#------------------------------------------------------------------------------
#$Date: 2016-03-25 13:18:00 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179836 $
#$URL: svn://www.crystallography.net/cod/cif/7/01/32/7013287.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7013287
loop_
_publ_author_name
'Hong, Fung-E'
'Chang, Chin-Pei'
'Chang, Yu-Chang'
_publ_section_title
;
 Synthesis and structural characterization of novel palladium complexes
 chelated by bulky cobalt-containing phosphine ligands: unusual
 palladium?cobalt bond formation
;
_journal_issue                   20
_journal_name_full               'Dalton Transactions'
_journal_page_first              3892
_journal_paper_doi               10.1039/b306228g
_journal_year                    2003
_chemical_formula_sum            'C56 H44 Cl4 Co2 O5 P4 Pd'
_chemical_formula_weight         1286.85
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                94.9880(10)
_cell_angle_beta                 100.917(2)
_cell_angle_gamma                101.4100(10)
_cell_formula_units_Z            2
_cell_length_a                   11.1922(8)
_cell_length_b                   13.1178(9)
_cell_length_c                   19.4159(14)
_cell_measurement_reflns_used    7517
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      26.014
_cell_measurement_theta_min      2.198
_cell_volume                     2720.7(3)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SHELXTL'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.985
_diffrn_measured_fraction_theta_max 0.985
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0225
_diffrn_reflns_av_sigmaI/netI    0.0369
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_number            15536
_diffrn_reflns_theta_full        26.04
_diffrn_reflns_theta_max         26.04
_diffrn_reflns_theta_min         1.81
_exptl_absorpt_coefficient_mu    1.291
_exptl_absorpt_correction_T_max  1.000000
_exptl_absorpt_correction_T_min  0.574474
_exptl_absorpt_correction_type   SADABS
_exptl_crystal_colour            red-brown
_exptl_crystal_density_diffrn    1.571
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       parallelepiped
_exptl_crystal_F_000             1296
_exptl_crystal_size_max          0.64
_exptl_crystal_size_mid          0.54
_exptl_crystal_size_min          0.33
_refine_diff_density_max         0.964
_refine_diff_density_min         -0.613
_refine_diff_density_rms         0.086
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.983
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     657
_refine_ls_number_reflns         10576
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.983
_refine_ls_R_factor_all          0.0542
_refine_ls_R_factor_gt           0.0385
_refine_ls_shift/su_max          0.045
_refine_ls_shift/su_mean         0.002
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0705P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0993
_refine_ls_wR_factor_ref         0.1096
_reflns_number_gt                8214
_reflns_number_total             10576
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b306228g.txt
_cod_data_source_block           hong158m
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7013287
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pd Pd 0.58144(2) 0.836680(19) 0.172953(14) 0.03847(9) Uani 1 1 d . . .
Co1 Co 0.25552(4) 0.61794(3) 0.20245(2) 0.03439(11) Uani 1 1 d . . .
Co2 Co 0.48822(4) 0.67166(3) 0.22803(2) 0.03149(11) Uani 1 1 d . . .
Cl1 Cl 0.77198(9) 0.78751(7) 0.15947(5) 0.0520(2) Uani 1 1 d . . .
Cl2 Cl 0.63033(10) 0.99758(8) 0.13119(6) 0.0643(3) Uani 1 1 d . . .
P1 P 0.37115(8) 0.69523(6) 0.38117(4) 0.03714(19) Uani 1 1 d . . .
P2 P 0.40817(8) 0.87016(6) 0.19847(5) 0.03513(19) Uani 1 1 d . . .
P3 P 0.24942(8) 0.44872(6) 0.21459(4) 0.03611(19) Uani 1 1 d . . .
P4 P 0.52767(8) 0.51709(6) 0.25590(4) 0.03144(17) Uani 1 1 d . . .
O1 O 0.1690(3) 0.6165(3) 0.04964(15) 0.0746(9) Uani 1 1 d . . .
O2 O 0.0094(3) 0.6146(3) 0.2334(2) 0.0906(11) Uani 1 1 d . . .
O3 O 0.7202(3) 0.7888(2) 0.32388(14) 0.0561(7) Uani 1 1 d . . .
O4 O 0.4784(2) 0.6264(2) 0.07550(12) 0.0520(6) Uani 1 1 d . . .
O5 O 0.3607(2) 0.58826(17) 0.40192(12) 0.0449(6) Uani 1 1 d . . .
C1 C 0.3700(3) 0.6972(2) 0.28902(16) 0.0337(7) Uani 1 1 d . . .
C2 C 0.3549(3) 0.7563(2) 0.23596(16) 0.0344(7) Uani 1 1 d . . .
C3 C 0.2441(3) 0.7530(3) 0.39904(18) 0.0416(8) Uani 1 1 d . . .
C4 C 0.1799(5) 0.8074(4) 0.3545(2) 0.0685(13) Uani 1 1 d . . .
H4A H 0.2034 0.8194 0.3119 0.082 Uiso 1 1 calc R . .
C5 C 0.0810(5) 0.8452(4) 0.3709(3) 0.0873(16) Uani 1 1 d . . .
H5B H 0.0382 0.8818 0.3395 0.105 Uiso 1 1 calc R . .
C6 C 0.0459(5) 0.8289(4) 0.4334(3) 0.0749(14) Uani 1 1 d . . .
H6A H -0.0218 0.8533 0.4442 0.090 Uiso 1 1 calc R . .
C7 C 0.1096(4) 0.7775(3) 0.4792(3) 0.0679(12) Uani 1 1 d . . .
H7A H 0.0867 0.7681 0.5222 0.082 Uiso 1 1 calc R . .
C8 C 0.2094(4) 0.7381(3) 0.4633(2) 0.0538(10) Uani 1 1 d . . .
H8A H 0.2525 0.7023 0.4952 0.065 Uiso 1 1 calc R . .
C9 C 0.5125(3) 0.7814(3) 0.43132(18) 0.0438(8) Uani 1 1 d . . .
C10 C 0.6028(4) 0.7356(3) 0.4676(2) 0.0617(11) Uani 1 1 d . . .
H10A H 0.5884 0.6630 0.4655 0.074 Uiso 1 1 calc R . .
C11 C 0.7140(5) 0.7966(4) 0.5068(3) 0.0805(14) Uani 1 1 d . . .
H11A H 0.7744 0.7654 0.5308 0.097 Uiso 1 1 calc R . .
C12 C 0.7339(5) 0.9029(5) 0.5098(3) 0.0852(16) Uani 1 1 d . . .
H12A H 0.8087 0.9442 0.5360 0.102 Uiso 1 1 calc R . .
C13 C 0.6466(5) 0.9499(4) 0.4751(3) 0.0770(14) Uani 1 1 d . . .
H13A H 0.6618 1.0226 0.4779 0.092 Uiso 1 1 calc R . .
C14 C 0.5350(4) 0.8891(3) 0.4357(2) 0.0566(10) Uani 1 1 d . . .
H14A H 0.4751 0.9212 0.4121 0.068 Uiso 1 1 calc R . .
C15 C 0.2822(3) 0.8756(2) 0.12583(17) 0.0386(7) Uani 1 1 d . . .
C16 C 0.3083(4) 0.8987(3) 0.06090(19) 0.0458(8) Uani 1 1 d . . .
H16A H 0.3902 0.9128 0.0549 0.055 Uiso 1 1 calc R . .
C17 C 0.2114(4) 0.9006(3) 0.0056(2) 0.0580(10) Uani 1 1 d . . .
H17A H 0.2284 0.9152 -0.0381 0.070 Uiso 1 1 calc R . .
C18 C 0.0902(4) 0.8811(3) 0.0140(2) 0.0619(11) Uani 1 1 d . . .
H18A H 0.0259 0.8826 -0.0237 0.074 Uiso 1 1 calc R . .
C19 C 0.0637(4) 0.8591(3) 0.0790(2) 0.0572(10) Uani 1 1 d . . .
H19A H -0.0182 0.8465 0.0851 0.069 Uiso 1 1 calc R . .
C20 C 0.1601(3) 0.8560(3) 0.1342(2) 0.0476(8) Uani 1 1 d . . .
H20A H 0.1427 0.8406 0.1776 0.057 Uiso 1 1 calc R . .
C21 C 0.4356(3) 0.9885(2) 0.26087(18) 0.0403(8) Uani 1 1 d . . .
C22 C 0.3405(4) 1.0358(3) 0.2721(2) 0.0657(12) Uani 1 1 d . . .
H22A H 0.2597 1.0076 0.2467 0.079 Uiso 1 1 calc R . .
C23 C 0.3635(6) 1.1250(4) 0.3207(3) 0.0816(15) Uani 1 1 d . . .
H23A H 0.2983 1.1556 0.3287 0.098 Uiso 1 1 calc R . .
C24 C 0.4827(6) 1.1675(4) 0.3568(3) 0.0791(15) Uani 1 1 d . . .
H24A H 0.4984 1.2271 0.3896 0.095 Uiso 1 1 calc R . .
C25 C 0.5786(5) 1.1239(4) 0.3454(3) 0.0765(14) Uani 1 1 d . . .
H25A H 0.6597 1.1547 0.3691 0.092 Uiso 1 1 calc R . .
C26 C 0.5553(4) 1.0332(3) 0.2981(2) 0.0669(12) Uani 1 1 d . . .
H26A H 0.6208 1.0022 0.2915 0.080 Uiso 1 1 calc R . .
C27 C 0.2052(4) 0.6155(3) 0.1079(2) 0.0480(9) Uani 1 1 d . . .
C28 C 0.1054(4) 0.6170(3) 0.2225(2) 0.0530(9) Uani 1 1 d . . .
C29 C 0.6339(3) 0.7475(2) 0.28325(18) 0.0399(7) Uani 1 1 d . . .
C30 C 0.4907(3) 0.6511(3) 0.13510(19) 0.0410(8) Uani 1 1 d . . .
C31 C 0.1201(3) 0.3877(3) 0.2529(2) 0.0439(8) Uani 1 1 d . . .
C32 C 0.0040(4) 0.3532(4) 0.2094(3) 0.0696(13) Uani 1 1 d . . .
H32A H -0.0059 0.3540 0.1608 0.084 Uiso 1 1 calc R . .
C33 C -0.0994(4) 0.3167(4) 0.2388(3) 0.0848(16) Uani 1 1 d . . .
H33A H -0.1779 0.2935 0.2094 0.102 Uiso 1 1 calc R . .
C34 C -0.0865(5) 0.3149(4) 0.3087(3) 0.0761(14) Uani 1 1 d . . .
H34A H -0.1560 0.2916 0.3276 0.091 Uiso 1 1 calc R . .
C35 C 0.0275(5) 0.3468(4) 0.3519(3) 0.0789(15) Uani 1 1 d . . .
H35A H 0.0362 0.3441 0.4002 0.095 Uiso 1 1 calc R . .
C36 C 0.1327(4) 0.3839(3) 0.3245(2) 0.0634(11) Uani 1 1 d . . .
H36A H 0.2107 0.4060 0.3545 0.076 Uiso 1 1 calc R . .
C37 C 0.2443(3) 0.3521(3) 0.13965(17) 0.0391(7) Uani 1 1 d . . .
C38 C 0.2219(4) 0.2464(3) 0.1478(2) 0.0515(9) Uani 1 1 d . . .
H38A H 0.2001 0.2250 0.1891 0.062 Uiso 1 1 calc R . .
C39 C 0.2319(4) 0.1728(3) 0.0953(2) 0.0578(10) Uani 1 1 d . . .
H39A H 0.2179 0.1023 0.1017 0.069 Uiso 1 1 calc R . .
C40 C 0.2623(4) 0.2028(3) 0.0336(2) 0.0610(11) Uani 1 1 d . . .
H40A H 0.2681 0.1528 -0.0018 0.073 Uiso 1 1 calc R . .
C41 C 0.2840(4) 0.3071(3) 0.0246(2) 0.0582(10) Uani 1 1 d . . .
H41A H 0.3047 0.3278 -0.0170 0.070 Uiso 1 1 calc R . .
C42 C 0.2751(4) 0.3820(3) 0.07796(19) 0.0493(9) Uani 1 1 d . . .
H42A H 0.2901 0.4526 0.0717 0.059 Uiso 1 1 calc R . .
C43 C 0.6504(3) 0.5199(2) 0.33336(17) 0.0366(7) Uani 1 1 d . . .
C44 C 0.6258(4) 0.4891(3) 0.39672(18) 0.0483(9) Uani 1 1 d . . .
H44A H 0.5440 0.4639 0.4007 0.058 Uiso 1 1 calc R . .
C45 C 0.7239(4) 0.4960(3) 0.4545(2) 0.0601(11) Uani 1 1 d . . .
H45A H 0.7074 0.4768 0.4973 0.072 Uiso 1 1 calc R . .
C46 C 0.8429(4) 0.5308(4) 0.4481(2) 0.0677(12) Uani 1 1 d . . .
H46A H 0.9080 0.5350 0.4867 0.081 Uiso 1 1 calc R . .
C47 C 0.8688(4) 0.5598(3) 0.3860(2) 0.0632(11) Uani 1 1 d . . .
H47A H 0.9511 0.5823 0.3820 0.076 Uiso 1 1 calc R . .
C48 C 0.7726(3) 0.5558(3) 0.32867(19) 0.0487(9) Uani 1 1 d . . .
H48A H 0.7905 0.5774 0.2867 0.058 Uiso 1 1 calc R . .
C49 C 0.5766(3) 0.4383(2) 0.18894(16) 0.0374(7) Uani 1 1 d . . .
C50 C 0.5430(3) 0.3299(3) 0.1790(2) 0.0496(9) Uani 1 1 d . . .
H50A H 0.4938 0.2951 0.2071 0.059 Uiso 1 1 calc R . .
C51 C 0.5824(4) 0.2727(3) 0.1274(2) 0.0640(12) Uani 1 1 d . . .
H51A H 0.5580 0.2000 0.1202 0.077 Uiso 1 1 calc R . .
C52 C 0.6574(5) 0.3234(4) 0.0869(2) 0.0742(14) Uani 1 1 d . . .
H52A H 0.6830 0.2849 0.0521 0.089 Uiso 1 1 calc R . .
C53 C 0.6945(5) 0.4300(4) 0.0973(2) 0.0670(12) Uani 1 1 d . . .
H53A H 0.7466 0.4638 0.0703 0.080 Uiso 1 1 calc R . .
C54 C 0.6549(4) 0.4884(3) 0.14810(18) 0.0474(9) Uani 1 1 d . . .
H54A H 0.6806 0.5611 0.1550 0.057 Uiso 1 1 calc R . .
C55 C 0.3887(3) 0.4383(3) 0.27651(18) 0.0365(7) Uani 1 1 d . . .
H55A H 0.384(3) 0.470(3) 0.318(2) 0.045(10) Uiso 1 1 d . . .
H55B H 0.389(3) 0.367(3) 0.2767(18) 0.046(10) Uiso 1 1 d . . .
C100 C -0.1066(5) 1.0354(4) 0.2708(3) 0.0842(15) Uani 1 1 d . . .
H10B H -0.1449 0.9624 0.2536 0.101 Uiso 1 1 calc R . .
H10C H -0.1623 1.0773 0.2494 0.101 Uiso 1 1 calc R . .
Cl3 Cl 0.03036(19) 1.06660(15) 0.24296(16) 0.1620(10) Uani 1 1 d . . .
Cl4 Cl -0.09347(18) 1.05404(13) 0.36101(10) 0.1134(5) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pd Pd -0.9988 1.0072 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P2 Pd Cl2 92.04(3) . . ?
P2 Pd Cl1 171.98(3) . . ?
Cl2 Pd Cl1 94.58(4) . . ?
P2 Pd C30 93.74(8) . . ?
Cl2 Pd C30 143.00(9) . . ?
Cl1 Pd C30 83.69(8) . . ?
P2 Pd C29 93.99(8) . . ?
Cl2 Pd C29 140.80(9) . . ?
Cl1 Pd C29 78.02(8) . . ?
C30 Pd C29 75.12(11) . . ?
P2 Pd Co2 75.90(2) . . ?
Cl2 Pd Co2 167.85(3) . . ?
Cl1 Pd Co2 97.33(3) . . ?
C30 Pd Co2 41.73(8) . . ?
C29 Pd Co2 41.15(8) . . ?
C28 Co1 C27 95.68(18) . . ?
C28 Co1 C2 106.33(15) . . ?
C27 Co1 C2 105.41(15) . . ?
C28 Co1 C1 102.32(16) . . ?
C27 Co1 C1 144.78(15) . . ?
C2 Co1 C1 40.48(13) . . ?
C28 Co1 P3 94.99(12) . . ?
C27 Co1 P3 103.15(12) . . ?
C2 Co1 P3 142.10(10) . . ?
C1 Co1 P3 105.11(9) . . ?
C28 Co1 Co2 153.40(13) . . ?
C27 Co1 Co2 105.84(12) . . ?
C2 Co1 Co2 53.30(9) . . ?
C1 Co1 Co2 51.22(9) . . ?
P3 Co1 Co2 95.12(3) . . ?
C30 Co2 C29 114.12(15) . . ?
C30 Co2 C1 138.93(15) . . ?
C29 Co2 C1 100.08(14) . . ?
C30 Co2 C2 106.25(14) . . ?
C29 Co2 C2 107.03(14) . . ?
C1 Co2 C2 38.94(12) . . ?
C30 Co2 P4 97.66(11) . . ?
C29 Co2 P4 93.69(11) . . ?
C1 Co2 P4 102.28(9) . . ?
C2 Co2 P4 137.71(9) . . ?
C30 Co2 Co1 91.64(11) . . ?
C29 Co2 Co1 150.31(10) . . ?
C1 Co2 Co1 50.63(9) . . ?
C2 Co2 Co1 48.62(9) . . ?
P4 Co2 Co1 97.35(3) . . ?
C30 Co2 Pd 63.70(11) . . ?
C29 Co2 Pd 67.62(10) . . ?
C1 Co2 Pd 113.99(9) . . ?
C2 Co2 Pd 81.07(8) . . ?
P4 Co2 Pd 141.21(3) . . ?
Co1 Co2 Pd 115.846(19) . . ?
O5 P1 C1 112.52(13) . . ?
O5 P1 C9 110.44(16) . . ?
C1 P1 C9 108.58(15) . . ?
O5 P1 C3 111.92(15) . . ?
C1 P1 C3 106.81(16) . . ?
C9 P1 C3 106.29(16) . . ?
C2 P2 C15 105.44(15) . . ?
C2 P2 C21 111.77(14) . . ?
C15 P2 C21 107.90(15) . . ?
C2 P2 Pd 100.36(10) . . ?
C15 P2 Pd 118.08(11) . . ?
C21 P2 Pd 112.84(12) . . ?
C55 P3 C37 102.50(16) . . ?
C55 P3 C31 104.70(16) . . ?
C37 P3 C31 103.27(16) . . ?
C55 P3 Co1 109.28(11) . . ?
C37 P3 Co1 121.79(11) . . ?
C31 P3 Co1 113.57(11) . . ?
C49 P4 C43 101.11(15) . . ?
C49 P4 C55 107.80(16) . . ?
C43 P4 C55 104.04(15) . . ?
C49 P4 Co2 116.34(11) . . ?
C43 P4 Co2 117.40(10) . . ?
C55 P4 Co2 109.06(12) . . ?
C2 C1 P1 143.2(2) . . ?
C2 C1 Co1 67.45(19) . . ?
P1 C1 Co1 132.90(17) . . ?
C2 C1 Co2 72.82(18) . . ?
P1 C1 Co2 134.14(18) . . ?
Co1 C1 Co2 78.14(11) . . ?
C1 C2 P2 149.1(3) . . ?
C1 C2 Co1 72.07(19) . . ?
P2 C2 Co1 136.81(19) . . ?
C1 C2 Co2 68.24(18) . . ?
P2 C2 Co2 102.65(14) . . ?
Co1 C2 Co2 78.08(11) . . ?
C4 C3 C8 118.3(3) . . ?
C4 C3 P1 125.2(3) . . ?
C8 C3 P1 116.5(3) . . ?
C3 C4 C5 121.5(4) . . ?
C6 C5 C4 120.0(5) . . ?
C7 C6 C5 119.7(4) . . ?
C6 C7 C8 121.0(4) . . ?
C3 C8 C7 119.4(4) . . ?
C14 C9 C10 118.8(4) . . ?
C14 C9 P1 123.7(3) . . ?
C10 C9 P1 117.5(3) . . ?
C11 C10 C9 120.8(4) . . ?
C12 C11 C10 119.1(5) . . ?
C13 C12 C11 121.3(5) . . ?
C12 C13 C14 119.8(5) . . ?
C9 C14 C13 120.2(4) . . ?
C20 C15 C16 119.7(3) . . ?
C20 C15 P2 120.5(3) . . ?
C16 C15 P2 119.8(3) . . ?
C17 C16 C15 119.3(3) . . ?
C18 C17 C16 120.9(4) . . ?
C17 C18 C19 120.1(4) . . ?
C20 C19 C18 119.2(4) . . ?
C19 C20 C15 120.9(3) . . ?
C22 C21 C26 118.4(4) . . ?
C22 C21 P2 122.0(3) . . ?
C26 C21 P2 119.6(3) . . ?
C21 C22 C23 120.9(4) . . ?
C24 C23 C22 119.4(5) . . ?
C25 C24 C23 120.8(4) . . ?
C24 C25 C26 119.8(5) . . ?
C21 C26 C25 120.6(4) . . ?
O1 C27 Co1 176.4(4) . . ?
O2 C28 Co1 178.1(4) . . ?
O3 C29 Co2 171.9(3) . . ?
O3 C29 Pd 116.4(2) . . ?
Co2 C29 Pd 71.24(12) . . ?
O4 C30 Co2 170.3(3) . . ?
O4 C30 Pd 114.1(2) . . ?
Co2 C30 Pd 74.57(12) . . ?
C32 C31 C36 119.1(3) . . ?
C32 C31 P3 118.5(3) . . ?
C36 C31 P3 122.2(3) . . ?
C31 C32 C33 119.5(4) . . ?
C34 C33 C32 120.9(5) . . ?
C33 C34 C35 120.0(4) . . ?
C34 C35 C36 120.7(5) . . ?
C31 C36 C35 119.8(4) . . ?
C42 C37 C38 118.9(3) . . ?
C42 C37 P3 121.6(3) . . ?
C38 C37 P3 119.2(3) . . ?
C39 C38 C37 120.5(4) . . ?
C40 C39 C38 120.5(4) . . ?
C39 C40 C41 119.7(4) . . ?
C40 C41 C42 120.0(4) . . ?
C37 C42 C41 120.4(3) . . ?
C48 C43 C44 118.8(3) . . ?
C48 C43 P4 118.3(3) . . ?
C44 C43 P4 122.9(3) . . ?
C43 C44 C45 120.0(4) . . ?
C46 C45 C44 119.9(4) . . ?
C45 C46 C47 120.9(4) . . ?
C46 C47 C48 120.0(4) . . ?
C43 C48 C47 120.5(4) . . ?
C50 C49 C54 118.7(3) . . ?
C50 C49 P4 122.1(3) . . ?
C54 C49 P4 119.1(2) . . ?
C49 C50 C51 120.3(4) . . ?
C52 C51 C50 120.2(4) . . ?
C53 C52 C51 120.4(4) . . ?
C52 C53 C54 120.3(4) . . ?
C53 C54 C49 120.2(4) . . ?
P3 C55 P4 110.83(17) . . ?
Cl3 C100 Cl4 115.2(3) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pd P2 2.2050(9) . ?
Pd Cl2 2.3282(9) . ?
Pd Cl1 2.3997(9) . ?
Pd C30 2.434(3) . ?
Pd C29 2.556(3) . ?
Pd Co2 2.6171(5) . ?
Co1 C28 1.793(4) . ?
Co1 C27 1.810(4) . ?
Co1 C2 1.917(3) . ?
Co1 C1 1.975(3) . ?
Co1 P3 2.2416(9) . ?
Co1 Co2 2.4999(6) . ?
Co2 C30 1.807(4) . ?
Co2 C29 1.819(4) . ?
Co2 C1 1.991(3) . ?
Co2 C2 2.049(3) . ?
Co2 P4 2.2480(9) . ?
P1 O5 1.482(2) . ?
P1 C1 1.789(3) . ?
P1 C9 1.802(4) . ?
P1 C3 1.813(3) . ?
P2 C2 1.766(3) . ?
P2 C15 1.813(4) . ?
P2 C21 1.821(3) . ?
P3 C55 1.816(4) . ?
P3 C37 1.829(3) . ?
P3 C31 1.828(3) . ?
P4 C49 1.822(3) . ?
P4 C43 1.827(3) . ?
P4 C55 1.822(3) . ?
O1 C27 1.130(4) . ?
O2 C28 1.129(5) . ?
O3 C29 1.131(4) . ?
O4 C30 1.149(4) . ?
C1 C2 1.348(4) . ?
C3 C4 1.359(5) . ?
C3 C8 1.392(5) . ?
C4 C5 1.376(6) . ?
C5 C6 1.365(7) . ?
C6 C7 1.346(7) . ?
C7 C8 1.394(6) . ?
C9 C14 1.378(5) . ?
C9 C10 1.386(6) . ?
C10 C11 1.381(6) . ?
C11 C12 1.363(7) . ?
C12 C13 1.359(7) . ?
C13 C14 1.385(6) . ?
C15 C20 1.383(5) . ?
C15 C16 1.392(4) . ?
C16 C17 1.380(5) . ?
C17 C18 1.374(6) . ?
C18 C19 1.391(5) . ?
C19 C20 1.379(5) . ?
C21 C22 1.375(5) . ?
C21 C26 1.382(6) . ?
C22 C23 1.388(6) . ?
C23 C24 1.367(7) . ?
C24 C25 1.357(7) . ?
C25 C26 1.386(6) . ?
C31 C32 1.376(5) . ?
C31 C36 1.376(5) . ?
C32 C33 1.406(6) . ?
C33 C34 1.341(7) . ?
C34 C35 1.352(7) . ?
C35 C36 1.400(6) . ?
C37 C42 1.376(5) . ?
C37 C38 1.389(5) . ?
C38 C39 1.377(5) . ?
C39 C40 1.375(6) . ?
C40 C41 1.374(6) . ?
C41 C42 1.396(5) . ?
C43 C48 1.379(5) . ?
C43 C44 1.387(5) . ?
C44 C45 1.396(5) . ?
C45 C46 1.353(6) . ?
C46 C47 1.362(6) . ?
C47 C48 1.383(5) . ?
C49 C50 1.383(5) . ?
C49 C54 1.398(5) . ?
C50 C51 1.390(5) . ?
C51 C52 1.372(7) . ?
C52 C53 1.363(7) . ?
C53 C54 1.386(5) . ?
C100 Cl3 1.707(5) . ?
C100 Cl4 1.721(6) . ?
