#------------------------------------------------------------------------------
#$Date: 2016-03-25 12:13:34 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179804 $
#$URL: svn://www.crystallography.net/cod/cif/7/01/00/7010059.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7010059
loop_
_publ_author_name
'Dilworth, Jonathan R.'
'Morales, David'
'Zheng, Yifan'
_publ_section_title
;
 Rhodium and iridium complexes with thiolate and tertiary phosphine
 ligands. The synthesis and structures of
 trans-[Ir(SC6H3Cl2-2,6)(CO)(PPh3)2],
 [Rh2(?-SC6H3Pri3-2,4,6)2(CO)2(PPh3)2],
 [Rh2H2(?-SC6H4PPh2-2)2(CO)2(PPh3)2][BF4]2, and [Rh2I6(MeSC6H4PPh2-2)2]
;
_journal_issue                   17
_journal_name_full
'Journal of the Chemical Society, Dalton Transactions'
_journal_page_first              3007
_journal_paper_doi               10.1039/b005588n
_journal_year                    2000
_chemical_formula_sum            'C68 H76 O2 P2 Rh2 S2'
_chemical_formula_weight         1257.17
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL
_cell_angle_alpha                90.00
_cell_angle_beta                 104.69(5)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   13.529(4)
_cell_length_b                   33.568(10)
_cell_length_c                   14.134(5)
_cell_measurement_temperature    293(2)
_cell_volume                     6209(4)
_computing_molecular_graphics    'ZORTEP (Zsolnai, 1994)'
_computing_publication_material  'SHELXL-93 (Sheldrick, 1993)'
_computing_structure_refinement  'SHELXL-93 (Sheldrick, 1993)'
_computing_structure_solution    'SHELXS-86 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measurement_device       'delft-Instruments FAST TV Area dector'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71069
_diffrn_reflns_av_R_equivalents  0.1085
_diffrn_reflns_av_sigmaI/netI    0.1470
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       37
_diffrn_reflns_limit_k_min       -36
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            20978
_diffrn_reflns_theta_max         25.06
_diffrn_reflns_theta_min         1.86
_exptl_absorpt_coefficient_mu    0.693
_exptl_crystal_density_diffrn    1.345
_exptl_crystal_description       cubic
_exptl_crystal_F_000             2608
_exptl_crystal_size_max          0.5
_exptl_crystal_size_mid          0.5
_exptl_crystal_size_min          0.5
_refine_diff_density_max         1.701
_refine_diff_density_min         -0.624
_refine_diff_density_rms         0.131
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_all   0.973
_refine_ls_goodness_of_fit_obs   1.182
_refine_ls_matrix_type           full
_refine_ls_number_parameters     685
_refine_ls_number_reflns         8986
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.973
_refine_ls_restrained_S_obs      1.182
_refine_ls_R_factor_all          0.1006
_refine_ls_R_factor_obs          0.0637
_refine_ls_shift/esd_max         0.001
_refine_ls_shift/esd_mean        0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0428P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_all         0.1432
_refine_ls_wR_factor_obs         0.1356
_reflns_number_observed          5682
_reflns_number_total             8986
_reflns_observed_criterion       >2sigma(I)
_cod_data_source_file            b005588n.txt
_cod_data_source_block           Compound(4)
_cod_depositor_comments
;
The following automatic conversions were performed:

'_refine_ls_weighting_scheme' value 'calc
w=1/[\s^2^(Fo^2^)+(0.0428P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3' was
changed to 'calc'. New tag '_refine_ls_weighting_details' was
created. The value of the new tag was set to
'w=1/[\s^2^(Fo^2^)+(0.0428P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'.

Automatic conversion script
Id: cif_fix_values 3143 2015-03-26 13:38:13Z robertas 
;
_cod_original_cell_volume        6208.9(34)
_cod_original_sg_symbol_H-M      P21/n
_cod_database_code               7010059
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_thermal_displace_type
_atom_site_occupancy
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_group
Rh1 Rh 0.43761(4) 0.14242(2) 0.63937(4) 0.0208(2) Uani 1 d . .
Rh2 Rh 0.24584(5) 0.10799(2) 0.74736(4) 0.0204(2) Uani 1 d . .
S1 S 0.41902(14) 0.09362(6) 0.75470(13) 0.0219(4) Uani 1 d . .
S2 S 0.25427(13) 0.13480(5) 0.58851(13) 0.0194(4) Uani 1 d . .
P1 P 0.44475(14) 0.18067(6) 0.50918(14) 0.0232(5) Uani 1 d . .
P2 P 0.08867(14) 0.13214(6) 0.74483(14) 0.0218(5) Uani 1 d . .
C C 0.5687(6) 0.1497(2) 0.6947(5) 0.028(2) Uani 1 d . .
C0 C 0.2541(5) 0.0858(3) 0.8662(6) 0.031(2) Uani 1 d . .
O O 0.6581(4) 0.1547(2) 0.7368(4) 0.047(2) Uani 1 d . .
O0 O 0.2610(4) 0.0704(2) 0.9402(5) 0.057(2) Uani 1 d . .
C11 C 0.5033(5) 0.0980(2) 0.8750(5) 0.021(2) Uani 1 d . .
C12 C 0.5045(5) 0.1308(2) 0.9361(5) 0.028(2) Uani 1 d . .
C13 C 0.5745(6) 0.1308(2) 1.0280(6) 0.033(2) Uani 1 d . .
H13 H 0.5773(6) 0.1529(2) 1.0681(6) 0.039 Uiso 1 calc R .
C14 C 0.6388(6) 0.0995(3) 1.0609(6) 0.041(2) Uani 1 d . .
C15 C 0.6372(6) 0.0674(3) 0.9991(6) 0.042(2) Uani 1 d . .
H15 H 0.6813(6) 0.0461(3) 1.0206(6) 0.051 Uiso 1 calc R .
C16 C 0.5714(6) 0.0660(2) 0.9054(5) 0.032(2) Uani 1 d . .
C121 C 0.4331(6) 0.1661(2) 0.9086(5) 0.028(2) Uani 1 d . .
H121 H 0.3845(6) 0.1594(2) 0.8466(5) 0.034 Uiso 1 calc R .
C122 C 0.4875(6) 0.2041(2) 0.8904(6) 0.044(2) Uani 1 d . .
H12A H 0.4387(6) 0.2254(2) 0.8732(6) 0.066 Uiso 1 calc R .
H12B H 0.5195(6) 0.1998(2) 0.8380(6) 0.066 Uiso 1 calc R .
H12C H 0.5385(6) 0.2112(2) 0.9487(6) 0.066 Uiso 1 calc R .
C123 C 0.3703(6) 0.1733(3) 0.9829(6) 0.045(2) Uani 1 d . .
H12D H 0.3260(6) 0.1957(3) 0.9628(6) 0.067 Uiso 1 calc R .
H12E H 0.4154(6) 0.1785(3) 1.0459(6) 0.067 Uiso 1 calc R .
H12F H 0.3300(6) 0.1500(3) 0.9866(6) 0.067 Uiso 1 calc R .
C141 C 0.7095(8) 0.0984(3) 1.1660(7) 0.067(3) Uani 1 d . .
H141 H 0.7544(8) 0.0753(3) 1.1692(7) 0.080 Uiso 1 calc R .
C142 C 0.7761(8) 0.1334(4) 1.1907(7) 0.084(4) Uani 1 d . .
H14A H 0.8140(8) 0.1368(4) 1.1423(7) 0.126 Uiso 1 calc R .
H14B H 0.8227(8) 0.1296(4) 1.2537(7) 0.126 Uiso 1 calc R .
H14C H 0.7352(8) 0.1566(4) 1.1923(7) 0.126 Uiso 1 calc R .
C143 C 0.6473(9) 0.0911(4) 1.2385(7) 0.098(5) Uani 1 d . .
H14D H 0.6054(9) 0.0679(4) 1.2193(7) 0.147 Uiso 1 calc R .
H14E H 0.6045(9) 0.1138(4) 1.2402(7) 0.147 Uiso 1 calc R .
H14F H 0.6921(9) 0.0870(4) 1.3022(7) 0.147 Uiso 1 calc R .
C161 C 0.5732(7) 0.0300(3) 0.8413(6) 0.041(2) Uani 1 d . .
H161 H 0.5036(7) 0.0266(3) 0.8002(6) 0.050 Uiso 1 calc R .
C162 C 0.6405(9) 0.0380(4) 0.7739(9) 0.101(4) Uani 1 d . .
H16A H 0.6412(9) 0.0151(4) 0.7335(9) 0.152 Uiso 1 calc R .
H16B H 0.7087(9) 0.0436(4) 0.8117(9) 0.152 Uiso 1 calc R .
H16C H 0.6146(9) 0.0606(4) 0.7332(9) 0.152 Uiso 1 calc R .
C163 C 0.6034(11) -0.0090(3) 0.8956(8) 0.129(6) Uani 1 d . .
H16D H 0.5599(11) -0.0138(3) 0.9384(8) 0.194 Uiso 1 calc R .
H16E H 0.6732(11) -0.0075(3) 0.9332(8) 0.194 Uiso 1 calc R .
H16F H 0.5963(11) -0.0304(3) 0.8493(8) 0.194 Uiso 1 calc R .
C21 C 0.1986(5) 0.1056(2) 0.4813(5) 0.024(2) Uani 1 d . .
C22 C 0.1279(5) 0.1257(2) 0.4035(5) 0.021(2) Uani 1 d . .
C23 C 0.0749(5) 0.1025(2) 0.3266(5) 0.025(2) Uani 1 d . .
H23 H 0.0277(5) 0.1152(2) 0.2763(5) 0.029 Uiso 1 calc R .
C24 C 0.0864(5) 0.0622(2) 0.3185(5) 0.027(2) Uani 1 d . .
C25 C 0.1600(5) 0.0433(2) 0.3923(5) 0.027(2) Uani 1 d . .
H25 H 0.1720(5) 0.0162(2) 0.3874(5) 0.032 Uiso 1 calc R .
C26 C 0.2160(5) 0.0646(2) 0.4736(5) 0.022(2) Uani 1 d . .
C221 C 0.1087(5) 0.1696(2) 0.4036(5) 0.027(2) Uani 1 d . .
H221 H 0.1722(5) 0.1821(2) 0.4410(5) 0.032 Uiso 1 calc R .
C222 C 0.0816(6) 0.1892(2) 0.3028(5) 0.034(2) Uani 1 d . .
H22A H 0.0705(6) 0.2172(2) 0.3097(5) 0.051 Uiso 1 calc R .
H22B H 0.0206(6) 0.1773(2) 0.2632(5) 0.051 Uiso 1 calc R .
H22C H 0.1367(6) 0.1854(2) 0.2722(5) 0.051 Uiso 1 calc R .
C223 C 0.0263(6) 0.1802(2) 0.4550(6) 0.040(2) Uani 1 d . .
H22D H 0.0162(6) 0.2085(2) 0.4531(6) 0.060 Uiso 1 calc R .
H22E H 0.0470(6) 0.1714(2) 0.5218(6) 0.060 Uiso 1 calc R .
H22F H -0.0364(6) 0.1672(2) 0.4226(6) 0.060 Uiso 1 calc R .
C241 C 0.0242(6) 0.0383(2) 0.2316(5) 0.033(2) Uani 1 d . .
H241 H -0.0185(6) 0.0573(2) 0.1863(5) 0.040 Uiso 1 calc R .
C242 C 0.0928(7) 0.0175(3) 0.1763(6) 0.056(3) Uani 1 d . .
H24A H 0.1367(7) 0.0368(3) 0.1575(6) 0.084 Uiso 1 calc R .
H24B H 0.0514(7) 0.0049(3) 0.1190(6) 0.084 Uiso 1 calc R .
H24C H 0.1336(7) -0.0022(3) 0.2178(6) 0.084 Uiso 1 calc R .
C243 C 0.2432(6) 0.0187(2) 0.6175(5) 0.034(2) Uani 1 d . .
H24D H 0.2938(6) 0.0046(2) 0.6659(5) 0.050 Uiso 1 calc R .
H24E H 0.1958(6) 0.0000(2) 0.5793(5) 0.050 Uiso 1 calc R .
H24F H 0.2073(6) 0.0369(2) 0.6493(5) 0.050 Uiso 1 calc R .
C261 C 0.2957(5) 0.0420(2) 0.5501(5) 0.025(2) Uani 1 d . .
H261 H 0.3404(5) 0.0618(2) 0.5906(5) 0.029 Uiso 1 calc R .
C262 C 0.3641(6) 0.0142(2) 0.5074(6) 0.036(2) Uani 1 d . .
H26A H 0.4121(6) 0.0010(2) 0.5597(6) 0.054 Uiso 1 calc R .
H26B H 0.4004(6) 0.0295(2) 0.4698(6) 0.054 Uiso 1 calc R .
H26C H 0.3224(6) -0.0054(2) 0.4660(6) 0.054 Uiso 1 calc R .
C263 C -0.0471(6) 0.0093(3) 0.2633(6) 0.053(3) Uani 1 d . .
H26D H -0.0851(6) -0.0053(3) 0.2075(6) 0.079 Uiso 1 calc R .
H26E H -0.0934(6) 0.0238(3) 0.2920(6) 0.079 Uiso 1 calc R .
H26F H -0.0078(6) -0.0089(3) 0.3106(6) 0.079 Uiso 1 calc R .
C31 C -0.0232(5) 0.1118(2) 0.6597(5) 0.025(2) Uani 1 d . .
C32 C -0.1226(5) 0.1166(2) 0.6696(5) 0.028(2) Uani 1 d . .
H32 H -0.1335(5) 0.1310(2) 0.7223(5) 0.034 Uiso 1 calc R .
C33 C -0.2053(6) 0.1002(3) 0.6023(6) 0.037(2) Uani 1 d . .
H33 H -0.2708(6) 0.1028(3) 0.6113(6) 0.044 Uiso 1 calc R .
C34 C -0.1902(6) 0.0799(2) 0.5211(6) 0.035(2) Uani 1 d . .
H34 H -0.2457(6) 0.0698(2) 0.4744(6) 0.042 Uiso 1 calc R .
C35 C -0.0931(6) 0.0750(2) 0.5108(6) 0.034(2) Uani 1 d . .
H35 H -0.0822(6) 0.0611(2) 0.4575(6) 0.040 Uiso 1 calc R .
C36 C -0.0105(6) 0.0910(2) 0.5802(5) 0.028(2) Uani 1 d . .
H36 H 0.0552(6) 0.0874(2) 0.5724(5) 0.034 Uiso 1 calc R .
C41 C 0.3966(5) 0.1539(2) 0.3954(5) 0.025(2) Uani 1 d . .
C42 C 0.3470(6) 0.1723(3) 0.3065(6) 0.035(2) Uani 1 d . .
H42 H 0.3354(6) 0.1996(3) 0.3046(6) 0.042 Uiso 1 calc R .
C43 C 0.3153(6) 0.1500(3) 0.2216(6) 0.047(3) Uani 1 d . .
H43 H 0.2830(6) 0.1626(3) 0.1634(6) 0.056 Uiso 1 calc R .
C44 C 0.3309(7) 0.1098(3) 0.2224(6) 0.047(2) Uani 1 d . .
H44 H 0.3088(7) 0.0951(3) 0.1651(6) 0.056 Uiso 1 calc R .
C45 C 0.3797(7) 0.0911(3) 0.3085(6) 0.050(3) Uani 1 d . .
H45 H 0.3917(7) 0.0638(3) 0.3094(6) 0.060 Uiso 1 calc R .
C46 C 0.4109(6) 0.1135(2) 0.3945(6) 0.038(2) Uani 1 d . .
H46 H 0.4422(6) 0.1007(2) 0.4527(6) 0.046 Uiso 1 calc R .
C51 C 0.6273(5) 0.1740(2) 0.4482(6) 0.030(2) Uani 1 d . .
C52 C 0.5768(5) 0.1957(2) 0.5040(5) 0.026(2) Uani 1 d . .
H52 H 0.5105(5) 0.1885(2) 0.5044(5) 0.031 Uiso 1 calc R .
C53 C 0.6216(6) 0.2273(2) 0.5587(6) 0.038(2) Uani 1 d . .
H53 H 0.5860(6) 0.2415(2) 0.5958(6) 0.045 Uiso 1 calc R .
C54 C 0.7193(6) 0.2380(3) 0.5587(7) 0.045(2) Uani 1 d . .
H54 H 0.7501(6) 0.2596(3) 0.5962(7) 0.053 Uiso 1 calc R .
C55 C 0.7711(6) 0.2175(3) 0.5048(6) 0.036(2) Uani 1 d . .
H55 H 0.8371(6) 0.2251(3) 0.5045(6) 0.043 Uiso 1 calc R .
C56 C 0.7270(6) 0.1856(3) 0.4507(6) 0.040(2) Uani 1 d . .
H56 H 0.7639(6) 0.1713(3) 0.4148(6) 0.048 Uiso 1 calc R .
C61 C 0.3803(5) 0.2285(2) 0.4930(5) 0.022(2) Uani 1 d . .
C62 C 0.3970(6) 0.2566(2) 0.4257(5) 0.030(2) Uani 1 d . .
H62 H 0.4461(6) 0.2514(2) 0.3917(5) 0.037 Uiso 1 calc R .
C63 C 0.3425(6) 0.2917(2) 0.4084(6) 0.035(2) Uani 1 d . .
H63 H 0.3521(6) 0.3092(2) 0.3605(6) 0.043 Uiso 1 calc R .
C64 C 0.2742(6) 0.3007(2) 0.4622(6) 0.037(2) Uani 1 d . .
H64 H 0.2389(6) 0.3248(2) 0.4524(6) 0.045 Uiso 1 calc R .
C65 C 0.2580(6) 0.2741(3) 0.5309(6) 0.041(2) Uani 1 d . .
H65 H 0.2114(6) 0.2801(3) 0.5672(6) 0.050 Uiso 1 calc R .
C66 C 0.3105(5) 0.2386(2) 0.5460(5) 0.030(2) Uani 1 d . .
H66 H 0.2991(5) 0.2210(2) 0.5929(5) 0.036 Uiso 1 calc R .
C71 C 0.0841(5) 0.1867(2) 0.7259(5) 0.020(2) Uani 1 d . .
C72 C -0.0073(5) 0.2072(2) 0.7007(5) 0.026(2) Uani 1 d . .
H72 H -0.0689(5) 0.1933(2) 0.6858(5) 0.031 Uiso 1 calc R .
C73 C -0.0071(6) 0.2491(2) 0.6977(6) 0.035(2) Uani 1 d . .
H73 H -0.0684(6) 0.2630(2) 0.6798(6) 0.042 Uiso 1 calc R .
C74 C 0.0836(6) 0.2691(2) 0.7213(5) 0.031(2) Uani 1 d . .
H74 H 0.0837(6) 0.2968(2) 0.7205(5) 0.037 Uiso 1 calc R .
C75 C 0.1754(6) 0.2487(2) 0.7462(5) 0.033(2) Uani 1 d . .
H75 H 0.2369(6) 0.2625(2) 0.7625(5) 0.039 Uiso 1 calc R .
C76 C 0.1751(6) 0.2075(2) 0.7467(5) 0.025(2) Uani 1 d . .
H76 H 0.2367(6) 0.1937(2) 0.7612(5) 0.030 Uiso 1 calc R .
C81 C 0.0526(5) 0.1302(2) 0.8620(5) 0.023(2) Uani 1 d . .
C82 C 0.0106(6) 0.0952(3) 0.8866(6) 0.041(2) Uani 1 d . .
H82 H -0.0017(6) 0.0738(3) 0.8433(6) 0.049 Uiso 1 calc R .
C83 C -0.0132(8) 0.0922(3) 0.9778(6) 0.059(3) Uani 1 d . .
H83 H -0.0475(8) 0.0700(3) 0.9927(6) 0.071 Uiso 1 calc R .
C84 C 0.0148(7) 0.1224(3) 1.0442(6) 0.057(3) Uani 1 d . .
H84 H 0.0030(7) 0.1199(3) 1.1059(6) 0.068 Uiso 1 calc R .
C85 C 0.0599(6) 0.1563(3) 1.0216(6) 0.041(2) Uani 1 d . .
H85 H 0.0759(6) 0.1772(3) 1.0661(6) 0.049 Uiso 1 calc R .
C86 C 0.0812(5) 0.1590(2) 0.9312(5) 0.025(2) Uani 1 d . .
H86 H 0.1162(5) 0.1811(2) 0.9173(5) 0.030 Uiso 1 calc R .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C Rh1 P1 92.1(2) . . ?
C Rh1 S1 93.5(2) . . ?
P1 Rh1 S1 169.90(7) . . ?
C Rh1 S2 171.1(2) . . ?
P1 Rh1 S2 94.03(7) . . ?
S1 Rh1 S2 81.45(6) . . ?
C0 Rh2 P2 89.9(2) . . ?
C0 Rh2 S1 92.7(2) . . ?
P2 Rh2 S1 170.69(7) . . ?
C0 Rh2 S2 173.4(2) . . ?
P2 Rh2 S2 96.65(7) . . ?
S1 Rh2 S2 80.76(6) . . ?
C11 S1 Rh1 116.2(2) . . ?
C11 S1 Rh2 114.1(2) . . ?
Rh1 S1 Rh2 96.05(7) . . ?
C21 S2 Rh1 119.1(2) . . ?
C21 S2 Rh2 117.7(3) . . ?
Rh1 S2 Rh2 92.81(6) . . ?
C41 P1 C61 105.8(3) . . ?
C41 P1 C52 103.3(3) . . ?
C61 P1 C52 101.0(3) . . ?
C41 P1 Rh1 111.1(3) . . ?
C61 P1 Rh1 119.1(2) . . ?
C52 P1 Rh1 114.9(2) . . ?
C31 P2 C81 102.5(3) . . ?
C31 P2 C71 106.6(3) . . ?
C81 P2 C71 99.1(3) . . ?
C31 P2 Rh2 119.8(3) . . ?
C81 P2 Rh2 115.7(2) . . ?
C71 P2 Rh2 110.7(2) . . ?
O C Rh1 177.1(6) . . ?
O0 C0 Rh2 177.3(8) . . ?
C12 C11 C16 120.6(6) . . ?
C12 C11 S1 123.7(6) . . ?
C16 C11 S1 115.7(5) . . ?
C11 C12 C13 118.3(7) . . ?
C11 C12 C121 123.5(6) . . ?
C13 C12 C121 118.3(7) . . ?
C14 C13 C12 122.5(8) . . ?
C13 C14 C15 118.5(7) . . ?
C13 C14 C141 122.0(8) . . ?
C15 C14 C141 119.5(8) . . ?
C14 C15 C16 121.9(8) . . ?
C15 C16 C11 118.2(7) . . ?
C15 C16 C161 119.4(7) . . ?
C11 C16 C161 122.3(6) . . ?
C12 C121 C123 112.0(6) . . ?
C12 C121 C122 113.2(6) . . ?
C123 C121 C122 111.2(7) . . ?
C142 C141 C143 112.7(9) . . ?
C142 C141 C14 113.7(9) . . ?
C143 C141 C14 109.9(8) . . ?
C162 C161 C16 110.0(8) . . ?
C162 C161 C163 110.2(8) . . ?
C16 C161 C163 115.4(7) . . ?
C26 C21 C22 119.8(7) . . ?
C26 C21 S2 123.8(6) . . ?
C22 C21 S2 116.4(6) . . ?
C23 C22 C21 116.8(7) . . ?
C23 C22 C221 120.0(6) . . ?
C21 C22 C221 123.2(6) . . ?
C24 C23 C22 125.1(7) . . ?
C23 C24 C25 117.4(7) . . ?
C23 C24 C241 122.3(7) . . ?
C25 C24 C241 120.3(7) . . ?
C24 C25 C26 121.0(7) . . ?
C25 C26 C21 119.7(7) . . ?
C25 C26 C261 117.9(7) . . ?
C21 C26 C261 122.3(6) . . ?
C22 C221 C223 112.2(6) . . ?
C22 C221 C222 115.1(6) . . ?
C223 C221 C222 108.3(6) . . ?
C263 C241 C24 111.2(7) . . ?
C263 C241 C242 111.9(8) . . ?
C24 C241 C242 111.6(7) . . ?
C26 C261 C243 109.8(6) . . ?
C26 C261 C262 114.2(6) . . ?
C243 C261 C262 110.5(6) . . ?
C36 C31 C32 117.7(7) . . ?
C36 C31 P2 118.7(6) . . ?
C32 C31 P2 123.6(6) . . ?
C33 C32 C31 121.1(7) . . ?
C32 C33 C34 119.9(7) . . ?
C35 C34 C33 119.4(7) . . ?
C34 C35 C36 119.9(8) . . ?
C31 C36 C35 121.9(7) . . ?
C46 C41 C42 117.5(7) . . ?
C46 C41 P1 118.5(6) . . ?
C42 C41 P1 123.9(6) . . ?
C43 C42 C41 120.6(8) . . ?
C44 C43 C42 120.9(8) . . ?
C43 C44 C45 119.7(8) . . ?
C44 C45 C46 119.4(9) . . ?
C41 C46 C45 121.8(8) . . ?
C52 C51 C56 117.2(8) . . ?
C53 C52 C51 121.6(7) . . ?
C53 C52 P1 118.5(6) . . ?
C51 C52 P1 119.9(6) . . ?
C54 C53 C52 119.7(8) . . ?
C55 C54 C53 120.2(8) . . ?
C54 C55 C56 120.2(8) . . ?
C55 C56 C51 121.0(8) . . ?
C62 C61 C66 116.8(7) . . ?
C62 C61 P1 121.8(6) . . ?
C66 C61 P1 121.3(6) . . ?
C63 C62 C61 121.8(7) . . ?
C64 C63 C62 119.6(8) . . ?
C63 C64 C65 119.8(8) . . ?
C66 C65 C64 120.2(8) . . ?
C65 C66 C61 121.6(8) . . ?
C76 C71 C72 119.8(7) . . ?
C76 C71 P2 118.3(5) . . ?
C72 C71 P2 121.6(5) . . ?
C71 C72 C73 119.7(7) . . ?
C74 C73 C72 119.6(7) . . ?
C73 C74 C75 120.8(8) . . ?
C76 C75 C74 119.5(8) . . ?
C75 C76 C71 120.6(7) . . ?
C86 C81 C82 118.7(7) . . ?
C86 C81 P2 122.0(6) . . ?
C82 C81 P2 118.3(6) . . ?
C83 C82 C81 119.5(8) . . ?
C84 C83 C82 119.1(9) . . ?
C83 C84 C85 121.3(9) . . ?
C86 C85 C84 118.7(8) . . ?
C85 C86 C81 122.2(8) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Rh1 C 1.764(8) . ?
Rh1 P1 2.266(2) . ?
Rh1 S1 2.369(2) . ?
Rh1 S2 2.415(2) . ?
Rh2 C0 1.814(8) . ?
Rh2 P2 2.267(2) . ?
Rh2 S1 2.368(2) . ?
Rh2 S2 2.448(2) . ?
S1 C11 1.798(7) . ?
S2 C21 1.803(7) . ?
P1 C41 1.813(7) . ?
P1 C61 1.813(8) . ?
P1 C52 1.876(7) . ?
P2 C31 1.812(7) . ?
P2 C81 1.842(7) . ?
P2 C71 1.851(8) . ?
C O 1.217(8) . ?
C0 O0 1.150(9) . ?
C11 C12 1.395(10) . ?
C11 C16 1.411(10) . ?
C12 C13 1.399(10) . ?
C12 C121 1.518(10) . ?
C13 C14 1.368(11) . ?
C14 C15 1.386(12) . ?
C14 C141 1.550(11) . ?
C15 C16 1.397(10) . ?
C16 C161 1.512(11) . ?
C121 C123 1.527(10) . ?
C121 C122 1.526(11) . ?
C141 C142 1.466(14) . ?
C141 C143 1.502(14) . ?
C161 C162 1.500(13) . ?
C161 C163 1.522(13) . ?
C21 C26 1.405(10) . ?
C21 C22 1.431(10) . ?
C22 C23 1.381(10) . ?
C22 C221 1.498(10) . ?
C23 C24 1.370(10) . ?
C24 C25 1.398(10) . ?
C24 C241 1.529(10) . ?
C25 C26 1.400(10) . ?
C26 C261 1.521(9) . ?
C221 C223 1.519(10) . ?
C221 C222 1.525(10) . ?
C241 C263 1.515(11) . ?
C241 C242 1.526(11) . ?
C243 C261 1.539(10) . ?
C261 C262 1.542(10) . ?
C31 C36 1.369(10) . ?
C31 C32 1.397(10) . ?
C32 C33 1.384(10) . ?
C33 C34 1.394(11) . ?
C34 C35 1.369(10) . ?
C35 C36 1.394(10) . ?
C41 C46 1.371(11) . ?
C41 C42 1.407(10) . ?
C42 C43 1.386(11) . ?
C43 C44 1.365(13) . ?
C44 C45 1.380(12) . ?
C45 C46 1.402(11) . ?
C51 C52 1.374(10) . ?
C51 C56 1.395(10) . ?
C52 C53 1.361(10) . ?
C53 C54 1.371(10) . ?
C54 C55 1.348(11) . ?
C55 C56 1.362(12) . ?
C61 C62 1.398(10) . ?
C61 C66 1.387(10) . ?
C62 C63 1.380(11) . ?
C63 C64 1.371(11) . ?
C64 C65 1.378(11) . ?
C65 C66 1.375(11) . ?
C71 C76 1.381(9) . ?
C71 C72 1.380(9) . ?
C72 C73 1.408(11) . ?
C73 C74 1.364(10) . ?
C74 C75 1.385(10) . ?
C75 C76 1.381(11) . ?
C81 C86 1.359(10) . ?
C81 C82 1.389(11) . ?
C82 C83 1.409(11) . ?
C83 C84 1.370(13) . ?
C84 C85 1.365(12) . ?
C85 C86 1.382(10) . ?
