#------------------------------------------------------------------------------
#$Date: 2016-03-25 12:22:40 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179813 $
#$URL: svn://www.crystallography.net/cod/cif/7/01/09/7010925.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7010925
loop_
_publ_author_name
'Wadepohl, Hubert'
'Merkel, Rüdiger'
'Pritzkow, Hans'
'Rihm, Sven'
_publ_section_title
;
 Tetranuclear rhodium clusters with facial cyclooctatetraene ligands
;
_journal_issue                   24
_journal_name_full
'Journal of the Chemical Society, Dalton Transactions'
_journal_page_first              3617
_journal_page_last               3626
_journal_paper_doi               10.1039/b105485f
_journal_year                    2001
_chemical_formula_moiety         'C34 H48 O6 Rh4 Si4'
_chemical_formula_sum            'C34 H48 O6 Rh4 Si4'
_chemical_formula_weight         1076.72
_chemical_name_systematic        ?
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   difmap
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 93.0510(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   12.3544(2)
_cell_length_b                   16.8339(3)
_cell_length_c                   20.2878(3)
_cell_measurement_temperature    173(2)
_cell_volume                     4213.33(12)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.980
_diffrn_measured_fraction_theta_max 0.980
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       omega-scans
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.04
_diffrn_reflns_av_sigmaI/netI    0.0177
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_limit_l_min       0
_diffrn_reflns_number            41388
_diffrn_reflns_theta_full        28.30
_diffrn_reflns_theta_max         28.30
_diffrn_reflns_theta_min         1.57
_exptl_absorpt_coefficient_mu    1.691
_exptl_absorpt_correction_T_max  0.881
_exptl_absorpt_correction_T_min  0.658
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            'dark red'
_exptl_crystal_density_diffrn    1.697
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             2144
_exptl_crystal_size_max          0.40
_exptl_crystal_size_mid          0.23
_exptl_crystal_size_min          0.12
_refine_diff_density_max         0.920
_refine_diff_density_min         -0.491
_refine_diff_density_rms         0.104
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.208
_refine_ls_hydrogen_treatment    refall
_refine_ls_matrix_type           full
_refine_ls_number_parameters     615
_refine_ls_number_reflns         10272
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.208
_refine_ls_R_factor_all          0.0330
_refine_ls_R_factor_gt           0.0278
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0263P)²+5.6718P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0660
_refine_ls_wR_factor_ref         0.0682
_reflns_number_gt                9141
_reflns_number_total             10272
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b105485f.txt
_cod_data_source_block           rued27
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      P2(1)/n
_cod_database_code               7010925
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh1 Rh 0.950258(17) 0.100607(13) 0.303286(11) 0.01908(5) Uani 1 1 d . . .
Rh2 Rh 0.749320(16) 0.153501(13) 0.311603(10) 0.01863(5) Uani 1 1 d . . .
Rh3 Rh 0.910195(17) 0.262738(13) 0.326838(10) 0.01960(5) Uani 1 1 d . . .
Rh4 Rh 0.855993(17) 0.200798(13) 0.203710(10) 0.01999(5) Uani 1 1 d . . .
Si1 Si 0.55293(8) 0.18058(6) 0.13890(5) 0.0344(2) Uani 1 1 d . . .
Si2 Si 0.70672(7) 0.35438(5) 0.44233(4) 0.02684(17) Uani 1 1 d . . .
Si3 Si 1.28287(7) 0.05250(5) 0.43479(4) 0.02804(18) Uani 1 1 d . . .
Si4 Si 1.20336(7) -0.07880(5) 0.20299(4) 0.02527(17) Uani 1 1 d . . .
O1 O 0.6301(2) 0.01345(14) 0.36663(13) 0.0400(6) Uani 1 1 d . . .
O2 O 1.1022(2) 0.3250(2) 0.41079(13) 0.0557(8) Uani 1 1 d . . .
O3 O 0.9402(3) 0.1607(2) 0.06958(15) 0.0672(9) Uani 1 1 d . . .
O4 O 0.88589(19) 0.15484(13) 0.44251(10) 0.0309(5) Uani 1 1 d . . .
O5 O 1.08830(17) 0.23409(12) 0.23635(11) 0.0278(4) Uani 1 1 d . . .
O6 O 0.77643(19) 0.03387(13) 0.20022(11) 0.0315(5) Uani 1 1 d . . .
C1 C 0.6458(2) 0.23580(17) 0.20169(14) 0.0245(6) Uani 1 1 d . . .
C2 C 0.6159(2) 0.22809(17) 0.26870(15) 0.0233(6) Uani 1 1 d . . .
C3 C 0.6500(2) 0.26183(17) 0.33091(14) 0.0234(6) Uani 1 1 d . . .
C4 C 0.7269(2) 0.32082(17) 0.35394(14) 0.0225(6) Uani 1 1 d . . .
C5 C 0.8022(2) 0.36725(17) 0.32069(14) 0.0232(6) Uani 1 1 d . . .
C6 C 0.8433(2) 0.36747(17) 0.25642(15) 0.0232(6) Uani 1 1 d . . .
C7 C 0.8106(2) 0.33424(17) 0.19438(15) 0.0248(6) Uani 1 1 d . . .
C8 C 0.7229(2) 0.28372(18) 0.17160(14) 0.0250(6) Uani 1 1 d . . .
C9 C 0.4531(4) 0.2560(3) 0.1057(3) 0.0777(18) Uani 1 1 d . . .
H9A H 0.4918 0.2998 0.0855 0.119(14) Uiso 1 1 calc R . .
H9B H 0.4114 0.2766 0.1417 0.119(14) Uiso 1 1 calc R . .
H9C H 0.4037 0.2312 0.0723 0.119(14) Uiso 1 1 calc R . .
C10 C 0.4851(5) 0.0961(4) 0.1787(3) 0.0649(15) Uani 1 1 d . . .
C11 C 0.6312(4) 0.1392(3) 0.0712(2) 0.0471(10) Uani 1 1 d . . .
C12 C 0.8325(3) 0.4018(3) 0.47910(19) 0.0431(9) Uani 1 1 d . . .
C13 C 0.5954(4) 0.4290(3) 0.4369(2) 0.0429(9) Uani 1 1 d . . .
C14 C 0.6691(4) 0.2690(3) 0.49473(19) 0.0423(9) Uani 1 1 d . . .
C15 C 1.1484(2) 0.04269(18) 0.38641(15) 0.0255(6) Uani 1 1 d . . .
C16 C 1.1268(2) 0.09115(18) 0.32566(15) 0.0234(6) Uani 1 1 d . . .
C17 C 1.1024(2) 0.05726(17) 0.26312(14) 0.0215(5) Uani 1 1 d . . .
C18 C 1.0953(2) -0.03038(17) 0.25083(14) 0.0243(6) Uani 1 1 d . . .
C19 C 1.0102(2) -0.06881(18) 0.27301(15) 0.0263(6) Uani 1 1 d . . .
C20 C 0.9286(2) -0.02740(17) 0.31219(16) 0.0249(6) Uani 1 1 d . . .
C21 C 0.9552(2) 0.00438(17) 0.37469(16) 0.0265(6) Uani 1 1 d . . .
C22 C 1.0663(3) 0.00019(19) 0.40806(16) 0.0283(6) Uani 1 1 d . . .
C23 C 1.2607(4) 0.1190(3) 0.5065(2) 0.0474(9) Uani 1 1 d . . .
C24 C 1.3847(3) 0.1012(3) 0.3838(2) 0.0380(8) Uani 1 1 d . . .
C25 C 1.3307(4) -0.0468(3) 0.4638(2) 0.0468(10) Uani 1 1 d . . .
C26 C 1.1656(3) -0.1842(2) 0.1859(2) 0.0400(8) Uani 1 1 d . . .
C27 C 1.3342(3) -0.0740(2) 0.2527(2) 0.0360(7) Uani 1 1 d . . .
C28 C 1.2133(3) -0.0220(3) 0.12474(19) 0.0392(8) Uani 1 1 d . . .
C29 C 0.6698(2) 0.06919(18) 0.34717(15) 0.0257(6) Uani 1 1 d . . .
C30 C 1.0273(3) 0.3064(2) 0.37968(15) 0.0302(7) Uani 1 1 d . . .
C31 C 0.9071(3) 0.1783(2) 0.11840(16) 0.0343(7) Uani 1 1 d . . .
C32 C 0.8828(2) 0.16557(17) 0.38521(15) 0.0249(6) Uani 1 1 d . . .
C33 C 1.0018(2) 0.21686(17) 0.25398(14) 0.0234(6) Uani 1 1 d . . .
C34 C 0.8144(2) 0.08763(17) 0.22982(15) 0.0259(6) Uani 1 1 d . . .
H2 H 0.551(3) 0.2014(19) 0.2718(14) 0.015(7) Uiso 1 1 d . . .
H3 H 0.601(3) 0.2480(18) 0.3638(15) 0.017(8) Uiso 1 1 d . . .
H5 H 0.834(3) 0.405(2) 0.3457(16) 0.020(8) Uiso 1 1 d . . .
H6 H 0.895(3) 0.401(2) 0.2524(16) 0.021(8) Uiso 1 1 d . . .
H7 H 0.850(3) 0.354(2) 0.1619(18) 0.030(9) Uiso 1 1 d . . .
H8 H 0.717(3) 0.2835(19) 0.1271(16) 0.019(8) Uiso 1 1 d . . .
H10A H 0.455(4) 0.062(3) 0.148(3) 0.075(16) Uiso 1 1 d . . .
H10B H 0.429(5) 0.115(3) 0.209(3) 0.081(18) Uiso 1 1 d . . .
H10C H 0.531(4) 0.064(3) 0.204(3) 0.069(17) Uiso 1 1 d . . .
H11A H 0.662(5) 0.178(3) 0.049(3) 0.085(19) Uiso 1 1 d . . .
H11B H 0.583(4) 0.115(3) 0.040(2) 0.052(12) Uiso 1 1 d . . .
H11C H 0.686(4) 0.103(3) 0.090(2) 0.069(15) Uiso 1 1 d . . .
H12A H 0.818(3) 0.413(2) 0.522(2) 0.045(11) Uiso 1 1 d . . .
H12B H 0.847(4) 0.451(3) 0.458(2) 0.061(14) Uiso 1 1 d . . .
H12C H 0.888(4) 0.369(3) 0.478(2) 0.053(13) Uiso 1 1 d . . .
H13A H 0.540(4) 0.407(3) 0.423(2) 0.060(16) Uiso 1 1 d . . .
H13B H 0.616(3) 0.470(3) 0.411(2) 0.047(12) Uiso 1 1 d . . .
H13C H 0.578(4) 0.448(3) 0.479(2) 0.061(13) Uiso 1 1 d . . .
H14A H 0.600(4) 0.249(2) 0.481(2) 0.043(11) Uiso 1 1 d . . .
H14B H 0.663(4) 0.282(3) 0.538(2) 0.057(13) Uiso 1 1 d . . .
H14C H 0.715(4) 0.230(3) 0.494(2) 0.067(15) Uiso 1 1 d . . .
H16 H 1.154(3) 0.141(2) 0.3263(17) 0.030(9) Uiso 1 1 d . . .
H17 H 1.117(3) 0.0901(19) 0.2265(16) 0.022(8) Uiso 1 1 d . . .
H19 H 0.999(3) -0.123(2) 0.2659(16) 0.024(8) Uiso 1 1 d . . .
H20 H 0.854(3) -0.0401(19) 0.3023(16) 0.023(8) Uiso 1 1 d . . .
H21 H 0.899(3) 0.009(2) 0.4024(17) 0.030(9) Uiso 1 1 d . . .
H22 H 1.073(3) -0.030(2) 0.4454(17) 0.030(9) Uiso 1 1 d . . .
H23A H 1.238(4) 0.167(3) 0.490(2) 0.056(14) Uiso 1 1 d . . .
H23B H 1.329(4) 0.128(3) 0.530(2) 0.056(13) Uiso 1 1 d . . .
H23C H 1.211(4) 0.096(3) 0.537(3) 0.073(16) Uiso 1 1 d . . .
H24A H 1.449(4) 0.112(3) 0.410(2) 0.047(12) Uiso 1 1 d . . .
H24B H 1.360(4) 0.147(3) 0.366(2) 0.061(14) Uiso 1 1 d . . .
H24C H 1.402(4) 0.072(3) 0.348(3) 0.081(17) Uiso 1 1 d . . .
H25A H 1.389(4) -0.042(3) 0.488(2) 0.055(13) Uiso 1 1 d . . .
H25B H 1.347(4) -0.078(3) 0.428(2) 0.055(13) Uiso 1 1 d . . .
H25C H 1.280(4) -0.076(3) 0.489(3) 0.076(16) Uiso 1 1 d . . .
H26A H 1.164(4) -0.213(3) 0.223(2) 0.060(14) Uiso 1 1 d . . .
H26B H 1.099(4) -0.187(3) 0.164(2) 0.054(13) Uiso 1 1 d . . .
H26C H 1.215(4) -0.208(3) 0.163(2) 0.063(14) Uiso 1 1 d . . .
H27A H 1.329(3) -0.101(3) 0.293(2) 0.048(12) Uiso 1 1 d . . .
H27B H 1.353(4) -0.022(3) 0.266(2) 0.058(13) Uiso 1 1 d . . .
H27C H 1.389(4) -0.094(3) 0.230(2) 0.060(13) Uiso 1 1 d . . .
H28A H 1.231(4) 0.033(3) 0.135(2) 0.062(14) Uiso 1 1 d . . .
H28B H 1.265(4) -0.041(3) 0.099(2) 0.049(12) Uiso 1 1 d . . .
H28C H 1.146(4) -0.023(3) 0.100(2) 0.071(15) Uiso 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C21 Rh1 C20 37.51(12) . . ?
C21 Rh1 C32 82.23(11) . . ?
C20 Rh1 C32 112.17(11) . . ?
C21 Rh1 C34 111.85(11) . . ?
C20 Rh1 C34 82.26(11) . . ?
C32 Rh1 C34 104.87(11) . . ?
C21 Rh1 C16 79.43(11) . . ?
C20 Rh1 C16 92.04(11) . . ?
C32 Rh1 C16 106.94(11) . . ?
C34 Rh1 C16 147.43(11) . . ?
C21 Rh1 C17 90.30(11) . . ?
C20 Rh1 C17 79.32(11) . . ?
C32 Rh1 C17 144.01(11) . . ?
C34 Rh1 C17 110.55(11) . . ?
C16 Rh1 C17 37.16(11) . . ?
C21 Rh1 C33 157.64(11) . . ?
C20 Rh1 C33 156.04(11) . . ?
C32 Rh1 C33 91.75(11) . . ?
C34 Rh1 C33 90.50(11) . . ?
C16 Rh1 C33 81.82(10) . . ?
C17 Rh1 C33 81.97(10) . . ?
C21 Rh1 Rh2 101.62(8) . . ?
C20 Rh1 Rh2 101.97(8) . . ?
C32 Rh1 Rh2 52.32(8) . . ?
C34 Rh1 Rh2 52.56(8) . . ?
C16 Rh1 Rh2 158.20(8) . . ?
C17 Rh1 Rh2 162.03(8) . . ?
C33 Rh1 Rh2 91.36(7) . . ?
C21 Rh1 Rh3 127.45(8) . . ?
C20 Rh1 Rh3 156.86(8) . . ?
C32 Rh1 Rh3 46.44(8) . . ?
C34 Rh1 Rh3 94.39(8) . . ?
C16 Rh1 Rh3 102.43(8) . . ?
C17 Rh1 Rh3 122.83(7) . . ?
C33 Rh1 Rh3 46.06(7) . . ?
Rh2 Rh1 Rh3 59.377(8) . . ?
C21 Rh1 Rh4 156.26(8) . . ?
C20 Rh1 Rh4 126.86(8) . . ?
C32 Rh1 Rh4 94.88(8) . . ?
C34 Rh1 Rh4 45.97(8) . . ?
C16 Rh1 Rh4 123.57(8) . . ?
C17 Rh1 Rh4 105.00(7) . . ?
C33 Rh1 Rh4 45.35(7) . . ?
Rh2 Rh1 Rh4 59.658(8) . . ?
Rh3 Rh1 Rh4 58.363(7) . . ?
C29 Rh2 C32 101.45(12) . . ?
C29 Rh2 C34 97.39(12) . . ?
C32 Rh2 C34 105.83(11) . . ?
C29 Rh2 C2 100.64(12) . . ?
C32 Rh2 C2 137.62(11) . . ?
C34 Rh2 C2 106.61(11) . . ?
C29 Rh2 C3 104.07(12) . . ?
C32 Rh2 C3 101.89(11) . . ?
C34 Rh2 C3 140.53(11) . . ?
C2 Rh2 C3 37.33(11) . . ?
C29 Rh2 Rh1 106.23(9) . . ?
C32 Rh2 Rh1 52.89(8) . . ?
C34 Rh2 Rh1 52.94(8) . . ?
C2 Rh2 Rh1 147.76(8) . . ?
C3 Rh2 Rh1 143.78(8) . . ?
C29 Rh2 Rh3 149.04(9) . . ?
C32 Rh2 Rh3 48.26(8) . . ?
C34 Rh2 Rh3 97.67(8) . . ?
C2 Rh2 Rh3 100.72(8) . . ?
C3 Rh2 Rh3 80.42(8) . . ?
Rh1 Rh2 Rh3 63.395(8) . . ?
C29 Rh2 Rh4 143.78(9) . . ?
C32 Rh2 Rh4 98.19(8) . . ?
C34 Rh2 Rh4 47.68(8) . . ?
C2 Rh2 Rh4 84.29(8) . . ?
C3 Rh2 Rh4 101.22(8) . . ?
Rh1 Rh2 Rh4 63.499(8) . . ?
Rh3 Rh2 Rh4 60.808(8) . . ?
C30 Rh3 C32 97.27(13) . . ?
C30 Rh3 C33 96.83(12) . . ?
C32 Rh3 C33 103.21(11) . . ?
C30 Rh3 C5 99.40(13) . . ?
C32 Rh3 C5 123.25(11) . . ?
C33 Rh3 C5 127.73(11) . . ?
C30 Rh3 C6 106.27(13) . . ?
C32 Rh3 C6 150.28(11) . . ?
C33 Rh3 C6 91.91(11) . . ?
C5 Rh3 C6 35.83(10) . . ?
C30 Rh3 C4 112.79(12) . . ?
C32 Rh3 C4 90.31(10) . . ?
C33 Rh3 C4 145.67(10) . . ?
C5 Rh3 C4 33.55(10) . . ?
C6 Rh3 C4 64.13(10) . . ?
C30 Rh3 Rh2 148.96(10) . . ?
C32 Rh3 Rh2 52.04(9) . . ?
C33 Rh3 Rh2 95.24(8) . . ?
C5 Rh3 Rh2 95.54(8) . . ?
C6 Rh3 Rh2 101.78(7) . . ?
C4 Rh3 Rh2 68.36(7) . . ?
C30 Rh3 Rh4 142.92(9) . . ?
C32 Rh3 Rh4 100.45(8) . . ?
C33 Rh3 Rh4 47.46(8) . . ?
C5 Rh3 Rh4 97.66(8) . . ?
C6 Rh3 Rh4 71.19(7) . . ?
C4 Rh3 Rh4 99.47(6) . . ?
Rh2 Rh3 Rh4 59.949(8) . . ?
C30 Rh3 Rh1 109.55(10) . . ?
C32 Rh3 Rh1 50.49(8) . . ?
C33 Rh3 Rh1 53.63(8) . . ?
C5 Rh3 Rh1 150.80(8) . . ?
C6 Rh3 Rh1 132.18(7) . . ?
C4 Rh3 Rh1 124.95(7) . . ?
Rh2 Rh3 Rh1 57.228(7) . . ?
Rh4 Rh3 Rh1 61.088(8) . . ?
C31 Rh4 C33 98.82(13) . . ?
C31 Rh4 C34 98.60(13) . . ?
C33 Rh4 C34 102.75(12) . . ?
C31 Rh4 C8 97.67(13) . . ?
C33 Rh4 C8 132.95(11) . . ?
C34 Rh4 C8 117.82(12) . . ?
C31 Rh4 C7 101.99(13) . . ?
C33 Rh4 C7 96.64(11) . . ?
C34 Rh4 C7 149.07(11) . . ?
C8 Rh4 C7 36.68(11) . . ?
C31 Rh4 Rh2 149.80(10) . . ?
C33 Rh4 Rh2 95.10(8) . . ?
C34 Rh4 Rh2 51.99(8) . . ?
C8 Rh4 Rh2 92.12(8) . . ?
C7 Rh4 Rh2 102.86(7) . . ?
C31 Rh4 Rh3 145.02(10) . . ?
C33 Rh4 Rh3 48.04(8) . . ?
C34 Rh4 Rh3 99.76(8) . . ?
C8 Rh4 Rh3 99.67(8) . . ?
C7 Rh4 Rh3 75.74(7) . . ?
Rh2 Rh4 Rh3 59.243(8) . . ?
C31 Rh4 Rh1 112.63(11) . . ?
C33 Rh4 Rh1 53.43(8) . . ?
C34 Rh4 Rh1 50.35(9) . . ?
C8 Rh4 Rh1 148.25(8) . . ?
C7 Rh4 Rh1 136.27(8) . . ?
Rh2 Rh4 Rh1 56.844(7) . . ?
Rh3 Rh4 Rh1 60.549(8) . . ?
C10 Si1 C11 107.4(3) . . ?
C10 Si1 C9 111.9(3) . . ?
C11 Si1 C9 110.3(2) . . ?
C10 Si1 C1 110.59(18) . . ?
C11 Si1 C1 110.95(17) . . ?
C9 Si1 C1 105.74(17) . . ?
C13 Si2 C14 110.4(2) . . ?
C13 Si2 C12 109.4(2) . . ?
C14 Si2 C12 109.3(2) . . ?
C13 Si2 C4 106.08(16) . . ?
C14 Si2 C4 110.93(16) . . ?
C12 Si2 C4 110.76(16) . . ?
C25 Si3 C24 111.1(2) . . ?
C25 Si3 C23 110.5(2) . . ?
C24 Si3 C23 107.4(2) . . ?
C25 Si3 C15 109.98(18) . . ?
C24 Si3 C15 110.56(16) . . ?
C23 Si3 C15 107.20(18) . . ?
C27 Si4 C28 110.15(19) . . ?
C27 Si4 C26 110.14(19) . . ?
C28 Si4 C26 110.9(2) . . ?
C27 Si4 C18 108.80(15) . . ?
C28 Si4 C18 107.39(16) . . ?
C26 Si4 C18 109.37(16) . . ?
C8 C1 C2 132.5(3) . . ?
C8 C1 Si1 112.6(2) . . ?
C2 C1 Si1 114.3(2) . . ?
C3 C2 C1 136.4(3) . . ?
C3 C2 Rh2 72.51(16) . . ?
C1 C2 Rh2 101.53(19) . . ?
C3 C2 H2 110.4(19) . . ?
C1 C2 H2 112.2(19) . . ?
Rh2 C2 H2 109.1(19) . . ?
C2 C3 C4 136.2(3) . . ?
C2 C3 Rh2 70.16(16) . . ?
C4 C3 Rh2 105.08(18) . . ?
C2 C3 H3 110.8(19) . . ?
C4 C3 H3 112.0(19) . . ?
Rh2 C3 H3 107.2(19) . . ?
C5 C4 C3 131.9(3) . . ?
C5 C4 Si2 114.0(2) . . ?
C3 C4 Si2 113.2(2) . . ?
C5 C4 Rh3 59.69(15) . . ?
C3 C4 Rh3 104.15(18) . . ?
Si2 C4 Rh3 118.50(13) . . ?
C4 C5 C6 135.6(3) . . ?
C4 C5 Rh3 86.76(17) . . ?
C6 C5 Rh3 79.02(17) . . ?
C4 C5 H5 114(2) . . ?
C6 C5 H5 111(2) . . ?
Rh3 C5 H5 107(2) . . ?
C7 C6 C5 135.5(3) . . ?
C7 C6 Rh3 108.26(19) . . ?
C5 C6 Rh3 65.14(15) . . ?
C7 C6 H6 111(2) . . ?
C5 C6 H6 113(2) . . ?
Rh3 C6 H6 108(2) . . ?
C6 C7 C8 134.1(3) . . ?
C6 C7 Rh4 104.68(19) . . ?
C8 C7 Rh4 68.12(16) . . ?
C6 C7 H7 111(2) . . ?
C8 C7 H7 114(2) . . ?
Rh4 C7 H7 106(2) . . ?
C1 C8 C7 135.6(3) . . ?
C1 C8 Rh4 91.14(18) . . ?
C7 C8 Rh4 75.20(17) . . ?
C1 C8 H8 114(2) . . ?
C7 C8 H8 110(2) . . ?
Rh4 C8 H8 108(2) . . ?
Si1 C9 H9A 109.5 . . ?
Si1 C9 H9B 109.5 . . ?
H9A C9 H9B 109.5 . . ?
Si1 C9 H9C 109.5 . . ?
H9A C9 H9C 109.5 . . ?
H9B C9 H9C 109.5 . . ?
Si1 C10 H10A 111(3) . . ?
Si1 C10 H10B 112(3) . . ?
H10A C10 H10B 111(4) . . ?
Si1 C10 H10C 114(3) . . ?
H10A C10 H10C 103(5) . . ?
H10B C10 H10C 106(4) . . ?
Si1 C11 H11A 111(4) . . ?
Si1 C11 H11B 109(3) . . ?
H11A C11 H11B 105(4) . . ?
Si1 C11 H11C 109(3) . . ?
H11A C11 H11C 111(5) . . ?
H11B C11 H11C 113(4) . . ?
Si2 C12 H12A 106(3) . . ?
Si2 C12 H12B 112(3) . . ?
H12A C12 H12B 107(4) . . ?
Si2 C12 H12C 111(3) . . ?
H12A C12 H12C 110(4) . . ?
H12B C12 H12C 111(4) . . ?
Si2 C13 H13A 109(4) . . ?
Si2 C13 H13B 109(3) . . ?
H13A C13 H13B 113(4) . . ?
Si2 C13 H13C 112(3) . . ?
H13A C13 H13C 104(4) . . ?
H13B C13 H13C 110(4) . . ?
Si2 C14 H14A 111(3) . . ?
Si2 C14 H14B 114(3) . . ?
H14A C14 H14B 104(4) . . ?
Si2 C14 H14C 113(3) . . ?
H14A C14 H14C 108(4) . . ?
H14B C14 H14C 106(4) . . ?
C22 C15 C16 117.4(3) . . ?
C22 C15 Si3 122.6(2) . . ?
C16 C15 Si3 119.7(2) . . ?
C17 C16 C15 122.9(3) . . ?
C17 C16 Rh1 71.51(16) . . ?
C15 C16 Rh1 109.92(19) . . ?
C17 C16 H16 117(2) . . ?
C15 C16 H16 117(2) . . ?
Rh1 C16 H16 107(2) . . ?
C16 C17 C18 123.8(3) . . ?
C16 C17 Rh1 71.34(16) . . ?
C18 C17 Rh1 110.03(18) . . ?
C16 C17 H17 115.4(19) . . ?
C18 C17 H17 117.0(19) . . ?
Rh1 C17 H17 107.1(19) . . ?
C19 C18 C17 117.5(3) . . ?
C19 C18 Si4 124.0(2) . . ?
C17 C18 Si4 118.4(2) . . ?
C18 C19 C20 121.4(3) . . ?
C18 C19 H19 122(2) . . ?
C20 C19 H19 116(2) . . ?
C21 C20 C19 122.0(3) . . ?
C21 C20 Rh1 70.92(17) . . ?
C19 C20 Rh1 109.21(19) . . ?
C21 C20 H20 117.0(19) . . ?
C19 C20 H20 117(2) . . ?
Rh1 C20 H20 109(2) . . ?
C20 C21 C22 123.8(3) . . ?
C20 C21 Rh1 71.56(17) . . ?
C22 C21 Rh1 109.22(19) . . ?
C20 C21 H21 116(2) . . ?
C22 C21 H21 115(2) . . ?
Rh1 C21 H21 110(2) . . ?
C15 C22 C21 121.3(3) . . ?
C15 C22 H22 122(2) . . ?
C21 C22 H22 116(2) . . ?
Si3 C23 H23A 108(3) . . ?
Si3 C23 H23B 108(3) . . ?
H23A C23 H23B 106(4) . . ?
Si3 C23 H23C 112(3) . . ?
H23A C23 H23C 113(4) . . ?
H23B C23 H23C 109(4) . . ?
Si3 C24 H24A 110(3) . . ?
Si3 C24 H24B 112(3) . . ?
H24A C24 H24B 108(4) . . ?
Si3 C24 H24C 113(3) . . ?
H24A C24 H24C 109(4) . . ?
H24B C24 H24C 104(4) . . ?
Si3 C25 H25A 110(3) . . ?
Si3 C25 H25B 109(3) . . ?
H25A C25 H25B 107(4) . . ?
Si3 C25 H25C 115(3) . . ?
H25A C25 H25C 107(4) . . ?
H25B C25 H25C 107(4) . . ?
Si4 C26 H26A 112(3) . . ?
Si4 C26 H26B 110(3) . . ?
H26A C26 H26B 109(4) . . ?
Si4 C26 H26C 111(3) . . ?
H26A C26 H26C 104(4) . . ?
H26B C26 H26C 110(4) . . ?
Si4 C27 H27A 111(3) . . ?
Si4 C27 H27B 113(3) . . ?
H27A C27 H27B 103(4) . . ?
Si4 C27 H27C 111(3) . . ?
H27A C27 H27C 111(4) . . ?
H27B C27 H27C 108(4) . . ?
Si4 C28 H28A 109(3) . . ?
Si4 C28 H28B 114(3) . . ?
H28A C28 H28B 107(4) . . ?
Si4 C28 H28C 111(3) . . ?
H28A C28 H28C 108(4) . . ?
H28B C28 H28C 108(4) . . ?
O1 C29 Rh2 173.0(3) . . ?
O2 C30 Rh3 172.9(3) . . ?
O3 C31 Rh4 175.6(4) . . ?
O4 C32 Rh3 133.9(2) . . ?
O4 C32 Rh2 130.4(2) . . ?
Rh3 C32 Rh2 79.70(10) . . ?
O4 C32 Rh1 132.8(2) . . ?
Rh3 C32 Rh1 83.07(10) . . ?
Rh2 C32 Rh1 74.79(10) . . ?
O5 C33 Rh4 132.1(2) . . ?
O5 C33 Rh3 131.8(2) . . ?
Rh4 C33 Rh3 84.50(11) . . ?
O5 C33 Rh1 128.0(2) . . ?
Rh4 C33 Rh1 81.22(10) . . ?
Rh3 C33 Rh1 80.31(10) . . ?
O6 C34 Rh4 133.2(2) . . ?
O6 C34 Rh2 128.9(2) . . ?
Rh4 C34 Rh2 80.33(10) . . ?
O6 C34 Rh1 134.1(2) . . ?
Rh4 C34 Rh1 83.68(11) . . ?
Rh2 C34 Rh1 74.50(10) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Rh1 C21 2.172(3) . ?
Rh1 C20 2.180(3) . ?
Rh1 C32 2.191(3) . ?
Rh1 C34 2.195(3) . ?
Rh1 C16 2.210(3) . ?
Rh1 C17 2.212(3) . ?
Rh1 C33 2.303(3) . ?
Rh1 Rh2 2.6511(3) . ?
Rh1 Rh3 2.8191(3) . ?
Rh1 Rh4 2.8340(3) . ?
Rh2 C29 1.891(3) . ?
Rh2 C32 2.174(3) . ?
Rh2 C34 2.184(3) . ?
Rh2 C2 2.213(3) . ?
Rh2 C3 2.244(3) . ?
Rh2 Rh3 2.7133(3) . ?
Rh2 Rh4 2.7330(3) . ?
Rh3 C30 1.902(3) . ?
Rh3 C32 2.058(3) . ?
Rh3 C33 2.059(3) . ?
Rh3 C5 2.208(3) . ?
Rh3 C6 2.389(3) . ?
Rh3 C4 2.553(3) . ?
Rh3 Rh4 2.7564(3) . ?
Rh4 C31 1.911(3) . ?
Rh4 C33 2.040(3) . ?
Rh4 C34 2.050(3) . ?
Rh4 C8 2.227(3) . ?
Rh4 C7 2.321(3) . ?
Si1 C10 1.857(5) . ?
Si1 C11 1.857(4) . ?
Si1 C9 1.871(5) . ?
Si1 C1 1.910(3) . ?
Si2 C13 1.861(4) . ?
Si2 C14 1.861(4) . ?
Si2 C12 1.867(4) . ?
Si2 C4 1.909(3) . ?
Si3 C25 1.858(4) . ?
Si3 C24 1.861(4) . ?
Si3 C23 1.868(4) . ?
Si3 C15 1.891(3) . ?
Si4 C27 1.861(4) . ?
Si4 C28 1.863(4) . ?
Si4 C26 1.863(4) . ?
Si4 C18 1.878(3) . ?
O1 C29 1.139(4) . ?
O2 C30 1.136(4) . ?
O3 C31 1.131(4) . ?
O4 C32 1.175(4) . ?
O5 C33 1.181(3) . ?
O6 C34 1.170(4) . ?
C1 C8 1.411(4) . ?
C1 C2 1.434(4) . ?
C2 C3 1.427(4) . ?
C2 H2 0.92(3) . ?
C3 C4 1.435(4) . ?
C3 H3 0.95(3) . ?
C4 C5 1.413(4) . ?
C5 C6 1.425(4) . ?
C5 H5 0.89(3) . ?
C6 C7 1.417(4) . ?
C6 H6 0.86(3) . ?
C7 C8 1.434(4) . ?
C7 H7 0.91(4) . ?
C8 H8 0.90(3) . ?
C9 H9A 0.9800 . ?
C9 H9B 0.9800 . ?
C9 H9C 0.9800 . ?
C10 H10A 0.91(6) . ?
C10 H10B 1.00(6) . ?
C10 H10C 0.93(5) . ?
C11 H11A 0.90(6) . ?
C11 H11B 0.93(5) . ?
C11 H11C 0.97(5) . ?
C12 H12A 0.92(4) . ?
C12 H12B 0.95(5) . ?
C12 H12C 0.87(5) . ?
C13 H13A 0.81(5) . ?
C13 H13B 0.90(5) . ?
C13 H13C 0.95(5) . ?
C14 H14A 0.94(4) . ?
C14 H14B 0.92(5) . ?
C14 H14C 0.87(5) . ?
C15 C22 1.335(4) . ?
C15 C16 1.490(4) . ?
C16 C17 1.409(4) . ?
C16 H16 0.91(4) . ?
C17 C18 1.498(4) . ?
C17 H17 0.95(3) . ?
C18 C19 1.332(4) . ?
C19 C20 1.490(4) . ?
C19 H19 0.93(4) . ?
C20 C21 1.399(5) . ?
C20 H20 0.95(3) . ?
C21 C22 1.499(4) . ?
C21 H21 0.92(4) . ?
C22 H22 0.91(4) . ?
C23 H23A 0.91(5) . ?
C23 H23B 0.96(5) . ?
C23 H23C 0.97(5) . ?
C24 H24A 0.94(4) . ?
C24 H24B 0.89(5) . ?
C24 H24C 0.91(6) . ?
C25 H25A 0.85(5) . ?
C25 H25B 0.92(5) . ?
C25 H25C 0.97(5) . ?
C26 H26A 0.90(5) . ?
C26 H26B 0.91(5) . ?
C26 H26C 0.88(5) . ?
C27 H27A 0.94(4) . ?
C27 H27B 0.93(5) . ?
C27 H27C 0.91(5) . ?
C28 H28A 0.97(5) . ?
C28 H28B 0.91(4) . ?
C28 H28C 0.95(5) . ?
