#------------------------------------------------------------------------------
#$Date: 2016-02-16 03:10:39 +0200 (Tue, 16 Feb 2016) $
#$Revision: 176453 $
#$URL: svn://www.crystallography.net/cod/cif/7/01/02/7010269.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7010269
loop_
_publ_author_name
'Tulloch, Arran A. D.'
'Danopoulos, Andreas A.'
'Winston, Scott'
'Kleinhenz, Sven'
'Eastham, Graham'
_publ_section_title
;
 N-Functionalised heterocyclic carbene complexes of silver
;
_journal_issue                   24
_journal_name_full
'Journal of the Chemical Society, Dalton Transactions'
_journal_page_first              4499
_journal_paper_doi               10.1039/b007504n
_journal_year                    2000
_chemical_formula_moiety         'C42 H44 Ag2 Cl2 N4'
_chemical_formula_sum            'C32.5 H35 Ag2 Cl3 N4'
_chemical_formula_weight         803.73
_chemical_name_common            00skl036
_chemical_name_systematic
;
a,a'-bis(3-mesityl-imidazol-2-ylidene)-o-xylene bis
(silver bromide)
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yab'
_symmetry_space_group_name_H-M   'P 1 21/a 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 117.4070(10)
_cell_angle_gamma                90.0000(10)
_cell_formula_units_Z            4
_cell_length_a                   17.2853(3)
_cell_length_b                   12.7079(3)
_cell_length_c                   18.5879(4)
_cell_measurement_reflns_used    51246
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      30.508
_cell_measurement_theta_min      1.018
_cell_volume                     3624.73(14)
_computing_cell_refinement       'Scalepack (Otwinowski & Minor 1997)'
_computing_data_collection       'Collect (Nonius BV, 1997-2000)'
_computing_data_reduction
'Denzo a. Scalepack (Otwinowski & Minor 1997)'
_computing_molecular_graphics    'ORTEP-3 (Farrugia, 1997)'
_computing_publication_material  'PLATON (Spek, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      150(2)
_diffrn_detector_area_resol_mean '9.091 pixels/mm'
_diffrn_measured_fraction_theta_full 0.858
_diffrn_measured_fraction_theta_max 0.858
_diffrn_measurement_device_type  'Enraf Nonius KappaCCD area detector'
_diffrn_measurement_method       'π and θ scans to fill Ewald sphere'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0821
_diffrn_reflns_av_sigmaI/netI    0.1081
_diffrn_reflns_limit_h_max       24
_diffrn_reflns_limit_h_min       -24
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_number            35356
_diffrn_reflns_theta_full        30.50
_diffrn_reflns_theta_max         30.50
_diffrn_reflns_theta_min         1.23
_diffrn_standards_decay_%        n/a
_diffrn_standards_interval_count n/a
_diffrn_standards_interval_time  n/a
_diffrn_standards_number         n/a
_exptl_absorpt_coefficient_mu    1.327
_exptl_absorpt_correction_T_max  0.9366
_exptl_absorpt_correction_T_min  0.8787
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
SORTAV - multi-scan from symmetry-related measurements (Blessing, 1995-1997)
;
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.473
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             1612
_exptl_crystal_size_max          0.10
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.05
_refine_diff_density_max         1.982
_refine_diff_density_min         -1.021
_refine_diff_density_rms         0.172
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.980
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     361
_refine_ls_number_reflns         9486
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.980
_refine_ls_R_factor_all          0.1598
_refine_ls_R_factor_gt           0.0734
_refine_ls_shift/su_max          0.034
_refine_ls_shift/su_mean         0.005
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1278P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2093
_refine_ls_wR_factor_ref         0.2360
_reflns_number_gt                4259
_reflns_number_total             9486
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b007504n.txt
_cod_data_source_block           11b
_cod_original_cell_volume        3624.73(13)
_cod_original_sg_symbol_H-M      'P 21/a'
_cod_original_formula_sum        'C32.50 H35 Ag2 Cl3 N4'
_cod_database_code               7010269
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z'
'-x, -y, -z'
'x-1/2, -y-1/2, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag2 Ag 0.75713(4) 0.83276(5) 0.79553(3) 0.0669(2) Uani 1 1 d . . .
Ag1 Ag 0.17093(4) 0.76188(4) 0.56683(3) 0.0596(2) Uani 1 1 d . . .
Cl2 Cl 0.85763(10) 0.90273(13) 0.75288(9) 0.0498(4) Uani 1 1 d . . .
Cl1 Cl 0.09236(13) 0.64421(14) 0.60526(13) 0.0665(5) Uani 1 1 d . . .
N6 N 0.7468(4) 0.7323(4) 0.9398(3) 0.0547(14) Uani 1 1 d . . .
C32 C 0.8379(5) 0.7512(6) 0.9857(4) 0.063(2) Uani 1 1 d . . .
N1 N 0.2013(4) 0.9323(4) 0.4656(3) 0.0542(14) Uani 1 1 d . . .
N3 N 0.6194(4) 0.7313(5) 0.8411(3) 0.0542(14) Uani 1 1 d . . .
C9 C 0.5002(7) 1.0180(7) 0.8370(5) 0.080(2) Uani 1 1 d . . .
H9 H 0.5258 1.0617 0.8837 0.096 Uiso 1 1 calc R . .
C27 C 1.0129(6) 0.8093(9) 1.0752(5) 0.087(3) Uani 1 1 d . . .
C29 C 0.9506(6) 0.8590(8) 1.0852(5) 0.089(3) Uani 1 1 d . . .
H29 H 0.9687 0.9149 1.1235 0.107 Uiso 1 1 calc R . .
C2 C 0.7026(5) 0.7622(5) 0.8634(4) 0.0597(19) Uani 1 1 d . . .
C21 C 0.0752(5) 1.0389(5) 0.4423(4) 0.0542(17) Uani 1 1 d . . .
C12 C 0.5438(5) 0.7558(6) 0.7657(4) 0.066(2) Uani 1 1 d . . .
H12A H 0.5003 0.6989 0.7529 0.079 Uiso 1 1 calc R . .
H12B H 0.5612 0.7575 0.7219 0.079 Uiso 1 1 calc R . .
N2 N 0.3230(4) 0.8728(5) 0.5538(4) 0.0619(15) Uani 1 1 d . . .
C4 C 0.3423(4) 0.9425(6) 0.5085(4) 0.0598(19) Uani 1 1 d . . .
H4 H 0.3987 0.9590 0.5149 0.072 Uiso 1 1 calc R . .
C10 C 0.5371(5) 0.9272(6) 0.8348(4) 0.065(2) Uani 1 1 d . . .
H10 H 0.5894 0.9067 0.8806 0.078 Uiso 1 1 calc R . .
C13 C 0.6135(6) 0.6802(6) 0.9050(5) 0.073(2) Uani 1 1 d . . .
H13 H 0.5629 0.6509 0.9048 0.088 Uiso 1 1 calc R . .
C20 C -0.0112(5) 1.0609(6) 0.3959(4) 0.0615(19) Uani 1 1 d . . .
H20 H -0.0351 1.1196 0.4104 0.074 Uiso 1 1 calc R . .
C3 C 0.2670(5) 0.9830(7) 0.4534(5) 0.069(2) Uani 1 1 d . . .
H3 H 0.2592 1.0353 0.4141 0.083 Uiso 1 1 calc R . .
C11 C 0.5014(4) 0.8604(5) 0.7669(4) 0.0556(17) Uani 1 1 d . . .
C8 C 0.4227(7) 1.0483(7) 0.7692(6) 0.087(3) Uani 1 1 d . . .
H8 H 0.3953 1.1126 0.7703 0.105 Uiso 1 1 calc R . .
C16 C 0.0605(5) 0.8915(6) 0.3520(5) 0.0615(18) Uani 1 1 d . . .
C15 C 0.0969(6) 0.7996(8) 0.3301(6) 0.095(3) Uani 1 1 d . . .
H15A H 0.0520 0.7678 0.2804 0.143 Uiso 1 1 calc R . .
H15B H 0.1170 0.7480 0.3742 0.143 Uiso 1 1 calc R . .
H15C H 0.1462 0.8219 0.3213 0.143 Uiso 1 1 calc R . .
C19 C -0.1601(5) 1.0268(8) 0.2836(5) 0.088(3) Uani 1 1 d . . .
H19A H -0.1726 1.0891 0.3076 0.132 Uiso 1 1 calc R . .
H19B H -0.1943 0.9670 0.2868 0.132 Uiso 1 1 calc R . .
H19C H -0.1757 1.0409 0.2267 0.132 Uiso 1 1 calc R . .
C24 C 0.8715(6) 0.6040(8) 0.9174(6) 0.093(3) Uani 1 1 d . . .
H24A H 0.9234 0.5730 0.9172 0.139 Uiso 1 1 calc R . .
H24B H 0.8315 0.6283 0.8627 0.139 Uiso 1 1 calc R . .
H24C H 0.8424 0.5511 0.9347 0.139 Uiso 1 1 calc R . .
C31 C 0.7945(7) 0.8980(8) 1.0583(6) 0.109(3) Uani 1 1 d . . .
H31A H 0.7373 0.8673 1.0233 0.163 Uiso 1 1 calc R . .
H31B H 0.7948 0.9721 1.0441 0.163 Uiso 1 1 calc R . .
H31C H 0.8062 0.8927 1.1151 0.163 Uiso 1 1 calc R . .
C14 C 0.6964(5) 0.6814(7) 0.9680(5) 0.070(2) Uani 1 1 d . . .
H14 H 0.7151 0.6527 1.0206 0.083 Uiso 1 1 calc R . .
C6 C 0.4255(5) 0.8910(6) 0.6976(5) 0.0616(19) Uani 1 1 d . . .
C7 C 0.3855(6) 0.9846(6) 0.7000(5) 0.072(2) Uani 1 1 d . . .
H7 H 0.3329 1.0055 0.6547 0.087 Uiso 1 1 calc R . .
C23 C 0.1094(5) 0.9527(5) 0.4187(4) 0.0544(17) Uani 1 1 d . . .
C18 C -0.0660(5) 1.0015(6) 0.3285(5) 0.064(2) Uani 1 1 d . . .
C30 C 0.8647(7) 0.8384(6) 1.0468(5) 0.075(2) Uani 1 1 d . . .
C1 C 0.2371(5) 0.8629(5) 0.5278(4) 0.0516(16) Uani 1 1 d . . .
C26 C 0.9874(6) 0.7244(8) 1.0202(5) 0.077(2) Uani 1 1 d . . .
H26 H 1.0302 0.6856 1.0130 0.092 Uiso 1 1 calc R . .
C17 C -0.0289(5) 0.9183(7) 0.3094(5) 0.072(2) Uani 1 1 d . . .
H17 H -0.0655 0.8756 0.2646 0.086 Uiso 1 1 calc R . .
C5 C 0.3879(5) 0.8213(6) 0.6268(4) 0.0589(18) Uani 1 1 d . . .
H5A H 0.4354 0.7942 0.6162 0.071 Uiso 1 1 calc R . .
H5B H 0.3605 0.7603 0.6393 0.071 Uiso 1 1 calc R . .
C25 C 0.8985(5) 0.6967(7) 0.9756(4) 0.0640(19) Uani 1 1 d . . .
C22 C 0.1298(6) 1.1057(7) 0.5120(5) 0.081(2) Uani 1 1 d . . .
H22A H 0.0941 1.1618 0.5176 0.121 Uiso 1 1 calc R . .
H22B H 0.1768 1.1368 0.5035 0.121 Uiso 1 1 calc R . .
H22C H 0.1549 1.0629 0.5614 0.121 Uiso 1 1 calc R . .
C28 C 1.1066(7) 0.8383(11) 1.1195(6) 0.137(5) Uani 1 1 d . . .
H28A H 1.1138 0.8983 1.1552 0.205 Uiso 1 1 calc R . .
H28B H 1.1277 0.8575 1.0805 0.205 Uiso 1 1 calc R . .
H28C H 1.1402 0.7783 1.1520 0.205 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C2 Ag2 Cl2 163.3(2) . . ?
C1 Ag1 Cl1 177.4(2) . . ?
C2 N6 C14 113.1(7) . . ?
C2 N6 C32 121.8(6) . . ?
C14 N6 C32 125.0(6) . . ?
C25 C32 N6 123.4(7) . . ?
C25 C32 C30 119.9(8) . . ?
N6 C32 C30 116.7(7) . . ?
C1 N1 C3 110.4(6) . . ?
C1 N1 C23 125.2(5) . . ?
C3 N1 C23 124.3(6) . . ?
C2 N3 C13 110.9(6) . . ?
C2 N3 C12 126.2(6) . . ?
C13 N3 C12 122.6(6) . . ?
C10 C9 C8 118.9(8) . . ?
C10 C9 H9 120.6 . . ?
C8 C9 H9 120.6 . . ?
C29 C27 C26 117.4(8) . . ?
C29 C27 C28 123.4(10) . . ?
C26 C27 C28 119.2(10) . . ?
C27 C29 C30 126.8(9) . . ?
C27 C29 H29 116.6 . . ?
C30 C29 H29 116.6 . . ?
N6 C2 N3 104.5(6) . . ?
N6 C2 Ag2 125.0(6) . . ?
N3 C2 Ag2 130.4(5) . . ?
C20 C21 C23 117.1(7) . . ?
C20 C21 C22 120.6(7) . . ?
C23 C21 C22 122.2(7) . . ?
N3 C12 C11 113.6(6) . . ?
N3 C12 H12A 108.8 . . ?
C11 C12 H12A 108.8 . . ?
N3 C12 H12B 108.8 . . ?
C11 C12 H12B 108.8 . . ?
H12A C12 H12B 107.7 . . ?
C1 N2 C4 112.5(6) . . ?
C1 N2 C5 123.0(6) . . ?
C4 N2 C5 124.3(6) . . ?
C3 C4 N2 107.2(6) . . ?
C3 C4 H4 126.4 . . ?
N2 C4 H4 126.4 . . ?
C9 C10 C11 122.3(8) . . ?
C9 C10 H10 118.9 . . ?
C11 C10 H10 118.9 . . ?
C14 C13 N3 105.3(7) . . ?
C14 C13 H13 127.3 . . ?
N3 C13 H13 127.3 . . ?
C21 C20 C18 123.4(7) . . ?
C21 C20 H20 118.3 . . ?
C18 C20 H20 118.3 . . ?
C4 C3 N1 105.8(6) . . ?
C4 C3 H3 127.1 . . ?
N1 C3 H3 127.1 . . ?
C6 C11 C10 119.6(7) . . ?
C6 C11 C12 118.8(6) . . ?
C10 C11 C12 121.6(6) . . ?
C7 C8 C9 120.6(8) . . ?
C7 C8 H8 119.7 . . ?
C9 C8 H8 119.7 . . ?
C23 C16 C17 115.4(7) . . ?
C23 C16 C15 122.3(7) . . ?
C17 C16 C15 122.2(7) . . ?
C16 C15 H15A 109.5 . . ?
C16 C15 H15B 109.5 . . ?
H15A C15 H15B 109.5 . . ?
C16 C15 H15C 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
C18 C19 H19A 109.5 . . ?
C18 C19 H19B 109.5 . . ?
H19A C19 H19B 109.5 . . ?
C18 C19 H19C 109.5 . . ?
H19A C19 H19C 109.5 . . ?
H19B C19 H19C 109.5 . . ?
C25 C24 H24A 109.5 . . ?
C25 C24 H24B 109.5 . . ?
H24A C24 H24B 109.5 . . ?
C25 C24 H24C 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?
C30 C31 H31A 109.5 . . ?
C30 C31 H31B 109.5 . . ?
H31A C31 H31B 109.5 . . ?
C30 C31 H31C 109.5 . . ?
H31A C31 H31C 109.5 . . ?
H31B C31 H31C 109.5 . . ?
N6 C14 C13 106.1(7) . . ?
N6 C14 H14 126.9 . . ?
C13 C14 H14 126.9 . . ?
C7 C6 C11 118.5(7) . . ?
C7 C6 C5 121.7(7) . . ?
C11 C6 C5 119.7(7) . . ?
C6 C7 C8 120.1(8) . . ?
C6 C7 H7 120.0 . . ?
C8 C7 H7 120.0 . . ?
C16 C23 C21 123.3(7) . . ?
C16 C23 N1 119.5(6) . . ?
C21 C23 N1 117.1(6) . . ?
C17 C18 C20 116.5(7) . . ?
C17 C18 C19 123.1(8) . . ?
C20 C18 C19 120.3(7) . . ?
C29 C30 C32 115.4(8) . . ?
C29 C30 C31 125.7(8) . . ?
C32 C30 C31 118.9(8) . . ?
N2 C1 N1 104.0(6) . . ?
N2 C1 Ag1 129.3(5) . . ?
N1 C1 Ag1 126.6(5) . . ?
C27 C26 C25 120.6(9) . . ?
C27 C26 H26 119.7 . . ?
C25 C26 H26 119.7 . . ?
C18 C17 C16 124.2(8) . . ?
C18 C17 H17 117.9 . . ?
C16 C17 H17 117.9 . . ?
N2 C5 C6 113.4(6) . . ?
N2 C5 H5A 108.9 . . ?
C6 C5 H5A 108.9 . . ?
N2 C5 H5B 108.9 . . ?
C6 C5 H5B 108.9 . . ?
H5A C5 H5B 107.7 . . ?
C32 C25 C26 119.9(8) . . ?
C32 C25 C24 119.8(7) . . ?
C26 C25 C24 120.3(8) . . ?
C21 C22 H22A 109.5 . . ?
C21 C22 H22B 109.5 . . ?
H22A C22 H22B 109.5 . . ?
C21 C22 H22C 109.5 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?
C27 C28 H28A 109.5 . . ?
C27 C28 H28B 109.5 . . ?
H28A C28 H28B 109.5 . . ?
C27 C28 H28C 109.5 . . ?
H28A C28 H28C 109.5 . . ?
H28B C28 H28C 109.5 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag2 C2 2.092(8) . ?
Ag2 Cl2 2.3886(15) . ?
Ag1 C1 2.061(7) . ?
Ag1 Cl1 2.3419(18) . ?
N6 C2 1.321(8) . ?
N6 C14 1.368(9) . ?
N6 C32 1.424(9) . ?
C32 C25 1.339(11) . ?
C32 C30 1.500(11) . ?
N1 C1 1.355(8) . ?
N1 C3 1.412(9) . ?
N1 C23 1.442(8) . ?
N3 C2 1.360(9) . ?
N3 C13 1.397(9) . ?
N3 C12 1.443(9) . ?
C9 C10 1.328(10) . ?
C9 C8 1.407(12) . ?
C9 H9 0.9500 . ?
C27 C29 1.333(13) . ?
C27 C26 1.411(13) . ?
C27 C28 1.487(12) . ?
C29 C30 1.343(12) . ?
C29 H29 0.9500 . ?
C21 C20 1.366(9) . ?
C21 C23 1.407(9) . ?
C21 C22 1.472(10) . ?
C12 C11 1.523(10) . ?
C12 H12A 0.9900 . ?
C12 H12B 0.9900 . ?
N2 C1 1.339(8) . ?
N2 C4 1.365(9) . ?
N2 C5 1.458(9) . ?
C4 C3 1.334(10) . ?
C4 H4 0.9500 . ?
C10 C11 1.407(10) . ?
C10 H10 0.9500 . ?
C13 C14 1.371(11) . ?
C13 H13 0.9500 . ?
C20 C18 1.394(10) . ?
C20 H20 0.9500 . ?
C3 H3 0.9500 . ?
C11 C6 1.405(10) . ?
C8 C7 1.400(12) . ?
C8 H8 0.9500 . ?
C16 C23 1.375(10) . ?
C16 C17 1.415(10) . ?
C16 C15 1.470(11) . ?
C15 H15A 0.9800 . ?
C15 H15B 0.9800 . ?
C15 H15C 0.9800 . ?
C19 C18 1.481(10) . ?
C19 H19A 0.9800 . ?
C19 H19B 0.9800 . ?
C19 H19C 0.9800 . ?
C24 C25 1.520(12) . ?
C24 H24A 0.9800 . ?
C24 H24B 0.9800 . ?
C24 H24C 0.9800 . ?
C31 C30 1.528(13) . ?
C31 H31A 0.9800 . ?
C31 H31B 0.9800 . ?
C31 H31C 0.9800 . ?
C14 H14 0.9500 . ?
C6 C7 1.386(10) . ?
C6 C5 1.467(10) . ?
C7 H7 0.9500 . ?
C18 C17 1.367(11) . ?
C26 C25 1.414(11) . ?
C26 H26 0.9500 . ?
C17 H17 0.9500 . ?
C5 H5A 0.9900 . ?
C5 H5B 0.9900 . ?
C22 H22A 0.9800 . ?
C22 H22B 0.9800 . ?
C22 H22C 0.9800 . ?
C28 H28A 0.9800 . ?
C28 H28B 0.9800 . ?
C28 H28C 0.9800 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C2 N6 C32 C25 -74.5(10) . . . . ?
C14 N6 C32 C25 104.4(9) . . . . ?
C2 N6 C32 C30 104.4(8) . . . . ?
C14 N6 C32 C30 -76.7(9) . . . . ?
C26 C27 C29 C30 -1.6(16) . . . . ?
C28 C27 C29 C30 179.0(10) . . . . ?
C14 N6 C2 N3 1.2(8) . . . . ?
C32 N6 C2 N3 -179.7(6) . . . . ?
C14 N6 C2 Ag2 -175.5(5) . . . . ?
C32 N6 C2 Ag2 3.5(9) . . . . ?
C13 N3 C2 N6 -1.0(8) . . . . ?
C12 N3 C2 N6 172.8(6) . . . . ?
C13 N3 C2 Ag2 175.5(5) . . . . ?
C12 N3 C2 Ag2 -10.6(11) . . . . ?
Cl2 Ag2 C2 N6 5.3(11) . . . . ?
Cl2 Ag2 C2 N3 -170.6(4) . . . . ?
C2 N3 C12 C11 -86.6(8) . . . . ?
C13 N3 C12 C11 86.5(8) . . . . ?
C1 N2 C4 C3 2.9(9) . . . . ?
C5 N2 C4 C3 -172.1(7) . . . . ?
C8 C9 C10 C11 0.1(13) . . . . ?
C2 N3 C13 C14 0.5(8) . . . . ?
C12 N3 C13 C14 -173.6(7) . . . . ?
C23 C21 C20 C18 1.2(10) . . . . ?
C22 C21 C20 C18 179.2(7) . . . . ?
N2 C4 C3 N1 -2.0(8) . . . . ?
C1 N1 C3 C4 0.5(8) . . . . ?
C23 N1 C3 C4 -180.0(6) . . . . ?
C9 C10 C11 C6 1.9(11) . . . . ?
C9 C10 C11 C12 -179.2(7) . . . . ?
N3 C12 C11 C6 -177.9(6) . . . . ?
N3 C12 C11 C10 3.2(10) . . . . ?
C10 C9 C8 C7 -0.8(13) . . . . ?
C2 N6 C14 C13 -1.0(9) . . . . ?
C32 N6 C14 C13 -179.9(7) . . . . ?
N3 C13 C14 N6 0.3(8) . . . . ?
C10 C11 C6 C7 -3.1(10) . . . . ?
C12 C11 C6 C7 177.9(7) . . . . ?
C10 C11 C6 C5 -179.8(7) . . . . ?
C12 C11 C6 C5 1.2(10) . . . . ?
C11 C6 C7 C8 2.4(11) . . . . ?
C5 C6 C7 C8 179.1(7) . . . . ?
C9 C8 C7 C6 -0.5(13) . . . . ?
C17 C16 C23 C21 -2.5(11) . . . . ?
C15 C16 C23 C21 -177.8(8) . . . . ?
C17 C16 C23 N1 -179.4(6) . . . . ?
C15 C16 C23 N1 5.2(11) . . . . ?
C20 C21 C23 C16 0.5(10) . . . . ?
C22 C21 C23 C16 -177.5(7) . . . . ?
C20 C21 C23 N1 177.5(6) . . . . ?
C22 C21 C23 N1 -0.5(10) . . . . ?
C1 N1 C23 C16 -87.2(8) . . . . ?
C3 N1 C23 C16 93.3(8) . . . . ?
C1 N1 C23 C21 95.6(8) . . . . ?
C3 N1 C23 C21 -83.9(8) . . . . ?
C21 C20 C18 C17 -0.6(11) . . . . ?
C21 C20 C18 C19 176.9(7) . . . . ?
C27 C29 C30 C32 -1.0(14) . . . . ?
C27 C29 C30 C31 -178.9(10) . . . . ?
C25 C32 C30 C29 3.2(11) . . . . ?
N6 C32 C30 C29 -175.7(7) . . . . ?
C25 C32 C30 C31 -178.8(8) . . . . ?
N6 C32 C30 C31 2.3(10) . . . . ?
C4 N2 C1 N1 -2.5(8) . . . . ?
C5 N2 C1 N1 172.6(6) . . . . ?
C4 N2 C1 Ag1 174.7(5) . . . . ?
C5 N2 C1 Ag1 -10.2(10) . . . . ?
C3 N1 C1 N2 1.2(7) . . . . ?
C23 N1 C1 N2 -178.4(6) . . . . ?
C3 N1 C1 Ag1 -176.2(5) . . . . ?
C23 N1 C1 Ag1 4.3(9) . . . . ?
Cl1 Ag1 C1 N2 -122(4) . . . . ?
Cl1 Ag1 C1 N1 54(5) . . . . ?
C29 C27 C26 C25 2.3(13) . . . . ?
C28 C27 C26 C25 -178.4(9) . . . . ?
C20 C18 C17 C16 -1.7(11) . . . . ?
C19 C18 C17 C16 -179.1(7) . . . . ?
C23 C16 C17 C18 3.2(11) . . . . ?
C15 C16 C17 C18 178.5(9) . . . . ?
C1 N2 C5 C6 -99.3(8) . . . . ?
C4 N2 C5 C6 75.2(9) . . . . ?
C7 C6 C5 N2 17.3(10) . . . . ?
C11 C6 C5 N2 -166.1(6) . . . . ?
N6 C32 C25 C26 176.2(7) . . . . ?
C30 C32 C25 C26 -2.6(11) . . . . ?
N6 C32 C25 C24 -4.9(12) . . . . ?
C30 C32 C25 C24 176.3(7) . . . . ?
C27 C26 C25 C32 -0.1(12) . . . . ?
C27 C26 C25 C24 -179.0(8) . . . . ?
