#------------------------------------------------------------------------------
#$Date: 2016-03-25 12:50:54 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179818 $
#$URL: svn://www.crystallography.net/cod/cif/7/01/14/7011454.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7011454
loop_
_publ_author_name
'Koshevoy, Igor O.'
'Tunik, Sergey P.'
'Jääskeläinen, Sirpa'
'Haukka, Matti'
'Pakkanen, Tapani A.'
'Podkorytov, Ivan S.'
_publ_section_title
;
 Synthesis and structural characterization of mixed-metal Pt--Rh
 clusters. Assembly of tetra- and tetra-hexanuclear clusters from
 smaller metal fragments
;
_journal_issue                   13
_journal_name_full
'Journal of the Chemical Society, Dalton Transactions'
_journal_page_first              2768
_journal_paper_doi               10.1039/b200003b
_journal_year                    2002
_chemical_formula_sum            'C56 H44 O6 P4 Pt2 Rh2'
_chemical_formula_weight         1532.79
_chemical_name_systematic
; 
? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     heavy
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                104.370(2)
_cell_angle_beta                 92.9790(10)
_cell_angle_gamma                95.5950(10)
_cell_formula_units_Z            2
_cell_length_a                   11.8198(4)
_cell_length_b                   12.5681(5)
_cell_length_c                   18.0603(7)
_cell_measurement_temperature    150(2)
_cell_volume                     2578.50(17)
_computing_cell_refinement       'Denzo/Scalepack (Otwinowski & Minor, 1997)'
_computing_data_collection       'Collect (Nonius, 1999)'
_computing_data_reduction        'Denzo/Scalepack (Otwinowski & Minor, 1997)'
_computing_molecular_graphics    'XP in SHELXTL v.5.1 (Bruker Axs, 1998)'
_computing_publication_material  SHELXL-97
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'DIRDIF99 (Beurskens et al., 1999)'
_diffrn_ambient_temperature      150(2)
_diffrn_detector_area_resol_mean 9
_diffrn_measured_fraction_theta_full 0.889
_diffrn_measured_fraction_theta_max 0.889
_diffrn_measurement_device       '95mm CCD camera on κ-goniostat'
_diffrn_measurement_device_type  KappaCCD
_diffrn_measurement_method       CCD
_diffrn_radiation_monochromator  'horizonally mounted graphite crystal'
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0341
_diffrn_reflns_av_sigmaI/netI    0.0449
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            30924
_diffrn_reflns_theta_full        27.43
_diffrn_reflns_theta_max         27.43
_diffrn_reflns_theta_min         2.80
_exptl_absorpt_coefficient_mu    6.212
_exptl_absorpt_correction_T_max  0.39367
_exptl_absorpt_correction_T_min  0.28856
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Xprep in Shelxtl v. 5.1 (Bruker AXS, 1998)'
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.974
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1468
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.20
_refine_diff_density_max         1.650
_refine_diff_density_min         -1.647
_refine_diff_density_rms         0.153
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.128
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     631
_refine_ls_number_reflns         10456
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.128
_refine_ls_R_factor_all          0.0437
_refine_ls_R_factor_gt           0.0342
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0220P)²+8.0583P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0742
_refine_ls_wR_factor_ref         0.0783
_reflns_number_gt                9011
_reflns_number_total             10456
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b200003b.txt
_cod_data_source_block           structure1a
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_cell_volume        2578.49(17)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7011454
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.481972(18) 0.420129(17) 0.278028(12) 0.02417(6) Uani 1 1 d . . .
Pt2 Pt 0.237287(17) 0.363191(15) 0.239856(10) 0.01752(6) Uani 1 1 d . . .
Rh1 Rh 0.36465(3) 0.23218(3) 0.29491(2) 0.01850(9) Uani 1 1 d . . .
Rh2 Rh 0.38763(3) 0.26448(3) 0.15251(2) 0.01890(9) Uani 1 1 d . . .
P1 P 0.21789(12) 0.20204(11) 0.36854(7) 0.0214(3) Uani 1 1 d . . .
P2 P 0.13041(12) 0.41032(11) 0.34061(7) 0.0210(3) Uani 1 1 d . . .
P3 P 0.18566(12) 0.46554(11) 0.15813(7) 0.0192(3) Uani 1 1 d . . .
P4 P 0.26436(12) 0.26959(11) 0.05258(7) 0.0187(3) Uani 1 1 d . . .
C1 C 0.5844(6) 0.5480(5) 0.3194(4) 0.0426(16) Uani 1 1 d . . .
O1 O 0.6476(5) 0.6228(5) 0.3434(4) 0.0733(18) Uani 1 1 d . . .
C2 C 0.4527(5) 0.3668(5) 0.3764(3) 0.0303(13) Uani 1 1 d . . .
O2 O 0.4776(4) 0.3930(4) 0.4410(2) 0.0431(11) Uani 1 1 d . . .
C3 C 0.4772(5) 0.4159(5) 0.1612(3) 0.0293(13) Uani 1 1 d . . .
O3 O 0.5097(4) 0.4719(4) 0.1228(3) 0.0406(11) Uani 1 1 d . . .
C4 C 0.3079(5) 0.1295(4) 0.1860(3) 0.0226(11) Uani 1 1 d . . .
O4 O 0.2664(4) 0.0408(3) 0.1579(2) 0.0296(9) Uani 1 1 d . . .
C5 C 0.4999(5) 0.1856(5) 0.0966(4) 0.0352(14) Uani 1 1 d . . .
O5 O 0.5668(5) 0.1405(5) 0.0617(3) 0.0589(14) Uani 1 1 d . . .
C6 C 0.4682(5) 0.1336(4) 0.3136(3) 0.0264(12) Uani 1 1 d . . .
O6 O 0.5324(4) 0.0754(4) 0.3237(3) 0.0489(12) Uani 1 1 d . . .
C7 C 0.1585(5) 0.3312(4) 0.4123(3) 0.0242(11) Uani 1 1 d . . .
H7A H 0.2129 0.3771 0.4542 0.029 Uiso 1 1 calc R . .
H7B H 0.0865 0.3135 0.4347 0.029 Uiso 1 1 calc R . .
C8 C 0.0976(5) 0.0996(4) 0.3229(3) 0.0239(12) Uani 1 1 d . . .
C9 C -0.0159(5) 0.1188(5) 0.3221(3) 0.0296(13) Uani 1 1 d . . .
H9 H -0.0359 0.1900 0.3459 0.036 Uiso 1 1 calc R . .
C10 C -0.1005(6) 0.0338(6) 0.2864(4) 0.0380(15) Uani 1 1 d . . .
H10 H -0.1780 0.0478 0.2851 0.046 Uiso 1 1 calc R . .
C11 C -0.0728(6) -0.0705(6) 0.2529(3) 0.0387(16) Uani 1 1 d . . .
H11 H -0.1307 -0.1281 0.2282 0.046 Uiso 1 1 calc R . .
C12 C 0.0391(6) -0.0901(5) 0.2555(3) 0.0390(15) Uani 1 1 d . . .
H12 H 0.0582 -0.1623 0.2334 0.047 Uiso 1 1 calc R . .
C13 C 0.1258(6) -0.0062(5) 0.2901(3) 0.0341(14) Uani 1 1 d . . .
H13 H 0.2031 -0.0209 0.2913 0.041 Uiso 1 1 calc R . .
C14 C 0.2473(5) 0.1530(5) 0.4549(3) 0.0274(12) Uani 1 1 d . . .
C15 C 0.1597(6) 0.1202(6) 0.4934(3) 0.0389(15) Uani 1 1 d . . .
H15 H 0.0835 0.1230 0.4753 0.047 Uiso 1 1 calc R . .
C16 C 0.1796(6) 0.0822(6) 0.5595(4) 0.0457(17) Uani 1 1 d . . .
H16 H 0.1174 0.0584 0.5850 0.055 Uiso 1 1 calc R . .
C17 C 0.2896(6) 0.0800(5) 0.5866(3) 0.0397(16) Uani 1 1 d . . .
H17 H 0.3042 0.0558 0.6316 0.048 Uiso 1 1 calc R . .
C18 C 0.3787(7) 0.1129(6) 0.5485(4) 0.0468(18) Uani 1 1 d . . .
H18 H 0.4548 0.1103 0.5671 0.056 Uiso 1 1 calc R . .
C19 C 0.3591(6) 0.1503(5) 0.4828(3) 0.0360(14) Uani 1 1 d . . .
H19 H 0.4214 0.1738 0.4572 0.043 Uiso 1 1 calc R . .
C20 C -0.0245(5) 0.3832(5) 0.3227(3) 0.0256(12) Uani 1 1 d . . .
C21 C -0.0691(5) 0.3259(4) 0.2496(3) 0.0249(12) Uani 1 1 d . . .
H21 H -0.0195 0.3110 0.2095 0.030 Uiso 1 1 calc R . .
C22 C -0.1836(5) 0.2900(5) 0.2339(4) 0.0320(13) Uani 1 1 d . . .
H22 H -0.2130 0.2502 0.1837 0.038 Uiso 1 1 calc R . .
C23 C -0.2555(5) 0.3131(6) 0.2929(4) 0.0391(15) Uani 1 1 d . . .
H23 H -0.3346 0.2884 0.2829 0.047 Uiso 1 1 calc R . .
C24 C -0.2137(6) 0.3711(6) 0.3655(4) 0.0435(17) Uani 1 1 d . . .
H24 H -0.2640 0.3873 0.4051 0.052 Uiso 1 1 calc R . .
C25 C -0.0986(5) 0.4060(5) 0.3810(3) 0.0342(14) Uani 1 1 d . . .
H25 H -0.0697 0.4455 0.4314 0.041 Uiso 1 1 calc R . .
C26 C 0.1588(5) 0.5542(5) 0.3961(3) 0.0271(12) Uani 1 1 d . . .
C27 C 0.2674(6) 0.5939(5) 0.4324(3) 0.0369(15) Uani 1 1 d . . .
H27 H 0.3216 0.5430 0.4331 0.044 Uiso 1 1 calc R . .
C28 C 0.2985(7) 0.7040(5) 0.4671(4) 0.0439(17) Uani 1 1 d . . .
H28 H 0.3724 0.7286 0.4922 0.053 Uiso 1 1 calc R . .
C29 C 0.2198(8) 0.7789(6) 0.4648(4) 0.058(2) Uani 1 1 d . . .
H29 H 0.2402 0.8553 0.4882 0.070 Uiso 1 1 calc R . .
C30 C 0.1121(7) 0.7425(6) 0.4287(4) 0.0522(19) Uani 1 1 d . . .
H30 H 0.0592 0.7941 0.4267 0.063 Uiso 1 1 calc R . .
C31 C 0.0809(6) 0.6309(5) 0.3952(4) 0.0388(15) Uani 1 1 d . . .
H31 H 0.0061 0.6064 0.3715 0.047 Uiso 1 1 calc R . .
C32 C 0.2299(5) 0.4117(4) 0.0603(3) 0.0212(11) Uani 1 1 d . . .
H32A H 0.1673 0.4117 0.0216 0.025 Uiso 1 1 calc R . .
H32B H 0.2975 0.4587 0.0514 0.025 Uiso 1 1 calc R . .
C33 C 0.0360(5) 0.4889(4) 0.1454(3) 0.0229(11) Uani 1 1 d . . .
C34 C -0.0427(5) 0.4175(5) 0.0905(3) 0.0280(12) Uani 1 1 d . . .
H34 H -0.0176 0.3605 0.0520 0.034 Uiso 1 1 calc R . .
C35 C -0.1573(5) 0.4305(5) 0.0928(3) 0.0337(14) Uani 1 1 d . . .
H35 H -0.2107 0.3814 0.0557 0.040 Uiso 1 1 calc R . .
C36 C -0.1957(5) 0.5133(5) 0.1477(4) 0.0374(15) Uani 1 1 d . . .
H36 H -0.2750 0.5199 0.1492 0.045 Uiso 1 1 calc R . .
C37 C -0.1184(5) 0.5862(5) 0.2004(4) 0.0372(15) Uani 1 1 d . . .
H37 H -0.1441 0.6446 0.2377 0.045 Uiso 1 1 calc R . .
C38 C -0.0036(5) 0.5747(5) 0.1993(3) 0.0307(13) Uani 1 1 d . . .
H38 H 0.0492 0.6259 0.2355 0.037 Uiso 1 1 calc R . .
C40 C 0.2537(5) 0.6072(4) 0.1833(3) 0.0235(11) Uani 1 1 d . . .
C41 C 0.2468(5) 0.6724(5) 0.1308(3) 0.0329(14) Uani 1 1 d . . .
H41 H 0.2088 0.6410 0.0814 0.039 Uiso 1 1 calc R . .
C42 C 0.2935(5) 0.7799(5) 0.1493(4) 0.0369(15) Uani 1 1 d . . .
H42 H 0.2896 0.8222 0.1125 0.044 Uiso 1 1 calc R . .
C43 C 0.3469(5) 0.8278(5) 0.2221(4) 0.0370(15) Uani 1 1 d . . .
H43 H 0.3779 0.9034 0.2358 0.044 Uiso 1 1 calc R . .
C44 C 0.3544(5) 0.7644(5) 0.2741(4) 0.0372(15) Uani 1 1 d . . .
H44 H 0.3903 0.7971 0.3240 0.045 Uiso 1 1 calc R . .
C45 C 0.3107(5) 0.6541(5) 0.2549(3) 0.0294(13) Uani 1 1 d . . .
H45 H 0.3197 0.6106 0.2905 0.035 Uiso 1 1 calc R . .
C46 C 0.1207(5) 0.1956(4) 0.0356(3) 0.0207(11) Uani 1 1 d . . .
C47 C 0.0644(5) 0.1617(4) 0.0930(3) 0.0226(11) Uani 1 1 d . . .
H47 H 0.1039 0.1700 0.1416 0.027 Uiso 1 1 calc R . .
C48 C -0.0488(5) 0.1160(4) 0.0801(3) 0.0279(12) Uani 1 1 d . . .
H48 H -0.0862 0.0927 0.1196 0.033 Uiso 1 1 calc R . .
C49 C -0.1071(5) 0.1044(5) 0.0095(3) 0.0303(13) Uani 1 1 d . . .
H49 H -0.1849 0.0740 0.0010 0.036 Uiso 1 1 calc R . .
C50 C -0.0523(5) 0.1369(5) -0.0492(3) 0.0288(13) Uani 1 1 d . . .
H50 H -0.0923 0.1281 -0.0977 0.035 Uiso 1 1 calc R . .
C51 C 0.0602(5) 0.1819(4) -0.0362(3) 0.0256(12) Uani 1 1 d . . .
H51 H 0.0976 0.2040 -0.0761 0.031 Uiso 1 1 calc R . .
C52 C 0.3169(4) 0.2260(4) -0.0424(3) 0.0216(11) Uani 1 1 d . . .
C53 C 0.3215(5) 0.1134(5) -0.0723(3) 0.0327(14) Uani 1 1 d . . .
H53 H 0.3008 0.0631 -0.0425 0.039 Uiso 1 1 calc R . .
C54 C 0.3563(5) 0.0737(5) -0.1459(3) 0.0325(13) Uani 1 1 d . . .
H54 H 0.3583 -0.0033 -0.1665 0.039 Uiso 1 1 calc R . .
C55 C 0.3877(5) 0.1475(5) -0.1884(3) 0.0328(14) Uani 1 1 d . . .
H55 H 0.4087 0.1212 -0.2392 0.039 Uiso 1 1 calc R . .
C56 C 0.3885(6) 0.2584(5) -0.1573(4) 0.0406(16) Uani 1 1 d . . .
H56 H 0.4133 0.3089 -0.1861 0.049 Uiso 1 1 calc R . .
C57 C 0.3538(5) 0.2982(5) -0.0846(3) 0.0300(13) Uani 1 1 d . . .
H57 H 0.3555 0.3756 -0.0637 0.036 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 Pt1 C2 100.6(3) . . ?
C1 Pt1 C3 100.7(3) . . ?
C2 Pt1 C3 158.5(2) . . ?
C1 Pt1 Rh2 148.3(2) . . ?
C2 Pt1 Rh2 109.94(16) . . ?
C3 Pt1 Rh2 48.58(16) . . ?
C1 Pt1 Rh1 149.6(2) . . ?
C2 Pt1 Rh1 49.60(16) . . ?
C3 Pt1 Rh1 108.93(16) . . ?
Rh2 Pt1 Rh1 60.372(12) . . ?
C1 Pt1 Pt2 137.9(2) . . ?
C2 Pt1 Pt2 85.30(16) . . ?
C3 Pt1 Pt2 81.20(16) . . ?
Rh2 Pt1 Pt2 55.734(10) . . ?
Rh1 Pt1 Pt2 56.411(10) . . ?
P2 Pt2 P3 105.32(5) . . ?
P2 Pt2 Rh2 159.78(4) . . ?
P3 Pt2 Rh2 94.90(4) . . ?
P2 Pt2 Rh1 97.99(4) . . ?
P3 Pt2 Rh1 156.17(4) . . ?
Rh2 Pt2 Rh1 61.870(13) . . ?
P2 Pt2 Pt1 114.26(4) . . ?
P3 Pt2 Pt1 106.56(4) . . ?
Rh2 Pt2 Pt1 58.104(11) . . ?
Rh1 Pt2 Pt1 57.962(10) . . ?
C6 Rh1 C2 92.9(2) . . ?
C6 Rh1 C4 92.5(2) . . ?
C2 Rh1 C4 158.1(2) . . ?
C6 Rh1 P1 103.00(18) . . ?
C2 Rh1 P1 96.28(17) . . ?
C4 Rh1 P1 103.13(15) . . ?
C6 Rh1 Pt2 167.90(17) . . ?
C2 Rh1 Pt2 91.83(16) . . ?
C4 Rh1 Pt2 79.13(14) . . ?
P1 Rh1 Pt2 87.52(4) . . ?
C6 Rh1 Pt1 109.78(17) . . ?
C2 Rh1 Pt1 49.30(16) . . ?
C4 Rh1 Pt1 109.06(14) . . ?
P1 Rh1 Pt1 132.19(4) . . ?
Pt2 Rh1 Pt1 65.627(11) . . ?
C6 Rh1 Rh2 109.42(17) . . ?
C2 Rh1 Rh2 108.95(17) . . ?
C4 Rh1 Rh2 49.40(14) . . ?
P1 Rh1 Rh2 137.18(4) . . ?
Pt2 Rh1 Rh2 58.485(12) . . ?
Pt1 Rh1 Rh2 59.684(12) . . ?
C5 Rh2 C3 93.2(3) . . ?
C5 Rh2 C4 96.0(2) . . ?
C3 Rh2 C4 159.6(2) . . ?
C5 Rh2 P4 99.28(19) . . ?
C3 Rh2 P4 95.86(17) . . ?
C4 Rh2 P4 100.56(15) . . ?
C5 Rh2 Pt2 174.48(18) . . ?
C3 Rh2 Pt2 89.34(16) . . ?
C4 Rh2 Pt2 80.03(15) . . ?
P4 Rh2 Pt2 85.29(4) . . ?
C5 Rh2 Pt1 112.0(2) . . ?
C3 Rh2 Pt1 50.00(16) . . ?
C4 Rh2 Pt1 109.56(14) . . ?
P4 Rh2 Pt1 133.01(4) . . ?
Pt2 Rh2 Pt1 66.162(11) . . ?
C5 Rh2 Rh1 114.85(18) . . ?
C3 Rh2 Rh1 109.92(16) . . ?
C4 Rh2 Rh1 49.64(14) . . ?
P4 Rh2 Rh1 134.92(4) . . ?
Pt2 Rh2 Rh1 59.645(12) . . ?
Pt1 Rh2 Rh1 59.943(12) . . ?
C8 P1 C7 107.1(3) . . ?
C8 P1 C14 99.0(2) . . ?
C7 P1 C14 99.8(2) . . ?
C8 P1 Rh1 117.75(17) . . ?
C7 P1 Rh1 111.61(18) . . ?
C14 P1 Rh1 119.4(2) . . ?
C20 P2 C26 105.5(3) . . ?
C20 P2 C7 101.9(2) . . ?
C26 P2 C7 103.5(2) . . ?
C20 P2 Pt2 118.05(18) . . ?
C26 P2 Pt2 115.00(19) . . ?
C7 P2 Pt2 111.24(18) . . ?
C40 P3 C33 100.4(2) . . ?
C40 P3 C32 102.1(2) . . ?
C33 P3 C32 105.6(2) . . ?
C40 P3 Pt2 114.43(18) . . ?
C33 P3 Pt2 119.72(17) . . ?
C32 P3 Pt2 112.47(17) . . ?
C52 P4 C46 100.9(2) . . ?
C52 P4 C32 104.8(2) . . ?
C46 P4 C32 99.9(2) . . ?
C52 P4 Rh2 115.39(17) . . ?
C46 P4 Rh2 122.76(17) . . ?
C32 P4 Rh2 110.70(17) . . ?
O1 C1 Pt1 178.3(7) . . ?
O2 C2 Pt1 139.9(5) . . ?
O2 C2 Rh1 138.8(5) . . ?
Pt1 C2 Rh1 81.1(2) . . ?
O3 C3 Rh2 140.4(5) . . ?
O3 C3 Pt1 138.2(5) . . ?
Rh2 C3 Pt1 81.4(2) . . ?
O4 C4 Rh2 138.6(4) . . ?
O4 C4 Rh1 140.0(4) . . ?
Rh2 C4 Rh1 81.0(2) . . ?
O5 C5 Rh2 178.0(6) . . ?
O6 C6 Rh1 178.2(6) . . ?
P1 C7 P2 111.3(3) . . ?
P1 C7 H7A 109.4 . . ?
P2 C7 H7A 109.4 . . ?
P1 C7 H7B 109.4 . . ?
P2 C7 H7B 109.4 . . ?
H7A C7 H7B 108.0 . . ?
C9 C8 C13 119.5(5) . . ?
C9 C8 P1 125.1(4) . . ?
C13 C8 P1 115.3(4) . . ?
C8 C9 C10 120.0(6) . . ?
C8 C9 H9 120.0 . . ?
C10 C9 H9 120.0 . . ?
C11 C10 C9 120.6(6) . . ?
C11 C10 H10 119.7 . . ?
C9 C10 H10 119.7 . . ?
C12 C11 C10 119.3(6) . . ?
C12 C11 H11 120.4 . . ?
C10 C11 H11 120.4 . . ?
C11 C12 C13 121.3(6) . . ?
C11 C12 H12 119.3 . . ?
C13 C12 H12 119.3 . . ?
C8 C13 C12 119.2(6) . . ?
C8 C13 H13 120.4 . . ?
C12 C13 H13 120.4 . . ?
C15 C14 C19 118.8(5) . . ?
C15 C14 P1 120.3(5) . . ?
C19 C14 P1 120.9(5) . . ?
C14 C15 C16 121.6(6) . . ?
C14 C15 H15 119.2 . . ?
C16 C15 H15 119.2 . . ?
C17 C16 C15 119.3(6) . . ?
C17 C16 H16 120.4 . . ?
C15 C16 H16 120.4 . . ?
C16 C17 C18 119.8(6) . . ?
C16 C17 H17 120.1 . . ?
C18 C17 H17 120.1 . . ?
C17 C18 C19 120.9(7) . . ?
C17 C18 H18 119.5 . . ?
C19 C18 H18 119.5 . . ?
C14 C19 C18 119.6(6) . . ?
C14 C19 H19 120.2 . . ?
C18 C19 H19 120.2 . . ?
C21 C20 C25 118.7(5) . . ?
C21 C20 P2 118.0(4) . . ?
C25 C20 P2 122.9(4) . . ?
C22 C21 C20 121.4(5) . . ?
C22 C21 H21 119.3 . . ?
C20 C21 H21 119.3 . . ?
C21 C22 C23 118.8(6) . . ?
C21 C22 H22 120.6 . . ?
C23 C22 H22 120.6 . . ?
C24 C23 C22 120.9(6) . . ?
C24 C23 H23 119.5 . . ?
C22 C23 H23 119.5 . . ?
C23 C24 C25 120.0(6) . . ?
C23 C24 H24 120.0 . . ?
C25 C24 H24 120.0 . . ?
C24 C25 C20 120.2(6) . . ?
C24 C25 H25 119.9 . . ?
C20 C25 H25 119.9 . . ?
C27 C26 C31 117.8(6) . . ?
C27 C26 P2 119.3(4) . . ?
C31 C26 P2 122.3(5) . . ?
C28 C27 C26 122.2(6) . . ?
C28 C27 H27 118.9 . . ?
C26 C27 H27 118.9 . . ?
C27 C28 C29 118.9(7) . . ?
C27 C28 H28 120.5 . . ?
C29 C28 H28 120.5 . . ?
C30 C29 C28 120.3(7) . . ?
C30 C29 H29 119.9 . . ?
C28 C29 H29 119.9 . . ?
C29 C30 C31 120.3(7) . . ?
C29 C30 H30 119.8 . . ?
C31 C30 H30 119.8 . . ?
C30 C31 C26 120.5(7) . . ?
C30 C31 H31 119.8 . . ?
C26 C31 H31 119.8 . . ?
P4 C32 P3 107.4(3) . . ?
P4 C32 H32A 110.2 . . ?
P3 C32 H32A 110.2 . . ?
P4 C32 H32B 110.2 . . ?
P3 C32 H32B 110.2 . . ?
H32A C32 H32B 108.5 . . ?
C38 C33 C34 118.5(5) . . ?
C38 C33 P3 117.9(4) . . ?
C34 C33 P3 123.1(4) . . ?
C35 C34 C33 119.6(5) . . ?
C35 C34 H34 120.2 . . ?
C33 C34 H34 120.2 . . ?
C36 C35 C34 121.3(6) . . ?
C36 C35 H35 119.4 . . ?
C34 C35 H35 119.4 . . ?
C37 C36 C35 119.6(6) . . ?
C37 C36 H36 120.2 . . ?
C35 C36 H36 120.2 . . ?
C36 C37 C38 120.1(6) . . ?
C36 C37 H37 120.0 . . ?
C38 C37 H37 120.0 . . ?
C37 C38 C33 120.9(6) . . ?
C37 C38 H38 119.5 . . ?
C33 C38 H38 119.5 . . ?
C45 C40 C41 118.6(5) . . ?
C45 C40 P3 121.2(4) . . ?
C41 C40 P3 120.1(4) . . ?
C42 C41 C40 121.2(6) . . ?
C42 C41 H41 119.4 . . ?
C40 C41 H41 119.4 . . ?
C41 C42 C43 120.0(6) . . ?
C41 C42 H42 120.0 . . ?
C43 C42 H42 120.0 . . ?
C44 C43 C42 119.2(6) . . ?
C44 C43 H43 120.4 . . ?
C42 C43 H43 120.4 . . ?
C43 C44 C45 121.2(6) . . ?
C43 C44 H44 119.4 . . ?
C45 C44 H44 119.4 . . ?
C44 C45 C40 119.7(6) . . ?
C44 C45 H45 120.2 . . ?
C40 C45 H45 120.2 . . ?
C47 C46 C51 118.5(5) . . ?
C47 C46 P4 122.5(4) . . ?
C51 C46 P4 118.7(4) . . ?
C48 C47 C46 120.8(5) . . ?
C48 C47 H47 119.6 . . ?
C46 C47 H47 119.6 . . ?
C49 C48 C47 119.9(5) . . ?
C49 C48 H48 120.1 . . ?
C47 C48 H48 120.1 . . ?
C48 C49 C50 120.4(5) . . ?
C48 C49 H49 119.8 . . ?
C50 C49 H49 119.8 . . ?
C51 C50 C49 119.4(5) . . ?
C51 C50 H50 120.3 . . ?
C49 C50 H50 120.3 . . ?
C50 C51 C46 121.0(5) . . ?
C50 C51 H51 119.5 . . ?
C46 C51 H51 119.5 . . ?
C57 C52 C53 118.8(5) . . ?
C57 C52 P4 123.7(4) . . ?
C53 C52 P4 117.4(4) . . ?
C52 C53 C54 120.6(5) . . ?
C52 C53 H53 119.7 . . ?
C54 C53 H53 119.7 . . ?
C55 C54 C53 119.3(5) . . ?
C55 C54 H54 120.4 . . ?
C53 C54 H54 120.4 . . ?
C56 C55 C54 120.0(5) . . ?
C56 C55 H55 120.0 . . ?
C54 C55 H55 120.0 . . ?
C55 C56 C57 121.0(6) . . ?
C55 C56 H56 119.5 . . ?
C57 C56 H56 119.5 . . ?
C52 C57 C56 120.2(5) . . ?
C52 C57 H57 119.9 . . ?
C56 C57 H57 119.9 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 C1 1.880(7) . ?
Pt1 C2 2.081(6) . ?
Pt1 C3 2.096(6) . ?
Pt1 Rh2 2.7055(4) . ?
Pt1 Rh1 2.7126(4) . ?
Pt1 Pt2 2.9148(3) . ?
Pt2 P2 2.2600(13) . ?
Pt2 P3 2.2821(13) . ?
Pt2 Rh2 2.6336(4) . ?
Pt2 Rh1 2.6657(4) . ?
Rh1 C6 1.899(6) . ?
Rh1 C2 2.091(6) . ?
Rh1 C4 2.102(5) . ?
Rh1 P1 2.2984(14) . ?
Rh1 Rh2 2.7243(6) . ?
Rh2 C5 1.914(6) . ?
Rh2 C3 2.052(6) . ?
Rh2 C4 2.094(5) . ?
Rh2 P4 2.2775(14) . ?
P1 C8 1.831(6) . ?
P1 C7 1.842(5) . ?
P1 C14 1.843(5) . ?
P2 C20 1.826(6) . ?
P2 C26 1.826(6) . ?
P2 C7 1.853(5) . ?
P3 C40 1.818(5) . ?
P3 C33 1.833(6) . ?
P3 C32 1.851(5) . ?
P4 C52 1.827(5) . ?
P4 C46 1.828(5) . ?
P4 C32 1.844(5) . ?
C1 O1 1.121(8) . ?
C2 O2 1.145(7) . ?
C3 O3 1.157(7) . ?
C4 O4 1.153(6) . ?
C5 O5 1.143(7) . ?
C6 O6 1.142(7) . ?
C7 H7A 0.9900 . ?
C7 H7B 0.9900 . ?
C8 C9 1.385(8) . ?
C8 C13 1.395(8) . ?
C9 C10 1.393(8) . ?
C9 H9 0.9500 . ?
C10 C11 1.379(10) . ?
C10 H10 0.9500 . ?
C11 C12 1.370(10) . ?
C11 H11 0.9500 . ?
C12 C13 1.395(9) . ?
C12 H12 0.9500 . ?
C13 H13 0.9500 . ?
C14 C15 1.365(9) . ?
C14 C19 1.395(8) . ?
C15 C16 1.407(8) . ?
C15 H15 0.9500 . ?
C16 C17 1.372(10) . ?
C16 H16 0.9500 . ?
C17 C18 1.373(10) . ?
C17 H17 0.9500 . ?
C18 C19 1.399(8) . ?
C18 H18 0.9500 . ?
C19 H19 0.9500 . ?
C20 C21 1.386(8) . ?
C20 C25 1.397(8) . ?
C21 C22 1.376(8) . ?
C21 H21 0.9500 . ?
C22 C23 1.388(9) . ?
C22 H22 0.9500 . ?
C23 C24 1.372(10) . ?
C23 H23 0.9500 . ?
C24 C25 1.380(9) . ?
C24 H24 0.9500 . ?
C25 H25 0.9500 . ?
C26 C27 1.397(9) . ?
C26 C31 1.398(8) . ?
C27 C28 1.374(9) . ?
C27 H27 0.9500 . ?
C28 C29 1.393(11) . ?
C28 H28 0.9500 . ?
C29 C30 1.381(11) . ?
C29 H29 0.9500 . ?
C30 C31 1.387(10) . ?
C30 H30 0.9500 . ?
C31 H31 0.9500 . ?
C32 H32A 0.9900 . ?
C32 H32B 0.9900 . ?
C33 C38 1.398(8) . ?
C33 C34 1.398(8) . ?
C34 C35 1.381(8) . ?
C34 H34 0.9500 . ?
C35 C36 1.378(9) . ?
C35 H35 0.9500 . ?
C36 C37 1.377(9) . ?
C36 H36 0.9500 . ?
C37 C38 1.379(9) . ?
C37 H37 0.9500 . ?
C38 H38 0.9500 . ?
C40 C45 1.388(8) . ?
C40 C41 1.404(8) . ?
C41 C42 1.361(8) . ?
C41 H41 0.9500 . ?
C42 C43 1.392(9) . ?
C42 H42 0.9500 . ?
C43 C44 1.380(9) . ?
C43 H43 0.9500 . ?
C44 C45 1.383(8) . ?
C44 H44 0.9500 . ?
C45 H45 0.9500 . ?
C46 C47 1.390(7) . ?
C46 C51 1.410(7) . ?
C47 C48 1.388(8) . ?
C47 H47 0.9500 . ?
C48 C49 1.384(8) . ?
C48 H48 0.9500 . ?
C49 C50 1.394(8) . ?
C49 H49 0.9500 . ?
C50 C51 1.379(8) . ?
C50 H50 0.9500 . ?
C51 H51 0.9500 . ?
C52 C57 1.377(7) . ?
C52 C53 1.392(8) . ?
C53 C54 1.397(8) . ?
C53 H53 0.9500 . ?
C54 C55 1.379(8) . ?
C54 H54 0.9500 . ?
C55 C56 1.366(9) . ?
C55 H55 0.9500 . ?
C56 C57 1.383(8) . ?
C56 H56 0.9500 . ?
C57 H57 0.9500 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C1 Pt1 Pt2 P2 -59.9(3) . . . . ?
C2 Pt1 Pt2 P2 40.69(16) . . . . ?
C3 Pt1 Pt2 P2 -156.07(17) . . . . ?
Rh2 Pt1 Pt2 P2 158.73(4) . . . . ?
Rh1 Pt1 Pt2 P2 84.13(4) . . . . ?
C1 Pt1 Pt2 P3 56.0(3) . . . . ?
C2 Pt1 Pt2 P3 156.56(16) . . . . ?
C3 Pt1 Pt2 P3 -40.20(17) . . . . ?
Rh2 Pt1 Pt2 P3 -85.40(4) . . . . ?
Rh1 Pt1 Pt2 P3 -160.00(4) . . . . ?
C1 Pt1 Pt2 Rh2 141.4(3) . . . . ?
C2 Pt1 Pt2 Rh2 -118.03(16) . . . . ?
C3 Pt1 Pt2 Rh2 45.20(16) . . . . ?
Rh1 Pt1 Pt2 Rh2 -74.596(15) . . . . ?
C1 Pt1 Pt2 Rh1 -144.0(3) . . . . ?
C2 Pt1 Pt2 Rh1 -43.44(16) . . . . ?
C3 Pt1 Pt2 Rh1 119.80(16) . . . . ?
Rh2 Pt1 Pt2 Rh1 74.596(15) . . . . ?
P2 Pt2 Rh1 C6 176.3(8) . . . . ?
P3 Pt2 Rh1 C6 -15.8(8) . . . . ?
Rh2 Pt2 Rh1 C6 -1.9(8) . . . . ?
Pt1 Pt2 Rh1 C6 -70.1(8) . . . . ?
P2 Pt2 Rh1 C2 -70.64(17) . . . . ?
P3 Pt2 Rh1 C2 97.28(19) . . . . ?
Rh2 Pt2 Rh1 C2 111.19(17) . . . . ?
Pt1 Pt2 Rh1 C2 43.04(17) . . . . ?
P2 Pt2 Rh1 C4 129.44(16) . . . . ?
P3 Pt2 Rh1 C4 -62.63(17) . . . . ?
Rh2 Pt2 Rh1 C4 -48.73(15) . . . . ?
Pt1 Pt2 Rh1 C4 -116.87(15) . . . . ?
P2 Pt2 Rh1 P1 25.57(5) . . . . ?
P3 Pt2 Rh1 P1 -166.51(9) . . . . ?
Rh2 Pt2 Rh1 P1 -152.60(4) . . . . ?
Pt1 Pt2 Rh1 P1 139.25(4) . . . . ?
P2 Pt2 Rh1 Pt1 -113.68(4) . . . . ?
P3 Pt2 Rh1 Pt1 54.24(9) . . . . ?
Rh2 Pt2 Rh1 Pt1 68.147(13) . . . . ?
P2 Pt2 Rh1 Rh2 178.17(4) . . . . ?
P3 Pt2 Rh1 Rh2 -13.91(9) . . . . ?
Pt1 Pt2 Rh1 Rh2 -68.147(13) . . . . ?
C1 Pt1 Rh1 C6 -63.2(5) . . . . ?
C2 Pt1 Rh1 C6 -76.2(3) . . . . ?
C3 Pt1 Rh1 C6 102.9(2) . . . . ?
Rh2 Pt1 Rh1 C6 101.48(17) . . . . ?
Pt2 Pt1 Rh1 C6 167.91(17) . . . . ?
C1 Pt1 Rh1 C2 13.0(5) . . . . ?
C3 Pt1 Rh1 C2 179.1(3) . . . . ?
Rh2 Pt1 Rh1 C2 177.7(2) . . . . ?
Pt2 Pt1 Rh1 C2 -115.9(2) . . . . ?
C1 Pt1 Rh1 C4 -163.2(5) . . . . ?
C2 Pt1 Rh1 C4 -176.2(3) . . . . ?
C3 Pt1 Rh1 C4 2.9(2) . . . . ?
Rh2 Pt1 Rh1 C4 1.51(16) . . . . ?
Pt2 Pt1 Rh1 C4 67.94(16) . . . . ?
C1 Pt1 Rh1 P1 67.2(4) . . . . ?
C2 Pt1 Rh1 P1 54.2(2) . . . . ?
C3 Pt1 Rh1 P1 -126.70(18) . . . . ?
Rh2 Pt1 Rh1 P1 -128.08(5) . . . . ?
Pt2 Pt1 Rh1 P1 -61.65(5) . . . . ?
C1 Pt1 Rh1 Pt2 128.9(4) . . . . ?
C2 Pt1 Rh1 Pt2 115.9(2) . . . . ?
C3 Pt1 Rh1 Pt2 -65.05(17) . . . . ?
Rh2 Pt1 Rh1 Pt2 -66.430(12) . . . . ?
C1 Pt1 Rh1 Rh2 -164.7(4) . . . . ?
C2 Pt1 Rh1 Rh2 -177.7(2) . . . . ?
C3 Pt1 Rh1 Rh2 1.39(17) . . . . ?
Pt2 Pt1 Rh1 Rh2 66.430(12) . . . . ?
P2 Pt2 Rh2 C5 -1(2) . . . . ?
P3 Pt2 Rh2 C5 179(2) . . . . ?
Rh1 Pt2 Rh2 C5 4(2) . . . . ?
Pt1 Pt2 Rh2 C5 72(2) . . . . ?
P2 Pt2 Rh2 C3 -118.94(19) . . . . ?
P3 Pt2 Rh2 C3 60.72(17) . . . . ?
Rh1 Pt2 Rh2 C3 -113.68(16) . . . . ?
Pt1 Pt2 Rh2 C3 -45.76(16) . . . . ?
P2 Pt2 Rh2 C4 43.52(18) . . . . ?
P3 Pt2 Rh2 C4 -136.82(15) . . . . ?
Rh1 Pt2 Rh2 C4 48.78(15) . . . . ?
Pt1 Pt2 Rh2 C4 116.70(15) . . . . ?
P2 Pt2 Rh2 P4 145.13(11) . . . . ?
P3 Pt2 Rh2 P4 -35.21(5) . . . . ?
Rh1 Pt2 Rh2 P4 150.38(4) . . . . ?
Pt1 Pt2 Rh2 P4 -141.69(4) . . . . ?
P2 Pt2 Rh2 Pt1 -73.18(11) . . . . ?
P3 Pt2 Rh2 Pt1 106.48(3) . . . . ?
Rh1 Pt2 Rh2 Pt1 -67.926(12) . . . . ?
P2 Pt2 Rh2 Rh1 -5.25(11) . . . . ?
P3 Pt2 Rh2 Rh1 174.41(4) . . . . ?
Pt1 Pt2 Rh2 Rh1 67.926(12) . . . . ?
C1 Pt1 Rh2 C5 58.4(5) . . . . ?
C2 Pt1 Rh2 C5 -105.0(3) . . . . ?
C3 Pt1 Rh2 C5 74.9(3) . . . . ?
Rh1 Pt1 Rh2 C5 -106.8(2) . . . . ?
Pt2 Pt1 Rh2 C5 -174.3(2) . . . . ?
C1 Pt1 Rh2 C3 -16.5(5) . . . . ?
C2 Pt1 Rh2 C3 -179.9(3) . . . . ?
Rh1 Pt1 Rh2 C3 178.3(2) . . . . ?
Pt2 Pt1 Rh2 C3 110.8(2) . . . . ?
C1 Pt1 Rh2 C4 163.8(4) . . . . ?
C2 Pt1 Rh2 C4 0.3(2) . . . . ?
C3 Pt1 Rh2 C4 -179.8(3) . . . . ?
Rh1 Pt1 Rh2 C4 -1.52(16) . . . . ?
Pt2 Pt1 Rh2 C4 -69.03(16) . . . . ?
C1 Pt1 Rh2 P4 -69.6(4) . . . . ?
C2 Pt1 Rh2 P4 127.01(18) . . . . ?
C3 Pt1 Rh2 P4 -53.1(2) . . . . ?
Rh1 Pt1 Rh2 P4 125.16(5) . . . . ?
Pt2 Pt1 Rh2 P4 57.66(5) . . . . ?
C1 Pt1 Rh2 Pt2 -127.2(4) . . . . ?
C2 Pt1 Rh2 Pt2 69.35(18) . . . . ?
C3 Pt1 Rh2 Pt2 -110.8(2) . . . . ?
Rh1 Pt1 Rh2 Pt2 67.503(12) . . . . ?
C1 Pt1 Rh2 Rh1 165.3(4) . . . . ?
C2 Pt1 Rh2 Rh1 1.85(18) . . . . ?
C3 Pt1 Rh2 Rh1 -178.3(2) . . . . ?
Pt2 Pt1 Rh2 Rh1 -67.503(12) . . . . ?
C6 Rh1 Rh2 C5 0.0(3) . . . . ?
C2 Rh1 Rh2 C5 100.3(3) . . . . ?
C4 Rh1 Rh2 C5 -76.0(3) . . . . ?
P1 Rh1 Rh2 C5 -137.0(2) . . . . ?
Pt2 Rh1 Rh2 C5 -179.5(2) . . . . ?
Pt1 Rh1 Rh2 C5 102.1(2) . . . . ?
C6 Rh1 Rh2 C3 -103.5(2) . . . . ?
C2 Rh1 Rh2 C3 -3.3(2) . . . . ?
C4 Rh1 Rh2 C3 -179.5(3) . . . . ?
P1 Rh1 Rh2 C3 119.47(18) . . . . ?
Pt2 Rh1 Rh2 C3 76.91(17) . . . . ?
Pt1 Rh1 Rh2 C3 -1.42(17) . . . . ?
C6 Rh1 Rh2 C4 76.0(3) . . . . ?
C2 Rh1 Rh2 C4 176.3(3) . . . . ?
P1 Rh1 Rh2 C4 -61.0(2) . . . . ?
Pt2 Rh1 Rh2 C4 -103.6(2) . . . . ?
Pt1 Rh1 Rh2 C4 178.1(2) . . . . ?
C6 Rh1 Rh2 P4 135.50(18) . . . . ?
C2 Rh1 Rh2 P4 -124.24(18) . . . . ?
C4 Rh1 Rh2 P4 59.5(2) . . . . ?
P1 Rh1 Rh2 P4 -1.51(8) . . . . ?
Pt2 Rh1 Rh2 P4 -44.07(5) . . . . ?
Pt1 Rh1 Rh2 P4 -122.41(5) . . . . ?
C6 Rh1 Rh2 Pt2 179.58(17) . . . . ?
C2 Rh1 Rh2 Pt2 -80.16(17) . . . . ?
C4 Rh1 Rh2 Pt2 103.6(2) . . . . ?
P1 Rh1 Rh2 Pt2 42.56(6) . . . . ?
Pt1 Rh1 Rh2 Pt2 -78.332(11) . . . . ?
C6 Rh1 Rh2 Pt1 -102.09(17) . . . . ?
C2 Rh1 Rh2 Pt1 -1.83(17) . . . . ?
C4 Rh1 Rh2 Pt1 -178.1(2) . . . . ?
P1 Rh1 Rh2 Pt1 120.90(6) . . . . ?
Pt2 Rh1 Rh2 Pt1 78.332(11) . . . . ?
C6 Rh1 P1 C8 -92.8(3) . . . . ?
C2 Rh1 P1 C8 172.7(3) . . . . ?
C4 Rh1 P1 C8 2.9(2) . . . . ?
Pt2 Rh1 P1 C8 81.2(2) . . . . ?
Pt1 Rh1 P1 C8 134.5(2) . . . . ?
Rh2 Rh1 P1 C8 45.9(2) . . . . ?
C6 Rh1 P1 C7 142.7(2) . . . . ?
C2 Rh1 P1 C7 48.3(2) . . . . ?
C4 Rh1 P1 C7 -121.5(2) . . . . ?
Pt2 Rh1 P1 C7 -43.30(18) . . . . ?
Pt1 Rh1 P1 C7 10.1(2) . . . . ?
Rh2 Rh1 P1 C7 -78.55(19) . . . . ?
C6 Rh1 P1 C14 27.1(3) . . . . ?
C2 Rh1 P1 C14 -67.3(3) . . . . ?
C4 Rh1 P1 C14 122.8(3) . . . . ?
Pt2 Rh1 P1 C14 -158.9(2) . . . . ?
Pt1 Rh1 P1 C14 -105.6(2) . . . . ?
Rh2 Rh1 P1 C14 165.8(2) . . . . ?
P3 Pt2 P2 C20 61.2(2) . . . . ?
Rh2 Pt2 P2 C20 -119.2(2) . . . . ?
Rh1 Pt2 P2 C20 -123.9(2) . . . . ?
Pt1 Pt2 P2 C20 177.8(2) . . . . ?
P3 Pt2 P2 C26 -64.4(2) . . . . ?
Rh2 Pt2 P2 C26 115.2(2) . . . . ?
Rh1 Pt2 P2 C26 110.6(2) . . . . ?
Pt1 Pt2 P2 C26 52.2(2) . . . . ?
P3 Pt2 P2 C7 178.36(19) . . . . ?
Rh2 Pt2 P2 C7 -2.0(2) . . . . ?
Rh1 Pt2 P2 C7 -6.67(19) . . . . ?
Pt1 Pt2 P2 C7 -65.04(19) . . . . ?
P2 Pt2 P3 C40 80.9(2) . . . . ?
Rh2 Pt2 P3 C40 -98.98(19) . . . . ?
Rh1 Pt2 P3 C40 -86.7(2) . . . . ?
Pt1 Pt2 P3 C40 -40.83(19) . . . . ?
P2 Pt2 P3 C33 -38.3(2) . . . . ?
Rh2 Pt2 P3 C33 141.9(2) . . . . ?
Rh1 Pt2 P3 C33 154.2(2) . . . . ?
Pt1 Pt2 P3 C33 -160.0(2) . . . . ?
P2 Pt2 P3 C32 -163.15(19) . . . . ?
Rh2 Pt2 P3 C32 16.97(19) . . . . ?
Rh1 Pt2 P3 C32 29.3(2) . . . . ?
Pt1 Pt2 P3 C32 75.11(19) . . . . ?
C5 Rh2 P4 C52 -10.6(3) . . . . ?
C3 Rh2 P4 C52 83.6(3) . . . . ?
C4 Rh2 P4 C52 -108.6(2) . . . . ?
Pt2 Rh2 P4 C52 172.49(19) . . . . ?
Pt1 Rh2 P4 C52 121.64(19) . . . . ?
Rh1 Rh2 P4 C52 -150.48(19) . . . . ?
C5 Rh2 P4 C46 113.1(3) . . . . ?
C3 Rh2 P4 C46 -152.7(3) . . . . ?
C4 Rh2 P4 C46 15.1(2) . . . . ?
Pt2 Rh2 P4 C46 -63.8(2) . . . . ?
Pt1 Rh2 P4 C46 -114.7(2) . . . . ?
Rh1 Rh2 P4 C46 -26.8(2) . . . . ?
C5 Rh2 P4 C32 -129.4(3) . . . . ?
C3 Rh2 P4 C32 -35.2(2) . . . . ?
C4 Rh2 P4 C32 132.6(2) . . . . ?
Pt2 Rh2 P4 C32 53.68(18) . . . . ?
Pt1 Rh2 P4 C32 2.84(19) . . . . ?
Rh1 Rh2 P4 C32 90.71(18) . . . . ?
C2 Pt1 C1 O1 102(23) . . . . ?
C3 Pt1 C1 O1 -75(24) . . . . ?
Rh2 Pt1 C1 O1 -62(24) . . . . ?
Rh1 Pt1 C1 O1 92(23) . . . . ?
Pt2 Pt1 C1 O1 -163(23) . . . . ?
C1 Pt1 C2 O2 2.1(8) . . . . ?
C3 Pt1 C2 O2 173.1(6) . . . . ?
Rh2 Pt1 C2 O2 173.3(7) . . . . ?
Rh1 Pt1 C2 O2 175.4(9) . . . . ?
Pt2 Pt1 C2 O2 -135.8(8) . . . . ?
C1 Pt1 C2 Rh1 -173.3(2) . . . . ?
C3 Pt1 C2 Rh1 -2.3(7) . . . . ?
Rh2 Pt1 C2 Rh1 -2.1(2) . . . . ?
Pt2 Pt1 C2 Rh1 48.78(13) . . . . ?
C6 Rh1 C2 O2 -61.8(8) . . . . ?
C4 Rh1 C2 O2 -165.9(6) . . . . ?
P1 Rh1 C2 O2 41.7(8) . . . . ?
Pt2 Rh1 C2 O2 129.4(8) . . . . ?
Pt1 Rh1 C2 O2 -175.5(9) . . . . ?
Rh2 Rh1 C2 O2 -173.4(7) . . . . ?
C6 Rh1 C2 Pt1 113.8(2) . . . . ?
C4 Rh1 C2 Pt1 9.7(7) . . . . ?
P1 Rh1 C2 Pt1 -142.80(13) . . . . ?
Pt2 Rh1 C2 Pt1 -55.10(15) . . . . ?
Rh2 Rh1 C2 Pt1 2.1(2) . . . . ?
C5 Rh2 C3 O3 63.5(8) . . . . ?
C4 Rh2 C3 O3 -179.6(6) . . . . ?
P4 Rh2 C3 O3 -36.2(8) . . . . ?
Pt2 Rh2 C3 O3 -121.4(8) . . . . ?
Pt1 Rh2 C3 O3 179.8(9) . . . . ?
Rh1 Rh2 C3 O3 -178.6(7) . . . . ?
C5 Rh2 C3 Pt1 -116.3(2) . . . . ?
C4 Rh2 C3 Pt1 0.6(7) . . . . ?
P4 Rh2 C3 Pt1 144.00(13) . . . . ?
Pt2 Rh2 C3 Pt1 58.81(14) . . . . ?
Rh1 Rh2 C3 Pt1 1.6(2) . . . . ?
C1 Pt1 C3 O3 -8.5(8) . . . . ?
C2 Pt1 C3 O3 -179.5(6) . . . . ?
Rh2 Pt1 C3 O3 -179.8(8) . . . . ?
Rh1 Pt1 C3 O3 178.6(7) . . . . ?
Pt2 Pt1 C3 O3 128.8(7) . . . . ?
C1 Pt1 C3 Rh2 171.3(2) . . . . ?
C2 Pt1 C3 Rh2 0.3(7) . . . . ?
Rh1 Pt1 C3 Rh2 -1.6(2) . . . . ?
Pt2 Pt1 C3 Rh2 -51.45(13) . . . . ?
C5 Rh2 C4 O4 -54.7(7) . . . . ?
C3 Rh2 C4 O4 -171.1(6) . . . . ?
P4 Rh2 C4 O4 46.0(7) . . . . ?
Pt2 Rh2 C4 O4 129.2(7) . . . . ?
Pt1 Rh2 C4 O4 -170.6(6) . . . . ?
Rh1 Rh2 C4 O4 -172.4(8) . . . . ?
C5 Rh2 C4 Rh1 117.7(2) . . . . ?
C3 Rh2 C4 Rh1 1.2(7) . . . . ?
P4 Rh2 C4 Rh1 -141.65(11) . . . . ?
Pt2 Rh2 C4 Rh1 -58.40(12) . . . . ?
Pt1 Rh2 C4 Rh1 1.73(18) . . . . ?
C6 Rh1 C4 O4 58.5(7) . . . . ?
C2 Rh1 C4 O4 162.7(6) . . . . ?
P1 Rh1 C4 O4 -45.5(7) . . . . ?
Pt2 Rh1 C4 O4 -130.3(7) . . . . ?
Pt1 Rh1 C4 O4 170.4(7) . . . . ?
Rh2 Rh1 C4 O4 172.1(8) . . . . ?
C6 Rh1 C4 Rh2 -113.6(2) . . . . ?
C2 Rh1 C4 Rh2 -9.5(7) . . . . ?
P1 Rh1 C4 Rh2 142.39(11) . . . . ?
Pt2 Rh1 C4 Rh2 57.55(11) . . . . ?
Pt1 Rh1 C4 Rh2 -1.72(18) . . . . ?
C3 Rh2 C5 O5 -52(19) . . . . ?
C4 Rh2 C5 O5 147(19) . . . . ?
P4 Rh2 C5 O5 45(19) . . . . ?
Pt2 Rh2 C5 O5 -170(17) . . . . ?
Pt1 Rh2 C5 O5 -100(19) . . . . ?
Rh1 Rh2 C5 O5 -165(19) . . . . ?
C2 Rh1 C6 O6 -80(17) . . . . ?
C4 Rh1 C6 O6 79(17) . . . . ?
P1 Rh1 C6 O6 -177(100) . . . . ?
Pt2 Rh1 C6 O6 33(17) . . . . ?
Pt1 Rh1 C6 O6 -32(17) . . . . ?
Rh2 Rh1 C6 O6 32(17) . . . . ?
C8 P1 C7 P2 -82.4(3) . . . . ?
C14 P1 C7 P2 174.9(3) . . . . ?
Rh1 P1 C7 P2 47.8(3) . . . . ?
C20 P2 C7 P1 104.2(3) . . . . ?
C26 P2 C7 P1 -146.5(3) . . . . ?
Pt2 P2 C7 P1 -22.5(3) . . . . ?
C7 P1 C8 C9 0.4(5) . . . . ?
C14 P1 C8 C9 103.6(5) . . . . ?
Rh1 P1 C8 C9 -126.3(4) . . . . ?
C7 P1 C8 C13 -176.6(4) . . . . ?
C14 P1 C8 C13 -73.4(4) . . . . ?
Rh1 P1 C8 C13 56.7(4) . . . . ?
C13 C8 C9 C10 -2.2(8) . . . . ?
P1 C8 C9 C10 -179.1(4) . . . . ?
C8 C9 C10 C11 1.3(8) . . . . ?
C9 C10 C11 C12 0.5(9) . . . . ?
C10 C11 C12 C13 -1.3(9) . . . . ?
C9 C8 C13 C12 1.5(8) . . . . ?
P1 C8 C13 C12 178.6(4) . . . . ?
C11 C12 C13 C8 0.3(9) . . . . ?
C8 P1 C14 C15 -42.0(6) . . . . ?
C7 P1 C14 C15 67.3(6) . . . . ?
Rh1 P1 C14 C15 -171.0(4) . . . . ?
C8 P1 C14 C19 139.1(5) . . . . ?
C7 P1 C14 C19 -111.7(5) . . . . ?
Rh1 P1 C14 C19 10.0(6) . . . . ?
C19 C14 C15 C16 -1.1(10) . . . . ?
P1 C14 C15 C16 179.9(5) . . . . ?
C14 C15 C16 C17 1.2(11) . . . . ?
C15 C16 C17 C18 -1.1(11) . . . . ?
C16 C17 C18 C19 0.9(11) . . . . ?
C15 C14 C19 C18 0.9(9) . . . . ?
P1 C14 C19 C18 179.8(5) . . . . ?
C17 C18 C19 C14 -0.8(10) . . . . ?
C26 P2 C20 C21 135.9(4) . . . . ?
C7 P2 C20 C21 -116.3(4) . . . . ?
Pt2 P2 C20 C21 5.8(5) . . . . ?
C26 P2 C20 C25 -51.8(5) . . . . ?
C7 P2 C20 C25 56.0(5) . . . . ?
Pt2 P2 C20 C25 178.1(4) . . . . ?
C25 C20 C21 C22 -1.0(8) . . . . ?
P2 C20 C21 C22 171.7(4) . . . . ?
C20 C21 C22 C23 0.6(8) . . . . ?
C21 C22 C23 C24 0.4(9) . . . . ?
C22 C23 C24 C25 -1.0(10) . . . . ?
C23 C24 C25 C20 0.6(10) . . . . ?
C21 C20 C25 C24 0.4(9) . . . . ?
P2 C20 C25 C24 -171.9(5) . . . . ?
C20 P2 C26 C27 166.9(4) . . . . ?
C7 P2 C26 C27 60.3(5) . . . . ?
Pt2 P2 C26 C27 -61.2(5) . . . . ?
C20 P2 C26 C31 -22.2(6) . . . . ?
C7 P2 C26 C31 -128.8(5) . . . . ?
Pt2 P2 C26 C31 109.7(5) . . . . ?
C31 C26 C27 C28 0.6(9) . . . . ?
P2 C26 C27 C28 172.0(5) . . . . ?
C26 C27 C28 C29 -1.2(10) . . . . ?
C27 C28 C29 C30 0.5(11) . . . . ?
C28 C29 C30 C31 0.8(12) . . . . ?
C29 C30 C31 C26 -1.5(11) . . . . ?
C27 C26 C31 C30 0.8(9) . . . . ?
P2 C26 C31 C30 -170.3(5) . . . . ?
C52 P4 C32 P3 -176.0(3) . . . . ?
C46 P4 C32 P3 79.8(3) . . . . ?
Rh2 P4 C32 P3 -51.0(3) . . . . ?
C40 P3 C32 P4 139.4(3) . . . . ?
C33 P3 C32 P4 -116.0(3) . . . . ?
Pt2 P3 C32 P4 16.3(3) . . . . ?
C40 P3 C33 C38 -43.1(5) . . . . ?
C32 P3 C33 C38 -148.9(4) . . . . ?
Pt2 P3 C33 C38 83.0(4) . . . . ?
C40 P3 C33 C34 144.9(4) . . . . ?
C32 P3 C33 C34 39.1(5) . . . . ?
Pt2 P3 C33 C34 -89.0(4) . . . . ?
C38 C33 C34 C35 -2.7(8) . . . . ?
P3 C33 C34 C35 169.3(4) . . . . ?
C33 C34 C35 C36 0.6(9) . . . . ?
C34 C35 C36 C37 1.6(9) . . . . ?
C35 C36 C37 C38 -1.6(9) . . . . ?
C36 C37 C38 C33 -0.6(9) . . . . ?
C34 C33 C38 C37 2.7(8) . . . . ?
P3 C33 C38 C37 -169.7(5) . . . . ?
C33 P3 C40 C45 115.7(5) . . . . ?
C32 P3 C40 C45 -135.6(5) . . . . ?
Pt2 P3 C40 C45 -13.8(5) . . . . ?
C33 P3 C40 C41 -62.6(5) . . . . ?
C32 P3 C40 C41 46.1(5) . . . . ?
Pt2 P3 C40 C41 167.9(4) . . . . ?
C45 C40 C41 C42 -0.8(9) . . . . ?
P3 C40 C41 C42 177.6(5) . . . . ?
C40 C41 C42 C43 -1.6(10) . . . . ?
C41 C42 C43 C44 1.7(10) . . . . ?
C42 C43 C44 C45 0.6(10) . . . . ?
C43 C44 C45 C40 -2.9(9) . . . . ?
C41 C40 C45 C44 3.0(9) . . . . ?
P3 C40 C45 C44 -175.4(5) . . . . ?
C52 P4 C46 C47 151.1(4) . . . . ?
C32 P4 C46 C47 -101.6(5) . . . . ?
Rh2 P4 C46 C47 21.1(5) . . . . ?
C52 P4 C46 C51 -35.4(5) . . . . ?
C32 P4 C46 C51 72.0(4) . . . . ?
Rh2 P4 C46 C51 -165.4(3) . . . . ?
C51 C46 C47 C48 -0.3(8) . . . . ?
P4 C46 C47 C48 173.3(4) . . . . ?
C46 C47 C48 C49 -0.4(8) . . . . ?
C47 C48 C49 C50 0.9(9) . . . . ?
C48 C49 C50 C51 -0.7(9) . . . . ?
C49 C50 C51 C46 -0.1(9) . . . . ?
C47 C46 C51 C50 0.5(8) . . . . ?
P4 C46 C51 C50 -173.3(4) . . . . ?
C46 P4 C52 C57 121.2(5) . . . . ?
C32 P4 C52 C57 17.8(5) . . . . ?
Rh2 P4 C52 C57 -104.2(5) . . . . ?
C46 P4 C52 C53 -60.1(5) . . . . ?
C32 P4 C52 C53 -163.6(4) . . . . ?
Rh2 P4 C52 C53 74.4(5) . . . . ?
C57 C52 C53 C54 -3.9(9) . . . . ?
P4 C52 C53 C54 177.3(5) . . . . ?
C52 C53 C54 C55 0.9(9) . . . . ?
C53 C54 C55 C56 2.4(10) . . . . ?
C54 C55 C56 C57 -2.6(10) . . . . ?
C53 C52 C57 C56 3.7(9) . . . . ?
P4 C52 C57 C56 -177.7(5) . . . . ?
C55 C56 C57 C52 -0.5(10) . . . . ?
