#------------------------------------------------------------------------------
#$Date: 2016-03-25 12:21:42 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179812 $
#$URL: svn://www.crystallography.net/cod/cif/7/01/08/7010815.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7010815
loop_
_publ_author_name
'William J. Evans'
'Dimitrios G. Giarikos'
'Matthew A. Johnston'
'Michael A. Greci'
'Joseph W. Ziller'
_publ_section_title
;
 Reactivity of the europium hexafluoroacetylacetonate (hfac) complex,
 Eu(hfac)3(diglyme), and related analogs with potassium: formation of
 the fluoride hfac “ate” complexes,
 [LnF(hfac)3K(diglyme)]2
;
_journal_issue                   4
_journal_name_full               'J. Chem. Soc., Dalton Trans.'
_journal_page_first              520
_journal_page_last               526
_journal_paper_doi               10.1039/b104095m
_journal_year                    2002
_chemical_formula_sum            'C44 H73 Eu F12 O13 Zr2'
_chemical_formula_weight         1372.42
_chemical_name_systematic
; 
? 
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXTL
_cell_angle_alpha                90.00
_cell_angle_beta                 100.9110(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   16.6625(9)
_cell_length_b                   21.3117(11)
_cell_length_c                   16.4412(8)
_cell_measurement_temperature    158(2)
_cell_volume                     5732.8(5)
_computing_cell_refinement       'Bruker SMART/SAINT'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SHELXTL'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'Bruker SHELXTL'
_computing_structure_solution    'Bruker SHELXTL'
_diffrn_ambient_temperature      158(2)
_diffrn_measured_fraction_theta_full 0.952
_diffrn_measured_fraction_theta_max 0.952
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0347
_diffrn_reflns_av_sigmaI/netI    0.0326
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -22
_diffrn_reflns_limit_k_max       28
_diffrn_reflns_limit_k_min       -27
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            18523
_diffrn_reflns_theta_full        28.29
_diffrn_reflns_theta_max         28.29
_diffrn_reflns_theta_min         1.91
_diffrn_standards_decay_%        '< 1.0'
_exptl_absorpt_coefficient_mu    1.530
_exptl_absorpt_correction_T_max  0.6917
_exptl_absorpt_correction_T_min  0.6088
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            brown
_exptl_crystal_density_diffrn    1.590
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       irregular
_exptl_crystal_F_000             2768
_exptl_crystal_size_max          0.36
_exptl_crystal_size_mid          0.29
_exptl_crystal_size_min          0.26
_refine_diff_density_max         1.458
_refine_diff_density_min         -1.083
_refine_diff_density_rms         0.131
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.098
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     315
_refine_ls_number_reflns         6764
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.098
_refine_ls_R_factor_all          0.0553
_refine_ls_R_factor_gt           0.0505
_refine_ls_shift/su_max          0.007
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0624P)²+38.1827P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1349
_refine_ls_wR_factor_ref         0.1398
_reflns_number_gt                6083
_reflns_number_total             6764
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b104095m.txt
_cod_data_source_block           maj33
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 

The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'none' was changed to '?' - the
value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 
;
_cod_original_sg_symbol_H-M      C2/c
_cod_database_code               7010815
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.0000 0.324876(12) 0.2500 0.02857(10) Uani 1 2 d S . .
Zr1 Zr 0.00503(2) 0.181057(18) 0.35228(2) 0.02812(11) Uani 1 1 d . . .
O1 O 0.1228(2) 0.36703(16) 0.2168(2) 0.0410(7) Uani 1 1 d . . .
O2 O 0.0436(2) 0.41330(16) 0.3377(2) 0.0455(8) Uani 1 1 d . . .
O3 O 0.07701(16) 0.22428(13) 0.26193(17) 0.0282(5) Uani 1 1 d . . .
O4 O 0.00912(19) 0.27640(14) 0.38311(17) 0.0344(6) Uani 1 1 d . . .
O5 O 0.0966(2) 0.15012(16) 0.43157(19) 0.0410(7) Uani 1 1 d . . .
O6 O -0.0848(2) 0.15429(17) 0.4018(2) 0.0423(7) Uani 1 1 d . . .
O7 O 0.0000 0.11494(19) 0.2500 0.0317(8) Uani 1 2 d S . .
C1 C 0.0833(4) 0.5105(3) 0.3992(5) 0.0706(19) Uani 1 1 d . . .
C2 C 0.0917(3) 0.4577(2) 0.3361(3) 0.0497(12) Uani 1 1 d . A .
C3 C 0.1497(3) 0.4644(3) 0.2870(3) 0.0508(12) Uani 1 1 d . . .
H3A H 0.1824 0.5012 0.2912 0.061 Uiso 1 1 calc R A .
C4 C 0.1604(3) 0.4173(3) 0.2310(3) 0.0465(11) Uani 1 1 d . A .
C5 C 0.2285(4) 0.4269(3) 0.1795(4) 0.0655(17) Uani 1 1 d . . .
C6 C 0.1659(2) 0.2250(2) 0.2704(3) 0.0365(9) Uani 1 1 d . . .
H6A H 0.1798 0.2453 0.2200 0.044 Uiso 1 1 calc R . .
C7 C 0.2047(3) 0.2631(3) 0.3457(3) 0.0478(11) Uani 1 1 d . . .
H7A H 0.1821 0.3057 0.3411 0.072 Uiso 1 1 calc R . .
H7B H 0.2640 0.2650 0.3488 0.072 Uiso 1 1 calc R . .
H7C H 0.1931 0.2431 0.3959 0.072 Uiso 1 1 calc R . .
C8 C 0.2008(3) 0.1590(3) 0.2771(4) 0.0502(12) Uani 1 1 d . . .
H8A H 0.1759 0.1347 0.2282 0.075 Uiso 1 1 calc R . .
H8B H 0.1890 0.1388 0.3270 0.075 Uiso 1 1 calc R . .
H8C H 0.2601 0.1610 0.2804 0.075 Uiso 1 1 calc R . .
C9 C 0.0072(4) 0.2955(4) 0.4666(4) 0.074(2) Uani 1 1 d . . .
H9A H -0.0011 0.2548 0.4943 0.089 Uiso 1 1 calc R . .
C10 C 0.0896(4) 0.3159(3) 0.5116(4) 0.0623(16) Uani 1 1 d . . .
H10A H 0.0862 0.3280 0.5683 0.093 Uiso 1 1 calc R . .
H10B H 0.1082 0.3518 0.4829 0.093 Uiso 1 1 calc R . .
H10C H 0.1285 0.2812 0.5130 0.093 Uiso 1 1 calc R . .
C11 C -0.0600(5) 0.3302(4) 0.4779(5) 0.086(3) Uani 1 1 d . . .
H11A H -0.1097 0.3116 0.4456 0.129 Uiso 1 1 calc R . .
H11B H -0.0543 0.3734 0.4593 0.129 Uiso 1 1 calc R . .
H11C H -0.0634 0.3303 0.5367 0.129 Uiso 1 1 calc R . .
C12 C 0.1562(4) 0.1328(3) 0.5019(3) 0.0565(14) Uani 1 1 d . . .
H12A H 0.1978 0.1671 0.5117 0.068 Uiso 1 1 calc R . .
C13 C 0.1173(5) 0.1293(4) 0.5770(4) 0.080(2) Uani 1 1 d . . .
H13A H 0.0906 0.1693 0.5842 0.120 Uiso 1 1 calc R . .
H13B H 0.1593 0.1207 0.6260 0.120 Uiso 1 1 calc R . .
H13C H 0.0765 0.0956 0.5698 0.120 Uiso 1 1 calc R . .
C14 C 0.1994(6) 0.0745(4) 0.4855(5) 0.110(4) Uani 1 1 d . . .
H14A H 0.2236 0.0803 0.4362 0.165 Uiso 1 1 calc R . .
H14B H 0.1604 0.0395 0.4764 0.165 Uiso 1 1 calc R . .
H14C H 0.2426 0.0651 0.5333 0.165 Uiso 1 1 calc R . .
C15 C -0.1454(4) 0.1289(3) 0.4428(4) 0.0673(17) Uani 1 1 d . . .
H15A H -0.1757 0.0975 0.4032 0.081 Uiso 1 1 calc R . .
C16 C -0.2072(5) 0.1775(3) 0.4528(6) 0.080(2) Uani 1 1 d . . .
H16A H -0.2278 0.1973 0.3991 0.120 Uiso 1 1 calc R . .
H16B H -0.1817 0.2093 0.4924 0.120 Uiso 1 1 calc R . .
H16C H -0.2526 0.1577 0.4733 0.120 Uiso 1 1 calc R . .
C17 C -0.1114(6) 0.0937(4) 0.5148(7) 0.118(4) Uani 1 1 d . . .
H17A H -0.0726 0.0629 0.5008 0.178 Uiso 1 1 calc R . .
H17B H -0.1552 0.0720 0.5357 0.178 Uiso 1 1 calc R . .
H17C H -0.0829 0.1222 0.5576 0.178 Uiso 1 1 calc R . .
C18 C 0.0254(6) 0.0499(4) 0.2621(7) 0.045(2) Uani 0.50 1 d P . .
C19 C 0.0111(6) 0.0177(3) 0.1782(4) 0.073(2) Uani 1 1 d . . .
F1 F 0.1008(7) 0.4827(5) 0.4792(6) 0.080(3) Uiso 0.62(2) 1 d P A 1
F2 F 0.0076(5) 0.5305(4) 0.3902(7) 0.078(3) Uiso 0.62(2) 1 d P A 1
F3 F 0.1469(5) 0.5496(4) 0.4121(6) 0.073(3) Uiso 0.62(2) 1 d P A 1
F1A F 0.0748(11) 0.4947(7) 0.4669(9) 0.074(4) Uiso 0.38(2) 1 d P A 2
F2A F 0.0138(8) 0.5460(7) 0.3615(10) 0.075(4) Uiso 0.38(2) 1 d P A 2
F3A F 0.1219(9) 0.5642(7) 0.3802(10) 0.075(4) Uiso 0.38(2) 1 d P A 2
F4 F 0.1987(6) 0.4552(6) 0.1111(6) 0.096(3) Uiso 0.577(15) 1 d P A 1
F5 F 0.2920(5) 0.4578(4) 0.2186(5) 0.068(2) Uiso 0.577(15) 1 d P A 1
F6 F 0.2629(5) 0.3686(4) 0.1644(6) 0.080(3) Uiso 0.577(15) 1 d P A 1
F4A F 0.2012(5) 0.4245(5) 0.0999(6) 0.060(3) Uiso 0.423(15) 1 d P A 2
F5A F 0.2627(10) 0.4855(8) 0.1918(10) 0.112(5) Uiso 0.423(15) 1 d P A 2
F6A F 0.2828(9) 0.3855(7) 0.1991(11) 0.102(4) Uiso 0.423(15) 1 d P A 2
C20 C -0.0390(7) 0.8202(5) 0.2352(8) 0.117(4) Uiso 1 1 d . . .
C21 C -0.0863(10) 0.7617(9) 0.2161(10) 0.157(5) Uiso 1 1 d . . .
C22 C -0.0683(14) 0.7148(12) 0.2193(14) 0.101(6) Uiso 0.50 1 d P . .
C23 C -0.0206(11) 0.7057(8) 0.2455(15) 0.086(5) Uiso 0.50 1 d P . .
C24 C -0.0627(19) 0.6538(15) 0.233(2) 0.152(10) Uiso 0.50 1 d P . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zr Zr -2.9673 0.5597 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Eu1 O1 135.83(16) 2 . ?
O1 Eu1 O4 117.45(11) 2 2 ?
O1 Eu1 O4 82.12(11) . 2 ?
O1 Eu1 O4 82.12(11) 2 . ?
O1 Eu1 O4 117.45(11) . . ?
O4 Eu1 O4 128.97(14) 2 . ?
O1 Eu1 O2 75.08(12) 2 . ?
O1 Eu1 O2 70.56(11) . . ?
O4 Eu1 O2 147.77(11) 2 . ?
O4 Eu1 O2 80.24(11) . . ?
O1 Eu1 O2 70.56(11) 2 2 ?
O1 Eu1 O2 75.08(12) . 2 ?
O4 Eu1 O2 80.24(11) 2 2 ?
O4 Eu1 O2 147.77(11) . 2 ?
O2 Eu1 O2 76.54(18) . 2 ?
O1 Eu1 O3 83.74(10) 2 2 ?
O1 Eu1 O3 139.22(10) . 2 ?
O4 Eu1 O3 67.30(9) 2 2 ?
O4 Eu1 O3 69.10(9) . 2 ?
O2 Eu1 O3 144.79(10) . 2 ?
O2 Eu1 O3 122.44(11) 2 2 ?
O1 Eu1 O3 139.22(10) 2 . ?
O1 Eu1 O3 83.74(10) . . ?
O4 Eu1 O3 69.10(9) 2 . ?
O4 Eu1 O3 67.30(9) . . ?
O2 Eu1 O3 122.44(11) . . ?
O2 Eu1 O3 144.79(10) 2 . ?
O3 Eu1 O3 60.92(12) 2 . ?
O1 Eu1 Zr1 119.78(8) 2 2 ?
O1 Eu1 Zr1 99.43(8) . 2 ?
O4 Eu1 Zr1 35.94(7) 2 2 ?
O4 Eu1 Zr1 93.03(7) . 2 ?
O2 Eu1 Zr1 162.95(9) . 2 ?
O2 Eu1 Zr1 115.04(9) 2 2 ?
O3 Eu1 Zr1 40.52(6) 2 2 ?
O3 Eu1 Zr1 41.05(6) . 2 ?
O1 Eu1 Zr1 99.43(8) 2 . ?
O1 Eu1 Zr1 119.78(8) . . ?
O4 Eu1 Zr1 93.03(7) 2 . ?
O4 Eu1 Zr1 35.94(7) . . ?
O2 Eu1 Zr1 115.04(9) . . ?
O2 Eu1 Zr1 162.95(9) 2 . ?
O3 Eu1 Zr1 41.05(6) 2 . ?
O3 Eu1 Zr1 40.52(6) . . ?
Zr1 Eu1 Zr1 57.103(14) 2 . ?
O6 Zr1 O5 101.10(15) . . ?
O6 Zr1 O4 100.25(14) . . ?
O5 Zr1 O4 100.56(13) . . ?
O6 Zr1 O7 102.44(12) . . ?
O5 Zr1 O7 102.14(12) . . ?
O4 Zr1 O7 143.91(11) . . ?
O6 Zr1 O3 161.28(13) . . ?
O5 Zr1 O3 97.62(12) . . ?
O4 Zr1 O3 76.58(11) . . ?
O7 Zr1 O3 72.92(9) . . ?
O6 Zr1 O3 94.29(13) . 2 ?
O5 Zr1 O3 164.51(12) . 2 ?
O4 Zr1 O3 78.20(11) . 2 ?
O7 Zr1 O3 72.47(9) . 2 ?
O3 Zr1 O3 66.99(12) . 2 ?
O6 Zr1 Zr1 122.21(11) . 2 ?
O5 Zr1 Zr1 124.38(10) . 2 ?
O4 Zr1 Zr1 103.73(8) . 2 ?
O7 Zr1 Zr1 40.19(8) . 2 ?
O3 Zr1 Zr1 43.38(7) . 2 ?
O3 Zr1 Zr1 42.85(7) 2 2 ?
O6 Zr1 Eu1 121.03(11) . . ?
O5 Zr1 Eu1 124.79(11) . . ?
O4 Zr1 Eu1 42.30(8) . . ?
O7 Zr1 Eu1 101.64(8) . . ?
O3 Zr1 Eu1 45.31(7) . . ?
O3 Zr1 Eu1 45.35(7) 2 . ?
Zr1 Zr1 Eu1 61.449(7) 2 . ?
C4 O1 Eu1 134.9(3) . . ?
C2 O2 Eu1 135.0(3) . . ?
C6 O3 Zr1 126.4(2) . . ?
C6 O3 Zr1 121.2(2) . 2 ?
Zr1 O3 Zr1 93.77(10) . 2 ?
C6 O3 Eu1 119.8(2) . . ?
Zr1 O3 Eu1 94.16(9) . . ?
Zr1 O3 Eu1 93.60(9) 2 . ?
C9 O4 Zr1 120.0(4) . . ?
C9 O4 Eu1 137.7(4) . . ?
Zr1 O4 Eu1 101.75(11) . . ?
C12 O5 Zr1 168.7(4) . . ?
C15 O6 Zr1 173.5(4) . . ?
C18 O7 C18 34.6(8) 2 . ?
C18 O7 Zr1 133.6(5) 2 . ?
C18 O7 Zr1 122.9(5) . . ?
C18 O7 Zr1 122.9(5) 2 2 ?
C18 O7 Zr1 133.6(5) . 2 ?
Zr1 O7 Zr1 99.61(16) . 2 ?
F1A C1 F2 85.2(10) . . ?
F1A C1 F3 105.0(11) . . ?
F2 C1 F3 122.1(8) . . ?
F1A C1 F3A 125.9(11) . . ?
F2 C1 F3A 100.6(11) . . ?
F3 C1 F3A 28.9(6) . . ?
F1A C1 F1 20.3(8) . . ?
F2 C1 F1 105.4(8) . . ?
F3 C1 F1 95.5(8) . . ?
F3A C1 F1 122.2(10) . . ?
F1A C1 F2A 109.0(11) . . ?
F2 C1 F2A 25.0(6) . . ?
F3 C1 F2A 107.0(10) . . ?
F3A C1 F2A 80.5(13) . . ?
F1 C1 F2A 129.3(9) . . ?
F1A C1 C2 117.3(9) . . ?
F2 C1 C2 111.5(6) . . ?
F3 C1 C2 112.9(6) . . ?
F3A C1 C2 110.2(8) . . ?
F1 C1 C2 106.6(6) . . ?
F2A C1 C2 105.2(7) . . ?
O2 C2 C3 128.2(5) . . ?
O2 C2 C1 113.3(5) . . ?
C3 C2 C1 118.5(5) . . ?
C2 C3 C4 120.1(5) . . ?
O1 C4 C3 128.5(5) . . ?
O1 C4 C5 114.0(5) . . ?
C3 C4 C5 117.5(5) . . ?
F6A C5 F4 133.6(10) . . ?
F6A C5 F4A 109.0(10) . . ?
F4 C5 F4A 30.5(5) . . ?
F6A C5 F5 75.6(9) . . ?
F4 C5 F5 109.6(7) . . ?
F4A C5 F5 127.5(7) . . ?
F6A C5 F5A 109.9(11) . . ?
F4 C5 F5A 77.5(8) . . ?
F4A C5 F5A 103.8(9) . . ?
F5 C5 F5A 36.3(7) . . ?
F6A C5 F6 29.8(7) . . ?
F4 C5 F6 111.2(8) . . ?
F4A C5 F6 82.2(7) . . ?
F5 C5 F6 102.2(7) . . ?
F5A C5 F6 131.0(9) . . ?
F6A C5 C4 109.4(8) . . ?
F4 C5 C4 109.7(7) . . ?
F4A C5 C4 113.0(6) . . ?
F5 C5 C4 113.9(6) . . ?
F5A C5 C4 111.5(9) . . ?
F6 C5 C4 110.1(6) . . ?
O3 C6 C8 111.4(4) . . ?
O3 C6 C7 110.5(4) . . ?
C8 C6 C7 109.7(4) . . ?
C11 C9 O4 116.4(6) . . ?
C11 C9 C10 118.0(6) . . ?
O4 C9 C10 111.7(5) . . ?
O5 C12 C14 111.0(5) . . ?
O5 C12 C13 109.7(5) . . ?
C14 C12 C13 114.0(7) . . ?
O6 C15 C17 112.8(6) . . ?
O6 C15 C16 110.8(5) . . ?
C17 C15 C16 116.6(6) . . ?
C18 C18 C19 79.0(14) 2 2 ?
C18 C18 O7 72.7(4) 2 . ?
C19 C18 O7 113.8(8) 2 . ?
C18 C18 C19 67.1(13) 2 . ?
C19 C18 C19 113.2(8) 2 . ?
O7 C18 C19 108.5(7) . . ?
C18 C19 C18 33.9(8) 2 . ?
C20 C20 C21 122.4(8) 2 . ?
C22 C21 C20 131(2) . . ?
C22 C21 C23 27.4(15) . . ?
C20 C21 C23 104.6(12) . . ?
C23 C22 C21 118(3) . . ?
C23 C22 C24 70(2) . . ?
C21 C22 C24 165(3) . . ?
C23 C22 C23 10(2) . 2 ?
C21 C22 C23 113(2) . 2 ?
C24 C22 C23 77.0(19) . 2 ?
C23 C23 C22 158(5) 2 . ?
C23 C23 C24 122.0(16) 2 . ?
C22 C23 C24 72(2) . . ?
C23 C23 C22 13(3) 2 2 ?
C22 C23 C22 158(3) . 2 ?
C24 C23 C22 129(2) . 2 ?
C23 C23 C21 131.6(13) 2 . ?
C22 C23 C21 34.3(19) . . ?
C24 C23 C21 105.2(19) . . ?
C22 C23 C21 125.5(17) 2 . ?
C23 C23 C24 39.1(12) 2 2 ?
C22 C23 C24 150(3) . 2 ?
C24 C23 C24 83(3) . 2 ?
C22 C23 C24 47.0(13) 2 2 ?
C21 C23 C24 168.8(18) . 2 ?
C23 C24 C22 37.8(14) . . ?
C23 C24 C23 18.9(12) . 2 ?
C22 C24 C23 56.0(17) . 2 ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O1 2.390(3) 2 ?
Eu1 O1 2.390(3) . ?
Eu1 O4 2.399(3) 2 ?
Eu1 O4 2.399(3) . ?
Eu1 O2 2.400(3) . ?
Eu1 O2 2.400(3) 2 ?
Eu1 O3 2.487(3) 2 ?
Eu1 O3 2.487(3) . ?
Eu1 Zr1 3.4894(5) 2 ?
Eu1 Zr1 3.4894(5) . ?
Zr1 O6 1.921(3) . ?
Zr1 O5 1.926(3) . ?
Zr1 O4 2.092(3) . ?
Zr1 O7 2.183(3) . ?
Zr1 O3 2.273(3) . ?
Zr1 O3 2.296(3) 2 ?
Zr1 Zr1 3.3355(8) 2 ?
O1 C4 1.241(6) . ?
O2 C2 1.243(6) . ?
O3 C6 1.462(5) . ?
O3 Zr1 2.296(3) 2 ?
O4 C9 1.439(6) . ?
O5 C12 1.423(6) . ?
O6 C15 1.423(6) . ?
O7 C18 1.451(9) 2 ?
O7 C18 1.451(9) . ?
O7 Zr1 2.183(3) 2 ?
C1 F1A 1.196(15) . ?
C1 F2 1.313(10) . ?
C1 F3 1.334(9) . ?
C1 F3A 1.377(14) . ?
C1 F1 1.422(13) . ?
C1 F2A 1.424(15) . ?
C1 C2 1.556(8) . ?
C2 C3 1.380(8) . ?
C3 C4 1.396(8) . ?
C4 C5 1.552(8) . ?
C5 F6A 1.262(15) . ?
C5 F4 1.290(11) . ?
C5 F4A 1.303(11) . ?
C5 F5 1.307(9) . ?
C5 F5A 1.371(16) . ?
C5 F6 1.411(12) . ?
C6 C8 1.517(7) . ?
C6 C7 1.519(6) . ?
C9 C11 1.382(10) . ?
C9 C10 1.496(9) . ?
C12 C14 1.486(10) . ?
C12 C13 1.501(9) . ?
C15 C17 1.425(11) . ?
C15 C16 1.490(9) . ?
C18 C18 0.86(2) 2 ?
C18 C19 1.425(13) 2 ?
C18 C19 1.518(13) . ?
C19 C18 1.425(13) 2 ?
C20 C20 1.30(2) 2 ?
C20 C21 1.476(18) . ?
C21 C22 1.04(2) . ?
C21 C23 1.63(2) . ?
C22 C23 0.85(2) . ?
C22 C24 1.32(4) . ?
C22 C23 1.50(3) 2 ?
C23 C23 0.67(4) 2 ?
C23 C24 1.31(3) . ?
C23 C22 1.50(3) 2 ?
C23 C24 1.76(3) 2 ?
C24 C23 1.76(3) 2 ?
