#------------------------------------------------------------------------------
#$Date: 2016-03-25 13:23:34 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179841 $
#$URL: svn://www.crystallography.net/cod/cif/7/01/37/7013794.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7013794
loop_
_publ_author_name
'Pechmann, Thomas'
'Brandt, Carsten D.'
'Werner, Helmut'
_publ_section_title
;
 Extending the coordination capabilities of tertiary phosphines and
 arsines: preparation, molecular structure, and reactivity of dinuclear
 rhodium complexes with PR3 and AsR3 in a doubly bridging coordination
 mode.
;
_journal_issue                   6
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              959
_journal_page_last               966
_journal_paper_doi               10.1039/b314734g
_journal_year                    2004
_chemical_formula_sum            'C70 H70 Cl4 P2 Rh4'
_chemical_formula_weight         1526.64
_chemical_name_systematic
; 
? 
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     Patterson
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 101.8780(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   22.2854(11)
_cell_length_b                   15.1150(7)
_cell_length_c                   19.2895(9)
_cell_measurement_reflns_used    8804
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      28.246
_cell_measurement_theta_min      2.303
_cell_volume                     6358.4(5)
_computing_cell_refinement       'SAINT-NT V6.0'
_computing_data_collection       'SMART-NT V5.6'
_computing_data_reduction        'SAINT-NT V6.0'
_computing_molecular_graphics    'XSHELL in SHELXTL-97'
_computing_publication_material  'XSHELL in SHELXTL-97'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker Smart Apex with D8-Goniometer'
_diffrn_measurement_method       omega-scans
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0228
_diffrn_reflns_av_sigmaI/netI    0.0153
_diffrn_reflns_limit_h_max       26
_diffrn_reflns_limit_h_min       -26
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            60158
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         1.64
_exptl_absorpt_coefficient_mu    1.280
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   'SADABS2.0 (Sheldick 2000)'
_exptl_crystal_colour            red-brown
_exptl_crystal_density_diffrn    1.595
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             3072
_exptl_crystal_size_max          0.40
_exptl_crystal_size_mid          0.40
_exptl_crystal_size_min          0.20
_refine_diff_density_max         0.472
_refine_diff_density_min         -0.351
_refine_diff_density_rms         0.069
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.078
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     727
_refine_ls_number_reflns         11183
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.078
_refine_ls_R_factor_all          0.0249
_refine_ls_R_factor_gt           0.0228
_refine_ls_shift/su_max          0.005
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0265P)²+4.0856P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0541
_refine_ls_wR_factor_ref         0.0551
_reflns_number_gt                10525
_reflns_number_total             11183
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b314734g.txt
_cod_data_source_block           tp4cb
_cod_original_sg_symbol_H-M      P2(1)/c
_cod_database_code               7013794
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh1 Rh 0.083229(8) 0.917474(11) 0.218533(8) 0.02346(5) Uani 1 1 d . . .
Rh2 Rh 0.039610(7) 0.954659(10) 0.091590(8) 0.01958(5) Uani 1 1 d . . .
Rh3 Rh 0.386688(8) 1.418240(11) 0.294523(9) 0.02460(5) Uani 1 1 d . . .
Rh4 Rh 0.452577(7) 1.453846(11) 0.412466(8) 0.02129(5) Uani 1 1 d . . .
P1 P 0.03496(3) 1.06197(4) 0.17937(3) 0.02857(13) Uani 1 1 d . . .
P2 P 0.44177(3) 1.55656(4) 0.31656(3) 0.02816(13) Uani 1 1 d . . .
Cl1 Cl 0.12648(3) 0.85404(4) 0.32610(3) 0.04055(15) Uani 1 1 d . . .
Cl2 Cl -0.06411(2) 0.97620(4) 0.01488(3) 0.02888(12) Uani 1 1 d . . .
Cl3 Cl 0.32639(3) 1.36621(5) 0.19140(3) 0.04618(16) Uani 1 1 d . . .
Cl4 Cl 0.44622(2) 1.56270(4) 0.50765(3) 0.03216(13) Uani 1 1 d . . .
C1 C 0.12832(9) 0.92869(14) 0.14013(11) 0.0231(4) Uani 1 1 d . . .
C2 C 0.01416(9) 0.85887(14) 0.15517(10) 0.0227(4) Uani 1 1 d . . .
C3 C -0.04607(12) 1.08124(17) 0.17539(14) 0.0426(6) Uani 1 1 d . . .
H3A H -0.0525 1.1433 0.1866 0.064 Uiso 1 1 calc R . .
H3B H -0.0603 1.0430 0.2098 0.064 Uiso 1 1 calc R . .
H3C H -0.0692 1.0678 0.1276 0.064 Uiso 1 1 calc R . .
C4 C 0.06518(14) 1.09995(19) 0.27044(14) 0.0487(7) Uani 1 1 d . . .
H4A H 0.1101 1.0980 0.2802 0.073 Uiso 1 1 calc R . .
H4B H 0.0500 1.0613 0.3038 0.073 Uiso 1 1 calc R . .
H4C H 0.0516 1.1608 0.2758 0.073 Uiso 1 1 calc R . .
C5 C 0.05862(17) 1.15548(17) 0.13229(16) 0.0598(9) Uani 1 1 d . . .
H5A H 0.0338 1.1575 0.0841 0.090 Uiso 1 1 calc R . .
H5B H 0.1020 1.1491 0.1302 0.090 Uiso 1 1 calc R . .
H5C H 0.0529 1.2104 0.1572 0.090 Uiso 1 1 calc R . .
C10 C 0.15634(10) 0.84588(14) 0.11693(12) 0.0262(5) Uani 1 1 d . . .
C11 C 0.13977(11) 0.81196(15) 0.04874(12) 0.0319(5) Uani 1 1 d . . .
H11 H 0.1071 0.8383 0.0158 0.038 Uiso 1 1 calc R . .
C12 C 0.17075(13) 0.73946(17) 0.02839(15) 0.0438(7) Uani 1 1 d . . .
H12 H 0.1591 0.7167 -0.0183 0.053 Uiso 1 1 calc R . .
C13 C 0.21814(13) 0.70081(18) 0.07574(17) 0.0498(7) Uani 1 1 d . . .
H13 H 0.2397 0.6521 0.0614 0.060 Uiso 1 1 calc R . .
C14 C 0.23423(12) 0.73266(17) 0.14370(17) 0.0501(7) Uani 1 1 d . . .
H14 H 0.2663 0.7050 0.1767 0.060 Uiso 1 1 calc R . .
C15 C 0.20408(11) 0.80480(16) 0.16446(14) 0.0391(6) Uani 1 1 d . . .
H15 H 0.2159 0.8267 0.2115 0.047 Uiso 1 1 calc R . .
C20 C 0.17606(10) 1.00065(14) 0.15441(12) 0.0282(5) Uani 1 1 d . . .
C21 C 0.20161(12) 1.02785(19) 0.22235(14) 0.0453(7) Uani 1 1 d . . .
H21 H 0.1880 1.0022 0.2613 0.054 Uiso 1 1 calc R . .
C22 C 0.24714(15) 1.0925(2) 0.23458(19) 0.0663(10) Uani 1 1 d . . .
H22 H 0.2643 1.1105 0.2817 0.080 Uiso 1 1 calc R . .
C23 C 0.26725(14) 1.1301(2) 0.1787(2) 0.0636(9) Uani 1 1 d . . .
H23 H 0.2974 1.1755 0.1869 0.076 Uiso 1 1 calc R . .
C24 C 0.24358(13) 1.10198(19) 0.11095(18) 0.0538(8) Uani 1 1 d . . .
H24 H 0.2580 1.1272 0.0723 0.065 Uiso 1 1 calc R . .
C25 C 0.19889(11) 1.03722(17) 0.09863(14) 0.0395(6) Uani 1 1 d . . .
H25 H 0.1835 1.0173 0.0516 0.047 Uiso 1 1 calc R . .
C30 C 0.02430(9) 0.77013(14) 0.12485(11) 0.0245(4) Uani 1 1 d . . .
C31 C 0.06362(10) 0.70780(15) 0.16355(13) 0.0308(5) Uani 1 1 d . . .
H31 H 0.0854 0.7220 0.2099 0.037 Uiso 1 1 calc R . .
C32 C 0.07122(12) 0.62558(16) 0.13514(15) 0.0419(6) Uani 1 1 d . . .
H32 H 0.0983 0.5839 0.1621 0.050 Uiso 1 1 calc R . .
C33 C 0.03977(13) 0.60363(18) 0.06800(17) 0.0500(7) Uani 1 1 d . . .
H33 H 0.0450 0.5470 0.0488 0.060 Uiso 1 1 calc R . .
C34 C 0.00095(13) 0.66427(18) 0.02930(15) 0.0483(7) Uani 1 1 d . . .
H34 H -0.0208 0.6493 -0.0169 0.058 Uiso 1 1 calc R . .
C35 C -0.00684(11) 0.74717(16) 0.05679(13) 0.0352(5) Uani 1 1 d . . .
H35 H -0.0336 0.7887 0.0291 0.042 Uiso 1 1 calc R . .
C40 C -0.04354(10) 0.86377(14) 0.18443(11) 0.0245(4) Uani 1 1 d . . .
C41 C -0.04015(11) 0.87276(16) 0.25696(12) 0.0326(5) Uani 1 1 d . . .
H41 H -0.0011 0.8756 0.2880 0.039 Uiso 1 1 calc R . .
C42 C -0.09279(12) 0.87764(18) 0.28460(13) 0.0396(6) Uani 1 1 d . . .
H42 H -0.0895 0.8845 0.3342 0.047 Uiso 1 1 calc R . .
C43 C -0.14979(11) 0.87261(18) 0.24046(14) 0.0411(6) Uani 1 1 d . . .
H43 H -0.1859 0.8760 0.2594 0.049 Uiso 1 1 calc R . .
C44 C -0.15390(11) 0.86263(17) 0.16841(14) 0.0391(6) Uani 1 1 d . . .
H44 H -0.1930 0.8592 0.1376 0.047 Uiso 1 1 calc R . .
C45 C -0.10150(10) 0.85755(15) 0.14084(12) 0.0309(5) Uani 1 1 d . . .
H45 H -0.1051 0.8497 0.0913 0.037 Uiso 1 1 calc R . .
C50 C 0.45249(10) 1.26273(14) 0.36392(12) 0.0283(5) Uani 1 1 d . . .
C51 C 0.46951(11) 1.23285(16) 0.43338(13) 0.0365(6) Uani 1 1 d . . .
H51 H 0.4886 1.2724 0.4695 0.044 Uiso 1 1 calc R . .
C52 C 0.45887(13) 1.14593(17) 0.45037(15) 0.0470(7) Uani 1 1 d . . .
H52 H 0.4706 1.1266 0.4981 0.056 Uiso 1 1 calc R . .
C53 C 0.43149(13) 1.08719(17) 0.39880(16) 0.0455(7) Uani 1 1 d . . .
H53 H 0.4241 1.0278 0.4108 0.055 Uiso 1 1 calc R . .
C54 C 0.41503(12) 1.11558(16) 0.32977(15) 0.0415(6) Uani 1 1 d . . .
H54 H 0.3965 1.0754 0.2939 0.050 Uiso 1 1 calc R . .
C55 C 0.42526(11) 1.20201(16) 0.31216(13) 0.0349(5) Uani 1 1 d . . .
H55 H 0.4136 1.2205 0.2642 0.042 Uiso 1 1 calc R . .
C60 C 0.51356(11) 1.36241(15) 0.30152(13) 0.0323(5) Uani 1 1 d . . .
C61 C 0.50084(13) 1.36834(16) 0.22836(14) 0.0422(6) Uani 1 1 d . . .
H61 H 0.4595 1.3671 0.2031 0.051 Uiso 1 1 calc R . .
C62 C 0.54827(16) 1.37611(18) 0.19122(17) 0.0547(8) Uani 1 1 d . . .
H62 H 0.5390 1.3797 0.1410 0.066 Uiso 1 1 calc R . .
C63 C 0.60779(16) 1.37860(19) 0.2270(2) 0.0645(10) Uani 1 1 d . . .
H63 H 0.6399 1.3868 0.2019 0.077 Uiso 1 1 calc R . .
C64 C 0.62121(14) 1.3692(2) 0.2991(2) 0.0658(10) Uani 1 1 d . . .
H64 H 0.6628 1.3692 0.3238 0.079 Uiso 1 1 calc R . .
C65 C 0.57466(12) 1.3598(2) 0.33648(16) 0.0529(8) Uani 1 1 d . . .
H65 H 0.5846 1.3515 0.3864 0.064 Uiso 1 1 calc R . .
C70 C 0.34788(9) 1.35134(14) 0.42597(11) 0.0243(4) Uani 1 1 d . . .
C71 C 0.36784(11) 1.34784(15) 0.49931(12) 0.0321(5) Uani 1 1 d . . .
H71 H 0.3905 1.3960 0.5233 0.039 Uiso 1 1 calc R . .
C72 C 0.35514(12) 1.27539(16) 0.53767(13) 0.0376(6) Uani 1 1 d . . .
H72 H 0.3698 1.2735 0.5875 0.045 Uiso 1 1 calc R . .
C73 C 0.32123(12) 1.20593(16) 0.50357(14) 0.0402(6) Uani 1 1 d . . .
H73 H 0.3119 1.1564 0.5297 0.048 Uiso 1 1 calc R . .
C74 C 0.30098(12) 1.20918(16) 0.43112(13) 0.0368(6) Uani 1 1 d . . .
H74 H 0.2778 1.1612 0.4076 0.044 Uiso 1 1 calc R . .
C75 C 0.31367(10) 1.28048(15) 0.39206(12) 0.0287(5) Uani 1 1 d . . .
H75 H 0.2992 1.2815 0.3422 0.034 Uiso 1 1 calc R . .
C80 C 0.31073(10) 1.50047(14) 0.38228(12) 0.0284(5) Uani 1 1 d . . .
C81 C 0.29525(12) 1.53419(17) 0.44371(14) 0.0388(6) Uani 1 1 d . . .
H81 H 0.3172 1.5148 0.4887 0.047 Uiso 1 1 calc R . .
C82 C 0.24860(13) 1.59522(19) 0.44005(17) 0.0519(7) Uani 1 1 d . . .
H82 H 0.2393 1.6181 0.4825 0.062 Uiso 1 1 calc R . .
C83 C 0.21562(13) 1.62310(19) 0.37580(18) 0.0552(8) Uani 1 1 d . . .
H83 H 0.1839 1.6656 0.3737 0.066 Uiso 1 1 calc R . .
C84 C 0.22865(13) 1.58941(19) 0.31454(17) 0.0522(8) Uani 1 1 d . . .
H84 H 0.2053 1.6078 0.2700 0.063 Uiso 1 1 calc R . .
C85 C 0.27610(11) 1.52819(17) 0.31726(14) 0.0398(6) Uani 1 1 d . . .
H85 H 0.2848 1.5053 0.2745 0.048 Uiso 1 1 calc R . .
C90 C 0.46270(10) 1.35625(14) 0.34290(11) 0.0258(5) Uani 1 1 d . . .
C91 C 0.36010(9) 1.43178(14) 0.38565(11) 0.0232(4) Uani 1 1 d . . .
C92 C 0.52152(13) 1.5898(2) 0.33738(16) 0.0590(9) Uani 1 1 d . . .
H92A H 0.5265 1.6452 0.3127 0.088 Uiso 1 1 calc R . .
H92B H 0.5468 1.5436 0.3221 0.088 Uiso 1 1 calc R . .
H92C H 0.5345 1.5987 0.3886 0.088 Uiso 1 1 calc R . .
C93 C 0.42768(15) 1.57419(18) 0.22011(13) 0.0483(7) Uani 1 1 d . . .
H93A H 0.4395 1.6347 0.2103 0.072 Uiso 1 1 calc R . .
H93B H 0.3840 1.5654 0.1998 0.072 Uiso 1 1 calc R . .
H93C H 0.4520 1.5320 0.1989 0.072 Uiso 1 1 calc R . .
C94 C 0.40158(15) 1.65191(17) 0.34159(17) 0.0535(8) Uani 1 1 d . . .
H94A H 0.4071 1.6542 0.3933 0.080 Uiso 1 1 calc R . .
H94B H 0.3578 1.6471 0.3204 0.080 Uiso 1 1 calc R . .
H94C H 0.4181 1.7060 0.3246 0.080 Uiso 1 1 calc R . .
C100 C -0.16620(12) 0.69936(18) -0.00880(14) 0.0451(6) Uani 1 1 d . . .
H100 H -0.1678 0.7620 -0.0059 0.054 Uiso 1 1 calc R . .
C101 C -0.14834(13) 0.64995(19) 0.05186(15) 0.0503(7) Uani 1 1 d . . .
H101 H -0.1380 0.6786 0.0966 0.060 Uiso 1 1 calc R . .
C102 C -0.14542(14) 0.55960(19) 0.04799(17) 0.0531(8) Uani 1 1 d . . .
H102 H -0.1333 0.5253 0.0898 0.064 Uiso 1 1 calc R . .
C103 C -0.16017(14) 0.5190(2) -0.01716(17) 0.0564(8) Uani 1 1 d . . .
H103 H -0.1575 0.4565 -0.0204 0.068 Uiso 1 1 calc R . .
C104 C -0.17875(14) 0.5682(2) -0.07747(16) 0.0547(8) Uani 1 1 d . . .
H104 H -0.1896 0.5395 -0.1221 0.066 Uiso 1 1 calc R . .
C105 C -0.18171(12) 0.6584(2) -0.07356(14) 0.0461(7) Uani 1 1 d . . .
H105 H -0.1944 0.6925 -0.1154 0.055 Uiso 1 1 calc R . .
C106 C 0.28510(14) 0.9015(2) 0.42252(17) 0.0581(8) Uani 1 1 d . . .
H106 H 0.2525 0.9136 0.3835 0.070 Uiso 1 1 calc R . .
C107 C 0.30341(16) 0.9644(2) 0.47228(18) 0.0618(9) Uani 1 1 d . . .
H107 H 0.2830 1.0200 0.4685 0.074 Uiso 1 1 calc R . .
C108 C 0.35071(15) 0.9487(2) 0.52750(18) 0.0624(9) Uani 1 1 d . . .
H108 H 0.3634 0.9931 0.5623 0.075 Uiso 1 1 calc R . .
C109 C 0.37956(16) 0.8700(3) 0.53293(17) 0.0778(12) Uani 1 1 d . . .
H109 H 0.4132 0.8596 0.5711 0.093 Uiso 1 1 calc R . .
C110 C 0.3611(2) 0.8053(3) 0.48444(18) 0.0833(13) Uani 1 1 d . . .
H110 H 0.3812 0.7495 0.4895 0.100 Uiso 1 1 calc R . .
C111 C 0.31330(18) 0.8203(2) 0.42800(17) 0.0671(9) Uani 1 1 d . . .
H111 H 0.3001 0.7756 0.3936 0.081 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C2 Rh1 C1 91.09(8) . . ?
C2 Rh1 Cl1 119.98(6) . . ?
C1 Rh1 Cl1 122.43(6) . . ?
C2 Rh1 P1 88.43(6) . . ?
C1 Rh1 P1 87.06(6) . . ?
Cl1 Rh1 P1 135.51(2) . . ?
C2 Rh1 Rh2 52.95(6) . . ?
C1 Rh1 Rh2 52.59(6) . . ?
Cl1 Rh1 Rh2 167.894(19) . . ?
P1 Rh1 Rh2 56.538(14) . . ?
C1 Rh2 C2 87.19(8) . . ?
C1 Rh2 P1 89.11(6) . . ?
C2 Rh2 P1 89.88(6) . . ?
C1 Rh2 Cl2 95.97(6) . 3_575 ?
C2 Rh2 Cl2 159.02(6) . 3_575 ?
P1 Rh2 Cl2 110.87(2) . 3_575 ?
C1 Rh2 Cl2 170.77(6) . . ?
C2 Rh2 Cl2 96.33(6) . . ?
P1 Rh2 Cl2 99.41(2) . . ?
Cl2 Rh2 Cl2 77.733(19) 3_575 . ?
C1 Rh2 Rh1 50.58(6) . . ?
C2 Rh2 Rh1 49.97(6) . . ?
P1 Rh2 Rh1 61.245(16) . . ?
Cl2 Rh2 Rh1 143.314(15) 3_575 . ?
Cl2 Rh2 Rh1 137.252(14) . . ?
C91 Rh3 C90 90.79(9) . . ?
C91 Rh3 Cl3 125.17(6) . . ?
C90 Rh3 Cl3 122.27(6) . . ?
C91 Rh3 P2 89.34(6) . . ?
C90 Rh3 P2 88.42(6) . . ?
Cl3 Rh3 P2 129.31(2) . . ?
C91 Rh3 Rh4 52.84(6) . . ?
C90 Rh3 Rh4 52.50(6) . . ?
Cl3 Rh3 Rh4 172.29(2) . . ?
P2 Rh3 Rh4 58.114(15) . . ?
C90 Rh4 C91 87.58(8) . . ?
C90 Rh4 P2 88.15(6) . . ?
C91 Rh4 P2 88.54(6) . . ?
C90 Rh4 Cl4 97.29(6) . 3_686 ?
C91 Rh4 Cl4 152.20(6) . 3_686 ?
P2 Rh4 Cl4 118.87(2) . 3_686 ?
C90 Rh4 Cl4 173.90(6) . . ?
C91 Rh4 Cl4 94.98(6) . . ?
P2 Rh4 Cl4 97.44(2) . . ?
Cl4 Rh4 Cl4 77.89(2) 3_686 . ?
C90 Rh4 Rh3 50.85(6) . . ?
C91 Rh4 Rh3 50.39(6) . . ?
P2 Rh4 Rh3 59.225(15) . . ?
Cl4 Rh4 Rh3 146.777(15) 3_686 . ?
Cl4 Rh4 Rh3 134.527(15) . . ?
C3 P1 C5 104.05(15) . . ?
C3 P1 C4 98.96(13) . . ?
C5 P1 C4 98.51(14) . . ?
C3 P1 Rh2 105.66(8) . . ?
C5 P1 Rh2 96.65(9) . . ?
C4 P1 Rh2 146.88(9) . . ?
C3 P1 Rh1 121.27(9) . . ?
C5 P1 Rh1 133.21(11) . . ?
C4 P1 Rh1 86.18(9) . . ?
Rh2 P1 Rh1 62.217(15) . . ?
C92 P2 C94 103.66(16) . . ?
C92 P2 C93 98.01(14) . . ?
C94 P2 C93 99.38(14) . . ?
C92 P2 Rh4 94.06(9) . . ?
C94 P2 Rh4 106.67(10) . . ?
C93 P2 Rh4 147.73(9) . . ?
C92 P2 Rh3 135.96(12) . . ?
C94 P2 Rh3 118.25(10) . . ?
C93 P2 Rh3 88.44(9) . . ?
Rh4 P2 Rh3 62.662(15) . . ?
Rh2 Cl2 Rh2 102.267(19) 3_575 . ?
Rh4 Cl4 Rh4 102.11(2) 3_686 . ?
C20 C1 C10 109.49(17) . . ?
C20 C1 Rh1 111.78(14) . . ?
C10 C1 Rh1 117.41(14) . . ?
C20 C1 Rh2 121.68(15) . . ?
C10 C1 Rh2 116.38(14) . . ?
Rh1 C1 Rh2 76.83(7) . . ?
C30 C2 C40 113.48(17) . . ?
C30 C2 Rh1 118.92(14) . . ?
C40 C2 Rh1 111.31(14) . . ?
C30 C2 Rh2 108.42(13) . . ?
C40 C2 Rh2 123.42(14) . . ?
Rh1 C2 Rh2 77.08(7) . . ?
C11 C10 C15 118.4(2) . . ?
C11 C10 C1 122.8(2) . . ?
C15 C10 C1 118.7(2) . . ?
C10 C11 C12 120.4(2) . . ?
C13 C12 C11 120.2(3) . . ?
C14 C13 C12 119.9(2) . . ?
C13 C14 C15 120.4(3) . . ?
C14 C15 C10 120.6(3) . . ?
C21 C20 C25 118.0(2) . . ?
C21 C20 C1 121.8(2) . . ?
C25 C20 C1 120.1(2) . . ?
C20 C21 C22 120.9(3) . . ?
C23 C22 C21 120.1(3) . . ?
C24 C23 C22 119.7(3) . . ?
C23 C24 C25 120.4(3) . . ?
C24 C25 C20 120.8(3) . . ?
C31 C30 C35 118.1(2) . . ?
C31 C30 C2 121.64(19) . . ?
C35 C30 C2 120.2(2) . . ?
C32 C31 C30 120.7(2) . . ?
C33 C32 C31 120.5(2) . . ?
C34 C33 C32 119.5(2) . . ?
C33 C34 C35 120.7(3) . . ?
C34 C35 C30 120.5(2) . . ?
C45 C40 C41 117.7(2) . . ?
C45 C40 C2 121.82(19) . . ?
C41 C40 C2 120.44(19) . . ?
C42 C41 C40 121.1(2) . . ?
C43 C42 C41 120.3(2) . . ?
C42 C43 C44 119.3(2) . . ?
C45 C44 C43 120.5(2) . . ?
C44 C45 C40 121.1(2) . . ?
C51 C50 C55 117.8(2) . . ?
C51 C50 C90 122.7(2) . . ?
C55 C50 C90 119.5(2) . . ?
C52 C51 C50 120.6(2) . . ?
C53 C52 C51 120.8(3) . . ?
C54 C53 C52 119.2(2) . . ?
C53 C54 C55 120.6(2) . . ?
C54 C55 C50 121.0(2) . . ?
C61 C60 C65 118.1(2) . . ?
C61 C60 C90 121.5(2) . . ?
C65 C60 C90 120.4(2) . . ?
C60 C61 C62 120.7(3) . . ?
C63 C62 C61 120.1(3) . . ?
C62 C63 C64 119.9(3) . . ?
C63 C64 C65 120.6(3) . . ?
C64 C65 C60 120.5(3) . . ?
C71 C70 C75 118.4(2) . . ?
C71 C70 C91 120.23(19) . . ?
C75 C70 C91 121.28(19) . . ?
C72 C71 C70 121.0(2) . . ?
C73 C72 C71 120.0(2) . . ?
C74 C73 C72 119.3(2) . . ?
C75 C74 C73 121.4(2) . . ?
C74 C75 C70 119.8(2) . . ?
C85 C80 C81 117.7(2) . . ?
C85 C80 C91 120.7(2) . . ?
C81 C80 C91 121.4(2) . . ?
C82 C81 C80 121.0(3) . . ?
C83 C82 C81 120.6(3) . . ?
C82 C83 C84 119.7(3) . . ?
C83 C84 C85 120.4(3) . . ?
C80 C85 C84 120.4(3) . . ?
C50 C90 C60 111.80(18) . . ?
C50 C90 Rh3 114.07(15) . . ?
C60 C90 Rh3 112.34(16) . . ?
C50 C90 Rh4 117.41(15) . . ?
C60 C90 Rh4 119.86(15) . . ?
Rh3 C90 Rh4 76.65(7) . . ?
C70 C91 C80 111.91(18) . . ?
C70 C91 Rh3 119.81(14) . . ?
C80 C91 Rh3 112.52(15) . . ?
C70 C91 Rh4 106.40(14) . . ?
C80 C91 Rh4 126.01(15) . . ?
Rh3 C91 Rh4 76.77(7) . . ?
C105 C100 C101 120.2(3) . . ?
C102 C101 C100 120.2(3) . . ?
C101 C102 C103 119.3(3) . . ?
C104 C103 C102 120.5(3) . . ?
C105 C104 C103 120.2(3) . . ?
C104 C105 C100 119.6(3) . . ?
C107 C106 C111 120.5(3) . . ?
C106 C107 C108 120.4(3) . . ?
C109 C108 C107 119.8(3) . . ?
C108 C109 C110 120.7(3) . . ?
C109 C110 C111 120.1(3) . . ?
C106 C111 C110 118.4(3) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Rh1 C2 1.968(2) . ?
Rh1 C1 1.988(2) . ?
Rh1 Cl1 2.3088(6) . ?
Rh1 P1 2.4826(6) . ?
Rh1 Rh2 2.5054(2) . ?
Rh2 C1 2.044(2) . ?
Rh2 C2 2.051(2) . ?
Rh2 P1 2.3625(6) . ?
Rh2 Cl2 2.4636(5) 3_575 ?
Rh2 Cl2 2.4961(5) . ?
Rh3 C91 1.978(2) . ?
Rh3 C90 1.992(2) . ?
Rh3 Cl3 2.2979(6) . ?
Rh3 P2 2.4173(6) . ?
Rh3 Rh4 2.4993(2) . ?
Rh4 C90 2.038(2) . ?
Rh4 C91 2.046(2) . ?
Rh4 P2 2.3890(6) . ?
Rh4 Cl4 2.4685(6) 3_686 ?
Rh4 Cl4 2.4911(5) . ?
P1 C3 1.815(3) . ?
P1 C5 1.816(3) . ?
P1 C4 1.839(2) . ?
P2 C92 1.811(3) . ?
P2 C94 1.814(3) . ?
P2 C93 1.841(3) . ?
Cl2 Rh2 2.4636(5) 3_575 ?
Cl4 Rh4 2.4685(6) 3_686 ?
C1 C20 1.507(3) . ?
C1 C10 1.507(3) . ?
C2 C30 1.499(3) . ?
C2 C40 1.509(3) . ?
C10 C11 1.389(3) . ?
C10 C15 1.399(3) . ?
C11 C12 1.394(3) . ?
C12 C13 1.376(4) . ?
C13 C14 1.373(4) . ?
C14 C15 1.383(4) . ?
C20 C21 1.380(3) . ?
C20 C25 1.396(3) . ?
C21 C22 1.393(4) . ?
C22 C23 1.374(5) . ?
C23 C24 1.372(4) . ?
C24 C25 1.382(4) . ?
C30 C31 1.394(3) . ?
C30 C35 1.397(3) . ?
C31 C32 1.383(3) . ?
C32 C33 1.380(4) . ?
C33 C34 1.371(4) . ?
C34 C35 1.385(4) . ?
C40 C45 1.392(3) . ?
C40 C41 1.392(3) . ?
C41 C42 1.387(3) . ?
C42 C43 1.378(4) . ?
C43 C44 1.382(4) . ?
C44 C45 1.381(3) . ?
C50 C51 1.391(3) . ?
C50 C55 1.399(3) . ?
C50 C90 1.501(3) . ?
C51 C52 1.386(4) . ?
C52 C53 1.379(4) . ?
C53 C54 1.375(4) . ?
C54 C55 1.380(4) . ?
C60 C61 1.384(4) . ?
C60 C65 1.390(4) . ?
C60 C90 1.517(3) . ?
C61 C62 1.398(4) . ?
C62 C63 1.364(5) . ?
C63 C64 1.369(5) . ?
C64 C65 1.387(4) . ?
C70 C71 1.394(3) . ?
C70 C75 1.397(3) . ?
C70 C91 1.498(3) . ?
C71 C72 1.383(3) . ?
C72 C73 1.379(4) . ?
C73 C74 1.378(4) . ?
C74 C75 1.377(3) . ?
C80 C85 1.395(3) . ?
C80 C81 1.397(3) . ?
C80 C91 1.504(3) . ?
C81 C82 1.381(4) . ?
C82 C83 1.371(4) . ?
C83 C84 1.371(4) . ?
C84 C85 1.398(4) . ?
C100 C105 1.373(4) . ?
C100 C101 1.376(4) . ?
C101 C102 1.370(4) . ?
C102 C103 1.376(4) . ?
C103 C104 1.371(4) . ?
C104 C105 1.369(4) . ?
C106 C107 1.354(4) . ?
C106 C111 1.373(5) . ?
C107 C108 1.357(4) . ?
C108 C109 1.347(5) . ?
C109 C110 1.357(5) . ?
C110 C111 1.376(5) . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C2 Rh1 Rh2 C1 -127.41(11) . . . . ?
Cl1 Rh1 Rh2 C1 -69.71(12) . . . . ?
P1 Rh1 Rh2 C1 115.35(8) . . . . ?
C1 Rh1 Rh2 C2 127.41(11) . . . . ?
Cl1 Rh1 Rh2 C2 57.70(12) . . . . ?
P1 Rh1 Rh2 C2 -117.24(8) . . . . ?
C2 Rh1 Rh2 P1 117.24(8) . . . . ?
C1 Rh1 Rh2 P1 -115.35(8) . . . . ?
Cl1 Rh1 Rh2 P1 174.94(9) . . . . ?
C2 Rh1 Rh2 Cl2 -156.00(8) . . . 3_575 ?
C1 Rh1 Rh2 Cl2 -28.59(8) . . . 3_575 ?
Cl1 Rh1 Rh2 Cl2 -98.30(9) . . . 3_575 ?
P1 Rh1 Rh2 Cl2 86.76(3) . . . 3_575 ?
C2 Rh1 Rh2 Cl2 45.84(8) . . . . ?
C1 Rh1 Rh2 Cl2 173.25(8) . . . . ?
Cl1 Rh1 Rh2 Cl2 103.54(9) . . . . ?
P1 Rh1 Rh2 Cl2 -71.40(3) . . . . ?
C91 Rh3 Rh4 C90 127.11(11) . . . . ?
Cl3 Rh3 Rh4 C90 49.28(17) . . . . ?
P2 Rh3 Rh4 C90 -115.87(8) . . . . ?
C90 Rh3 Rh4 C91 -127.11(11) . . . . ?
Cl3 Rh3 Rh4 C91 -77.83(17) . . . . ?
P2 Rh3 Rh4 C91 117.02(8) . . . . ?
C91 Rh3 Rh4 P2 -117.02(8) . . . . ?
C90 Rh3 Rh4 P2 115.87(8) . . . . ?
Cl3 Rh3 Rh4 P2 165.15(15) . . . . ?
C91 Rh3 Rh4 Cl4 146.30(8) . . . 3_686 ?
C90 Rh3 Rh4 Cl4 19.19(9) . . . 3_686 ?
Cl3 Rh3 Rh4 Cl4 68.47(16) . . . 3_686 ?
P2 Rh3 Rh4 Cl4 -96.68(4) . . . 3_686 ?
C91 Rh3 Rh4 Cl4 -49.00(8) . . . . ?
C90 Rh3 Rh4 Cl4 -176.11(8) . . . . ?
Cl3 Rh3 Rh4 Cl4 -126.83(15) . . . . ?
P2 Rh3 Rh4 Cl4 68.02(3) . . . . ?
C1 Rh2 P1 C3 -161.77(11) . . . . ?
C2 Rh2 P1 C3 -74.59(11) . . . . ?
Cl2 Rh2 P1 C3 102.18(10) 3_575 . . . ?
Cl2 Rh2 P1 C3 21.81(10) . . . . ?
Rh1 Rh2 P1 C3 -117.49(10) . . . . ?
C1 Rh2 P1 C5 91.58(14) . . . . ?
C2 Rh2 P1 C5 178.77(13) . . . . ?
Cl2 Rh2 P1 C5 -4.47(12) 3_575 . . . ?
Cl2 Rh2 P1 C5 -84.83(12) . . . . ?
Rh1 Rh2 P1 C5 135.87(12) . . . . ?
C1 Rh2 P1 C4 -25.2(2) . . . . ?
C2 Rh2 P1 C4 61.9(2) . . . . ?
Cl2 Rh2 P1 C4 -121.3(2) 3_575 . . . ?
Cl2 Rh2 P1 C4 158.3(2) . . . . ?
Rh1 Rh2 P1 C4 19.04(19) . . . . ?
C1 Rh2 P1 Rh1 -44.29(6) . . . . ?
C2 Rh2 P1 Rh1 42.90(6) . . . . ?
Cl2 Rh2 P1 Rh1 -140.332(16) 3_575 . . . ?
Cl2 Rh2 P1 Rh1 139.300(16) . . . . ?
C2 Rh1 P1 C3 46.90(12) . . . . ?
C1 Rh1 P1 C3 138.07(12) . . . . ?
Cl1 Rh1 P1 C3 -86.37(10) . . . . ?
Rh2 Rh1 P1 C3 92.12(10) . . . . ?
C2 Rh1 P1 C5 -116.84(16) . . . . ?
C1 Rh1 P1 C5 -25.67(16) . . . . ?
Cl1 Rh1 P1 C5 109.89(15) . . . . ?
Rh2 Rh1 P1 C5 -71.62(14) . . . . ?
C2 Rh1 P1 C4 145.07(12) . . . . ?
C1 Rh1 P1 C4 -123.76(12) . . . . ?
Cl1 Rh1 P1 C4 11.80(11) . . . . ?
Rh2 Rh1 P1 C4 -169.71(11) . . . . ?
C2 Rh1 P1 Rh2 -45.22(6) . . . . ?
C1 Rh1 P1 Rh2 45.95(6) . . . . ?
Cl1 Rh1 P1 Rh2 -178.49(3) . . . . ?
C90 Rh4 P2 C92 -96.49(14) . . . . ?
C91 Rh4 P2 C92 175.88(14) . . . . ?
Cl4 Rh4 P2 C92 0.81(13) 3_686 . . . ?
Cl4 Rh4 P2 C92 81.05(12) . . . . ?
Rh3 Rh4 P2 C92 -140.77(12) . . . . ?
C90 Rh4 P2 C94 157.94(13) . . . . ?
C91 Rh4 P2 C94 70.31(13) . . . . ?
Cl4 Rh4 P2 C94 -104.75(11) 3_686 . . . ?
Cl4 Rh4 P2 C94 -24.52(11) . . . . ?
Rh3 Rh4 P2 C94 113.67(11) . . . . ?
C90 Rh4 P2 C93 15.5(2) . . . . ?
C91 Rh4 P2 C93 -72.2(2) . . . . ?
Cl4 Rh4 P2 C93 112.8(2) 3_686 . . . ?
Cl4 Rh4 P2 C93 -167.0(2) . . . . ?
Rh3 Rh4 P2 C93 -28.8(2) . . . . ?
C90 Rh4 P2 Rh3 44.28(6) . . . . ?
C91 Rh4 P2 Rh3 -43.35(6) . . . . ?
Cl4 Rh4 P2 Rh3 141.582(18) 3_686 . . . ?
Cl4 Rh4 P2 Rh3 -138.185(17) . . . . ?
C91 Rh3 P2 C92 110.41(16) . . . . ?
C90 Rh3 P2 C92 19.60(16) . . . . ?
Cl3 Rh3 P2 C92 -112.29(15) . . . . ?
Rh4 Rh3 P2 C92 65.17(15) . . . . ?
C91 Rh3 P2 C94 -49.86(13) . . . . ?
C90 Rh3 P2 C94 -140.66(13) . . . . ?
Cl3 Rh3 P2 C94 87.45(12) . . . . ?
Rh4 Rh3 P2 C94 -95.10(12) . . . . ?
C91 Rh3 P2 C93 -149.67(12) . . . . ?
C90 Rh3 P2 C93 119.52(12) . . . . ?
Cl3 Rh3 P2 C93 -12.37(11) . . . . ?
Rh4 Rh3 P2 C93 165.09(11) . . . . ?
C91 Rh3 P2 Rh4 45.24(6) . . . . ?
C90 Rh3 P2 Rh4 -45.57(6) . . . . ?
Cl3 Rh3 P2 Rh4 -177.45(3) . . . . ?
C1 Rh2 Cl2 Rh2 -47.6(4) . . . 3_575 ?
C2 Rh2 Cl2 Rh2 -159.60(6) . . . 3_575 ?
P1 Rh2 Cl2 Rh2 109.48(2) . . . 3_575 ?
Cl2 Rh2 Cl2 Rh2 0.0 3_575 . . 3_575 ?
Rh1 Rh2 Cl2 Rh2 166.855(14) . . . 3_575 ?
C90 Rh4 Cl4 Rh4 38.2(6) . . . 3_686 ?
C91 Rh4 Cl4 Rh4 152.80(6) . . . 3_686 ?
P2 Rh4 Cl4 Rh4 -118.03(2) . . . 3_686 ?
Cl4 Rh4 Cl4 Rh4 0.0 3_686 . . 3_686 ?
Rh3 Rh4 Cl4 Rh4 -171.497(14) . . . 3_686 ?
C2 Rh1 C1 C20 158.51(15) . . . . ?
Cl1 Rh1 C1 C20 -74.31(15) . . . . ?
P1 Rh1 C1 C20 70.15(14) . . . . ?
Rh2 Rh1 C1 C20 119.17(16) . . . . ?
C2 Rh1 C1 C10 -73.77(16) . . . . ?
Cl1 Rh1 C1 C10 53.40(17) . . . . ?
P1 Rh1 C1 C10 -162.14(15) . . . . ?
Rh2 Rh1 C1 C10 -113.12(17) . . . . ?
C2 Rh1 C1 Rh2 39.35(8) . . . . ?
Cl1 Rh1 C1 Rh2 166.52(3) . . . . ?
P1 Rh1 C1 Rh2 -49.02(5) . . . . ?
C2 Rh2 C1 C20 -145.17(18) . . . . ?
P1 Rh2 C1 C20 -55.25(17) . . . . ?
Cl2 Rh2 C1 C20 55.64(17) 3_575 . . . ?
Cl2 Rh2 C1 C20 102.1(4) . . . . ?
Rh1 Rh2 C1 C20 -107.66(18) . . . . ?
C2 Rh2 C1 C10 76.80(16) . . . . ?
P1 Rh2 C1 C10 166.72(15) . . . . ?
Cl2 Rh2 C1 C10 -82.39(15) 3_575 . . . ?
Cl2 Rh2 C1 C10 -35.9(5) . . . . ?
Rh1 Rh2 C1 C10 114.31(17) . . . . ?
C2 Rh2 C1 Rh1 -37.51(7) . . . . ?
P1 Rh2 C1 Rh1 52.41(5) . . . . ?
Cl2 Rh2 C1 Rh1 163.30(4) 3_575 . . . ?
Cl2 Rh2 C1 Rh1 -150.2(3) . . . . ?
C1 Rh1 C2 C30 64.98(16) . . . . ?
Cl1 Rh1 C2 C30 -64.09(17) . . . . ?
P1 Rh1 C2 C30 152.01(15) . . . . ?
Rh2 Rh1 C2 C30 104.10(17) . . . . ?
C1 Rh1 C2 C40 -160.26(15) . . . . ?
Cl1 Rh1 C2 C40 70.67(15) . . . . ?
P1 Rh1 C2 C40 -73.23(14) . . . . ?
Rh2 Rh1 C2 C40 -121.14(16) . . . . ?
C1 Rh1 C2 Rh2 -39.12(8) . . . . ?
Cl1 Rh1 C2 Rh2 -168.19(3) . . . . ?
P1 Rh1 C2 Rh2 47.90(5) . . . . ?
C1 Rh2 C2 C30 -78.62(14) . . . . ?
P1 Rh2 C2 C30 -167.74(13) . . . . ?
Cl2 Rh2 C2 C30 20.7(3) 3_575 . . . ?
Cl2 Rh2 C2 C30 92.81(13) . . . . ?
Rh1 Rh2 C2 C30 -116.53(16) . . . . ?
C1 Rh2 C2 C40 145.08(17) . . . . ?
P1 Rh2 C2 C40 55.97(16) . . . . ?
Cl2 Rh2 C2 C40 -115.56(19) 3_575 . . . ?
Cl2 Rh2 C2 C40 -43.49(17) . . . . ?
Rh1 Rh2 C2 C40 107.18(18) . . . . ?
C1 Rh2 C2 Rh1 37.90(8) . . . . ?
P1 Rh2 C2 Rh1 -51.21(5) . . . . ?
Cl2 Rh2 C2 Rh1 137.26(12) 3_575 . . . ?
Cl2 Rh2 C2 Rh1 -150.66(5) . . . . ?
C20 C1 C10 C11 -112.2(2) . . . . ?
Rh1 C1 C10 C11 119.0(2) . . . . ?
Rh2 C1 C10 C11 30.7(3) . . . . ?
C20 C1 C10 C15 63.2(3) . . . . ?
Rh1 C1 C10 C15 -65.6(2) . . . . ?
Rh2 C1 C10 C15 -153.90(17) . . . . ?
C15 C10 C11 C12 -0.8(3) . . . . ?
C1 C10 C11 C12 174.6(2) . . . . ?
C10 C11 C12 C13 0.0(4) . . . . ?
C11 C12 C13 C14 1.2(4) . . . . ?
C12 C13 C14 C15 -1.6(4) . . . . ?
C13 C14 C15 C10 0.7(4) . . . . ?
C11 C10 C15 C14 0.5(4) . . . . ?
C1 C10 C15 C14 -175.1(2) . . . . ?
C10 C1 C20 C21 -107.3(3) . . . . ?
Rh1 C1 C20 C21 24.5(3) . . . . ?
Rh2 C1 C20 C21 112.1(2) . . . . ?
C10 C1 C20 C25 68.0(3) . . . . ?
Rh1 C1 C20 C25 -160.19(18) . . . . ?
Rh2 C1 C20 C25 -72.6(3) . . . . ?
C25 C20 C21 C22 2.5(4) . . . . ?
C1 C20 C21 C22 177.9(3) . . . . ?
C20 C21 C22 C23 0.0(5) . . . . ?
C21 C22 C23 C24 -1.9(5) . . . . ?
C22 C23 C24 C25 1.2(5) . . . . ?
C23 C24 C25 C20 1.4(4) . . . . ?
C21 C20 C25 C24 -3.2(4) . . . . ?
C1 C20 C25 C24 -178.7(2) . . . . ?
C40 C2 C30 C31 -98.4(2) . . . . ?
Rh1 C2 C30 C31 35.5(3) . . . . ?
Rh2 C2 C30 C31 120.57(18) . . . . ?
C40 C2 C30 C35 80.3(2) . . . . ?
Rh1 C2 C30 C35 -145.86(17) . . . . ?
Rh2 C2 C30 C35 -60.7(2) . . . . ?
C35 C30 C31 C32 -0.2(3) . . . . ?
C2 C30 C31 C32 178.5(2) . . . . ?
C30 C31 C32 C33 -0.3(4) . . . . ?
C31 C32 C33 C34 0.3(4) . . . . ?
C32 C33 C34 C35 0.2(4) . . . . ?
C33 C34 C35 C30 -0.7(4) . . . . ?
C31 C30 C35 C34 0.7(3) . . . . ?
C2 C30 C35 C34 -178.1(2) . . . . ?
C30 C2 C40 C45 -66.5(3) . . . . ?
Rh1 C2 C40 C45 156.13(17) . . . . ?
Rh2 C2 C40 C45 67.8(3) . . . . ?
C30 C2 C40 C41 112.0(2) . . . . ?
Rh1 C2 C40 C41 -25.3(2) . . . . ?
Rh2 C2 C40 C41 -113.6(2) . . . . ?
C45 C40 C41 C42 -1.6(3) . . . . ?
C2 C40 C41 C42 179.8(2) . . . . ?
C40 C41 C42 C43 0.8(4) . . . . ?
C41 C42 C43 C44 0.0(4) . . . . ?
C42 C43 C44 C45 0.1(4) . . . . ?
C43 C44 C45 C40 -1.1(4) . . . . ?
C41 C40 C45 C44 1.8(3) . . . . ?
C2 C40 C45 C44 -179.7(2) . . . . ?
C55 C50 C51 C52 -0.9(4) . . . . ?
C90 C50 C51 C52 179.7(2) . . . . ?
C50 C51 C52 C53 0.3(4) . . . . ?
C51 C52 C53 C54 0.4(4) . . . . ?
C52 C53 C54 C55 -0.5(4) . . . . ?
C53 C54 C55 C50 0.0(4) . . . . ?
C51 C50 C55 C54 0.7(3) . . . . ?
C90 C50 C55 C54 -179.8(2) . . . . ?
C65 C60 C61 C62 -3.3(4) . . . . ?
C90 C60 C61 C62 178.5(2) . . . . ?
C60 C61 C62 C63 -0.5(4) . . . . ?
C61 C62 C63 C64 3.1(4) . . . . ?
C62 C63 C64 C65 -1.9(5) . . . . ?
C63 C64 C65 C60 -1.9(5) . . . . ?
C61 C60 C65 C64 4.5(4) . . . . ?
C90 C60 C65 C64 -177.2(3) . . . . ?
C75 C70 C71 C72 1.2(3) . . . . ?
C91 C70 C71 C72 177.8(2) . . . . ?
C70 C71 C72 C73 -1.3(4) . . . . ?
C71 C72 C73 C74 0.8(4) . . . . ?
C72 C73 C74 C75 -0.3(4) . . . . ?
C73 C74 C75 C70 0.2(4) . . . . ?
C71 C70 C75 C74 -0.6(3) . . . . ?
C91 C70 C75 C74 -177.2(2) . . . . ?
C85 C80 C81 C82 -2.2(4) . . . . ?
C91 C80 C81 C82 -178.0(2) . . . . ?
C80 C81 C82 C83 1.1(4) . . . . ?
C81 C82 C83 C84 0.7(4) . . . . ?
C82 C83 C84 C85 -1.3(4) . . . . ?
C81 C80 C85 C84 1.6(4) . . . . ?
C91 C80 C85 C84 177.4(2) . . . . ?
C83 C84 C85 C80 0.1(4) . . . . ?
C51 C50 C90 C60 108.0(2) . . . . ?
C55 C50 C90 C60 -71.5(3) . . . . ?
C51 C50 C90 Rh3 -123.2(2) . . . . ?
C55 C50 C90 Rh3 57.3(2) . . . . ?
C51 C50 C90 Rh4 -36.3(3) . . . . ?
C55 C50 C90 Rh4 144.30(18) . . . . ?
C61 C60 C90 C50 99.6(3) . . . . ?
C65 C60 C90 C50 -78.6(3) . . . . ?
C61 C60 C90 Rh3 -30.1(3) . . . . ?
C65 C60 C90 Rh3 151.6(2) . . . . ?
C61 C60 C90 Rh4 -117.2(2) . . . . ?
C65 C60 C90 Rh4 64.6(3) . . . . ?
C91 Rh3 C90 C50 74.87(16) . . . . ?
Cl3 Rh3 C90 C50 -58.76(17) . . . . ?
P2 Rh3 C90 C50 164.18(15) . . . . ?
Rh4 Rh3 C90 C50 114.34(17) . . . . ?
C91 Rh3 C90 C60 -156.58(15) . . . . ?
Cl3 Rh3 C90 C60 69.79(16) . . . . ?
P2 Rh3 C90 C60 -67.26(14) . . . . ?
Rh4 Rh3 C90 C60 -117.11(17) . . . . ?
C91 Rh3 C90 Rh4 -39.47(8) . . . . ?
Cl3 Rh3 C90 Rh4 -173.10(3) . . . . ?
P2 Rh3 C90 Rh4 49.84(5) . . . . ?
C91 Rh4 C90 C50 -72.50(17) . . . . ?
P2 Rh4 C90 C50 -161.11(16) . . . . ?
Cl4 Rh4 C90 C50 80.02(16) 3_686 . . . ?
Cl4 Rh4 C90 C50 42.5(7) . . . . ?
Rh3 Rh4 C90 C50 -110.44(18) . . . . ?
C91 Rh4 C90 C60 146.26(18) . . . . ?
P2 Rh4 C90 C60 57.64(17) . . . . ?
Cl4 Rh4 C90 C60 -61.23(17) 3_686 . . . ?
Cl4 Rh4 C90 C60 -98.8(6) . . . . ?
Rh3 Rh4 C90 C60 108.31(19) . . . . ?
C91 Rh4 C90 Rh3 37.94(8) . . . . ?
P2 Rh4 C90 Rh3 -50.67(5) . . . . ?
Cl4 Rh4 C90 Rh3 -169.54(5) 3_686 . . . ?
Cl4 Rh4 C90 Rh3 152.9(5) . . . . ?
C71 C70 C91 C80 -87.1(2) . . . . ?
C75 C70 C91 C80 89.4(2) . . . . ?
C71 C70 C91 Rh3 137.92(18) . . . . ?
C75 C70 C91 Rh3 -45.6(3) . . . . ?
C71 C70 C91 Rh4 54.0(2) . . . . ?
C75 C70 C91 Rh4 -129.46(18) . . . . ?
C85 C80 C91 C70 -119.6(2) . . . . ?
C81 C80 C91 C70 56.1(3) . . . . ?
C85 C80 C91 Rh3 18.7(3) . . . . ?
C81 C80 C91 Rh3 -165.59(18) . . . . ?
C85 C80 C91 Rh4 108.5(2) . . . . ?
C81 C80 C91 Rh4 -75.9(3) . . . . ?
C90 Rh3 C91 C70 -62.26(17) . . . . ?
Cl3 Rh3 C91 C70 69.26(17) . . . . ?
P2 Rh3 C91 C70 -150.67(15) . . . . ?
Rh4 Rh3 C91 C70 -101.51(17) . . . . ?
C90 Rh3 C91 C80 163.06(15) . . . . ?
Cl3 Rh3 C91 C80 -65.42(16) . . . . ?
P2 Rh3 C91 C80 74.65(14) . . . . ?
Rh4 Rh3 C91 C80 123.80(17) . . . . ?
C90 Rh3 C91 Rh4 39.25(8) . . . . ?
Cl3 Rh3 C91 Rh4 170.77(3) . . . . ?
P2 Rh3 C91 Rh4 -49.15(5) . . . . ?
C90 Rh4 C91 C70 79.35(14) . . . . ?
P2 Rh4 C91 C70 167.56(13) . . . . ?
Cl4 Rh4 C91 C70 -21.7(2) 3_686 . . . ?
Cl4 Rh4 C91 C70 -95.10(13) . . . . ?
Rh3 Rh4 C91 C70 117.59(15) . . . . ?
C90 Rh4 C91 C80 -146.64(19) . . . . ?
P2 Rh4 C91 C80 -58.43(18) . . . . ?
Cl4 Rh4 C91 C80 112.27(18) 3_686 . . . ?
Cl4 Rh4 C91 C80 38.91(18) . . . . ?
Rh3 Rh4 C91 C80 -108.4(2) . . . . ?
C90 Rh4 C91 Rh3 -38.24(8) . . . . ?
P2 Rh4 C91 Rh3 49.96(5) . . . . ?
Cl4 Rh4 C91 Rh3 -139.33(9) 3_686 . . . ?
Cl4 Rh4 C91 Rh3 147.31(5) . . . . ?
C105 C100 C101 C102 0.5(5) . . . . ?
C100 C101 C102 C103 0.4(5) . . . . ?
C101 C102 C103 C104 -1.3(5) . . . . ?
C102 C103 C104 C105 1.2(5) . . . . ?
C103 C104 C105 C100 -0.3(5) . . . . ?
C101 C100 C105 C104 -0.6(4) . . . . ?
C111 C106 C107 C108 1.3(5) . . . . ?
C106 C107 C108 C109 -0.1(6) . . . . ?
C107 C108 C109 C110 -1.3(6) . . . . ?
C108 C109 C110 C111 1.5(6) . . . . ?
C107 C106 C111 C110 -1.1(5) . . . . ?
C109 C110 C111 C106 -0.3(6) . . . . ?
