#------------------------------------------------------------------------------
#$Date: 2016-03-25 12:15:32 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179806 $
#$URL: svn://www.crystallography.net/cod/cif/7/01/02/7010289.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7010289
loop_
_publ_author_name
'Bowmaker, Graham A.'
'Hanna, John V.'
'Rickard, Clifton E. F.'
'Lipton, Andrew S.'
_publ_section_title
;
 Crystal structures and vibrational and solid-state (CPMAS) NMR
 spectroscopy of some bis(triphenylphosphine)silver(I) sulfate,
 selenate and phosphate systems
;
_journal_issue                   1
_journal_name_full
'Journal of the Chemical Society, Dalton Transactions'
_journal_page_first              20
_journal_paper_doi               10.1039/b007796h
_journal_year                    2001
_chemical_formula_sum            'C72 H64 Ag2 O6 P4 S'
_chemical_formula_weight         1396.91
_chemical_name_systematic
; 
 mu-sulphatotetrakis(triphenylphosphine)disilver(I) dihydrate 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                91.1910(10)
_cell_angle_beta                 95.3060(10)
_cell_angle_gamma                118.2300(10)
_cell_formula_units_Z            2
_cell_length_a                   12.4953(4)
_cell_length_b                   13.3274(4)
_cell_length_c                   21.7824(6)
_cell_measurement_reflns_used    8192
_cell_measurement_temperature    200(2)
_cell_measurement_theta_max      27
_cell_measurement_theta_min      2
_cell_volume                     3173.65(17)
_computing_cell_refinement       'Siemens SMART'
_computing_data_collection       'Siemens SMART (Siemens, 1995)'
_computing_data_reduction        'Siemens SAINT  (Siemens, 1995)'
_computing_molecular_graphics    'Siemens SHELXTL (Siemens, 1994)'
_computing_publication_material  SHELXL-97
_computing_structure_refinement  'SHELXL-97 Sheldrick, (1997)'
_computing_structure_solution    'SHELXS Sheldrick, (1990)'
_diffrn_ambient_temperature      200(2)
_diffrn_measured_fraction_theta_full 0.962
_diffrn_measured_fraction_theta_max 0.962
_diffrn_measurement_device_type  'Siemens SMART'
_diffrn_measurement_method       'Area detector ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0238
_diffrn_reflns_av_sigmaI/netI    0.0349
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_limit_l_min       0
_diffrn_reflns_number            30713
_diffrn_reflns_theta_full        27.03
_diffrn_reflns_theta_max         27.03
_diffrn_reflns_theta_min         0.94
_diffrn_standards_decay_%        0
_exptl_absorpt_coefficient_mu    0.804
_exptl_absorpt_correction_T_max  0.8558
_exptl_absorpt_correction_T_min  0.6707
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Blessing, 1995'
_exptl_crystal_colour            Plate
_exptl_crystal_density_diffrn    1.462
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Colourless
_exptl_crystal_F_000             1428
_exptl_crystal_size_max          0.54
_exptl_crystal_size_mid          0.36
_exptl_crystal_size_min          0.20
_refine_diff_density_max         1.043
_refine_diff_density_min         -0.500
_refine_diff_density_rms         0.094
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.140
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     772
_refine_ls_number_reflns         13366
_refine_ls_number_restraints     2
_refine_ls_restrained_S_all      1.143
_refine_ls_R_factor_all          0.0580
_refine_ls_R_factor_gt           0.0478
_refine_ls_shift/su_max          0.039
_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0288P)²+12.5289P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1198
_refine_ls_wR_factor_ref         0.1247
_reflns_number_gt                11528
_reflns_number_total             13366
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b007796h.txt
_cod_data_source_block           gab9952b
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from
2010-06-29.

'_exptl_absorpt_correction_type' value 'Multi-scan' changed
to 'multi-scan' according to
'/home/saulius/struct/CIF-dictionaries/cif_core.dic' dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 

The following automatic conversions were performed:

'_refine_ls_weighting_scheme' value 'calc
w=1/[\s^2^(Fo^2^)+(0.0288P)^2^+12.5289P] where P=(Fo^2^+2Fc^2^)/3'
was changed to 'calc'. New tag '_refine_ls_weighting_details' was
created. The value of the new tag was set to
'w=1/[\s^2^(Fo^2^)+(0.0288P)^2^+12.5289P] where P=(Fo^2^+2Fc^2^)/3'.

Automatic conversion script
Id: cif_fix_values 3143 2015-03-26 13:38:13Z robertas 
;
_cod_original_cell_volume        3173.64(16)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7010289
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.49546(3) 0.66553(3) 0.639834(15) 0.02844(9) Uani 1 d . . .
Ag2 Ag 0.66520(3) 0.64234(3) 0.855135(16) 0.03041(9) Uani 1 d . . .
S S 0.52041(10) 0.48416(9) 0.73834(5) 0.0296(2) Uani 1 d . . .
P1 P 0.27831(10) 0.59243(10) 0.59422(5) 0.0266(2) Uani 1 d . . .
P2 P 0.67635(10) 0.82821(9) 0.61193(5) 0.0251(2) Uani 1 d . . .
P3 P 0.80157(10) 0.57616(10) 0.90697(5) 0.0272(2) Uani 1 d . . .
P4 P 0.64122(10) 0.80758(10) 0.88426(5) 0.0269(2) Uani 1 d . . .
O1 O 0.4529(4) 0.5040(4) 0.6852(2) 0.0693(14) Uani 1 d . . .
O2 O 0.5228(4) 0.3777(3) 0.72319(18) 0.0477(9) Uani 1 d . . .
O3 O 0.4627(4) 0.4765(3) 0.79490(19) 0.0569(11) Uani 1 d . . .
O4 O 0.6476(3) 0.5805(3) 0.74895(15) 0.0398(8) Uani 1 d . . .
C1 C 0.1584(4) 0.4631(4) 0.6221(2) 0.0306(9) Uani 1 d . . .
C2 C 0.0578(4) 0.3828(4) 0.5827(2) 0.0350(10) Uani 1 d . . .
H2B H 0.0524 0.3930 0.5397 0.042 Uiso 1 calc R . .
C3 C -0.0347(4) 0.2877(4) 0.6060(3) 0.0423(12) Uani 1 d . . .
H3B H -0.1026 0.2330 0.5790 0.051 Uiso 1 calc R . .
C4 C -0.0270(5) 0.2735(4) 0.6692(3) 0.0449(13) Uani 1 d . . .
H4A H -0.0916 0.2110 0.6856 0.054 Uiso 1 calc R . .
C5 C 0.0750(6) 0.3507(5) 0.7080(3) 0.0571(16) Uani 1 d . . .
H5A H 0.0816 0.3395 0.7509 0.069 Uiso 1 calc R . .
C6 C 0.1680(5) 0.4444(4) 0.6844(2) 0.0443(12) Uani 1 d . . .
H6A H 0.2385 0.4960 0.7110 0.053 Uiso 1 calc R . .
C7 C 0.2194(4) 0.6950(4) 0.59449(19) 0.0272(9) Uani 1 d . . .
C8 C 0.3035(4) 0.8111(4) 0.5957(2) 0.0314(9) Uani 1 d . . .
H8A H 0.3886 0.8347 0.5991 0.038 Uiso 1 calc R . .
C9 C 0.2631(5) 0.8929(4) 0.5920(2) 0.0366(10) Uani 1 d . . .
H9A H 0.3207 0.9716 0.5924 0.044 Uiso 1 calc R . .
C10 C 0.1398(5) 0.8591(4) 0.5877(2) 0.0409(11) Uani 1 d . . .
H10A H 0.1126 0.9145 0.5846 0.049 Uiso 1 calc R . .
C11 C 0.0553(5) 0.7442(5) 0.5879(3) 0.0468(13) Uani 1 d . . .
H11A H -0.0295 0.7214 0.5856 0.056 Uiso 1 calc R . .
C12 C 0.0948(4) 0.6624(4) 0.5914(2) 0.0380(11) Uani 1 d . . .
H12A H 0.0367 0.5840 0.5918 0.046 Uiso 1 calc R . .
C13 C 0.2690(4) 0.5554(4) 0.5118(2) 0.0267(9) Uani 1 d . . .
C14 C 0.2168(4) 0.5936(4) 0.4645(2) 0.0327(10) Uani 1 d . . .
H14A H 0.1792 0.6382 0.4746 0.039 Uiso 1 calc R . .
C15 C 0.2196(5) 0.5670(4) 0.4034(2) 0.0387(11) Uani 1 d . . .
H15A H 0.1829 0.5933 0.3721 0.046 Uiso 1 calc R . .
C16 C 0.2742(5) 0.5033(4) 0.3865(2) 0.0424(12) Uani 1 d . . .
H16A H 0.2766 0.4866 0.3442 0.051 Uiso 1 calc R . .
C17 C 0.3259(5) 0.4641(4) 0.4333(3) 0.0462(13) Uani 1 d . . .
H17A H 0.3626 0.4189 0.4226 0.055 Uiso 1 calc R . .
C18 C 0.3246(5) 0.4898(4) 0.4950(3) 0.0398(11) Uani 1 d . . .
H18A H 0.3613 0.4632 0.5262 0.048 Uiso 1 calc R . .
C19 C 0.6533(4) 0.9541(4) 0.6143(2) 0.0269(9) Uani 1 d . . .
C20 C 0.6272(4) 0.9870(4) 0.6697(2) 0.0360(10) Uani 1 d . . .
H20A H 0.6268 0.9471 0.7054 0.043 Uiso 1 calc R . .
C21 C 0.6016(5) 1.0780(4) 0.6734(2) 0.0402(11) Uani 1 d . . .
H21A H 0.5850 1.1003 0.7115 0.048 Uiso 1 calc R . .
C22 C 0.6004(5) 1.1358(4) 0.6216(3) 0.0402(11) Uani 1 d . . .
H22A H 0.5822 1.1973 0.6242 0.048 Uiso 1 calc R . .
C23 C 0.6256(5) 1.1040(4) 0.5660(2) 0.0406(11) Uani 1 d . . .
H23A H 0.6243 1.1435 0.5303 0.049 Uiso 1 calc R . .
C24 C 0.6531(4) 1.0138(4) 0.5622(2) 0.0354(10) Uani 1 d . . .
H24A H 0.6717 0.9931 0.5242 0.043 Uiso 1 calc R . .
C25 C 0.7021(4) 0.8097(4) 0.5319(2) 0.0277(9) Uani 1 d . . .
C26 C 0.5999(4) 0.7523(4) 0.4873(2) 0.0337(10) Uani 1 d . . .
H26A H 0.5203 0.7281 0.4988 0.040 Uiso 1 calc R . .
C27 C 0.6134(5) 0.7303(4) 0.4262(2) 0.0379(11) Uani 1 d . . .
H27A H 0.5436 0.6923 0.3964 0.046 Uiso 1 calc R . .
C28 C 0.7295(5) 0.7644(4) 0.4096(2) 0.0404(11) Uani 1 d . . .
H28A H 0.7395 0.7489 0.3683 0.048 Uiso 1 calc R . .
C29 C 0.8311(5) 0.8212(5) 0.4531(2) 0.0426(12) Uani 1 d . . .
H29A H 0.9104 0.8446 0.4414 0.051 Uiso 1 calc R . .
C30 C 0.8183(4) 0.8446(4) 0.5141(2) 0.0362(10) Uani 1 d . . .
H30A H 0.8887 0.8842 0.5434 0.043 Uiso 1 calc R . .
C31 C 0.8249(4) 0.8748(4) 0.65751(19) 0.0264(9) Uani 1 d . . .
C32 C 0.8415(4) 0.7962(4) 0.6933(2) 0.0346(10) Uani 1 d . . .
H32A H 0.7760 0.7213 0.6950 0.041 Uiso 1 calc R . .
C33 C 0.9559(5) 0.8293(5) 0.7263(2) 0.0425(12) Uani 1 d . . .
H33A H 0.9676 0.7761 0.7505 0.051 Uiso 1 calc R . .
C34 C 1.0511(5) 0.9368(5) 0.7246(2) 0.0457(13) Uani 1 d . . .
H34A H 1.1280 0.9576 0.7474 0.055 Uiso 1 calc R . .
C35 C 1.0355(4) 1.0162(5) 0.6892(2) 0.0409(12) Uani 1 d . . .
H35A H 1.1013 1.0912 0.6881 0.049 Uiso 1 calc R . .
C36 C 0.9225(4) 0.9844(4) 0.6556(2) 0.0330(10) Uani 1 d . . .
H36A H 0.9117 1.0379 0.6312 0.040 Uiso 1 calc R . .
C37 C 0.7850(4) 0.5555(4) 0.9892(2) 0.0282(9) Uani 1 d . . .
C38 C 0.8822(4) 0.5917(4) 1.0354(2) 0.0339(10) Uani 1 d . . .
H38A H 0.9636 0.6283 1.0249 0.041 Uiso 1 calc R . .
C39 C 0.8624(5) 0.5751(4) 1.0969(2) 0.0392(11) Uani 1 d . . .
H39A H 0.9300 0.6007 1.1281 0.047 Uiso 1 calc R . .
C40 C 0.7441(5) 0.5213(4) 1.1131(2) 0.0401(11) Uani 1 d . . .
H40A H 0.7306 0.5102 1.1552 0.048 Uiso 1 calc R . .
C41 C 0.6464(5) 0.4842(5) 1.0677(3) 0.0444(12) Uani 1 d . . .
H41A H 0.5655 0.4477 1.0788 0.053 Uiso 1 calc R . .
C42 C 0.6649(4) 0.4998(4) 1.0052(2) 0.0386(11) Uani 1 d . . .
H42A H 0.5970 0.4729 0.9741 0.046 Uiso 1 calc R . .
C43 C 0.9626(4) 0.6830(4) 0.9054(2) 0.0294(9) Uani 1 d . . .
C44 C 0.9915(5) 0.7966(4) 0.8971(2) 0.0364(10) Uani 1 d . . .
H44A H 0.9278 0.8165 0.8912 0.044 Uiso 1 calc R . .
C45 C 1.1129(5) 0.8809(4) 0.8974(2) 0.0434(12) Uani 1 d . . .
H45A H 1.1315 0.9578 0.8918 0.052 Uiso 1 calc R . .
C46 C 1.2065(5) 0.8522(5) 0.9060(3) 0.0482(13) Uani 1 d . . .
H46A H 1.2892 0.9097 0.9069 0.058 Uiso 1 calc R . .
C47 C 1.1791(5) 0.7394(5) 0.9133(3) 0.0511(14) Uani 1 d . . .
H47A H 1.2428 0.7195 0.9182 0.061 Uiso 1 calc R . .
C48 C 1.0578(4) 0.6558(4) 0.9132(2) 0.0395(11) Uani 1 d . . .
H48A H 1.0396 0.5790 0.9186 0.047 Uiso 1 calc R . .
C49 C 0.7943(4) 0.4442(4) 0.8757(2) 0.0288(9) Uani 1 d . . .
C50 C 0.7798(5) 0.4252(4) 0.8114(2) 0.0396(11) Uani 1 d . . .
H50A H 0.7716 0.4788 0.7859 0.048 Uiso 1 calc R . .
C51 C 0.7773(6) 0.3287(5) 0.7845(3) 0.0514(14) Uani 1 d . . .
H51A H 0.7679 0.3166 0.7407 0.062 Uiso 1 calc R . .
C52 C 0.7884(5) 0.2503(5) 0.8212(3) 0.0484(13) Uani 1 d . . .
H52A H 0.7873 0.1847 0.8026 0.058 Uiso 1 calc R . .
C53 C 0.8010(4) 0.2666(4) 0.8845(3) 0.0400(11) Uani 1 d . . .
H53A H 0.8083 0.2122 0.9095 0.048 Uiso 1 calc R . .
C54 C 0.8029(4) 0.3633(4) 0.9122(2) 0.0348(10) Uani 1 d . . .
H54A H 0.8102 0.3737 0.9560 0.042 Uiso 1 calc R . .
C55 C 0.5322(4) 0.8343(4) 0.8351(2) 0.0297(9) Uani 1 d . . .
C56 C 0.5367(5) 0.9413(4) 0.8357(2) 0.0363(10) Uani 1 d . . .
H56A H 0.6009 1.0042 0.8605 0.044 Uiso 1 calc R . .
C57 C 0.4471(5) 0.9556(5) 0.8000(2) 0.0426(12) Uani 1 d . . .
H57A H 0.4497 1.0281 0.8006 0.051 Uiso 1 calc R . .
C58 C 0.3539(5) 0.8637(6) 0.7634(3) 0.0508(14) Uani 1 d . . .
H58A H 0.2927 0.8738 0.7394 0.061 Uiso 1 calc R . .
C59 C 0.3490(5) 0.7586(5) 0.7616(2) 0.0479(13) Uani 1 d . . .
H59A H 0.2848 0.6966 0.7363 0.057 Uiso 1 calc R . .
C60 C 0.4385(4) 0.7422(4) 0.7971(2) 0.0368(11) Uani 1 d . . .
H60A H 0.4359 0.6698 0.7954 0.044 Uiso 1 calc R . .
C61 C 0.5979(4) 0.8072(4) 0.9623(2) 0.0301(9) Uani 1 d . . .
C62 C 0.5176(5) 0.8464(4) 0.9784(2) 0.0382(11) Uani 1 d . . .
H62A H 0.4829 0.8759 0.9479 0.046 Uiso 1 calc R . .
C63 C 0.4885(5) 0.8423(5) 1.0385(3) 0.0487(13) Uani 1 d . . .
H63A H 0.4348 0.8702 1.0492 0.058 Uiso 1 calc R . .
C64 C 0.5372(6) 0.7980(5) 1.0832(3) 0.0543(15) Uani 1 d . . .
H64A H 0.5158 0.7942 1.1241 0.065 Uiso 1 calc R . .
C65 C 0.6165(6) 0.7594(5) 1.0680(3) 0.0517(14) Uani 1 d . . .
H65A H 0.6511 0.7302 1.0988 0.062 Uiso 1 calc R . .
C66 C 0.6462(5) 0.7629(5) 1.0082(2) 0.0407(11) Uani 1 d . . .
H66A H 0.7002 0.7349 0.9982 0.049 Uiso 1 calc R . .
C67 C 0.7864(4) 0.9402(4) 0.8865(2) 0.0288(9) Uani 1 d . . .
C68 C 0.8356(5) 0.9750(4) 0.8312(2) 0.0400(11) Uani 1 d . . .
H68A H 0.7905 0.9338 0.7933 0.048 Uiso 1 calc R . .
C69 C 0.9509(5) 1.0700(5) 0.8310(3) 0.0473(13) Uani 1 d . . .
H69A H 0.9826 1.0941 0.7928 0.057 Uiso 1 calc R . .
C70 C 1.0189(5) 1.1293(4) 0.8857(3) 0.0442(12) Uani 1 d . . .
H70A H 1.0983 1.1924 0.8855 0.053 Uiso 1 calc R . .
C71 C 0.9703(5) 1.0958(5) 0.9409(3) 0.0482(13) Uani 1 d . . .
H71A H 1.0161 1.1368 0.9787 0.058 Uiso 1 calc R . .
C72 C 0.8546(5) 1.0023(4) 0.9415(2) 0.0383(11) Uani 1 d . . .
H72A H 0.8219 0.9806 0.9796 0.046 Uiso 1 calc R . .
O5 C 0.3796(5) 0.1509(4) 0.7341(3) 0.0407(12) Uani 1 d D . .
H5B H 0.438(4) 0.202(4) 0.753(2) 0.049 Uiso 1 d D . .
O6 C 0.2474(4) 0.2600(4) 0.7916(2) 0.0326(10) Uani 1 d D . .
H6B H 0.272(5) 0.220(4) 0.780(2) 0.039 Uiso 1 d D . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Ag1 P2 136.65(12) . . y
O1 Ag1 P1 92.81(11) . . y
P2 Ag1 P1 128.04(4) . . y
O4 Ag2 P4 121.36(9) . . y
O4 Ag2 P3 102.97(9) . . y
P4 Ag2 P3 128.60(4) . . y
O4 Ag2 O3 56.42(11) . . y
P4 Ag2 O3 112.04(10) . . y
P3 Ag2 O3 113.73(10) . . y
O2 S O3 110.6(2) . . y
O2 S O1 107.4(3) . . y
O3 S O1 111.4(3) . . y
O2 S O4 109.8(2) . . y
O3 S O4 108.0(2) . . y
O1 S O4 109.7(2) . . y
C13 P1 C1 104.0(2) . . y
C13 P1 C7 103.20(19) . . y
C1 P1 C7 104.8(2) . . y
C13 P1 Ag1 107.61(14) . . y
C1 P1 Ag1 119.13(15) . . y
C7 P1 Ag1 116.35(15) . . y
C19 P2 C31 104.6(2) . . y
C19 P2 C25 105.0(2) . . y
C31 P2 C25 105.0(2) . . y
C19 P2 Ag1 109.07(14) . . y
C31 P2 Ag1 120.19(14) . . y
C25 P2 Ag1 111.75(14) . . y
C49 P3 C37 104.4(2) . . y
C49 P3 C43 103.5(2) . . y
C37 P3 C43 104.7(2) . . y
C49 P3 Ag2 118.52(14) . . y
C37 P3 Ag2 113.87(14) . . y
C43 P3 Ag2 110.51(15) . . y
C55 P4 C61 104.7(2) . . y
C55 P4 C67 104.5(2) . . y
C61 P4 C67 103.7(2) . . y
C55 P4 Ag2 117.80(15) . . y
C61 P4 Ag2 113.67(15) . . y
C67 P4 Ag2 111.13(14) . . y
S O1 Ag1 129.6(2) . . y
S O3 Ag2 92.79(18) . . y
S O4 Ag2 102.63(17) . . y
C6 C1 C2 119.1(4) . . ?
C6 C1 P1 118.9(4) . . ?
C2 C1 P1 122.0(4) . . ?
C1 C2 C3 120.5(5) . . ?
C4 C3 C2 119.6(5) . . ?
C5 C4 C3 119.9(5) . . ?
C4 C5 C6 120.1(5) . . ?
C1 C6 C5 120.6(5) . . ?
C8 C7 C12 118.8(4) . . ?
C8 C7 P1 117.9(3) . . ?
C12 C7 P1 123.2(4) . . ?
C7 C8 C9 120.4(4) . . ?
C10 C9 C8 120.0(5) . . ?
C9 C10 C11 120.2(5) . . ?
C10 C11 C12 120.1(5) . . ?
C11 C12 C7 120.4(5) . . ?
C14 C13 C18 118.1(4) . . ?
C14 C13 P1 124.2(3) . . ?
C18 C13 P1 117.5(4) . . ?
C15 C14 C13 120.6(4) . . ?
C14 C15 C16 121.8(5) . . ?
C15 C16 C17 118.1(5) . . ?
C18 C17 C16 121.2(5) . . ?
C17 C18 C13 120.1(5) . . ?
C20 C19 C24 118.8(4) . . ?
C20 C19 P2 118.1(3) . . ?
C24 C19 P2 123.0(3) . . ?
C19 C20 C21 120.7(4) . . ?
C22 C21 C20 120.2(5) . . ?
C21 C22 C23 120.0(5) . . ?
C22 C23 C24 120.1(5) . . ?
C19 C24 C23 120.2(4) . . ?
C30 C25 C26 118.6(4) . . ?
C30 C25 P2 122.8(3) . . ?
C26 C25 P2 118.5(3) . . ?
C27 C26 C25 121.2(4) . . ?
C28 C27 C26 119.4(5) . . ?
C29 C28 C27 120.0(4) . . ?
C28 C29 C30 120.8(5) . . ?
C25 C30 C29 120.0(5) . . ?
C36 C31 C32 119.4(4) . . ?
C36 C31 P2 121.9(3) . . ?
C32 C31 P2 118.6(3) . . ?
C33 C32 C31 119.1(5) . . ?
C34 C33 C32 121.3(5) . . ?
C33 C34 C35 120.1(5) . . ?
C36 C35 C34 119.4(5) . . ?
C35 C36 C31 120.7(5) . . ?
C38 C37 C42 119.1(4) . . ?
C38 C37 P3 124.3(3) . . ?
C42 C37 P3 116.6(4) . . ?
C37 C38 C39 120.9(4) . . ?
C40 C39 C38 120.2(5) . . ?
C41 C40 C39 119.6(5) . . ?
C40 C41 C42 120.9(5) . . ?
C41 C42 C37 119.2(5) . . ?
C48 C43 C44 118.5(4) . . ?
C48 C43 P3 122.6(4) . . ?
C44 C43 P3 118.9(4) . . ?
C45 C44 C43 120.8(5) . . ?
C46 C45 C44 119.8(5) . . ?
C45 C46 C47 120.1(5) . . ?
C46 C47 C48 119.8(5) . . ?
C47 C48 C43 121.1(5) . . ?
C54 C49 C50 118.9(4) . . ?
C54 C49 P3 123.8(4) . . ?
C50 C49 P3 117.3(3) . . ?
C51 C50 C49 120.5(5) . . ?
C52 C51 C50 120.0(5) . . ?
C53 C52 C51 120.3(5) . . ?
C52 C53 C54 120.2(5) . . ?
C49 C54 C53 120.1(5) . . ?
C56 C55 C60 119.6(4) . . ?
C56 C55 P4 122.3(4) . . ?
C60 C55 P4 118.1(3) . . ?
C57 C56 C55 120.0(5) . . ?
C58 C57 C56 119.9(5) . . ?
C59 C58 C57 120.9(5) . . ?
C58 C59 C60 120.3(5) . . ?
C59 C60 C55 119.3(5) . . ?
C62 C61 C66 118.2(4) . . ?
C62 C61 P4 123.7(4) . . ?
C66 C61 P4 118.0(4) . . ?
C63 C62 C61 120.3(5) . . ?
C64 C63 C62 120.5(5) . . ?
C65 C64 C63 119.8(5) . . ?
C64 C65 C66 120.3(5) . . ?
C65 C66 C61 120.9(5) . . ?
C68 C67 C72 118.5(4) . . ?
C68 C67 P4 118.2(4) . . ?
C72 C67 P4 123.1(4) . . ?
C67 C68 C69 120.5(5) . . ?
C70 C69 C68 120.5(5) . . ?
C69 C70 C71 119.3(5) . . ?
C70 C71 C72 120.5(5) . . ?
C71 C72 C67 120.6(5) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 O1 2.235(4) . y
Ag1 P2 2.4190(11) . y
Ag1 P1 2.5018(11) . y
Ag2 O4 2.394(3) . y
Ag2 P4 2.4380(11) . y
Ag2 P3 2.4625(11) . y
Ag2 O3 2.643(4) . y
S O2 1.464(4) . y
S O3 1.466(4) . y
S O1 1.472(4) . y
S O4 1.489(3) . y
P1 C13 1.831(5) . y
P1 C1 1.831(4) . y
P1 C7 1.834(4) . y
P2 C19 1.833(4) . y
P2 C31 1.833(4) . y
P2 C25 1.835(4) . y
P3 C49 1.830(5) . y
P3 C37 1.833(5) . y
P3 C43 1.839(5) . y
P4 C55 1.826(4) . y
P4 C61 1.830(5) . y
P4 C67 1.834(5) . y
C1 C6 1.388(7) . ?
C1 C2 1.397(7) . ?
C2 C3 1.397(7) . ?
C3 C4 1.394(8) . ?
C4 C5 1.386(8) . ?
C5 C6 1.393(7) . ?
C7 C8 1.398(6) . ?
C7 C12 1.399(6) . ?
C8 C9 1.403(6) . ?
C9 C10 1.378(7) . ?
C10 C11 1.390(8) . ?
C11 C12 1.394(7) . ?
C13 C14 1.398(6) . ?
C13 C18 1.411(6) . ?
C14 C15 1.377(7) . ?
C15 C16 1.381(7) . ?
C16 C17 1.397(8) . ?
C17 C18 1.384(8) . ?
C19 C20 1.394(6) . ?
C19 C24 1.399(6) . ?
C20 C21 1.395(7) . ?
C21 C22 1.380(7) . ?
C22 C23 1.388(7) . ?
C23 C24 1.401(7) . ?
C25 C30 1.396(6) . ?
C25 C26 1.405(6) . ?
C26 C27 1.398(7) . ?
C27 C28 1.388(7) . ?
C28 C29 1.386(8) . ?
C29 C30 1.398(7) . ?
C31 C36 1.397(6) . ?
C31 C32 1.399(6) . ?
C32 C33 1.398(7) . ?
C33 C34 1.367(8) . ?
C34 C35 1.397(8) . ?
C35 C36 1.392(7) . ?
C37 C38 1.386(6) . ?
C37 C42 1.407(6) . ?
C38 C39 1.388(7) . ?
C39 C40 1.388(7) . ?
C40 C41 1.377(8) . ?
C41 C42 1.405(7) . ?
C43 C48 1.396(6) . ?
C43 C44 1.400(7) . ?
C44 C45 1.396(7) . ?
C45 C46 1.391(8) . ?
C46 C47 1.391(8) . ?
C47 C48 1.393(7) . ?
C49 C54 1.391(6) . ?
C49 C50 1.398(7) . ?
C50 C51 1.389(7) . ?
C51 C52 1.378(8) . ?
C52 C53 1.376(8) . ?
C53 C54 1.400(7) . ?
C55 C56 1.401(6) . ?
C55 C60 1.407(7) . ?
C56 C57 1.394(7) . ?
C57 C58 1.388(8) . ?
C58 C59 1.373(8) . ?
C59 C60 1.405(7) . ?
C61 C62 1.398(7) . ?
C61 C66 1.401(6) . ?
C62 C63 1.388(7) . ?
C63 C64 1.386(9) . ?
C64 C65 1.376(9) . ?
C65 C66 1.382(7) . ?
C67 C68 1.391(6) . ?
C67 C72 1.395(7) . ?
C68 C69 1.398(8) . ?
C69 C70 1.382(8) . ?
C70 C71 1.383(8) . ?
C71 C72 1.393(7) . ?
