#------------------------------------------------------------------------------
#$Date: 2016-03-25 13:27:38 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179845 $
#$URL: svn://www.crystallography.net/cod/cif/7/01/41/7014167.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7014167
loop_
_publ_author_name
'Mokuolu, Q. Folashade'
'Duckmanton, Paul A.'
'Hitchcock, Peter B.'
'Wilson, Claire'
'Blake, Alexander J.'
'Shukla, Lena'
'Love, Jason B.'
_publ_section_title
;
 Early-late, mixed-metal compounds supported by amidophosphine ligands.
;
_journal_issue                   13
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              1960
_journal_page_last               1970
_journal_paper_doi               10.1039/b402409e
_journal_year                    2004
_chemical_compound_source        'synthesis as described'
_chemical_formula_moiety         '(C54 H68 Cl2 N2 P2 Pt1).2(C1 H2 Cl2)'
_chemical_formula_sum            'C56 H72 Cl6 N2 P2 Pt'
_chemical_formula_weight         1242.89
_chemical_name_common            (PtCl2(P(C6H5)2(C6H4NHCHtBu2))2).2(CH2Cl2)
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_conform_dict_location     ftp://ftp.iucr.org/cifdics/cif_core.dic
_audit_conform_dict_name         cif_core.dic
_audit_conform_dict_version      2.1
_audit_creation_date             2001-05-11T11:29:54-00:00
_audit_creation_method           'WinGX routine CIF_UPDATE'
_cell_angle_alpha                114.459(2)
_cell_angle_beta                 99.179(4)
_cell_angle_gamma                95.075(4)
_cell_formula_units_Z            2
_cell_length_a                   14.2195(6)
_cell_length_b                   14.8092(9)
_cell_length_c                   15.4020(11)
_cell_measurement_reflns_used    14284
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      25.028
_cell_measurement_theta_min      3.705
_cell_measurement_wavelength     0.71073
_cell_volume                     2871.1(3)
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.971
_diffrn_measured_fraction_theta_max 0.971
_diffrn_measurement_device       KappaCCD
_diffrn_measurement_method       CCD
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.086
_diffrn_reflns_av_unetI/netI     0.1251
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            19811
_diffrn_reflns_theta_full        25.04
_diffrn_reflns_theta_max         25.04
_diffrn_reflns_theta_min         3.71
_exptl_absorpt_coefficient_mu    2.815
_exptl_absorpt_correction_T_max  0.952
_exptl_absorpt_correction_T_min  0.863
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
[c.f. r.h. blessing, acta cryst. (1995), a51, 33-38]
;
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.438
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       needle
_exptl_crystal_F_000             1264
_exptl_crystal_size_max          0.1
_exptl_crystal_size_mid          0.02
_exptl_crystal_size_min          0.02
_refine_diff_density_max         1.502
_refine_diff_density_min         -1.367
_refine_diff_density_rms         0.16
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.011
_refine_ls_hydrogen_treatment    riding
_refine_ls_matrix_type           full
_refine_ls_number_parameters     604
_refine_ls_number_reflns         9870
_refine_ls_number_restraints     6
_refine_ls_restrained_S_all      1.013
_refine_ls_R_factor_all          0.0966
_refine_ls_R_factor_gt           0.0618
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0282P)²+11.2447P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1153
_refine_ls_wR_factor_ref         0.1295
_reflns_number_gt                7288
_reflns_number_total             9870
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b402409e.txt
_cod_data_source_block           may1501
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7014167
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt Pt 0.81155(2) 0.83393(2) 0.55650(3) 0.02221(11) Uani 1 1 d . A 1
Cl1 Cl 0.75500(14) 0.86080(16) 0.41711(16) 0.0308(5) Uani 1 1 d . A 1
Cl2 Cl 0.83174(16) 0.67414(15) 0.44912(17) 0.0362(5) Uani 1 1 d . A 1
P1 P 0.87619(14) 0.80574(16) 0.68453(17) 0.0251(5) Uani 1 1 d . A 1
P2 P 0.77963(14) 0.98990(16) 0.64393(17) 0.0231(5) Uani 1 1 d . A 1
N1 N 0.5309(5) 0.7950(5) 0.7420(6) 0.0358(19) Uani 1 1 d . A 1
H1 H 0.5232 0.8331 0.711 0.043 Uiso 1 1 calc R A 1
N2 N 0.4864(5) 1.1777(5) 0.7107(6) 0.0345(18) Uani 1 1 d . A 1
H2 H 0.4295 1.1825 0.6824 0.041 Uiso 1 1 calc R A 1
C1 C 0.9207(6) 0.6864(6) 0.6567(7) 0.034(2) Uani 1 1 d . A 1
C2 C 0.8529(7) 0.5995(7) 0.6256(8) 0.044(3) Uani 1 1 d . A 1
H2' H 0.7858 0.6029 0.6176 0.053 Uiso 1 1 calc R A 1
C3 C 0.8835(8) 0.5074(8) 0.6063(9) 0.059(3) Uani 1 1 d . A 1
H3 H 0.8373 0.448 0.5846 0.071 Uiso 1 1 calc R A 1
C4 C 0.9804(8) 0.5031(8) 0.6186(12) 0.091(5) Uani 1 1 d . A 1
H4 H 1.0019 0.4411 0.6079 0.109 Uiso 1 1 calc R A 1
C5 C 1.0461(8) 0.5888(8) 0.6466(11) 0.088(5) Uani 1 1 d . A 1
H5 H 1.1131 0.5852 0.6532 0.106 Uiso 1 1 calc R A 1
C6 C 1.0168(6) 0.6805(7) 0.6655(9) 0.058(3) Uani 1 1 d . A 1
H6 H 1.0633 0.7391 0.6845 0.07 Uiso 1 1 calc R A 1
C7 C 0.9842(5) 0.8997(6) 0.7562(6) 0.0255(19) Uani 1 1 d . A 1
C8 C 1.0137(6) 0.9406(6) 0.8568(7) 0.033(2) Uani 1 1 d . A 1
H8 H 0.9753 0.9214 0.8934 0.039 Uiso 1 1 calc R A 1
C9 C 1.0998(6) 1.0100(7) 0.9051(7) 0.038(2) Uani 1 1 d . A 1
H9 H 1.1201 1.0373 0.9741 0.045 Uiso 1 1 calc R A 1
C10 C 1.1548(6) 1.0382(7) 0.8517(8) 0.041(2) Uani 1 1 d . A 1
H10 H 1.2131 1.0856 0.8845 0.049 Uiso 1 1 calc R A 1
C11 C 1.1264(6) 0.9984(7) 0.7504(7) 0.037(2) Uani 1 1 d . A 1
H11 H 1.1643 1.0185 0.7139 0.044 Uiso 1 1 calc R A 1
C12 C 1.0416(5) 0.9289(6) 0.7042(7) 0.030(2) Uani 1 1 d . A 1
H12 H 1.0222 0.9005 0.635 0.035 Uiso 1 1 calc R A 1
C13 C 0.7924(5) 0.7987(6) 0.7604(6) 0.0262(19) Uani 1 1 d . A 1
C14 C 0.6962(5) 0.8017(5) 0.7290(6) 0.0226(18) Uani 1 1 d . A 1
H14 H 0.6783 0.8133 0.6729 0.027 Uiso 1 1 calc R A 1
C15 C 0.6244(6) 0.7881(6) 0.7776(6) 0.028(2) Uani 1 1 d . A 1
C16 C 0.6543(6) 0.7704(7) 0.8587(7) 0.036(2) Uani 1 1 d . A 1
H16 H 0.6081 0.7621 0.8942 0.043 Uiso 1 1 calc R A 1
C17 C 0.7488(6) 0.7645(7) 0.8886(7) 0.036(2) Uani 1 1 d . A 1
H17 H 0.7663 0.7502 0.9432 0.043 Uiso 1 1 calc R A 1
C18 C 0.8194(6) 0.7790(6) 0.8405(7) 0.031(2) Uani 1 1 d . A 1
H18 H 0.8848 0.7756 0.8621 0.037 Uiso 1 1 calc R A 1
C19 C 0.4438(6) 0.7430(7) 0.7524(7) 0.037(2) Uani 1 1 d . A 1
H19 H 0.4656 0.7244 0.8069 0.045 Uiso 1 1 calc R A 1
C20 C 0.4065(7) 0.6412(8) 0.6590(8) 0.054(3) Uani 1 1 d . A 1
C21 C 0.3643(14) 0.6494(11) 0.5659(12) 0.148(9) Uani 1 1 d . A 1
H21A H 0.4103 0.6953 0.5555 0.222 Uiso 1 1 calc R A 1
H21B H 0.3036 0.6756 0.5721 0.222 Uiso 1 1 calc R A 1
H21C H 0.3519 0.5828 0.5103 0.222 Uiso 1 1 calc R A 1
C22 C 0.4924(8) 0.5845(8) 0.6400(9) 0.060(3) Uani 1 1 d . A 1
H22A H 0.543 0.6245 0.6279 0.09 Uiso 1 1 calc R A 1
H22B H 0.4705 0.5193 0.5828 0.09 Uiso 1 1 calc R A 1
H22C H 0.5184 0.5738 0.6972 0.09 Uiso 1 1 calc R A 1
C23 C 0.3340(8) 0.5699(9) 0.6769(13) 0.101(6) Uani 1 1 d . A 1
H23A H 0.2756 0.5995 0.6889 0.152 Uiso 1 1 calc R A 1
H23B H 0.3636 0.5605 0.7338 0.152 Uiso 1 1 calc R A 1
H23C H 0.3167 0.5047 0.6192 0.152 Uiso 1 1 calc R A 1
C24 C 0.3757(6) 0.8216(9) 0.7902(8) 0.049(3) Uani 1 1 d . A 1
C25 C 0.3490(10) 0.8740(11) 0.7263(10) 0.091(5) Uani 1 1 d . A 1
H25A H 0.3136 0.8242 0.6614 0.137 Uiso 1 1 calc R A 1
H25B H 0.4079 0.9086 0.7204 0.137 Uiso 1 1 calc R A 1
H25C H 0.3082 0.9233 0.7558 0.137 Uiso 1 1 calc R A 1
C26 C 0.4296(8) 0.9046(8) 0.8887(10) 0.071(4) Uani 1 1 d . A 1
H26A H 0.4489 0.8751 0.9338 0.106 Uiso 1 1 calc R A 1
H26B H 0.3873 0.9533 0.9154 0.106 Uiso 1 1 calc R A 1
H26C H 0.4873 0.9388 0.8804 0.106 Uiso 1 1 calc R A 1
C27 C 0.2829(8) 0.7798(10) 0.8080(10) 0.076(4) Uani 1 1 d . A 1
H27A H 0.2448 0.7259 0.7465 0.115 Uiso 1 1 calc R A 1
H27B H 0.2452 0.8337 0.8331 0.115 Uiso 1 1 calc R A 1
H27C H 0.2988 0.7528 0.8558 0.115 Uiso 1 1 calc R A 1
C28 C 0.8320(6) 1.0778(6) 0.6026(6) 0.0251(19) Uani 1 1 d . A 1
C29 C 0.7805(6) 1.1450(6) 0.5798(7) 0.035(2) Uani 1 1 d . A 1
H29 H 0.7146 1.1446 0.5845 0.042 Uiso 1 1 calc R A 1
C30 C 0.8241(6) 1.2106(7) 0.5510(7) 0.040(2) Uani 1 1 d . A 1
H30 H 0.7876 1.2543 0.5346 0.049 Uiso 1 1 calc R A 1
C31 C 0.9206(7) 1.2148(7) 0.5452(7) 0.041(2) Uani 1 1 d . A 1
H31 H 0.9503 1.2609 0.5253 0.049 Uiso 1 1 calc R A 1
C32 C 0.9732(6) 1.1504(7) 0.5690(7) 0.036(2) Uani 1 1 d . A 1
H32 H 1.04 1.154 0.5677 0.043 Uiso 1 1 calc R A 1
C33 C 0.9286(6) 1.0812(7) 0.5946(7) 0.036(2) Uani 1 1 d . A 1
H33 H 0.9644 1.035 0.6069 0.043 Uiso 1 1 calc R A 1
C34 C 0.8199(6) 1.0577(6) 0.7772(6) 0.0273(19) Uani 1 1 d . A 1
C35 C 0.9068(6) 1.1257(6) 0.8211(7) 0.033(2) Uani 1 1 d . A 1
H35 H 0.948 1.1362 0.7821 0.039 Uiso 1 1 calc R A 1
C36 C 0.9327(7) 1.1778(7) 0.9219(7) 0.042(2) Uani 1 1 d . A 1
H36 H 0.9922 1.2236 0.9513 0.051 Uiso 1 1 calc R A 1
C37 C 0.8746(7) 1.1649(8) 0.9804(8) 0.046(3) Uani 1 1 d . A 1
H37 H 0.8932 1.2019 1.0494 0.055 Uiso 1 1 calc R A 1
C38 C 0.7892(7) 1.0977(7) 0.9379(7) 0.043(2) Uani 1 1 d . A 1
H38 H 0.7488 1.0877 0.9778 0.051 Uiso 1 1 calc R A 1
C39 C 0.7619(6) 1.0445(7) 0.8377(7) 0.036(2) Uani 1 1 d . A 1
H39 H 0.7027 0.9982 0.8093 0.043 Uiso 1 1 calc R A 1
C40 C 0.6500(5) 0.9916(6) 0.6272(6) 0.0235(19) Uani 1 1 d . A 1
C41 C 0.6191(5) 1.0822(6) 0.6802(6) 0.027(2) Uani 1 1 d . A 1
H41 H 0.6652 1.1395 0.7254 0.032 Uiso 1 1 calc R A 1
C42 C 0.5197(6) 1.0885(6) 0.6666(6) 0.0258(19) Uani 1 1 d . A 1
C43 C 0.4533(5) 1.0007(6) 0.6033(6) 0.0256(19) Uani 1 1 d . A 1
H43 H 0.3859 1.0022 0.5944 0.031 Uiso 1 1 calc R A 1
C44 C 0.4861(6) 0.9122(6) 0.5539(6) 0.028(2) Uani 1 1 d . A 1
H44 H 0.44 0.8537 0.5112 0.034 Uiso 1 1 calc R A 1
C45 C 0.5834(5) 0.9054(6) 0.5640(6) 0.0237(19) Uani 1 1 d . A 1
H45 H 0.604 0.8437 0.5289 0.028 Uiso 1 1 calc R A 1
C46 C 0.5371(6) 1.2649(6) 0.8003(7) 0.032(2) Uani 1 1 d . A 1
H46 H 0.605 1.2527 0.8127 0.038 Uiso 1 1 calc R A 1
C47 C 0.5443(7) 1.3592(7) 0.7764(8) 0.044(3) Uani 1 1 d . A 1
C48 C 0.5958(9) 1.4574(8) 0.8635(9) 0.075(4) Uani 1 1 d . A 1
H48A H 0.6592 1.448 0.891 0.112 Uiso 1 1 calc R A 1
H48B H 0.557 1.4765 0.9135 0.112 Uiso 1 1 calc R A 1
H48C H 0.6044 1.5107 0.842 0.112 Uiso 1 1 calc R A 1
C49 C 0.4457(9) 1.3757(9) 0.7336(11) 0.084(5) Uani 1 1 d . A 1
H49A H 0.412 1.3131 0.6775 0.126 Uiso 1 1 calc R A 1
H49B H 0.4553 1.4292 0.7125 0.126 Uiso 1 1 calc R A 1
H49C H 0.4068 1.3951 0.7835 0.126 Uiso 1 1 calc R A 1
C50 C 0.6052(9) 1.3368(9) 0.6976(9) 0.072(4) Uani 1 1 d . A 1
H50A H 0.6688 1.3258 0.7225 0.108 Uiso 1 1 calc R A 1
H50B H 0.6131 1.3941 0.6815 0.108 Uiso 1 1 calc R A 1
H50C H 0.5722 1.2763 0.6388 0.108 Uiso 1 1 calc R A 1
C51 C 0.4949(7) 1.2665(8) 0.8894(7) 0.045(3) Uani 1 1 d . A 1
C52 C 0.5651(9) 1.3358(10) 0.9864(9) 0.073(4) Uani 1 1 d . A 1
H52A H 0.6287 1.3153 0.9859 0.109 Uiso 1 1 calc R A 1
H52B H 0.5405 1.3308 1.0405 0.109 Uiso 1 1 calc R A 1
H52C H 0.5707 1.4055 0.9948 0.109 Uiso 1 1 calc R A 1
C53 C 0.3957(8) 1.2966(10) 0.8901(9) 0.078(4) Uani 1 1 d . A 1
H53A H 0.3997 1.365 0.8951 0.117 Uiso 1 1 calc R A 1
H53B H 0.373 1.2945 0.9462 0.117 Uiso 1 1 calc R A 1
H53C H 0.3503 1.2497 0.8296 0.117 Uiso 1 1 calc R A 1
C54 C 0.4859(11) 1.1610(9) 0.8826(10) 0.082(4) Uani 1 1 d . A 1
H54A H 0.5494 1.14 0.8828 0.124 Uiso 1 1 calc R A 1
H54B H 0.4404 1.1145 0.822 0.124 Uiso 1 1 calc R A 1
H54C H 0.4622 1.1601 0.9386 0.124 Uiso 1 1 calc R A 1
C55 C 0.8491(10) 0.6461(8) 0.2182(10) 0.080(4) Uani 1 1 d D B 2
H55A H 0.8095 0.679 0.266 0.096 Uiso 1 1 calc R B 2
H55B H 0.9135 0.6482 0.2553 0.096 Uiso 1 1 calc R B 2
Cl3 Cl 0.7949(3) 0.5215(3) 0.1468(4) 0.1180(15) Uani 1 1 d D B 2
Cl4 Cl 0.8626(3) 0.7134(3) 0.1509(3) 0.1024(13) Uani 1 1 d D B 2
C56 C 0.907(3) 0.4915(11) 0.929(2) 0.59(6) Uani 1 1 d D C 2
H56A H 0.8532 0.5069 0.9628 0.71 Uiso 1 1 calc R C 2
H56B H 0.9663 0.5001 0.977 0.71 Uiso 1 1 calc R C 2
Cl5 Cl 0.8812(4) 0.3717(4) 0.8398(6) 0.204(3) Uani 1 1 d D C 2
Cl6 Cl 0.9242(11) 0.5690(6) 0.8772(6) 0.333(7) Uani 1 1 d D C 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0 0 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P1 Pt P2 97.16(8) . . ?
P1 Pt Cl2 90.09(8) . . ?
P2 Pt Cl2 172.57(8) . . ?
P1 Pt Cl1 175.41(7) . . ?
P2 Pt Cl1 85.51(8) . . ?
Cl2 Pt Cl1 87.36(8) . . ?
C13 P1 C7 111.7(4) . . ?
C13 P1 C1 100.6(4) . . ?
C7 P1 C1 103.0(4) . . ?
C13 P1 Pt 114.6(3) . . ?
C7 P1 Pt 109.3(3) . . ?
C1 P1 Pt 117.0(3) . . ?
C28 P2 C40 107.1(4) . . ?
C28 P2 C34 102.7(4) . . ?
C40 P2 C34 101.8(4) . . ?
C28 P2 Pt 109.6(3) . . ?
C40 P2 Pt 111.8(3) . . ?
C34 P2 Pt 122.7(3) . . ?
C15 N1 C19 124.3(7) . . ?
C42 N2 C46 125.9(7) . . ?
C6 C1 C2 119.7(8) . . ?
C6 C1 P1 122.5(7) . . ?
C2 C1 P1 117.9(6) . . ?
C1 C2 C3 119.9(9) . . ?
C4 C3 C2 119.8(10) . . ?
C5 C4 C3 119.5(10) . . ?
C4 C5 C6 121.2(10) . . ?
C1 C6 C5 119.8(9) . . ?
C8 C7 C12 118.6(8) . . ?
C8 C7 P1 124.9(6) . . ?
C12 C7 P1 116.5(7) . . ?
C7 C8 C9 120.7(8) . . ?
C10 C9 C8 119.4(9) . . ?
C9 C10 C11 121.0(9) . . ?
C12 C11 C10 118.5(8) . . ?
C11 C12 C7 121.8(9) . . ?
C14 C13 C18 119.7(7) . . ?
C14 C13 P1 117.7(6) . . ?
C18 C13 P1 122.1(6) . . ?
C13 C14 C15 122.1(8) . . ?
N1 C15 C16 125.7(7) . . ?
N1 C15 C14 117.7(8) . . ?
C16 C15 C14 116.6(7) . . ?
C17 C16 C15 121.7(8) . . ?
C16 C17 C18 121.2(8) . . ?
C13 C18 C17 118.6(7) . . ?
N1 C19 C20 109.3(8) . . ?
N1 C19 C24 107.9(7) . . ?
C20 C19 C24 121.2(8) . . ?
C21 C20 C22 107.5(12) . . ?
C21 C20 C23 109.8(11) . . ?
C22 C20 C23 103.4(8) . . ?
C21 C20 C19 116.0(9) . . ?
C22 C20 C19 107.8(7) . . ?
C23 C20 C19 111.5(10) . . ?
C25 C24 C27 108.0(9) . . ?
C25 C24 C26 105.5(11) . . ?
C27 C24 C26 105.9(9) . . ?
C25 C24 C19 114.4(8) . . ?
C27 C24 C19 114.4(9) . . ?
C26 C24 C19 107.9(8) . . ?
C33 C28 C29 117.5(7) . . ?
C33 C28 P2 119.2(6) . . ?
C29 C28 P2 123.3(6) . . ?
C30 C29 C28 120.8(8) . . ?
C29 C30 C31 121.2(9) . . ?
C30 C31 C32 118.9(8) . . ?
C33 C32 C31 120.1(8) . . ?
C32 C33 C28 121.4(8) . . ?
C35 C34 C39 118.1(8) . . ?
C35 C34 P2 121.6(6) . . ?
C39 C34 P2 120.2(7) . . ?
C36 C35 C34 119.6(8) . . ?
C37 C36 C35 121.7(9) . . ?
C36 C37 C38 119.1(10) . . ?
C37 C38 C39 120.4(10) . . ?
C38 C39 C34 121.1(9) . . ?
C45 C40 C41 120.8(7) . . ?
C45 C40 P2 121.0(6) . . ?
C41 C40 P2 118.2(6) . . ?
C40 C41 C42 120.3(8) . . ?
N2 C42 C43 119.3(7) . . ?
N2 C42 C41 122.4(8) . . ?
C43 C42 C41 118.2(7) . . ?
C44 C43 C42 120.0(7) . . ?
C43 C44 C45 122.6(8) . . ?
C44 C45 C40 118.0(7) . . ?
N2 C46 C51 109.9(7) . . ?
N2 C46 C47 107.3(7) . . ?
C51 C46 C47 121.5(7) . . ?
C48 C47 C49 108.8(9) . . ?
C48 C47 C50 107.1(9) . . ?
C49 C47 C50 107.2(10) . . ?
C48 C47 C46 113.8(9) . . ?
C49 C47 C46 113.2(8) . . ?
C50 C47 C46 106.3(8) . . ?
C54 C51 C53 107.9(10) . . ?
C54 C51 C52 107.0(10) . . ?
C53 C51 C52 109.8(9) . . ?
C54 C51 C46 107.6(8) . . ?
C53 C51 C46 113.6(9) . . ?
C52 C51 C46 110.7(9) . . ?
Cl4 C55 Cl3 113.2(8) . . ?
Cl6 C56 Cl5 108.5(16) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt P1 2.254(2) . ?
Pt P2 2.271(2) . ?
Pt Cl2 2.334(2) . ?
Pt Cl1 2.372(2) . ?
P1 C13 1.822(8) . ?
P1 C7 1.823(8) . ?
P1 C1 1.834(8) . ?
P2 C28 1.822(8) . ?
P2 C40 1.824(7) . ?
P2 C34 1.835(9) . ?
N1 C15 1.384(10) . ?
N1 C19 1.467(10) . ?
N2 C42 1.379(10) . ?
N2 C46 1.461(11) . ?
C1 C6 1.365(12) . ?
C1 C2 1.392(12) . ?
C2 C3 1.395(13) . ?
C3 C4 1.372(14) . ?
C4 C5 1.371(15) . ?
C5 C6 1.383(13) . ?
C7 C8 1.383(12) . ?
C7 C12 1.390(11) . ?
C8 C9 1.401(12) . ?
C9 C10 1.376(13) . ?
C10 C11 1.393(13) . ?
C11 C12 1.386(12) . ?
C13 C14 1.386(11) . ?
C13 C18 1.387(12) . ?
C14 C15 1.406(10) . ?
C15 C16 1.389(12) . ?
C16 C17 1.372(12) . ?
C17 C18 1.391(11) . ?
C19 C20 1.563(14) . ?
C19 C24 1.565(13) . ?
C20 C21 1.521(17) . ?
C20 C22 1.541(14) . ?
C20 C23 1.546(15) . ?
C24 C25 1.510(14) . ?
C24 C27 1.520(13) . ?
C24 C26 1.523(16) . ?
C28 C33 1.398(11) . ?
C28 C29 1.409(11) . ?
C29 C30 1.366(12) . ?
C30 C31 1.387(12) . ?
C31 C32 1.390(12) . ?
C32 C33 1.380(12) . ?
C34 C35 1.396(12) . ?
C34 C39 1.398(12) . ?
C35 C36 1.384(12) . ?
C36 C37 1.373(13) . ?
C37 C38 1.374(13) . ?
C38 C39 1.379(13) . ?
C40 C45 1.392(11) . ?
C40 C41 1.404(10) . ?
C41 C42 1.411(11) . ?
C42 C43 1.404(11) . ?
C43 C44 1.382(11) . ?
C44 C45 1.385(10) . ?
C46 C51 1.577(12) . ?
C46 C47 1.583(13) . ?
C47 C48 1.528(14) . ?
C47 C49 1.536(14) . ?
C47 C50 1.545(14) . ?
C51 C54 1.515(14) . ?
C51 C53 1.517(14) . ?
C51 C52 1.535(15) . ?
C55 Cl4 1.727(11) . ?
C55 Cl3 1.734(10) . ?
C56 Cl6 1.664(18) . ?
C56 Cl5 1.693(17) . ?
