#------------------------------------------------------------------------------
#$Date: 2016-03-25 12:53:03 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179819 $
#$URL: svn://www.crystallography.net/cod/cif/7/01/15/7011576.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7011576
loop_
_publ_author_name
'Wachtler, Helmuth'
'Schuh, Walter'
'Ongania, Karl-Hans'
'Kopacka, Holger'
'Wurst, Klaus'
'Peringer, Paul'
_publ_section_title
;
 P(CH2CH2PPh2)3 Bridged Group 10 dimetal centres
;
_journal_issue                   12
_journal_name_full
'Journal of the Chemical Society, Dalton Transactions'
_journal_page_first              2532
_journal_paper_doi               10.1039/b201709a
_journal_year                    2002
_chemical_formula_sum            'C65 H77 Cl4 O5 P5 Pt2'
_chemical_formula_weight         1625.10
_chemical_name_systematic
; 
? 
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL
_cell_angle_alpha                90.00
_cell_angle_beta                 111.84(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   13.933(8)
_cell_length_b                   32.568(7)
_cell_length_c                   15.599(13)
_cell_measurement_reflns_used    26
_cell_measurement_temperature    213(2)
_cell_measurement_theta_max      12.5
_cell_measurement_theta_min      5.0
_cell_volume                     6570(7)
_computing_structure_refinement  'SHELXL-93 (Sheldrick, 1993)'
_computing_structure_solution    'SHELXS-86 (Sheldrick, 1990)'
_diffrn_ambient_temperature      213(2)
_diffrn_measurement_device       'Bruker P4'
_diffrn_measurement_method       omega-scans
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0601
_diffrn_reflns_av_sigmaI/netI    0.0748
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -1
_diffrn_reflns_limit_k_max       32
_diffrn_reflns_limit_k_min       -1
_diffrn_reflns_limit_l_max       14
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            8100
_diffrn_reflns_theta_max         20.99
_diffrn_reflns_theta_min         2.50
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 97
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    4.585
_exptl_absorpt_correction_T_max  0.984
_exptl_absorpt_correction_T_min  0.764
_exptl_absorpt_correction_type   psi-scan
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.643
_exptl_crystal_description       prism
_exptl_crystal_F_000             3224
_exptl_crystal_size_max          0.6
_exptl_crystal_size_mid          0.4
_exptl_crystal_size_min          0.25
_refine_diff_density_max         0.983
_refine_diff_density_min         -1.429
_refine_diff_density_rms         0.160
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_all   1.063
_refine_ls_goodness_of_fit_obs   1.121
_refine_ls_hydrogen_treatment    riding
_refine_ls_matrix_type           full
_refine_ls_number_parameters     729
_refine_ls_number_reflns         6032
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.917
_refine_ls_restrained_S_obs      1.121
_refine_ls_R_factor_all          0.0946
_refine_ls_R_factor_obs          0.0518
_refine_ls_shift/esd_max         -0.004
_refine_ls_shift/esd_mean        0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0468P)²+107.5350P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_all         0.2365
_refine_ls_wR_factor_obs         0.1182
_reflns_number_observed          4898
_reflns_number_total             6703
_reflns_observed_criterion       >2sigma(I)
_cod_data_source_file            b201709a.txt
_cod_data_source_block           kon
_cod_depositor_comments
;
The following automatic conversions were performed:

'_refine_ls_weighting_scheme' value 'calc
w=1/[\s^2^(Fo^2^)+(0.0468P)^2^+107.5350P] where P=(Fo^2^+2Fc^2^)/3'
was changed to 'calc'. New tag '_refine_ls_weighting_details' was
created. The value of the new tag was set to
'w=1/[\s^2^(Fo^2^)+(0.0468P)^2^+107.5350P] where P=(Fo^2^+2Fc^2^)/3'.

Automatic conversion script
Id: cif_fix_values 3143 2015-03-26 13:38:13Z robertas 
;
_cod_original_cell_volume        6570.3(68)
_cod_original_sg_symbol_H-M      P2(1)/n
_cod_database_code               7011576
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_thermal_displace_type
_atom_site_occupancy
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_group
Pt1 Pt 0.60837(5) 0.13113(2) 0.82443(4) 0.0255(2) Uani 1 d . .
Pt2 Pt 0.42318(5) 0.10437(2) 0.72523(4) 0.0242(2) Uani 1 d . .
P1 P 0.5502(3) 0.15013(13) 0.9304(3) 0.0294(11) Uani 1 d . .
P2 P 0.7646(3) 0.15639(13) 0.9155(3) 0.0308(11) Uani 1 d . .
P3 P 0.3813(3) 0.17347(12) 0.7075(3) 0.0264(10) Uani 1 d . .
P4 P 0.4759(3) 0.05160(12) 0.8297(3) 0.0281(10) Uani 1 d . .
P5 P 0.2977(3) 0.07530(12) 0.5936(3) 0.0269(10) Uani 1 d . .
C1 C 0.8409(12) 0.1895(5) 0.8740(11) 0.039(5) Uani 1 d . .
C2 C 0.8507(15) 0.1807(6) 0.7906(13) 0.057(6) Uani 1 d . .
H2 H 0.8136 0.1585 0.7551 0.068 Uiso 1 calc . .
C3 C 0.9146(18) 0.2042(8) 0.7575(16) 0.077(7) Uani 1 d . .
H3 H 0.9235 0.1966 0.7028 0.093 Uiso 1 calc . .
C4 C 0.9626(17) 0.2375(8) 0.8047(16) 0.077(8) Uani 1 d . .
H4 H 1.0030 0.2539 0.7815 0.092 Uiso 1 calc . .
C5 C 0.9531(19) 0.2482(7) 0.8882(18) 0.084(8) Uani 1 d . .
H5 H 0.9880 0.2713 0.9214 0.101 Uiso 1 calc . .
C6 C 0.8921(18) 0.2247(7) 0.9217(14) 0.072(7) Uani 1 d . .
H6 H 0.8847 0.2323 0.9770 0.086 Uiso 1 calc . .
C7 C 0.8586(13) 0.1173(5) 0.9761(10) 0.035(4) Uani 1 d . .
C8 C 0.9573(15) 0.1269(6) 1.0333(16) 0.073(7) Uani 1 d . .
H8 H 0.9787 0.1544 1.0436 0.087 Uiso 1 calc . .
C9 C 1.0249(20) 0.0955(9) 1.0759(19) 0.114(12) Uani 1 d . .
H9 H 1.0921 0.1025 1.1159 0.137 Uiso 1 calc . .
C10 C 1.0011(18) 0.0569(8) 1.0638(16) 0.076(7) Uani 1 d . .
H10 H 1.0509 0.0368 1.0934 0.092 Uiso 1 calc . .
C11 C 0.9018(17) 0.0451(6) 1.0070(17) 0.070(7) Uani 1 d . .
H11 H 0.8827 0.0173 0.9979 0.085 Uiso 1 calc . .
C12 C 0.8316(15) 0.0761(6) 0.9640(15) 0.063(6) Uani 1 d . .
H12 H 0.7638 0.0689 0.9258 0.076 Uiso 1 calc . .
C13 C 0.4637(12) 0.2129(4) 0.6924(10) 0.024(4) Uani 1 d . .
C14 C 0.5450(14) 0.2048(5) 0.6631(12) 0.041(5) Uani 1 d . .
H14 H 0.5589 0.1773 0.6532 0.049 Uiso 1 calc . .
C15 C 0.6057(15) 0.2351(6) 0.6479(13) 0.051(5) Uani 1 d . .
H15 H 0.6542 0.2286 0.6212 0.061 Uiso 1 calc . .
C16 C 0.5949(16) 0.2740(5) 0.6717(12) 0.051(6) Uani 1 d . .
H16 H 0.6421 0.2941 0.6694 0.061 Uiso 1 calc . .
C17 C 0.5138(15) 0.2848(5) 0.6998(11) 0.040(5) Uani 1 d . .
H17 H 0.5032 0.3123 0.7124 0.048 Uiso 1 calc . .
C18 C 0.4498(13) 0.2539(5) 0.7085(10) 0.036(4) Uani 1 d . .
H18 H 0.3944 0.2610 0.7262 0.043 Uiso 1 calc . .
C19 C 0.2548(13) 0.1898(5) 0.6221(12) 0.036(5) Uani 1 d . .
C20 C 0.1661(16) 0.1951(6) 0.6398(13) 0.050(5) Uani 1 d . .
H20 H 0.1689 0.1923 0.7007 0.060 Uiso 1 calc . .
C21 C 0.0727(14) 0.2043(6) 0.5702(16) 0.065(7) Uani 1 d . .
H21 H 0.0136 0.2087 0.5843 0.078 Uiso 1 calc . .
C22 C 0.0667(16) 0.2069(6) 0.4835(14) 0.049(5) Uiso 1 d . .
H22 H 0.0012 0.2106 0.4367 0.059 Uiso 1 calc . .
C23 C 0.1512(18) 0.2044(5) 0.4591(12) 0.064(7) Uani 1 d . .
H23 H 0.1458 0.2087 0.3979 0.076 Uiso 1 calc . .
C24 C 0.2484(13) 0.1951(5) 0.5311(11) 0.043(5) Uani 1 d . .
H24 H 0.3082 0.1925 0.5171 0.052 Uiso 1 calc . .
C25 C 0.3656(13) 0.0196(5) 0.8289(10) 0.033(4) Uani 1 d . .
C26 C 0.3659(13) -0.0231(5) 0.8290(11) 0.040(5) Uani 1 d . .
H26 H 0.4259 -0.0373 0.8319 0.048 Uiso 1 calc . .
C27 C 0.2816(18) -0.0445(6) 0.8249(12) 0.051(6) Uani 1 d . .
H27 H 0.2836 -0.0734 0.8252 0.062 Uiso 1 calc . .
C28 C 0.1952(17) -0.0252(8) 0.8204(13) 0.063(6) Uani 1 d . .
H28 H 0.1360 -0.0403 0.8156 0.075 Uiso 1 calc . .
C29 C 0.1937(17) 0.0177(7) 0.8228(14) 0.066(6) Uani 1 d . .
H29 H 0.1337 0.0314 0.8213 0.079 Uiso 1 calc . .
C30 C 0.2778(14) 0.0396(5) 0.8273(12) 0.040(5) Uani 1 d . .
H30 H 0.2764 0.0684 0.8293 0.048 Uiso 1 calc . .
C31 C 0.5712(11) 0.0128(4) 0.8291(11) 0.027(4) Uani 1 d . .
C32 C 0.5701(14) 0.0008(5) 0.7442(12) 0.047(5) Uani 1 d . .
H32 H 0.5294 0.0149 0.6903 0.057 Uiso 1 calc . .
C33 C 0.6308(15) -0.0329(5) 0.7391(12) 0.049(5) Uani 1 d . .
H33 H 0.6302 -0.0418 0.6815 0.059 Uiso 1 calc . .
C34 C 0.6920(15) -0.0532(6) 0.8199(14) 0.055(6) Uani 1 d . .
H34 H 0.7314 -0.0761 0.8162 0.067 Uiso 1 calc . .
C35 C 0.6953(13) -0.0404(5) 0.9023(12) 0.039(5) Uani 1 d . .
H35 H 0.7383 -0.0537 0.9564 0.047 Uiso 1 calc . .
C36 C 0.6354(13) -0.0075(5) 0.9076(11) 0.039(5) Uani 1 d . .
H36 H 0.6380 0.0013 0.9658 0.047 Uiso 1 calc . .
C37 C 0.3044(13) 0.1013(4) 0.4927(11) 0.031(4) Uani 1 d . .
C38 C 0.4013(13) 0.1145(5) 0.4959(11) 0.043(5) Uani 1 d . .
H38 H 0.4604 0.1093 0.5490 0.051 Uiso 1 calc . .
C39 C 0.4116(14) 0.1352(5) 0.4216(12) 0.043(5) Uani 1 d . .
H39 H 0.4767 0.1445 0.4249 0.051 Uiso 1 calc . .
C40 C 0.3262(21) 0.1418(6) 0.3439(13) 0.060(6) Uani 1 d . .
H40 H 0.3329 0.1556 0.2935 0.072 Uiso 1 calc . .
C41 C 0.2311(17) 0.1286(6) 0.3385(11) 0.049(5) Uani 1 d . .
H41 H 0.1729 0.1338 0.2847 0.059 Uiso 1 calc . .
C42 C 0.2194(12) 0.1077(5) 0.4114(12) 0.038(4) Uani 1 d . .
H42 H 0.1540 0.0977 0.4058 0.045 Uiso 1 calc . .
C43 C 0.1619(12) 0.0760(5) 0.5810(11) 0.034(4) Uani 1 d . .
C44 C 0.0867(13) 0.0522(5) 0.5138(11) 0.039(5) Uani 1 d . .
H44 H 0.1072 0.0348 0.4757 0.047 Uiso 1 calc . .
C45 C -0.0148(14) 0.0536(5) 0.5026(13) 0.042(5) Uani 1 d . .
H45 H -0.0645 0.0391 0.4543 0.050 Uiso 1 calc . .
C46 C -0.0436(14) 0.0765(6) 0.5626(15) 0.057(6) Uani 1 d . .
H46 H -0.1132 0.0767 0.5569 0.068 Uiso 1 calc . .
C47 C 0.0291(14) 0.0998(6) 0.6327(14) 0.051(5) Uani 1 d . .
H47 H 0.0082 0.1159 0.6727 0.061 Uiso 1 calc . .
C48 C 0.1336(14) 0.0988(5) 0.6425(12) 0.043(5) Uani 1 d . .
H48 H 0.1836 0.1135 0.6903 0.051 Uiso 1 calc . .
C49 C 0.3144(11) 0.0221(4) 0.5668(9) 0.025(4) Uani 1 d . .
C50 C 0.2811(13) -0.0094(5) 0.6089(11) 0.038(4) Uiso 1 d . .
H50 H 0.2458 -0.0030 0.6482 0.046 Uiso 1 calc . .
C51 C 0.2991(13) -0.0506(5) 0.5939(11) 0.039(5) Uani 1 d . .
H51 H 0.2776 -0.0717 0.6240 0.047 Uiso 1 calc . .
C52 C 0.3485(13) -0.0599(5) 0.5347(12) 0.043(5) Uani 1 d . .
H52 H 0.3599 -0.0876 0.5240 0.052 Uiso 1 calc . .
C53 C 0.3818(13) -0.0291(5) 0.4905(12) 0.037(4) Uani 1 d . .
H53 H 0.4158 -0.0355 0.4502 0.045 Uiso 1 calc . .
C54 C 0.3636(14) 0.0106(5) 0.5077(12) 0.045(5) Uani 1 d . .
H54 H 0.3856 0.0314 0.4776 0.054 Uiso 1 calc . .
C55 C 0.6613(13) 0.1650(5) 1.0334(11) 0.041(5) Uani 1 d . .
H55A H 0.6386 0.1838 1.0711 0.049 Uiso 1 calc . .
H55B H 0.6909 0.1406 1.0705 0.049 Uiso 1 calc . .
C56 C 0.7428(14) 0.1858(5) 1.0057(11) 0.042(5) Uani 1 d . .
H56A H 0.8075 0.1880 1.0596 0.051 Uiso 1 calc . .
H56B H 0.7200 0.2136 0.9833 0.051 Uiso 1 calc . .
C57 C 0.4637(13) 0.1939(5) 0.9007(11) 0.037(4) Uani 1 d . .
H57A H 0.4445 0.2002 0.9537 0.044 Uiso 1 calc . .
H57B H 0.5019 0.2176 0.8912 0.044 Uiso 1 calc . .
C58 C 0.3635(12) 0.1892(5) 0.8145(11) 0.037(4) Uani 1 d . .
H58A H 0.3265 0.2155 0.8031 0.044 Uiso 1 calc . .
H58B H 0.3193 0.1688 0.8282 0.044 Uiso 1 calc . .
C59 C 0.4841(13) 0.1099(5) 0.9681(11) 0.037(4) Uani 1 d . .
H59A H 0.4965 0.1137 1.0337 0.045 Uiso 1 calc . .
H59B H 0.4095 0.1119 0.9332 0.045 Uiso 1 calc . .
C60 C 0.5225(12) 0.0674(5) 0.9533(10) 0.032(4) Uani 1 d . .
H60A H 0.4995 0.0471 0.9879 0.038 Uiso 1 calc . .
H60B H 0.5982 0.0675 0.9785 0.038 Uiso 1 calc . .
Cl1 Cl 0.6507(3) 0.10187(13) 0.7021(3) 0.0375(11) Uani 1 d . .
Cl2 Cl 0.2269(5) 0.2877(2) 0.7932(4) 0.077(2) Uani 1 d . .
Cl3 Cl 0.8882(8) -0.0107(3) 0.7070(6) 0.149(4) Uani 1 d . .
Cl4 Cl 0.9338(8) 0.0671(3) 0.7990(7) 0.151(4) Uani 1 d . .
O1 O 0.3416(12) 0.3570(5) 0.7337(10) 0.083(5) Uani 1 d . .
O2 O 0.0206(14) 0.3333(8) 0.6905(15) 0.141(9) Uani 1 d . .
O3 O 0.1699(26) 0.3216(10) 0.9581(21) 0.108(10) Uani 0.60 d P .
O3A O 0.2848(33) 0.2860(16) 1.0033(26) 0.107(15) Uani 0.40 d P .
O4 O -0.2794(24) 0.3674(8) 0.4265(19) 0.168(10) Uani 1 d . .
O5 O -0.1923(12) 0.3027(8) 0.5596(11) 0.133(9) Uani 1 d . .
C61 C 0.8381(28) 0.0343(9) 0.7344(23) 0.137(13) Uani 1 d . .
H61A H 0.7950 0.0482 0.6772 0.164 Uiso 1 calc . .
H61B H 0.7941 0.0274 0.7688 0.164 Uiso 1 calc . .
C62 C 0.4115(20) 0.3770(7) 0.8136(17) 0.097(9) Uani 1 d . .
C63 C 0.0371(24) 0.3700(7) 0.7329(19) 0.103(10) Uani 1 d . .
C64 C 0.2581(21) 0.3326(8) 1.0219(19) 0.098(9) Uani 1 d . .
C65 C -0.3577(20) 0.3520(11) 0.3924(19) 0.110(12) Uani 1 d . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P1 Pt1 P2 87.9(2) . . ?
P1 Pt1 Cl1 170.6(2) . . ?
P2 Pt1 Cl1 100.4(2) . . ?
P1 Pt1 Pt2 88.86(12) . . ?
P2 Pt1 Pt2 176.63(12) . . ?
Cl1 Pt1 Pt2 82.93(11) . . ?
P4 Pt2 P3 144.40(15) . . ?
P4 Pt2 P5 104.91(15) . . ?
P3 Pt2 P5 102.44(14) . . ?
P4 Pt2 Pt1 81.05(11) . . ?
P3 Pt2 Pt1 84.02(10) . . ?
P5 Pt2 Pt1 154.50(11) . . ?
C57 P1 C59 106.3(8) . . ?
C57 P1 C55 106.3(8) . . ?
C59 P1 C55 105.7(8) . . ?
C57 P1 Pt1 115.4(6) . . ?
C59 P1 Pt1 114.5(5) . . ?
C55 P1 Pt1 108.0(6) . . ?
C1 P2 C7 101.5(8) . . ?
C1 P2 C56 104.8(8) . . ?
C7 P2 C56 105.2(7) . . ?
C1 P2 Pt1 123.5(5) . . ?
C7 P2 Pt1 114.2(6) . . ?
C56 P2 Pt1 106.2(6) . . ?
C13 P3 C58 103.2(7) . . ?
C13 P3 C19 100.6(7) . . ?
C58 P3 C19 99.1(8) . . ?
C13 P3 Pt2 124.5(5) . . ?
C58 P3 Pt2 105.9(5) . . ?
C19 P3 Pt2 119.8(5) . . ?
C31 P4 C25 102.3(7) . . ?
C31 P4 C60 102.8(7) . . ?
C25 P4 C60 97.5(7) . . ?
C31 P4 Pt2 123.6(5) . . ?
C25 P4 Pt2 111.8(5) . . ?
C60 P4 Pt2 115.1(5) . . ?
C49 P5 C37 101.2(7) . . ?
C49 P5 C43 101.7(7) . . ?
C37 P5 C43 106.6(7) . . ?
C49 P5 Pt2 117.9(5) . . ?
C37 P5 Pt2 107.9(5) . . ?
C43 P5 Pt2 119.6(6) . . ?
C2 C1 C6 117.2(18) . . ?
C2 C1 P2 119.5(13) . . ?
C6 C1 P2 123.3(15) . . ?
C1 C2 C3 121.8(18) . . ?
C4 C3 C2 119.5(21) . . ?
C3 C4 C5 120.8(18) . . ?
C6 C5 C4 119.8(19) . . ?
C5 C6 C1 120.9(20) . . ?
C8 C7 C12 117.8(16) . . ?
C8 C7 P2 122.2(13) . . ?
C12 C7 P2 120.0(13) . . ?
C7 C8 C9 118.9(20) . . ?
C10 C9 C8 123.8(22) . . ?
C9 C10 C11 120.0(20) . . ?
C10 C11 C12 117.5(19) . . ?
C7 C12 C11 122.0(19) . . ?
C18 C13 C14 115.4(15) . . ?
C18 C13 P3 121.8(13) . . ?
C14 C13 P3 122.9(12) . . ?
C15 C14 C13 123.0(16) . . ?
C16 C15 C14 119.3(18) . . ?
C15 C16 C17 120.6(17) . . ?
C18 C17 C16 118.2(15) . . ?
C13 C18 C17 123.0(16) . . ?
C20 C19 C24 117.8(16) . . ?
C20 C19 P3 125.4(14) . . ?
C24 C19 P3 116.7(14) . . ?
C19 C20 C21 121.5(19) . . ?
C22 C21 C20 120.0(21) . . ?
C21 C22 C23 123.0(19) . . ?
C22 C23 C24 117.1(18) . . ?
C19 C24 C23 120.3(18) . . ?
C30 C25 C26 118.3(16) . . ?
C30 C25 P4 117.6(12) . . ?
C26 C25 P4 124.0(14) . . ?
C27 C26 C25 121.0(17) . . ?
C28 C27 C26 120.8(18) . . ?
C27 C28 C29 119.4(19) . . ?
C30 C29 C28 120.5(20) . . ?
C29 C30 C25 120.0(17) . . ?
C32 C31 C36 119.0(15) . . ?
C32 C31 P4 117.0(12) . . ?
C36 C31 P4 123.7(13) . . ?
C31 C32 C33 119.1(15) . . ?
C34 C33 C32 119.7(16) . . ?
C35 C34 C33 120.8(16) . . ?
C34 C35 C36 119.6(16) . . ?
C35 C36 C31 121.6(16) . . ?
C42 C37 C38 118.0(15) . . ?
C42 C37 P5 123.9(13) . . ?
C38 C37 P5 118.1(12) . . ?
C39 C38 C37 120.9(15) . . ?
C40 C39 C38 119.4(17) . . ?
C39 C40 C41 120.8(17) . . ?
C40 C41 C42 120.7(17) . . ?
C41 C42 C37 120.1(17) . . ?
C48 C43 C44 119.2(16) . . ?
C48 C43 P5 118.9(12) . . ?
C44 C43 P5 121.9(14) . . ?
C45 C44 C43 121.9(17) . . ?
C44 C45 C46 119.1(16) . . ?
C45 C46 C47 121.1(17) . . ?
C46 C47 C48 119.4(17) . . ?
C43 C48 C47 119.2(15) . . ?
C50 C49 C54 116.7(15) . . ?
C50 C49 P5 120.1(13) . . ?
C54 C49 P5 123.2(12) . . ?
C49 C50 C51 121.1(16) . . ?
C52 C51 C50 119.3(16) . . ?
C51 C52 C53 121.1(15) . . ?
C54 C53 C52 117.7(17) . . ?
C53 C54 C49 124.1(16) . . ?
C56 C55 P1 110.3(11) . . ?
C55 C56 P2 110.1(11) . . ?
C58 C57 P1 116.3(11) . . ?
C57 C58 P3 115.6(12) . . ?
C60 C59 P1 110.8(11) . . ?
C59 C60 P4 113.5(10) . . ?
Cl4 C61 Cl3 111.9(20) . . ?
O3 C64 O3A 79.7(26) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 P1 2.183(4) . ?
Pt1 P2 2.266(4) . ?
Pt1 Cl1 2.395(4) . ?
Pt1 Pt2 2.616(2) . ?
Pt2 P4 2.293(4) . ?
Pt2 P3 2.315(4) . ?
Pt2 P5 2.345(4) . ?
P1 C57 1.81(2) . ?
P1 C59 1.82(2) . ?
P1 C55 1.83(2) . ?
P2 C1 1.80(2) . ?
P2 C7 1.82(2) . ?
P2 C56 1.82(2) . ?
P3 C13 1.80(2) . ?
P3 C58 1.85(2) . ?
P3 C19 1.85(2) . ?
P4 C31 1.83(2) . ?
P4 C25 1.85(2) . ?
P4 C60 1.86(2) . ?
P5 C49 1.82(2) . ?
P5 C37 1.82(2) . ?
P5 C43 1.83(2) . ?
C1 C2 1.39(2) . ?
C1 C6 1.41(3) . ?
C2 C3 1.41(3) . ?
C3 C4 1.34(3) . ?
C4 C5 1.40(3) . ?
C5 C6 1.38(3) . ?
C7 C8 1.37(2) . ?
C7 C12 1.39(3) . ?
C8 C9 1.38(3) . ?
C9 C10 1.30(3) . ?
C10 C11 1.39(3) . ?
C11 C12 1.39(3) . ?
C13 C18 1.38(2) . ?
C13 C14 1.40(2) . ?
C14 C15 1.38(2) . ?
C15 C16 1.35(3) . ?
C16 C17 1.40(3) . ?
C17 C18 1.39(2) . ?
C19 C20 1.37(3) . ?
C19 C24 1.40(2) . ?
C20 C21 1.38(3) . ?
C21 C22 1.33(3) . ?
C22 C23 1.37(3) . ?
C23 C24 1.43(2) . ?
C25 C30 1.38(2) . ?
C25 C26 1.39(2) . ?
C26 C27 1.35(2) . ?
C27 C28 1.34(3) . ?
C28 C29 1.40(3) . ?
C29 C30 1.35(3) . ?
C31 C32 1.38(2) . ?
C31 C36 1.39(2) . ?
C32 C33 1.41(2) . ?
C33 C34 1.40(2) . ?
C34 C35 1.34(2) . ?
C35 C36 1.38(2) . ?
C37 C42 1.39(2) . ?
C37 C38 1.40(2) . ?
C38 C39 1.39(2) . ?
C39 C40 1.36(3) . ?
C40 C41 1.36(3) . ?
C41 C42 1.39(2) . ?
C43 C48 1.38(2) . ?
C43 C44 1.41(2) . ?
C44 C45 1.36(2) . ?
C45 C46 1.37(3) . ?
C46 C47 1.40(3) . ?
C47 C48 1.41(2) . ?
C49 C50 1.39(2) . ?
C49 C54 1.39(2) . ?
C50 C51 1.40(2) . ?
C51 C52 1.38(2) . ?
C52 C53 1.39(2) . ?
C53 C54 1.36(2) . ?
C55 C56 1.52(2) . ?
C57 C58 1.54(2) . ?
C59 C60 1.53(2) . ?
Cl3 C61 1.75(3) . ?
Cl4 C61 1.71(3) . ?
O1 C62 1.42(3) . ?
O2 C63 1.35(3) . ?
O3 C64 1.31(4) . ?
O3A C64 1.61(5) . ?
O4 C65 1.14(3) . ?
