#------------------------------------------------------------------------------
#$Date: 2019-03-05 10:52:05 +0200 (Tue, 05 Mar 2019) $
#$Revision: 213973 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/01/27/7012714.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7012714
loop_
_publ_author_name
'Ouyang, Xing-Mei'
'Liu, De-Jun'
'Okamura, Taka-aki'
'Bu, Hong-Wei'
'Sun, Wei-Yin'
'Tang, Wen-Xia'
'Ueyama, Norikazu'
_publ_section_title
;
 Syntheses, structures and photoluminescent properties of cadmium(ii),
 silver(i) and copper(i) complexes with novel long chain tetradentate
 ligands
;
_journal_issue                   9
_journal_name_full               'Dalton Transactions'
_journal_page_first              1836
_journal_paper_doi               10.1039/b300479a
_journal_year                    2003
_chemical_formula_moiety         '[Ag3(L1)2](ClO4)3'
_chemical_formula_sum            'C48 H56 Ag3 Cl3 N12 O12'
_chemical_formula_weight         1423.01
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_date             'Mon Dec  2 22:06:46 2002'
_audit_creation_method           SHELXL-97
_cell_angle_alpha                94.69(9)
_cell_angle_beta                 90.38(7)
_cell_angle_gamma                115.90(8)
_cell_formula_units_Z            2
_cell_length_a                   8.879(7)
_cell_length_b                   9.997(12)
_cell_length_c                   35.53(3)
_cell_measurement_reflns_used    19741
_cell_measurement_temperature    200
_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      3.0
_cell_volume                     2824(5)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SIR92 (Altomare, 1994)'
_diffrn_ambient_temperature      200
_diffrn_detector_area_resol_mean 10.00
_diffrn_measured_fraction_theta_full 0.992
_diffrn_measured_fraction_theta_max 0.992
_diffrn_measurement_device_type  'Rigaku RAXIS-RAPID Imaging Plate'
_diffrn_measurement_method       ω
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71075
_diffrn_reflns_av_R_equivalents  0.0578
_diffrn_reflns_av_sigmaI/netI    0.0812
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       46
_diffrn_reflns_limit_l_min       -45
_diffrn_reflns_number            27740
_diffrn_reflns_theta_full        27.47
_diffrn_reflns_theta_max         27.47
_diffrn_reflns_theta_min         3.01
_exptl_absorpt_coefficient_mu    1.241
_exptl_absorpt_correction_T_max  0.940
_exptl_absorpt_correction_T_min  0.624
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(Higashi, 1995)'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.673
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       platelet
_exptl_crystal_F_000             1432
_exptl_crystal_size_max          0.200
_exptl_crystal_size_mid          0.200
_exptl_crystal_size_min          0.050
_refine_diff_density_max         1.753
_refine_diff_density_min         -0.900
_refine_diff_density_rms         0.102
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.936
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     703
_refine_ls_number_reflns         12802
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.936
_refine_ls_R_factor_all          0.0985
_refine_ls_R_factor_gt           0.0525
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0799P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1303
_refine_ls_wR_factor_ref         0.1474
_reflns_number_gt                7554
_reflns_number_total             12802
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b300479a.txt
_cod_data_source_block           '[Ag3(L1)2](ClO4)3_(2)'
_cod_original_sg_symbol_H-M      'P -1         '
_cod_database_code               7012714
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.69420(5) 0.33576(5) 0.228115(11) 0.04725(12) Uani 1 1 d . . .
Ag2 Ag 0.33998(6) -0.02463(7) 0.520961(13) 0.06834(17) Uani 1 1 d . . .
Ag3 Ag 0.34657(6) -0.62605(5) 0.014662(11) 0.05556(14) Uani 1 1 d . . .
Cl1 Cl 0.79792(17) 0.43589(16) 0.05224(4) 0.0526(3) Uani 1 1 d . . .
Cl2 Cl 0.36332(18) -0.30459(18) 0.23684(4) 0.0622(4) Uani 1 1 d . . .
Cl3 Cl 0.2126(4) -0.3281(2) 0.44076(6) 0.1066(9) Uani 1 1 d . . .
O11 O 0.8522(6) 0.5880(5) 0.04673(17) 0.0897(16) Uani 1 1 d . . .
O12 O 0.8298(6) 0.4157(6) 0.09025(12) 0.0805(14) Uani 1 1 d . . .
O13 O 0.6242(5) 0.3545(6) 0.04183(14) 0.0790(13) Uani 1 1 d . . .
O14 O 0.8891(6) 0.3763(6) 0.02790(14) 0.0822(14) Uani 1 1 d . . .
O21 O 0.3106(8) -0.3467(6) 0.19798(14) 0.0927(16) Uani 1 1 d . . .
O22 O 0.3459(13) -0.4316(7) 0.2526(2) 0.204(6) Uani 1 1 d . . .
O23 O 0.2680(7) -0.2365(11) 0.2526(2) 0.173(4) Uani 1 1 d . . .
O24 O 0.5310(5) -0.1970(5) 0.24120(18) 0.0903(17) Uani 1 1 d . . .
O31 O 0.0968(9) -0.4765(7) 0.4329(2) 0.128(2) Uani 1 1 d . . .
O32 O 0.3591(10) -0.3053(12) 0.4558(2) 0.172(4) Uani 1 1 d . . .
O33 O 0.1228(15) -0.2877(12) 0.4722(3) 0.199(5) Uani 1 1 d . . .
O34 O 0.2037(12) -0.2389(9) 0.4133(2) 0.176(4) Uani 1 1 d . . .
N1 N 0.5157(5) 0.2509(5) 0.28221(11) 0.0397(9) Uani 1 1 d . . .
H1 H 0.5569 0.3296 0.3011 0.048 Uiso 1 1 calc R . .
N2 N 0.7524(5) 0.1483(5) 0.24858(11) 0.0401(9) Uani 1 1 d . . .
H2 H 0.6722 0.0583 0.2369 0.048 Uiso 1 1 calc R . .
N3 N 0.6617(5) 0.4261(5) 0.17167(11) 0.0408(9) Uani 1 1 d . . .
H3 H 0.7198 0.3980 0.1535 0.049 Uiso 1 1 calc R . .
N4 N 0.8845(5) 0.5990(5) 0.23921(11) 0.0441(10) Uani 1 1 d . . .
H4 H 0.9864 0.6065 0.2485 0.053 Uiso 1 1 calc R . .
N101 N 0.1005(7) 0.1418(8) 0.44757(13) 0.0655(15) Uani 1 1 d . . .
N102 N 0.2518(7) 0.0961(7) 0.48888(12) 0.0604(13) Uani 1 1 d . . .
N201 N 0.1359(5) -1.0388(5) -0.05444(12) 0.0457(10) Uani 1 1 d . . .
N202 N 0.2758(6) -0.8355(5) -0.01647(12) 0.0496(11) Uani 1 1 d . . .
N301 N 0.2959(6) -0.3172(5) 0.09444(13) 0.0531(11) Uani 1 1 d . . .
N302 N 0.3855(6) -0.4412(5) 0.05387(12) 0.0517(11) Uani 1 1 d . . .
N401 N 0.3641(6) -0.3687(6) 0.57839(11) 0.0509(11) Uani 1 1 d . . .
N402 N 0.3835(6) -0.1658(7) 0.55571(12) 0.0594(13) Uani 1 1 d . . .
C1 C 0.5482(7) 0.1284(6) 0.29614(14) 0.0482(12) Uani 1 1 d . . .
H5 H 0.5302 0.1256 0.3236 0.058 Uiso 1 1 calc R . .
H6 H 0.4672 0.0315 0.2832 0.058 Uiso 1 1 calc R . .
C2 C 0.7215(7) 0.1484(7) 0.28929(14) 0.0491(13) Uani 1 1 d . . .
H7 H 0.8028 0.2441 0.3027 0.059 Uiso 1 1 calc R . .
H8 H 0.7384 0.0666 0.2996 0.059 Uiso 1 1 calc R . .
C3 C 0.7441(7) 0.5916(6) 0.17804(14) 0.0467(12) Uani 1 1 d . . .
H9 H 0.6684 0.6260 0.1916 0.056 Uiso 1 1 calc R . .
H10 H 0.7657 0.6344 0.1534 0.056 Uiso 1 1 calc R . .
C4 C 0.9086(6) 0.6472(7) 0.20103(15) 0.0512(13) Uani 1 1 d . . .
H11 H 0.9823 0.6096 0.1878 0.061 Uiso 1 1 calc R . .
H12 H 0.9655 0.7577 0.2027 0.061 Uiso 1 1 calc R . .
C10 C 0.3342(6) 0.2096(7) 0.27621(13) 0.0479(13) Uani 1 1 d . . .
H13 H 0.2837 0.1181 0.2584 0.057 Uiso 1 1 calc R . .
H14 H 0.3229 0.2905 0.2640 0.057 Uiso 1 1 calc R . .
C11 C 0.2359(6) 0.1823(6) 0.31138(13) 0.0440(12) Uani 1 1 d . . .
C12 C 0.2122(7) 0.2968(7) 0.33090(14) 0.0482(13) Uani 1 1 d . . .
H15 H 0.2551 0.3921 0.3214 0.058 Uiso 1 1 calc R . .
C13 C 0.1265(7) 0.2739(8) 0.36415(15) 0.0581(16) Uani 1 1 d . . .
H16 H 0.1111 0.3536 0.3771 0.070 Uiso 1 1 calc R . .
C14 C 0.0641(7) 0.1377(8) 0.37842(15) 0.0576(16) Uani 1 1 d . . .
C15 C 0.0844(7) 0.0200(8) 0.35841(16) 0.0595(15) Uani 1 1 d . . .
H17 H 0.0393 -0.0758 0.3676 0.071 Uiso 1 1 calc R . .
C16 C 0.1697(7) 0.0429(7) 0.32541(14) 0.0517(13) Uani 1 1 d . . .
H18 H 0.1834 -0.0372 0.3121 0.062 Uiso 1 1 calc R . .
C17 C -0.0207(9) 0.1136(11) 0.41565(17) 0.086(3) Uani 1 1 d . . .
H19 H -0.0747 0.1815 0.4197 0.104 Uiso 1 1 calc R . .
H20 H -0.1093 0.0096 0.4148 0.104 Uiso 1 1 calc R . .
C20 C 0.9163(7) 0.1555(7) 0.24008(15) 0.0479(12) Uani 1 1 d . . .
H21 H 0.9259 0.0690 0.2496 0.057 Uiso 1 1 calc R . .
H22 H 1.0053 0.2477 0.2532 0.057 Uiso 1 1 calc R . .
C21 C 0.9405(6) 0.1543(6) 0.19804(14) 0.0418(11) Uani 1 1 d . . .
C22 C 1.0302(6) 0.2831(6) 0.18179(16) 0.0478(12) Uani 1 1 d . . .
H23 H 1.0827 0.3743 0.1975 0.057 Uiso 1 1 calc R . .
C23 C 1.0469(7) 0.2849(6) 0.14337(15) 0.0483(12) Uani 1 1 d . . .
H24 H 1.1089 0.3767 0.1328 0.058 Uiso 1 1 calc R . .
C24 C 0.9729(6) 0.1520(6) 0.11989(15) 0.0443(11) Uani 1 1 d . . .
C25 C 0.8820(8) 0.0199(6) 0.13588(16) 0.0553(14) Uani 1 1 d . . .
H25 H 0.8299 -0.0716 0.1203 0.066 Uiso 1 1 calc R . .
C26 C 0.8669(7) 0.0214(6) 0.17487(16) 0.0542(13) Uani 1 1 d . . .
H26 H 0.8055 -0.0697 0.1857 0.065 Uiso 1 1 calc R . .
C27 C 1.0006(7) 0.1559(6) 0.07822(15) 0.0515(13) Uani 1 1 d . . .
H27 H 1.0161 0.2543 0.0708 0.062 Uiso 1 1 calc R . .
H28 H 1.1054 0.1467 0.0733 0.062 Uiso 1 1 calc R . .
C30 C 0.4864(7) 0.3721(6) 0.15669(17) 0.0526(13) Uani 1 1 d . . .
H29 H 0.4848 0.4259 0.1346 0.063 Uiso 1 1 calc R . .
H30 H 0.4191 0.3931 0.1764 0.063 Uiso 1 1 calc R . .
C31 C 0.4106(6) 0.2072(6) 0.14510(14) 0.0440(12) Uani 1 1 d . . .
C32 C 0.3926(7) 0.1536(7) 0.10726(15) 0.0546(14) Uani 1 1 d . . .
H31 H 0.4292 0.2219 0.0884 0.065 Uiso 1 1 calc R . .
C33 C 0.3219(7) 0.0020(7) 0.09676(15) 0.0576(15) Uani 1 1 d . . .
H32 H 0.3116 -0.0333 0.0708 0.069 Uiso 1 1 calc R . .
C34 C 0.2663(7) -0.0987(6) 0.12363(16) 0.0499(13) Uani 1 1 d . . .
C35 C 0.2887(7) -0.0421(7) 0.16165(15) 0.0550(14) Uani 1 1 d . . .
H33 H 0.2568 -0.1089 0.1808 0.066 Uiso 1 1 calc R . .
C36 C 0.3558(7) 0.1075(6) 0.17137(14) 0.0516(13) Uani 1 1 d . . .
H34 H 0.3645 0.1431 0.1973 0.062 Uiso 1 1 calc R . .
C37 C 0.1818(8) -0.2652(7) 0.1131(2) 0.0690(18) Uani 1 1 d . . .
H35 H 0.1421 -0.3172 0.1361 0.083 Uiso 1 1 calc R . .
H36 H 0.0829 -0.2907 0.0959 0.083 Uiso 1 1 calc R . .
C40 C 0.8379(8) 0.6951(6) 0.26439(14) 0.0502(13) Uani 1 1 d . . .
H37 H 0.7386 0.7000 0.2529 0.060 Uiso 1 1 calc R . .
H38 H 0.9308 0.7973 0.2665 0.060 Uiso 1 1 calc R . .
C41 C 0.7982(7) 0.6458(6) 0.30366(13) 0.0441(12) Uani 1 1 d . . .
C42 C 0.6709(7) 0.6642(7) 0.32245(15) 0.0551(14) Uani 1 1 d . . .
H39 H 0.6069 0.7044 0.3101 0.066 Uiso 1 1 calc R . .
C43 C 0.6359(8) 0.6252(7) 0.35881(16) 0.0579(14) Uani 1 1 d . . .
H40 H 0.5471 0.6373 0.3710 0.070 Uiso 1 1 calc R . .
C44 C 0.7282(8) 0.5689(6) 0.37774(14) 0.0516(13) Uani 1 1 d . . .
C45 C 0.8558(8) 0.5515(7) 0.35940(15) 0.0568(15) Uani 1 1 d . . .
H41 H 0.9201 0.5127 0.3722 0.068 Uiso 1 1 calc R . .
C46 C 0.8922(7) 0.5887(6) 0.32317(14) 0.0501(13) Uani 1 1 d . . .
H42 H 0.9810 0.5760 0.3112 0.060 Uiso 1 1 calc R . .
C47 C 0.6894(9) 0.5290(7) 0.41846(16) 0.0667(17) Uani 1 1 d . . .
H43 H 0.7907 0.5880 0.4352 0.080 Uiso 1 1 calc R . .
H44 H 0.5997 0.5559 0.4271 0.080 Uiso 1 1 calc R . .
C101 C 0.1303(8) 0.0376(8) 0.46329(17) 0.0632(17) Uani 1 1 d . . .
H45 H 0.0696 -0.0667 0.4565 0.076 Uiso 1 1 calc R . .
C102 C 0.3018(10) 0.2476(9) 0.48973(17) 0.076(2) Uani 1 1 d . . .
H46 H 0.3888 0.3214 0.5060 0.091 Uiso 1 1 calc R . .
C103 C 0.2113(11) 0.2755(10) 0.46472(17) 0.078(2) Uani 1 1 d . . .
H47 H 0.2219 0.3710 0.4597 0.093 Uiso 1 1 calc R . .
C201 C 0.1343(7) -0.9173(6) -0.03554(14) 0.0491(13) Uani 1 1 d . . .
H48 H 0.0416 -0.8939 -0.0360 0.059 Uiso 1 1 calc R . .
C202 C 0.3775(7) -0.9063(6) -0.02371(16) 0.0542(14) Uani 1 1 d . . .
H49 H 0.4892 -0.8722 -0.0139 0.065 Uiso 1 1 calc R . .
C203 C 0.2920(7) -1.0321(7) -0.04712(17) 0.0568(14) Uani 1 1 d . . .
H50 H 0.3317 -1.1019 -0.0566 0.068 Uiso 1 1 calc R . .
C301 C 0.2635(8) -0.4020(7) 0.06088(16) 0.0564(14) Uani 1 1 d . . .
H51 H 0.1669 -0.4294 0.0447 0.068 Uiso 1 1 calc R . .
C302 C 0.5020(8) -0.3780(6) 0.08357(14) 0.0517(13) Uani 1 1 d . . .
H52 H 0.6041 -0.3864 0.0859 0.062 Uiso 1 1 calc R . .
C303 C 0.4482(8) -0.3022(7) 0.10883(15) 0.0536(14) Uani 1 1 d . . .
H53 H 0.5041 -0.2488 0.1320 0.064 Uiso 1 1 calc R . .
C401 C 0.3048(8) -0.3111(8) 0.55246(15) 0.0570(15) Uani 1 1 d . . .
H54 H 0.2169 -0.3688 0.5342 0.068 Uiso 1 1 calc R . .
C402 C 0.5027(7) -0.1258(8) 0.58559(14) 0.0558(15) Uani 1 1 d . . .
H55 H 0.5792 -0.0270 0.5949 0.067 Uiso 1 1 calc R . .
C403 C 0.4890(7) -0.2532(7) 0.59885(15) 0.0538(14) Uani 1 1 d . . .
H56 H 0.5554 -0.2604 0.6189 0.065 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N2 Ag1 N3 139.24(15) . . ?
N2 Ag1 N4 123.34(16) . . ?
N3 Ag1 N4 77.85(17) . . ?
N2 Ag1 N1 75.70(16) . . ?
N3 Ag1 N1 133.40(15) . . ?
N4 Ag1 N1 110.70(17) . . ?
N102 Ag2 N402 169.8(2) . . ?
N102 Ag2 Ag2 99.40(15) . 2_656 ?
N402 Ag2 Ag2 90.07(15) . 2_656 ?
N202 Ag3 N302 168.68(18) . . ?
N202 Ag3 Ag3 113.62(16) . 2_645 ?
N302 Ag3 Ag3 77.37(16) . 2_645 ?
O11 Cl1 O13 109.8(3) . . ?
O11 Cl1 O12 112.0(3) . . ?
O13 Cl1 O12 110.5(3) . . ?
O11 Cl1 O14 108.7(3) . . ?
O13 Cl1 O14 108.1(3) . . ?
O12 Cl1 O14 107.7(3) . . ?
O22 Cl2 O23 115.0(7) . . ?
O22 Cl2 O24 109.7(5) . . ?
O23 Cl2 O24 106.3(4) . . ?
O22 Cl2 O21 107.1(4) . . ?
O23 Cl2 O21 107.4(4) . . ?
O24 Cl2 O21 111.4(4) . . ?
O32 Cl3 O31 116.0(6) . . ?
O32 Cl3 O34 120.3(6) . . ?
O31 Cl3 O34 111.8(4) . . ?
O32 Cl3 O33 105.9(5) . . ?
O31 Cl3 O33 97.6(6) . . ?
O34 Cl3 O33 100.8(7) . . ?
C10 N1 C1 113.1(4) . . ?
C10 N1 Ag1 117.3(3) . . ?
C1 N1 Ag1 106.1(3) . . ?
C10 N1 H1 106.5 . . ?
C1 N1 H1 106.5 . . ?
Ag1 N1 H1 106.5 . . ?
C20 N2 C2 113.3(4) . . ?
C20 N2 Ag1 116.6(3) . . ?
C2 N2 Ag1 105.3(3) . . ?
C20 N2 H2 107.0 . . ?
C2 N2 H2 107.0 . . ?
Ag1 N2 H2 107.0 . . ?
C3 N3 C30 110.4(4) . . ?
C3 N3 Ag1 107.0(3) . . ?
C30 N3 Ag1 115.7(3) . . ?
C3 N3 H3 107.8 . . ?
C30 N3 H3 107.8 . . ?
Ag1 N3 H3 107.8 . . ?
C40 N4 C4 111.4(4) . . ?
C40 N4 Ag1 119.2(3) . . ?
C4 N4 Ag1 102.8(3) . . ?
C40 N4 H4 107.6 . . ?
C4 N4 H4 107.6 . . ?
Ag1 N4 H4 107.6 . . ?
C101 N101 C103 106.3(6) . . ?
C101 N101 C17 125.8(7) . . ?
C103 N101 C17 127.7(6) . . ?
C101 N102 C102 104.5(5) . . ?
C101 N102 Ag2 125.1(5) . . ?
C102 N102 Ag2 130.3(5) . . ?
C201 N201 C203 106.7(5) . . ?
C201 N201 C27 127.0(5) . 2_645 ?
C203 N201 C27 126.3(5) . 2_645 ?
C201 N202 C202 106.1(4) . . ?
C201 N202 Ag3 127.4(4) . . ?
C202 N202 Ag3 126.2(4) . . ?
C301 N301 C303 106.8(5) . . ?
C301 N301 C37 125.7(5) . . ?
C303 N301 C37 127.2(5) . . ?
C301 N302 C302 107.0(5) . . ?
C301 N302 Ag3 120.9(4) . . ?
C302 N302 Ag3 128.7(4) . . ?
C401 N401 C403 107.4(5) . . ?
C401 N401 C47 125.6(5) . 2_656 ?
C403 N401 C47 126.8(5) . 2_656 ?
C401 N402 C402 106.4(5) . . ?
C401 N402 Ag2 125.5(4) . . ?
C402 N402 Ag2 128.0(5) . . ?
C2 C1 N1 112.2(4) . . ?
C2 C1 H5 109.2 . . ?
N1 C1 H5 109.2 . . ?
C2 C1 H6 109.2 . . ?
N1 C1 H6 109.2 . . ?
H5 C1 H6 107.9 . . ?
N2 C2 C1 111.1(4) . . ?
N2 C2 H7 109.4 . . ?
C1 C2 H7 109.4 . . ?
N2 C2 H8 109.4 . . ?
C1 C2 H8 109.4 . . ?
H7 C2 H8 108.0 . . ?
N3 C3 C4 111.1(4) . . ?
N3 C3 H9 109.4 . . ?
C4 C3 H9 109.4 . . ?
N3 C3 H10 109.4 . . ?
C4 C3 H10 109.4 . . ?
H9 C3 H10 108.0 . . ?
N4 C4 C3 112.4(4) . . ?
N4 C4 H11 109.1 . . ?
C3 C4 H11 109.1 . . ?
N4 C4 H12 109.1 . . ?
C3 C4 H12 109.1 . . ?
H11 C4 H12 107.9 . . ?
N1 C10 C11 115.2(4) . . ?
N1 C10 H13 108.5 . . ?
C11 C10 H13 108.5 . . ?
N1 C10 H14 108.5 . . ?
C11 C10 H14 108.5 . . ?
H13 C10 H14 107.5 . . ?
C12 C11 C16 118.7(5) . . ?
C12 C11 C10 120.4(5) . . ?
C16 C11 C10 120.9(5) . . ?
C11 C12 C13 120.8(6) . . ?
C11 C12 H15 119.6 . . ?
C13 C12 H15 119.6 . . ?
C14 C13 C12 120.7(6) . . ?
C14 C13 H16 119.6 . . ?
C12 C13 H16 119.6 . . ?
C13 C14 C15 118.9(5) . . ?
C13 C14 C17 121.3(7) . . ?
C15 C14 C17 119.7(6) . . ?
C16 C15 C14 120.3(6) . . ?
C16 C15 H17 119.9 . . ?
C14 C15 H17 119.9 . . ?
C15 C16 C11 120.6(6) . . ?
C15 C16 H18 119.7 . . ?
C11 C16 H18 119.7 . . ?
N101 C17 C14 111.4(5) . . ?
N101 C17 H19 109.3 . . ?
C14 C17 H19 109.3 . . ?
N101 C17 H20 109.3 . . ?
C14 C17 H20 109.3 . . ?
H19 C17 H20 108.0 . . ?
N2 C20 C21 110.9(4) . . ?
N2 C20 H21 109.5 . . ?
C21 C20 H21 109.5 . . ?
N2 C20 H22 109.5 . . ?
C21 C20 H22 109.5 . . ?
H21 C20 H22 108.0 . . ?
C22 C21 C26 118.4(5) . . ?
C22 C21 C20 121.3(5) . . ?
C26 C21 C20 120.3(5) . . ?
C21 C22 C23 122.0(5) . . ?
C21 C22 H23 119.0 . . ?
C23 C22 H23 119.0 . . ?
C22 C23 C24 119.9(5) . . ?
C22 C23 H24 120.0 . . ?
C24 C23 H24 120.0 . . ?
C25 C24 C23 118.9(5) . . ?
C25 C24 C27 122.1(5) . . ?
C23 C24 C27 118.9(5) . . ?
C24 C25 C26 119.9(5) . . ?
C24 C25 H25 120.0 . . ?
C26 C25 H25 120.0 . . ?
C21 C26 C25 120.8(5) . . ?
C21 C26 H26 119.6 . . ?
C25 C26 H26 119.6 . . ?
N201 C27 C24 114.3(5) 2_645 . ?
N201 C27 H27 108.7 2_645 . ?
C24 C27 H27 108.7 . . ?
N201 C27 H28 108.7 2_645 . ?
C24 C27 H28 108.7 . . ?
H27 C27 H28 107.6 . . ?
N3 C30 C31 110.5(4) . . ?
N3 C30 H29 109.6 . . ?
C31 C30 H29 109.6 . . ?
N3 C30 H30 109.6 . . ?
C31 C30 H30 109.6 . . ?
H29 C30 H30 108.1 . . ?
C36 C31 C32 118.6(5) . . ?
C36 C31 C30 120.7(5) . . ?
C32 C31 C30 120.8(5) . . ?
C33 C32 C31 120.5(5) . . ?
C33 C32 H31 119.7 . . ?
C31 C32 H31 119.7 . . ?
C34 C33 C32 120.6(5) . . ?
C34 C33 H32 119.7 . . ?
C32 C33 H32 119.7 . . ?
C33 C34 C35 117.9(5) . . ?
C33 C34 C37 122.0(5) . . ?
C35 C34 C37 120.1(6) . . ?
C36 C35 C34 120.6(5) . . ?
C36 C35 H33 119.7 . . ?
C34 C35 H33 119.7 . . ?
C31 C36 C35 121.8(5) . . ?
C31 C36 H34 119.1 . . ?
C35 C36 H34 119.1 . . ?
N301 C37 C34 111.6(5) . . ?
N301 C37 H35 109.3 . . ?
C34 C37 H35 109.3 . . ?
N301 C37 H36 109.3 . . ?
C34 C37 H36 109.3 . . ?
H35 C37 H36 108.0 . . ?
N4 C40 C41 114.6(4) . . ?
N4 C40 H37 108.6 . . ?
C41 C40 H37 108.6 . . ?
N4 C40 H38 108.6 . . ?
C41 C40 H38 108.6 . . ?
H37 C40 H38 107.6 . . ?
C42 C41 C46 117.8(5) . . ?
C42 C41 C40 119.8(5) . . ?
C46 C41 C40 122.3(5) . . ?
C43 C42 C41 121.0(5) . . ?
C43 C42 H39 119.5 . . ?
C41 C42 H39 119.5 . . ?
C42 C43 C44 120.8(6) . . ?
C42 C43 H40 119.6 . . ?
C44 C43 H40 119.6 . . ?
C43 C44 C45 118.5(5) . . ?
C43 C44 C47 120.0(6) . . ?
C45 C44 C47 121.5(5) . . ?
C46 C45 C44 121.7(5) . . ?
C46 C45 H41 119.2 . . ?
C44 C45 H41 119.2 . . ?
C45 C46 C41 120.1(5) . . ?
C45 C46 H42 119.9 . . ?
C41 C46 H42 119.9 . . ?
N401 C47 C44 111.8(5) 2_656 . ?
N401 C47 H43 109.3 2_656 . ?
C44 C47 H43 109.3 . . ?
N401 C47 H44 109.3 2_656 . ?
C44 C47 H44 109.3 . . ?
H43 C47 H44 107.9 . . ?
N102 C101 N101 112.0(7) . . ?
N102 C101 H45 124.0 . . ?
N101 C101 H45 124.0 . . ?
C103 C102 N102 110.2(7) . . ?
C103 C102 H46 124.9 . . ?
N102 C102 H46 124.9 . . ?
C102 C103 N101 106.8(7) . . ?
C102 C103 H47 126.6 . . ?
N101 C103 H47 126.6 . . ?
N202 C201 N201 111.8(5) . . ?
N202 C201 H48 124.1 . . ?
N201 C201 H48 124.1 . . ?
C203 C202 N202 109.0(5) . . ?
C203 C202 H49 125.5 . . ?
N202 C202 H49 125.5 . . ?
C202 C203 N201 106.4(5) . . ?
C202 C203 H50 126.8 . . ?
N201 C203 H50 126.8 . . ?
N302 C301 N301 110.3(5) . . ?
N302 C301 H51 124.9 . . ?
N301 C301 H51 124.9 . . ?
C303 C302 N302 109.1(5) . . ?
C303 C302 H52 125.5 . . ?
N302 C302 H52 125.5 . . ?
C302 C303 N301 106.8(5) . . ?
C302 C303 H53 126.6 . . ?
N301 C303 H53 126.6 . . ?
N402 C401 N401 111.1(5) . . ?
N402 C401 H54 124.5 . . ?
N401 C401 H54 124.5 . . ?
C403 C402 N402 107.4(6) . . ?
C403 C402 H55 126.3 . . ?
N402 C402 H55 126.3 . . ?
N401 C403 C402 107.7(5) . . ?
N401 C403 H56 126.1 . . ?
C402 C403 H56 126.1 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 N2 2.317(5) . ?
Ag1 N3 2.332(4) . ?
Ag1 N4 2.423(6) . ?
Ag1 N1 2.461(5) . ?
Ag2 N102 2.100(5) . ?
Ag2 N402 2.103(5) . ?
Ag2 Ag2 3.081(3) 2_656 ?
Ag3 N202 2.113(5) . ?
Ag3 N302 2.119(5) . ?
Ag3 Ag3 3.054(4) 2_645 ?
Cl1 O11 1.412(5) . ?
Cl1 O13 1.423(5) . ?
Cl1 O12 1.427(5) . ?
Cl1 O14 1.450(5) . ?
Cl2 O22 1.376(7) . ?
Cl2 O23 1.393(7) . ?
Cl2 O24 1.403(5) . ?
Cl2 O21 1.424(5) . ?
Cl3 O32 1.319(8) . ?
Cl3 O31 1.390(7) . ?
Cl3 O34 1.399(8) . ?
Cl3 O33 1.506(13) . ?
N1 C10 1.487(6) . ?
N1 C1 1.495(7) . ?
N1 H1 0.9300 . ?
N2 C20 1.460(7) . ?
N2 C2 1.474(6) . ?
N2 H2 0.9300 . ?
N3 C3 1.484(7) . ?
N3 C30 1.485(7) . ?
N3 H3 0.9300 . ?
N4 C40 1.452(7) . ?
N4 C4 1.463(6) . ?
N4 H4 0.9300 . ?
N101 C101 1.342(8) . ?
N101 C103 1.355(10) . ?
N101 C17 1.480(8) . ?
N102 C101 1.296(8) . ?
N102 C102 1.377(9) . ?
N201 C201 1.344(7) . ?
N201 C203 1.380(7) . ?
N201 C27 1.462(7) 2_645 ?
N202 C201 1.307(7) . ?
N202 C202 1.383(7) . ?
N301 C301 1.357(7) . ?
N301 C303 1.384(7) . ?
N301 C37 1.465(7) . ?
N302 C301 1.321(8) . ?
N302 C302 1.374(7) . ?
N401 C401 1.343(7) . ?
N401 C403 1.351(8) . ?
N401 C47 1.473(8) 2_656 ?
N402 C401 1.303(8) . ?
N402 C402 1.397(7) . ?
C1 C2 1.486(8) . ?
C1 H5 0.9900 . ?
C1 H6 0.9900 . ?
C2 H7 0.9900 . ?
C2 H8 0.9900 . ?
C3 C4 1.520(7) . ?
C3 H9 0.9900 . ?
C3 H10 0.9900 . ?
C4 H11 0.9900 . ?
C4 H12 0.9900 . ?
C10 C11 1.504(7) . ?
C10 H13 0.9900 . ?
C10 H14 0.9900 . ?
C11 C12 1.384(8) . ?
C11 C16 1.392(8) . ?
C12 C13 1.390(8) . ?
C12 H15 0.9500 . ?
C13 C14 1.369(9) . ?
C13 H16 0.9500 . ?
C14 C15 1.405(9) . ?
C14 C17 1.511(8) . ?
C15 C16 1.380(8) . ?
C15 H17 0.9500 . ?
C16 H18 0.9500 . ?
C17 H19 0.9900 . ?
C17 H20 0.9900 . ?
C20 C21 1.510(7) . ?
C20 H21 0.9900 . ?
C20 H22 0.9900 . ?
C21 C22 1.362(8) . ?
C21 C26 1.388(7) . ?
C22 C23 1.375(8) . ?
C22 H23 0.9500 . ?
C23 C24 1.394(7) . ?
C23 H24 0.9500 . ?
C24 C25 1.384(8) . ?
C24 C27 1.503(8) . ?
C25 C26 1.392(8) . ?
C25 H25 0.9500 . ?
C26 H26 0.9500 . ?
C27 N201 1.462(7) 2_645 ?
C27 H27 0.9900 . ?
C27 H28 0.9900 . ?
C30 C31 1.502(8) . ?
C30 H29 0.9900 . ?
C30 H30 0.9900 . ?
C31 C36 1.355(8) . ?
C31 C32 1.387(7) . ?
C32 C33 1.380(8) . ?
C32 H31 0.9500 . ?
C33 C34 1.378(8) . ?
C33 H32 0.9500 . ?
C34 C35 1.399(8) . ?
C34 C37 1.509(8) . ?
C35 C36 1.358(8) . ?
C35 H33 0.9500 . ?
C36 H34 0.9500 . ?
C37 H35 0.9900 . ?
C37 H36 0.9900 . ?
C40 C41 1.510(7) . ?
C40 H37 0.9900 . ?
C40 H38 0.9900 . ?
C41 C42 1.389(8) . ?
C41 C46 1.406(7) . ?
C42 C43 1.378(8) . ?
C42 H39 0.9500 . ?
C43 C44 1.378(8) . ?
C43 H40 0.9500 . ?
C44 C45 1.379(8) . ?
C44 C47 1.534(8) . ?
C45 C46 1.371(8) . ?
C45 H41 0.9500 . ?
C46 H42 0.9500 . ?
C47 N401 1.473(8) 2_656 ?
C47 H43 0.9900 . ?
C47 H44 0.9900 . ?
C101 H45 0.9500 . ?
C102 C103 1.319(9) . ?
C102 H46 0.9500 . ?
C103 H47 0.9500 . ?
C201 H48 0.9500 . ?
C202 C203 1.355(8) . ?
C202 H49 0.9500 . ?
C203 H50 0.9500 . ?
C301 H51 0.9500 . ?
C302 C303 1.348(8) . ?
C302 H52 0.9500 . ?
C303 H53 0.9500 . ?
C401 H54 0.9500 . ?
C402 C403 1.351(8) . ?
C402 H55 0.9500 . ?
C403 H56 0.9500 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N2 Ag1 N1 C10 -128.1(4) . . . . ?
N3 Ag1 N1 C10 18.5(4) . . . . ?
N4 Ag1 N1 C10 111.3(4) . . . . ?
N2 Ag1 N1 C1 -0.5(3) . . . . ?
N3 Ag1 N1 C1 146.1(3) . . . . ?
N4 Ag1 N1 C1 -121.2(3) . . . . ?
N3 Ag1 N2 C20 63.3(4) . . . . ?
N4 Ag1 N2 C20 -48.9(4) . . . . ?
N1 Ag1 N2 C20 -154.5(4) . . . . ?
N3 Ag1 N2 C2 -170.2(3) . . . . ?
N4 Ag1 N2 C2 77.7(4) . . . . ?
N1 Ag1 N2 C2 -27.9(3) . . . . ?
N2 Ag1 N3 C3 -139.6(3) . . . . ?
N4 Ag1 N3 C3 -12.0(3) . . . . ?
N1 Ag1 N3 C3 95.2(4) . . . . ?
N2 Ag1 N3 C30 96.8(4) . . . . ?
N4 Ag1 N3 C30 -135.5(4) . . . . ?
N1 Ag1 N3 C30 -28.4(4) . . . . ?
N2 Ag1 N4 C40 -112.5(3) . . . . ?
N3 Ag1 N4 C40 105.7(4) . . . . ?
N1 Ag1 N4 C40 -26.4(4) . . . . ?
N2 Ag1 N4 C4 123.7(3) . . . . ?
N3 Ag1 N4 C4 -18.1(3) . . . . ?
N1 Ag1 N4 C4 -150.1(3) . . . . ?
N402 Ag2 N102 C101 -54.9(13) . . . . ?
Ag2 Ag2 N102 C101 102.4(4) 2_656 . . . ?
N402 Ag2 N102 C102 123.9(12) . . . . ?
Ag2 Ag2 N102 C102 -78.8(5) 2_656 . . . ?
N302 Ag3 N202 C201 76.0(10) . . . . ?
Ag3 Ag3 N202 C201 -118.3(4) 2_645 . . . ?
N302 Ag3 N202 C202 -110.8(10) . . . . ?
Ag3 Ag3 N202 C202 54.9(5) 2_645 . . . ?
N202 Ag3 N302 C301 -67.6(11) . . . . ?
Ag3 Ag3 N302 C301 125.9(5) 2_645 . . . ?
N202 Ag3 N302 C302 88.7(11) . . . . ?
Ag3 Ag3 N302 C302 -77.9(5) 2_645 . . . ?
N102 Ag2 N402 C401 54.4(14) . . . . ?
Ag2 Ag2 N402 C401 -103.3(5) 2_656 . . . ?
N102 Ag2 N402 C402 -127.7(11) . . . . ?
Ag2 Ag2 N402 C402 74.6(4) 2_656 . . . ?
C10 N1 C1 C2 159.9(4) . . . . ?
Ag1 N1 C1 C2 29.9(5) . . . . ?
C20 N2 C2 C1 -175.3(5) . . . . ?
Ag1 N2 C2 C1 56.1(5) . . . . ?
N1 C1 C2 N2 -60.7(6) . . . . ?
C30 N3 C3 C4 167.7(4) . . . . ?
Ag1 N3 C3 C4 41.0(5) . . . . ?
C40 N4 C4 C3 -81.8(6) . . . . ?
Ag1 N4 C4 C3 47.0(5) . . . . ?
N3 C3 C4 N4 -64.1(6) . . . . ?
C1 N1 C10 C11 65.3(6) . . . . ?
Ag1 N1 C10 C11 -170.6(4) . . . . ?
N1 C10 C11 C12 93.3(6) . . . . ?
N1 C10 C11 C16 -85.5(6) . . . . ?
C16 C11 C12 C13 1.0(7) . . . . ?
C10 C11 C12 C13 -177.7(5) . . . . ?
C11 C12 C13 C14 0.3(8) . . . . ?
C12 C13 C14 C15 -1.6(8) . . . . ?
C12 C13 C14 C17 176.5(5) . . . . ?
C13 C14 C15 C16 1.6(8) . . . . ?
C17 C14 C15 C16 -176.5(5) . . . . ?
C14 C15 C16 C11 -0.3(8) . . . . ?
C12 C11 C16 C15 -1.0(8) . . . . ?
C10 C11 C16 C15 177.8(5) . . . . ?
C101 N101 C17 C14 -96.3(8) . . . . ?
C103 N101 C17 C14 78.1(9) . . . . ?
C13 C14 C17 N101 -91.2(7) . . . . ?
C15 C14 C17 N101 86.8(8) . . . . ?
C2 N2 C20 C21 179.7(4) . . . . ?
Ag1 N2 C20 C21 -57.7(5) . . . . ?
N2 C20 C21 C22 99.2(6) . . . . ?
N2 C20 C21 C26 -78.8(6) . . . . ?
C26 C21 C22 C23 1.1(8) . . . . ?
C20 C21 C22 C23 -176.9(5) . . . . ?
C21 C22 C23 C24 -0.9(8) . . . . ?
C22 C23 C24 C25 0.6(8) . . . . ?
C22 C23 C24 C27 -176.9(5) . . . . ?
C23 C24 C25 C26 -0.5(8) . . . . ?
C27 C24 C25 C26 176.8(5) . . . . ?
C22 C21 C26 C25 -1.0(8) . . . . ?
C20 C21 C26 C25 177.0(5) . . . . ?
C24 C25 C26 C21 0.7(9) . . . . ?
C25 C24 C27 N201 31.0(7) . . . 2_645 ?
C23 C24 C27 N201 -151.6(5) . . . 2_645 ?
C3 N3 C30 C31 172.0(4) . . . . ?
Ag1 N3 C30 C31 -66.2(5) . . . . ?
N3 C30 C31 C36 77.7(7) . . . . ?
N3 C30 C31 C32 -103.5(6) . . . . ?
C36 C31 C32 C33 -0.7(8) . . . . ?
C30 C31 C32 C33 -179.6(5) . . . . ?
C31 C32 C33 C34 0.8(9) . . . . ?
C32 C33 C34 C35 -2.0(9) . . . . ?
C32 C33 C34 C37 177.4(5) . . . . ?
C33 C34 C35 C36 3.2(9) . . . . ?
C37 C34 C35 C36 -176.2(5) . . . . ?
C32 C31 C36 C35 1.9(9) . . . . ?
C30 C31 C36 C35 -179.2(5) . . . . ?
C34 C35 C36 C31 -3.2(9) . . . . ?
C301 N301 C37 C34 -128.1(6) . . . . ?
C303 N301 C37 C34 58.5(9) . . . . ?
C33 C34 C37 N301 64.2(8) . . . . ?
C35 C34 C37 N301 -116.4(6) . . . . ?
C4 N4 C40 C41 175.7(4) . . . . ?
Ag1 N4 C40 C41 56.2(6) . . . . ?
N4 C40 C41 C42 -143.3(5) . . . . ?
N4 C40 C41 C46 40.4(7) . . . . ?
C46 C41 C42 C43 -1.2(9) . . . . ?
C40 C41 C42 C43 -177.7(5) . . . . ?
C41 C42 C43 C44 1.0(10) . . . . ?
C42 C43 C44 C45 -0.4(9) . . . . ?
C42 C43 C44 C47 178.8(6) . . . . ?
C43 C44 C45 C46 0.0(9) . . . . ?
C47 C44 C45 C46 -179.2(6) . . . . ?
C44 C45 C46 C41 -0.2(9) . . . . ?
C42 C41 C46 C45 0.8(8) . . . . ?
C40 C41 C46 C45 177.2(5) . . . . ?
C43 C44 C47 N401 117.9(6) . . . 2_656 ?
C45 C44 C47 N401 -62.9(8) . . . 2_656 ?
C102 N102 C101 N101 0.5(6) . . . . ?
Ag2 N102 C101 N101 179.6(3) . . . . ?
C103 N101 C101 N102 -0.2(6) . . . . ?
C17 N101 C101 N102 175.2(5) . . . . ?
C101 N102 C102 C103 -0.6(7) . . . . ?
Ag2 N102 C102 C103 -179.6(4) . . . . ?
N102 C102 C103 N101 0.5(8) . . . . ?
C101 N101 C103 C102 -0.2(7) . . . . ?
C17 N101 C103 C102 -175.5(5) . . . . ?
C202 N202 C201 N201 0.9(6) . . . . ?
Ag3 N202 C201 N201 175.2(3) . . . . ?
C203 N201 C201 N202 -0.8(6) . . . . ?
C27 N201 C201 N202 179.2(5) 2_645 . . . ?
C201 N202 C202 C203 -0.6(7) . . . . ?
Ag3 N202 C202 C203 -175.0(4) . . . . ?
N202 C202 C203 N201 0.1(7) . . . . ?
C201 N201 C203 C202 0.4(7) . . . . ?
C27 N201 C203 C202 -179.6(5) 2_645 . . . ?
C302 N302 C301 N301 -0.8(7) . . . . ?
Ag3 N302 C301 N301 159.9(4) . . . . ?
C303 N301 C301 N302 0.5(7) . . . . ?
C37 N301 C301 N302 -174.1(6) . . . . ?
C301 N302 C302 C303 0.9(7) . . . . ?
Ag3 N302 C302 C303 -157.9(4) . . . . ?
N302 C302 C303 N301 -0.6(7) . . . . ?
C301 N301 C303 C302 0.0(7) . . . . ?
C37 N301 C303 C302 174.5(6) . . . . ?
C402 N402 C401 N401 0.3(6) . . . . ?
Ag2 N402 C401 N401 178.6(3) . . . . ?
C403 N401 C401 N402 -0.9(6) . . . . ?
C47 N401 C401 N402 -176.4(5) 2_656 . . . ?
C401 N402 C402 C403 0.4(6) . . . . ?
Ag2 N402 C402 C403 -177.9(4) . . . . ?
C401 N401 C403 C402 1.1(6) . . . . ?
C47 N401 C403 C402 176.6(5) 2_656 . . . ?
N402 C402 C403 N401 -0.9(6) . . . . ?
