#------------------------------------------------------------------------------
#$Date: 2016-03-25 13:08:46 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179828 $
#$URL: svn://www.crystallography.net/cod/cif/7/01/24/7012486.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7012486
loop_
_publ_author_name
'Li, Qing-Shan'
'Xu, Feng-Bo'
'Cui, Da-Jun'
'Yu, Kai'
'Zeng, Xian-Shun'
'Leng, Xue-Bing'
'Song, Hai-Bin'
'Zhang, Zheng-Zhi'
_publ_section_title
;
 Heterobimetallic Pt(ii)--M(i) (M = Cu, Ag) eight-membered
 macrocyclic complexes with large-bite P,N-ligand bridgesElectronic
 supplementary information (ESI) available: UV-vis absorption spectra
 and the fluorescence excitation and emission spectra of complexes 3
 and 5. See http://www.rsc.org/suppdata/dt/b2/b211301p/
;
_journal_issue                   8
_journal_name_full               'Dalton Transactions'
_journal_page_first              1551
_journal_paper_doi               10.1039/b211301p
_journal_year                    2003
_chemical_formula_sum            'C66 H60 Cl2 Cu2 N4 O10 P2 Pt'
_chemical_formula_weight         1524.19
_chemical_name_systematic
; 
? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                108.946(6)
_cell_angle_beta                 97.064(5)
_cell_angle_gamma                98.108(6)
_cell_formula_units_Z            1
_cell_length_a                   10.585(4)
_cell_length_b                   12.007(4)
_cell_length_c                   13.292(5)
_cell_measurement_temperature    293(2)
_cell_volume                     1555.9(10)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SHELXTL'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.946
_diffrn_measured_fraction_theta_max 0.946
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0254
_diffrn_reflns_av_sigmaI/netI    0.0752
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       6
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            4708
_diffrn_reflns_theta_full        23.34
_diffrn_reflns_theta_max         23.34
_diffrn_reflns_theta_min         1.65
_exptl_absorpt_coefficient_mu    3.119
_exptl_absorpt_correction_T_max  0.8349
_exptl_absorpt_correction_T_min  0.5743
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_density_diffrn    1.627
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             764
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.06
_refine_diff_density_max         1.360
_refine_diff_density_min         -1.336
_refine_diff_density_rms         0.180
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.071
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     394
_refine_ls_number_reflns         4275
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.071
_refine_ls_R_factor_all          0.0559
_refine_ls_R_factor_gt           0.0429
_refine_ls_shift/su_max          0.007
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0500P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0910
_refine_ls_wR_factor_ref         0.1068
_reflns_number_gt                3621
_reflns_number_total             4275
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b211301p.txt
_cod_data_source_block           complex_4'
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from
2010-06-29.

'_exptl_absorpt_correction_type' value 'MULTI-SCAN' changed
to 'multi-scan' according to
'/home/saulius/struct/CIF-dictionaries/cif_core.dic' dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_cell_volume        1555.9(9)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7012486
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Cu1 Cu 0.53711(9) 0.79184(9) 0.53247(8) 0.0427(3) Uani 1 1 d . . .
Pt1 Pt 0.5000 0.5000 0.5000 0.02740(17) Uani 1 2 d S . .
P1 P 0.49086(19) 0.59346(18) 0.67964(15) 0.0301(5) Uani 1 1 d . . .
Cl1 Cl 0.7042(3) 0.9126(3) 0.2805(3) 0.0832(9) Uani 1 1 d . . .
O1 O 0.8162(9) 0.9268(8) 0.3497(8) 0.137(4) Uani 1 1 d . . .
O2 O 0.6796(10) 1.0264(8) 0.2840(7) 0.118(3) Uani 1 1 d . . .
O3 O 0.7124(18) 0.8448(12) 0.1805(9) 0.239(9) Uani 1 1 d . . .
O4 O 0.6052(12) 0.8601(13) 0.3143(18) 0.257(10) Uani 1 1 d . . .
O5 O 0.5619(7) 0.9742(6) 0.5923(7) 0.085(2) Uani 1 1 d . . .
N1 N 0.6326(6) 0.8285(6) 0.7891(5) 0.0382(17) Uani 1 1 d . . .
N2 N 0.7016(6) 0.7884(6) 0.6246(5) 0.0422(18) Uani 1 1 d . . .
C1 C 0.6603(10) 0.8789(7) 0.9077(6) 0.050(2) Uani 1 1 d . . .
H1A H 0.7351 0.8510 0.9338 0.060 Uiso 1 1 calc R . .
H1B H 0.5870 0.8487 0.9351 0.060 Uiso 1 1 calc R . .
C2 C 0.6866(9) 1.0138(8) 0.9525(6) 0.045(2) Uani 1 1 d . . .
C3 C 0.7886(11) 1.0756(9) 1.0352(8) 0.077(4) Uani 1 1 d . . .
H3A H 0.8440 1.0338 1.0615 0.092 Uiso 1 1 calc R . .
C4 C 0.8102(12) 1.1985(10) 1.0797(9) 0.079(4) Uani 1 1 d . . .
H4A H 0.8806 1.2389 1.1351 0.095 Uiso 1 1 calc R . .
C5 C 0.7318(11) 1.2602(9) 1.0445(8) 0.070(3) Uani 1 1 d . . .
H5A H 0.7465 1.3433 1.0763 0.084 Uiso 1 1 calc R . .
C6 C 0.6283(10) 1.2012(9) 0.9608(8) 0.062(3) Uani 1 1 d . . .
H6A H 0.5735 1.2438 0.9350 0.075 Uiso 1 1 calc R . .
C7 C 0.6079(9) 1.0783(8) 0.9166(8) 0.054(3) Uani 1 1 d . . .
H7A H 0.5382 1.0381 0.8604 0.065 Uiso 1 1 calc R . .
C8 C 0.7325(8) 0.8317(7) 0.7325(6) 0.036(2) Uani 1 1 d . . .
C9 C 0.8623(9) 0.8745(8) 0.7845(8) 0.050(2) Uani 1 1 d . . .
H9A H 0.8833 0.9090 0.8594 0.060 Uiso 1 1 calc R . .
C10 C 0.9576(9) 0.8645(9) 0.7227(8) 0.056(3) Uani 1 1 d . . .
H10A H 1.0442 0.8927 0.7560 0.068 Uiso 1 1 calc R . .
C11 C 0.9269(9) 0.8140(9) 0.6142(8) 0.061(3) Uani 1 1 d . . .
H11A H 0.9915 0.8040 0.5723 0.073 Uiso 1 1 calc R . .
C12 C 0.7967(9) 0.7772(9) 0.5662(7) 0.056(3) Uani 1 1 d . . .
H12A H 0.7749 0.7437 0.4912 0.067 Uiso 1 1 calc R . .
C13 C 0.5023(7) 0.7615(7) 0.7381(6) 0.037(2) Uani 1 1 d . . .
H13A H 0.4708 0.7894 0.6806 0.044 Uiso 1 1 calc R . .
H13B H 0.4457 0.7787 0.7910 0.044 Uiso 1 1 calc R . .
C14 C 0.6057(8) 0.5758(7) 0.7844(6) 0.037(2) Uani 1 1 d . . .
C15 C 0.7339(8) 0.5747(7) 0.7702(7) 0.042(2) Uani 1 1 d . . .
H15A H 0.7568 0.5697 0.7038 0.051 Uiso 1 1 calc R . .
C16 C 0.8263(9) 0.5812(9) 0.8555(8) 0.060(3) Uani 1 1 d . . .
H16A H 0.9117 0.5814 0.8455 0.072 Uiso 1 1 calc R . .
C17 C 0.7976(10) 0.5870(9) 0.9519(8) 0.066(3) Uani 1 1 d . . .
H17A H 0.8617 0.5901 1.0078 0.079 Uiso 1 1 calc R . .
C18 C 0.6716(11) 0.5884(9) 0.9670(7) 0.065(3) Uani 1 1 d . . .
H18A H 0.6505 0.5926 1.0338 0.078 Uiso 1 1 calc R . .
C19 C 0.5761(9) 0.5837(8) 0.8846(7) 0.046(2) Uani 1 1 d . . .
H19A H 0.4915 0.5857 0.8963 0.056 Uiso 1 1 calc R . .
C20 C 0.3277(8) 0.5357(7) 0.6927(6) 0.036(2) Uani 1 1 d . . .
C21 C 0.3007(9) 0.4340(8) 0.7213(7) 0.045(2) Uani 1 1 d . . .
H21A H 0.3678 0.3979 0.7397 0.055 Uiso 1 1 calc R . .
C22 C 0.1743(10) 0.3871(9) 0.7223(8) 0.060(3) Uani 1 1 d . . .
H22A H 0.1569 0.3216 0.7446 0.073 Uiso 1 1 calc R . .
C23 C 0.0759(10) 0.4356(9) 0.6911(8) 0.064(3) Uani 1 1 d . . .
H23A H -0.0090 0.4019 0.6905 0.076 Uiso 1 1 calc R . .
C24 C 0.0991(9) 0.5337(10) 0.6602(8) 0.061(3) Uani 1 1 d . . .
H24A H 0.0303 0.5666 0.6396 0.073 Uiso 1 1 calc R . .
C25 C 0.2262(8) 0.5847(8) 0.6596(7) 0.049(2) Uani 1 1 d . . .
H25A H 0.2423 0.6504 0.6374 0.059 Uiso 1 1 calc R . .
C26 C 0.4271(7) 0.6278(7) 0.4592(6) 0.034(2) Uani 1 1 d . . .
C27 C 0.3724(7) 0.6994(7) 0.4297(6) 0.0330(19) Uani 1 1 d . . .
C28 C 0.2782(7) 0.7523(7) 0.3792(7) 0.035(2) Uani 1 1 d . . .
C29 C 0.2613(8) 0.7297(8) 0.2688(7) 0.048(2) Uani 1 1 d . . .
H29A H 0.3121 0.6832 0.2270 0.058 Uiso 1 1 calc R . .
C30 C 0.1686(9) 0.7767(9) 0.2208(8) 0.062(3) Uani 1 1 d . . .
H30A H 0.1554 0.7598 0.1465 0.074 Uiso 1 1 calc R . .
C31 C 0.0968(9) 0.8475(9) 0.2825(9) 0.061(3) Uani 1 1 d . . .
H31A H 0.0347 0.8788 0.2501 0.073 Uiso 1 1 calc R . .
C32 C 0.1152(8) 0.8723(8) 0.3904(9) 0.057(3) Uani 1 1 d . . .
H32A H 0.0659 0.9212 0.4316 0.068 Uiso 1 1 calc R . .
C33 C 0.2062(8) 0.8264(7) 0.4405(8) 0.050(2) Uani 1 1 d . . .
H33A H 0.2189 0.8452 0.5151 0.060 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C26 Cu1 C27 36.0(3) . . ?
C26 Cu1 N2 111.9(3) . . ?
C27 Cu1 N2 147.9(3) . . ?
C26 Cu1 O5 152.3(3) . . ?
C27 Cu1 O5 118.1(3) . . ?
N2 Cu1 O5 93.7(3) . . ?
C26 Pt1 C26 180.0(4) 2_666 . ?
C26 Pt1 P1 88.4(2) 2_666 . ?
C26 Pt1 P1 91.6(2) . . ?
C26 Pt1 P1 91.6(2) 2_666 2_666 ?
C26 Pt1 P1 88.4(2) . 2_666 ?
P1 Pt1 P1 180.0 . 2_666 ?
C20 P1 C14 108.5(4) . . ?
C20 P1 C13 102.5(3) . . ?
C14 P1 C13 99.0(3) . . ?
C20 P1 Pt1 104.5(2) . . ?
C14 P1 Pt1 119.9(3) . . ?
C13 P1 Pt1 120.9(3) . . ?
O3 Cl1 O4 110.1(11) . . ?
O3 Cl1 O1 110.1(8) . . ?
O4 Cl1 O1 108.7(10) . . ?
O3 Cl1 O2 111.2(7) . . ?
O4 Cl1 O2 107.1(8) . . ?
O1 Cl1 O2 109.5(6) . . ?
C8 N1 C13 122.7(6) . . ?
C8 N1 C1 119.5(7) . . ?
C13 N1 C1 117.2(7) . . ?
C8 N2 C12 119.2(7) . . ?
C8 N2 Cu1 127.3(6) . . ?
C12 N2 Cu1 109.5(6) . . ?
N1 C1 C2 113.7(7) . . ?
N1 C1 H1A 108.8 . . ?
C2 C1 H1A 108.8 . . ?
N1 C1 H1B 108.8 . . ?
C2 C1 H1B 108.8 . . ?
H1A C1 H1B 107.7 . . ?
C7 C2 C3 117.7(9) . . ?
C7 C2 C1 121.8(8) . . ?
C3 C2 C1 120.4(9) . . ?
C2 C3 C4 120.9(10) . . ?
C2 C3 H3A 119.6 . . ?
C4 C3 H3A 119.6 . . ?
C5 C4 C3 120.8(10) . . ?
C5 C4 H4A 119.6 . . ?
C3 C4 H4A 119.6 . . ?
C4 C5 C6 120.1(10) . . ?
C4 C5 H5A 119.9 . . ?
C6 C5 H5A 119.9 . . ?
C7 C6 C5 118.6(10) . . ?
C7 C6 H6A 120.7 . . ?
C5 C6 H6A 120.7 . . ?
C2 C7 C6 121.9(9) . . ?
C2 C7 H7A 119.0 . . ?
C6 C7 H7A 119.0 . . ?
N2 C8 N1 117.2(7) . . ?
N2 C8 C9 120.7(8) . . ?
N1 C8 C9 122.0(8) . . ?
C10 C9 C8 118.7(9) . . ?
C10 C9 H9A 120.6 . . ?
C8 C9 H9A 120.6 . . ?
C11 C10 C9 120.5(9) . . ?
C11 C10 H10A 119.8 . . ?
C9 C10 H10A 119.8 . . ?
C10 C11 C12 118.6(10) . . ?
C10 C11 H11A 120.7 . . ?
C12 C11 H11A 120.7 . . ?
N2 C12 C11 122.0(9) . . ?
N2 C12 H12A 119.0 . . ?
C11 C12 H12A 119.0 . . ?
N1 C13 P1 114.1(5) . . ?
N1 C13 H13A 108.7 . . ?
P1 C13 H13A 108.7 . . ?
N1 C13 H13B 108.7 . . ?
P1 C13 H13B 108.7 . . ?
H13A C13 H13B 107.6 . . ?
C19 C14 C15 118.3(7) . . ?
C19 C14 P1 122.0(6) . . ?
C15 C14 P1 118.8(6) . . ?
C16 C15 C14 119.4(8) . . ?
C16 C15 H15A 120.3 . . ?
C14 C15 H15A 120.3 . . ?
C17 C16 C15 122.4(10) . . ?
C17 C16 H16A 118.8 . . ?
C15 C16 H16A 118.8 . . ?
C16 C17 C18 118.8(9) . . ?
C16 C17 H17A 120.6 . . ?
C18 C17 H17A 120.6 . . ?
C17 C18 C19 120.9(9) . . ?
C17 C18 H18A 119.5 . . ?
C19 C18 H18A 119.5 . . ?
C18 C19 C14 120.1(9) . . ?
C18 C19 H19A 119.9 . . ?
C14 C19 H19A 119.9 . . ?
C25 C20 C21 119.4(8) . . ?
C25 C20 P1 118.6(7) . . ?
C21 C20 P1 121.4(6) . . ?
C22 C21 C20 119.9(9) . . ?
C22 C21 H21A 120.0 . . ?
C20 C21 H21A 120.0 . . ?
C23 C22 C21 120.5(10) . . ?
C23 C22 H22A 119.8 . . ?
C21 C22 H22A 119.8 . . ?
C22 C23 C24 120.9(9) . . ?
C22 C23 H23A 119.5 . . ?
C24 C23 H23A 119.5 . . ?
C23 C24 C25 120.2(9) . . ?
C23 C24 H24A 119.9 . . ?
C25 C24 H24A 119.9 . . ?
C20 C25 C24 119.0(9) . . ?
C20 C25 H25A 120.5 . . ?
C24 C25 H25A 120.5 . . ?
C27 C26 Pt1 174.4(7) . . ?
C27 C26 Cu1 72.1(5) . . ?
Pt1 C26 Cu1 113.4(4) . . ?
C26 C27 C28 163.1(8) . . ?
C26 C27 Cu1 71.9(5) . . ?
C28 C27 Cu1 124.9(6) . . ?
C33 C28 C29 119.1(8) . . ?
C33 C28 C27 120.7(8) . . ?
C29 C28 C27 120.1(8) . . ?
C28 C29 C30 119.8(9) . . ?
C28 C29 H29A 120.1 . . ?
C30 C29 H29A 120.1 . . ?
C31 C30 C29 120.0(9) . . ?
C31 C30 H30A 120.0 . . ?
C29 C30 H30A 120.0 . . ?
C32 C31 C30 120.4(9) . . ?
C32 C31 H31A 119.8 . . ?
C30 C31 H31A 119.8 . . ?
C31 C32 C33 121.0(9) . . ?
C31 C32 H32A 119.5 . . ?
C33 C32 H32A 119.5 . . ?
C32 C33 C28 119.5(9) . . ?
C32 C33 H33A 120.2 . . ?
C28 C33 H33A 120.2 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Cu1 C26 2.003(7) . ?
Cu1 C27 2.005(7) . ?
Cu1 N2 2.016(6) . ?
Cu1 O5 2.038(7) . ?
Pt1 C26 2.003(8) 2_666 ?
Pt1 C26 2.003(8) . ?
Pt1 P1 2.306(2) . ?
Pt1 P1 2.306(2) 2_666 ?
P1 C20 1.818(8) . ?
P1 C14 1.819(8) . ?
P1 C13 1.892(8) . ?
Cl1 O3 1.336(11) . ?
Cl1 O4 1.346(13) . ?
Cl1 O1 1.361(8) . ?
Cl1 O2 1.413(8) . ?
N1 C8 1.374(10) . ?
N1 C13 1.453(9) . ?
N1 C1 1.468(10) . ?
N2 C8 1.336(10) . ?
N2 C12 1.341(11) . ?
C1 C2 1.504(12) . ?
C1 H1A 0.9700 . ?
C1 H1B 0.9700 . ?
C2 C7 1.359(12) . ?
C2 C3 1.370(12) . ?
C3 C4 1.372(14) . ?
C3 H3A 0.9300 . ?
C4 C5 1.326(14) . ?
C4 H4A 0.9300 . ?
C5 C6 1.382(13) . ?
C5 H5A 0.9300 . ?
C6 C7 1.373(13) . ?
C6 H6A 0.9300 . ?
C7 H7A 0.9300 . ?
C8 C9 1.402(11) . ?
C9 C10 1.372(13) . ?
C9 H9A 0.9300 . ?
C10 C11 1.348(13) . ?
C10 H10A 0.9300 . ?
C11 C12 1.389(12) . ?
C11 H11A 0.9300 . ?
C12 H12A 0.9300 . ?
C13 H13A 0.9700 . ?
C13 H13B 0.9700 . ?
C14 C19 1.382(11) . ?
C14 C15 1.394(11) . ?
C15 C16 1.377(11) . ?
C15 H15A 0.9300 . ?
C16 C17 1.335(13) . ?
C16 H16A 0.9300 . ?
C17 C18 1.374(14) . ?
C17 H17A 0.9300 . ?
C18 C19 1.377(12) . ?
C18 H18A 0.9300 . ?
C19 H19A 0.9300 . ?
C20 C25 1.387(11) . ?
C20 C21 1.396(12) . ?
C21 C22 1.379(12) . ?
C21 H21A 0.9300 . ?
C22 C23 1.349(13) . ?
C22 H22A 0.9300 . ?
C23 C24 1.368(14) . ?
C23 H23A 0.9300 . ?
C24 C25 1.399(13) . ?
C24 H24A 0.9300 . ?
C25 H25A 0.9300 . ?
C26 C27 1.238(10) . ?
C27 C28 1.463(10) . ?
C28 C33 1.382(11) . ?
C28 C29 1.387(11) . ?
C29 C30 1.387(12) . ?
C29 H29A 0.9300 . ?
C30 C31 1.362(14) . ?
C30 H30A 0.9300 . ?
C31 C32 1.349(13) . ?
C31 H31A 0.9300 . ?
C32 C33 1.381(12) . ?
C32 H32A 0.9300 . ?
C33 H33A 0.9300 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C26 Pt1 P1 C20 -93.1(4) 2_666 . . . ?
C26 Pt1 P1 C20 86.9(4) . . . . ?
P1 Pt1 P1 C20 -154(100) 2_666 . . . ?
C26 Pt1 P1 C14 28.7(4) 2_666 . . . ?
C26 Pt1 P1 C14 -151.3(4) . . . . ?
P1 Pt1 P1 C14 -33(100) 2_666 . . . ?
C26 Pt1 P1 C13 152.3(4) 2_666 . . . ?
C26 Pt1 P1 C13 -27.7(4) . . . . ?
P1 Pt1 P1 C13 91(100) 2_666 . . . ?
C26 Cu1 N2 C8 -110.5(7) . . . . ?
C27 Cu1 N2 C8 -112.8(8) . . . . ?
O5 Cu1 N2 C8 58.8(8) . . . . ?
C26 Cu1 N2 C12 92.1(6) . . . . ?
C27 Cu1 N2 C12 89.8(8) . . . . ?
O5 Cu1 N2 C12 -98.5(6) . . . . ?
C8 N1 C1 C2 75.5(10) . . . . ?
C13 N1 C1 C2 -113.4(8) . . . . ?
N1 C1 C2 C7 48.0(12) . . . . ?
N1 C1 C2 C3 -134.9(10) . . . . ?
C7 C2 C3 C4 -0.1(16) . . . . ?
C1 C2 C3 C4 -177.2(10) . . . . ?
C2 C3 C4 C5 0.8(19) . . . . ?
C3 C4 C5 C6 -1.2(19) . . . . ?
C4 C5 C6 C7 0.9(16) . . . . ?
C3 C2 C7 C6 -0.2(15) . . . . ?
C1 C2 C7 C6 176.9(9) . . . . ?
C5 C6 C7 C2 -0.2(15) . . . . ?
C12 N2 C8 N1 -172.5(8) . . . . ?
Cu1 N2 C8 N1 32.1(11) . . . . ?
C12 N2 C8 C9 5.3(12) . . . . ?
Cu1 N2 C8 C9 -150.1(7) . . . . ?
C13 N1 C8 N2 11.6(11) . . . . ?
C1 N1 C8 N2 -177.8(7) . . . . ?
C13 N1 C8 C9 -166.2(8) . . . . ?
C1 N1 C8 C9 4.4(12) . . . . ?
N2 C8 C9 C10 -3.8(13) . . . . ?
N1 C8 C9 C10 173.9(8) . . . . ?
C8 C9 C10 C11 -0.3(14) . . . . ?
C9 C10 C11 C12 2.7(15) . . . . ?
C8 N2 C12 C11 -2.8(14) . . . . ?
Cu1 N2 C12 C11 156.6(8) . . . . ?
C10 C11 C12 N2 -1.2(16) . . . . ?
C8 N1 C13 P1 64.5(9) . . . . ?
C1 N1 C13 P1 -106.3(7) . . . . ?
C20 P1 C13 N1 149.7(6) . . . . ?
C14 P1 C13 N1 38.4(6) . . . . ?
Pt1 P1 C13 N1 -94.6(6) . . . . ?
C20 P1 C14 C19 -32.5(8) . . . . ?
C13 P1 C14 C19 74.0(7) . . . . ?
Pt1 P1 C14 C19 -152.3(6) . . . . ?
C20 P1 C14 C15 158.6(6) . . . . ?
C13 P1 C14 C15 -94.9(7) . . . . ?
Pt1 P1 C14 C15 38.8(7) . . . . ?
C19 C14 C15 C16 0.1(12) . . . . ?
P1 C14 C15 C16 169.5(7) . . . . ?
C14 C15 C16 C17 0.8(14) . . . . ?
C15 C16 C17 C18 -0.9(16) . . . . ?
C16 C17 C18 C19 0.1(16) . . . . ?
C17 C18 C19 C14 0.9(15) . . . . ?
C15 C14 C19 C18 -1.0(13) . . . . ?
P1 C14 C19 C18 -169.9(7) . . . . ?
C14 P1 C20 C25 151.1(6) . . . . ?
C13 P1 C20 C25 47.1(7) . . . . ?
Pt1 P1 C20 C25 -79.9(6) . . . . ?
C14 P1 C20 C21 -37.5(7) . . . . ?
C13 P1 C20 C21 -141.6(7) . . . . ?
Pt1 P1 C20 C21 91.5(7) . . . . ?
C25 C20 C21 C22 -3.6(12) . . . . ?
P1 C20 C21 C22 -174.9(7) . . . . ?
C20 C21 C22 C23 3.0(14) . . . . ?
C21 C22 C23 C24 -1.5(15) . . . . ?
C22 C23 C24 C25 0.6(16) . . . . ?
C21 C20 C25 C24 2.7(12) . . . . ?
P1 C20 C25 C24 174.3(7) . . . . ?
C23 C24 C25 C20 -1.3(14) . . . . ?
C26 Pt1 C26 C27 82(100) 2_666 . . . ?
P1 Pt1 C26 C27 -110(7) . . . . ?
P1 Pt1 C26 C27 70(7) 2_666 . . . ?
C26 Pt1 C26 Cu1 -109(100) 2_666 . . . ?
P1 Pt1 C26 Cu1 60.3(3) . . . . ?
P1 Pt1 C26 Cu1 -119.7(3) 2_666 . . . ?
N2 Cu1 C26 C27 -177.9(5) . . . . ?
O5 Cu1 C26 C27 25.5(10) . . . . ?
C27 Cu1 C26 Pt1 -179.0(8) . . . . ?
N2 Cu1 C26 Pt1 3.1(5) . . . . ?
O5 Cu1 C26 Pt1 -153.4(6) . . . . ?
Pt1 C26 C27 C28 -5(9) . . . . ?
Cu1 C26 C27 C28 -175(3) . . . . ?
Pt1 C26 C27 Cu1 170(7) . . . . ?
N2 Cu1 C27 C26 3.6(9) . . . . ?
O5 Cu1 C27 C26 -166.9(5) . . . . ?
C26 Cu1 C27 C28 178.2(10) . . . . ?
N2 Cu1 C27 C28 -178.2(6) . . . . ?
O5 Cu1 C27 C28 11.3(8) . . . . ?
C26 C27 C28 C33 107(3) . . . . ?
Cu1 C27 C28 C33 -67.5(10) . . . . ?
C26 C27 C28 C29 -74(3) . . . . ?
Cu1 C27 C28 C29 111.7(8) . . . . ?
C33 C28 C29 C30 -3.1(13) . . . . ?
C27 C28 C29 C30 177.7(8) . . . . ?
C28 C29 C30 C31 1.8(14) . . . . ?
C29 C30 C31 C32 0.0(15) . . . . ?
C30 C31 C32 C33 -0.4(15) . . . . ?
C31 C32 C33 C28 -1.0(14) . . . . ?
C29 C28 C33 C32 2.7(13) . . . . ?
C27 C28 C33 C32 -178.1(8) . . . . ?
