#------------------------------------------------------------------------------
#$Date: 2016-03-25 13:26:34 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179844 $
#$URL: svn://www.crystallography.net/cod/cif/7/01/40/7014029.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7014029
loop_
_publ_author_name
'Levason, William'
'Matthews, Melissa L.'
'Reid, Gillian'
'Webster, Michael'
_publ_section_title
;
 Synthesis and characterisation of transition metal halide complexes of
 the xylyl-distibine, 1,2-bis(dimethylstibanylmethyl)benzene.
;
_journal_issue                   4
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              554
_journal_page_last               561
_journal_paper_doi               10.1039/b400214h
_journal_year                    2004
_chemical_formula_moiety         'C24 H40 I Ni Sb4 1+, Cl O4 1-'
_chemical_formula_sum            'C24 H40 Cl I Ni O4 Sb4'
_chemical_formula_weight         1100.62
_chemical_name_systematic
;
Iodobis(1,2-bis(dimethylstibanylmethyl)benzene)nickel(II) perchlorate
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           'SHELXL-97 + hand edit'
_cell_angle_alpha                95.814(10)
_cell_angle_beta                 95.740(10)
_cell_angle_gamma                107.789(8)
_cell_formula_units_Z            4
_cell_length_a                   9.4616(15)
_cell_length_b                   13.608(3)
_cell_length_c                   27.146(4)
_cell_measurement_reflns_used    47934
_cell_measurement_temperature    120(2)
_cell_measurement_theta_max      27.48
_cell_measurement_theta_min      2.91
_cell_volume                     3279.1(10)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      120(2)
_diffrn_measured_fraction_theta_full 0.973
_diffrn_measured_fraction_theta_max 0.973
_diffrn_measurement_device_type  'area detector, Nonius Kappa ccd'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'Nonius rotating anode'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.1004
_diffrn_reflns_av_sigmaI/netI    0.1030
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       32
_diffrn_reflns_limit_l_min       -32
_diffrn_reflns_number            38793
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         3.00
_exptl_absorpt_coefficient_mu    4.866
_exptl_absorpt_correction_T_max  0.88270
_exptl_absorpt_correction_T_min  0.78889
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
'SORTAV, R H Blessing, J. Appl. Cryst., 1997, 30, 421-426.'
_exptl_crystal_colour            'dark green'
_exptl_crystal_density_diffrn    2.229
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             2072
_exptl_crystal_size_max          0.12
_exptl_crystal_size_mid          0.12
_exptl_crystal_size_min          0.02
_refine_diff_density_max         1.759
_refine_diff_density_min         -1.889
_refine_diff_density_rms         0.268
_refine_ls_extinction_coef       0.00079(8)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.007
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     634
_refine_ls_number_reflns         11251
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.007
_refine_ls_R_factor_all          0.1123
_refine_ls_R_factor_gt           0.0586
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0771P)²+3.4579P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1387
_refine_ls_wR_factor_ref         0.1595
_reflns_number_gt                7012
_reflns_number_total             11251
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b400214h.txt
_cod_data_source_block           niisb4
_cod_original_cell_volume        3279.2(9)
_cod_database_code               7014029
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ni1 Ni 0.91208(18) 0.26624(13) 0.10829(6) 0.0214(4) Uani 1 1 d . . .
Ni2 Ni 0.60374(18) 0.75059(13) 0.38430(6) 0.0212(4) Uani 1 1 d . . .
I1 I 1.16888(10) 0.40270(7) 0.09953(4) 0.0330(3) Uani 1 1 d . . .
I2 I 0.34215(10) 0.61043(7) 0.38388(4) 0.0340(3) Uani 1 1 d . . .
Sb1 Sb 0.90650(10) 0.08661(7) 0.11597(3) 0.0215(2) Uani 1 1 d . . .
Sb2 Sb 0.98963(10) 0.31280(7) 0.19816(3) 0.0269(2) Uani 1 1 d . . .
Sb3 Sb 0.69061(10) 0.32609(7) 0.10740(3) 0.0241(2) Uani 1 1 d . . .
Sb4 Sb 0.87317(10) 0.23453(7) 0.01700(3) 0.0229(2) Uani 1 1 d . . .
Sb5 Sb 0.82862(10) 0.69401(7) 0.38358(3) 0.0234(2) Uani 1 1 d . . .
Sb6 Sb 0.62999(10) 0.76122(7) 0.47494(3) 0.0233(2) Uani 1 1 d . . .
Sb7 Sb 0.60698(10) 0.93239(7) 0.38440(3) 0.0220(2) Uani 1 1 d . . .
Sb8 Sb 0.54366(10) 0.72249(7) 0.29383(3) 0.0260(2) Uani 1 1 d . . .
Cl1 Cl 0.9780(4) 0.7223(3) 0.15298(12) 0.0306(8) Uani 1 1 d . . .
Cl2 Cl 0.5393(4) 0.3073(3) 0.35341(13) 0.0326(8) Uani 1 1 d . . .
O1 O 0.942(4) 0.6806(15) 0.1954(7) 0.142(11) Uani 1 1 d . . .
O2 O 0.9024(14) 0.7978(9) 0.1461(4) 0.049(3) Uani 1 1 d . . .
O3 O 1.1335(16) 0.7768(13) 0.1572(9) 0.107(7) Uani 1 1 d . . .
O4 O 0.9373(13) 0.6431(9) 0.1107(4) 0.046(3) Uani 1 1 d . . .
O5 O 0.5365(12) 0.3611(9) 0.4016(4) 0.044(3) Uani 1 1 d . . .
O6 O 0.6470(17) 0.3742(11) 0.3288(5) 0.070(4) Uani 1 1 d . . .
O7 O 0.5835(16) 0.2183(9) 0.3600(4) 0.057(3) Uani 1 1 d . . .
O8 O 0.3989(15) 0.2771(13) 0.3240(5) 0.081(5) Uani 1 1 d . . .
C1 C 0.7472(17) -0.0419(11) 0.0683(5) 0.030(3) Uani 1 1 d . . .
H1A H 0.7565 -0.0326 0.0333 0.099(11) Uiso 1 1 calc R . .
H1B H 0.6458 -0.0457 0.0748 0.099(11) Uiso 1 1 calc R . .
H1C H 0.7662 -0.1066 0.0748 0.099(11) Uiso 1 1 calc R . .
C2 C 1.1088(17) 0.0470(14) 0.1136(7) 0.042(4) Uani 1 1 d . . .
H2A H 1.1518 0.0676 0.0834 0.099(11) Uiso 1 1 calc R . .
H2B H 1.0861 -0.0283 0.1132 0.099(11) Uiso 1 1 calc R . .
H2C H 1.1808 0.0838 0.1432 0.099(11) Uiso 1 1 calc R . .
C3 C 0.8440(15) 0.0345(10) 0.1846(5) 0.023(3) Uani 1 1 d . . .
H3A H 0.8295 -0.0410 0.1828 0.044(8) Uiso 1 1 calc R . .
H3B H 0.9250 0.0716 0.2124 0.044(8) Uiso 1 1 calc R . .
C4 C 0.6998(16) 0.0553(11) 0.1947(5) 0.028(3) Uani 1 1 d . . .
C5 C 0.5642(16) -0.0169(12) 0.1748(5) 0.032(3) Uani 1 1 d . . .
H5 H 0.5639 -0.0766 0.1533 0.044(8) Uiso 1 1 calc R . .
C6 C 0.4271(18) -0.0069(14) 0.1844(6) 0.041(4) Uani 1 1 d . . .
H6 H 0.3351 -0.0605 0.1725 0.044(8) Uiso 1 1 calc R . .
C7 C 0.4325(19) 0.0874(13) 0.2129(6) 0.037(4) Uani 1 1 d . . .
H7 H 0.3409 0.0981 0.2192 0.044(8) Uiso 1 1 calc R . .
C8 C 0.5651(19) 0.1643(14) 0.2318(6) 0.038(4) Uani 1 1 d . . .
H8 H 0.5649 0.2265 0.2511 0.044(8) Uiso 1 1 calc R . .
C9 C 0.7011(17) 0.1494(12) 0.2223(6) 0.035(4) Uani 1 1 d . . .
C10 C 0.8460(19) 0.2325(13) 0.2474(6) 0.043(4) Uani 1 1 d . . .
H10A H 0.9031 0.1990 0.2689 0.044(8) Uiso 1 1 calc R . .
H10B H 0.8194 0.2847 0.2696 0.044(8) Uiso 1 1 calc R . .
C11 C 1.0383(19) 0.4708(11) 0.2301(6) 0.041(4) Uani 1 1 d . . .
H11A H 1.1049 0.5164 0.2105 0.099(11) Uiso 1 1 calc R . .
H11B H 1.0875 0.4808 0.2645 0.099(11) Uiso 1 1 calc R . .
H11C H 0.9449 0.4879 0.2299 0.099(11) Uiso 1 1 calc R . .
C12 C 1.1923(18) 0.2826(12) 0.2256(6) 0.039(4) Uani 1 1 d . . .
H12A H 1.1842 0.2106 0.2135 0.099(11) Uiso 1 1 calc R . .
H12B H 1.2066 0.2932 0.2623 0.099(11) Uiso 1 1 calc R . .
H12C H 1.2780 0.3304 0.2136 0.099(11) Uiso 1 1 calc R . .
C13 C 0.4784(18) 0.2078(12) 0.0872(7) 0.040(4) Uani 1 1 d . . .
H13A H 0.4827 0.1601 0.0582 0.099(11) Uiso 1 1 calc R . .
H13B H 0.4013 0.2400 0.0787 0.099(11) Uiso 1 1 calc R . .
H13C H 0.4539 0.1688 0.1153 0.099(11) Uiso 1 1 calc R . .
C14 C 0.645(2) 0.4147(13) 0.1701(6) 0.040(4) Uani 1 1 d . . .
H14A H 0.7347 0.4737 0.1834 0.099(11) Uiso 1 1 calc R . .
H14B H 0.6167 0.3702 0.1960 0.099(11) Uiso 1 1 calc R . .
H14C H 0.5625 0.4407 0.1594 0.099(11) Uiso 1 1 calc R . .
C15 C 0.6709(16) 0.4326(11) 0.0546(5) 0.028(3) Uani 1 1 d . . .
H15A H 0.6044 0.4711 0.0663 0.044(8) Uiso 1 1 calc R . .
H15B H 0.7711 0.4841 0.0551 0.044(8) Uiso 1 1 calc R . .
C16 C 0.6116(15) 0.3828(10) 0.0020(5) 0.024(3) Uani 1 1 d . . .
C17 C 0.4609(16) 0.3674(10) -0.0151(6) 0.033(3) Uani 1 1 d . . .
H17 H 0.3994 0.3847 0.0077 0.044(8) Uiso 1 1 calc R . .
C18 C 0.3992(17) 0.3281(11) -0.0638(6) 0.032(3) Uani 1 1 d . . .
H18 H 0.2954 0.3153 -0.0738 0.044(8) Uiso 1 1 calc R . .
C19 C 0.487(2) 0.3074(12) -0.0978(6) 0.045(4) Uani 1 1 d . . .
H19 H 0.4458 0.2843 -0.1320 0.044(8) Uiso 1 1 calc R . .
C20 C 0.6373(17) 0.3205(12) -0.0819(5) 0.030(3) Uani 1 1 d . . .
H20 H 0.6986 0.3030 -0.1047 0.044(8) Uiso 1 1 calc R . .
C21 C 0.6968(15) 0.3599(12) -0.0317(6) 0.033(4) Uani 1 1 d . . .
C22 C 0.8598(15) 0.3670(11) -0.0173(6) 0.027(3) Uani 1 1 d . . .
H22A H 0.9115 0.4315 0.0063 0.044(8) Uiso 1 1 calc R . .
H22B H 0.9108 0.3705 -0.0475 0.044(8) Uiso 1 1 calc R . .
C23 C 1.0426(18) 0.1882(12) -0.0134(6) 0.039(4) Uani 1 1 d . . .
H23A H 1.0535 0.1274 0.0011 0.099(11) Uiso 1 1 calc R . .
H23B H 1.1376 0.2455 -0.0058 0.099(11) Uiso 1 1 calc R . .
H23C H 1.0157 0.1700 -0.0497 0.099(11) Uiso 1 1 calc R . .
C24 C 0.6775(15) 0.1169(10) -0.0237(6) 0.031(3) Uani 1 1 d . . .
H24A H 0.5873 0.1288 -0.0132 0.099(11) Uiso 1 1 calc R . .
H24B H 0.6794 0.0479 -0.0169 0.099(11) Uiso 1 1 calc R . .
H24C H 0.6767 0.1205 -0.0596 0.099(11) Uiso 1 1 calc R . .
C25 C 1.0383(15) 0.8151(12) 0.4114(6) 0.032(3) Uani 1 1 d . . .
H25A H 1.0456 0.8756 0.3939 0.099(11) Uiso 1 1 calc R . .
H25B H 1.1218 0.7890 0.4056 0.099(11) Uiso 1 1 calc R . .
H25C H 1.0426 0.8356 0.4473 0.099(11) Uiso 1 1 calc R . .
C26 C 0.8879(18) 0.6245(12) 0.3165(6) 0.036(4) Uani 1 1 d . . .
H26A H 0.8847 0.6676 0.2899 0.099(11) Uiso 1 1 calc R . .
H26B H 0.8165 0.5544 0.3059 0.099(11) Uiso 1 1 calc R . .
H26C H 0.9892 0.6200 0.3235 0.099(11) Uiso 1 1 calc R . .
C27 C 0.8494(16) 0.5779(11) 0.4290(5) 0.028(3) Uani 1 1 d . . .
H27A H 0.7515 0.5218 0.4242 0.044(8) Uiso 1 1 calc R . .
H27B H 0.9229 0.5469 0.4162 0.044(8) Uiso 1 1 calc R . .
C28 C 0.8960(17) 0.6113(10) 0.4841(5) 0.029(3) Uani 1 1 d . . .
C29 C 1.0467(16) 0.6281(11) 0.5024(6) 0.033(3) Uani 1 1 d . . .
H29 H 1.1145 0.6229 0.4794 0.044(8) Uiso 1 1 calc R . .
C30 C 1.0988(17) 0.6518(11) 0.5525(6) 0.037(4) Uani 1 1 d . . .
H30 H 1.2002 0.6599 0.5644 0.044(8) Uiso 1 1 calc R . .
C31 C 0.9984(18) 0.6640(11) 0.5863(6) 0.039(4) Uani 1 1 d . . .
H31 H 1.0329 0.6820 0.6211 0.044(8) Uiso 1 1 calc R . .
C32 C 0.8499(19) 0.6499(12) 0.5686(6) 0.036(4) Uani 1 1 d . . .
H32 H 0.7816 0.6556 0.5913 0.044(8) Uiso 1 1 calc R . .
C33 C 0.8027(17) 0.6275(11) 0.5181(5) 0.030(3) Uani 1 1 d . . .
C34 C 0.6381(17) 0.6177(11) 0.5002(6) 0.032(3) Uani 1 1 d . . .
H34A H 0.5779 0.6031 0.5280 0.044(8) Uiso 1 1 calc R . .
H34B H 0.5954 0.5593 0.4726 0.044(8) Uiso 1 1 calc R . .
C35 C 0.4562(16) 0.7999(13) 0.5077(6) 0.039(4) Uani 1 1 d . . .
H35A H 0.3588 0.7549 0.4901 0.099(11) Uiso 1 1 calc R . .
H35B H 0.4657 0.8729 0.5051 0.099(11) Uiso 1 1 calc R . .
H35C H 0.4638 0.7898 0.5430 0.099(11) Uiso 1 1 calc R . .
C36 C 0.8199(18) 0.8710(12) 0.5211(6) 0.038(4) Uani 1 1 d . . .
H36A H 0.9120 0.8630 0.5103 0.099(11) Uiso 1 1 calc R . .
H36B H 0.8167 0.8585 0.5560 0.099(11) Uiso 1 1 calc R . .
H36C H 0.8181 0.9419 0.5183 0.099(11) Uiso 1 1 calc R . .
C37 C 0.7597(16) 1.0536(11) 0.4379(5) 0.028(3) Uani 1 1 d . . .
H37A H 0.8598 1.0463 0.4395 0.099(11) Uiso 1 1 calc R . .
H37B H 0.7262 1.0488 0.4708 0.099(11) Uiso 1 1 calc R . .
H37C H 0.7632 1.1215 0.4279 0.099(11) Uiso 1 1 calc R . .
C38 C 0.4046(16) 0.9694(14) 0.3898(6) 0.040(4) Uani 1 1 d . . .
H38A H 0.3225 0.9187 0.3666 0.099(11) Uiso 1 1 calc R . .
H38B H 0.4177 1.0395 0.3810 0.099(11) Uiso 1 1 calc R . .
H38C H 0.3808 0.9669 0.4240 0.099(11) Uiso 1 1 calc R . .
C39 C 0.6757(17) 1.0000(12) 0.3180(5) 0.033(3) Uani 1 1 d . . .
H39A H 0.6016 0.9630 0.2884 0.044(8) Uiso 1 1 calc R . .
H39B H 0.6813 1.0743 0.3219 0.044(8) Uiso 1 1 calc R . .
C40 C 0.8238(17) 0.9907(10) 0.3109(5) 0.030(3) Uani 1 1 d . . .
C41 C 0.9557(18) 1.0677(12) 0.3326(5) 0.034(4) Uani 1 1 d . . .
H41 H 0.9478 1.1254 0.3537 0.044(8) Uiso 1 1 calc R . .
C42 C 1.0975(17) 1.0658(13) 0.3256(5) 0.037(4) Uani 1 1 d . . .
H42 H 1.1841 1.1221 0.3400 0.044(8) Uiso 1 1 calc R . .
C43 C 1.1096(18) 0.9804(14) 0.2972(6) 0.042(4) Uani 1 1 d . . .
H43 H 1.2055 0.9763 0.2919 0.044(8) Uiso 1 1 calc R . .
C44 C 0.9787(18) 0.8983(13) 0.2759(6) 0.036(4) Uani 1 1 d . . .
H44 H 0.9887 0.8382 0.2575 0.044(8) Uiso 1 1 calc R . .
C45 C 0.8359(16) 0.9025(11) 0.2808(5) 0.027(3) Uani 1 1 d . . .
C46 C 0.7006(17) 0.8186(12) 0.2526(5) 0.033(3) Uani 1 1 d . . .
H46A H 0.7367 0.7720 0.2304 0.044(8) Uiso 1 1 calc R . .
H46B H 0.6449 0.8525 0.2309 0.044(8) Uiso 1 1 calc R . .
C47 C 0.3434(19) 0.7508(12) 0.2669(6) 0.040(4) Uani 1 1 d . . .
H47A H 0.3456 0.8198 0.2822 0.099(11) Uiso 1 1 calc R . .
H47B H 0.2571 0.6975 0.2756 0.099(11) Uiso 1 1 calc R . .
H47C H 0.3350 0.7483 0.2305 0.099(11) Uiso 1 1 calc R . .
C48 C 0.5085(19) 0.5723(12) 0.2554(6) 0.041(4) Uani 1 1 d . . .
H48A H 0.5953 0.5497 0.2646 0.099(11) Uiso 1 1 calc R . .
H48B H 0.4956 0.5743 0.2193 0.099(11) Uiso 1 1 calc R . .
H48C H 0.4184 0.5233 0.2644 0.099(11) Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ni Ni 0.3393 1.1124 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
I I -0.4742 1.8119 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Sb2 Ni1 Sb4 171.36(8) . . ?
Sb2 Ni1 Sb1 89.35(6) . . ?
Sb4 Ni1 Sb1 93.19(6) . . ?
Sb2 Ni1 Sb3 95.19(6) . . ?
Sb4 Ni1 Sb3 90.20(6) . . ?
Sb1 Ni1 Sb3 124.26(7) . . ?
Sb2 Ni1 I1 85.74(6) . . ?
Sb4 Ni1 I1 85.77(6) . . ?
Sb1 Ni1 I1 117.99(7) . . ?
Sb3 Ni1 I1 117.75(7) . . ?
Sb8 Ni2 Sb6 172.07(8) . . ?
Sb8 Ni2 Sb7 89.18(6) . . ?
Sb6 Ni2 Sb7 94.21(6) . . ?
Sb8 Ni2 Sb5 94.04(6) . . ?
Sb6 Ni2 Sb5 89.97(6) . . ?
Sb7 Ni2 Sb5 124.28(7) . . ?
Sb8 Ni2 I2 85.85(6) . . ?
Sb6 Ni2 I2 86.22(6) . . ?
Sb7 Ni2 I2 116.69(7) . . ?
Sb5 Ni2 I2 119.02(7) . . ?
C1 Sb1 C3 96.1(6) . . ?
C1 Sb1 C2 101.7(6) . . ?
C3 Sb1 C2 100.3(6) . . ?
C1 Sb1 Ni1 120.6(4) . . ?
C3 Sb1 Ni1 114.7(4) . . ?
C2 Sb1 Ni1 119.2(5) . . ?
C11 Sb2 C10 101.5(7) . . ?
C11 Sb2 C12 101.1(6) . . ?
C10 Sb2 C12 98.8(7) . . ?
C11 Sb2 Ni1 118.6(4) . . ?
C10 Sb2 Ni1 118.6(4) . . ?
C12 Sb2 Ni1 114.9(4) . . ?
C13 Sb3 C14 100.3(7) . . ?
C13 Sb3 C15 100.3(6) . . ?
C14 Sb3 C15 95.6(6) . . ?
C13 Sb3 Ni1 115.9(4) . . ?
C14 Sb3 Ni1 123.9(5) . . ?
C15 Sb3 Ni1 116.6(4) . . ?
C23 Sb4 C22 106.1(6) . . ?
C23 Sb4 C24 100.2(6) . . ?
C22 Sb4 C24 100.0(6) . . ?
C23 Sb4 Ni1 113.4(5) . . ?
C22 Sb4 Ni1 113.7(4) . . ?
C24 Sb4 Ni1 121.4(4) . . ?
C27 Sb5 C25 99.5(6) . . ?
C27 Sb5 C26 96.4(6) . . ?
C25 Sb5 C26 100.3(6) . . ?
C27 Sb5 Ni2 118.3(4) . . ?
C25 Sb5 Ni2 114.7(4) . . ?
C26 Sb5 Ni2 123.3(4) . . ?
C35 Sb6 C36 99.5(6) . . ?
C35 Sb6 C34 106.4(6) . . ?
C36 Sb6 C34 100.9(6) . . ?
C35 Sb6 Ni2 114.3(4) . . ?
C36 Sb6 Ni2 121.2(5) . . ?
C34 Sb6 Ni2 112.6(4) . . ?
C37 Sb7 C38 100.4(6) . . ?
C37 Sb7 C39 96.9(6) . . ?
C38 Sb7 C39 100.9(6) . . ?
C37 Sb7 Ni2 120.3(4) . . ?
C38 Sb7 Ni2 119.5(5) . . ?
C39 Sb7 Ni2 114.8(4) . . ?
C48 Sb8 C47 101.2(6) . . ?
C48 Sb8 C46 101.7(6) . . ?
C47 Sb8 C46 101.0(6) . . ?
C48 Sb8 Ni2 118.5(5) . . ?
C47 Sb8 Ni2 114.5(4) . . ?
C46 Sb8 Ni2 117.2(4) . . ?
O1 Cl1 O3 111.4(17) . . ?
O1 Cl1 O4 110.9(11) . . ?
O3 Cl1 O4 108.8(9) . . ?
O1 Cl1 O2 108.6(10) . . ?
O3 Cl1 O2 106.4(9) . . ?
O4 Cl1 O2 110.6(7) . . ?
O8 Cl2 O6 109.4(10) . . ?
O8 Cl2 O7 109.9(9) . . ?
O6 Cl2 O7 108.1(9) . . ?
O8 Cl2 O5 111.2(8) . . ?
O6 Cl2 O5 108.9(7) . . ?
O7 Cl2 O5 109.3(7) . . ?
Sb1 C1 H1A 109.5 . . ?
Sb1 C1 H1B 109.5 . . ?
H1A C1 H1B 109.5 . . ?
Sb1 C1 H1C 109.5 . . ?
H1A C1 H1C 109.5 . . ?
H1B C1 H1C 109.5 . . ?
Sb1 C2 H2A 109.5 . . ?
Sb1 C2 H2B 109.5 . . ?
H2A C2 H2B 109.5 . . ?
Sb1 C2 H2C 109.5 . . ?
H2A C2 H2C 109.5 . . ?
H2B C2 H2C 109.5 . . ?
C4 C3 Sb1 109.9(8) . . ?
C4 C3 H3A 109.7 . . ?
Sb1 C3 H3A 109.7 . . ?
C4 C3 H3B 109.7 . . ?
Sb1 C3 H3B 109.7 . . ?
H3A C3 H3B 108.2 . . ?
C5 C4 C9 118.7(13) . . ?
C5 C4 C3 119.6(13) . . ?
C9 C4 C3 121.6(13) . . ?
C4 C5 C6 123.3(15) . . ?
C4 C5 H5 118.3 . . ?
C6 C5 H5 118.3 . . ?
C5 C6 C7 116.3(15) . . ?
C5 C6 H6 121.9 . . ?
C7 C6 H6 121.9 . . ?
C8 C7 C6 122.5(15) . . ?
C8 C7 H7 118.7 . . ?
C6 C7 H7 118.7 . . ?
C7 C8 C9 119.1(15) . . ?
C7 C8 H8 120.5 . . ?
C9 C8 H8 120.5 . . ?
C8 C9 C4 119.8(14) . . ?
C8 C9 C10 117.4(14) . . ?
C4 C9 C10 122.5(13) . . ?
C9 C10 Sb2 115.9(10) . . ?
C9 C10 H10A 108.3 . . ?
Sb2 C10 H10A 108.3 . . ?
C9 C10 H10B 108.3 . . ?
Sb2 C10 H10B 108.3 . . ?
H10A C10 H10B 107.4 . . ?
Sb2 C11 H11A 109.5 . . ?
Sb2 C11 H11B 109.5 . . ?
H11A C11 H11B 109.5 . . ?
Sb2 C11 H11C 109.5 . . ?
H11A C11 H11C 109.5 . . ?
H11B C11 H11C 109.5 . . ?
Sb2 C12 H12A 109.5 . . ?
Sb2 C12 H12B 109.5 . . ?
H12A C12 H12B 109.5 . . ?
Sb2 C12 H12C 109.5 . . ?
H12A C12 H12C 109.5 . . ?
H12B C12 H12C 109.5 . . ?
Sb3 C13 H13A 109.5 . . ?
Sb3 C13 H13B 109.5 . . ?
H13A C13 H13B 109.5 . . ?
Sb3 C13 H13C 109.5 . . ?
H13A C13 H13C 109.5 . . ?
H13B C13 H13C 109.5 . . ?
Sb3 C14 H14A 109.5 . . ?
Sb3 C14 H14B 109.5 . . ?
H14A C14 H14B 109.5 . . ?
Sb3 C14 H14C 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
C16 C15 Sb3 115.3(9) . . ?
C16 C15 H15A 108.4 . . ?
Sb3 C15 H15A 108.4 . . ?
C16 C15 H15B 108.4 . . ?
Sb3 C15 H15B 108.4 . . ?
H15A C15 H15B 107.5 . . ?
C21 C16 C17 117.5(14) . . ?
C21 C16 C15 124.3(13) . . ?
C17 C16 C15 118.0(13) . . ?
C18 C17 C16 121.9(15) . . ?
C18 C17 H17 119.0 . . ?
C16 C17 H17 119.0 . . ?
C19 C18 C17 120.2(14) . . ?
C19 C18 H18 119.9 . . ?
C17 C18 H18 119.9 . . ?
C18 C19 C20 119.3(15) . . ?
C18 C19 H19 120.4 . . ?
C20 C19 H19 120.4 . . ?
C19 C20 C21 119.1(14) . . ?
C19 C20 H20 120.5 . . ?
C21 C20 H20 120.5 . . ?
C16 C21 C20 121.9(13) . . ?
C16 C21 C22 122.5(13) . . ?
C20 C21 C22 115.4(13) . . ?
C21 C22 Sb4 110.5(9) . . ?
C21 C22 H22A 109.5 . . ?
Sb4 C22 H22A 109.5 . . ?
C21 C22 H22B 109.5 . . ?
Sb4 C22 H22B 109.5 . . ?
H22A C22 H22B 108.1 . . ?
Sb4 C23 H23A 109.5 . . ?
Sb4 C23 H23B 109.5 . . ?
H23A C23 H23B 109.5 . . ?
Sb4 C23 H23C 109.5 . . ?
H23A C23 H23C 109.5 . . ?
H23B C23 H23C 109.5 . . ?
Sb4 C24 H24A 109.5 . . ?
Sb4 C24 H24B 109.5 . . ?
H24A C24 H24B 109.5 . . ?
Sb4 C24 H24C 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?
Sb5 C25 H25A 109.5 . . ?
Sb5 C25 H25B 109.5 . . ?
H25A C25 H25B 109.5 . . ?
Sb5 C25 H25C 109.5 . . ?
H25A C25 H25C 109.5 . . ?
H25B C25 H25C 109.5 . . ?
Sb5 C26 H26A 109.5 . . ?
Sb5 C26 H26B 109.5 . . ?
H26A C26 H26B 109.5 . . ?
Sb5 C26 H26C 109.5 . . ?
H26A C26 H26C 109.5 . . ?
H26B C26 H26C 109.5 . . ?
C28 C27 Sb5 117.8(9) . . ?
C28 C27 H27A 107.9 . . ?
Sb5 C27 H27A 107.9 . . ?
C28 C27 H27B 107.9 . . ?
Sb5 C27 H27B 107.9 . . ?
H27A C27 H27B 107.2 . . ?
C33 C28 C29 117.6(14) . . ?
C33 C28 C27 125.3(14) . . ?
C29 C28 C27 117.0(13) . . ?
C30 C29 C28 121.8(15) . . ?
C30 C29 H29 119.1 . . ?
C28 C29 H29 119.1 . . ?
C29 C30 C31 118.7(14) . . ?
C29 C30 H30 120.7 . . ?
C31 C30 H30 120.7 . . ?
C32 C31 C30 120.2(15) . . ?
C32 C31 H31 119.9 . . ?
C30 C31 H31 119.9 . . ?
C33 C32 C31 119.3(16) . . ?
C33 C32 H32 120.3 . . ?
C31 C32 H32 120.3 . . ?
C32 C33 C28 122.2(15) . . ?
C32 C33 C34 117.2(14) . . ?
C28 C33 C34 120.6(13) . . ?
C33 C34 Sb6 109.2(9) . . ?
C33 C34 H34A 109.8 . . ?
Sb6 C34 H34A 109.8 . . ?
C33 C34 H34B 109.8 . . ?
Sb6 C34 H34B 109.8 . . ?
H34A C34 H34B 108.3 . . ?
Sb6 C35 H35A 109.5 . . ?
Sb6 C35 H35B 109.5 . . ?
H35A C35 H35B 109.5 . . ?
Sb6 C35 H35C 109.5 . . ?
H35A C35 H35C 109.5 . . ?
H35B C35 H35C 109.5 . . ?
Sb6 C36 H36A 109.5 . . ?
Sb6 C36 H36B 109.5 . . ?
H36A C36 H36B 109.5 . . ?
Sb6 C36 H36C 109.5 . . ?
H36A C36 H36C 109.5 . . ?
H36B C36 H36C 109.5 . . ?
Sb7 C37 H37A 109.5 . . ?
Sb7 C37 H37B 109.5 . . ?
H37A C37 H37B 109.5 . . ?
Sb7 C37 H37C 109.5 . . ?
H37A C37 H37C 109.5 . . ?
H37B C37 H37C 109.5 . . ?
Sb7 C38 H38A 109.5 . . ?
Sb7 C38 H38B 109.5 . . ?
H38A C38 H38B 109.5 . . ?
Sb7 C38 H38C 109.5 . . ?
H38A C38 H38C 109.5 . . ?
H38B C38 H38C 109.5 . . ?
C40 C39 Sb7 108.8(10) . . ?
C40 C39 H39A 109.9 . . ?
Sb7 C39 H39A 109.9 . . ?
C40 C39 H39B 109.9 . . ?
Sb7 C39 H39B 109.9 . . ?
H39A C39 H39B 108.3 . . ?
C41 C40 C45 117.7(14) . . ?
C41 C40 C39 121.6(14) . . ?
C45 C40 C39 120.7(13) . . ?
C42 C41 C40 124.4(15) . . ?
C42 C41 H41 117.8 . . ?
C40 C41 H41 117.8 . . ?
C43 C42 C41 118.0(15) . . ?
C43 C42 H42 121.0 . . ?
C41 C42 H42 121.0 . . ?
C42 C43 C44 119.6(14) . . ?
C42 C43 H43 120.2 . . ?
C44 C43 H43 120.2 . . ?
C45 C44 C43 122.4(15) . . ?
C45 C44 H44 118.8 . . ?
C43 C44 H44 118.8 . . ?
C44 C45 C40 117.8(14) . . ?
C44 C45 C46 120.2(13) . . ?
C40 C45 C46 122.0(13) . . ?
C45 C46 Sb8 119.1(9) . . ?
C45 C46 H46A 107.6 . . ?
Sb8 C46 H46A 107.6 . . ?
C45 C46 H46B 107.6 . . ?
Sb8 C46 H46B 107.6 . . ?
H46A C46 H46B 107.0 . . ?
Sb8 C47 H47A 109.5 . . ?
Sb8 C47 H47B 109.5 . . ?
H47A C47 H47B 109.5 . . ?
Sb8 C47 H47C 109.5 . . ?
H47A C47 H47C 109.5 . . ?
H47B C47 H47C 109.5 . . ?
Sb8 C48 H48A 109.5 . . ?
Sb8 C48 H48B 109.5 . . ?
H48A C48 H48B 109.5 . . ?
Sb8 C48 H48C 109.5 . . ?
H48A C48 H48C 109.5 . . ?
H48B C48 H48C 109.5 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ni1 Sb2 2.4364(19) . ?
Ni1 Sb4 2.4427(19) . ?
Ni1 Sb1 2.4592(19) . ?
Ni1 Sb3 2.4681(19) . ?
Ni1 I1 2.6185(19) . ?
Ni2 Sb8 2.4286(19) . ?
Ni2 Sb6 2.4333(19) . ?
Ni2 Sb7 2.4645(19) . ?
Ni2 Sb5 2.4751(19) . ?
Ni2 I2 2.6209(19) . ?
Sb1 C1 2.132(14) . ?
Sb1 C3 2.135(12) . ?
Sb1 C2 2.146(15) . ?
Sb2 C11 2.126(14) . ?
Sb2 C10 2.141(15) . ?
Sb2 C12 2.158(15) . ?
Sb3 C13 2.133(15) . ?
Sb3 C14 2.141(14) . ?
Sb3 C15 2.172(14) . ?
Sb4 C23 2.104(15) . ?
Sb4 C22 2.142(13) . ?
Sb4 C24 2.152(13) . ?
Sb5 C27 2.144(13) . ?
Sb5 C25 2.161(14) . ?
Sb5 C26 2.168(15) . ?
Sb6 C35 2.121(15) . ?
Sb6 C36 2.136(15) . ?
Sb6 C34 2.155(14) . ?
Sb7 C37 2.134(14) . ?
Sb7 C38 2.138(15) . ?
Sb7 C39 2.174(14) . ?
Sb8 C48 2.112(16) . ?
Sb8 C47 2.121(17) . ?
Sb8 C46 2.147(14) . ?
Cl1 O1 1.363(15) . ?
Cl1 O3 1.418(15) . ?
Cl1 O4 1.427(11) . ?
Cl1 O2 1.436(12) . ?
Cl2 O8 1.400(13) . ?
Cl2 O6 1.416(13) . ?
Cl2 O7 1.417(12) . ?
Cl2 O5 1.439(12) . ?
C1 H1A 0.9800 . ?
C1 H1B 0.9800 . ?
C1 H1C 0.9800 . ?
C2 H2A 0.9800 . ?
C2 H2B 0.9800 . ?
C2 H2C 0.9800 . ?
C3 C4 1.520(19) . ?
C3 H3A 0.9900 . ?
C3 H3B 0.9900 . ?
C4 C5 1.37(2) . ?
C4 C9 1.41(2) . ?
C5 C6 1.39(2) . ?
C5 H5 0.9500 . ?
C6 C7 1.41(2) . ?
C6 H6 0.9500 . ?
C7 C8 1.38(2) . ?
C7 H7 0.9500 . ?
C8 C9 1.41(2) . ?
C8 H8 0.9500 . ?
C9 C10 1.53(2) . ?
C10 H10A 0.9900 . ?
C10 H10B 0.9900 . ?
C11 H11A 0.9800 . ?
C11 H11B 0.9800 . ?
C11 H11C 0.9800 . ?
C12 H12A 0.9800 . ?
C12 H12B 0.9800 . ?
C12 H12C 0.9800 . ?
C13 H13A 0.9800 . ?
C13 H13B 0.9800 . ?
C13 H13C 0.9800 . ?
C14 H14A 0.9800 . ?
C14 H14B 0.9800 . ?
C14 H14C 0.9800 . ?
C15 C16 1.493(19) . ?
C15 H15A 0.9900 . ?
C15 H15B 0.9900 . ?
C16 C21 1.35(2) . ?
C16 C17 1.40(2) . ?
C17 C18 1.37(2) . ?
C17 H17 0.9500 . ?
C18 C19 1.36(2) . ?
C18 H18 0.9500 . ?
C19 C20 1.40(2) . ?
C19 H19 0.9500 . ?
C20 C21 1.41(2) . ?
C20 H20 0.9500 . ?
C21 C22 1.524(19) . ?
C22 H22A 0.9900 . ?
C22 H22B 0.9900 . ?
C23 H23A 0.9800 . ?
C23 H23B 0.9800 . ?
C23 H23C 0.9800 . ?
C24 H24A 0.9800 . ?
C24 H24B 0.9800 . ?
C24 H24C 0.9800 . ?
C25 H25A 0.9800 . ?
C25 H25B 0.9800 . ?
C25 H25C 0.9800 . ?
C26 H26A 0.9800 . ?
C26 H26B 0.9800 . ?
C26 H26C 0.9800 . ?
C27 C28 1.50(2) . ?
C27 H27A 0.9900 . ?
C27 H27B 0.9900 . ?
C28 C33 1.39(2) . ?
C28 C29 1.40(2) . ?
C29 C30 1.37(2) . ?
C29 H29 0.9500 . ?
C30 C31 1.42(2) . ?
C30 H30 0.9500 . ?
C31 C32 1.39(2) . ?
C31 H31 0.9500 . ?
C32 C33 1.37(2) . ?
C32 H32 0.9500 . ?
C33 C34 1.55(2) . ?
C34 H34A 0.9900 . ?
C34 H34B 0.9900 . ?
C35 H35A 0.9800 . ?
C35 H35B 0.9800 . ?
C35 H35C 0.9800 . ?
C36 H36A 0.9800 . ?
C36 H36B 0.9800 . ?
C36 H36C 0.9800 . ?
C37 H37A 0.9800 . ?
C37 H37B 0.9800 . ?
C37 H37C 0.9800 . ?
C38 H38A 0.9800 . ?
C38 H38B 0.9800 . ?
C38 H38C 0.9800 . ?
C39 C40 1.47(2) . ?
C39 H39A 0.9900 . ?
C39 H39B 0.9900 . ?
C40 C41 1.39(2) . ?
C40 C45 1.42(2) . ?
C41 C42 1.38(2) . ?
C41 H41 0.9500 . ?
C42 C43 1.37(2) . ?
C42 H42 0.9500 . ?
C43 C44 1.41(2) . ?
C43 H43 0.9500 . ?
C44 C45 1.39(2) . ?
C44 H44 0.9500 . ?
C45 C46 1.50(2) . ?
C46 H46A 0.9900 . ?
C46 H46B 0.9900 . ?
C47 H47A 0.9800 . ?
C47 H47B 0.9800 . ?
C47 H47C 0.9800 . ?
C48 H48A 0.9800 . ?
C48 H48B 0.9800 . ?
C48 H48C 0.9800 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Sb2 Ni1 Sb1 C1 146.8(5) . . . . ?
Sb4 Ni1 Sb1 C1 -41.5(5) . . . . ?
Sb3 Ni1 Sb1 C1 51.0(5) . . . . ?
I1 Ni1 Sb1 C1 -128.4(5) . . . . ?
Sb2 Ni1 Sb1 C3 32.7(4) . . . . ?
Sb4 Ni1 Sb1 C3 -155.6(4) . . . . ?
Sb3 Ni1 Sb1 C3 -63.2(4) . . . . ?
I1 Ni1 Sb1 C3 117.5(4) . . . . ?
Sb2 Ni1 Sb1 C2 -86.2(5) . . . . ?
Sb4 Ni1 Sb1 C2 85.5(5) . . . . ?
Sb3 Ni1 Sb1 C2 178.0(5) . . . . ?
I1 Ni1 Sb1 C2 -1.4(6) . . . . ?
Sb1 Ni1 Sb2 C11 176.7(6) . . . . ?
Sb3 Ni1 Sb2 C11 -58.9(6) . . . . ?
I1 Ni1 Sb2 C11 58.6(6) . . . . ?
Sb1 Ni1 Sb2 C10 -59.4(6) . . . . ?
Sb3 Ni1 Sb2 C10 64.9(6) . . . . ?
I1 Ni1 Sb2 C10 -177.6(6) . . . . ?
Sb1 Ni1 Sb2 C12 57.1(5) . . . . ?
Sb3 Ni1 Sb2 C12 -178.6(5) . . . . ?
I1 Ni1 Sb2 C12 -61.1(5) . . . . ?
Sb2 Ni1 Sb3 C13 -114.3(5) . . . . ?
Sb4 Ni1 Sb3 C13 72.5(5) . . . . ?
Sb1 Ni1 Sb3 C13 -21.5(5) . . . . ?
I1 Ni1 Sb3 C13 157.8(5) . . . . ?
Sb2 Ni1 Sb3 C14 10.2(5) . . . . ?
Sb4 Ni1 Sb3 C14 -163.1(5) . . . . ?
Sb1 Ni1 Sb3 C14 102.9(5) . . . . ?
I1 Ni1 Sb3 C14 -77.8(5) . . . . ?
Sb2 Ni1 Sb3 C15 128.0(4) . . . . ?
Sb4 Ni1 Sb3 C15 -45.2(4) . . . . ?
Sb1 Ni1 Sb3 C15 -139.2(4) . . . . ?
I1 Ni1 Sb3 C15 40.1(4) . . . . ?
Sb1 Ni1 Sb4 C23 -60.2(5) . . . . ?
Sb3 Ni1 Sb4 C23 175.5(5) . . . . ?
I1 Ni1 Sb4 C23 57.7(5) . . . . ?
Sb1 Ni1 Sb4 C22 178.5(4) . . . . ?
Sb3 Ni1 Sb4 C22 54.1(4) . . . . ?
I1 Ni1 Sb4 C22 -63.7(4) . . . . ?
Sb1 Ni1 Sb4 C24 59.1(5) . . . . ?
Sb3 Ni1 Sb4 C24 -65.2(5) . . . . ?
I1 Ni1 Sb4 C24 176.9(5) . . . . ?
Sb8 Ni2 Sb5 C27 -128.4(5) . . . . ?
Sb6 Ni2 Sb5 C27 44.7(5) . . . . ?
Sb7 Ni2 Sb5 C27 139.8(5) . . . . ?
I2 Ni2 Sb5 C27 -40.9(5) . . . . ?
Sb8 Ni2 Sb5 C25 114.5(5) . . . . ?
Sb6 Ni2 Sb5 C25 -72.4(5) . . . . ?
Sb7 Ni2 Sb5 C25 22.7(5) . . . . ?
I2 Ni2 Sb5 C25 -158.0(5) . . . . ?
Sb8 Ni2 Sb5 C26 -8.0(5) . . . . ?
Sb6 Ni2 Sb5 C26 165.1(5) . . . . ?
Sb7 Ni2 Sb5 C26 -99.8(5) . . . . ?
I2 Ni2 Sb5 C26 79.4(5) . . . . ?
Sb7 Ni2 Sb6 C35 59.3(5) . . . . ?
Sb5 Ni2 Sb6 C35 -176.3(5) . . . . ?
I2 Ni2 Sb6 C35 -57.2(5) . . . . ?
Sb7 Ni2 Sb6 C36 -59.7(5) . . . . ?
Sb5 Ni2 Sb6 C36 64.7(5) . . . . ?
I2 Ni2 Sb6 C36 -176.2(5) . . . . ?
Sb7 Ni2 Sb6 C34 -179.1(4) . . . . ?
Sb5 Ni2 Sb6 C34 -54.7(4) . . . . ?
I2 Ni2 Sb6 C34 64.4(4) . . . . ?
Sb8 Ni2 Sb7 C37 -145.7(4) . . . . ?
Sb6 Ni2 Sb7 C37 41.5(4) . . . . ?
Sb5 Ni2 Sb7 C37 -51.3(4) . . . . ?
I2 Ni2 Sb7 C37 129.4(4) . . . . ?
Sb8 Ni2 Sb7 C38 89.6(5) . . . . ?
Sb6 Ni2 Sb7 C38 -83.3(5) . . . . ?
Sb5 Ni2 Sb7 C38 -176.1(5) . . . . ?
I2 Ni2 Sb7 C38 4.6(5) . . . . ?
Sb8 Ni2 Sb7 C39 -30.5(5) . . . . ?
Sb6 Ni2 Sb7 C39 156.6(5) . . . . ?
Sb5 Ni2 Sb7 C39 63.8(5) . . . . ?
I2 Ni2 Sb7 C39 -115.5(5) . . . . ?
Sb7 Ni2 Sb8 C48 -178.0(5) . . . . ?
Sb5 Ni2 Sb8 C48 57.7(5) . . . . ?
I2 Ni2 Sb8 C48 -61.2(5) . . . . ?
Sb7 Ni2 Sb8 C47 -58.6(5) . . . . ?
Sb5 Ni2 Sb8 C47 177.1(5) . . . . ?
I2 Ni2 Sb8 C47 58.2(5) . . . . ?
Sb7 Ni2 Sb8 C46 59.4(5) . . . . ?
Sb5 Ni2 Sb8 C46 -64.9(5) . . . . ?
I2 Ni2 Sb8 C46 176.3(5) . . . . ?
C1 Sb1 C3 C4 -77.1(10) . . . . ?
C2 Sb1 C3 C4 179.8(10) . . . . ?
Ni1 Sb1 C3 C4 50.8(10) . . . . ?
Sb1 C3 C4 C5 86.4(14) . . . . ?
Sb1 C3 C4 C9 -90.7(14) . . . . ?
C9 C4 C5 C6 -7(2) . . . . ?
C3 C4 C5 C6 176.2(13) . . . . ?
C4 C5 C6 C7 5(2) . . . . ?
C5 C6 C7 C8 -2(2) . . . . ?
C6 C7 C8 C9 1(2) . . . . ?
C7 C8 C9 C4 -2(2) . . . . ?
C7 C8 C9 C10 -175.2(14) . . . . ?
C5 C4 C9 C8 5(2) . . . . ?
C3 C4 C9 C8 -178.3(13) . . . . ?
C5 C4 C9 C10 177.7(14) . . . . ?
C3 C4 C9 C10 -5(2) . . . . ?
C8 C9 C10 Sb2 -118.1(14) . . . . ?
C4 C9 C10 Sb2 68.6(18) . . . . ?
C11 Sb2 C10 C9 131.9(12) . . . . ?
C12 Sb2 C10 C9 -124.8(12) . . . . ?
Ni1 Sb2 C10 C9 0.0(14) . . . . ?
C13 Sb3 C15 C16 -46.1(11) . . . . ?
C14 Sb3 C15 C16 -147.7(11) . . . . ?
Ni1 Sb3 C15 C16 79.9(10) . . . . ?
Sb3 C15 C16 C21 -85.1(15) . . . . ?
Sb3 C15 C16 C17 100.9(12) . . . . ?
C21 C16 C17 C18 2(2) . . . . ?
C15 C16 C17 C18 176.0(13) . . . . ?
C16 C17 C18 C19 -3(2) . . . . ?
C17 C18 C19 C20 4(2) . . . . ?
C18 C19 C20 C21 -3(2) . . . . ?
C17 C16 C21 C20 -1(2) . . . . ?
C15 C16 C21 C20 -175.0(13) . . . . ?
C17 C16 C21 C22 -176.2(12) . . . . ?
C15 C16 C21 C22 10(2) . . . . ?
C19 C20 C21 C16 2(2) . . . . ?
C19 C20 C21 C22 177.4(13) . . . . ?
C16 C21 C22 Sb4 78.0(16) . . . . ?
C20 C21 C22 Sb4 -97.6(12) . . . . ?
C23 Sb4 C22 C21 137.4(11) . . . . ?
C24 Sb4 C22 C21 33.6(11) . . . . ?
Ni1 Sb4 C22 C21 -97.3(10) . . . . ?
C25 Sb5 C27 C28 48.0(11) . . . . ?
C26 Sb5 C27 C28 149.5(11) . . . . ?
Ni2 Sb5 C27 C28 -77.0(11) . . . . ?
Sb5 C27 C28 C33 79.0(15) . . . . ?
Sb5 C27 C28 C29 -100.6(13) . . . . ?
C33 C28 C29 C30 5(2) . . . . ?
C27 C28 C29 C30 -175.4(12) . . . . ?
C28 C29 C30 C31 -3(2) . . . . ?
C29 C30 C31 C32 1(2) . . . . ?
C30 C31 C32 C33 -2(2) . . . . ?
C31 C32 C33 C28 5(2) . . . . ?
C31 C32 C33 C34 -177.1(13) . . . . ?
C29 C28 C33 C32 -6(2) . . . . ?
C27 C28 C33 C32 174.5(13) . . . . ?
C29 C28 C33 C34 175.9(12) . . . . ?
C27 C28 C33 C34 -4(2) . . . . ?
C32 C33 C34 Sb6 99.4(12) . . . . ?
C28 C33 C34 Sb6 -82.3(14) . . . . ?
C35 Sb6 C34 C33 -133.3(10) . . . . ?
C36 Sb6 C34 C33 -29.9(11) . . . . ?
Ni2 Sb6 C34 C33 100.8(10) . . . . ?
C37 Sb7 C39 C40 72.6(11) . . . . ?
C38 Sb7 C39 C40 174.6(10) . . . . ?
Ni2 Sb7 C39 C40 -55.5(11) . . . . ?
Sb7 C39 C40 C41 -89.2(14) . . . . ?
Sb7 C39 C40 C45 91.6(13) . . . . ?
C45 C40 C41 C42 2(2) . . . . ?
C39 C40 C41 C42 -176.9(14) . . . . ?
C40 C41 C42 C43 -3(2) . . . . ?
C41 C42 C43 C44 1(2) . . . . ?
C42 C43 C44 C45 3(2) . . . . ?
C43 C44 C45 C40 -4(2) . . . . ?
C43 C44 C45 C46 173.2(13) . . . . ?
C41 C40 C45 C44 1.1(19) . . . . ?
C39 C40 C45 C44 -179.7(13) . . . . ?
C41 C40 C45 C46 -175.5(13) . . . . ?
C39 C40 C45 C46 4(2) . . . . ?
C44 C45 C46 Sb8 117.0(12) . . . . ?
C40 C45 C46 Sb8 -66.4(17) . . . . ?
C48 Sb8 C46 C45 -134.1(12) . . . . ?
C47 Sb8 C46 C45 121.9(12) . . . . ?
Ni2 Sb8 C46 C45 -3.2(13) . . . . ?
