#------------------------------------------------------------------------------
#$Date: 2016-03-25 12:48:47 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179816 $
#$URL: svn://www.crystallography.net/cod/cif/7/01/12/7011243.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7011243
loop_
_publ_author_name
'Elena V. Grachova'
'Peter Jutzi'
'Beate Neumann'
'Lars O. Schebaum'
'Hans-Georg Stammler'
'Sergey P. Tunik'
_publ_section_title
;
 Unusual selective substitution of triply bridging carbonyl ligands for
 GaCp* in Rh6(CO)16. Synthesis and structural characterization of the
 Rh6(μ3-CO)4 −x(μ3-GaCp*)x(CO)12 clusters, x = 1--4
;
_journal_issue                   3
_journal_name_full               'J. Chem. Soc., Dalton Trans.'
_journal_page_first              302
_journal_page_last               304
_journal_paper_doi               10.1039/b109327d
_journal_year                    2002
_chemical_formula_moiety         'C34 H30 Ga2 O14 Rh6'
_chemical_formula_sum            'C34 H30 Ga2 O14 Rh6'
_chemical_formula_weight         1419.48
_chemical_name_systematic
; 
?
;
_space_group_IT_number           11
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yb'
_symmetry_space_group_name_H-M   'P 1 21/m 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 114.1911(13)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   11.3400(3)
_cell_length_b                   15.2260(5)
_cell_length_c                   12.6640(5)
_cell_measurement_reflns_used    6032
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      30.034
_cell_measurement_theta_min      2.037
_cell_volume                     1994.58(12)
_computing_cell_refinement       'HKL Scalepack (Otwinowski & Minor 1997)'
_computing_data_collection       KappaCCD
_computing_data_reduction
'Denzo and Scalepak (Otwinowski & Minor, 1997)'
_computing_molecular_graphics    'SHELXTL-PLUS (1990)'
_computing_publication_material  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  KappaCCD
_diffrn_measurement_method       'CCD; rotation images; thick slices'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.080
_diffrn_reflns_av_sigmaI/netI    0.0488
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            36192
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         2.21
_exptl_absorpt_coefficient_mu    3.811
_exptl_absorpt_correction_T_max  0.9277
_exptl_absorpt_correction_T_min  0.4492
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            green
_exptl_crystal_density_diffrn    2.364
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       needle
_exptl_crystal_F_000             1356
_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.12
_exptl_crystal_size_min          0.02
_refine_diff_density_max         0.994
_refine_diff_density_min         -0.986
_refine_diff_density_rms         0.140
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.004
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     275
_refine_ls_number_reflns         3646
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.004
_refine_ls_R_factor_all          0.0577
_refine_ls_R_factor_gt           0.0319
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0318P)²+1.7970P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0653
_refine_ls_wR_factor_ref         0.0727
_reflns_number_gt                2627
_reflns_number_total             3646
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b109327d.txt
_cod_data_source_block           compound2
_cod_depositor_comments
;
The following automatic conversions were performed:
'_atom_site_symetry_multiplicity' tag replaced with
'_atom_site_symmetry_multiplicity'.

Automatic conversion script
Id: cif_correct_tags 1440 2010-10-19 06:21:57Z saulius 

The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      'P 21/m'
_cod_database_code               7011243
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z'
'-x, -y, -z'
'x, -y-1/2, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh1 Rh -0.13434(6) 0.2500 -0.89072(5) 0.01472(15) Uani 1 2 d S . .
Rh2 Rh -0.37024(4) 0.34329(3) -0.96596(4) 0.01467(12) Uani 1 1 d . . .
Rh3 Rh -0.20581(4) 0.34291(3) -0.73415(4) 0.01458(12) Uani 1 1 d . . .
Rh4 Rh -0.43458(6) 0.2500 -0.81031(5) 0.01531(15) Uani 1 2 d S . .
Ga1 Ga -0.30001(8) 0.2500 -1.10188(7) 0.0192(2) Uani 1 2 d S . .
Ga2 Ga -0.00013(9) 0.2500 -0.67234(8) 0.0238(2) Uani 1 2 d S . .
O1 O 0.0134(4) 0.4001(3) -0.9370(4) 0.0346(11) Uani 1 1 d . . .
O2 O -0.2680(4) 0.5153(2) -1.0172(3) 0.0261(10) Uani 1 1 d . . .
O3 O -0.6457(4) 0.3642(2) -1.1474(3) 0.0297(10) Uani 1 1 d . . .
O4 O -0.0711(4) 0.5136(2) -0.7417(3) 0.0312(10) Uani 1 1 d . . .
O5 O -0.1823(4) 0.3634(3) -0.4877(4) 0.0394(11) Uani 1 1 d . . .
O6 O -0.7245(6) 0.2500 -0.9548(5) 0.0360(16) Uani 1 2 d S . .
O7 O -0.4545(6) 0.2500 -0.5784(5) 0.0368(16) Uani 1 2 d S . .
O8 O -0.4534(3) 0.4532(2) -0.8038(3) 0.0227(9) Uani 1 1 d . . .
C1 C -0.0400(5) 0.3431(4) -0.9194(5) 0.0229(13) Uani 1 1 d . . .
C2 C -0.3072(5) 0.4502(4) -1.0011(5) 0.0201(13) Uani 1 1 d . . .
C3 C -0.5413(6) 0.3575(3) -1.0808(5) 0.0181(12) Uani 1 1 d . . .
C4 C -0.1198(5) 0.4487(4) -0.7375(5) 0.0209(13) Uani 1 1 d . . .
C5 C -0.1886(5) 0.3558(3) -0.5784(5) 0.0211(13) Uani 1 1 d . . .
C6 C -0.6160(9) 0.2500 -0.9015(7) 0.026(2) Uani 1 2 d S . .
C7 C -0.4483(8) 0.2500 -0.6638(8) 0.0232(19) Uani 1 2 d S . .
C8 C -0.4019(5) 0.3902(4) -0.8195(5) 0.0212(13) Uani 1 1 d . . .
C9 C -0.1731(8) 0.2500 -1.2121(7) 0.028(2) Uani 1 2 d S . .
C10 C -0.2553(6) 0.3251(4) -1.2411(5) 0.0285(15) Uani 1 1 d . . .
C11 C -0.3850(6) 0.2968(4) -1.2876(5) 0.0258(14) Uani 1 1 d . . .
C12 C -0.0286(9) 0.2500 -1.1650(9) 0.053(3) Uani 1 2 d S . .
H12A H -0.0015 0.2500 -1.2292 0.080 Uiso 1 2 calc SR . .
H12B H 0.0051 0.1974 -1.1174 0.080 Uiso 0.50 1 calc PR . .
H12C H 0.0051 0.3026 -1.1174 0.080 Uiso 0.50 1 calc PR . .
C13 C -0.2127(7) 0.4194(4) -1.2345(6) 0.0445(19) Uani 1 1 d . . .
H13A H -0.1319 0.4277 -1.1656 0.067 Uiso 1 1 calc R . .
H13B H -0.2797 0.4578 -1.2297 0.067 Uiso 1 1 calc R . .
H13C H -0.1988 0.4341 -1.3039 0.067 Uiso 1 1 calc R . .
C14 C -0.5042(7) 0.3543(4) -1.3416(5) 0.0449(19) Uani 1 1 d . . .
H14A H -0.5145 0.3726 -1.4190 0.067 Uiso 1 1 calc R . .
H14B H -0.4945 0.4063 -1.2931 0.067 Uiso 1 1 calc R . .
H14C H -0.5807 0.3210 -1.3474 0.067 Uiso 1 1 calc R . .
C15 C 0.2095(5) 0.2972(3) -0.6108(5) 0.0238(14) Uani 1 1 d . . .
C16 C 0.1676(5) 0.3261(3) -0.5249(5) 0.0263(14) Uani 1 1 d . . .
C17 C 0.1439(7) 0.2500 -0.4707(7) 0.026(2) Uani 1 2 d S . .
C18 C 0.2536(6) 0.3549(4) -0.6836(6) 0.0337(16) Uani 1 1 d . . .
H18A H 0.3430 0.3734 -0.6383 0.051 Uiso 1 1 calc R . .
H18B H 0.1977 0.4068 -0.7083 0.051 Uiso 1 1 calc R . .
H18C H 0.2488 0.3223 -0.7520 0.051 Uiso 1 1 calc R . .
C19 C 0.1613(6) 0.4190(4) -0.4895(5) 0.0355(16) Uani 1 1 d . . .
H19A H 0.0835 0.4272 -0.4749 0.053 Uiso 1 1 calc R . .
H19B H 0.1582 0.4587 -0.5515 0.053 Uiso 1 1 calc R . .
H19C H 0.2381 0.4322 -0.4188 0.053 Uiso 1 1 calc R . .
C20 C 0.1052(8) 0.2500 -0.3711(8) 0.035(2) Uani 1 2 d S . .
H20A H 0.1829 0.2500 -0.2982 0.052 Uiso 1 2 calc SR . .
H20B H 0.0538 0.1974 -0.3749 0.052 Uiso 0.50 1 calc PR . .
H20C H 0.0538 0.3026 -0.3749 0.052 Uiso 0.50 1 calc PR . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ga Ga 0.2307 1.6083 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 Rh1 C1 96.6(3) . 4_565 ?
C1 Rh1 Ga2 94.29(17) . . ?
C1 Rh1 Ga2 94.29(17) 4_565 . ?
C1 Rh1 Ga1 91.72(17) . . ?
C1 Rh1 Ga1 91.72(17) 4_565 . ?
Ga2 Rh1 Ga1 170.96(4) . . ?
C1 Rh1 Rh3 96.17(16) . . ?
C1 Rh1 Rh3 149.15(17) 4_565 . ?
Ga2 Rh1 Rh3 56.78(2) . . ?
Ga1 Rh1 Rh3 115.85(3) . . ?
C1 Rh1 Rh3 149.15(17) . 4_565 ?
C1 Rh1 Rh3 96.17(16) 4_565 4_565 ?
Ga2 Rh1 Rh3 56.78(2) . 4_565 ?
Ga1 Rh1 Rh3 115.85(3) . 4_565 ?
Rh3 Rh1 Rh3 60.41(2) . 4_565 ?
C1 Rh1 Rh2 147.17(17) . 4_565 ?
C1 Rh1 Rh2 95.18(16) 4_565 4_565 ?
Ga2 Rh1 Rh2 115.27(3) . 4_565 ?
Ga1 Rh1 Rh2 57.34(2) . 4_565 ?
Rh3 Rh1 Rh2 89.09(2) . 4_565 ?
Rh3 Rh1 Rh2 58.571(16) 4_565 4_565 ?
C1 Rh1 Rh2 95.18(16) . . ?
C1 Rh1 Rh2 147.17(17) 4_565 . ?
Ga2 Rh1 Rh2 115.27(3) . . ?
Ga1 Rh1 Rh2 57.34(2) . . ?
Rh3 Rh1 Rh2 58.570(16) . . ?
Rh3 Rh1 Rh2 89.09(2) 4_565 . ?
Rh2 Rh1 Rh2 60.32(2) 4_565 . ?
C3 Rh2 C2 95.0(2) . . ?
C3 Rh2 C8 98.2(2) . . ?
C2 Rh2 C8 97.4(2) . . ?
C3 Rh2 Ga1 92.82(16) . . ?
C2 Rh2 Ga1 93.79(16) . . ?
C8 Rh2 Ga1 163.47(15) . . ?
C3 Rh2 Rh3 147.93(16) . . ?
C2 Rh2 Rh3 95.49(16) . . ?
C8 Rh2 Rh3 50.34(15) . . ?
Ga1 Rh2 Rh3 116.57(2) . . ?
C3 Rh2 Rh4 96.85(16) . . ?
C2 Rh2 Rh4 147.38(16) . . ?
C8 Rh2 Rh4 50.85(14) . . ?
Ga1 Rh2 Rh4 115.772(19) . . ?
Rh3 Rh2 Rh4 59.999(17) . . ?
C3 Rh2 Rh1 147.46(16) . . ?
C2 Rh2 Rh1 96.55(16) . . ?
C8 Rh2 Rh1 110.21(15) . . ?
Ga1 Rh2 Rh1 56.19(2) . . ?
Rh3 Rh2 Rh1 60.439(17) . . ?
Rh4 Rh2 Rh1 89.501(19) . . ?
C3 Rh2 Rh2 96.52(15) . 4_565 ?
C2 Rh2 Rh2 148.81(16) . 4_565 ?
C8 Rh2 Rh2 109.41(15) . 4_565 ?
Ga1 Rh2 Rh2 56.825(14) . 4_565 ?
Rh3 Rh2 Rh2 89.881(11) . 4_565 ?
Rh4 Rh2 Rh2 59.019(11) . 4_565 ?
Rh1 Rh2 Rh2 59.840(10) . 4_565 ?
C4 Rh3 C5 95.8(2) . . ?
C4 Rh3 C8 98.0(2) . . ?
C5 Rh3 C8 97.5(2) . . ?
C4 Rh3 Ga2 93.65(17) . . ?
C5 Rh3 Ga2 92.65(17) . . ?
C8 Rh3 Ga2 163.64(15) . . ?
C4 Rh3 Rh2 95.97(16) . . ?
C5 Rh3 Rh2 146.82(17) . . ?
C8 Rh3 Rh2 50.07(15) . . ?
Ga2 Rh3 Rh2 117.40(3) . . ?
C4 Rh3 Rh4 147.99(16) . . ?
C5 Rh3 Rh4 95.59(16) . . ?
C8 Rh3 Rh4 50.81(14) . . ?
Ga2 Rh3 Rh4 115.58(2) . . ?
Rh2 Rh3 Rh4 60.016(17) . . ?
C4 Rh3 Rh1 96.43(16) . . ?
C5 Rh3 Rh1 147.40(16) . . ?
C8 Rh3 Rh1 110.49(15) . . ?
Ga2 Rh3 Rh1 56.50(2) . . ?
Rh2 Rh3 Rh1 60.991(17) . . ?
Rh4 Rh3 Rh1 89.825(19) . . ?
C4 Rh3 Rh3 148.33(17) . 4_565 ?
C5 Rh3 Rh3 95.90(15) . 4_565 ?
C8 Rh3 Rh3 109.49(14) . 4_565 ?
Ga2 Rh3 Rh3 56.467(14) . 4_565 ?
Rh2 Rh3 Rh3 90.120(11) . 4_565 ?
Rh4 Rh3 Rh3 59.151(11) . 4_565 ?
Rh1 Rh3 Rh3 59.795(10) . 4_565 ?
C6 Rh4 C7 95.2(3) . . ?
C6 Rh4 C8 97.65(15) . . ?
C7 Rh4 C8 97.72(15) . . ?
C6 Rh4 C8 97.65(15) . 4_565 ?
C7 Rh4 C8 97.72(15) . 4_565 ?
C8 Rh4 C8 157.1(3) . 4_565 ?
C6 Rh4 Rh3 147.18(8) . . ?
C7 Rh4 Rh3 95.7(2) . . ?
C8 Rh4 Rh3 50.19(14) . . ?
C8 Rh4 Rh3 111.41(14) 4_565 . ?
C6 Rh4 Rh3 147.18(8) . 4_565 ?
C7 Rh4 Rh3 95.7(2) . 4_565 ?
C8 Rh4 Rh3 111.41(14) . 4_565 ?
C8 Rh4 Rh3 50.19(14) 4_565 4_565 ?
Rh3 Rh4 Rh3 61.70(2) . 4_565 ?
C6 Rh4 Rh2 95.9(2) . . ?
C7 Rh4 Rh2 146.95(8) . . ?
C8 Rh4 Rh2 49.96(15) . . ?
C8 Rh4 Rh2 111.45(15) 4_565 . ?
Rh3 Rh4 Rh2 59.985(16) . . ?
Rh3 Rh4 Rh2 91.59(2) 4_565 . ?
C6 Rh4 Rh2 95.9(2) . 4_565 ?
C7 Rh4 Rh2 146.95(8) . 4_565 ?
C8 Rh4 Rh2 111.45(15) . 4_565 ?
C8 Rh4 Rh2 49.96(15) 4_565 4_565 ?
Rh3 Rh4 Rh2 91.59(2) . 4_565 ?
Rh3 Rh4 Rh2 59.986(16) 4_565 4_565 ?
Rh2 Rh4 Rh2 61.96(2) . 4_565 ?
C11 Ga1 C11 36.7(3) 4_565 . ?
C11 Ga1 C10 59.89(19) 4_565 . ?
C11 Ga1 C10 35.8(2) . . ?
C11 Ga1 C10 35.8(2) 4_565 4_565 ?
C11 Ga1 C10 59.89(19) . 4_565 ?
C10 Ga1 C10 58.9(3) . 4_565 ?
C11 Ga1 C9 59.5(2) 4_565 . ?
C11 Ga1 C9 59.5(2) . . ?
C10 Ga1 C9 35.22(18) . . ?
C10 Ga1 C9 35.23(18) 4_565 . ?
C11 Ga1 Rh1 154.64(15) 4_565 . ?
C11 Ga1 Rh1 154.64(15) . . ?
C10 Ga1 Rh1 119.81(15) . . ?
C10 Ga1 Rh1 119.81(15) 4_565 . ?
C9 Ga1 Rh1 104.6(2) . . ?
C11 Ga1 Rh2 113.68(14) 4_565 4_565 ?
C11 Ga1 Rh2 138.29(16) . 4_565 ?
C10 Ga1 Rh2 173.44(15) . 4_565 ?
C10 Ga1 Rh2 117.08(14) 4_565 4_565 ?
C9 Ga1 Rh2 144.33(7) . 4_565 ?
Rh1 Ga1 Rh2 66.48(2) . 4_565 ?
C11 Ga1 Rh2 138.29(16) 4_565 . ?
C11 Ga1 Rh2 113.68(14) . . ?
C10 Ga1 Rh2 117.08(14) . . ?
C10 Ga1 Rh2 173.44(15) 4_565 . ?
C9 Ga1 Rh2 144.33(7) . . ?
Rh1 Ga1 Rh2 66.48(2) . . ?
Rh2 Ga1 Rh2 66.35(3) 4_565 . ?
C15 Ga2 C15 36.6(3) 4_565 . ?
C15 Ga2 C16 35.67(19) 4_565 4_565 ?
C15 Ga2 C16 59.77(19) . 4_565 ?
C15 Ga2 C16 59.77(19) 4_565 . ?
C15 Ga2 C16 35.67(19) . . ?
C16 Ga2 C16 59.0(3) 4_565 . ?
C15 Ga2 C17 58.7(2) 4_565 . ?
C15 Ga2 C17 58.7(2) . . ?
C16 Ga2 C17 34.90(17) 4_565 . ?
C16 Ga2 C17 34.90(17) . . ?
C15 Ga2 Rh1 116.29(15) 4_565 . ?
C15 Ga2 Rh1 116.29(15) . . ?
C16 Ga2 Rh1 142.11(15) 4_565 . ?
C16 Ga2 Rh1 142.11(15) . . ?
C17 Ga2 Rh1 174.60(19) . . ?
C15 Ga2 Rh3 128.18(13) 4_565 4_565 ?
C15 Ga2 Rh3 164.74(13) . 4_565 ?
C16 Ga2 Rh3 108.01(13) 4_565 4_565 ?
C16 Ga2 Rh3 148.57(16) . 4_565 ?
C17 Ga2 Rh3 117.55(15) . 4_565 ?
Rh1 Ga2 Rh3 66.72(3) . 4_565 ?
C15 Ga2 Rh3 164.74(13) 4_565 . ?
C15 Ga2 Rh3 128.18(13) . . ?
C16 Ga2 Rh3 148.57(16) 4_565 . ?
C16 Ga2 Rh3 108.02(13) . . ?
C17 Ga2 Rh3 117.55(15) . . ?
Rh1 Ga2 Rh3 66.72(3) . . ?
Rh3 Ga2 Rh3 67.07(3) 4_565 . ?
O1 C1 Rh1 178.0(5) . . ?
O2 C2 Rh2 176.9(5) . . ?
O3 C3 Rh2 177.5(5) . . ?
O4 C4 Rh3 178.0(5) . . ?
O5 C5 Rh3 178.0(5) . . ?
O6 C6 Rh4 179.3(7) . . ?
O7 C7 Rh4 179.1(8) . . ?
O8 C8 Rh2 133.1(4) . . ?
O8 C8 Rh3 131.7(4) . . ?
Rh2 C8 Rh3 79.60(19) . . ?
O8 C8 Rh4 132.9(4) . . ?
Rh2 C8 Rh4 79.20(19) . . ?
Rh3 C8 Rh4 79.00(19) . . ?
C10 C9 C10 106.8(7) . 4_565 ?
C10 C9 C12 126.6(4) . . ?
C10 C9 C12 126.6(4) 4_565 . ?
C10 C9 Ga1 70.3(4) . . ?
C10 C9 Ga1 70.3(4) 4_565 . ?
C12 C9 Ga1 126.3(6) . . ?
C11 C10 C9 108.8(5) . . ?
C11 C10 C13 124.8(6) . . ?
C9 C10 C13 126.1(6) . . ?
C11 C10 Ga1 69.6(3) . . ?
C9 C10 Ga1 74.5(4) . . ?
C13 C10 Ga1 126.2(4) . . ?
C10 C11 C11 107.8(3) . 4_565 ?
C10 C11 C14 126.6(6) . . ?
C11 C11 C14 125.2(4) 4_565 . ?
C10 C11 Ga1 74.6(3) . . ?
C11 C11 Ga1 71.63(14) 4_565 . ?
C14 C11 Ga1 124.8(4) . . ?
C16 C15 C15 108.0(3) . 4_565 ?
C16 C15 C18 126.1(5) . . ?
C15 C15 C18 125.9(3) 4_565 . ?
C16 C15 Ga2 74.4(3) . . ?
C15 C15 Ga2 71.72(13) 4_565 . ?
C18 C15 Ga2 122.3(4) . . ?
C15 C16 C17 107.7(5) . . ?
C15 C16 C19 126.4(5) . . ?
C17 C16 C19 125.7(6) . . ?
C15 C16 Ga2 69.9(3) . . ?
C17 C16 Ga2 74.4(4) . . ?
C19 C16 Ga2 125.6(4) . . ?
C16 C17 C16 108.6(7) . 4_565 ?
C16 C17 C20 125.7(4) . . ?
C16 C17 C20 125.7(4) 4_565 . ?
C16 C17 Ga2 70.7(4) . . ?
C16 C17 Ga2 70.7(4) 4_565 . ?
C20 C17 Ga2 126.1(5) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Rh1 C1 1.898(6) . ?
Rh1 C1 1.898(6) 4_565 ?
Rh1 Ga2 2.5524(11) . ?
Rh1 Ga1 2.5618(10) . ?
Rh1 Rh3 2.8119(7) . ?
Rh1 Rh3 2.8119(7) 4_565 ?
Rh1 Rh2 2.8271(6) 4_565 ?
Rh1 Rh2 2.8271(6) . ?
Rh2 C3 1.901(6) . ?
Rh2 C2 1.902(6) . ?
Rh2 C8 2.150(6) . ?
Rh2 Ga1 2.5958(8) . ?
Rh2 Rh3 2.7584(6) . ?
Rh2 Rh4 2.7592(7) . ?
Rh2 Rh2 2.8407(8) 4_565 ?
Rh3 C4 1.893(6) . ?
Rh3 C5 1.910(6) . ?
Rh3 C8 2.159(5) . ?
Rh3 Ga2 2.5608(8) . ?
Rh3 Rh4 2.7588(7) . ?
Rh3 Rh3 2.8293(8) 4_565 ?
Rh4 C6 1.902(9) . ?
Rh4 C7 1.924(9) . ?
Rh4 C8 2.178(5) . ?
Rh4 C8 2.178(5) 4_565 ?
Rh4 Rh3 2.7588(7) 4_565 ?
Rh4 Rh2 2.7593(7) 4_565 ?
Ga1 C11 2.261(5) 4_565 ?
Ga1 C11 2.261(5) . ?
Ga1 C10 2.326(6) . ?
Ga1 C10 2.326(6) 4_565 ?
Ga1 C9 2.380(8) . ?
Ga1 Rh2 2.5957(8) 4_565 ?
Ga2 C15 2.293(5) 4_565 ?
Ga2 C15 2.293(5) . ?
Ga2 C16 2.353(6) 4_565 ?
Ga2 C16 2.353(6) . ?
Ga2 C17 2.402(8) . ?
Ga2 Rh3 2.5608(9) 4_565 ?
O1 C1 1.131(6) . ?
O2 C2 1.139(6) . ?
O3 C3 1.142(6) . ?
O4 C4 1.144(6) . ?
O5 C5 1.127(6) . ?
O6 C6 1.135(9) . ?
O7 C7 1.113(9) . ?
O8 C8 1.181(6) . ?
C9 C10 1.425(8) . ?
C9 C10 1.425(8) 4_565 ?
C9 C12 1.497(12) . ?
C10 C11 1.409(8) . ?
C10 C13 1.507(8) . ?
C11 C11 1.425(11) 4_565 ?
C11 C14 1.518(8) . ?
C15 C16 1.424(8) . ?
C15 C15 1.439(10) 4_565 ?
C15 C18 1.500(8) . ?
C16 C17 1.427(7) . ?
C16 C19 1.495(7) . ?
C17 C16 1.427(7) 4_565 ?
C17 C20 1.496(11) . ?
