#------------------------------------------------------------------------------
#$Date: 2016-03-25 12:48:47 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179816 $
#$URL: svn://www.crystallography.net/cod/cif/7/01/12/7011220.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7011220
loop_
_publ_author_name
'Hai-Bin Song'
'Zheng-Zhi Zhang'
'Thomas C. W. Mak'
_publ_section_title
;
 Synthesis and structural study of late transition metal complexes of
 N-[(diphenylphosphino)methyl]-2-pyridinamine and
 N-cyclohexyl-N-[(diphenylphosphino)methyl]-2-pyridinamine
;
_journal_issue                   7
_journal_name_full               'J. Chem. Soc., Dalton Trans.'
_journal_page_first              1336
_journal_page_last               1343
_journal_paper_doi               10.1039/b109191n
_journal_year                    2002
_chemical_formula_sum            'C97 H110 Ag3 Cl5 N8 O12 P4'
_chemical_formula_weight         2204.67
_chemical_name_systematic
; 
? 
;
_space_group_IT_number           5
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  'C 2y'
_symmetry_space_group_name_H-M   'C 1 2 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 110.207(4)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   21.413(3)
_cell_length_b                   9.5311(15)
_cell_length_c                   26.950(5)
_cell_measurement_temperature    293(2)
_cell_volume                     5161.7(15)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.995
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0463
_diffrn_reflns_av_sigmaI/netI    0.1063
_diffrn_reflns_limit_h_max       26
_diffrn_reflns_limit_h_min       -23
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_l_max       33
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            12559
_diffrn_reflns_theta_full        26.00
_diffrn_reflns_theta_max         26.00
_diffrn_reflns_theta_min         1.61
_exptl_absorpt_coefficient_mu    0.815
_exptl_absorpt_correction_T_max  1.000000
_exptl_absorpt_correction_T_min  0.709492
_exptl_absorpt_correction_type   SADABS
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.419
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             2260
_exptl_crystal_size_max          0.38
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.16
_refine_diff_density_max         1.188
_refine_diff_density_min         -0.794
_refine_diff_density_rms         0.122
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.04(5)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.952
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     597
_refine_ls_number_reflns         9356
_refine_ls_number_restraints     3
_refine_ls_restrained_S_all      0.952
_refine_ls_R_factor_all          0.1180
_refine_ls_R_factor_gt           0.0768
_refine_ls_shift/su_max          0.179
_refine_ls_shift/su_mean         0.013
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1157P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1781
_refine_ls_wR_factor_ref         0.2047
_reflns_number_gt                5844
_reflns_number_total             9356
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b109191n.txt
_cod_data_source_block           compd10b
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_cell_volume        5161.7(14)
_cod_original_sg_symbol_H-M      C2
_cod_database_code               7011220
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.55844(4) 0.43333(9) -0.01520(3) 0.0493(2) Uani 1 1 d . . .
Ag2 Ag 0.5000 0.56695(12) 0.5000 0.0546(4) Uani 1 2 d S . .
P1 P 0.61925(12) 0.3349(3) 0.06841(10) 0.0416(6) Uani 1 1 d . . .
P2 P 0.39064(12) 0.6001(3) 0.43736(10) 0.0445(7) Uani 1 1 d . . .
N1 N 0.4848(4) 0.5104(10) 0.0992(4) 0.050(2) Uani 1 1 d . . .
N2 N 0.5081(4) 0.2811(9) 0.0965(3) 0.0407(19) Uani 1 1 d . . .
C1 C 0.6631(5) 0.4585(13) 0.1207(4) 0.051(3) Uani 1 1 d . . .
C2 C 0.7038(5) 0.4177(18) 0.1691(4) 0.066(3) Uani 1 1 d . . .
H2A H 0.7104 0.3219 0.1754 0.079 Uiso 1 1 calc R . .
C3 C 0.7348(7) 0.5049(18) 0.2081(6) 0.078(4) Uani 1 1 d . . .
H3A H 0.7624 0.4716 0.2408 0.094 Uiso 1 1 calc R . .
C4 C 0.7247(7) 0.647(2) 0.1986(8) 0.090(5) Uani 1 1 d . . .
H4A H 0.7462 0.7111 0.2251 0.108 Uiso 1 1 calc R . .
C5 C 0.6839(8) 0.6950(16) 0.1512(7) 0.088(5) Uani 1 1 d . . .
H5A H 0.6774 0.7910 0.1454 0.105 Uiso 1 1 calc R . .
C6 C 0.6517(6) 0.6015(12) 0.1114(5) 0.056(3) Uani 1 1 d . . .
H6A H 0.6229 0.6336 0.0789 0.067 Uiso 1 1 calc R . .
C7 C 0.6847(5) 0.2231(11) 0.0625(4) 0.043(2) Uani 1 1 d . . .
C8 C 0.6845(6) 0.0836(13) 0.0648(5) 0.062(3) Uani 1 1 d . . .
H8A H 0.6500 0.0385 0.0719 0.074 Uiso 1 1 calc R . .
C9 C 0.7370(7) -0.0008(16) 0.0564(6) 0.079(4) Uani 1 1 d . . .
H9A H 0.7360 -0.0983 0.0567 0.095 Uiso 1 1 calc R . .
C10 C 0.7877(7) 0.0716(18) 0.0483(5) 0.075(4) Uani 1 1 d . . .
H10A H 0.8226 0.0217 0.0436 0.090 Uiso 1 1 calc R . .
C11 C 0.7887(6) 0.2112(19) 0.0467(5) 0.077(4) Uani 1 1 d . . .
H11A H 0.8235 0.2563 0.0401 0.092 Uiso 1 1 calc R . .
C12 C 0.7390(6) 0.2902(15) 0.0546(5) 0.064(3) Uani 1 1 d . . .
H12A H 0.7414 0.3876 0.0547 0.077 Uiso 1 1 calc R . .
C13 C 0.5728(5) 0.2146(10) 0.0969(4) 0.040(2) Uani 1 1 d . . .
H13A H 0.5632 0.1282 0.0767 0.048 Uiso 1 1 calc R . .
H13B H 0.6000 0.1917 0.1330 0.048 Uiso 1 1 calc R . .
C14 C 0.5172(5) 0.4010(11) 0.1285(4) 0.043(3) Uani 1 1 d . . .
C15 C 0.5527(5) 0.4113(13) 0.1799(4) 0.053(3) Uani 1 1 d . . .
H15A H 0.5721 0.3321 0.1993 0.064 Uiso 1 1 calc R . .
C16 C 0.5603(6) 0.5421(16) 0.2040(5) 0.067(4) Uani 1 1 d . . .
H16A H 0.5866 0.5516 0.2394 0.081 Uiso 1 1 calc R . .
C17 C 0.5300(7) 0.6540(14) 0.1766(5) 0.068(4) Uani 1 1 d . . .
H17A H 0.5341 0.7425 0.1920 0.081 Uiso 1 1 calc R . .
C18 C 0.4911(6) 0.6314(14) 0.1227(6) 0.064(3) Uani 1 1 d . . .
H18A H 0.4687 0.7077 0.1030 0.077 Uiso 1 1 calc R . .
C19 C 0.4611(5) 0.1689(12) 0.1044(6) 0.059(3) Uani 1 1 d . . .
H19A H 0.4557 0.0990 0.0766 0.071 Uiso 1 1 calc R . .
C20 C 0.4826(6) 0.0919(15) 0.1539(6) 0.073(4) Uani 1 1 d . . .
H20A H 0.4899 0.1574 0.1829 0.087 Uiso 1 1 calc R . .
H20B H 0.5247 0.0463 0.1583 0.087 Uiso 1 1 calc R . .
C21 C 0.4338(7) -0.0154(14) 0.1565(7) 0.081(4) Uani 1 1 d . . .
H21A H 0.4497 -0.0596 0.1911 0.097 Uiso 1 1 calc R . .
H21B H 0.4306 -0.0873 0.1303 0.097 Uiso 1 1 calc R . .
C22 C 0.3660(6) 0.0439(15) 0.1471(5) 0.068(4) Uani 1 1 d . . .
H22A H 0.3351 -0.0315 0.1460 0.081 Uiso 1 1 calc R . .
H22B H 0.3674 0.1063 0.1759 0.081 Uiso 1 1 calc R . .
C23 C 0.3430(6) 0.1216(14) 0.0969(7) 0.077(4) Uani 1 1 d . . .
H23A H 0.3007 0.1658 0.0928 0.093 Uiso 1 1 calc R . .
H23B H 0.3356 0.0558 0.0679 0.093 Uiso 1 1 calc R . .
C24 C 0.3925(5) 0.2348(13) 0.0932(5) 0.058(3) Uani 1 1 d . . .
H24A H 0.3771 0.2760 0.0581 0.070 Uiso 1 1 calc R . .
H24B H 0.3952 0.3086 0.1186 0.070 Uiso 1 1 calc R . .
N3 N 0.5015(5) 0.3622(10) 0.4340(4) 0.063(3) Uani 1 1 d . . .
N4 N 0.4363(4) 0.4852(9) 0.3608(3) 0.045(2) Uani 1 1 d . . .
C25 C 0.3630(6) 0.7715(15) 0.4090(4) 0.056(3) Uani 1 1 d . . .
C26 C 0.4066(7) 0.8828(13) 0.4222(5) 0.065(3) Uani 1 1 d . . .
H26A H 0.4503 0.8690 0.4445 0.078 Uiso 1 1 calc R . .
C27 C 0.3856(10) 1.0150(17) 0.4023(6) 0.093(5) Uani 1 1 d . . .
H27A H 0.4150 1.0899 0.4131 0.111 Uiso 1 1 calc R . .
C28 C 0.3235(12) 1.0386(18) 0.3677(7) 0.104(6) Uani 1 1 d . . .
H28A H 0.3113 1.1262 0.3522 0.124 Uiso 1 1 calc R . .
C29 C 0.2785(8) 0.927(2) 0.3560(5) 0.088(5) Uani 1 1 d . . .
H29A H 0.2346 0.9426 0.3345 0.105 Uiso 1 1 calc R . .
C30 C 0.2981(6) 0.7947(13) 0.3761(4) 0.052(3) Uani 1 1 d . . .
H30A H 0.2678 0.7210 0.3674 0.062 Uiso 1 1 calc R . .
C31 C 0.3256(5) 0.5442(11) 0.4618(4) 0.044(2) Uani 1 1 d . . .
C32 C 0.3310(6) 0.5764(15) 0.5127(4) 0.062(3) Uani 1 1 d . . .
H32A H 0.3677 0.6264 0.5340 0.075 Uiso 1 1 calc R . .
C33 C 0.2814(10) 0.5344(19) 0.5328(7) 0.100(6) Uani 1 1 d . . .
H33A H 0.2854 0.5580 0.5673 0.120 Uiso 1 1 calc R . .
C34 C 0.2295(8) 0.4621(18) 0.5033(7) 0.088(5) Uani 1 1 d . . .
H34A H 0.1975 0.4333 0.5173 0.105 Uiso 1 1 calc R . .
C35 C 0.2227(6) 0.431(2) 0.4547(6) 0.087(4) Uani 1 1 d . . .
H35A H 0.1854 0.3811 0.4339 0.104 Uiso 1 1 calc R . .
C36 C 0.2710(6) 0.4708(14) 0.4338(5) 0.070(4) Uani 1 1 d . . .
H36A H 0.2653 0.4461 0.3991 0.083 Uiso 1 1 calc R . .
C37 C 0.3823(5) 0.4808(12) 0.3823(4) 0.049(3) Uani 1 1 d . . .
H37A H 0.3788 0.3857 0.3939 0.059 Uiso 1 1 calc R . .
H37B H 0.3409 0.5022 0.3540 0.059 Uiso 1 1 calc R . .
C38 C 0.4927(6) 0.4025(11) 0.3857(4) 0.054(3) Uani 1 1 d . . .
C39 C 0.5375(7) 0.3661(17) 0.3616(7) 0.089(5) Uani 1 1 d . . .
H39A H 0.5311 0.3974 0.3275 0.107 Uiso 1 1 calc R . .
C40 C 0.5901(9) 0.2861(19) 0.3867(7) 0.102(6) Uani 1 1 d . . .
H40A H 0.6182 0.2555 0.3692 0.122 Uiso 1 1 calc R . .
C41 C 0.6025(8) 0.249(2) 0.4393(9) 0.108(6) Uani 1 1 d . . .
H41A H 0.6407 0.2008 0.4594 0.130 Uiso 1 1 calc R . .
C42 C 0.5561(7) 0.2861(15) 0.4584(6) 0.087(5) Uani 1 1 d . . .
H42A H 0.5620 0.2565 0.4926 0.104 Uiso 1 1 calc R . .
C43 C 0.4198(5) 0.5288(12) 0.3056(4) 0.051(3) Uani 1 1 d . . .
H43A H 0.4622 0.5411 0.2999 0.061 Uiso 1 1 calc R . .
C44 C 0.3817(6) 0.4198(16) 0.2666(4) 0.072(4) Uani 1 1 d . . .
H44A H 0.3391 0.4041 0.2708 0.087 Uiso 1 1 calc R . .
H44B H 0.4062 0.3321 0.2739 0.087 Uiso 1 1 calc R . .
C45 C 0.3703(7) 0.4645(17) 0.2093(5) 0.078(4) Uani 1 1 d . . .
H45A H 0.4126 0.4682 0.2037 0.094 Uiso 1 1 calc R . .
H45B H 0.3426 0.3954 0.1852 0.094 Uiso 1 1 calc R . .
C46 C 0.3384(9) 0.601(2) 0.1981(5) 0.108(6) Uani 1 1 d . . .
H46A H 0.2938 0.5934 0.1994 0.129 Uiso 1 1 calc R . .
H46B H 0.3345 0.6289 0.1626 0.129 Uiso 1 1 calc R . .
C47 C 0.3753(8) 0.7089(17) 0.2357(5) 0.082(4) Uani 1 1 d . . .
H47A H 0.3512 0.7970 0.2274 0.098 Uiso 1 1 calc R . .
H47B H 0.4185 0.7227 0.2322 0.098 Uiso 1 1 calc R . .
C48 C 0.3848(7) 0.6665(13) 0.2933(4) 0.061(3) Uani 1 1 d . . .
H48A H 0.4107 0.7375 0.3175 0.074 Uiso 1 1 calc R . .
H48B H 0.3418 0.6596 0.2977 0.074 Uiso 1 1 calc R . .
Cl1 Cl 0.3320(2) 0.0291(5) 0.74022(15) 0.0891(12) Uani 1 1 d . . .
O1 O 0.2765(6) -0.0327(17) 0.7070(5) 0.137(5) Uani 1 1 d . . .
O2 O 0.3833(7) -0.060(2) 0.7534(8) 0.205(8) Uani 1 1 d . . .
O3 O 0.3480(11) 0.142(2) 0.7178(10) 0.241(12) Uani 1 1 d . . .
O4 O 0.3275(11) 0.055(3) 0.7871(7) 0.263(15) Uani 1 1 d . . .
Cl2 Cl 0.0000 0.3313(6) 0.0000 0.118(2) Uani 1 2 d S . .
O5 O -0.0490(9) 0.2417(14) 0.0109(5) 0.188(9) Uani 1 1 d . . .
O6 O 0.0306(10) 0.3914(18) 0.0475(9) 0.244(11) Uani 1 1 d . . .
C49 C 0.5581(14) 0.962(2) 0.3381(15) 0.20(3) Uani 0.50 1 d PD . .
H49A H 0.5818 0.9642 0.3132 0.245 Uiso 0.50 1 calc PR . .
H49B H 0.5808 1.0233 0.3676 0.245 Uiso 0.50 1 calc PR . .
Cl3 Cl 0.4757(12) 1.0154(17) 0.3075(7) 0.228(9) Uani 0.50 1 d PD . .
Cl4 Cl 0.5534(8) 0.792(2) 0.3598(9) 0.296(15) Uani 0.50 1 d PD . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Ag1 P1 169.7(2) 2_655 . ?
N1 Ag1 N2 54.6(3) 2_655 2_655 ?
P1 Ag1 N2 122.68(19) . 2_655 ?
N1 Ag1 Ag1 100.9(2) 2_655 2_655 ?
P1 Ag1 Ag1 88.60(7) . 2_655 ?
N2 Ag1 Ag1 87.87(17) 2_655 2_655 ?
P2 Ag2 P2 164.81(15) . 2_656 ?
C7 P1 C1 103.9(5) . . ?
C7 P1 C13 102.4(5) . . ?
C1 P1 C13 106.6(5) . . ?
C7 P1 Ag1 109.7(4) . . ?
C1 P1 Ag1 116.4(4) . . ?
C13 P1 Ag1 116.3(3) . . ?
C31 P2 C25 103.8(5) . . ?
C31 P2 C37 103.9(5) . . ?
C25 P2 C37 107.0(5) . . ?
C31 P2 Ag2 113.1(3) . . ?
C25 P2 Ag2 120.9(4) . . ?
C37 P2 Ag2 106.8(4) . . ?
C18 N1 C14 117.1(10) . . ?
C18 N1 Ag1 135.8(9) . 2_655 ?
C14 N1 Ag1 106.7(7) . 2_655 ?
C14 N2 C13 113.6(7) . . ?
C14 N2 C19 116.1(8) . . ?
C13 N2 C19 110.4(8) . . ?
C14 N2 Ag1 89.1(6) . 2_655 ?
C13 N2 Ag1 118.2(6) . 2_655 ?
C19 N2 Ag1 108.2(6) . 2_655 ?
C2 C1 C6 118.0(12) . . ?
C2 C1 P1 123.1(11) . . ?
C6 C1 P1 118.7(8) . . ?
C3 C2 C1 124.4(16) . . ?
C2 C3 C4 117.7(16) . . ?
C5 C4 C3 120.8(15) . . ?
C4 C5 C6 120.2(15) . . ?
C5 C6 C1 118.8(13) . . ?
C8 C7 C12 118.5(10) . . ?
C8 C7 P1 124.7(9) . . ?
C12 C7 P1 116.8(8) . . ?
C7 C8 C9 121.8(12) . . ?
C10 C9 C8 116.3(13) . . ?
C11 C10 C9 122.1(12) . . ?
C10 C11 C12 121.3(14) . . ?
C11 C12 C7 119.9(13) . . ?
N2 C13 P1 111.0(6) . . ?
C15 C14 N1 123.1(10) . . ?
C15 C14 N2 127.4(10) . . ?
N1 C14 N2 109.5(8) . . ?
C14 C15 C16 118.9(11) . . ?
C17 C16 C15 120.3(11) . . ?
C16 C17 C18 116.5(12) . . ?
N1 C18 C17 124.0(13) . . ?
C20 C19 C24 111.6(10) . . ?
C20 C19 N2 117.8(10) . . ?
C24 C19 N2 108.6(9) . . ?
C19 C20 C21 112.8(12) . . ?
C20 C21 C22 113.0(11) . . ?
C23 C22 C21 110.1(10) . . ?
C22 C23 C24 113.1(12) . . ?
C19 C24 C23 109.6(10) . . ?
C38 N3 C42 116.6(13) . . ?
C38 N4 C37 117.6(9) . . ?
C38 N4 C43 120.6(9) . . ?
C37 N4 C43 117.6(8) . . ?
C26 C25 C30 118.9(13) . . ?
C26 C25 P2 119.5(10) . . ?
C30 C25 P2 121.5(10) . . ?
C25 C26 C27 120.1(14) . . ?
C28 C27 C26 122.0(15) . . ?
C27 C28 C29 117.8(14) . . ?
C30 C29 C28 120.9(14) . . ?
C29 C30 C25 120.0(13) . . ?
C36 C31 C32 115.7(11) . . ?
C36 C31 P2 125.1(9) . . ?
C32 C31 P2 119.2(9) . . ?
C31 C32 C33 120.6(13) . . ?
C34 C33 C32 120.5(14) . . ?
C35 C34 C33 120.4(14) . . ?
C34 C35 C36 120.3(14) . . ?
C31 C36 C35 122.5(13) . . ?
N4 C37 P2 115.7(7) . . ?
N3 C38 C39 120.9(12) . . ?
N3 C38 N4 116.4(10) . . ?
C39 C38 N4 122.7(11) . . ?
C40 C39 C38 120.5(17) . . ?
C39 C40 C41 119.5(17) . . ?
C42 C41 C40 115.1(16) . . ?
C41 C42 N3 127.2(17) . . ?
N4 C43 C48 113.6(9) . . ?
N4 C43 C44 113.4(10) . . ?
C48 C43 C44 110.2(10) . . ?
C43 C44 C45 111.8(12) . . ?
C46 C45 C44 110.9(12) . . ?
C45 C46 C47 112.5(12) . . ?
C46 C47 C48 111.1(13) . . ?
C43 C48 C47 109.5(10) . . ?
O3 Cl1 O4 113.1(18) . . ?
O3 Cl1 O2 108.6(16) . . ?
O4 Cl1 O2 101.0(15) . . ?
O3 Cl1 O1 110.8(11) . . ?
O4 Cl1 O1 112.3(12) . . ?
O2 Cl1 O1 110.6(11) . . ?
O6 Cl2 O6 130(2) 2 . ?
O6 Cl2 O5 101.9(9) 2 2 ?
O6 Cl2 O5 107.0(10) . 2 ?
O6 Cl2 O5 107.0(10) 2 . ?
O6 Cl2 O5 101.9(9) . . ?
O5 Cl2 O5 108.4(16) 2 . ?
Cl4 C49 Cl3 105.2(17) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 N1 2.252(9) 2_655 ?
Ag1 P1 2.372(3) . ?
Ag1 N2 2.603(8) 2_655 ?
Ag1 Ag1 2.8898(15) 2_655 ?
Ag2 P2 2.388(2) . ?
Ag2 P2 2.388(2) 2_656 ?
P1 C7 1.810(10) . ?
P1 C1 1.828(12) . ?
P1 C13 1.850(10) . ?
P2 C31 1.814(11) . ?
P2 C25 1.814(14) . ?
P2 C37 1.829(11) . ?
N1 C18 1.300(14) . ?
N1 C14 1.347(13) . ?
N1 Ag1 2.252(9) 2_655 ?
N2 C14 1.405(13) . ?
N2 C13 1.520(12) . ?
N2 C19 1.533(14) . ?
N2 Ag1 2.603(8) 2_655 ?
C1 C2 1.351(15) . ?
C1 C6 1.393(16) . ?
C2 C3 1.325(17) . ?
C3 C4 1.39(2) . ?
C4 C5 1.35(2) . ?
C5 C6 1.382(18) . ?
C7 C8 1.331(16) . ?
C7 C12 1.407(16) . ?
C8 C9 1.462(17) . ?
C9 C10 1.37(2) . ?
C10 C11 1.33(2) . ?
C11 C12 1.378(17) . ?
C14 C15 1.332(14) . ?
C15 C16 1.389(17) . ?
C16 C17 1.331(18) . ?
C17 C18 1.419(18) . ?
C19 C20 1.451(17) . ?
C19 C24 1.529(14) . ?
C20 C21 1.482(17) . ?
C21 C22 1.496(17) . ?
C22 C23 1.471(18) . ?
C23 C24 1.540(16) . ?
N3 C38 1.308(14) . ?
N3 C42 1.340(16) . ?
N4 C38 1.404(13) . ?
N4 C37 1.461(13) . ?
N4 C43 1.467(13) . ?
C25 C26 1.375(18) . ?
C25 C30 1.384(16) . ?
C26 C27 1.382(19) . ?
C27 C28 1.35(2) . ?
C28 C29 1.39(2) . ?
C29 C30 1.38(2) . ?
C31 C36 1.349(16) . ?
C31 C32 1.370(14) . ?
C32 C33 1.408(19) . ?
C33 C34 1.32(2) . ?
C34 C35 1.30(2) . ?
C35 C36 1.392(17) . ?
C38 C39 1.377(17) . ?
C39 C40 1.33(2) . ?
C40 C41 1.40(2) . ?
C41 C42 1.31(2) . ?
C43 C48 1.491(16) . ?
C43 C44 1.502(17) . ?
C44 C45 1.537(17) . ?
C45 C46 1.45(2) . ?
C46 C47 1.47(2) . ?
C47 C48 1.549(17) . ?
Cl1 O3 1.336(18) . ?
Cl1 O4 1.324(16) . ?
Cl1 O2 1.338(18) . ?
Cl1 O1 1.351(12) . ?
Cl2 O6 1.347(18) 2 ?
Cl2 O6 1.347(18) . ?
Cl2 O5 1.459(14) 2 ?
Cl2 O5 1.459(14) . ?
C49 Cl4 1.738(10) . ?
C49 Cl3 1.745(10) . ?
