#------------------------------------------------------------------------------
#$Date: 2016-03-25 12:17:41 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179808 $
#$URL: svn://www.crystallography.net/cod/cif/7/01/04/7010490.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7010490
loop_
_publ_author_name
'Aucott, Stephen M.'
'Clarke, Matthew L.'
'Slawin, Alexandra M. Z.'
'Woollins, J. Derek'
_publ_section_title
;
 Synthesis and co-ordination chemistry of a novel multifunctional
 bis-phosphine containing a P--N--Si--N--P backbone
;
_journal_issue                   7
_journal_name_full
'Journal of the Chemical Society, Dalton Transactions'
_journal_page_first              972
_journal_paper_doi               10.1039/b009722p
_journal_year                    2001
_chemical_compound_source        -
_chemical_formula_analytical     'C35 H31 Cl5 N4 P2 Pt'
_chemical_formula_moiety         'C34 H30 Cl2 N4 P2 Pt.C H Cl3'
_chemical_formula_structural     'C35 H31 Cl5 N4 P2 Pt'
_chemical_formula_sum            'C35 H31 Cl5 N4 P2 Pt'
_chemical_formula_weight         941.92
_chemical_melting_point          ?
_chemical_name_common            9
_chemical_name_systematic
; 
9 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL
_cell_angle_alpha                101.805(2)
_cell_angle_beta                 105.754(2)
_cell_angle_gamma                95.534(2)
_cell_formula_units_Z            2
_cell_length_a                   10.0529(2)
_cell_length_b                   15.5961(6)
_cell_length_c                   16.3639(3)
_cell_measurement_reflns_used    59
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      168
_cell_measurement_theta_min      12
_cell_volume                     2385.37(12)
_computing_cell_refinement       SMART/SAINT
_computing_data_collection       SMART
_computing_data_reduction        SAINT
_computing_molecular_graphics    SHELXTL
_computing_publication_material  SHELXTL
_computing_structure_refinement  'SHELXL-93 (Sheldrick, 1993)'
_computing_structure_solution    'SHELXS-86 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measurement_device       SMART
_diffrn_measurement_method       CCD
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0541
_diffrn_reflns_av_sigmaI/netI    0.0911
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            14884
_diffrn_reflns_theta_max         23.25
_diffrn_reflns_theta_min         1.65
_diffrn_standards_decay_%        -
_diffrn_standards_interval_count -
_diffrn_standards_interval_time  -
_diffrn_standards_number         -
_exptl_absorpt_coefficient_mu    3.313
_exptl_absorpt_correction_T_max  1.000000
_exptl_absorpt_correction_T_min  0.768560
_exptl_absorpt_correction_type   sadabs
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.311
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    -
_exptl_crystal_description       plate
_exptl_crystal_F_000             924
_exptl_crystal_size_max          .27
_exptl_crystal_size_mid          .13
_exptl_crystal_size_min          .02
_refine_diff_density_max         3.031
_refine_diff_density_min         -1.377
_refine_diff_density_rms         0.251
_refine_ls_extinction_coef       0.0031(5)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_all   1.084
_refine_ls_goodness_of_fit_obs   1.193
_refine_ls_hydrogen_treatment    riding
_refine_ls_matrix_type           full
_refine_ls_number_parameters     459
_refine_ls_number_reflns         6788
_refine_ls_number_restraints     2
_refine_ls_restrained_S_all      1.364
_refine_ls_restrained_S_obs      1.193
_refine_ls_R_factor_all          0.1247
_refine_ls_R_factor_obs          0.0928
_refine_ls_shift/esd_max         -0.422
_refine_ls_shift/esd_mean        0.013
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.1457P)²+26.8939P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_all         0.3252
_refine_ls_wR_factor_obs         0.2508
_reflns_number_observed          5121
_reflns_number_total             6838
_reflns_observed_criterion       >2sigma(I)
_cod_data_source_file            b009722p.txt
_cod_data_source_block           9
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to '/home/adriana/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1555 2011-01-17 13:19:09Z saulius 

The following automatic conversions were performed:

'_chemical_melting_point' value '-' was changed to '?' - the value is
undefined or not given.

Automatic conversion script
Id: cif_fix_values 1569 2011-02-09 13:29:24Z adriana 

The following automatic conversions were performed:

'_exptl_crystal_density_meas' value '-' was changed to '?' - the
value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 

The following automatic conversions were performed:

'_refine_ls_weighting_scheme' value 'calc
w=1/[\s^2^(Fo^2^)+(0.1457P)^2^+26.8939P] where P=(Fo^2^+2Fc^2^)/3'
was changed to 'calc'. New tag '_refine_ls_weighting_details' was
created. The value of the new tag was set to
'w=1/[\s^2^(Fo^2^)+(0.1457P)^2^+26.8939P] where P=(Fo^2^+2Fc^2^)/3'.

Automatic conversion script
Id: cif_fix_values 3143 2015-03-26 13:38:13Z robertas 
;
_cod_original_cell_volume        2385.37(11)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7010490
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_thermal_displace_type
_atom_site_occupancy
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_group
Pt1 Pt 0.10912(5) 0.14002(3) 0.27563(3) 0.04344(13) Uani 1 d . .
Cl1 Cl -0.2037(4) 0.2485(3) 0.5370(2) 0.0739(11) Uani 1 d . .
Cl2 Cl 0.5733(5) 0.2043(5) 0.1144(3) 0.128(2) Uani 1 d . .
P1 P 0.0643(3) 0.2337(2) 0.3840(2) 0.0432(8) Uani 1 d . .
N1 N -0.0731(5) 0.1698(5) 0.3942(6) 0.049(3) Uani 1 d D .
H1N H -0.1549(8) 0.1957(14) 0.4025(24) 0.067(41) Uiso 1 d D .
C1 C -0.0054(12) 0.3346(8) 0.3652(8) 0.047(3) Uani 1 d . .
C2 C -0.1301(14) 0.3267(10) 0.3049(10) 0.063(4) Uani 1 d . .
H2A H -0.1820(14) 0.2709(10) 0.2757(10) 0.076 Uiso 1 calc R .
C3 C -0.1791(16) 0.4002(10) 0.2871(10) 0.077(5) Uani 1 d . .
H3A H -0.2662(16) 0.3952(10) 0.2465(10) 0.092 Uiso 1 calc R .
C4 C -0.1026(20) 0.4810(10) 0.3279(11) 0.086(5) Uani 1 d . .
H4A H -0.1380(20) 0.5315(10) 0.3160(11) 0.104 Uiso 1 calc R .
C5 C 0.0286(20) 0.4894(9) 0.3874(11) 0.084(5) Uani 1 d . .
H5A H 0.0830(20) 0.5451(9) 0.4137(11) 0.101 Uiso 1 calc R .
C6 C 0.0769(17) 0.4152(9) 0.4068(10) 0.071(5) Uani 1 d . .
H6A H 0.1638(17) 0.4192(9) 0.4474(10) 0.085 Uiso 1 calc R .
C7 C 0.2008(12) 0.2605(7) 0.4846(8) 0.044(3) Uani 1 d . .
C8 C 0.3320(13) 0.2450(10) 0.4886(9) 0.062(4) Uani 1 d . .
H8A H 0.3515(13) 0.2200(10) 0.4374(9) 0.074 Uiso 1 calc R .
C9 C 0.4420(14) 0.2662(11) 0.5703(11) 0.072(5) Uani 1 d . .
H9A H 0.5332(14) 0.2582(11) 0.5723(11) 0.086 Uiso 1 calc R .
C10 C 0.4092(14) 0.2974(10) 0.6422(10) 0.068(5) Uani 1 d . .
H10A H 0.4786(14) 0.3100(10) 0.6957(10) 0.082 Uiso 1 calc R .
C11 C 0.2779(14) 0.3118(9) 0.6408(9) 0.059(4) Uani 1 d . .
H11A H 0.2596(14) 0.3349(9) 0.6930(9) 0.071 Uiso 1 calc R .
C12 C 0.1756(13) 0.2933(8) 0.5664(9) 0.056(4) Uani 1 d . .
H12A H 0.0856(13) 0.3018(8) 0.5672(9) 0.067 Uiso 1 calc R .
C13 C -0.0715(12) 0.0781(7) 0.3771(8) 0.046(3) Uani 1 d . .
N14 N 0.0094(11) 0.0487(7) 0.3293(7) 0.054(3) Uani 1 d . .
C15 C 0.0277(15) -0.0364(9) 0.3212(10) 0.062(4) Uani 1 d . .
H15A H 0.0906(15) -0.0567(9) 0.2922(10) 0.074 Uiso 1 calc R .
C16 C -0.0418(16) -0.0945(10) 0.3534(10) 0.068(4) Uani 1 d . .
H16A H -0.0285(16) -0.1535(10) 0.3459(10) 0.082 Uiso 1 calc R .
C17 C -0.1322(16) -0.0626(10) 0.3975(11) 0.075(5) Uani 1 d . .
H17A H -0.1828(16) -0.1011(10) 0.4188(11) 0.090 Uiso 1 calc R .
C18 C -0.1494(14) 0.0248(8) 0.4107(9) 0.057(4) Uani 1 d . .
H18A H -0.2102(14) 0.0469(8) 0.4406(9) 0.068 Uiso 1 calc R .
P2 P 0.2253(4) 0.2331(2) 0.2222(2) 0.0509(9) Uani 1 d . .
N2 N 0.3113(6) 0.1625(6) 0.1738(5) 0.065(3) Uani 1 d D .
H2N H 0.3792(12) 0.1889(17) 0.1492(12) 0.107(59) Uiso 1 d D .
C19 C 0.3601(12) 0.3232(9) 0.2940(8) 0.050(4) Uani 1 d . .
C20 C 0.4849(17) 0.3065(12) 0.3377(12) 0.088(5) Uani 1 d . .
H20A H 0.5063(17) 0.2493(12) 0.3294(12) 0.105 Uiso 1 calc R .
C21 C 0.5863(18) 0.3818(14) 0.3991(11) 0.096(7) Uani 1 d . .
H21A H 0.6712(18) 0.3722(14) 0.4335(11) 0.115 Uiso 1 calc R .
C22 C 0.5565(19) 0.4629(13) 0.4054(12) 0.096(6) Uani 1 d . .
H22A H 0.6236(19) 0.5115(13) 0.4398(12) 0.115 Uiso 1 calc R .
C23 C 0.4276(19) 0.4750(11) 0.3615(12) 0.088(6) Uani 1 d . .
H23A H 0.4056(19) 0.5321(11) 0.3681(12) 0.106 Uiso 1 calc R .
C24 C 0.3321(15) 0.4077(8) 0.3096(9) 0.060(4) Uani 1 d . .
H24A H 0.2431(15) 0.4183(8) 0.2829(9) 0.072 Uiso 1 calc R .
C25 C 0.1153(15) 0.2798(9) 0.1411(8) 0.057(4) Uani 1 d . .
C26 C -0.0273(15) 0.2713(9) 0.1277(10) 0.063(4) Uani 1 d . .
H26A H -0.0678(15) 0.2404(9) 0.1602(10) 0.075 Uiso 1 calc R .
C27 C -0.1108(18) 0.3084(11) 0.0665(11) 0.079(5) Uani 1 d . .
H27A H -0.2072(18) 0.3002(11) 0.0565(11) 0.095 Uiso 1 calc R .
C28 C -0.0538(22) 0.3560(12) 0.0218(12) 0.098(7) Uani 1 d . .
H28A H -0.1098(22) 0.3823(12) -0.0180(12) 0.117 Uiso 1 calc R .
C29 C 0.0993(22) 0.3665(12) 0.0362(11) 0.094(6) Uani 1 d . .
H29A H 0.1396(22) 0.3970(12) 0.0034(11) 0.112 Uiso 1 calc R .
C30 C 0.1788(17) 0.3321(11) 0.0963(9) 0.075(5) Uani 1 d . .
H30A H 0.2757(17) 0.3423(11) 0.1088(9) 0.090 Uiso 1 calc R .
C31 C 0.2423(14) 0.0752(9) 0.1355(8) 0.057(4) Uani 1 d . .
N32 N 0.1377(11) 0.0490(8) 0.1667(8) 0.066(4) Uani 1 d . .
C33 C 0.0579(14) -0.0316(8) 0.1269(9) 0.059(4) Uani 1 d . .
H33A H -0.0215(14) -0.0478(8) 0.1425(9) 0.071 Uiso 1 calc R .
C34 C 0.0911(18) -0.0867(10) 0.0671(10) 0.079(5) Uani 1 d . .
H34A H 0.0378(18) -0.1429(10) 0.0428(10) 0.095 Uiso 1 calc R .
C35 C 0.2077(16) -0.0623(9) 0.0382(10) 0.068(4) Uani 1 d . .
H35A H 0.2321(16) -0.1023(9) -0.0037(10) 0.081 Uiso 1 calc R .
C36 C 0.2801(15) 0.0182(10) 0.0724(10) 0.067(4) Uani 1 d . .
H36A H 0.3558(15) 0.0365(10) 0.0542(10) 0.080 Uiso 1 calc R .
C50 C -0.3933(25) -0.1412(16) 0.1011(17) 0.050(6) Uiso 0.50 d P .
H50A H -0.4539(25) -0.1511(16) 0.0409(17) 0.059 Uiso 0.50 calc PR .
Cl3 Cl -0.3427(8) -0.0309(5) 0.1420(5) 0.068(2) Uani 0.50 d P .
Cl4 Cl -0.2498(7) -0.1957(5) 0.0988(7) 0.091(3) Uani 0.50 d P .
Cl5 Cl -0.4926(11) -0.1819(9) 0.1628(6) 0.137(4) Uani 0.50 d P .
C60 C -0.1462(15) 0.3451(10) 0.7296(10) 0.008(3) Uiso 0.50 d P .
H60A H -0.1732(15) 0.3398(10) 0.6664(10) 0.009 Uiso 0.50 calc PR .
Cl6 Cl 0.0489(7) 0.3372(7) 0.7966(5) 0.082(3) Uani 0.50 d P .
Cl7 Cl -0.1970(8) 0.4162(4) 0.7919(5) 0.077(2) Uani 0.50 d P .
Cl8 Cl -0.2031(10) 0.2340(5) 0.7841(5) 0.090(3) Uani 0.50 d P .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N14 Pt1 N32 99.5(4) . . ?
N14 Pt1 P1 79.6(3) . . ?
N32 Pt1 P1 176.2(3) . . ?
N14 Pt1 P2 176.7(3) . . ?
N32 Pt1 P2 79.6(3) . . ?
P1 Pt1 P2 101.50(12) . . ?
N1 P1 C7 108.9(5) . . ?
N1 P1 C1 103.2(5) . . ?
C7 P1 C1 109.1(5) . . ?
N1 P1 Pt1 99.4(3) . . ?
C7 P1 Pt1 114.4(4) . . ?
C1 P1 Pt1 120.2(4) . . ?
C13 N1 P1 116.4(7) . . ?
C2 C1 C6 122.1(13) . . ?
C2 C1 P1 118.8(9) . . ?
C6 C1 P1 118.8(10) . . ?
C3 C2 C1 119.5(13) . . ?
C2 C3 C4 120.3(14) . . ?
C3 C4 C5 120.5(14) . . ?
C6 C5 C4 119.1(14) . . ?
C5 C6 C1 118.4(15) . . ?
C8 C7 C12 116.3(11) . . ?
C8 C7 P1 121.6(10) . . ?
C12 C7 P1 121.9(9) . . ?
C7 C8 C9 121.5(13) . . ?
C10 C9 C8 117.7(13) . . ?
C9 C10 C11 122.3(13) . . ?
C12 C11 C10 120.9(14) . . ?
C11 C12 C7 121.1(12) . . ?
N14 C13 C18 124.1(11) . . ?
N14 C13 N1 115.9(11) . . ?
C18 C13 N1 120.0(11) . . ?
C13 N14 C15 117.4(12) . . ?
C13 N14 Pt1 118.3(8) . . ?
C15 N14 Pt1 124.3(10) . . ?
N14 C15 C16 123.0(14) . . ?
C15 C16 C17 117.4(14) . . ?
C18 C17 C16 121.5(15) . . ?
C17 C18 C13 116.2(13) . . ?
N2 P2 C25 109.2(5) . . ?
N2 P2 C19 104.8(5) . . ?
C25 P2 C19 106.5(6) . . ?
N2 P2 Pt1 99.3(3) . . ?
C25 P2 Pt1 114.6(5) . . ?
C19 P2 Pt1 121.2(5) . . ?
C31 N2 P2 117.4(7) . . ?
C20 C19 C24 119.2(13) . . ?
C20 C19 P2 120.4(12) . . ?
C24 C19 P2 120.2(9) . . ?
C19 C20 C21 117.7(17) . . ?
C22 C21 C20 119.8(17) . . ?
C21 C22 C23 119.4(16) . . ?
C24 C23 C22 121.6(17) . . ?
C23 C24 C19 121.9(15) . . ?
C26 C25 C30 119.9(14) . . ?
C26 C25 P2 120.9(11) . . ?
C30 C25 P2 119.0(11) . . ?
C25 C26 C27 120.6(15) . . ?
C28 C27 C26 120.5(17) . . ?
C27 C28 C29 119.4(17) . . ?
C30 C29 C28 119.7(17) . . ?
C29 C30 C25 119.7(16) . . ?
N32 C31 C36 121.7(13) . . ?
N32 C31 N2 115.2(11) . . ?
C36 C31 N2 123.1(12) . . ?
C31 N32 C33 118.3(12) . . ?
C31 N32 Pt1 117.0(9) . . ?
C33 N32 Pt1 124.8(10) . . ?
C34 C33 N32 120.8(14) . . ?
C33 C34 C35 121.1(13) . . ?
C36 C35 C34 118.3(14) . . ?
C35 C36 C31 119.3(15) . . ?
Cl3 C50 Cl4 111.5(13) . . ?
Cl3 C50 Cl5 108.7(15) . . ?
Cl4 C50 Cl5 112.3(16) . . ?
Cl7 C60 Cl6 105.8(8) . . ?
Cl7 C60 Cl8 95.1(9) . . ?
Cl6 C60 Cl8 83.5(7) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 N14 2.126(11) . ?
Pt1 N32 2.143(12) . ?
Pt1 P1 2.231(3) . ?
Pt1 P2 2.233(4) . ?
P1 N1 1.690(8) . ?
P1 C7 1.775(12) . ?
P1 C1 1.832(13) . ?
N1 C13 1.402(14) . ?
C1 C2 1.35(2) . ?
C1 C6 1.37(2) . ?
C2 C3 1.34(2) . ?
C3 C4 1.35(2) . ?
C4 C5 1.39(2) . ?
C5 C6 1.36(2) . ?
C7 C8 1.35(2) . ?
C7 C12 1.43(2) . ?
C8 C9 1.44(2) . ?
C9 C10 1.32(2) . ?
C10 C11 1.36(2) . ?
C11 C12 1.32(2) . ?
C13 N14 1.32(2) . ?
C13 C18 1.38(2) . ?
N14 C15 1.34(2) . ?
C15 C16 1.36(2) . ?
C16 C17 1.37(2) . ?
C17 C18 1.37(2) . ?
P2 N2 1.667(9) . ?
P2 C25 1.808(15) . ?
P2 C19 1.812(12) . ?
N2 C31 1.40(2) . ?
C19 C20 1.34(2) . ?
C19 C24 1.36(2) . ?
C20 C21 1.47(2) . ?
C21 C22 1.32(3) . ?
C22 C23 1.35(3) . ?
C23 C24 1.32(2) . ?
C25 C26 1.38(2) . ?
C25 C30 1.42(2) . ?
C26 C27 1.38(2) . ?
C27 C28 1.33(3) . ?
C28 C29 1.48(3) . ?
C29 C30 1.33(2) . ?
C31 N32 1.35(2) . ?
C31 C36 1.38(2) . ?
N32 C33 1.35(2) . ?
C33 C34 1.30(2) . ?
C34 C35 1.42(2) . ?
C35 C36 1.32(2) . ?
C50 Cl3 1.68(3) . ?
C50 Cl4 1.75(3) . ?
C50 Cl5 1.76(3) . ?
C60 Cl7 1.57(2) . ?
C60 Cl6 2.00(2) . ?
C60 Cl8 2.20(2) . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N14 Pt1 P1 N1 -25.0(4) . . . . ?
N32 Pt1 P1 N1 51.6(55) . . . . ?
P2 Pt1 P1 N1 158.2(3) . . . . ?
N14 Pt1 P1 C7 90.9(5) . . . . ?
N32 Pt1 P1 C7 167.4(55) . . . . ?
P2 Pt1 P1 C7 -86.0(5) . . . . ?
N14 Pt1 P1 C1 -136.3(5) . . . . ?
N32 Pt1 P1 C1 -59.8(55) . . . . ?
P2 Pt1 P1 C1 46.8(5) . . . . ?
C7 P1 N1 C13 -87.0(9) . . . . ?
C1 P1 N1 C13 157.2(9) . . . . ?
Pt1 P1 N1 C13 33.0(8) . . . . ?
N1 P1 C1 C2 -48.2(12) . . . . ?
C7 P1 C1 C2 -164.0(11) . . . . ?
Pt1 P1 C1 C2 61.0(12) . . . . ?
N1 P1 C1 C6 138.0(12) . . . . ?
C7 P1 C1 C6 22.3(13) . . . . ?
Pt1 P1 C1 C6 -112.7(11) . . . . ?
C6 C1 C2 C3 -2.9(23) . . . . ?
P1 C1 C2 C3 -176.5(12) . . . . ?
C1 C2 C3 C4 1.6(26) . . . . ?
C2 C3 C4 C5 1.2(28) . . . . ?
C3 C4 C5 C6 -2.7(29) . . . . ?
C4 C5 C6 C1 1.3(26) . . . . ?
C2 C1 C6 C5 1.4(24) . . . . ?
P1 C1 C6 C5 175.0(13) . . . . ?
N1 P1 C7 C8 126.8(11) . . . . ?
C1 P1 C7 C8 -121.2(12) . . . . ?
Pt1 P1 C7 C8 16.6(13) . . . . ?
N1 P1 C7 C12 -48.3(11) . . . . ?
C1 P1 C7 C12 63.7(12) . . . . ?
Pt1 P1 C7 C12 -158.4(9) . . . . ?
C12 C7 C8 C9 -4.2(21) . . . . ?
P1 C7 C8 C9 -179.5(12) . . . . ?
C7 C8 C9 C10 3.3(24) . . . . ?
C8 C9 C10 C11 -1.7(25) . . . . ?
C9 C10 C11 C12 1.2(25) . . . . ?
C10 C11 C12 C7 -2.2(22) . . . . ?
C8 C7 C12 C11 3.7(20) . . . . ?
P1 C7 C12 C11 179.0(11) . . . . ?
P1 N1 C13 N14 -20.6(13) . . . . ?
P1 N1 C13 C18 158.3(10) . . . . ?
C18 C13 N14 C15 -7.3(18) . . . . ?
N1 C13 N14 C15 171.6(10) . . . . ?
C18 C13 N14 Pt1 175.5(10) . . . . ?
N1 C13 N14 Pt1 -5.7(13) . . . . ?
N32 Pt1 N14 C13 -155.3(9) . . . . ?
P1 Pt1 N14 C13 20.9(8) . . . . ?
P2 Pt1 N14 C13 131.4(46) . . . . ?
N32 Pt1 N14 C15 27.6(11) . . . . ?
P1 Pt1 N14 C15 -156.2(10) . . . . ?
P2 Pt1 N14 C15 -45.6(54) . . . . ?
C13 N14 C15 C16 5.6(19) . . . . ?
Pt1 N14 C15 C16 -177.4(10) . . . . ?
N14 C15 C16 C17 -1.2(21) . . . . ?
C15 C16 C17 C18 -1.7(22) . . . . ?
C16 C17 C18 C13 0.2(21) . . . . ?
N14 C13 C18 C17 4.5(19) . . . . ?
N1 C13 C18 C17 -174.4(11) . . . . ?
N14 Pt1 P2 N2 47.6(49) . . . . ?
N32 Pt1 P2 N2 -26.2(4) . . . . ?
P1 Pt1 P2 N2 157.5(3) . . . . ?
N14 Pt1 P2 C25 163.8(49) . . . . ?
N32 Pt1 P2 C25 90.0(6) . . . . ?
P1 Pt1 P2 C25 -86.3(5) . . . . ?
N14 Pt1 P2 C19 -66.1(50) . . . . ?
N32 Pt1 P2 C19 -139.9(6) . . . . ?
P1 Pt1 P2 C19 43.8(5) . . . . ?
C25 P2 N2 C31 -85.1(10) . . . . ?
C19 P2 N2 C31 161.0(9) . . . . ?
Pt1 P2 N2 C31 35.1(9) . . . . ?
N2 P2 C19 C20 -38.2(14) . . . . ?
C25 P2 C19 C20 -153.9(13) . . . . ?
Pt1 P2 C19 C20 72.6(14) . . . . ?
N2 P2 C19 C24 147.1(11) . . . . ?
C25 P2 C19 C24 31.4(14) . . . . ?
Pt1 P2 C19 C24 -102.1(12) . . . . ?
C24 C19 C20 C21 -1.4(24) . . . . ?
P2 C19 C20 C21 -176.2(12) . . . . ?
C19 C20 C21 C22 -4.4(27) . . . . ?
C20 C21 C22 C23 6.4(30) . . . . ?
C21 C22 C23 C24 -2.7(32) . . . . ?
C22 C23 C24 C19 -3.3(29) . . . . ?
C20 C19 C24 C23 5.2(25) . . . . ?
P2 C19 C24 C23 180.0(14) . . . . ?
N2 P2 C25 C26 122.5(11) . . . . ?
C19 P2 C25 C26 -124.8(11) . . . . ?
Pt1 P2 C25 C26 12.1(12) . . . . ?
N2 P2 C25 C30 -63.0(12) . . . . ?
C19 P2 C25 C30 49.7(12) . . . . ?
Pt1 P2 C25 C30 -173.3(9) . . . . ?
C30 C25 C26 C27 4.4(20) . . . . ?
P2 C25 C26 C27 178.9(11) . . . . ?
C25 C26 C27 C28 -2.6(23) . . . . ?
C26 C27 C28 C29 1.9(26) . . . . ?
C27 C28 C29 C30 -3.2(26) . . . . ?
C28 C29 C30 C25 5.0(24) . . . . ?
C26 C25 C30 C29 -5.7(22) . . . . ?
P2 C25 C30 C29 179.7(13) . . . . ?
P2 N2 C31 N32 -22.2(15) . . . . ?
P2 N2 C31 C36 159.9(11) . . . . ?
C36 C31 N32 C33 -8.2(21) . . . . ?
N2 C31 N32 C33 173.8(12) . . . . ?
C36 C31 N32 Pt1 172.5(11) . . . . ?
N2 C31 N32 Pt1 -5.5(16) . . . . ?
N14 Pt1 N32 C31 -155.5(10) . . . . ?
P1 Pt1 N32 C31 128.6(50) . . . . ?
P2 Pt1 N32 C31 21.3(10) . . . . ?
N14 Pt1 N32 C33 25.3(12) . . . . ?
P1 Pt1 N32 C33 -50.6(62) . . . . ?
P2 Pt1 N32 C33 -157.9(12) . . . . ?
C31 N32 C33 C34 8.0(22) . . . . ?
Pt1 N32 C33 C34 -172.8(12) . . . . ?
N32 C33 C34 C35 -3.4(25) . . . . ?
C33 C34 C35 C36 -1.2(25) . . . . ?
C34 C35 C36 C31 1.1(24) . . . . ?
N32 C31 C36 C35 3.7(23) . . . . ?
N2 C31 C36 C35 -178.5(14) . . . . ?
