#------------------------------------------------------------------------------
#$Date: 2016-03-25 12:17:41 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179808 $
#$URL: svn://www.crystallography.net/cod/cif/7/01/04/7010488.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7010488
loop_
_publ_author_name
'Aucott, Stephen M.'
'Clarke, Matthew L.'
'Slawin, Alexandra M. Z.'
'Woollins, J. Derek'
_publ_section_title
;
 Synthesis and co-ordination chemistry of a novel multifunctional
 bis-phosphine containing a P--N--Si--N--P backbone
;
_journal_issue                   7
_journal_name_full
'Journal of the Chemical Society, Dalton Transactions'
_journal_page_first              972
_journal_paper_doi               10.1039/b009722p
_journal_year                    2001
_chemical_formula_analytical     'C38 H40 N4 P2 Pt Si'
_chemical_formula_moiety         'C38 H40 N4 P2 Pt Si'
_chemical_formula_structural     'C38 H40 N4 P2 Pt Si'
_chemical_formula_sum            'C38 H40 N4 P2 Pt Si'
_chemical_formula_weight         837.86
_chemical_melting_point          ?
_chemical_name_systematic        10
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL
_cell_angle_alpha                90.00
_cell_angle_beta                 90.8350(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   12.5811(2)
_cell_length_b                   18.3389(3)
_cell_length_c                   15.4399(3)
_cell_measurement_reflns_used    192
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      168
_cell_measurement_theta_min      12
_cell_volume                     3561.97(11)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SHELXTL'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-93 (Sheldrick, 1993)'
_computing_structure_solution    'SHELXS-86 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measurement_device       CCD
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0413
_diffrn_reflns_av_sigmaI/netI    0.0452
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            15304
_diffrn_reflns_theta_max         23.21
_diffrn_reflns_theta_min         1.96
_diffrn_standards_decay_%        -
_diffrn_standards_interval_count -
_diffrn_standards_interval_time  -
_diffrn_standards_number         -
_exptl_absorpt_coefficient_mu    4.096
_exptl_absorpt_correction_T_max  0.693218
_exptl_absorpt_correction_T_min  0.466137
_exptl_absorpt_correction_type   sadabs
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.562
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    -
_exptl_crystal_description       plate
_exptl_crystal_F_000             1672
_exptl_crystal_size_max          .14
_exptl_crystal_size_mid          .1
_exptl_crystal_size_min          .03
_refine_diff_density_max         0.680
_refine_diff_density_min         -0.401
_refine_diff_density_rms         0.074
_refine_ls_extinction_coef       0.00000(6)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_all   0.931
_refine_ls_goodness_of_fit_obs   0.974
_refine_ls_hydrogen_treatment    riding
_refine_ls_matrix_type           full
_refine_ls_number_parameters     416
_refine_ls_number_reflns         5033
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.985
_refine_ls_restrained_S_obs      0.974
_refine_ls_R_factor_all          0.0429
_refine_ls_R_factor_obs          0.0259
_refine_ls_shift/esd_max         -0.896
_refine_ls_shift/esd_mean        0.002
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0270P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_all         0.0597
_refine_ls_wR_factor_obs         0.0517
_reflns_number_observed          3940
_reflns_number_total             5072
_reflns_observed_criterion       >2sigma(I)
_cod_data_source_file            b009722p.txt
_cod_data_source_block           10
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/adriana/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1555 2011-01-17 13:19:09Z saulius 

The following automatic conversions were performed:

'_chemical_melting_point' value '-' was changed to '?' - the value is
undefined or not given.

Automatic conversion script
Id: cif_fix_values 1569 2011-02-09 13:29:24Z adriana 

The following automatic conversions were performed:

'_exptl_crystal_density_meas' value '-' was changed to '?' - the
value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 

The following automatic conversions were performed:

'_refine_ls_weighting_scheme' value 'calc
w=1/[\s^2^(Fo^2^)+(0.0270P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3' was
changed to 'calc'. New tag '_refine_ls_weighting_details' was
created. The value of the new tag was set to
'w=1/[\s^2^(Fo^2^)+(0.0270P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'.

Automatic conversion script
Id: cif_fix_values 3143 2015-03-26 13:38:13Z robertas 
;
_cod_original_sg_symbol_H-M      P2(1)/n
_cod_database_code               7010488
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_thermal_displace_type
_atom_site_occupancy
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_group
Pt1 Pt 0.871910(14) 0.209233(9) 0.529712(12) 0.03556(8) Uani 1 d . .
C39 C 0.9608(4) 0.2971(3) 0.4819(4) 0.0617(15) Uani 1 d . .
H39A H 0.9135(4) 0.3355(3) 0.4641(4) 0.093 Uiso 1 calc R .
H39B H 1.0013(4) 0.2811(3) 0.4332(4) 0.093 Uiso 1 calc R .
H39C H 1.0081(4) 0.3147(3) 0.5265(4) 0.093 Uiso 1 calc R .
C40 C 1.0211(4) 0.1613(3) 0.5485(3) 0.0541(14) Uani 1 d . .
H40A H 1.0127(4) 0.1136(3) 0.5730(3) 0.081 Uiso 1 calc R .
H40B H 1.0631(4) 0.1909(3) 0.5872(3) 0.081 Uiso 1 calc R .
H40C H 1.0562(4) 0.1574(3) 0.4939(3) 0.081 Uiso 1 calc R .
P1 P 0.71638(10) 0.26100(6) 0.48015(8) 0.0353(3) Uani 1 d . .
C1 C 0.6845(4) 0.2261(2) 0.3711(3) 0.0398(12) Uani 1 d . .
C2 C 0.7517(4) 0.1755(3) 0.3355(3) 0.0494(13) Uani 1 d . .
H2A H 0.8102(4) 0.1591(3) 0.3675(3) 0.059 Uiso 1 calc R .
C3 C 0.7338(5) 0.1485(3) 0.2521(3) 0.065(2) Uani 1 d . .
H3A H 0.7804(5) 0.1148(3) 0.2284(3) 0.078 Uiso 1 calc R .
C4 C 0.6474(5) 0.1718(3) 0.2055(4) 0.066(2) Uani 1 d . .
H4A H 0.6350(5) 0.1537(3) 0.1500(4) 0.080 Uiso 1 calc R .
C5 C 0.5783(5) 0.2217(3) 0.2400(4) 0.067(2) Uani 1 d . .
H5A H 0.5188(5) 0.2366(3) 0.2083(4) 0.081 Uiso 1 calc R .
C6 C 0.5973(4) 0.2498(3) 0.3214(4) 0.0564(15) Uani 1 d . .
H6A H 0.5518(4) 0.2848(3) 0.3436(4) 0.068 Uiso 1 calc R .
C7 C 0.7133(4) 0.3606(2) 0.4620(3) 0.0374(11) Uani 1 d . .
C8 C 0.7568(4) 0.3906(3) 0.3885(3) 0.0545(14) Uani 1 d . .
H8A H 0.7805(4) 0.3602(3) 0.3446(3) 0.065 Uiso 1 calc R .
C9 C 0.7653(5) 0.4655(3) 0.3795(3) 0.062(2) Uani 1 d . .
H9A H 0.7959(5) 0.4850(3) 0.3301(3) 0.075 Uiso 1 calc R .
C10 C 0.7291(5) 0.5108(3) 0.4426(4) 0.065(2) Uani 1 d . .
H10A H 0.7337(5) 0.5611(3) 0.4360(4) 0.078 Uiso 1 calc R .
C11 C 0.6856(5) 0.4814(3) 0.5162(4) 0.069(2) Uani 1 d . .
H11A H 0.6611(5) 0.5121(3) 0.5596(4) 0.082 Uiso 1 calc R .
C12 C 0.6783(4) 0.4067(3) 0.5259(3) 0.0535(14) Uani 1 d . .
H12A H 0.6495(4) 0.3873(3) 0.5760(3) 0.064 Uiso 1 calc R .
N1 N 0.6099(3) 0.2438(2) 0.5445(2) 0.0377(9) Uani 1 d . .
C13 C 0.5026(4) 0.2459(3) 0.5117(3) 0.0404(12) Uani 1 d . .
N14 N 0.4525(4) 0.1806(2) 0.5048(3) 0.0720(15) Uani 1 d . .
C15 C 0.3504(5) 0.1806(4) 0.4759(4) 0.081(2) Uani 1 d . .
H15A H 0.3149(5) 0.1362(4) 0.4714(4) 0.097 Uiso 1 calc R .
C16 C 0.2970(5) 0.2429(4) 0.4529(4) 0.070(2) Uani 1 d . .
H16A H 0.2268(5) 0.2417(4) 0.4334(4) 0.083 Uiso 1 calc R .
C17 C 0.3524(5) 0.3072(3) 0.4601(4) 0.071(2) Uani 1 d . .
H17A H 0.3196(5) 0.3506(3) 0.4436(4) 0.085 Uiso 1 calc R .
C18 C 0.4537(4) 0.3085(2) 0.4908(3) 0.0493(14) Uani 1 d . .
H18A H 0.4892(4) 0.3527(2) 0.4973(3) 0.059 Uiso 1 calc R .
P2 P 0.79292(10) 0.10803(6) 0.58701(8) 0.0352(3) Uani 1 d . .
C19 C 0.8742(4) 0.0512(2) 0.6606(3) 0.0388(12) Uani 1 d . .
C20 C 0.9160(4) 0.0847(3) 0.7343(3) 0.0477(13) Uani 1 d . .
H20A H 0.9041(4) 0.1342(3) 0.7435(3) 0.057 Uiso 1 calc R .
C21 C 0.9751(4) 0.0452(3) 0.7941(3) 0.0576(15) Uani 1 d . .
H21A H 1.0019(4) 0.0682(3) 0.8435(3) 0.069 Uiso 1 calc R .
C22 C 0.9946(4) -0.0277(3) 0.7814(4) 0.060(2) Uani 1 d . .
H22A H 1.0339(4) -0.0541(3) 0.8222(4) 0.072 Uiso 1 calc R .
C23 C 0.9555(4) -0.0614(3) 0.7079(4) 0.060(2) Uani 1 d . .
H23A H 0.9694(4) -0.1106(3) 0.6985(4) 0.072 Uiso 1 calc R .
C24 C 0.8953(4) -0.0222(3) 0.6474(3) 0.0484(13) Uani 1 d . .
H24A H 0.8690(4) -0.0453(3) 0.5979(3) 0.058 Uiso 1 calc R .
C25 C 0.7492(4) 0.0470(2) 0.5001(3) 0.0372(11) Uani 1 d . .
C26 C 0.8230(4) 0.0147(3) 0.4467(3) 0.0478(13) Uani 1 d . .
H26A H 0.8952(4) 0.0210(3) 0.4584(3) 0.057 Uiso 1 calc R .
C27 C 0.7911(5) -0.0266(3) 0.3764(3) 0.0556(15) Uani 1 d . .
H27A H 0.8415(5) -0.0485(3) 0.3414(3) 0.067 Uiso 1 calc R .
C28 C 0.6861(6) -0.0351(3) 0.3584(3) 0.064(2) Uani 1 d . .
H28A H 0.6645(6) -0.0643(3) 0.3121(3) 0.077 Uiso 1 calc R .
C29 C 0.6123(5) -0.0013(4) 0.4077(4) 0.072(2) Uani 1 d . .
H29A H 0.5406(5) -0.0055(4) 0.3931(4) 0.087 Uiso 1 calc R .
C30 C 0.6429(4) 0.0393(3) 0.4794(3) 0.0530(14) Uani 1 d . .
H30A H 0.5917(4) 0.0613(3) 0.5135(3) 0.064 Uiso 1 calc R .
N2 N 0.6847(3) 0.1249(2) 0.6501(2) 0.0375(9) Uani 1 d . .
C31 C 0.6519(4) 0.0749(3) 0.7148(3) 0.0407(12) Uani 1 d . .
N32 N 0.6338(4) 0.1042(2) 0.7934(3) 0.0608(13) Uani 1 d . .
C33 C 0.5995(6) 0.0595(4) 0.8554(4) 0.081(2) Uani 1 d . .
H33A H 0.5840(6) 0.0796(4) 0.9091(4) 0.097 Uiso 1 calc R .
C34 C 0.5860(5) -0.0129(4) 0.8447(5) 0.086(2) Uani 1 d . .
H34A H 0.5628(5) -0.0418(4) 0.8901(5) 0.103 Uiso 1 calc R .
C35 C 0.6076(5) -0.0433(3) 0.7647(5) 0.071(2) Uani 1 d . .
H35A H 0.5993(5) -0.0931(3) 0.7556(5) 0.085 Uiso 1 calc R .
C36 C 0.6417(4) 0.0016(3) 0.6986(3) 0.0474(13) Uani 1 d . .
H36A H 0.6573(4) -0.0174(3) 0.6444(3) 0.057 Uiso 1 calc R .
Si1 Si 0.63227(11) 0.21523(7) 0.65299(8) 0.0386(3) Uani 1 d . .
C37 C 0.7268(4) 0.2777(2) 0.7100(3) 0.0527(14) Uani 1 d . .
H37A H 0.7378(4) 0.2613(2) 0.7685(3) 0.079 Uiso 1 calc R .
H37B H 0.6980(4) 0.3262(2) 0.7104(3) 0.079 Uiso 1 calc R .
H37C H 0.7934(4) 0.2779(2) 0.6804(3) 0.079 Uiso 1 calc R .
C38 C 0.4994(4) 0.2190(3) 0.7050(3) 0.0568(15) Uani 1 d . .
H38A H 0.5061(4) 0.2040(3) 0.7644(3) 0.085 Uiso 1 calc R .
H38B H 0.4511(4) 0.1870(3) 0.6749(3) 0.085 Uiso 1 calc R .
H38C H 0.4725(4) 0.2680(3) 0.7024(3) 0.085 Uiso 1 calc R .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C40 Pt1 C39 83.7(2) . . ?
C40 Pt1 P2 89.98(15) . . ?
C39 Pt1 P2 173.6(2) . . ?
C40 Pt1 P1 168.5(2) . . ?
C39 Pt1 P1 91.2(2) . . ?
P2 Pt1 P1 95.24(4) . . ?
N1 P1 C1 107.8(2) . . ?
N1 P1 C7 104.9(2) . . ?
C1 P1 C7 101.6(2) . . ?
N1 P1 Pt1 113.66(13) . . ?
C1 P1 Pt1 109.5(2) . . ?
C7 P1 Pt1 118.4(2) . . ?
C2 C1 C6 118.1(4) . . ?
C2 C1 P1 118.2(4) . . ?
C6 C1 P1 123.6(4) . . ?
C1 C2 C3 121.1(5) . . ?
C4 C3 C2 119.5(5) . . ?
C3 C4 C5 120.6(5) . . ?
C4 C5 C6 120.0(5) . . ?
C5 C6 C1 120.7(5) . . ?
C12 C7 C8 118.6(4) . . ?
C12 C7 P1 120.3(4) . . ?
C8 C7 P1 120.8(4) . . ?
C7 C8 C9 120.7(5) . . ?
C10 C9 C8 120.3(5) . . ?
C9 C10 C11 119.5(5) . . ?
C10 C11 C12 120.3(5) . . ?
C7 C12 C11 120.6(5) . . ?
C13 N1 P1 122.0(3) . . ?
C13 N1 Si1 118.5(3) . . ?
P1 N1 Si1 119.3(2) . . ?
C18 C13 N14 121.7(5) . . ?
C18 C13 N1 122.3(5) . . ?
N14 C13 N1 115.9(4) . . ?
C15 N14 C13 117.6(5) . . ?
N14 C15 C16 123.0(6) . . ?
C15 C16 C17 116.7(5) . . ?
C18 C17 C16 121.2(5) . . ?
C13 C18 C17 119.7(5) . . ?
N2 P2 C25 107.1(2) . . ?
N2 P2 C19 101.0(2) . . ?
C25 P2 C19 105.4(2) . . ?
N2 P2 Pt1 115.25(13) . . ?
C25 P2 Pt1 109.95(15) . . ?
C19 P2 Pt1 117.2(2) . . ?
C24 C19 C20 118.6(4) . . ?
C24 C19 P2 124.4(4) . . ?
C20 C19 P2 117.0(3) . . ?
C21 C20 C19 120.5(5) . . ?
C22 C21 C20 120.7(5) . . ?
C21 C22 C23 119.5(5) . . ?
C22 C23 C24 120.3(5) . . ?
C19 C24 C23 120.4(5) . . ?
C30 C25 C26 118.4(5) . . ?
C30 C25 P2 121.0(4) . . ?
C26 C25 P2 120.1(4) . . ?
C27 C26 C25 120.9(5) . . ?
C28 C27 C26 119.8(5) . . ?
C27 C28 C29 120.4(5) . . ?
C28 C29 C30 120.6(6) . . ?
C25 C30 C29 119.9(5) . . ?
C31 N2 P2 121.7(3) . . ?
C31 N2 Si1 118.0(3) . . ?
P2 N2 Si1 118.6(2) . . ?
N32 C31 C36 122.5(5) . . ?
N32 C31 N2 115.5(4) . . ?
C36 C31 N2 122.0(4) . . ?
C33 N32 C31 117.4(5) . . ?
N32 C33 C34 123.9(6) . . ?
C33 C34 C35 118.6(6) . . ?
C36 C35 C34 119.0(6) . . ?
C31 C36 C35 118.5(5) . . ?
N1 Si1 N2 107.7(2) . . ?
N1 Si1 C37 110.8(2) . . ?
N2 Si1 C37 110.4(2) . . ?
N1 Si1 C38 105.3(2) . . ?
N2 Si1 C38 112.3(2) . . ?
C37 Si1 C38 110.1(2) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 C40 2.089(5) . ?
Pt1 C39 2.101(5) . ?
Pt1 P2 2.2892(12) . ?
Pt1 P1 2.2961(12) . ?
P1 N1 1.709(4) . ?
P1 C1 1.840(5) . ?
P1 C7 1.848(4) . ?
C1 C2 1.376(7) . ?
C1 C6 1.398(7) . ?
C2 C3 1.395(7) . ?
C3 C4 1.363(7) . ?
C4 C5 1.374(8) . ?
C5 C6 1.376(7) . ?
C7 C12 1.377(6) . ?
C7 C8 1.380(6) . ?
C8 C9 1.386(7) . ?
C9 C10 1.363(7) . ?
C10 C11 1.379(8) . ?
C11 C12 1.383(7) . ?
N1 C13 1.435(6) . ?
N1 Si1 1.773(4) . ?
C13 C18 1.340(6) . ?
C13 N14 1.357(6) . ?
N14 C15 1.353(8) . ?
C15 C16 1.371(8) . ?
C16 C17 1.372(8) . ?
C17 C18 1.354(8) . ?
P2 N2 1.713(4) . ?
P2 C25 1.826(5) . ?
P2 C19 1.841(5) . ?
C19 C24 1.387(6) . ?
C19 C20 1.391(6) . ?
C20 C21 1.382(6) . ?
C21 C22 1.375(7) . ?
C22 C23 1.377(7) . ?
C23 C24 1.394(7) . ?
C25 C30 1.378(6) . ?
C25 C26 1.384(7) . ?
C26 C27 1.379(7) . ?
C27 C28 1.355(8) . ?
C28 C29 1.359(8) . ?
C29 C30 1.384(7) . ?
N2 C31 1.422(6) . ?
N2 Si1 1.785(4) . ?
C31 N32 1.350(6) . ?
C31 C36 1.372(6) . ?
N32 C33 1.336(7) . ?
C33 C34 1.349(9) . ?
C34 C35 1.385(9) . ?
C35 C36 1.384(7) . ?
Si1 C37 1.863(5) . ?
Si1 C38 1.867(5) . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C40 Pt1 P1 N1 150.2(7) . . . . ?
C39 Pt1 P1 N1 -146.5(2) . . . . ?
P2 Pt1 P1 N1 33.61(15) . . . . ?
C40 Pt1 P1 C1 29.6(7) . . . . ?
C39 Pt1 P1 C1 92.9(2) . . . . ?
P2 Pt1 P1 C1 -87.0(2) . . . . ?
C40 Pt1 P1 C7 -86.1(7) . . . . ?
C39 Pt1 P1 C7 -22.8(2) . . . . ?
P2 Pt1 P1 C7 157.3(2) . . . . ?
N1 P1 C1 C2 -122.9(4) . . . . ?
C7 P1 C1 C2 127.2(4) . . . . ?
Pt1 P1 C1 C2 1.2(4) . . . . ?
N1 P1 C1 C6 59.1(5) . . . . ?
C7 P1 C1 C6 -50.8(5) . . . . ?
Pt1 P1 C1 C6 -176.8(4) . . . . ?
C6 C1 C2 C3 0.0(8) . . . . ?
P1 C1 C2 C3 -178.1(4) . . . . ?
C1 C2 C3 C4 -0.9(9) . . . . ?
C2 C3 C4 C5 0.2(10) . . . . ?
C3 C4 C5 C6 1.3(10) . . . . ?
C4 C5 C6 C1 -2.2(9) . . . . ?
C2 C1 C6 C5 1.6(8) . . . . ?
P1 C1 C6 C5 179.6(4) . . . . ?
N1 P1 C7 C12 33.8(5) . . . . ?
C1 P1 C7 C12 145.9(4) . . . . ?
Pt1 P1 C7 C12 -94.2(4) . . . . ?
N1 P1 C7 C8 -153.5(4) . . . . ?
C1 P1 C7 C8 -41.4(5) . . . . ?
Pt1 P1 C7 C8 78.6(4) . . . . ?
C12 C7 C8 C9 0.2(8) . . . . ?
P1 C7 C8 C9 -172.6(4) . . . . ?
C7 C8 C9 C10 -1.2(9) . . . . ?
C8 C9 C10 C11 1.2(10) . . . . ?
C9 C10 C11 C12 -0.3(10) . . . . ?
C8 C7 C12 C11 0.6(8) . . . . ?
P1 C7 C12 C11 173.6(4) . . . . ?
C10 C11 C12 C7 -0.6(9) . . . . ?
C1 P1 N1 C13 -34.2(4) . . . . ?
C7 P1 N1 C13 73.4(4) . . . . ?
Pt1 P1 N1 C13 -155.8(3) . . . . ?
C1 P1 N1 Si1 140.6(2) . . . . ?
C7 P1 N1 Si1 -111.8(2) . . . . ?
Pt1 P1 N1 Si1 19.0(3) . . . . ?
P1 N1 C13 C18 -72.1(6) . . . . ?
Si1 N1 C13 C18 113.1(5) . . . . ?
P1 N1 C13 N14 109.4(5) . . . . ?
Si1 N1 C13 N14 -65.4(5) . . . . ?
C18 C13 N14 C15 0.1(8) . . . . ?
N1 C13 N14 C15 178.6(5) . . . . ?
C13 N14 C15 C16 0.5(10) . . . . ?
N14 C15 C16 C17 0.3(10) . . . . ?
C15 C16 C17 C18 -1.8(10) . . . . ?
N14 C13 C18 C17 -1.5(8) . . . . ?
N1 C13 C18 C17 -180.0(5) . . . . ?
C16 C17 C18 C13 2.4(9) . . . . ?
C40 Pt1 P2 N2 142.4(2) . . . . ?
C39 Pt1 P2 N2 132.8(14) . . . . ?
P1 Pt1 P2 N2 -47.84(14) . . . . ?
C40 Pt1 P2 C25 -96.4(2) . . . . ?
C39 Pt1 P2 C25 -106.0(15) . . . . ?
P1 Pt1 P2 C25 73.3(2) . . . . ?
C40 Pt1 P2 C19 23.8(2) . . . . ?
C39 Pt1 P2 C19 14.2(15) . . . . ?
P1 Pt1 P2 C19 -166.5(2) . . . . ?
N2 P2 C19 C24 112.2(4) . . . . ?
C25 P2 C19 C24 0.8(5) . . . . ?
Pt1 P2 C19 C24 -121.8(4) . . . . ?
N2 P2 C19 C20 -67.3(4) . . . . ?
C25 P2 C19 C20 -178.6(4) . . . . ?
Pt1 P2 C19 C20 58.7(4) . . . . ?
C24 C19 C20 C21 -1.5(7) . . . . ?
P2 C19 C20 C21 178.0(4) . . . . ?
C19 C20 C21 C22 0.7(8) . . . . ?
C20 C21 C22 C23 0.6(9) . . . . ?
C21 C22 C23 C24 -1.0(9) . . . . ?
C20 C19 C24 C23 1.1(8) . . . . ?
P2 C19 C24 C23 -178.3(4) . . . . ?
C22 C23 C24 C19 0.1(8) . . . . ?
N2 P2 C25 C30 18.4(4) . . . . ?
C19 P2 C25 C30 125.3(4) . . . . ?
Pt1 P2 C25 C30 -107.6(4) . . . . ?
N2 P2 C25 C26 -169.9(4) . . . . ?
C19 P2 C25 C26 -63.0(4) . . . . ?
Pt1 P2 C25 C26 64.2(4) . . . . ?
C30 C25 C26 C27 -2.6(7) . . . . ?
P2 C25 C26 C27 -174.5(4) . . . . ?
C25 C26 C27 C28 0.9(8) . . . . ?
C26 C27 C28 C29 2.1(9) . . . . ?
C27 C28 C29 C30 -3.3(9) . . . . ?
C26 C25 C30 C29 1.4(8) . . . . ?
P2 C25 C30 C29 173.3(4) . . . . ?
C28 C29 C30 C25 1.5(9) . . . . ?
C25 P2 N2 C31 81.5(4) . . . . ?
C19 P2 N2 C31 -28.5(4) . . . . ?
Pt1 P2 N2 C31 -155.9(3) . . . . ?
C25 P2 N2 Si1 -113.9(2) . . . . ?
C19 P2 N2 Si1 136.1(2) . . . . ?
Pt1 P2 N2 Si1 8.8(3) . . . . ?
P2 N2 C31 N32 130.9(4) . . . . ?
Si1 N2 C31 N32 -33.9(5) . . . . ?
P2 N2 C31 C36 -47.8(6) . . . . ?
Si1 N2 C31 C36 147.5(4) . . . . ?
C36 C31 N32 C33 -3.5(8) . . . . ?
N2 C31 N32 C33 177.9(5) . . . . ?
C31 N32 C33 C34 2.6(10) . . . . ?
N32 C33 C34 C35 -0.8(11) . . . . ?
C33 C34 C35 C36 -0.3(10) . . . . ?
N32 C31 C36 C35 2.5(8) . . . . ?
N2 C31 C36 C35 -179.0(5) . . . . ?
C34 C35 C36 C31 -0.6(8) . . . . ?
C13 N1 Si1 N2 105.0(3) . . . . ?
P1 N1 Si1 N2 -69.9(3) . . . . ?
C13 N1 Si1 C37 -134.0(4) . . . . ?
P1 N1 Si1 C37 51.0(3) . . . . ?
C13 N1 Si1 C38 -15.0(4) . . . . ?
P1 N1 Si1 C38 170.0(2) . . . . ?
C31 N2 Si1 N1 -142.6(3) . . . . ?
P2 N2 Si1 N1 52.2(3) . . . . ?
C31 N2 Si1 C37 96.3(4) . . . . ?
P2 N2 Si1 C37 -69.0(3) . . . . ?
C31 N2 Si1 C38 -27.0(4) . . . . ?
P2 N2 Si1 C38 167.7(2) . . . . ?
