138 0.169 Uiso 1 1 calc R . .
H36C H 0.4049 0.8275 1.0273 0.169 Uiso 1 1 calc R . .
C37 C 0.7537(6) 0.9092(3) 0.9340(5) 0.103(3) Uani 1 1 d . . .
H37A H 0.8161 0.9422 0.9074 0.155 Uiso 1 1 calc R . .
H37B H 0.7753 0.8522 0.9210 0.155 Uiso 1 1 calc R . .
H37C H 0.7628 0.9266 0.9917 0.155 Uiso 1 1 calc R . .
C38 C 0.6489(6) 1.0013(3) 0.7875(3) 0.0736(18) Uani 1 1 d . . .
H38A H 0.6461 1.0599 0.8036 0.110 Uiso 1 1 calc R . .
H38B H 0.6148 0.9865 0.7322 0.110 Uiso 1 1 calc R . .
H38C H 0.7425 0.9849 0.7919 0.110 Uiso 1 1 calc R . .
C39 C 0.1623(3) 0.76743(17) 0.73281(19) 0.0187(6) Uani 1 1 d . . .
C40 C 0.1778(3) 0.81596(19) 0.67153(19) 0.0212(6) Uani 1 1 d . . .
H40 H 0.2640 0.8230 0.6500 0.025 Uiso 1 1 calc R . .
C41 C 0.0642(3) 0.8537(2) 0.6429(2) 0.0254(7) Uani 1 1 d . . .
H41 H 0.0745 0.8850 0.6015 0.030 Uiso 1 1 calc R . .
C42 C -0.0642(3) 0.8447(2) 0.6758(2) 0.0274(7) Uani 1 1 d . . .
H42 H -0.1394 0.8708 0.6571 0.033 Uiso 1 1 calc R . .
C43 C -0.0806(3) 0.7972(2) 0.7364(2) 0.0292(8) Uani 1 1 d . . .
H43 H -0.1671 0.7908 0.7579 0.035 Uiso 1 1 calc R . .
C44 C 0.0322(3) 0.7588(2) 0.7652(2) 0.0253(7) Uani 1 1 d . . .
H44 H 0.0208 0.7272 0.8063 0.030 Uiso 1 1 calc R . .
C45 C 0.2531(3) 0.66033(18) 0.84390(18) 0.0186(6) Uani 1 1 d . . .
C46 C 0.1571(3) 0.59525(18) 0.8168(2) 0.0223(7) Uani 1 1 d . . .
H46 H 0.1275 0.5845 0.7624 0.027 Uiso 1 1 calc R . .
C47 C 0.1057(3) 0.5465(2) 0.8709(2) 0.0265(7) Uani 1 1 d . . .
H47 H 0.0429 0.5026 0.8527 0.032 Uiso 1 1 calc R . .
C48 C 0.1485(3) 0.5637(2) 0.9521(2) 0.0273(7) Uani 1 1 d . . .
H48 H 0.1127 0.5317 0.9885 0.033 Uiso 1 1 calc R . .
C49 C 0.2436(3) 0.6275(2) 0.9797(2) 0.0273(7) Uani 1 1 d . . .
H49 H 0.2711 0.6387 1.0344 0.033 Uiso 1 1 calc R . .
C50 C 0.2982(3) 0.67492(19) 0.92503(19) 0.0208(6) Uani 1 1 d . . .
H50 H 0.3651 0.7166 0.9429 0.025 Uiso 1 1 calc R . .
Cl1S Cl -0.06934(15) 0.73200(9) 0.00114(8) 0.0696(4) Uani 1 1 d . . .
C1S C -0.0454(4) 0.7724(3) 0.1038(3) 0.0413(10) Uani 1 1 d . . .
H1S H 0.005(5) 0.737(3) 0.126(3) 0.054(13) Uiso 1 1 d . . .
Cl2S Cl -0.20652(16) 0.77997(7) 0.14864(8) 0.0696(4) Uani 1 1 d . . .
Cl3S Cl 0.03892(18) 0.87091(10) 0.11514(10) 0.0868(5) Uani 1 1 d . . .
H1 H 0.421(3) 0.700(2) 0.598(2) 0.019(9) Uiso 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C2 Rh1 C5 64.66(12) . . ?
C2 Rh1 C1 38.64(12) . . ?
C5 Rh1 C1 38.30(12) . . ?
C2 Rh1 C3 38.25(11) . . ?
C5 Rh1 C3 63.55(12) . . ?
C1 Rh1 C3 63.55(11) . . ?
C2 Rh1 C4 63.45(12) . . ?
C5 Rh1 C4 38.57(11) . . ?
C1 Rh1 C4 63.59(11) . . ?
C3 Rh1 C4 36.77(11) . . ?
C2 Rh1 P1 104.64(9) . . ?
C5 Rh1 P1 118.85(9) . . ?
C1 Rh1 P1 94.30(9) . . ?
C3 Rh1 P1 141.22(8) . . ?
C4 Rh1 P1 156.62(8) . . ?
C2 Rh1 Cl1 104.13(9) . . ?
C5 Rh1 Cl1 152.41(9) . . ?
C1 Rh1 Cl1 141.87(9) . . ?
C3 Rh1 Cl1 91.73(8) . . ?
C4 Rh1 Cl1 113.99(8) . . ?
P1 Rh1 Cl1 87.89(3) . . ?
C2 Rh1 Cl2 153.93(8) . . ?
C5 Rh1 Cl2 93.66(9) . . ?
C1 Rh1 Cl2 128.50(9) . . ?
C3 Rh1 Cl2 120.32(9) . . ?
C4 Rh1 Cl2 90.63(9) . . ?
P1 Rh1 Cl2 98.44(4) . . ?
Cl1 Rh1 Cl2 88.50(4) . . ?
O1 P1 C17 100.81(13) . . ?
O1 P1 C11 96.40(13) . . ?
C17 P1 C11 102.78(14) . . ?
O1 P1 Rh1 116.93(8) . . ?
C17 P1 Rh1 123.94(11) . . ?
C11 P1 Rh1 111.74(11) . . ?
C23 O1 P1 126.25(19) . . ?
C24 N1 C28 121.2(3) . . ?
C5 C1 C2 108.1(3) . . ?
C5 C1 C6 125.6(3) . . ?
C2 C1 C6 125.9(3) . . ?
C5 C1 Rh1 70.45(17) . . ?
C2 C1 Rh1 70.16(16) . . ?
C6 C1 Rh1 130.5(2) . . ?
C29 Rh2 C30 38.54(15) . . ?
C29 Rh2 C31 64.23(14) . . ?
C30 Rh2 C31 38.33(17) . . ?
C29 Rh2 C32 63.42(14) . . ?
C30 Rh2 C32 63.86(15) . . ?
C31 Rh2 C32 38.43(16) . . ?
C29 Rh2 C33 38.11(14) . . ?
C30 Rh2 C33 63.39(13) . . ?
C31 Rh2 C33 62.88(14) . . ?
C32 Rh2 C33 36.55(14) . . ?
C29 Rh2 P2 114.11(10) . . ?
C30 Rh2 P2 99.67(10) . . ?
C31 Rh2 P2 119.20(13) . . ?
C32 Rh2 P2 157.48(12) . . ?
C33 Rh2 P2 151.12(11) . . ?
C29 Rh2 Cl4 157.69(10) . . ?
C30 Rh2 Cl4 130.98(12) . . ?
C31 Rh2 Cl4 97.16(12) . . ?
C32 Rh2 Cl4 94.43(10) . . ?
C33 Rh2 Cl4 123.71(11) . . ?
P2 Rh2 Cl4 85.15(3) . . ?
C29 Rh2 Cl3 99.39(11) . . ?
C30 Rh2 Cl3 136.56(12) . . ?
C31 Rh2 Cl3 151.62(11) . . ?
C32 Rh2 Cl3 114.28(12) . . ?
C33 Rh2 Cl3 89.72(10) . . ?
P2 Rh2 Cl3 88.23(4) . . ?
Cl4 Rh2 Cl3 92.03(4) . . ?
C39 P2 C45 104.92(14) . . ?
C39 P2 C28 107.90(14) . . ?
C45 P2 C28 99.86(13) . . ?
C39 P2 Rh2 112.01(10) . . ?
C45 P2 Rh2 118.35(11) . . ?
C28 P2 Rh2 112.67(10) . . ?
C24 N2 C27 117.1(3) . . ?
C1 C2 C3 107.7(3) . . ?
C1 C2 C7 126.2(3) . . ?
C3 C2 C7 125.2(3) . . ?
C1 C2 Rh1 71.21(17) . . ?
C3 C2 Rh1 73.50(17) . . ?
C7 C2 Rh1 129.5(2) . . ?
C4 C3 C2 108.5(3) . . ?
C4 C3 C8 126.2(3) . . ?
C2 C3 C8 125.3(3) . . ?
C4 C3 Rh1 71.77(18) . . ?
C2 C3 Rh1 68.25(17) . . ?
C8 C3 Rh1 125.9(2) . . ?
C3 C4 C5 107.9(3) . . ?
C3 C4 C9 126.9(3) . . ?
C5 C4 C9 125.2(3) . . ?
C3 C4 Rh1 71.46(17) . . ?
C5 C4 Rh1 68.10(16) . . ?
C9 C4 Rh1 127.5(2) . . ?
C1 C5 C4 107.7(3) . . ?
C1 C5 C10 127.2(3) . . ?
C4 C5 C10 124.7(3) . . ?
C1 C5 Rh1 71.25(17) . . ?
C4 C5 Rh1 73.33(16) . . ?
C10 C5 Rh1 127.1(2) . . ?
C16 C11 C12 119.0(3) . . ?
C16 C11 P1 118.6(2) . . ?
C12 C11 P1 122.3(2) . . ?
C13 C12 C11 120.4(3) . . ?
C14 C13 C12 120.2(3) . . ?
C13 C14 C15 119.8(3) . . ?
C16 C15 C14 120.6(3) . . ?
C15 C16 C11 120.0(3) . . ?
C18 C17 C22 119.7(3) . . ?
C18 C17 P1 123.7(2) . . ?
C22 C17 P1 116.5(2) . . ?
C19 C18 C17 119.3(3) . . ?
C20 C19 C18 120.5(3) . . ?
C19 C20 C21 120.6(3) . . ?
C22 C21 C20 119.4(3) . . ?
C21 C22 C17 120.5(3) . . ?
C25 C23 O1 125.5(3) . . ?
C25 C23 C24 120.5(3) . . ?
O1 C23 C24 114.0(3) . . ?
N2 C24 N1 119.0(3) . . ?
N2 C24 C23 121.9(3) . . ?
N1 C24 C23 119.1(3) . . ?
C23 C25 C26 117.2(3) . . ?
C27 C26 C25 118.9(3) . . ?
N2 C27 C26 124.4(3) . . ?
N1 C28 P2 117.8(2) . . ?
C30 C29 C33 107.5(3) . . ?
C30 C29 C34 128.5(5) . . ?
C33 C29 C34 123.3(4) . . ?
C30 C29 Rh2 70.9(2) . . ?
C33 C29 Rh2 73.37(19) . . ?
C34 C29 Rh2 128.5(3) . . ?
C31 C30 C29 107.7(3) . . ?
C31 C30 C35 126.2(5) . . ?
C29 C30 C35 125.9(5) . . ?
C31 C30 Rh2 71.0(2) . . ?
C29 C30 Rh2 70.6(2) . . ?
C35 C30 Rh2 127.1(3) . . ?
C30 C31 C32 107.8(3) . . ?
C30 C31 C36 127.7(5) . . ?
C32 C31 C36 124.0(5) . . ?
C30 C31 Rh2 70.7(2) . . ?
C32 C31 Rh2 72.4(2) . . ?
C36 C31 Rh2 128.6(3) . . ?
C33 C32 C31 107.9(3) . . ?
C33 C32 C37 128.9(5) . . ?
C31 C32 C37 123.1(5) . . ?
C33 C32 Rh2 72.2(2) . . ?
C31 C32 Rh2 69.1(2) . . ?
C37 C32 Rh2 123.9(3) . . ?
C32 C33 C29 108.9(3) . . ?
C32 C33 C38 126.3(4) . . ?
C29 C33 C38 124.7(4) . . ?
C32 C33 Rh2 71.23(19) . . ?
C29 C33 Rh2 68.51(18) . . ?
C38 C33 Rh2 125.9(3) . . ?
C44 C39 C40 119.0(3) . . ?
C44 C39 P2 122.9(2) . . ?
C40 C39 P2 118.0(2) . . ?
C41 C40 C39 120.1(3) . . ?
C42 C41 C40 120.3(3) . . ?
C43 C42 C41 120.1(3) . . ?
C42 C43 C44 120.0(3) . . ?
C43 C44 C39 120.5(3) . . ?
C50 C45 C46 119.4(3) . . ?
C50 C45 P2 121.1(2) . . ?
C46 C45 P2 119.5(2) . . ?
C47 C46 C45 120.2(3) . . ?
C48 C47 C46 119.6(3) . . ?
C49 C48 C47 121.0(3) . . ?
C48 C49 C50 119.5(3) . . ?
C45 C50 C49 120.3(3) . . ?
Cl1S C1S Cl2S 109.3(2) . . ?
Cl1S C1S Cl3S 109.9(2) . . ?
Cl2S C1S Cl3S 109.8(3) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Rh1 C2 2.167(3) . ?
Rh1 C5 2.171(3) . ?
Rh1 C1 2.181(3) . ?
Rh1 C3 2.237(3) . ?
Rh1 C4 2.241(3) . ?
Rh1 P1 2.2944(11) . ?
Rh1 Cl1 2.4015(10) . ?
Rh1 Cl2 2.4320(9) . ?
P1 O1 1.641(2) . ?
P1 C17 1.815(3) . ?
P1 C11 1.818(3) . ?
O1 C23 1.394(3) . ?
N1 C24 1.378(4) . ?
N1 C28 1.446(4) . ?
C1 C5 1.428(5) . ?
C1 C2 1.438(4) . ?
C1 C6 1.501(4) . ?
Rh2 C29 2.158(3) . ?
Rh2 C30 2.161(4) . ?
Rh2 C31 2.166(4) . ?
Rh2 C32 2.209(3) . ?
Rh2 C33 2.222(3) . ?
Rh2 P2 2.3136(11) . ?
Rh2 Cl4 2.3925(10) . ?
Rh2 Cl3 2.4163(9) . ?
P2 C39 1.820(3) . ?
P2 C45 1.828(3) . ?
P2 C28 1.867(3) . ?
N2 C24 1.335(4) . ?
N2 C27 1.343(4) . ?
C2 C3 1.444(4) . ?
C2 C7 1.507(5) . ?
C3 C4 1.412(4) . ?
C3 C8 1.493(4) . ?
C4 C5 1.459(4) . ?
C4 C9 1.493(4) . ?
C5 C10 1.489(4) . ?
C11 C16 1.399(4) . ?
C11 C12 1.401(4) . ?
C12 C13 1.385(4) . ?
C13 C14 1.382(5) . ?
C14 C15 1.390(5) . ?
C15 C16 1.385(5) . ?
C17 C18 1.397(4) . ?
C17 C22 1.398(5) . ?
C18 C19 1.394(4) . ?
C19 C20 1.380(5) . ?
C20 C21 1.388(5) . ?
C21 C22 1.385(5) . ?
C23 C25 1.368(4) . ?
C23 C24 1.413(4) . ?
C25 C26 1.406(4) . ?
C26 C27 1.373(5) . ?
C29 C30 1.425(5) . ?
C29 C33 1.431(5) . ?
C29 C34 1.491(5) . ?
C30 C31 1.421(6) . ?
C30 C35 1.497(6) . ?
C31 C32 1.441(6) . ?
C31 C36 1.498(5) . ?
C32 C33 1.390(5) . ?
C32 C37 1.514(6) . ?
C33 C38 1.501(5) . ?
C39 C44 1.397(4) . ?
C39 C40 1.401(4) . ?
C40 C41 1.392(4) . ?
C41 C42 1.387(5) . ?
C42 C43 1.382(5) . ?
C43 C44 1.394(4) . ?
C45 C50 1.390(4) . ?
C45 C46 1.398(4) . ?
C46 C47 1.389(4) . ?
C47 C48 1.386(5) . ?
C48 C49 1.379(5) . ?
C49 C50 1.394(4) . ?
Cl1S C1S 1.740(4) . ?
C1S Cl2S 1.751(5) . ?
C1S Cl3S 1.763(4) . ?
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
C1S H1S Cl2 0.89(5) 2.70(5) 3.573(4) 166(4) .
N1 H1 Cl3 0.85(3) 2.48(3) 3.148(3) 136(3) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C2 Rh1 P1 O1 -78.49(13) . . . . ?
C5 Rh1 P1 O1 -9.66(14) . . . . ?
C1 Rh1 P1 O1 -40.68(13) . . . . ?
C3 Rh1 P1 O1 -92.40(15) . . . . ?
C4 Rh1 P1 O1 -22.5(2) . . . . ?
Cl1 Rh1 P1 O1 177.46(9) . . . . ?
Cl2 Rh1 P1 O1 89.28(10) . . . . ?
C2 Rh1 P1 C17 154.96(14) . . . . ?
C5 Rh1 P1 C17 -136.21(15) . . . . ?
C1 Rh1 P1 C17 -167.22(15) . . . . ?
C3 Rh1 P1 C17 141.05(17) . . . . ?
C4 Rh1 P1 C17 -149.1(2) . . . . ?
Cl1 Rh1 P1 C17 50.91(12) . . . . ?
Cl2 Rh1 P1 C17 -37.26(12) . . . . ?
C2 Rh1 P1 C11 31.22(13) . . . . ?
C5 Rh1 P1 C11 100.05(15) . . . . ?
C1 Rh1 P1 C11 69.03(14) . . . . ?
C3 Rh1 P1 C11 17.31(17) . . . . ?
C4 Rh1 P1 C11 87.2(2) . . . . ?
Cl1 Rh1 P1 C11 -72.83(11) . . . . ?
Cl2 Rh1 P1 C11 -161.01(10) . . . . ?
C17 P1 O1 C23 76.4(2) . . . . ?
C11 P1 O1 C23 -179.3(2) . . . . ?
Rh1 P1 O1 C23 -60.9(2) . . . . ?
C2 Rh1 C1 C5 -118.5(3) . . . . ?
C3 Rh1 C1 C5 -80.0(2) . . . . ?
C4 Rh1 C1 C5 -38.79(18) . . . . ?
P1 Rh1 C1 C5 133.27(18) . . . . ?
Cl1 Rh1 C1 C5 -134.66(17) . . . . ?
Cl2 Rh1 C1 C5 28.9(2) . . . . ?
C5 Rh1 C1 C2 118.5(3) . . . . ?
C3 Rh1 C1 C2 38.51(17) . . . . ?
C4 Rh1 C1 C2 79.76(19) . . . . ?
P1 Rh1 C1 C2 -108.18(17) . . . . ?
Cl1 Rh1 C1 C2 -16.1(2) . . . . ?
Cl2 Rh1 C1 C2 147.47(15) . . . . ?
C2 Rh1 C1 C6 120.8(4) . . . . ?
C5 Rh1 C1 C6 -120.6(4) . . . . ?
C3 Rh1 C1 C6 159.3(4) . . . . ?
C4 Rh1 C1 C6 -159.4(4) . . . . ?
P1 Rh1 C1 C6 12.7(3) . . . . ?
Cl1 Rh1 C1 C6 104.7(3) . . . . ?
Cl2 Rh1 C1 C6 -91.7(3) . . . . ?
C29 Rh2 P2 C39 15.92(16) . . . . ?
C30 Rh2 P2 C39 53.45(17) . . . . ?
C31 Rh2 P2 C39 88.73(17) . . . . ?
C32 Rh2 P2 C39 94.4(3) . . . . ?
C33 Rh2 P2 C39 2.6(2) . . . . ?
Cl4 Rh2 P2 C39 -175.77(11) . . . . ?
Cl3 Rh2 P2 C39 -83.58(12) . . . . ?
C29 Rh2 P2 C45 -106.34(16) . . . . ?
C30 Rh2 P2 C45 -68.81(17) . . . . ?
C31 Rh2 P2 C45 -33.53(18) . . . . ?
C32 Rh2 P2 C45 -27.9(3) . . . . ?
C33 Rh2 P2 C45 -119.6(2) . . . . ?
Cl4 Rh2 P2 C45 61.97(12) . . . . ?
Cl3 Rh2 P2 C45 154.16(11) . . . . ?
C29 Rh2 P2 C28 137.79(15) . . . . ?
C30 Rh2 P2 C28 175.32(16) . . . . ?
C31 Rh2 P2 C28 -149.40(16) . . . . ?
C32 Rh2 P2 C28 -143.8(3) . . . . ?
C33 Rh2 P2 C28 124.5(2) . . . . ?
Cl4 Rh2 P2 C28 -53.89(10) . . . . ?
Cl3 Rh2 P2 C28 38.30(10) . . . . ?
C5 C1 C2 C3 -4.4(3) . . . . ?
C6 C1 C2 C3 168.8(3) . . . . ?
Rh1 C1 C2 C3 -65.0(2) . . . . ?
C5 C1 C2 C7 -173.8(3) . . . . ?
C6 C1 C2 C7 -0.5(5) . . . . ?
Rh1 C1 C2 C7 125.7(3) . . . . ?
C5 C1 C2 Rh1 60.5(2) . . . . ?
C6 C1 C2 Rh1 -126.2(3) . . . . ?
C5 Rh1 C2 C1 -37.05(18) . . . . ?
C3 Rh1 C2 C1 -115.8(3) . . . . ?
C4 Rh1 C2 C1 -80.13(19) . . . . ?
P1 Rh1 C2 C1 78.30(17) . . . . ?
Cl1 Rh1 C2 C1 169.82(16) . . . . ?
Cl2 Rh1 C2 C1 -73.2(3) . . . . ?
C5 Rh1 C2 C3 78.73(19) . . . . ?
C1 Rh1 C2 C3 115.8(3) . . . . ?
C4 Rh1 C2 C3 35.65(17) . . . . ?
P1 Rh1 C2 C3 -165.93(15) . . . . ?
Cl1 Rh1 C2 C3 -74.40(17) . . . . ?
Cl2 Rh1 C2 C3 42.5(3) . . . . ?
C5 Rh1 C2 C7 -158.9(3) . . . . ?
C1 Rh1 C2 C7 -121.8(4) . . . . ?
C3 Rh1 C2 C7 122.4(4) . . . . ?
C4 Rh1 C2 C7 158.0(3) . . . . ?
P1 Rh1 C2 C7 -43.5(3) . . . . ?
Cl1 Rh1 C2 C7 48.0(3) . . . . ?
Cl2 Rh1 C2 C7 164.9(2) . . . . ?
C1 C2 C3 C4 2.7(3) . . . . ?
C7 C2 C3 C4 172.2(3) . . . . ?
Rh1 C2 C3 C4 -60.7(2) . . . . ?
C1 C2 C3 C8 -177.2(3) . . . . ?
C7 C2 C3 C8 -7.7(5) . . . . ?
Rh1 C2 C3 C8 119.4(3) . . . . ?
C1 C2 C3 Rh1 63.5(2) . . . . ?
C7 C2 C3 Rh1 -127.0(3) . . . . ?
C2 Rh1 C3 C4 119.4(2) . . . . ?
C5 Rh1 C3 C4 37.54(18) . . . . ?
C1 Rh1 C3 C4 80.54(19) . . . . ?
P1 Rh1 C3 C4 141.50(15) . . . . ?
Cl1 Rh1 C3 C4 -129.71(16) . . . . ?
Cl2 Rh1 C3 C4 -40.43(19) . . . . ?
C5 Rh1 C3 C2 -81.89(19) . . . . ?
C1 Rh1 C3 C2 -38.90(17) . . . . ?
C4 Rh1 C3 C2 -119.4(2) . . . . ?
P1 Rh1 C3 C2 22.1(2) . . . . ?
Cl1 Rh1 C3 C2 110.86(17) . . . . ?
Cl2 Rh1 C3 C2 -159.87(15) . . . . ?
C2 Rh1 C3 C8 -118.6(3) . . . . ?
C5 Rh1 C3 C8 159.5(3) . . . . ?
C1 Rh1 C3 C8 -157.5(3) . . . . ?
C4 Rh1 C3 C8 121.9(3) . . . . ?
P1 Rh1 C3 C8 -96.6(3) . . . . ?
Cl1 Rh1 C3 C8 -7.8(3) . . . . ?
Cl2 Rh1 C3 C8 81.5(3) . . . . ?
C2 C3 C4 C5 0.0(3) . . . . ?
C8 C3 C4 C5 179.9(3) . . . . ?
Rh1 C3 C4 C5 -58.6(2) . . . . ?
C2 C3 C4 C9 -178.0(3) . . . . ?
C8 C3 C4 C9 1.9(5) . . . . ?
Rh1 C3 C4 C9 123.4(3) . . . . ?
C2 C3 C4 Rh1 58.5(2) . . . . ?
C8 C3 C4 Rh1 -121.6(3) . . . . ?
C2 Rh1 C4 C3 -37.06(17) . . . . ?
C5 Rh1 C4 C3 -119.0(3) . . . . ?
C1 Rh1 C4 C3 -80.44(19) . . . . ?
P1 Rh1 C4 C3 -100.7(2) . . . . ?
Cl1 Rh1 C4 C3 57.31(18) . . . . ?
Cl2 Rh1 C4 C3 145.96(16) . . . . ?
C2 Rh1 C4 C5 81.9(2) . . . . ?
C1 Rh1 C4 C5 38.52(18) . . . . ?
C3 Rh1 C4 C5 119.0(3) . . . . ?
P1 Rh1 C4 C5 18.2(3) . . . . ?
Cl1 Rh1 C4 C5 176.27(16) . . . . ?
Cl2 Rh1 C4 C5 -95.08(17) . . . . ?
C2 Rh1 C4 C9 -159.7(3) . . . . ?
C5 Rh1 C4 C9 118.4(4) . . . . ?
C1 Rh1 C4 C9 156.9(3) . . . . ?
C3 Rh1 C4 C9 -122.7(4) . . . . ?
P1 Rh1 C4 C9 136.6(2) . . . . ?
Cl1 Rh1 C4 C9 -65.4(3) . . . . ?
Cl2 Rh1 C4 C9 23.3(3) . . . . ?
C2 C1 C5 C4 4.4(3) . . . . ?
C6 C1 C5 C4 -168.9(3) . . . . ?
Rh1 C1 C5 C4 64.8(2) . . . . ?
C2 C1 C5 C10 176.8(3) . . . . ?
C6 C1 C5 C10 3.5(5) . . . . ?
Rh1 C1 C5 C10 -122.8(3) . . . . ?
C2 C1 C5 Rh1 -60.4(2) . . . . ?
C6 C1 C5 Rh1 126.3(3) . . . . ?
C3 C4 C5 C1 -2.7(3) . . . . ?
C9 C4 C5 C1 175.3(3) . . . . ?
Rh1 C4 C5 C1 -63.4(2) . . . . ?
C3 C4 C5 C10 -175.4(3) . . . . ?
C9 C4 C5 C10 2.7(5) . . . . ?
Rh1 C4 C5 C10 124.0(3) . . . . ?
C3 C4 C5 Rh1 60.7(2) . . . . ?
C9 C4 C5 Rh1 -121.3(3) . . . . ?
C2 Rh1 C5 C1 37.36(18) . . . . ?
C3 Rh1 C5 C1 80.1(2) . . . . ?
C4 Rh1 C5 C1 115.9(3) . . . . ?
P1 Rh1 C5 C1 -56.0(2) . . . . ?
Cl1 Rh1 C5 C1 108.5(2) . . . . ?
Cl2 Rh1 C5 C1 -157.71(17) . . . . ?
C2 Rh1 C5 C4 -78.51(19) . . . . ?
C1 Rh1 C5 C4 -115.9(3) . . . . ?
C3 Rh1 C5 C4 -35.81(18) . . . . ?
P1 Rh1 C5 C4 -171.86(15) . . . . ?
Cl1 Rh1 C5 C4 -7.4(3) . . . . ?
Cl2 Rh1 C5 C4 86.42(17) . . . . ?
C2 Rh1 C5 C10 160.3(3) . . . . ?
C1 Rh1 C5 C10 122.9(4) . . . . ?
C3 Rh1 C5 C10 -157.0(3) . . . . ?
C4 Rh1 C5 C10 -121.2(4) . . . . ?
P1 Rh1 C5 C10 66.9(3) . . . . ?
Cl1 Rh1 C5 C10 -128.6(3) . . . . ?
Cl2 Rh1 C5 C10 -34.8(3) . . . . ?
O1 P1 C11 C16 -169.9(2) . . . . ?
C17 P1 C11 C16 -67.3(3) . . . . ?
Rh1 P1 C11 C16 67.7(3) . . . . ?
O1 P1 C11 C12 14.2(3) . . . . ?
C17 P1 C11 C12 116.8(3) . . . . ?
Rh1 P1 C11 C12 -108.2(3) . . . . ?
C16 C11 C12 C13 -2.2(5) . . . . ?
P1 C11 C12 C13 173.7(2) . . . . ?
C11 C12 C13 C14 1.5(5) . . . . ?
C12 C13 C14 C15 0.2(5) . . . . ?
C13 C14 C15 C16 -1.1(5) . . . . ?
C14 C15 C16 C11 0.3(5) . . . . ?
C12 C11 C16 C15 1.3(5) . . . . ?
P1 C11 C16 C15 -174.7(3) . . . . ?
O1 P1 C17 C18 -129.6(3) . . . . ?
C11 P1 C17 C18 131.2(3) . . . . ?
Rh1 P1 C17 C18 3.6(3) . . . . ?
O1 P1 C17 C22 47.9(3) . . . . ?
C11 P1 C17 C22 -51.2(3) . . . . ?
Rh1 P1 C17 C22 -178.9(2) . . . . ?
C22 C17 C18 C19 0.1(4) . . . . ?
P1 C17 C18 C19 177.6(2) . . . . ?
C17 C18 C19 C20 -0.6(5) . . . . ?
C18 C19 C20 C21 0.8(5) . . . . ?
C19 C20 C21 C22 -0.5(5) . . . . ?
C20 C21 C22 C17 0.0(5) . . . . ?
C18 C17 C22 C21 0.2(5) . . . . ?
P1 C17 C22 C21 -177.4(3) . . . . ?
P1 O1 C23 C25 -4.3(4) . . . . ?
P1 O1 C23 C24 176.2(2) . . . . ?
C27 N2 C24 N1 179.9(3) . . . . ?
C27 N2 C24 C23 -1.5(4) . . . . ?
C28 N1 C24 N2 -9.0(4) . . . . ?
C28 N1 C24 C23 172.3(3) . . . . ?
C25 C23 C24 N2 2.2(5) . . . . ?
O1 C23 C24 N2 -178.3(3) . . . . ?
C25 C23 C24 N1 -179.1(3) . . . . ?
O1 C23 C24 N1 0.3(4) . . . . ?
O1 C23 C25 C26 179.3(3) . . . . ?
C24 C23 C25 C26 -1.3(5) . . . . ?
C23 C25 C26 C27 -0.3(5) . . . . ?
C24 N2 C27 C26 -0.1(5) . . . . ?
C25 C26 C27 N2 1.0(5) . . . . ?
C24 N1 C28 P2 -82.0(3) . . . . ?
C39 P2 C28 N1 39.9(3) . . . . ?
C45 P2 C28 N1 149.2(2) . . . . ?
Rh2 P2 C28 N1 -84.3(2) . . . . ?
C31 Rh2 C29 C30 -37.6(2) . . . . ?
C32 Rh2 C29 C30 -80.7(2) . . . . ?
C33 Rh2 C29 C30 -115.8(3) . . . . ?
P2 Rh2 C29 C30 74.5(2) . . . . ?
Cl4 Rh2 C29 C30 -73.3(4) . . . . ?
Cl3 Rh2 C29 C30 166.8(2) . . . . ?
C30 Rh2 C29 C33 115.8(3) . . . . ?
C31 Rh2 C29 C33 78.2(2) . . . . ?
C32 Rh2 C29 C33 35.2(2) . . . . ?
P2 Rh2 C29 C33 -169.64(18) . . . . ?
Cl4 Rh2 C29 C33 42.5(4) . . . . ?
Cl3 Rh2 C29 C33 -77.4(2) . . . . ?
C30 Rh2 C29 C34 -124.5(6) . . . . ?
C31 Rh2 C29 C34 -162.1(5) . . . . ?
C32 Rh2 C29 C34 154.9(5) . . . . ?
C33 Rh2 C29 C34 119.7(6) . . . . ?
P2 Rh2 C29 C34 -50.0(5) . . . . ?
Cl4 Rh2 C29 C34 162.2(4) . . . . ?
Cl3 Rh2 C29 C34 42.3(5) . . . . ?
C33 C29 C30 C31 -3.1(4) . . . . ?
C34 C29 C30 C31 -173.9(4) . . . . ?
Rh2 C29 C30 C31 61.6(2) . . . . ?
C33 C29 C30 C35 172.9(3) . . . . ?
C34 C29 C30 C35 2.2(6) . . . . ?
Rh2 C29 C30 C35 -122.3(4) . . . . ?
C33 C29 C30 Rh2 -64.7(2) . . . . ?
C34 C29 C30 Rh2 124.5(4) . . . . ?
C29 Rh2 C30 C31 -117.6(3) . . . . ?
C32 Rh2 C30 C31 -38.2(2) . . . . ?
C33 Rh2 C30 C31 -79.1(2) . . . . ?
P2 Rh2 C30 C31 125.6(2) . . . . ?
Cl4 Rh2 C30 C31 33.6(3) . . . . ?
Cl3 Rh2 C30 C31 -136.7(2) . . . . ?
C31 Rh2 C30 C29 117.6(3) . . . . ?
C32 Rh2 C30 C29 79.4(2) . . . . ?
C33 Rh2 C30 C29 38.4(2) . . . . ?
P2 Rh2 C30 C29 -116.8(2) . . . . ?
Cl4 Rh2 C30 C29 151.20(18) . . . . ?
Cl3 Rh2 C30 C29 -19.1(3) . . . . ?
C29 Rh2 C30 C35 120.9(6) . . . . ?
C31 Rh2 C30 C35 -121.6(6) . . . . ?
C32 Rh2 C30 C35 -159.7(6) . . . . ?
C33 Rh2 C30 C35 159.3(6) . . . . ?
P2 Rh2 C30 C35 4.0(6) . . . . ?
Cl4 Rh2 C30 C35 -87.9(6) . . . . ?
Cl3 Rh2 C30 C35 101.8(5) . . . . ?
C29 C30 C31 C32 2.0(4) . . . . ?
C35 C30 C31 C32 -174.1(3) . . . . ?
Rh2 C30 C31 C32 63.3(2) . . . . ?
C29 C30 C31 C36 174.3(4) . . . . ?
C35 C30 C31 C36 -1.7(6) . . . . ?
Rh2 C30 C31 C36 -124.3(4) . . . . ?
C29 C30 C31 Rh2 -61.4(2) . . . . ?
C35 C30 C31 Rh2 122.6(4) . . . . ?
C29 Rh2 C31 C30 37.8(2) . . . . ?
C32 Rh2 C31 C30 116.8(3) . . . . ?
C33 Rh2 C31 C30 80.6(2) . . . . ?
P2 Rh2 C31 C30 -66.6(2) . . . . ?
Cl4 Rh2 C31 C30 -155.1(2) . . . . ?
Cl3 Rh2 C31 C30 97.0(3) . . . . ?
C29 Rh2 C31 C32 -79.0(2) . . . . ?
C30 Rh2 C31 C32 -116.8(3) . . . . ?
C33 Rh2 C31 C32 -36.2(2) . . . . ?
P2 Rh2 C31 C32 176.54(18) . . . . ?
Cl4 Rh2 C31 C32 88.1(2) . . . . ?
Cl3 Rh2 C31 C32 -19.8(4) . . . . ?
C29 Rh2 C31 C36 161.2(6) . . . . ?
C30 Rh2 C31 C36 123.4(7) . . . . ?
C32 Rh2 C31 C36 -119.8(7) . . . . ?
C33 Rh2 C31 C36 -156.1(6) . . . . ?
P2 Rh2 C31 C36 56.7(6) . . . . ?
Cl4 Rh2 C31 C36 -31.7(6) . . . . ?
Cl3 Rh2 C31 C36 -139.6(5) . . . . ?
C30 C31 C32 C33 0.0(4) . . . . ?
C36 C31 C32 C33 -172.7(4) . . . . ?
Rh2 C31 C32 C33 62.2(3) . . . . ?
C30 C31 C32 C37 -179.8(3) . . . . ?
C36 C31 C32 C37 7.5(6) . . . . ?
Rh2 C31 C32 C37 -117.6(4) . . . . ?
C30 C31 C32 Rh2 -62.2(2) . . . . ?
C36 C31 C32 Rh2 125.1(4) . . . . ?
C29 Rh2 C32 C33 -36.6(2) . . . . ?
C30 Rh2 C32 C33 -79.9(3) . . . . ?
C31 Rh2 C32 C33 -117.9(3) . . . . ?
P2 Rh2 C32 C33 -125.8(3) . . . . ?
Cl4 Rh2 C32 C33 146.1(2) . . . . ?
Cl3 Rh2 C32 C33 51.9(2) . . . . ?
C29 Rh2 C32 C31 81.3(2) . . . . ?
C30 Rh2 C32 C31 38.1(2) . . . . ?
C33 Rh2 C32 C31 117.9(3) . . . . ?
P2 Rh2 C32 C31 -7.9(4) . . . . ?
Cl4 Rh2 C32 C31 -95.9(2) . . . . ?
Cl3 Rh2 C32 C31 169.8(2) . . . . ?
C29 Rh2 C32 C37 -162.0(5) . . . . ?
C30 Rh2 C32 C37 154.7(5) . . . . ?
C31 Rh2 C32 C37 116.7(6) . . . . ?
C33 Rh2 C32 C37 -125.4(6) . . . . ?
P2 Rh2 C32 C37 108.8(5) . . . . ?
Cl4 Rh2 C32 C37 20.7(5) . . . . ?
Cl3 Rh2 C32 C37 -73.5(5) . . . . ?
C31 C32 C33 C29 -1.9(4) . . . . ?
C37 C32 C33 C29 177.9(4) . . . . ?
Rh2 C32 C33 C29 58.3(2) . . . . ?
C31 C32 C33 C38 178.5(3) . . . . ?
C37 C32 C33 C38 -1.7(6) . . . . ?
Rh2 C32 C33 C38 -121.3(4) . . . . ?
C31 C32 C33 Rh2 -60.2(2) . . . . ?
C37 C32 C33 Rh2 119.6(4) . . . . ?
C30 C29 C33 C32 3.1(4) . . . . ?
C34 C29 C33 C32 174.5(3) . . . . ?
Rh2 C29 C33 C32 -60.0(2) . . . . ?
C30 C29 C33 C38 -177.3(3) . . . . ?
C34 C29 C33 C38 -5.9(6) . . . . ?
Rh2 C29 C33 C38 119.6(4) . . . . ?
C30 C29 C33 Rh2 63.1(2) . . . . ?
C34 C29 C33 Rh2 -125.6(4) . . . . ?
C29 Rh2 C33 C32 120.1(3) . . . . ?
C30 Rh2 C33 C32 81.3(3) . . . . ?
C31 Rh2 C33 C32 38.1(3) . . . . ?
P2 Rh2 C33 C32 140.0(2) . . . . ?
Cl4 Rh2 C33 C32 -41.9(3) . . . . ?
Cl3 Rh2 C33 C32 -134.2(2) . . . . ?
C30 Rh2 C33 C29 -38.9(2) . . . . ?
C31 Rh2 C33 C29 -82.0(2) . . . . ?
C32 Rh2 C33 C29 -120.1(3) . . . . ?
P2 Rh2 C33 C29 19.9(3) . . . . ?
Cl4 Rh2 C33 C29 -162.05(17) . . . . ?
Cl3 Rh2 C33 C29 105.7(2) . . . . ?
C29 Rh2 C33 C38 -118.1(5) . . . . ?
C30 Rh2 C33 C38 -156.9(5) . . . . ?
C31 Rh2 C33 C38 159.9(5) . . . . ?
C32 Rh2 C33 C38 121.8(5) . . . . ?
P2 Rh2 C33 C38 -98.2(4) . . . . ?
Cl4 Rh2 C33 C38 79.9(4) . . . . ?
Cl3 Rh2 C33 C38 -12.4(4) . . . . ?
C45 P2 C39 C44 9.3(3) . . . . ?
C28 P2 C39 C44 115.1(3) . . . . ?
Rh2 P2 C39 C44 -120.3(3) . . . . ?
C45 P2 C39 C40 -175.8(2) . . . . ?
C28 P2 C39 C40 -70.0(3) . . . . ?
Rh2 P2 C39 C40 54.6(3) . . . . ?
C44 C39 C40 C41 -1.0(5) . . . . ?
P2 C39 C40 C41 -176.2(2) . . . . ?
C39 C40 C41 C42 1.2(5) . . . . ?
C40 C41 C42 C43 -1.1(5) . . . . ?
C41 C42 C43 C44 0.7(5) . . . . ?
C42 C43 C44 C39 -0.5(5) . . . . ?
C40 C39 C44 C43 0.6(5) . . . . ?
P2 C39 C44 C43 175.6(3) . . . . ?
C39 P2 C45 C50 -121.4(3) . . . . ?
C28 P2 C45 C50 126.9(3) . . . . ?
Rh2 P2 C45 C50 4.4(3) . . . . ?
C39 P2 C45 C46 58.2(3) . . . . ?
C28 P2 C45 C46 -53.5(3) . . . . ?
Rh2 P2 C45 C46 -176.0(2) . . . . ?
C50 C45 C46 C47 1.0(5) . . . . ?
P2 C45 C46 C47 -178.6(2) . . . . ?
C45 C46 C47 C48 1.0(5) . . . . ?
C46 C47 C48 C49 -1.3(5) . . . . ?
C47 C48 C49 C50 -0.5(5) . . . . ?
C46 C45 C50 C49 -2.8(5) . . . . ?
P2 C45 C50 C49 176.8(2) . . . . ?
C48 C49 C50 C45 2.6(5) . . . . ?
