#------------------------------------------------------------------------------
#$Date: 2016-03-25 13:30:56 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179848 $
#$URL: svn://www.crystallography.net/cod/cif/7/01/44/7014422.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7014422
loop_
_publ_author_name
'Yang, Ming-Xing'
'Chen, Li-Juan'
'Lin, Shen'
'Chen, Xiao-Hua'
'Huang, Hua'
_publ_section_title
;
 Inorganic-organic hybrid compounds based on molybdenum oxide chains
 and tetrazolate-bridged polymeric silver cations.
;
_journal_issue                   9
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              1866
_journal_page_last               1872
_journal_paper_doi               10.1039/c0dt00781a
_journal_volume                  40
_journal_year                    2011
_chemical_formula_moiety         'C10 H6 Ag4 Mo4 N12 O13'
_chemical_formula_sum            'C10 H6 Ag4 Mo4 N12 O13'
_chemical_formula_weight         1317.51
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                102.000(2)
_cell_angle_beta                 93.610(4)
_cell_angle_gamma                110.870(6)
_cell_formula_units_Z            2
_cell_length_a                   9.690(4)
_cell_length_b                   10.240(5)
_cell_length_c                   13.130(5)
_cell_measurement_reflns_used    3041
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      25.50
_cell_measurement_theta_min      2.28
_cell_volume                     1177.3(9)
_computing_cell_refinement       '(CrystalClear; Rigaku, 2002)'
_computing_data_collection       '(CrystalClear; Rigaku, 2002)'
_computing_data_reduction        '(CrystalClear; Rigaku, 2002)'
_computing_molecular_graphics    'SHELXL-97 (Sheldrick, 1997)'
_computing_publication_material  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_detector_area_resol_mean 14.6306
_diffrn_measured_fraction_theta_full 0.949
_diffrn_measured_fraction_theta_max 0.949
_diffrn_measurement_device_type  'Rigaku Mercury CCD'
_diffrn_measurement_method       'ω scan'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0246
_diffrn_reflns_av_sigmaI/netI    0.0349
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_l_max       14
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            7846
_diffrn_reflns_theta_full        25.50
_diffrn_reflns_theta_max         25.50
_diffrn_reflns_theta_min         2.28
_exptl_absorpt_coefficient_mu    5.405
_exptl_absorpt_correction_T_max  0.7236
_exptl_absorpt_correction_T_min  0.5846
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(CrystalClear; Rigaku, 2002)'
_exptl_crystal_colour            Orange
_exptl_crystal_density_diffrn    3.717
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Prism
_exptl_crystal_F_000             1219
_exptl_crystal_size_max          0.1500
_exptl_crystal_size_mid          0.1000
_exptl_crystal_size_min          0.1000
_refine_diff_density_max         3.036
_refine_diff_density_min         -2.736
_refine_diff_density_rms         0.175
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.036
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     388
_refine_ls_number_reflns         4164
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.036
_refine_ls_R_factor_all          0.0451
_refine_ls_R_factor_gt           0.0356
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0518P)²+2.6955P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0886
_refine_ls_wR_factor_ref         0.0958
_reflns_number_gt                3526
_reflns_number_total             4164
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            C0DT00781A.TXT
_cod_data_source_block           3
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from
2010-06-29.

'_exptl_absorpt_correction_type' value 'Multi-scan' changed
to 'multi-scan' according to
'/home/saulius/struct/CIF-dictionaries/cif_core.dic' dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1555 2011-01-17 13:19:09Z saulius 
;
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7014422
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.29563(7) 0.26643(8) 0.28797(5) 0.0428(2) Uani 1 1 d . . .
Ag2 Ag 0.36389(7) -0.14566(7) 0.76282(5) 0.03575(18) Uani 1 1 d . . .
Ag3 Ag 0.92661(7) 0.50974(7) 0.66956(5) 0.03809(19) Uani 1 1 d . . .
Ag4 Ag 0.74076(7) 0.60097(7) 0.37188(5) 0.0410(2) Uani 1 1 d . . .
Mo1 Mo 0.43414(6) 0.52771(6) 0.11873(4) 0.01142(14) Uani 1 1 d . . .
Mo2 Mo 0.21659(6) 0.57438(6) -0.07857(4) 0.01294(14) Uani 1 1 d . . .
Mo3 Mo 0.09372(6) 0.29337(6) 0.03947(4) 0.01349(15) Uani 1 1 d . . .
Mo4 Mo 0.56227(6) 0.80076(6) -0.01060(4) 0.01324(15) Uani 1 1 d . . .
O1 O 0.4285(5) 0.5572(5) -0.0579(3) 0.0139(9) Uani 1 1 d . . .
O2 O 0.2460(5) 0.5288(5) 0.0873(3) 0.0141(9) Uani 1 1 d . . .
O3 O 0.2989(5) 0.3043(5) 0.0303(3) 0.0157(10) Uani 1 1 d . . .
O4 O 0.4388(5) 0.4953(5) 0.2412(3) 0.0222(11) Uani 1 1 d . . .
O5 O 0.5480(5) 0.7095(5) 0.1381(3) 0.0173(10) Uani 1 1 d . . .
O6 O 0.0636(5) 0.6278(5) -0.0406(4) 0.0227(11) Uani 1 1 d . . .
O7 O 0.1290(5) 0.3835(5) -0.1010(3) 0.0177(10) Uani 1 1 d . . .
O8 O 0.3638(5) 0.7702(5) 0.0009(3) 0.0163(10) Uani 1 1 d . . .
O9 O 0.2264(5) 0.5969(5) -0.2042(4) 0.0224(11) Uani 1 1 d . . .
O10 O -0.0060(5) 0.1258(5) -0.0355(4) 0.0278(12) Uani 1 1 d . . .
O11 O 0.0939(5) 0.2796(5) 0.1675(4) 0.0258(11) Uani 1 1 d . . .
O12 O 0.5686(5) 0.8307(5) -0.1353(4) 0.0232(11) Uani 1 1 d . . .
O13 O 0.6652(5) 0.9638(5) 0.0744(4) 0.0263(11) Uani 1 1 d . . .
N1 N 0.7711(6) 0.3036(6) 0.6975(4) 0.0174(12) Uani 1 1 d . . .
N2 N 0.5594(6) 0.0519(6) 0.7307(4) 0.0218(13) Uani 1 1 d . . .
N3 N 0.4738(7) 0.2376(7) 0.4846(5) 0.0332(16) Uani 1 1 d . . .
N4 N 0.4893(7) 0.3220(7) 0.4183(5) 0.0341(16) Uani 1 1 d . . .
N5 N 0.6209(7) 0.4294(7) 0.4468(5) 0.0281(15) Uani 1 1 d . . .
N6 N 0.6923(7) 0.4175(7) 0.5316(5) 0.0280(15) Uani 1 1 d . . .
N7 N -0.1014(6) -0.1908(6) 0.3446(4) 0.0210(13) Uani 1 1 d . . .
N8 N 0.1056(6) 0.0650(6) 0.3160(4) 0.0213(13) Uani 1 1 d . . .
N9 N 0.1911(7) -0.1189(6) 0.5627(5) 0.0251(14) Uani 1 1 d . . .
N10 N 0.1755(6) -0.2072(6) 0.6266(4) 0.0220(13) Uani 1 1 d . . .
N11 N 0.0482(7) -0.3173(7) 0.5968(5) 0.0247(14) Uani 1 1 d . . .
N12 N -0.0222(7) -0.3045(7) 0.5105(5) 0.0288(15) Uani 1 1 d . . .
C1 C 0.6344(8) 0.2361(7) 0.6372(5) 0.0189(15) Uani 1 1 d . . .
C2 C 0.7975(8) 0.2428(7) 0.7741(5) 0.0215(15) Uani 1 1 d . . .
H2A H 0.8892 0.2860 0.8178 0.026 Uiso 1 1 calc R . .
C3 C 0.6930(7) 0.1181(7) 0.7905(5) 0.0183(14) Uani 1 1 d . . .
H3B H 0.7166 0.0798 0.8443 0.022 Uiso 1 1 calc R . .
C4 C 0.5318(8) 0.1130(8) 0.6554(5) 0.0255(16) Uani 1 1 d . . .
H4A H 0.4388 0.0704 0.6133 0.031 Uiso 1 1 calc R . .
C5 C 0.6002(8) 0.2991(7) 0.5532(5) 0.0213(15) Uani 1 1 d . . .
C6 C 0.0322(7) -0.1206(7) 0.4077(5) 0.0171(14) Uani 1 1 d . . .
C7 C -0.1300(9) -0.1290(8) 0.2679(5) 0.0254(16) Uani 1 1 d . . .
H7B H -0.2218 -0.1714 0.2243 0.031 Uiso 1 1 calc R . .
C8 C -0.0250(8) -0.0047(8) 0.2538(6) 0.0227(15) Uani 1 1 d . . .
H8A H -0.0464 0.0322 0.1985 0.027 Uiso 1 1 calc R . .
C9 C 0.1342(8) 0.0052(7) 0.3923(5) 0.0203(15) Uani 1 1 d . . .
H9B H 0.2257 0.0500 0.4362 0.024 Uiso 1 1 calc R . .
C10 C 0.0679(7) -0.1824(7) 0.4931(5) 0.0191(15) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Mo Mo -1.6832 0.6857 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N4 Ag1 N8 105.2(2) . . ?
N4 Ag1 O4 88.0(2) . . ?
N8 Ag1 O4 164.38(18) . . ?
N4 Ag1 O11 163.4(2) . . ?
N8 Ag1 O11 84.45(18) . . ?
O4 Ag1 O11 80.81(16) . . ?
N4 Ag1 O12 94.2(2) . 2_665 ?
N8 Ag1 O12 107.08(18) . 2_665 ?
O4 Ag1 O12 79.66(15) . 2_665 ?
O11 Ag1 O12 95.81(15) . 2_665 ?
N4 Ag1 Ag3 115.54(18) . 2_666 ?
N8 Ag1 Ag3 93.08(15) . 2_666 ?
O4 Ag1 Ag3 73.39(12) . 2_666 ?
O11 Ag1 Ag3 49.43(11) . 2_666 ?
O12 Ag1 Ag3 138.40(10) 2_665 2_666 ?
N10 Ag2 N2 104.7(2) . . ?
N10 Ag2 O12 156.66(19) . 1_546 ?
N2 Ag2 O12 82.56(18) . 1_546 ?
N10 Ag2 O13 110.93(19) . 2_666 ?
N2 Ag2 O13 87.43(18) . 2_666 ?
O12 Ag2 O13 91.29(16) 1_546 2_666 ?
N10 Ag2 O9 87.32(18) . 1_546 ?
N2 Ag2 O9 158.55(18) . 1_546 ?
O12 Ag2 O9 79.81(16) 1_546 1_546 ?
O13 Ag2 O9 105.02(15) 2_666 1_546 ?
N11 Ag3 N1 164.0(2) 1_665 . ?
N11 Ag3 N6 93.2(2) 1_665 . ?
N1 Ag3 N6 72.8(2) . . ?
N11 Ag3 Ag1 79.44(17) 1_665 2_666 ?
N1 Ag3 Ag1 101.35(14) . 2_666 ?
N6 Ag3 Ag1 67.05(15) . 2_666 ?
N5 Ag4 N7 162.8(2) . 1_665 ?
N5 Ag4 N12 92.8(2) . 1_665 ?
N7 Ag4 N12 72.0(2) 1_665 1_665 ?
O4 Mo1 O5 105.1(2) . . ?
O4 Mo1 O2 104.9(2) . . ?
O5 Mo1 O2 102.0(2) . . ?
O4 Mo1 O1 101.4(2) . 2_665 ?
O5 Mo1 O1 98.5(2) . 2_665 ?
O2 Mo1 O1 140.81(19) . 2_665 ?
O4 Mo1 O3 97.1(2) . . ?
O5 Mo1 O3 157.47(18) . . ?
O2 Mo1 O3 75.77(17) . . ?
O1 Mo1 O3 72.60(17) 2_665 . ?
O4 Mo1 O1 176.02(19) . . ?
O5 Mo1 O1 77.98(17) . . ?
O2 Mo1 O1 76.70(16) . . ?
O1 Mo1 O1 75.44(18) 2_665 . ?
O3 Mo1 O1 79.73(15) . . ?
O4 Mo1 Mo3 93.19(16) . . ?
O5 Mo1 Mo3 143.67(15) . . ?
O2 Mo1 Mo3 42.16(13) . . ?
O1 Mo1 Mo3 108.48(13) 2_665 . ?
O3 Mo1 Mo3 36.03(11) . . ?
O1 Mo1 Mo3 85.60(10) . . ?
O4 Mo1 Mo4 90.79(16) . 2_665 ?
O5 Mo1 Mo4 139.04(15) . 2_665 ?
O2 Mo1 Mo4 110.08(13) . 2_665 ?
O1 Mo1 Mo4 40.76(12) 2_665 2_665 ?
O3 Mo1 Mo4 34.43(11) . 2_665 ?
O1 Mo1 Mo4 85.24(10) . 2_665 ?
Mo3 Mo1 Mo4 69.92(3) . 2_665 ?
O9 Mo2 O7 102.3(2) . . ?
O9 Mo2 O6 103.5(2) . . ?
O7 Mo2 O6 100.5(2) . . ?
O9 Mo2 O8 98.8(2) . . ?
O7 Mo2 O8 153.49(19) . . ?
O6 Mo2 O8 89.86(19) . . ?
O9 Mo2 O1 95.01(19) . . ?
O7 Mo2 O1 89.22(18) . . ?
O6 Mo2 O1 156.6(2) . . ?
O8 Mo2 O1 73.05(17) . . ?
O9 Mo2 O2 167.88(19) . . ?
O7 Mo2 O2 75.22(17) . . ?
O6 Mo2 O2 88.64(18) . . ?
O8 Mo2 O2 80.76(17) . . ?
O1 Mo2 O2 73.21(15) . . ?
O9 Mo2 Mo4 88.75(16) . . ?
O7 Mo2 Mo4 133.37(14) . . ?
O6 Mo2 Mo4 120.94(15) . . ?
O8 Mo2 Mo4 31.16(12) . . ?
O1 Mo2 Mo4 44.39(12) . . ?
O2 Mo2 Mo4 84.74(10) . . ?
O9 Mo2 Mo3 137.45(17) . . ?
O7 Mo2 Mo3 35.15(14) . . ?
O6 Mo2 Mo3 90.17(15) . . ?
O8 Mo2 Mo3 121.66(13) . . ?
O1 Mo2 Mo3 85.65(11) . . ?
O2 Mo2 Mo3 40.93(10) . . ?
Mo4 Mo2 Mo3 118.51(3) . . ?
O10 Mo3 O11 105.8(3) . . ?
O10 Mo3 O6 98.8(2) . 2_565 ?
O11 Mo3 O6 94.9(2) . 2_565 ?
O10 Mo3 O3 101.2(2) . . ?
O11 Mo3 O3 96.3(2) . . ?
O6 Mo3 O3 153.41(19) 2_565 . ?
O10 Mo3 O7 92.0(2) . . ?
O11 Mo3 O7 162.1(2) . . ?
O6 Mo3 O7 80.38(18) 2_565 . ?
O3 Mo3 O7 81.59(17) . . ?
O10 Mo3 O2 161.0(2) . . ?
O11 Mo3 O2 92.8(2) . . ?
O6 Mo3 O2 83.05(17) 2_565 . ?
O3 Mo3 O2 72.39(17) . . ?
O7 Mo3 O2 69.53(16) . . ?
O10 Mo3 Mo1 142.47(17) . . ?
O11 Mo3 Mo1 85.67(17) . . ?
O6 Mo3 Mo1 116.04(14) 2_565 . ?
O3 Mo3 Mo1 41.36(13) . . ?
O7 Mo3 Mo1 81.03(11) . . ?
O2 Mo3 Mo1 33.31(11) . . ?
O10 Mo3 Mo2 119.29(18) . . ?
O11 Mo3 Mo2 134.60(17) . . ?
O6 Mo3 Mo2 74.40(14) 2_565 . ?
O3 Mo3 Mo2 80.58(13) . . ?
O7 Mo3 Mo2 27.51(11) . . ?
O2 Mo3 Mo2 42.76(11) . . ?
Mo1 Mo3 Mo2 62.15(2) . . ?
O13 Mo4 O12 105.8(2) . . ?
O13 Mo4 O8 105.9(2) . . ?
O12 Mo4 O8 100.0(2) . . ?
O13 Mo4 O3 105.3(2) . 2_665 ?
O12 Mo4 O3 92.6(2) . 2_665 ?
O8 Mo4 O3 141.49(18) . 2_665 ?
O13 Mo4 O1 155.7(2) . . ?
O12 Mo4 O1 98.3(2) . . ?
O8 Mo4 O1 72.16(17) . . ?
O3 Mo4 O1 70.08(16) 2_665 . ?
O13 Mo4 O5 85.4(2) . . ?
O12 Mo4 O5 167.4(2) . . ?
O8 Mo4 O5 82.09(17) . . ?
O3 Mo4 O5 78.50(17) 2_665 . ?
O1 Mo4 O5 70.35(15) . . ?
O13 Mo4 Mo2 139.73(16) . . ?
O12 Mo4 Mo2 91.14(16) . . ?
O8 Mo4 Mo2 34.11(13) . . ?
O3 Mo4 Mo2 110.27(13) 2_665 . ?
O1 Mo4 Mo2 40.59(10) . . ?
O5 Mo4 Mo2 83.71(11) . . ?
O13 Mo4 Mo1 143.17(17) . 2_665 ?
O12 Mo4 Mo1 86.86(16) . 2_665 ?
O8 Mo4 Mo1 105.59(13) . 2_665 ?
O3 Mo4 Mo1 38.60(12) 2_665 2_665 ?
O1 Mo4 Mo1 33.96(10) . 2_665 ?
O5 Mo4 Mo1 80.60(11) . 2_665 ?
Mo2 Mo4 Mo1 72.27(3) . 2_665 ?
Mo1 O1 Mo2 146.8(2) 2_665 . ?
Mo1 O1 Mo4 105.28(18) 2_665 . ?
Mo2 O1 Mo4 95.03(16) . . ?
Mo1 O1 Mo1 104.56(18) 2_665 . ?
Mo2 O1 Mo1 99.24(15) . . ?
Mo4 O1 Mo1 95.30(15) . . ?
Mo1 O2 Mo3 104.53(19) . . ?
Mo1 O2 Mo2 110.53(18) . . ?
Mo3 O2 Mo2 96.32(16) . . ?
Mo3 O3 Mo4 147.6(2) . 2_665 ?
Mo3 O3 Mo1 102.61(19) . . ?
Mo4 O3 Mo1 106.97(19) 2_665 . ?
Mo1 O4 Ag1 126.7(2) . . ?
Mo1 O5 Mo4 115.9(2) . . ?
Mo2 O6 Mo3 162.2(3) . 2_565 ?
Mo2 O7 Mo3 117.3(2) . . ?
Mo4 O8 Mo2 114.7(2) . . ?
Mo2 O9 Ag2 120.8(2) . 1_564 ?
Mo3 O11 Ag1 128.5(2) . . ?
Mo4 O12 Ag2 123.5(2) . 1_564 ?
Mo4 O12 Ag1 128.3(2) . 2_665 ?
Ag2 O12 Ag1 101.49(17) 1_564 2_665 ?
Mo4 O13 Ag2 139.7(2) . 2_666 ?
C2 N1 C1 115.9(6) . . ?
C2 N1 Ag3 125.3(4) . . ?
C1 N1 Ag3 118.7(5) . . ?
C3 N2 C4 116.4(6) . . ?
C3 N2 Ag2 124.2(5) . . ?
C4 N2 Ag2 119.0(5) . . ?
N4 N3 C5 104.9(6) . . ?
N5 N4 N3 108.7(6) . . ?
N5 N4 Ag1 132.8(5) . . ?
N3 N4 Ag1 118.4(5) . . ?
N4 N5 N6 110.0(6) . . ?
N4 N5 Ag4 131.8(5) . . ?
N6 N5 Ag4 117.9(5) . . ?
C5 N6 N5 104.7(6) . . ?
C5 N6 Ag3 105.6(5) . . ?
N5 N6 Ag3 149.6(5) . . ?
C6 N7 C7 116.5(6) . . ?
C6 N7 Ag4 119.0(5) . 1_445 ?
C7 N7 Ag4 124.5(5) . 1_445 ?
C8 N8 C9 116.7(6) . . ?
C8 N8 Ag1 124.1(5) . . ?
C9 N8 Ag1 118.8(5) . . ?
C10 N9 N10 103.9(6) . . ?
N11 N10 N9 110.3(6) . . ?
N11 N10 Ag2 131.9(5) . . ?
N9 N10 Ag2 117.8(4) . . ?
N10 N11 N12 108.7(5) . . ?
N10 N11 Ag3 132.9(5) . 1_445 ?
N12 N11 Ag3 117.9(4) . 1_445 ?
C10 N12 N11 104.5(6) . . ?
C10 N12 Ag4 106.7(5) . 1_445 ?
N11 N12 Ag4 148.5(4) . 1_445 ?
N1 C1 C4 120.7(6) . . ?
N1 C1 C5 117.8(6) . . ?
C4 C1 C5 121.5(6) . . ?
N1 C2 C3 122.5(6) . . ?
N1 C2 H2A 118.8 . . ?
C3 C2 H2A 118.8 . . ?
N2 C3 C2 121.4(7) . . ?
N2 C3 H3B 119.3 . . ?
C2 C3 H3B 119.3 . . ?
N2 C4 C1 123.2(7) . . ?
N2 C4 H4A 118.4 . . ?
C1 C4 H4A 118.4 . . ?
N6 C5 N3 111.7(6) . . ?
N6 C5 C1 124.9(6) . . ?
N3 C5 C1 123.3(6) . . ?
N7 C6 C9 121.0(6) . . ?
N7 C6 C10 118.6(6) . . ?
C9 C6 C10 120.3(6) . . ?
N7 C7 C8 120.9(7) . . ?
N7 C7 H7B 119.6 . . ?
C8 C7 H7B 119.6 . . ?
N8 C8 C7 122.7(7) . . ?
N8 C8 H8A 118.6 . . ?
C7 C8 H8A 118.6 . . ?
N8 C9 C6 122.1(6) . . ?
N8 C9 H9B 119.0 . . ?
C6 C9 H9B 119.0 . . ?
N12 C10 N9 112.6(6) . . ?
N12 C10 C6 123.7(6) . . ?
N9 C10 C6 123.7(6) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 N4 2.281(7) . ?
Ag1 N8 2.340(6) . ?
Ag1 O4 2.486(5) . ?
Ag1 O11 2.496(5) . ?
Ag1 Ag3 3.6522(16) 2_666 ?
Ag2 N10 2.287(6) . ?
Ag2 N2 2.363(6) . ?
Ag2 O12 2.434(5) 1_546 ?
Ag2 O9 2.637(5) 1_546 ?
Ag3 N11 2.190(6) 1_665 ?
Ag3 N1 2.233(6) . ?
Ag3 N6 2.564(6) . ?
Ag3 Ag1 3.6522(16) 2_666 ?
Ag4 N5 2.194(6) . ?
Ag4 N7 2.253(6) 1_665 ?
Ag4 N12 2.585(6) 1_665 ?
Mo1 O4 1.709(5) . ?
Mo1 O5 1.747(4) . ?
Mo1 O2 1.848(4) . ?
Mo1 O1 1.958(4) 2_665 ?
Mo1 O3 2.206(4) . ?
Mo1 O1 2.399(4) . ?
Mo1 Mo3 3.2576(13) . ?
Mo1 Mo4 3.3814(17) 2_665 ?
Mo2 O9 1.716(5) . ?
Mo2 O7 1.782(5) . ?
Mo2 O6 1.817(5) . ?
Mo2 O8 2.012(4) . ?
Mo2 O1 2.128(4) . ?
Mo2 O2 2.341(4) . ?
Mo2 Mo4 3.2590(13) . ?
Mo2 Mo3 3.4272(14) . ?
Mo3 O10 1.686(5) . ?
Mo3 O11 1.716(5) . ?
Mo3 O6 1.962(5) 2_565 ?
Mo3 O3 1.964(4) . ?
Mo3 O7 2.221(5) . ?
Mo3 O2 2.259(4) . ?
Mo4 O13 1.710(5) . ?
Mo4 O12 1.728(5) . ?
Mo4 O8 1.856(4) . ?
Mo4 O3 1.999(4) 2_665 ?
Mo4 O1 2.289(4) . ?
Mo4 O5 2.325(4) . ?
Mo4 Mo1 3.3814(17) 2_665 ?
N1 C2 1.344(9) . ?
N1 C1 1.359(9) . ?
N2 C3 1.333(9) . ?
N2 C4 1.335(9) . ?
N3 N4 1.328(9) . ?
N3 C5 1.335(9) . ?
N4 N5 1.321(9) . ?
N5 N6 1.324(9) . ?
N6 C5 1.323(9) . ?
N7 C6 1.353(9) . ?
N7 C7 1.360(9) . ?
N7 Ag4 2.253(6) 1_445 ?
N8 C8 1.327(9) . ?
N8 C9 1.339(9) . ?
N9 C10 1.321(9) . ?
N9 N10 1.333(8) . ?
N10 N11 1.308(8) . ?
N11 N12 1.340(8) . ?
N11 Ag3 2.190(6) 1_445 ?
N12 C10 1.321(9) . ?
N12 Ag4 2.585(6) 1_445 ?
C1 C4 1.378(10) . ?
C1 C5 1.464(10) . ?
C2 C3 1.386(10) . ?
C2 H2A 0.9300 . ?
C3 H3B 0.9300 . ?
C4 H4A 0.9300 . ?
C6 C9 1.380(9) . ?
C6 C10 1.476(10) . ?
C7 C8 1.374(10) . ?
C7 H7B 0.9300 . ?
C8 H8A 0.9300 . ?
C9 H9B 0.9300 . ?
