#------------------------------------------------------------------------------
#$Date: 2016-03-25 13:23:34 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179841 $
#$URL: svn://www.crystallography.net/cod/cif/7/01/37/7013766.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7013766
loop_
_publ_author_name
'Zhang, Kehua'
'Zhang, Wu'
'Wang, Shaowu'
'Sheng, Enhong'
'Yang, Gaosheng'
'Xie, Meihua'
'Zhou, Shuangliu'
'Feng, Yan'
'Mao, Lili'
'Huang, Zixiang'
_publ_section_title
;
 Homolysis of the Ln-N (Ln = Yb, Eu) bond. Synthesis, structural
 characterization and catalytic activity of ytterbium(II) and
 europium(II) complexes with methoxyethyl functionalized indenyl
 ligands.
;
_journal_issue                   7
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              1029
_journal_page_last               1037
_journal_paper_doi               10.1039/b314115b
_journal_year                    2004
_chemical_formula_sum            'C30 H42 Eu O2 Si2'
_chemical_formula_weight         642.78
_chemical_name_systematic
;
?
;
_space_group_IT_number           4
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  'P 2yb'
_symmetry_space_group_name_H-M   'P 1 21 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 95.4450(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   10.5365(3)
_cell_length_b                   16.2922(5)
_cell_length_c                   18.6379(6)
_cell_measurement_reflns_used    7549
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      24.92
_cell_measurement_theta_min      1.66
_cell_volume                     3185.00(17)
_computing_cell_refinement       'Siemens SMART & SAINT'
_computing_data_collection       'Siemens SMART'
_computing_data_reduction        'Siemens SMART & SAINT'
_computing_molecular_graphics    'SHELXL-97 (Sheldrick, 1997)'
_computing_publication_material  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.984
_diffrn_measured_fraction_theta_max 0.984
_diffrn_measurement_device_type  'SMART CCD'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0298
_diffrn_reflns_av_sigmaI/netI    0.0393
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            10892
_diffrn_reflns_theta_full        24.92
_diffrn_reflns_theta_max         24.92
_diffrn_reflns_theta_min         1.66
_diffrn_standards_decay_%        0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    2.067
_exptl_absorpt_correction_T_max  1.0000
_exptl_absorpt_correction_T_min  0.5639
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   'SADABS (Sheldrick, 1996)'
_exptl_crystal_density_diffrn    1.340
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1316
_exptl_crystal_size_max          0.98
_exptl_crystal_size_mid          0.34
_exptl_crystal_size_min          0.26
_refine_diff_density_max         0.659
_refine_diff_density_min         -0.644
_refine_diff_density_rms         0.089
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.009(14)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.133
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     632
_refine_ls_number_reflns         8612
_refine_ls_number_restraints     1
_refine_ls_restrained_S_all      1.133
_refine_ls_R_factor_all          0.0480
_refine_ls_R_factor_gt           0.0397
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0000P)²+9.8667P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0786
_refine_ls_wR_factor_ref         0.0850
_reflns_number_gt                7922
_reflns_number_total             8612
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b314115b.txt
_cod_data_source_block           compound_3
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      P2(1)
_cod_database_code               7013766
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.05607(4) 0.43102(2) 0.36741(2) 0.04555(12) Uani 1 1 d . . .
Eu2 Eu 0.52453(4) 0.06989(2) 0.09760(2) 0.04269(11) Uani 1 1 d . . .
Si1 Si 0.3418(3) 0.26100(19) 0.43525(16) 0.0686(8) Uani 1 1 d . . .
Si2 Si -0.0899(3) 0.66352(18) 0.30027(14) 0.0635(8) Uani 1 1 d . . .
Si3 Si 0.8122(3) 0.17942(16) -0.01103(13) 0.0562(7) Uani 1 1 d . . .
Si4 Si 0.4024(4) -0.10054(19) 0.24559(18) 0.0804(9) Uani 1 1 d . . .
O1 O -0.1303(7) 0.3965(5) 0.2739(4) 0.085(2) Uani 1 1 d . . .
O2 O -0.0603(7) 0.3486(4) 0.4617(4) 0.074(2) Uani 1 1 d . . .
O3 O 0.3477(6) 0.1517(4) 0.1511(4) 0.073(2) Uani 1 1 d . . .
O4 O 0.3858(7) 0.0966(4) -0.0238(4) 0.075(2) Uani 1 1 d . . .
C1 C -0.2596(11) 0.4021(9) 0.2894(8) 0.118(6) Uani 1 1 d . . .
H1A H -0.3145 0.3866 0.2476 0.177 Uiso 1 1 calc R . .
H1B H -0.2781 0.4574 0.3026 0.177 Uiso 1 1 calc R . .
H1C H -0.2734 0.3659 0.3286 0.177 Uiso 1 1 calc R . .
C2 C -0.1103(13) 0.3576(11) 0.2097(8) 0.116(6) Uani 1 1 d . . .
H2A H -0.1833 0.3223 0.1975 0.140 Uiso 1 1 calc R . .
H2B H -0.1125 0.3997 0.1728 0.140 Uiso 1 1 calc R . .
C3 C -0.0072(16) 0.3128(12) 0.2034(9) 0.175(10) Uani 1 1 d . . .
H3A H 0.0184 0.3223 0.1555 0.209 Uiso 1 1 calc R . .
H3B H -0.0323 0.2557 0.2055 0.209 Uiso 1 1 calc R . .
C4 C 0.1082(11) 0.3238(8) 0.2552(6) 0.076(3) Uani 1 1 d . . .
C5 C 0.1455(9) 0.2793(6) 0.3165(6) 0.065(3) Uani 1 1 d . . .
H5A H 0.1084 0.2261 0.3274 0.078 Uiso 1 1 calc R . .
C6 C 0.2544(8) 0.3122(6) 0.3560(5) 0.049(2) Uani 1 1 d . . .
C7 C 0.2931(9) 0.3813(6) 0.3147(5) 0.053(2) Uani 1 1 d . . .
C8 C 0.1981(11) 0.3866(7) 0.2512(5) 0.073(4) Uani 1 1 d . . .
C9 C 0.2193(17) 0.4498(12) 0.2020(8) 0.128(7) Uani 1 1 d . . .
H9A H 0.1637 0.4556 0.1605 0.154 Uiso 1 1 calc R . .
C10 C 0.318(2) 0.5015(12) 0.2137(12) 0.158(12) Uani 1 1 d . . .
H10A H 0.3257 0.5430 0.1802 0.190 Uiso 1 1 calc R . .
C11 C 0.4077(16) 0.4970(10) 0.2724(12) 0.131(7) Uani 1 1 d . . .
H11A H 0.4759 0.5335 0.2769 0.157 Uiso 1 1 calc R . .
C12 C 0.3951(10) 0.4361(8) 0.3261(7) 0.082(3) Uani 1 1 d . . .
H12A H 0.4525 0.4329 0.3671 0.098 Uiso 1 1 calc R . .
C13 C 0.2949(17) 0.2995(11) 0.5216(6) 0.145(7) Uani 1 1 d . . .
H13A H 0.3126 0.3572 0.5255 0.217 Uiso 1 1 calc R . .
H13B H 0.3422 0.2710 0.5606 0.217 Uiso 1 1 calc R . .
H13C H 0.2053 0.2904 0.5239 0.217 Uiso 1 1 calc R . .
C14 C 0.3065(18) 0.1480(9) 0.4305(9) 0.156(7) Uani 1 1 d . . .
H14A H 0.2167 0.1394 0.4319 0.234 Uiso 1 1 calc R . .
H14B H 0.3522 0.1208 0.4707 0.234 Uiso 1 1 calc R . .
H14C H 0.3327 0.1261 0.3864 0.234 Uiso 1 1 calc R . .
C15 C 0.5165(12) 0.2725(14) 0.4329(9) 0.192(11) Uani 1 1 d . . .
H15A H 0.5387 0.3296 0.4356 0.288 Uiso 1 1 calc R . .
H15B H 0.5414 0.2497 0.3889 0.288 Uiso 1 1 calc R . .
H15C H 0.5599 0.2440 0.4732 0.288 Uiso 1 1 calc R . .
C16 C -0.1001(14) 0.2649(8) 0.4514(8) 0.111(5) Uani 1 1 d . . .
H16A H -0.1409 0.2467 0.4925 0.167 Uiso 1 1 calc R . .
H16B H -0.0270 0.2311 0.4459 0.167 Uiso 1 1 calc R . .
H16C H -0.1588 0.2608 0.4090 0.167 Uiso 1 1 calc R . .
C17 C -0.1254(13) 0.3909(9) 0.5152(7) 0.098(4) Uani 1 1 d . . .
H17A H -0.1365 0.3537 0.5548 0.117 Uiso 1 1 calc R . .
H17B H -0.2094 0.4071 0.4942 0.117 Uiso 1 1 calc R . .
C18 C -0.0549(16) 0.4653(8) 0.5439(6) 0.106(5) Uani 1 1 d . . .
H18A H 0.0214 0.4482 0.5733 0.128 Uiso 1 1 calc R . .
H18B H -0.1080 0.4954 0.5746 0.128 Uiso 1 1 calc R . .
C19 C -0.0170(13) 0.5225(6) 0.4842(5) 0.070(3) Uani 1 1 d . . .
C20 C -0.0964(10) 0.5564(7) 0.4273(5) 0.064(3) Uani 1 1 d . . .
H20A H -0.1898 0.5555 0.4244 0.077 Uiso 1 1 calc R . .
C21 C -0.0255(10) 0.6003(5) 0.3793(5) 0.053(2) Uani 1 1 d . . .
C22 C 0.1070(11) 0.5969(6) 0.4115(5) 0.059(3) Uani 1 1 d . . .
C23 C 0.1098(12) 0.5480(6) 0.4766(5) 0.068(3) Uani 1 1 d . . .
C24 C 0.2280(15) 0.5307(8) 0.5167(6) 0.090(4) Uani 1 1 d . . .
H24A H 0.2322 0.4975 0.5574 0.108 Uiso 1 1 calc R . .
C25 C 0.3342(15) 0.5642(10) 0.4936(7) 0.105(4) Uani 1 1 d . . .
H25A H 0.4120 0.5536 0.5199 0.126 Uiso 1 1 calc R . .
C26 C 0.3333(13) 0.6146(8) 0.4314(8) 0.099(4) Uani 1 1 d . . .
H26A H 0.4088 0.6372 0.4183 0.119 Uiso 1 1 calc R . .
C27 C 0.2192(12) 0.6300(7) 0.3906(7) 0.080(4) Uani 1 1 d . . .
H27A H 0.2177 0.6623 0.3494 0.096 Uiso 1 1 calc R . .
C28 C -0.0167(14) 0.6336(9) 0.2161(6) 0.111(5) Uani 1 1 d . . .
H28A H -0.0325 0.5764 0.2064 0.167 Uiso 1 1 calc R . .
H28B H 0.0735 0.6432 0.2226 0.167 Uiso 1 1 calc R . .
H28C H -0.0538 0.6658 0.1764 0.167 Uiso 1 1 calc R . .
C29 C -0.2645(12) 0.6481(10) 0.2848(7) 0.115(5) Uani 1 1 d . . .
H29A H -0.3037 0.6645 0.3270 0.173 Uiso 1 1 calc R . .
H29B H -0.2822 0.5912 0.2750 0.173 Uiso 1 1 calc R . .
H29C H -0.2980 0.6806 0.2444 0.173 Uiso 1 1 calc R . .
C30 C -0.0576(15) 0.7752(7) 0.3175(7) 0.114(5) Uani 1 1 d . . .
H30A H -0.0953 0.7919 0.3601 0.170 Uiso 1 1 calc R . .
H30B H -0.0939 0.8067 0.2771 0.170 Uiso 1 1 calc R . .
H30C H 0.0327 0.7843 0.3240 0.170 Uiso 1 1 calc R . .
C31 C 0.2178(11) 0.1397(10) 0.1374(9) 0.129(6) Uani 1 1 d . . .
H31A H 0.1734 0.1784 0.1647 0.193 Uiso 1 1 calc R . .
H31B H 0.1966 0.0849 0.1511 0.193 Uiso 1 1 calc R . .
H31C H 0.1931 0.1473 0.0870 0.193 Uiso 1 1 calc R . .
C32 C 0.3816(16) 0.2181(13) 0.1935(15) 0.253(17) Uani 1 1 d . . .
H32A H 0.3103 0.2559 0.1871 0.304 Uiso 1 1 calc R . .
H32B H 0.3850 0.1988 0.2429 0.304 Uiso 1 1 calc R . .
C33 C 0.4861(10) 0.2635(6) 0.1896(6) 0.069(3) Uani 1 1 d . . .
H33A H 0.5151 0.2818 0.2379 0.083 Uiso 1 1 calc R . .
H33B H 0.4622 0.3120 0.1613 0.083 Uiso 1 1 calc R . .
C34 C 0.5969(8) 0.2240(5) 0.1579(5) 0.048(2) Uani 1 1 d . . .
C35 C 0.6283(8) 0.2289(5) 0.0869(5) 0.045(2) Uani 1 1 d . . .
H35A H 0.5925 0.2703 0.0525 0.054 Uiso 1 1 calc R . .
C36 C 0.7335(8) 0.1784(5) 0.0743(4) 0.046(2) Uani 1 1 d . . .
C37 C 0.7730(9) 0.1404(5) 0.1422(4) 0.047(2) Uani 1 1 d . . .
C38 C 0.6897(9) 0.1707(5) 0.1942(4) 0.050(2) Uani 1 1 d . . .
C39 C 0.7137(10) 0.1443(7) 0.2679(5) 0.066(3) Uani 1 1 d . . .
H39A H 0.6589 0.1610 0.3013 0.079 Uiso 1 1 calc R . .
C40 C 0.8155(11) 0.0951(7) 0.2899(5) 0.077(4) Uani 1 1 d . . .
H40A H 0.8337 0.0821 0.3384 0.093 Uiso 1 1 calc R . .
C41 C 0.8924(10) 0.0646(8) 0.2379(5) 0.081(3) Uani 1 1 d . . .
H41A H 0.9577 0.0281 0.2526 0.097 Uiso 1 1 calc R . .
C42 C 0.8745(9) 0.0866(6) 0.1663(5) 0.064(3) Uani 1 1 d . . .
H42A H 0.9285 0.0663 0.1338 0.077 Uiso 1 1 calc R . .
C43 C 0.6863(12) 0.1928(7) -0.0897(5) 0.087(4) Uani 1 1 d . . .
H43A H 0.6390 0.2422 -0.0833 0.130 Uiso 1 1 calc R . .
H43B H 0.6295 0.1466 -0.0921 0.130 Uiso 1 1 calc R . .
H43C H 0.7267 0.1964 -0.1337 0.130 Uiso 1 1 calc R . .
C44 C 0.9258(12) 0.2676(7) -0.0125(6) 0.092(4) Uani 1 1 d . . .
H44A H 0.9912 0.2623 0.0267 0.138 Uiso 1 1 calc R . .
H44B H 0.8805 0.3181 -0.0077 0.138 Uiso 1 1 calc R . .
H44C H 0.9638 0.2676 -0.0573 0.138 Uiso 1 1 calc R . .
C45 C 0.9040(11) 0.0820(7) -0.0252(5) 0.087(3) Uani 1 1 d . . .
H45A H 0.9683 0.0744 0.0144 0.131 Uiso 1 1 calc R . .
H45B H 0.9438 0.0859 -0.0693 0.131 Uiso 1 1 calc R . .
H45C H 0.8467 0.0360 -0.0278 0.131 Uiso 1 1 calc R . .
C46 C 0.3411(15) 0.1757(7) -0.0476(7) 0.099(5) Uani 1 1 d . . .
H46A H 0.2927 0.1707 -0.0937 0.149 Uiso 1 1 calc R . .
H46B H 0.4126 0.2113 -0.0518 0.149 Uiso 1 1 calc R . .
H46C H 0.2881 0.1982 -0.0134 0.149 Uiso 1 1 calc R . .
C47 C 0.341(2) 0.0332(8) -0.0670(8) 0.195(11) Uani 1 1 d . . .
H47A H 0.2503 0.0434 -0.0784 0.234 Uiso 1 1 calc R . .
H47B H 0.3797 0.0390 -0.1118 0.234 Uiso 1 1 calc R . .
C48 C 0.3519(15) -0.0467(7) -0.0483(6) 0.101(5) Uani 1 1 d . . .
H48A H 0.4001 -0.0736 -0.0833 0.122 Uiso 1 1 calc R . .
H48B H 0.2670 -0.0704 -0.0533 0.122 Uiso 1 1 calc R . .
C49 C 0.4131(10) -0.0693(6) 0.0259(5) 0.061(2) Uani 1 1 d . . .
C50 C 0.3534(9) -0.0671(7) 0.0894(6) 0.067(3) Uani 1 1 d . . .
H50A H 0.2610 -0.0625 0.0912 0.081 Uiso 1 1 calc R . .
C51 C 0.4420(10) -0.0862(6) 0.1508(5) 0.057(3) Uani 1 1 d . . .
C52 C 0.5610(10) -0.1022(5) 0.1214(5) 0.052(2) Uani 1 1 d . . .
C53 C 0.5427(10) -0.0918(5) 0.0446(5) 0.050(2) Uani 1 1 d . . .
C54 C 0.6501(15) -0.0988(6) 0.0032(7) 0.087(4) Uani 1 1 d . . .
H54A H 0.6403 -0.0895 -0.0462 0.104 Uiso 1 1 calc R . .
C55 C 0.7687(14) -0.1194(7) 0.0372(9) 0.099(4) Uani 1 1 d . . .
H55A H 0.8385 -0.1257 0.0107 0.119 Uiso 1 1 calc R . .
C56 C 0.7813(13) -0.1305(7) 0.1116(9) 0.091(4) Uani 1 1 d . . .
H56A H 0.8611 -0.1448 0.1337 0.109 Uiso 1 1 calc R . .
C57 C 0.6845(11) -0.1217(6) 0.1535(7) 0.071(3) Uani 1 1 d . . .
H57A H 0.6989 -0.1284 0.2032 0.086 Uiso 1 1 calc R . .
C58 C 0.4267(18) -0.2059(9) 0.2775(7) 0.142(7) Uani 1 1 d . . .
H58A H 0.5143 -0.2211 0.2754 0.212 Uiso 1 1 calc R . .
H58B H 0.3730 -0.2423 0.2476 0.212 Uiso 1 1 calc R . .
H58C H 0.4056 -0.2099 0.3264 0.212 Uiso 1 1 calc R . .
C59 C 0.494(2) -0.0320(11) 0.3108(8) 0.200(11) Uani 1 1 d . . .
H59A H 0.5839 -0.0428 0.3102 0.300 Uiso 1 1 calc R . .
H59B H 0.4698 -0.0419 0.3584 0.300 Uiso 1 1 calc R . .
H59C H 0.4773 0.0242 0.2978 0.300 Uiso 1 1 calc R . .
C60 C 0.2274(17) -0.0778(18) 0.2482(10) 0.235(13) Uani 1 1 d . . .
H60A H 0.1783 -0.1130 0.2149 0.353 Uiso 1 1 calc R . .
H60B H 0.2111 -0.0215 0.2350 0.353 Uiso 1 1 calc R . .
H60C H 0.2037 -0.0871 0.2960 0.353 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Eu1 O2 88.1(3) . . ?
O1 Eu1 C19 113.3(3) . . ?
O2 Eu1 C19 64.5(3) . . ?
O1 Eu1 C23 137.0(3) . . ?
O2 Eu1 C23 86.4(3) . . ?
C19 Eu1 C23 29.3(3) . . ?
O1 Eu1 C4 63.2(3) . . ?
O2 Eu1 C4 108.5(3) . . ?
C19 Eu1 C4 172.8(4) . . ?
C23 Eu1 C4 156.8(4) . . ?
O1 Eu1 C8 81.4(3) . . ?
O2 Eu1 C8 134.3(3) . . ?
C19 Eu1 C8 158.4(4) . . ?
C23 Eu1 C8 129.9(4) . . ?
C4 Eu1 C8 28.7(3) . . ?
O1 Eu1 C5 80.7(3) . . ?
O2 Eu1 C5 88.3(3) . . ?
C19 Eu1 C5 147.8(3) . . ?
C23 Eu1 C5 141.5(3) . . ?
C4 Eu1 C5 28.2(3) . . ?
C8 Eu1 C5 46.2(3) . . ?
O1 Eu1 C22 120.9(3) . . ?
O2 Eu1 C22 112.3(3) . . ?
C19 Eu1 C22 48.2(3) . . ?
C23 Eu1 C22 29.6(3) . . ?
C4 Eu1 C22 139.0(4) . . ?
C8 Eu1 C22 111.2(4) . . ?
C5 Eu1 C22 149.2(3) . . ?
O1 Eu1 C6 108.5(2) . . ?
O2 Eu1 C6 95.4(2) . . ?
C19 Eu1 C6 132.1(3) . . ?
C23 Eu1 C6 114.4(3) . . ?
C4 Eu1 C6 48.1(3) . . ?
C8 Eu1 C6 48.1(3) . . ?
C5 Eu1 C6 28.6(3) . . ?
C22 Eu1 C6 122.7(3) . . ?
O1 Eu1 C7 109.8(3) . . ?
O2 Eu1 C7 124.2(2) . . ?
C19 Eu1 C7 136.3(3) . . ?
C23 Eu1 C7 108.4(3) . . ?
C4 Eu1 C7 48.5(3) . . ?
C8 Eu1 C7 29.9(3) . . ?
C5 Eu1 C7 46.9(3) . . ?
C22 Eu1 C7 102.6(3) . . ?
C6 Eu1 C7 29.1(2) . . ?
O1 Eu1 C20 90.0(3) . . ?
O2 Eu1 C20 77.8(3) . . ?
C19 Eu1 C20 28.4(3) . . ?
C23 Eu1 C20 47.2(3) . . ?
C4 Eu1 C20 151.6(3) . . ?
C8 Eu1 C20 145.9(3) . . ?
C5 Eu1 C20 163.5(3) . . ?
C22 Eu1 C20 46.9(3) . . ?
C6 Eu1 C20 160.2(3) . . ?
C7 Eu1 C20 149.5(3) . . ?
O1 Eu1 C21 92.7(3) . . ?
O2 Eu1 C21 106.0(2) . . ?
C19 Eu1 C21 48.0(3) . . ?
C23 Eu1 C21 48.7(3) . . ?
C4 Eu1 C21 136.5(3) . . ?
C8 Eu1 C21 118.8(3) . . ?
C5 Eu1 C21 164.2(3) . . ?
C22 Eu1 C21 29.5(3) . . ?
C6 Eu1 C21 150.3(3) . . ?
C7 Eu1 C21 124.4(3) . . ?
C20 Eu1 C21 28.3(3) . . ?
O3 Eu2 O4 83.3(2) . . ?
O3 Eu2 C53 134.0(3) . . ?
O4 Eu2 C53 84.4(2) . . ?
O3 Eu2 C35 81.5(2) . . ?
O4 Eu2 C35 88.5(2) . . ?
C53 Eu2 C35 142.2(3) . . ?
O3 Eu2 C34 64.1(2) . . ?
O4 Eu2 C34 107.7(2) . . ?
C53 Eu2 C34 160.5(3) . . ?
C35 Eu2 C34 28.6(2) . . ?
O3 Eu2 C49 108.4(3) . . ?
O4 Eu2 C49 63.3(2) . . ?
C53 Eu2 C49 29.2(3) . . ?
C35 Eu2 C49 147.9(3) . . ?
C34 Eu2 C49 169.7(3) . . ?
O3 Eu2 C52 122.7(3) . . ?
O4 Eu2 C52 110.7(2) . . ?
C53 Eu2 C52 29.3(2) . . ?
C35 Eu2 C52 149.6(3) . . ?
C34 Eu2 C52 141.5(3) . . ?
C49 Eu2 C52 48.0(3) . . ?
O3 Eu2 C50 87.1(3) . . ?
O4 Eu2 C50 77.6(3) . . ?
C53 Eu2 C50 47.0(3) . . ?
C35 Eu2 C50 163.0(3) . . ?
C34 Eu2 C50 149.1(3) . . ?
C49 Eu2 C50 28.3(3) . . ?
C52 Eu2 C50 47.0(3) . . ?
O3 Eu2 C36 109.4(2) . . ?
O4 Eu2 C36 98.0(2) . . ?
C53 Eu2 C36 116.1(3) . . ?
C35 Eu2 C36 28.7(2) . . ?
C34 Eu2 C36 48.3(2) . . ?
C49 Eu2 C36 135.0(3) . . ?
C52 Eu2 C36 122.1(3) . . ?
C50 Eu2 C36 162.5(3) . . ?
O3 Eu2 C38 83.1(2) . . ?
O4 Eu2 C38 134.3(2) . . ?
C53 Eu2 C38 133.6(3) . . ?
C35 Eu2 C38 46.4(3) . . ?
C34 Eu2 C38 28.9(2) . . ?
C49 Eu2 C38 161.2(3) . . ?
C52 Eu2 C38 113.3(3) . . ?
C50 Eu2 C38 144.5(3) . . ?
C36 Eu2 C38 47.5(2) . . ?
O3 Eu2 C51 94.0(3) . . ?
O4 Eu2 C51 106.4(2) . . ?
C53 Eu2 C51 48.2(3) . . ?
C35 Eu2 C51 163.9(3) . . ?
C34 Eu2 C51 136.3(3) . . ?
C49 Eu2 C51 48.1(3) . . ?
C52 Eu2 C51 29.0(3) . . ?
C50 Eu2 C51 29.0(3) . . ?
C36 Eu2 C51 148.0(3) . . ?
C38 Eu2 C51 117.9(3) . . ?
O3 Eu2 C37 110.5(2) . . ?
O4 Eu2 C37 126.6(2) . . ?
C53 Eu2 C37 112.3(3) . . ?
C35 Eu2 C37 46.7(2) . . ?
C34 Eu2 C37 48.2(2) . . ?
C49 Eu2 C37 140.7(3) . . ?
C52 Eu2 C37 103.8(3) . . ?
C50 Eu2 C37 150.3(3) . . ?
C36 Eu2 C37 28.7(2) . . ?
C38 Eu2 C37 29.0(2) . . ?
C51 Eu2 C37 122.8(3) . . ?
C13 Si1 C15 109.6(9) . . ?
C13 Si1 C6 112.8(5) . . ?
C15 Si1 C6 110.7(5) . . ?
C13 Si1 C14 107.9(8) . . ?
C15 Si1 C14 106.9(9) . . ?
C6 Si1 C14 108.7(6) . . ?
C29 Si2 C21 109.2(6) . . ?
C29 Si2 C30 108.6(7) . . ?
C21 Si2 C30 110.7(5) . . ?
C29 Si2 C28 108.4(6) . . ?
C21 Si2 C28 111.6(5) . . ?
C30 Si2 C28 108.3(7) . . ?
C36 Si3 C44 110.9(5) . . ?
C36 Si3 C45 112.8(4) . . ?
C44 Si3 C45 107.8(6) . . ?
C36 Si3 C43 109.0(5) . . ?
C44 Si3 C43 107.6(6) . . ?
C45 Si3 C43 108.6(5) . . ?
C58 Si4 C59 107.7(8) . . ?
C58 Si4 C51 112.9(6) . . ?
C59 Si4 C51 113.3(6) . . ?
C58 Si4 C60 106.5(10) . . ?
C59 Si4 C60 108.4(11) . . ?
C51 Si4 C60 107.8(6) . . ?
C2 O1 C1 115.5(10) . . ?
C2 O1 Eu1 121.2(7) . . ?
C1 O1 Eu1 122.3(7) . . ?
C16 O2 C17 113.3(9) . . ?
C16 O2 Eu1 123.3(7) . . ?
C17 O2 Eu1 120.4(6) . . ?
C32 O3 C31 114.7(11) . . ?
C32 O3 Eu2 118.4(8) . . ?
C31 O3 Eu2 126.7(7) . . ?
C47 O4 C46 114.4(8) . . ?
C47 O4 Eu2 121.3(6) . . ?
C46 O4 Eu2 124.1(6) . . ?
C3 C2 O1 121.4(11) . . ?
C2 C3 C4 120.2(12) . . ?
C5 C4 C8 106.7(9) . . ?
C5 C4 C3 128.7(15) . . ?
C8 C4 C3 124.5(14) . . ?
C5 C4 Eu1 76.8(6) . . ?
C8 C4 Eu1 76.5(5) . . ?
C3 C4 Eu1 110.5(8) . . ?
C4 C5 C6 112.8(10) . . ?
C4 C5 Eu1 75.0(6) . . ?
C6 C5 Eu1 76.9(5) . . ?
C5 C6 C7 106.0(9) . . ?
C5 C6 Si1 124.2(8) . . ?
C7 C6 Si1 128.9(7) . . ?
C5 C6 Eu1 74.5(5) . . ?
C7 C6 Eu1 76.0(5) . . ?
Si1 C6 Eu1 123.5(4) . . ?
C12 C7 C6 132.0(10) . . ?
C12 C7 C8 122.4(10) . . ?
C6 C7 C8 105.6(9) . . ?
C12 C7 Eu1 116.5(6) . . ?
C6 C7 Eu1 74.9(5) . . ?
C8 C7 Eu1 73.3(5) . . ?
C4 C8 C9 135.8(13) . . ?
C4 C8 C7 108.9(9) . . ?
C9 C8 C7 115.3(13) . . ?
C4 C8 Eu1 74.8(5) . . ?
C9 C8 Eu1 116.0(8) . . ?
C7 C8 Eu1 76.8(5) . . ?
C10 C9 C8 121.4(17) . . ?
C9 C10 C11 124.0(16) . . ?
C10 C11 C12 119.4(16) . . ?
C7 C12 C11 117.4(13) . . ?
O2 C17 C18 112.5(11) . . ?
C17 C18 C19 112.8(10) . . ?
C20 C19 C23 108.0(9) . . ?
C20 C19 C18 127.7(12) . . ?
C23 C19 C18 124.3(11) . . ?
C20 C19 Eu1 79.1(5) . . ?
C23 C19 Eu1 75.4(5) . . ?
C18 C19 Eu1 110.5(7) . . ?
C19 C20 C21 111.4(10) . . ?
C19 C20 Eu1 72.5(5) . . ?
C21 C20 Eu1 76.5(5) . . ?
C20 C21 C22 105.1(8) . . ?
C20 C21 Si2 127.1(8) . . ?
C22 C21 Si2 127.1(7) . . ?
C20 C21 Eu1 75.3(5) . . ?
C22 C21 Eu1 73.6(5) . . ?
Si2 C21 Eu1 123.4(4) . . ?
C27 C22 C23 119.9(10) . . ?
C27 C22 C21 132.3(10) . . ?
C23 C22 C21 107.9(10) . . ?
C27 C22 Eu1 115.3(7) . . ?
C23 C22 Eu1 73.1(5) . . ?
C21 C22 Eu1 76.9(5) . . ?
C24 C23 C19 132.6(11) . . ?
C24 C23 C22 119.8(12) . . ?
C19 C23 C22 107.5(10) . . ?
C24 C23 Eu1 110.7(7) . . ?
C19 C23 Eu1 75.3(5) . . ?
C22 C23 Eu1 77.3(5) . . ?
C25 C24 C23 117.7(12) . . ?
C24 C25 C26 123.5(13) . . ?
C27 C26 C25 119.4(13) . . ?
C26 C27 C22 119.6(12) . . ?
C33 C32 O3 125.4(14) . . ?
C32 C33 C34 117.5(10) . . ?
C35 C34 C38 105.7(7) . . ?
C35 C34 C33 127.6(9) . . ?
C38 C34 C33 126.7(8) . . ?
C35 C34 Eu2 75.7(5) . . ?
C38 C34 Eu2 78.1(5) . . ?
C33 C34 Eu2 110.2(6) . . ?
C34 C35 C36 112.5(8) . . ?
C34 C35 Eu2 75.7(5) . . ?
C36 C35 Eu2 78.1(5) . . ?
C35 C36 C37 105.7(8) . . ?
C35 C36 Si3 123.7(6) . . ?
C37 C36 Si3 129.9(7) . . ?
C35 C36 Eu2 73.2(5) . . ?
C37 C36 Eu2 76.4(5) . . ?
Si3 C36 Eu2 122.7(4) . . ?
C42 C37 C36 133.7(9) . . ?
C42 C37 C38 118.8(8) . . ?
C36 C37 C38 107.4(8) . . ?
C42 C37 Eu2 118.4(6) . . ?
C36 C37 Eu2 74.9(5) . . ?
C38 C37 Eu2 74.9(5) . . ?
C34 C38 C39 133.1(9) . . ?
C34 C38 C37 108.7(7) . . ?
C39 C38 C37 118.2(9) . . ?
C34 C38 Eu2 73.0(4) . . ?
C39 C38 Eu2 117.7(6) . . ?
C37 C38 Eu2 76.0(5) . . ?
C40 C39 C38 121.5(9) . . ?
C39 C40 C41 119.0(9) . . ?
C42 C41 C40 122.6(11) . . ?
C41 C42 C37 119.7(10) . . ?
C48 C47 O4 124.0(10) . . ?
C47 C48 C49 119.3(10) . . ?
C50 C49 C53 107.4(8) . . ?
C50 C49 C48 125.6(11) . . ?
C53 C49 C48 126.9(11) . . ?
C50 C49 Eu2 77.3(5) . . ?
C53 C49 Eu2 75.3(5) . . ?
C48 C49 Eu2 111.0(7) . . ?
C49 C50 C51 111.0(9) . . ?
C49 C50 Eu2 74.5(6) . . ?
C51 C50 Eu2 76.6(5) . . ?
C52 C51 C50 105.0(9) . . ?
C52 C51 Si4 128.2(7) . . ?
C50 C51 Si4 126.3(8) . . ?
C52 C51 Eu2 74.2(5) . . ?
C50 C51 Eu2 74.4(5) . . ?
Si4 C51 Eu2 122.4(4) . . ?
C57 C52 C53 118.6(10) . . ?
C57 C52 C51 132.8(10) . . ?
C53 C52 C51 108.6(8) . . ?
C57 C52 Eu2 112.9(6) . . ?
C53 C52 Eu2 74.1(4) . . ?
C51 C52 Eu2 76.8(5) . . ?
C49 C53 C54 132.6(10) . . ?
C49 C53 C52 107.9(8) . . ?
C54 C53 C52 119.3(10) . . ?
C49 C53 Eu2 75.6(5) . . ?
C54 C53 Eu2 110.2(6) . . ?
C52 C53 Eu2 76.7(4) . . ?
C55 C54 C53 119.8(11) . . ?
C54 C55 C56 118.9(12) . . ?
C57 C56 C55 123.8(13) . . ?
C56 C57 C52 119.6(12) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O1 2.561(7) . ?
Eu1 O2 2.609(7) . ?
Eu1 C19 2.806(9) . ?
Eu1 C23 2.806(9) . ?
Eu1 C4 2.819(10) . ?
Eu1 C8 2.840(8) . ?
Eu1 C5 2.841(9) . ?
Eu1 C22 2.861(9) . ?
Eu1 C6 2.871(8) . ?
Eu1 C7 2.886(9) . ?
Eu1 C20 2.888(9) . ?
Eu1 C21 2.904(9) . ?
Eu2 O3 2.567(7) . ?
Eu2 O4 2.611(6) . ?
Eu2 C53 2.826(7) . ?
Eu2 C35 2.827(8) . ?
Eu2 C34 2.827(8) . ?
Eu2 C49 2.829(9) . ?
Eu2 C52 2.860(9) . ?
Eu2 C50 2.865(9) . ?
Eu2 C36 2.889(9) . ?
Eu2 C38 2.893(8) . ?
Eu2 C51 2.894(9) . ?
Eu2 C37 2.908(8) . ?
Si1 C13 1.839(13) . ?
Si1 C15 1.855(14) . ?
Si1 C6 1.862(9) . ?
Si1 C14 1.878(15) . ?
Si2 C29 1.852(13) . ?
Si2 C21 1.870(9) . ?
Si2 C30 1.873(12) . ?
Si2 C28 1.877(11) . ?
Si3 C36 1.863(9) . ?
Si3 C44 1.871(11) . ?
Si3 C45 1.891(11) . ?
Si3 C43 1.895(11) . ?
Si4 C58 1.828(14) . ?
Si4 C59 1.855(15) . ?
Si4 C51 1.868(10) . ?
Si4 C60 1.886(17) . ?
O1 C2 1.387(16) . ?
O1 C1 1.423(13) . ?
O2 C16 1.435(13) . ?
O2 C17 1.438(13) . ?
O3 C32 1.368(15) . ?
O3 C31 1.382(13) . ?
O4 C47 1.366(13) . ?
O4 C46 1.428(11) . ?
C2 C3 1.322(18) . ?
C3 C4 1.490(16) . ?
C4 C5 1.377(15) . ?
C4 C8 1.402(15) . ?
C5 C6 1.409(12) . ?
C6 C7 1.444(13) . ?
C7 C12 1.398(14) . ?
C7 C8 1.478(13) . ?
C8 C9 1.411(18) . ?
C9 C10 1.34(3) . ?
C10 C11 1.38(3) . ?
C11 C12 1.425(19) . ?
C17 C18 1.495(17) . ?
C18 C19 1.533(15) . ?
C19 C20 1.400(14) . ?
C19 C23 1.419(15) . ?
C20 C21 1.414(13) . ?
C21 C22 1.468(14) . ?
C22 C27 1.388(15) . ?
C22 C23 1.448(13) . ?
C23 C24 1.419(16) . ?
C24 C25 1.351(18) . ?
C25 C26 1.420(18) . ?
C26 C27 1.383(16) . ?
C32 C33 1.334(18) . ?
C33 C34 1.501(12) . ?
C34 C35 1.398(12) . ?
C34 C38 1.429(12) . ?
C35 C36 1.418(11) . ?
C36 C37 1.435(11) . ?
C37 C42 1.423(13) . ?
C37 C38 1.453(12) . ?
C38 C39 1.438(13) . ?
C39 C40 1.370(15) . ?
C40 C41 1.411(15) . ?
C41 C42 1.378(13) . ?
C47 C48 1.351(15) . ?
C48 C49 1.515(13) . ?
C49 C50 1.392(13) . ?
C49 C53 1.424(13) . ?
C50 C51 1.440(13) . ?
C51 C52 1.439(13) . ?
C52 C57 1.416(14) . ?
C52 C53 1.437(12) . ?
C53 C54 1.432(15) . ?
C54 C55 1.387(18) . ?
C55 C56 1.393(18) . ?
C56 C57 1.350(17) . ?
