#------------------------------------------------------------------------------
#$Date: 2016-03-25 13:34:00 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179851 $
#$URL: svn://www.crystallography.net/cod/cif/7/01/47/7014730.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7014730
loop_
_publ_author_name
'Ullrich, Matthias'
'Berger, Raphael J. F.'
'Jana, Surajit'
'Pape, Tania'
'Fröhlich, Roland'
'Mitzel, Norbert W.'
_publ_section_title
;
 Organozinc hydroxylamides: on the bulk-dependent interplay of
 nuclearity, structure and dynamics.
;
_journal_issue                   5
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              1144
_journal_page_last               1157
_journal_paper_doi               10.1039/c0dt01100b
_journal_volume                  40
_journal_year                    2011
_chemical_formula_sum            'C20 H52 N4 O4 Zn4'
_chemical_formula_weight         674.14
_chemical_name_systematic
;
?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 102.82(1)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   9.171(1)
_cell_length_b                   17.464(1)
_cell_length_c                   19.446(1)
_cell_measurement_reflns_used    5894
_cell_measurement_temperature    198(2)
_cell_measurement_theta_max      28.28
_cell_measurement_theta_min      0.41
_cell_volume                     3036.9(4)
_computing_cell_refinement       'Collect (Nonius B.V., 1998)'
_computing_data_collection       'Collect (Nonius B.V., 1998)'
_computing_data_reduction        'Denzo-SMN (Otwinowski & Minor, 1997)'
_computing_publication_material  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      198(2)
_diffrn_measured_fraction_theta_full 0.942
_diffrn_measured_fraction_theta_max 0.942
_diffrn_measurement_device_type  'Nonius KappaCCD'
_diffrn_measurement_method       'ω and φ scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'rotating anode Nonius FR591'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.025
_diffrn_reflns_av_sigmaI/netI    0.0305
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_number            17711
_diffrn_reflns_theta_full        27.88
_diffrn_reflns_theta_max         27.88
_diffrn_reflns_theta_min         2.56
_exptl_absorpt_coefficient_mu    3.149
_exptl_absorpt_correction_T_max  0.5065
_exptl_absorpt_correction_T_min  0.3656
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
'Denzo (Otwinowski, Borek, Majewski & Minor, 2003)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.474
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1408
_exptl_crystal_size_max          0.40
_exptl_crystal_size_mid          0.30
_exptl_crystal_size_min          0.25
_refine_diff_density_max         0.320
_refine_diff_density_min         -0.514
_refine_diff_density_rms         0.068
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.034
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     301
_refine_ls_number_reflns         6829
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.034
_refine_ls_R_factor_all          0.0380
_refine_ls_R_factor_gt           0.0275
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0249P)²+1.8882P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0602
_refine_ls_wR_factor_ref         0.0635
_reflns_number_gt                5690
_reflns_number_total             6829
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            C0DT01100B.TXT
_cod_data_source_block           fro3819
_cod_original_sg_symbol_H-M      P21/c
_cod_database_code               7014730
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Zn1 Zn 0.56365(3) 0.672027(14) -0.408247(12) 0.02373(7) Uani 1 1 d . . .
Zn2 Zn 0.35923(3) 0.824285(14) -0.390794(13) 0.02469(7) Uani 1 1 d . . .
Zn3 Zn 0.35380(3) 0.661977(14) -0.292774(12) 0.02235(6) Uani 1 1 d . . .
Zn4 Zn 0.70364(3) 0.775651(15) -0.258915(13) 0.02498(7) Uani 1 1 d . . .
O1 O 0.35005(16) 0.71646(8) -0.43116(7) 0.0234(3) Uani 1 1 d . . .
O2 O 0.38018(16) 0.77755(8) -0.29208(7) 0.0245(3) Uani 1 1 d . . .
O3 O 0.55790(15) 0.63020(8) -0.31089(7) 0.0225(3) Uani 1 1 d . . .
O4 O 0.66204(16) 0.77260(8) -0.36675(7) 0.0246(3) Uani 1 1 d . . .
N1 N 0.25147(19) 0.66672(10) -0.40187(9) 0.0225(4) Uani 1 1 d . . .
N2 N 0.4945(2) 0.81206(10) -0.23686(9) 0.0247(4) Uani 1 1 d . . .
N3 N 0.69187(19) 0.65245(10) -0.25902(9) 0.0232(4) Uani 1 1 d . . .
N4 N 0.5837(2) 0.83831(10) -0.40454(9) 0.0247(4) Uani 1 1 d . . .
C1 C 0.6387(3) 0.61065(15) -0.47848(13) 0.0396(6) Uani 1 1 d . . .
H1A H 0.7073 0.6418 -0.4990 0.059 Uiso 1 1 calc R . .
H1B H 0.5544 0.5942 -0.5159 0.059 Uiso 1 1 calc R . .
H1C H 0.6918 0.5656 -0.4554 0.059 Uiso 1 1 calc R . .
C2 C 0.2209(3) 0.91114(15) -0.42090(15) 0.0437(6) Uani 1 1 d . . .
H2A H 0.1614 0.9015 -0.4685 0.066 Uiso 1 1 calc R . .
H2B H 0.2787 0.9583 -0.4209 0.066 Uiso 1 1 calc R . .
H2C H 0.1543 0.9166 -0.3882 0.066 Uiso 1 1 calc R . .
C3 C 0.2594(3) 0.60553(15) -0.22532(12) 0.0336(5) Uani 1 1 d . . .
H3A H 0.3337 0.5720 -0.1959 0.050 Uiso 1 1 calc R . .
H3B H 0.1763 0.5746 -0.2515 0.050 Uiso 1 1 calc R . .
H3C H 0.2218 0.6422 -0.1952 0.050 Uiso 1 1 calc R . .
C4 C 0.8919(3) 0.82203(18) -0.20499(17) 0.0521(8) Uani 1 1 d . . .
H4A H 0.9763 0.7887 -0.2078 0.078 Uiso 1 1 calc R . .
H4B H 0.8863 0.8281 -0.1555 0.078 Uiso 1 1 calc R . .
H4C H 0.9062 0.8723 -0.2250 0.078 Uiso 1 1 calc R . .
C11 C 0.1021(2) 0.70458(14) -0.41342(12) 0.0313(5) Uani 1 1 d . . .
H11A H 0.1133 0.7532 -0.3865 0.038 Uiso 1 1 calc R . .
H11B H 0.0343 0.6712 -0.3936 0.038 Uiso 1 1 calc R . .
C12 C 0.0279(3) 0.72210(18) -0.49001(14) 0.0474(7) Uani 1 1 d . . .
H12A H 0.0969 0.7516 -0.5116 0.071 Uiso 1 1 calc R . .
H12B H -0.0634 0.7520 -0.4918 0.071 Uiso 1 1 calc R . .
H12C H 0.0024 0.6740 -0.5159 0.071 Uiso 1 1 calc R . .
C13 C 0.2453(3) 0.59356(13) -0.44083(12) 0.0297(5) Uani 1 1 d . . .
H13A H 0.3463 0.5704 -0.4310 0.036 Uiso 1 1 calc R . .
H13B H 0.2157 0.6041 -0.4921 0.036 Uiso 1 1 calc R . .
C14 C 0.1358(3) 0.53643(14) -0.42124(13) 0.0360(6) Uani 1 1 d . . .
H14A H 0.1519 0.5333 -0.3698 0.054 Uiso 1 1 calc R . .
H14B H 0.1519 0.4859 -0.4402 0.054 Uiso 1 1 calc R . .
H14C H 0.0332 0.5533 -0.4411 0.054 Uiso 1 1 calc R . .
C21 C 0.4763(3) 0.78155(13) -0.16773(11) 0.0290(5) Uani 1 1 d . . .
H21A H 0.5598 0.8011 -0.1306 0.035 Uiso 1 1 calc R . .
H21B H 0.4860 0.7251 -0.1686 0.035 Uiso 1 1 calc R . .
C22 C 0.3310(3) 0.80056(17) -0.14663(14) 0.0437(6) Uani 1 1 d . . .
H22A H 0.3285 0.8554 -0.1362 0.066 Uiso 1 1 calc R . .
H22B H 0.3241 0.7710 -0.1046 0.066 Uiso 1 1 calc R . .
H22C H 0.2466 0.7876 -0.1854 0.066 Uiso 1 1 calc R . .
C23 C 0.4616(3) 0.89560(13) -0.24129(12) 0.0291(5) Uani 1 1 d . . .
H23A H 0.3583 0.9040 -0.2355 0.035 Uiso 1 1 calc R . .
H23B H 0.4672 0.9144 -0.2887 0.035 Uiso 1 1 calc R . .
C24 C 0.5687(3) 0.94146(14) -0.18601(13) 0.0417(6) Uani 1 1 d . . .
H24A H 0.5524 0.9290 -0.1392 0.063 Uiso 1 1 calc R . .
H24B H 0.5512 0.9963 -0.1952 0.063 Uiso 1 1 calc R . .
H24C H 0.6718 0.9288 -0.1879 0.063 Uiso 1 1 calc R . .
C31 C 0.6864(2) 0.60979(13) -0.19345(11) 0.0276(5) Uani 1 1 d . . .
H31A H 0.6896 0.5541 -0.2027 0.033 Uiso 1 1 calc R . .
H31B H 0.5906 0.6210 -0.1800 0.033 Uiso 1 1 calc R . .
C32 C 0.8150(3) 0.63057(17) -0.13247(13) 0.0438(6) Uani 1 1 d . . .
H32A H 0.9097 0.6145 -0.1435 0.066 Uiso 1 1 calc R . .
H32B H 0.8021 0.6045 -0.0896 0.066 Uiso 1 1 calc R . .
H32C H 0.8162 0.6861 -0.1250 0.066 Uiso 1 1 calc R . .
C33 C 0.8229(2) 0.62620(14) -0.28687(12) 0.0307(5) Uani 1 1 d . . .
H33A H 0.9153 0.6417 -0.2529 0.037 Uiso 1 1 calc R . .
H33B H 0.8211 0.6537 -0.3316 0.037 Uiso 1 1 calc R . .
C34 C 0.8325(3) 0.54113(15) -0.30056(14) 0.0407(6) Uani 1 1 d . . .
H34A H 0.8560 0.5136 -0.2555 0.061 Uiso 1 1 calc R . .
H34B H 0.9112 0.5317 -0.3263 0.061 Uiso 1 1 calc R . .
H34C H 0.7365 0.5231 -0.3287 0.061 Uiso 1 1 calc R . .
C41 C 0.5835(3) 0.82628(13) -0.48045(12) 0.0302(5) Uani 1 1 d . . .
H41A H 0.5280 0.7787 -0.4970 0.036 Uiso 1 1 calc R . .
H41B H 0.6877 0.8196 -0.4856 0.036 Uiso 1 1 calc R . .
C42 C 0.5127(3) 0.89244(15) -0.52620(12) 0.0403(6) Uani 1 1 d . . .
H42A H 0.4160 0.9049 -0.5154 0.060 Uiso 1 1 calc R . .
H42B H 0.4978 0.8781 -0.5760 0.060 Uiso 1 1 calc R . .
H42C H 0.5786 0.9372 -0.5168 0.060 Uiso 1 1 calc R . .
C43 C 0.6688(3) 0.90794(13) -0.37636(12) 0.0310(5) Uani 1 1 d . . .
H43A H 0.6743 0.9104 -0.3250 0.037 Uiso 1 1 calc R . .
H43B H 0.6118 0.9533 -0.3980 0.037 Uiso 1 1 calc R . .
C44 C 0.8274(3) 0.91376(17) -0.38830(16) 0.0482(7) Uani 1 1 d . . .
H44A H 0.8827 0.8669 -0.3715 0.072 Uiso 1 1 calc R . .
H44B H 0.8782 0.9578 -0.3623 0.072 Uiso 1 1 calc R . .
H44C H 0.8233 0.9203 -0.4387 0.072 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 Zn1 O3 122.12(9) . . ?
C1 Zn1 O4 123.00(9) . . ?
O3 Zn1 O4 92.35(6) . . ?
C1 Zn1 O1 120.99(9) . . ?
O3 Zn1 O1 96.68(6) . . ?
O4 Zn1 O1 94.39(6) . . ?
C2 Zn2 O1 128.74(10) . . ?
C2 Zn2 O2 120.08(9) . . ?
O1 Zn2 O2 88.86(6) . . ?
C2 Zn2 N4 116.39(9) . . ?
O1 Zn2 N4 90.93(6) . . ?
O2 Zn2 N4 105.54(6) . . ?
C3 Zn3 O2 123.86(8) . . ?
C3 Zn3 O3 121.72(8) . . ?
O2 Zn3 O3 99.07(6) . . ?
C3 Zn3 N1 121.25(8) . . ?
O2 Zn3 N1 89.62(6) . . ?
O3 Zn3 N1 93.25(6) . . ?
C4 Zn4 O4 119.66(10) . . ?
C4 Zn4 N2 118.93(11) . . ?
O4 Zn4 N2 103.89(6) . . ?
C4 Zn4 N3 116.49(10) . . ?
O4 Zn4 N3 88.57(6) . . ?
N2 Zn4 N3 104.39(7) . . ?
N1 O1 Zn2 112.14(10) . . ?
N1 O1 Zn1 109.47(10) . . ?
Zn2 O1 Zn1 108.00(6) . . ?
N2 O2 Zn3 118.79(11) . . ?
N2 O2 Zn2 115.32(11) . . ?
Zn3 O2 Zn2 113.69(6) . . ?
N3 O3 Zn1 110.79(10) . . ?
N3 O3 Zn3 117.95(11) . . ?
Zn1 O3 Zn3 105.91(6) . . ?
N4 O4 Zn4 116.96(11) . . ?
N4 O4 Zn1 110.43(11) . . ?
Zn4 O4 Zn1 112.96(7) . . ?
O1 N1 C13 105.73(15) . . ?
O1 N1 C11 107.79(16) . . ?
C13 N1 C11 112.06(17) . . ?
O1 N1 Zn3 103.81(10) . . ?
C13 N1 Zn3 115.86(13) . . ?
C11 N1 Zn3 110.80(13) . . ?
O2 N2 C23 105.05(15) . . ?
O2 N2 C21 108.13(16) . . ?
C23 N2 C21 109.93(17) . . ?
O2 N2 Zn4 105.00(11) . . ?
C23 N2 Zn4 117.15(14) . . ?
C21 N2 Zn4 110.96(13) . . ?
O3 N3 C31 106.02(15) . . ?
O3 N3 C33 106.81(15) . . ?
C31 N3 C33 109.84(17) . . ?
O3 N3 Zn4 107.52(11) . . ?
C31 N3 Zn4 120.71(13) . . ?
C33 N3 Zn4 105.21(13) . . ?
O4 N4 C43 107.34(16) . . ?
O4 N4 C41 106.23(15) . . ?
C43 N4 C41 111.50(17) . . ?
O4 N4 Zn2 103.04(11) . . ?
C43 N4 Zn2 119.21(14) . . ?
C41 N4 Zn2 108.45(14) . . ?
N1 C11 C12 115.56(19) . . ?
N1 C13 C14 112.97(18) . . ?
N2 C21 C22 116.6(2) . . ?
N2 C23 C24 112.71(19) . . ?
N3 C31 C32 112.44(19) . . ?
N3 C33 C34 116.55(19) . . ?
N4 C41 C42 112.37(18) . . ?
N4 C43 C44 116.1(2) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Zn1 C1 1.976(2) . ?
Zn1 O3 2.0408(14) . ?
Zn1 O4 2.0560(15) . ?
Zn1 O1 2.0617(15) . ?
Zn2 C2 1.981(2) . ?
Zn2 O1 2.0347(15) . ?
Zn2 O2 2.0553(14) . ?
Zn2 N4 2.1476(19) . ?
Zn3 C3 1.986(2) . ?
Zn3 O2 2.0326(15) . ?
Zn3 O3 2.0563(14) . ?
Zn3 N1 2.1225(17) . ?
Zn4 C4 1.983(3) . ?
Zn4 O4 2.0471(14) . ?
Zn4 N2 2.1522(19) . ?
Zn4 N3 2.1542(18) . ?
O1 N1 1.458(2) . ?
O2 N2 1.455(2) . ?
O3 N3 1.459(2) . ?
O4 N4 1.463(2) . ?
N1 C13 1.480(3) . ?
N1 C11 1.493(3) . ?
N2 C23 1.488(3) . ?
N2 C21 1.490(3) . ?
N3 C31 1.487(3) . ?
N3 C33 1.495(3) . ?
N4 C43 1.483(3) . ?
N4 C41 1.491(3) . ?
C11 C12 1.525(3) . ?
C13 C14 1.522(3) . ?
C21 C22 1.515(3) . ?
C23 C24 1.514(3) . ?
C31 C32 1.519(3) . ?
C33 C34 1.515(3) . ?
C41 C42 1.514(3) . ?
C43 C44 1.527(3) . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C2 Zn2 O1 N1 -83.95(15) . . . . ?
O2 Zn2 O1 N1 44.86(11) . . . . ?
N4 Zn2 O1 N1 150.39(11) . . . . ?
C2 Zn2 O1 Zn1 155.35(11) . . . . ?
O2 Zn2 O1 Zn1 -75.84(7) . . . . ?
N4 Zn2 O1 Zn1 29.69(7) . . . . ?
C1 Zn1 O1 N1 98.30(14) . . . . ?
O3 Zn1 O1 N1 -35.70(11) . . . . ?
O4 Zn1 O1 N1 -128.60(11) . . . . ?
C1 Zn1 O1 Zn2 -139.34(10) . . . . ?
O3 Zn1 O1 Zn2 86.65(7) . . . . ?
O4 Zn1 O1 Zn2 -6.24(7) . . . . ?
C3 Zn3 O2 N2 73.89(15) . . . . ?
O3 Zn3 O2 N2 -64.54(13) . . . . ?
N1 Zn3 O2 N2 -157.77(13) . . . . ?
C3 Zn3 O2 Zn2 -145.40(9) . . . . ?
O3 Zn3 O2 Zn2 76.17(8) . . . . ?
N1 Zn3 O2 Zn2 -17.06(8) . . . . ?
C2 Zn2 O2 N2 -89.71(15) . . . . ?
O1 Zn2 O2 N2 134.91(12) . . . . ?
N4 Zn2 O2 N2 44.26(13) . . . . ?
C2 Zn2 O2 Zn3 128.17(11) . . . . ?
O1 Zn2 O2 Zn3 -7.21(8) . . . . ?
N4 Zn2 O2 Zn3 -97.86(8) . . . . ?
C1 Zn1 O3 N3 94.66(15) . . . . ?
O4 Zn1 O3 N3 -37.36(12) . . . . ?
O1 Zn1 O3 N3 -132.06(11) . . . . ?
C1 Zn1 O3 Zn3 -136.31(10) . . . . ?
O4 Zn1 O3 Zn3 91.66(7) . . . . ?
O1 Zn1 O3 Zn3 -3.04(7) . . . . ?
C3 Zn3 O3 N3 -78.69(15) . . . . ?
O2 Zn3 O3 N3 60.94(12) . . . . ?
N1 Zn3 O3 N3 151.07(12) . . . . ?
C3 Zn3 O3 Zn1 156.62(9) . . . . ?
O2 Zn3 O3 Zn1 -63.75(7) . . . . ?
N1 Zn3 O3 Zn1 26.39(7) . . . . ?
C4 Zn4 O4 N4 -89.56(16) . . . . ?
N2 Zn4 O4 N4 46.02(13) . . . . ?
N3 Zn4 O4 N4 150.50(13) . . . . ?
C4 Zn4 O4 Zn1 140.59(12) . . . . ?
N2 Zn4 O4 Zn1 -83.84(8) . . . . ?
N3 Zn4 O4 Zn1 20.64(8) . . . . ?
C1 Zn1 O4 N4 97.01(14) . . . . ?
O3 Zn1 O4 N4 -131.60(11) . . . . ?
O1 Zn1 O4 N4 -34.72(11) . . . . ?
C1 Zn1 O4 Zn4 -129.89(10) . . . . ?
O3 Zn1 O4 Zn4 1.50(7) . . . . ?
O1 Zn1 O4 Zn4 98.39(7) . . . . ?
Zn2 O1 N1 C13 174.76(12) . . . . ?
Zn1 O1 N1 C13 -65.39(15) . . . . ?
Zn2 O1 N1 C11 54.75(16) . . . . ?
Zn1 O1 N1 C11 174.59(12) . . . . ?
Zn2 O1 N1 Zn3 -62.83(11) . . . . ?
Zn1 O1 N1 Zn3 57.01(11) . . . . ?
C3 Zn3 N1 O1 176.67(12) . . . . ?
O2 Zn3 N1 O1 46.31(11) . . . . ?
O3 Zn3 N1 O1 -52.75(11) . . . . ?
C3 Zn3 N1 C13 -67.89(17) . . . . ?
O2 Zn3 N1 C13 161.74(15) . . . . ?
O3 Zn3 N1 C13 62.68(15) . . . . ?
C3 Zn3 N1 C11 61.21(17) . . . . ?
O2 Zn3 N1 C11 -69.16(14) . . . . ?
O3 Zn3 N1 C11 -168.22(14) . . . . ?
Zn3 O2 N2 C23 -167.29(12) . . . . ?
Zn2 O2 N2 C23 52.61(17) . . . . ?
Zn3 O2 N2 C21 -49.94(18) . . . . ?
Zn2 O2 N2 C21 169.96(13) . . . . ?
Zn3 O2 N2 Zn4 68.57(12) . . . . ?
Zn2 O2 N2 Zn4 -71.52(12) . . . . ?
C4 Zn4 N2 O2 170.87(13) . . . . ?
O4 Zn4 N2 O2 34.90(12) . . . . ?
N3 Zn4 N2 O2 -57.22(12) . . . . ?
C4 Zn4 N2 C23 54.80(18) . . . . ?
O4 Zn4 N2 C23 -81.18(14) . . . . ?
N3 Zn4 N2 C23 -173.29(14) . . . . ?
C4 Zn4 N2 C21 -72.54(17) . . . . ?
O4 Zn4 N2 C21 151.48(13) . . . . ?
N3 Zn4 N2 C21 59.37(14) . . . . ?
Zn1 O3 N3 C31 -171.81(12) . . . . ?
Zn3 O3 N3 C31 65.95(17) . . . . ?
Zn1 O3 N3 C33 -54.71(17) . . . . ?
Zn3 O3 N3 C33 -176.95(12) . . . . ?
Zn1 O3 N3 Zn4 57.80(12) . . . . ?
Zn3 O3 N3 Zn4 -64.44(12) . . . . ?
C4 Zn4 N3 O3 -170.17(14) . . . . ?
O4 Zn4 N3 O3 -47.45(11) . . . . ?
N2 Zn4 N3 O3 56.52(12) . . . . ?
C4 Zn4 N3 C31 68.21(18) . . . . ?
O4 Zn4 N3 C31 -169.07(15) . . . . ?
N2 Zn4 N3 C31 -65.09(15) . . . . ?
C4 Zn4 N3 C33 -56.59(17) . . . . ?
O4 Zn4 N3 C33 66.13(13) . . . . ?
N2 Zn4 N3 C33 170.11(12) . . . . ?
Zn4 O4 N4 C43 54.15(18) . . . . ?
Zn1 O4 N4 C43 -174.81(12) . . . . ?
Zn4 O4 N4 C41 173.54(13) . . . . ?
Zn1 O4 N4 C41 -55.42(17) . . . . ?
Zn4 O4 N4 Zn2 -72.51(12) . . . . ?
Zn1 O4 N4 Zn2 58.53(11) . . . . ?
C2 Zn2 N4 O4 170.29(12) . . . . ?
O1 Zn2 N4 O4 -54.74(11) . . . . ?
O2 Zn2 N4 O4 34.34(12) . . . . ?
C2 Zn2 N4 C43 51.60(18) . . . . ?
O1 Zn2 N4 C43 -173.42(15) . . . . ?
O2 Zn2 N4 C43 -84.35(16) . . . . ?
C2 Zn2 N4 C41 -77.39(16) . . . . ?
O1 Zn2 N4 C41 57.58(13) . . . . ?
O2 Zn2 N4 C41 146.66(13) . . . . ?
O1 N1 C11 C12 58.2(2) . . . . ?
C13 N1 C11 C12 -57.7(3) . . . . ?
Zn3 N1 C11 C12 171.21(18) . . . . ?
O1 N1 C13 C14 -175.12(17) . . . . ?
C11 N1 C13 C14 -57.9(2) . . . . ?
Zn3 N1 C13 C14 70.5(2) . . . . ?
O2 N2 C21 C22 -63.3(2) . . . . ?
C23 N2 C21 C22 50.8(3) . . . . ?
Zn4 N2 C21 C22 -177.97(17) . . . . ?
O2 N2 C23 C24 178.80(18) . . . . ?
C21 N2 C23 C24 62.7(2) . . . . ?
Zn4 N2 C23 C24 -65.2(2) . . . . ?
O3 N3 C31 C32 -176.59(18) . . . . ?
C33 N3 C31 C32 68.4(2) . . . . ?
Zn4 N3 C31 C32 -54.2(2) . . . . ?
O3 N3 C33 C34 -59.2(2) . . . . ?
C31 N3 C33 C34 55.4(3) . . . . ?
Zn4 N3 C33 C34 -173.25(17) . . . . ?
O4 N4 C41 C42 -176.92(19) . . . . ?
C43 N4 C41 C42 -60.3(3) . . . . ?
Zn2 N4 C41 C42 72.9(2) . . . . ?
O4 N4 C43 C44 63.6(2) . . . . ?
C41 N4 C43 C44 -52.3(3) . . . . ?
Zn2 N4 C43 C44 -179.94(17) . . . . ?
