#------------------------------------------------------------------------------
#$Date: 2016-03-25 13:29:40 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179847 $
#$URL: svn://www.crystallography.net/cod/cif/7/01/43/7014345.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7014345
loop_
_publ_author_name
'Zhao, Xiao-Qing'
'Cui, Ping'
'Zhao, Bin'
'Shi, Wei'
'Cheng, Peng'
_publ_section_title
;
 Investigation on structures, luminescent and magnetic properties of
 Ln(III)-M (M = Fe(II)(HS), Co(II)) coordination polymers.
;
_journal_issue                   4
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              805
_journal_page_last               819
_journal_paper_doi               10.1039/c0dt00516a
_journal_volume                  40
_journal_year                    2011
_chemical_formula_moiety         'C21 H40 Co2 Eu N3 O31'
_chemical_formula_sum            'C21 H40 Co2 Eu N3 O31'
_chemical_formula_weight         1100.38
_chemical_name_systematic
;
?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 111.497(4)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   8.9767(4)
_cell_length_b                   23.9151(10)
_cell_length_c                   18.6746(9)
_cell_measurement_reflns_used    7914
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      29.0776
_cell_measurement_theta_min      2.4314
_cell_volume                     3730.2(3)
_computing_cell_refinement
;
CrysAlisPro, Oxford Diffraction Ltd.,
Version 1.171.33.48 (release 15-09-2009 CrysAlis171 .NET)
(compiled Sep 15 2009,11:49:04)
;
_computing_data_collection
;
CrysAlisPro, Oxford Diffraction Ltd.,
Version 1.171.33.48 (release 15-09-2009 CrysAlis171 .NET)
(compiled Sep 15 2009,11:49:04)
;
_computing_data_reduction
;
CrysAlisPro, Oxford Diffraction Ltd.,
Version 1.171.33.48 (release 15-09-2009 CrysAlis171 .NET)
(compiled Sep 15 2009,11:49:04)
;
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_detector_area_resol_mean 16.2116
_diffrn_measured_fraction_theta_full 0.992
_diffrn_measured_fraction_theta_max 0.992
_diffrn_measurement_device_type  'SuperNova, Single source at offset), Eos'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'Enhance (Mo) X-ray Source'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0532
_diffrn_reflns_av_sigmaI/netI    0.0741
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_k_min       -28
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            14276
_diffrn_reflns_theta_full        25.10
_diffrn_reflns_theta_max         25.10
_diffrn_reflns_theta_min         2.44
_exptl_absorpt_coefficient_mu    2.654
_exptl_absorpt_correction_T_max  0.9013
_exptl_absorpt_correction_T_min  0.7772
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro, Oxford Diffraction Ltd.,
Version 1.171.33.48 (release 15-09-2009 CrysAlis171 .NET)
(compiled Sep 15 2009,11:49:04)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.959
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             2208
_exptl_crystal_size_max          0.10
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.04
_refine_diff_density_max         3.984
_refine_diff_density_min         -1.766
_refine_diff_density_rms         0.256
_refine_ls_extinction_coef       0.0017(3)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.087
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     525
_refine_ls_number_reflns         6597
_refine_ls_number_restraints     18
_refine_ls_restrained_S_all      1.086
_refine_ls_R_factor_all          0.0988
_refine_ls_R_factor_gt           0.0772
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0950P)²+61.2353P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1881
_refine_ls_wR_factor_ref         0.1965
_reflns_number_gt                5126
_reflns_number_total             6597
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            C0DT00516A.TXT
_cod_data_source_block           18
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from
2010-06-29.

'_exptl_absorpt_correction_type' value 'MULTI-SCAN' changed
to 'multi-scan' according to
'/home/saulius/struct/CIF-dictionaries/cif_core.dic' dictionary named
'cif_core.dic' version 2.4.1 from
2010-06-29.

'_refine_ls_hydrogen_treatment' value 'CONSTR' changed to
'constr' according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1555 2011-01-17 13:19:09Z saulius 
;
_cod_original_sg_symbol_H-M      P21/c
_cod_database_code               7014345
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.44627(6) 0.80955(2) 0.40905(3) 0.0113(2) Uani 1 1 d . . .
Co1 Co 1.06306(17) 0.90215(6) 0.55650(9) 0.0169(4) Uani 1 1 d . . .
Co2 Co -0.00749(17) 0.66350(7) 0.46378(9) 0.0212(4) Uani 1 1 d . . .
C1 C 0.7559(12) 0.8475(4) 0.5633(6) 0.014(2) Uani 1 1 d U . .
C2 C 0.6822(13) 0.8043(5) 0.5989(6) 0.016(2) Uani 1 1 d . . .
C3 C 0.7451(13) 0.7882(5) 0.6771(7) 0.020(2) Uani 1 1 d . . .
H3 H 0.8359 0.8055 0.7116 0.024 Uiso 1 1 calc R . .
C4 C 0.6677(14) 0.7456(5) 0.7013(7) 0.022(3) Uani 1 1 d . . .
C5 C 0.5255(12) 0.7235(5) 0.6492(6) 0.019(2) Uani 1 1 d . . .
H5 H 0.4688 0.6968 0.6649 0.022 Uiso 1 1 calc R . .
C6 C 0.4691(12) 0.7422(5) 0.5725(6) 0.015(2) Uani 1 1 d . . .
C7 C 0.3220(12) 0.7213(5) 0.5117(6) 0.018(2) Uani 1 1 d . . .
C8 C 0.6382(13) 0.6961(5) 0.3878(7) 0.018(2) Uani 1 1 d . . .
C9 C 0.4827(13) 0.6931(5) 0.3164(6) 0.018(2) Uani 1 1 d . . .
C10 C 0.4521(13) 0.6505(5) 0.2648(7) 0.021(2) Uani 1 1 d . . .
H10 H 0.5254 0.6216 0.2718 0.025 Uiso 1 1 calc R . .
C11 C 0.3050(13) 0.6509(5) 0.1995(6) 0.020(2) Uani 1 1 d . . .
C12 C 0.2011(13) 0.6966(5) 0.1937(6) 0.018(2) Uani 1 1 d . . .
H12 H 0.1030 0.6991 0.1531 0.022 Uiso 1 1 calc R . .
C13 C 0.2488(13) 0.7375(5) 0.2497(6) 0.017(2) Uani 1 1 d . . .
C14 C 0.1427(13) 0.7875(5) 0.2488(6) 0.014(2) Uani 1 1 d U . .
C15 C 0.5749(12) 0.8941(5) 0.3002(6) 0.017(2) Uani 1 1 d . . .
C16 C 0.4984(12) 0.9355(5) 0.3375(6) 0.017(2) Uani 1 1 d . . .
C17 C 0.5154(12) 0.9925(5) 0.3331(6) 0.017(2) Uani 1 1 d . . .
H17 H 0.5694 1.0073 0.3034 0.020 Uiso 1 1 calc R . .
C18 C 0.4510(12) 1.0277(5) 0.3736(6) 0.016(2) Uani 1 1 d U . .
C19 C 0.3644(12) 1.0035(5) 0.4147(6) 0.015(2) Uani 1 1 d . . .
H19 H 0.3141 1.0255 0.4402 0.018 Uiso 1 1 calc R . .
C20 C 0.3562(12) 0.9465(5) 0.4161(6) 0.017(2) Uani 1 1 d . . .
C21 C 0.2765(13) 0.9149(5) 0.4633(6) 0.018(2) Uani 1 1 d . . .
N1 N 0.5480(10) 0.7820(4) 0.5480(5) 0.0151(19) Uani 1 1 d . . .
N2 N 0.3841(10) 0.7376(4) 0.3101(5) 0.016(2) Uani 1 1 d . . .
N3 N 0.4232(11) 0.9115(4) 0.3794(6) 0.021(2) Uani 1 1 d . . .
O1 O 0.6845(9) 0.8556(3) 0.4926(4) 0.0184(17) Uani 1 1 d . . .
O2 O 0.8873(9) 0.8693(3) 0.6033(4) 0.0192(17) Uani 1 1 d . . .
O3 O 0.7283(9) 0.7295(4) 0.7740(4) 0.0221(18) Uani 1 1 d . . .
H3A H 0.6553 0.7218 0.7888 0.033 Uiso 1 1 calc R . .
O4 O 0.2336(9) 0.6869(3) 0.5298(5) 0.0212(18) Uani 1 1 d . . .
O5 O 0.2909(9) 0.7413(3) 0.4439(4) 0.0216(18) Uani 1 1 d . . .
O6 O 0.6509(9) 0.7392(3) 0.4297(4) 0.0177(17) Uani 1 1 d . . .
O7 O 0.7394(9) 0.6578(3) 0.4002(5) 0.0236(18) Uani 1 1 d . . .
O8 O 0.2700(9) 0.6097(3) 0.1485(4) 0.0205(17) Uani 1 1 d . . .
O9 O 0.0196(9) 0.7967(3) 0.1896(5) 0.0243(19) Uani 1 1 d . . .
O10 O 0.1896(9) 0.8183(3) 0.3084(5) 0.0209(18) Uani 1 1 d . . .
O11 O 0.5666(8) 0.8429(3) 0.3183(4) 0.0185(17) Uani 1 1 d . . .
O12 O 0.6431(11) 0.9100(4) 0.2566(5) 0.029(2) Uani 1 1 d . . .
O13 O 0.4669(9) 1.0827(3) 0.3753(5) 0.0208(17) Uani 1 1 d . . .
H13 H 0.5459 1.0925 0.3628 0.031 Uiso 1 1 d R . .
O14 O 0.2011(9) 0.9426(3) 0.4969(4) 0.0174(17) Uani 1 1 d . . .
O15 O 0.2954(8) 0.8623(3) 0.4673(4) 0.0161(16) Uani 1 1 d . . .
O16 O 1.0358(9) 0.9814(3) 0.5935(5) 0.0228(18) Uani 1 1 d . . .
H16A H 1.0467 0.9864 0.6436 0.027 Uiso 1 1 d R . .
H16B H 1.1166 1.0017 0.5917 0.027 Uiso 1 1 d R . .
O17 O 0.8736(9) 0.9187(3) 0.4495(4) 0.0227(18) Uani 1 1 d . . .
H17A H 0.8084 0.8976 0.4625 0.027 Uiso 1 1 d R . .
H17B H 0.8666 0.9044 0.4040 0.027 Uiso 1 1 d R . .
O18 O 1.0692(11) 0.8247(3) 0.5109(5) 0.030(2) Uani 1 1 d . . .
H18A H 1.0430 0.7929 0.5260 0.036 Uiso 1 1 d R . .
H18B H 1.1638 0.8194 0.5095 0.036 Uiso 1 1 d R . .
O19 O -0.0602(9) 0.7259(3) 0.5340(4) 0.0208(18) Uani 1 1 d . . .
H19A H -0.0362 0.7184 0.5820 0.025 Uiso 1 1 d R . .
H19B H -0.1628 0.7302 0.5138 0.025 Uiso 1 1 d R . .
O20 O -0.0141(10) 0.7168(5) 0.3773(5) 0.039(2) Uani 1 1 d . . .
H20A H 0.0425 0.7479 0.3979 0.047 Uiso 1 1 d R . .
H20B H -0.0039 0.7170 0.3317 0.047 Uiso 1 1 d R . .
O21 O 0.0437(12) 0.6007(4) 0.4016(5) 0.041(2) Uani 1 1 d . . .
H21A H 0.1115 0.5732 0.4036 0.049 Uiso 1 1 d R . .
H21B H 0.0338 0.6166 0.3557 0.049 Uiso 1 1 d R . .
O22 O -0.0033(10) 0.6034(4) 0.5395(5) 0.032(2) Uani 1 1 d . . .
H22A H -0.0541 0.6053 0.5716 0.039 Uiso 1 1 d R . .
H22B H 0.0310 0.5691 0.5449 0.039 Uiso 1 1 d R . .
O23 O 0.9696(10) 0.8903(4) 0.3314(5) 0.032(2) Uani 1 1 d . . .
H23A H 0.9181 0.8756 0.2851 0.038 Uiso 1 1 d R . .
H23B H 1.0711 0.8821 0.3445 0.038 Uiso 1 1 d R . .
O24 O 0.3277(12) 0.5177(5) 0.3154(6) 0.046(3) Uani 1 1 d . . .
H24A H 0.3187 0.4836 0.2975 0.055 Uiso 1 1 d R . .
H24B H 0.2581 0.5411 0.2897 0.055 Uiso 1 1 d R . .
O25 O 1.0226(14) 0.5764(4) 0.2536(5) 0.049(3) Uani 1 1 d . . .
H25A H 0.9718 0.6007 0.2172 0.059 Uiso 1 1 d R . .
H25B H 0.9545 0.5524 0.2612 0.059 Uiso 1 1 d R . .
O26 O 0.2893(12) 0.5243(5) 0.4603(6) 0.053(3) Uani 1 1 d . . .
H26A H 0.3378 0.5542 0.4838 0.064 Uiso 1 1 d R . .
H26B H 0.3139 0.5132 0.4217 0.064 Uiso 1 1 d R . .
O27 O 0.0667(12) 0.9665(5) 0.2362(6) 0.047(3) Uani 1 1 d . . .
H27A H 0.0927 0.9575 0.2848 0.057 Uiso 1 1 d R . .
H27B H -0.0341 0.9799 0.2206 0.057 Uiso 1 1 d R . .
O28 O 0.8390(12) 0.6065(4) 0.6378(6) 0.046(3) Uani 1 1 d . . .
H28B H 0.7376 0.6038 0.6160 0.055 Uiso 1 1 d R . .
H28A H 0.8695 0.6303 0.6763 0.055 Uiso 1 1 d R . .
O29 O 0.6436(13) 0.5439(5) 0.4098(6) 0.059(3) Uani 1 1 d . . .
H29A H 0.6919 0.5641 0.3860 0.070 Uiso 1 1 d R . .
H29B H 0.5469 0.5356 0.3833 0.070 Uiso 1 1 d R . .
O30 O 0.2599(13) 0.5535(5) 0.6427(6) 0.054(3) Uani 1 1 d . . .
H30B H 0.2392 0.5637 0.6828 0.065 Uiso 1 1 d R . .
H30A H 0.2475 0.5171 0.6340 0.065 Uiso 1 1 d R . .
O31 O 0.5139(14) 0.9092(5) 0.0798(7) 0.059(3) Uani 1 1 d . . .
H31A H 0.5154 0.8740 0.0653 0.071 Uiso 1 1 d R . .
H31B H 0.4280 0.9143 0.0916 0.071 Uiso 1 1 d R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O15 Eu1 O5 75.6(3) . . ?
O15 Eu1 O10 76.6(3) . . ?
O5 Eu1 O10 77.4(3) . . ?
O15 Eu1 O1 88.9(3) . . ?
O5 Eu1 O1 127.3(3) . . ?
O10 Eu1 O1 147.4(3) . . ?
O15 Eu1 O6 145.2(3) . . ?
O5 Eu1 O6 88.1(3) . . ?
O10 Eu1 O6 130.1(2) . . ?
O1 Eu1 O6 76.8(3) . . ?
O15 Eu1 N2 135.2(3) . . ?
O5 Eu1 N2 74.3(3) . . ?
O10 Eu1 N2 65.0(3) . . ?
O1 Eu1 N2 135.9(3) . . ?
O6 Eu1 N2 65.1(3) . . ?
O15 Eu1 O11 127.6(3) . . ?
O5 Eu1 O11 149.3(3) . . ?
O10 Eu1 O11 88.3(3) . . ?
O1 Eu1 O11 77.7(3) . . ?
O6 Eu1 O11 80.5(3) . . ?
N2 Eu1 O11 75.0(3) . . ?
O15 Eu1 N3 64.5(3) . . ?
O5 Eu1 N3 136.1(3) . . ?
O10 Eu1 N3 76.3(3) . . ?
O1 Eu1 N3 71.2(3) . . ?
O6 Eu1 N3 135.5(3) . . ?
N2 Eu1 N3 123.0(3) . . ?
O11 Eu1 N3 63.3(3) . . ?
O15 Eu1 N1 73.7(3) . . ?
O5 Eu1 N1 64.2(3) . . ?
O10 Eu1 N1 135.9(3) . . ?
O1 Eu1 N1 63.1(3) . . ?
O6 Eu1 N1 71.6(3) . . ?
N2 Eu1 N1 119.7(3) . . ?
O11 Eu1 N1 135.7(3) . . ?
N3 Eu1 N1 117.2(3) . . ?
O8 Co1 O18 94.0(4) 4_676 . ?
O8 Co1 O16 91.6(3) 4_676 . ?
O18 Co1 O16 174.4(4) . . ?
O8 Co1 O17 169.8(3) 4_676 . ?
O18 Co1 O17 85.0(3) . . ?
O16 Co1 O17 89.5(3) . . ?
O8 Co1 O14 88.8(3) 4_676 1_655 ?
O18 Co1 O14 94.7(3) . 1_655 ?
O16 Co1 O14 85.5(3) . 1_655 ?
O17 Co1 O14 81.2(3) . 1_655 ?
O8 Co1 O2 100.3(3) 4_676 . ?
O18 Co1 O2 88.5(3) . . ?
O16 Co1 O2 90.3(3) . . ?
O17 Co1 O2 89.8(3) . . ?
O14 Co1 O2 170.1(3) 1_655 . ?
O22 Co2 O20 172.9(4) . . ?
O22 Co2 O21 85.6(4) . . ?
O20 Co2 O21 87.5(4) . . ?
O22 Co2 O4 91.6(3) . . ?
O20 Co2 O4 91.3(3) . . ?
O21 Co2 O4 97.4(4) . . ?
O22 Co2 O7 95.0(3) . 1_455 ?
O20 Co2 O7 83.3(3) . 1_455 ?
O21 Co2 O7 92.9(4) . 1_455 ?
O4 Co2 O7 168.1(3) . 1_455 ?
O22 Co2 O19 91.1(3) . . ?
O20 Co2 O19 95.7(4) . . ?
O21 Co2 O19 176.8(4) . . ?
O4 Co2 O19 82.5(3) . . ?
O7 Co2 O19 87.5(3) 1_455 . ?
O1 C1 O2 124.7(10) . . ?
O1 C1 C2 115.7(9) . . ?
O2 C1 C2 119.4(9) . . ?
N1 C2 C3 122.7(10) . . ?
N1 C2 C1 112.6(9) . . ?
C3 C2 C1 124.7(10) . . ?
C4 C3 C2 118.4(10) . . ?
C4 C3 H3 120.8 . . ?
C2 C3 H3 120.8 . . ?
O3 C4 C5 122.2(10) . . ?
O3 C4 C3 118.6(10) . . ?
C5 C4 C3 119.1(10) . . ?
C4 C5 C6 119.1(10) . . ?
C4 C5 H5 120.4 . . ?
C6 C5 H5 120.4 . . ?
N1 C6 C5 121.8(9) . . ?
N1 C6 C7 114.0(9) . . ?
C5 C6 C7 124.2(10) . . ?
O4 C7 O5 124.8(10) . . ?
O4 C7 C6 118.9(10) . . ?
O5 C7 C6 116.2(10) . . ?
O7 C8 O6 125.7(10) . . ?
O7 C8 C9 119.6(10) . . ?
O6 C8 C9 114.7(9) . . ?
C10 C9 N2 124.7(11) . . ?
C10 C9 C8 122.1(10) . . ?
N2 C9 C8 113.1(9) . . ?
C9 C10 C11 118.8(11) . . ?
C9 C10 H10 120.6 . . ?
C11 C10 H10 120.6 . . ?
O8 C11 C12 123.0(10) . . ?
O8 C11 C10 120.5(10) . . ?
C12 C11 C10 116.5(10) . . ?
C13 C12 C11 118.5(10) . . ?
C13 C12 H12 120.8 . . ?
C11 C12 H12 120.8 . . ?
N2 C13 C12 125.6(10) . . ?
N2 C13 C14 112.5(9) . . ?
C12 C13 C14 121.9(10) . . ?
O9 C14 O10 124.6(10) . . ?
O9 C14 C13 119.3(9) . . ?
O10 C14 C13 116.1(9) . . ?
O12 C15 O11 123.9(11) . . ?
O12 C15 C16 121.1(10) . . ?
O11 C15 C16 115.1(10) . . ?
N3 C16 C17 123.4(10) . . ?
N3 C16 C15 113.6(10) . . ?
C17 C16 C15 122.8(10) . . ?
C16 C17 C18 119.3(10) . . ?
C16 C17 H17 120.3 . . ?
C18 C17 H17 120.3 . . ?
O13 C18 C17 123.5(10) . . ?
O13 C18 C19 118.4(10) . . ?
C17 C18 C19 118.1(10) . . ?
C20 C19 C18 117.9(10) . . ?
C20 C19 H19 121.0 . . ?
C18 C19 H19 121.0 . . ?
N3 C20 C19 124.7(10) . . ?
N3 C20 C21 112.1(10) . . ?
C19 C20 C21 123.1(10) . . ?
O14 C21 O15 125.0(10) . . ?
O14 C21 C20 118.5(10) . . ?
O15 C21 C20 116.5(10) . . ?
C2 N1 C6 118.8(9) . . ?
C2 N1 Eu1 121.5(7) . . ?
C6 N1 Eu1 119.7(7) . . ?
C13 N2 C9 115.9(9) . . ?
C13 N2 Eu1 122.2(7) . . ?
C9 N2 Eu1 121.8(7) . . ?
C16 N3 C20 116.4(10) . . ?
C16 N3 Eu1 122.1(7) . . ?
C20 N3 Eu1 120.5(7) . . ?
C1 O1 Eu1 127.0(7) . . ?
C1 O2 Co1 124.3(7) . . ?
C4 O3 H3A 109.5 . . ?
C7 O4 Co2 128.0(7) . . ?
C7 O5 Eu1 125.8(7) . . ?
C8 O6 Eu1 125.0(7) . . ?
C8 O7 Co2 127.3(7) . 1_655 ?
C11 O8 Co1 127.7(7) . 4_475 ?
C14 O10 Eu1 123.6(7) . . ?
C15 O11 Eu1 125.3(7) . . ?
C18 O13 H13 111.1 . . ?
C21 O14 Co1 122.0(7) . 1_455 ?
C21 O15 Eu1 125.7(7) . . ?
Co1 O16 H16A 118.9 . . ?
Co1 O16 H16B 107.0 . . ?
H16A O16 H16B 100.7 . . ?
Co1 O17 H17A 91.0 . . ?
Co1 O17 H17B 124.8 . . ?
H17A O17 H17B 102.8 . . ?
Co1 O18 H18A 127.1 . . ?
Co1 O18 H18B 108.7 . . ?
H18A O18 H18B 105.2 . . ?
Co2 O19 H19A 117.6 . . ?
Co2 O19 H19B 104.8 . . ?
H19A O19 H19B 107.3 . . ?
Co2 O20 H20A 109.1 . . ?
Co2 O20 H20B 140.9 . . ?
H20A O20 H20B 99.6 . . ?
Co2 O21 H21A 144.1 . . ?
Co2 O21 H21B 105.2 . . ?
H21A O21 H21B 100.3 . . ?
Co2 O22 H22A 124.3 . . ?
Co2 O22 H22B 132.3 . . ?
H22A O22 H22B 102.6 . . ?
H23A O23 H23B 107.5 . . ?
H24A O24 H24B 117.1 . . ?
H25A O25 H25B 110.9 . . ?
H26A O26 H26B 116.0 . . ?
H27A O27 H27B 105.9 . . ?
H28B O28 H28A 113.4 . . ?
H29A O29 H29B 115.1 . . ?
H30B O30 H30A 112.5 . . ?
H31A O31 H31B 108.6 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O15 2.385(7) . ?
Eu1 O5 2.386(8) . ?
Eu1 O10 2.390(8) . ?
Eu1 O1 2.403(7) . ?
Eu1 O6 2.415(7) . ?
Eu1 N2 2.435(9) . ?
Eu1 O11 2.452(8) . ?
Eu1 N3 2.493(10) . ?
Eu1 N1 2.503(9) . ?
Co1 O8 2.036(8) 4_676 ?
Co1 O18 2.047(8) . ?
Co1 O16 2.063(8) . ?
Co1 O17 2.133(7) . ?
Co1 O14 2.172(8) 1_655 ?
Co1 O2 2.210(8) . ?
Co2 O22 2.007(9) . ?
Co2 O20 2.042(9) . ?
Co2 O21 2.052(9) . ?
Co2 O4 2.136(8) . ?
Co2 O7 2.148(8) 1_455 ?
Co2 O19 2.150(8) . ?
C1 O1 1.254(13) . ?
C1 O2 1.256(13) . ?
C1 C2 1.506(15) . ?
C2 N1 1.341(14) . ?
C2 C3 1.411(16) . ?
C3 C4 1.399(17) . ?
C3 H3 0.9300 . ?
C4 O3 1.321(14) . ?
C4 C5 1.395(16) . ?
C5 C6 1.404(15) . ?
C5 H5 0.9300 . ?
C6 N1 1.363(14) . ?
C6 C7 1.478(14) . ?
C7 O4 1.271(14) . ?
C7 O5 1.286(13) . ?
C8 O7 1.251(13) . ?
C8 O6 1.274(13) . ?
C8 C9 1.538(15) . ?
C9 C10 1.361(16) . ?
C9 N2 1.361(15) . ?
C10 C11 1.432(16) . ?
C10 H10 0.9300 . ?
C11 O8 1.325(14) . ?
C11 C12 1.415(16) . ?
C12 C13 1.381(16) . ?
C12 H12 0.9300 . ?
C13 N2 1.320(14) . ?
C13 C14 1.525(15) . ?
C14 O9 1.264(13) . ?
C14 O10 1.271(13) . ?
C15 O12 1.243(14) . ?
C15 O11 1.280(13) . ?
C15 C16 1.513(16) . ?
C16 N3 1.335(14) . ?
C16 C17 1.378(16) . ?
C17 C18 1.391(16) . ?
C17 H17 0.9300 . ?
C18 O13 1.320(13) . ?
C18 C19 1.404(15) . ?
C19 C20 1.364(15) . ?
C19 H19 0.9300 . ?
C20 N3 1.356(14) . ?
C20 C21 1.523(15) . ?
C21 O14 1.266(14) . ?
C21 O15 1.269(13) . ?
O3 H3A 0.8200 . ?
O7 Co2 2.148(8) 1_655 ?
O8 Co1 2.036(8) 4_475 ?
O13 H13 0.8559 . ?
O14 Co1 2.172(7) 1_455 ?
O16 H16A 0.9119 . ?
O16 H16B 0.8829 . ?
O17 H17A 0.8724 . ?
O17 H17B 0.8968 . ?
O18 H18A 0.8730 . ?
O18 H18B 0.8682 . ?
O19 H19A 0.8600 . ?
O19 H19B 0.8645 . ?
O20 H20A 0.9038 . ?
O20 H20B 0.8888 . ?
O21 H21A 0.8863 . ?
O21 H21B 0.9116 . ?
O22 H22A 0.8782 . ?
O22 H22B 0.8687 . ?
O23 H23A 0.8897 . ?
O23 H23B 0.8748 . ?
O24 H24A 0.8728 . ?
O24 H24B 0.8455 . ?
O25 H25A 0.8843 . ?
O25 H25B 0.8879 . ?
O26 H26A 0.8668 . ?
O26 H26B 0.8700 . ?
O27 H27A 0.8778 . ?
O27 H27B 0.9018 . ?
O28 H28B 0.8525 . ?
O28 H28A 0.8792 . ?
O29 H29A 0.8727 . ?
O29 H29B 0.8497 . ?
O30 H30B 0.8696 . ?
O30 H30A 0.8854 . ?
O31 H31A 0.8871 . ?
O31 H31B 0.8837 . ?
