#------------------------------------------------------------------------------
#$Date: 2016-03-25 13:34:00 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179851 $
#$URL: svn://www.crystallography.net/cod/cif/7/01/47/7014738.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7014738
loop_
_publ_author_name
'Traut, Stephan'
'Hähnel, Alexander Peter'
'von Hänisch, Carsten'
_publ_section_title
;
 Dichloro organosilicon bismuthanes as precursors for rare compounds
 with a bismuth-pnictogen or bismuth-tellurium bond.
;
_journal_issue                   6
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              1365
_journal_page_last               1371
_journal_paper_doi               10.1039/c0dt01111h
_journal_volume                  40
_journal_year                    2011
_chemical_formula_moiety         'C10 H27 Bi Cl2 Si3'
_chemical_formula_sum            'C10 H27 Bi Cl2 Si3'
_chemical_formula_weight         511.47
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                117.33(3)
_cell_angle_beta                 101.66(3)
_cell_angle_gamma                91.24(3)
_cell_formula_units_Z            4
_cell_length_a                   8.8348(18)
_cell_length_b                   15.403(3)
_cell_length_c                   16.015(3)
_cell_measurement_reflns_used    1081
_cell_measurement_temperature    180(2)
_cell_measurement_theta_max      26.13
_cell_measurement_theta_min      1.33
_cell_volume                     1879.7(9)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      180(2)
_diffrn_measured_fraction_theta_full 0.936
_diffrn_measured_fraction_theta_max 0.936
_diffrn_measurement_device_type  'STOE IPDS 2'
_diffrn_measurement_method       'rotation method'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0769
_diffrn_reflns_av_sigmaI/netI    0.0680
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            11994
_diffrn_reflns_theta_full        25.59
_diffrn_reflns_theta_max         25.59
_diffrn_reflns_theta_min         1.47
_exptl_absorpt_coefficient_mu    9.836
_exptl_absorpt_correction_T_max  0.2361
_exptl_absorpt_correction_T_min  0.0632
_exptl_absorpt_correction_type   integration
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.807
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             984
_exptl_crystal_size_max          0.407
_exptl_crystal_size_mid          0.384
_exptl_crystal_size_min          0.159
_refine_diff_density_max         4.664
_refine_diff_density_min         -4.650
_refine_diff_density_rms         0.337
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.075
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     289
_refine_ls_number_reflns         6628
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.075
_refine_ls_R_factor_all          0.0707
_refine_ls_R_factor_gt           0.0645
_refine_ls_shift/su_max          0.008
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1258P)²+1.4202P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1721
_refine_ls_wR_factor_ref         0.1774
_reflns_number_gt                5790
_reflns_number_total             6628
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            C0DT01111H.TXT
_cod_data_source_block           e:\traut\crystal\st243\p-1
_cod_original_cell_volume        1879.6(7)
_cod_database_code               7014738
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Si1 Si 0.9395(3) 0.7262(3) 0.7875(2) 0.0418(7) Uani 1 1 d . . .
Si2 Si 1.2020(3) 0.8960(2) 0.83138(19) 0.0398(6) Uani 1 1 d . . .
Si3 Si 1.2383(3) 0.6713(2) 0.7026(2) 0.0409(7) Uani 1 1 d . . .
Si4 Si 0.6330(3) 0.7359(2) 0.26106(19) 0.0372(6) Uani 1 1 d . . .
Si5 Si 0.2885(3) 0.6319(2) 0.15019(19) 0.0392(6) Uani 1 1 d . . .
Si6 Si 0.3521(3) 0.8634(2) 0.28515(19) 0.0357(6) Uani 1 1 d . . .
Cl1 Cl 0.7495(3) 0.8446(2) 0.63755(19) 0.0491(6) Uani 1 1 d . . .
Cl2 Cl 1.1225(4) 0.8849(3) 0.5889(2) 0.0588(8) Uani 1 1 d . . .
Cl3 Cl 0.5329(4) 0.5995(3) 0.3989(2) 0.0559(7) Uani 1 1 d . . .
Cl4 Cl 0.1366(3) 0.6503(2) 0.3594(2) 0.0501(6) Uani 1 1 d . . .
Bi1 Bi 0.97196(4) 0.75029(3) 0.59350(2) 0.03721(16) Uani 1 1 d . . .
Bi2 Bi 0.40185(4) 0.74260(3) 0.40691(2) 0.03448(16) Uani 1 1 d . . .
C1 C 1.0956(11) 0.7687(8) 0.7415(6) 0.035(2) Uani 1 1 d . . .
C2 C 0.7839(14) 0.6317(10) 0.6854(10) 0.055(3) Uani 1 1 d . . .
H2A H 0.8307 0.5740 0.6464 0.066 Uiso 1 1 calc R . .
H2B H 0.7330 0.6598 0.6448 0.066 Uiso 1 1 calc R . .
H2C H 0.7065 0.6118 0.7114 0.066 Uiso 1 1 calc R . .
C3 C 0.8349(15) 0.8266(12) 0.8586(9) 0.063(4) Uani 1 1 d . . .
H3A H 0.7833 0.8550 0.8185 0.076 Uiso 1 1 calc R . .
H3B H 0.9092 0.8778 0.9155 0.076 Uiso 1 1 calc R . .
H3C H 0.7566 0.8002 0.8794 0.076 Uiso 1 1 calc R . .
C4 C 1.0230(14) 0.6750(12) 0.8702(10) 0.058(3) Uani 1 1 d . . .
H4A H 1.0988 0.7257 0.9267 0.070 Uiso 1 1 calc R . .
H4B H 1.0749 0.6180 0.8356 0.070 Uiso 1 1 calc R . .
H4C H 0.9390 0.6544 0.8915 0.070 Uiso 1 1 calc R . .
C5 C 1.3897(12) 0.6792(10) 0.8078(8) 0.050(3) Uani 1 1 d . . .
H5A H 1.3381 0.6689 0.8519 0.060 Uiso 1 1 calc R . .
H5B H 1.4518 0.7445 0.8423 0.060 Uiso 1 1 calc R . .
H5C H 1.4579 0.6284 0.7840 0.060 Uiso 1 1 calc R . .
C6 C 1.1304(16) 0.5416(10) 0.6356(10) 0.060(3) Uani 1 1 d . . .
H6A H 1.0547 0.5333 0.5777 0.072 Uiso 1 1 calc R . .
H6B H 1.0757 0.5303 0.6779 0.072 Uiso 1 1 calc R . .
H6C H 1.2050 0.4941 0.6165 0.072 Uiso 1 1 calc R . .
C7 C 1.3407(15) 0.6806(13) 0.6150(9) 0.065(4) Uani 1 1 d . . .
H7A H 1.4011 0.7461 0.6451 0.078 Uiso 1 1 calc R . .
H7B H 1.2636 0.6705 0.5569 0.078 Uiso 1 1 calc R . .
H7C H 1.4110 0.6302 0.5971 0.078 Uiso 1 1 calc R . .
C8 C 1.3884(13) 0.9230(10) 0.8062(9) 0.054(3) Uani 1 1 d . . .
H8A H 1.3680 0.9181 0.7416 0.065 Uiso 1 1 calc R . .
H8B H 1.4583 0.8754 0.8090 0.065 Uiso 1 1 calc R . .
H8C H 1.4374 0.9898 0.8547 0.065 Uiso 1 1 calc R . .
C9 C 1.0820(15) 0.9964(9) 0.8372(8) 0.052(3) Uani 1 1 d . . .
H9A H 0.9870 0.9881 0.8570 0.063 Uiso 1 1 calc R . .
H9B H 1.0537 0.9931 0.7733 0.063 Uiso 1 1 calc R . .
H9C H 1.1423 1.0606 0.8844 0.063 Uiso 1 1 calc R . .
C10 C 1.2588(18) 0.9071(10) 0.9556(8) 0.061(4) Uani 1 1 d . . .
H10C H 1.3137 0.9733 1.0016 0.073 Uiso 1 1 calc R . .
H10B H 1.3275 0.8578 0.9550 0.073 Uiso 1 1 calc R . .
H10A H 1.1650 0.8961 0.9751 0.073 Uiso 1 1 calc R . .
C11 C 0.4173(10) 0.7387(7) 0.2636(6) 0.0306(19) Uani 1 1 d . . .
C12 C 0.1804(13) 0.8868(9) 0.3430(8) 0.047(3) Uani 1 1 d . . .
H12A H 0.2101 0.8869 0.4054 0.056 Uiso 1 1 calc R . .
H12B H 0.0931 0.8348 0.3005 0.056 Uiso 1 1 calc R . .
H12C H 0.1489 0.9509 0.3532 0.056 Uiso 1 1 calc R . .
C13 C 0.5104(15) 0.9661(8) 0.3727(8) 0.048(3) Uani 1 1 d . . .
H13A H 0.6032 0.9582 0.3464 0.057 Uiso 1 1 calc R . .
H13B H 0.5360 0.9645 0.4344 0.057 Uiso 1 1 calc R . .
H13C H 0.4749 1.0293 0.3831 0.057 Uiso 1 1 calc R . .
C14 C 0.2981(14) 0.8761(10) 0.1718(8) 0.050(3) Uani 1 1 d . . .
H14A H 0.2123 0.8248 0.1252 0.060 Uiso 1 1 calc R . .
H14B H 0.3885 0.8691 0.1435 0.060 Uiso 1 1 calc R . .
H14C H 0.2653 0.9412 0.1877 0.060 Uiso 1 1 calc R . .
C15 C 0.0773(13) 0.6481(10) 0.1298(8) 0.048(3) Uani 1 1 d . . .
H15A H 0.0648 0.7078 0.1231 0.058 Uiso 1 1 calc R . .
H15B H 0.0381 0.6542 0.1850 0.058 Uiso 1 1 calc R . .
H15C H 0.0184 0.5908 0.0707 0.058 Uiso 1 1 calc R . .
C16 C 0.3477(15) 0.6208(11) 0.0400(8) 0.057(3) Uani 1 1 d . . .
H16A H 0.4567 0.6084 0.0441 0.068 Uiso 1 1 calc R . .
H16B H 0.3366 0.6822 0.0363 0.068 Uiso 1 1 calc R . .
H16C H 0.2810 0.5660 -0.0180 0.068 Uiso 1 1 calc R . .
C17 C 0.3018(15) 0.5098(9) 0.1490(9) 0.055(3) Uani 1 1 d . . .
H17A H 0.2691 0.5124 0.2050 0.067 Uiso 1 1 calc R . .
H17B H 0.4097 0.4953 0.1522 0.067 Uiso 1 1 calc R . .
H17C H 0.2336 0.4579 0.0893 0.067 Uiso 1 1 calc R . .
C18 C 0.6847(12) 0.7941(11) 0.1886(8) 0.048(3) Uani 1 1 d . . .
H18A H 0.6648 0.8629 0.2176 0.058 Uiso 1 1 calc R . .
H18B H 0.6211 0.7582 0.1220 0.058 Uiso 1 1 calc R . .
H18C H 0.7953 0.7915 0.1881 0.058 Uiso 1 1 calc R . .
C19 C 0.6888(14) 0.6093(10) 0.2099(8) 0.056(3) Uani 1 1 d . . .
H19A H 0.6265 0.5696 0.1435 0.067 Uiso 1 1 calc R . .
H19B H 0.6698 0.5790 0.2495 0.067 Uiso 1 1 calc R . .
H19C H 0.7997 0.6125 0.2098 0.067 Uiso 1 1 calc R . .
C20 C 0.7664(14) 0.8042(10) 0.3825(8) 0.054(3) Uani 1 1 d . . .
H20A H 0.7463 0.7755 0.4233 0.064 Uiso 1 1 calc R . .
H20B H 0.7491 0.8735 0.4120 0.064 Uiso 1 1 calc R . .
H20C H 0.8746 0.7997 0.3766 0.064 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Bi Bi -4.1077 10.2566 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C3 Si1 C2 104.9(6) . . ?
C3 Si1 C4 104.8(7) . . ?
C2 Si1 C4 108.8(6) . . ?
C3 Si1 C1 113.4(6) . . ?
C2 Si1 C1 111.7(5) . . ?
C4 Si1 C1 112.7(5) . . ?
C8 Si2 C9 107.4(6) . . ?
C8 Si2 C10 104.7(6) . . ?
C9 Si2 C10 108.2(6) . . ?
C8 Si2 C1 113.4(5) . . ?
C9 Si2 C1 112.7(5) . . ?
C10 Si2 C1 110.1(6) . . ?
C7 Si3 C5 108.3(5) . . ?
C7 Si3 C6 104.6(7) . . ?
C5 Si3 C6 107.1(6) . . ?
C7 Si3 C1 112.1(6) . . ?
C5 Si3 C1 113.0(5) . . ?
C6 Si3 C1 111.2(5) . . ?
C7 Si3 Bi1 80.2(4) . . ?
C5 Si3 Bi1 155.5(4) . . ?
C6 Si3 Bi1 92.2(4) . . ?
C1 Si3 Bi1 44.0(3) . . ?
C20 Si4 C19 104.9(6) . . ?
C20 Si4 C18 106.0(6) . . ?
C19 Si4 C18 107.9(6) . . ?
C20 Si4 C11 113.3(5) . . ?
C19 Si4 C11 113.3(5) . . ?
C18 Si4 C11 111.0(5) . . ?
C15 Si5 C16 105.0(5) . . ?
C15 Si5 C17 107.2(6) . . ?
C16 Si5 C17 107.2(6) . . ?
C15 Si5 C11 113.9(5) . . ?
C16 Si5 C11 109.8(5) . . ?
C17 Si5 C11 113.1(5) . . ?
C13 Si6 C14 107.4(6) . . ?
C13 Si6 C12 105.5(6) . . ?
C14 Si6 C12 108.5(5) . . ?
C13 Si6 C11 110.5(5) . . ?
C14 Si6 C11 113.5(5) . . ?
C12 Si6 C11 111.0(5) . . ?
C13 Si6 Bi2 94.2(4) . . ?
C14 Si6 Bi2 154.8(4) . . ?
C12 Si6 Bi2 76.9(4) . . ?
C11 Si6 Bi2 44.4(3) . . ?
C1 Bi1 Cl2 100.8(3) . . ?
C1 Bi1 Cl1 99.8(3) . . ?
Cl2 Bi1 Cl1 94.15(12) . . ?
C1 Bi1 Si3 36.2(3) . . ?
Cl2 Bi1 Si3 102.48(10) . . ?
Cl1 Bi1 Si3 134.91(9) . . ?
C11 Bi2 Cl3 102.1(3) . . ?
C11 Bi2 Cl4 100.8(2) . . ?
Cl3 Bi2 Cl4 92.72(11) . . ?
C11 Bi2 Si6 35.6(2) . . ?
Cl3 Bi2 Si6 136.88(9) . . ?
Cl4 Bi2 Si6 101.88(9) . . ?
Si2 C1 Si1 113.0(5) . . ?
Si2 C1 Si3 111.9(5) . . ?
Si1 C1 Si3 110.1(5) . . ?
Si2 C1 Bi1 115.4(5) . . ?
Si1 C1 Bi1 105.8(4) . . ?
Si3 C1 Bi1 99.7(4) . . ?
Si5 C11 Si6 112.1(4) . . ?
Si5 C11 Si4 111.4(5) . . ?
Si6 C11 Si4 112.0(5) . . ?
Si5 C11 Bi2 115.0(5) . . ?
Si6 C11 Bi2 100.0(4) . . ?
Si4 C11 Bi2 105.7(4) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Si1 C3 1.847(13) . ?
Si1 C2 1.872(12) . ?
Si1 C4 1.874(12) . ?
Si1 C1 1.919(11) . ?
Si2 C8 1.855(13) . ?
Si2 C9 1.872(13) . ?
Si2 C10 1.875(11) . ?
Si2 C1 1.892(11) . ?
Si3 C7 1.872(14) . ?
Si3 C5 1.879(11) . ?
Si3 C6 1.893(14) . ?
Si3 C1 1.943(11) . ?
Si3 Bi1 3.239(3) . ?
Si4 C20 1.849(12) . ?
Si4 C19 1.859(13) . ?
Si4 C18 1.874(12) . ?
Si4 C11 1.915(9) . ?
Si5 C15 1.870(11) . ?
Si5 C16 1.876(12) . ?
Si5 C17 1.879(14) . ?
Si5 C11 1.908(9) . ?
Si6 C13 1.870(12) . ?
Si6 C14 1.882(11) . ?
Si6 C12 1.891(11) . ?
Si6 C11 1.913(10) . ?
Si6 Bi2 3.237(3) . ?
Cl1 Bi1 2.493(3) . ?
Cl2 Bi1 2.476(3) . ?
Cl3 Bi2 2.476(3) . ?
Cl4 Bi2 2.497(3) . ?
Bi1 C1 2.284(9) . ?
Bi2 C11 2.301(9) . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C7 Si3 Bi1 C1 -136.9(7) . . . . ?
C5 Si3 Bi1 C1 -24.0(10) . . . . ?
C6 Si3 Bi1 C1 118.7(7) . . . . ?
C7 Si3 Bi1 Cl2 -45.6(6) . . . . ?
C5 Si3 Bi1 Cl2 67.3(10) . . . . ?
C6 Si3 Bi1 Cl2 -150.0(5) . . . . ?
C1 Si3 Bi1 Cl2 91.3(5) . . . . ?
C7 Si3 Bi1 Cl1 -154.6(6) . . . . ?
C5 Si3 Bi1 Cl1 -41.7(10) . . . . ?
C6 Si3 Bi1 Cl1 101.0(5) . . . . ?
C1 Si3 Bi1 Cl1 -17.7(5) . . . . ?
C13 Si6 Bi2 C11 -115.3(6) . . . . ?
C14 Si6 Bi2 C11 34.1(10) . . . . ?
C12 Si6 Bi2 C11 139.7(6) . . . . ?
C13 Si6 Bi2 Cl3 -100.0(4) . . . . ?
C14 Si6 Bi2 Cl3 49.3(9) . . . . ?
C12 Si6 Bi2 Cl3 155.0(4) . . . . ?
C11 Si6 Bi2 Cl3 15.3(4) . . . . ?
C13 Si6 Bi2 Cl4 152.8(4) . . . . ?
C14 Si6 Bi2 Cl4 -57.9(9) . . . . ?
C12 Si6 Bi2 Cl4 47.8(4) . . . . ?
C11 Si6 Bi2 Cl4 -91.9(4) . . . . ?
C8 Si2 C1 Si1 162.6(5) . . . . ?
C9 Si2 C1 Si1 -75.2(7) . . . . ?
C10 Si2 C1 Si1 45.7(7) . . . . ?
C8 Si2 C1 Si3 37.6(7) . . . . ?
C9 Si2 C1 Si3 159.8(6) . . . . ?
C10 Si2 C1 Si3 -79.3(7) . . . . ?
C8 Si2 C1 Bi1 -75.5(6) . . . . ?
C9 Si2 C1 Bi1 46.7(7) . . . . ?
C10 Si2 C1 Bi1 167.6(6) . . . . ?
C3 Si1 C1 Si2 37.1(7) . . . . ?
C2 Si1 C1 Si2 155.5(6) . . . . ?
C4 Si1 C1 Si2 -81.7(7) . . . . ?
C3 Si1 C1 Si3 163.1(5) . . . . ?
C2 Si1 C1 Si3 -78.6(6) . . . . ?
C4 Si1 C1 Si3 44.2(7) . . . . ?
C3 Si1 C1 Bi1 -90.0(6) . . . . ?
C2 Si1 C1 Bi1 28.3(7) . . . . ?
C4 Si1 C1 Bi1 151.1(6) . . . . ?
C7 Si3 C1 Si2 -75.9(7) . . . . ?
C5 Si3 C1 Si2 46.9(7) . . . . ?
C6 Si3 C1 Si2 167.4(6) . . . . ?
Bi1 Si3 C1 Si2 -122.6(7) . . . . ?
C7 Si3 C1 Si1 157.6(6) . . . . ?
C5 Si3 C1 Si1 -79.7(6) . . . . ?
C6 Si3 C1 Si1 40.9(7) . . . . ?
Bi1 Si3 C1 Si1 110.9(6) . . . . ?
C7 Si3 C1 Bi1 46.7(7) . . . . ?
C5 Si3 C1 Bi1 169.4(5) . . . . ?
C6 Si3 C1 Bi1 -70.0(7) . . . . ?
Cl2 Bi1 C1 Si2 23.6(5) . . . . ?
Cl1 Bi1 C1 Si2 -72.6(5) . . . . ?
Si3 Bi1 C1 Si2 120.1(7) . . . . ?
Cl2 Bi1 C1 Si1 149.3(4) . . . . ?
Cl1 Bi1 C1 Si1 53.1(5) . . . . ?
Si3 Bi1 C1 Si1 -114.3(7) . . . . ?
Cl2 Bi1 C1 Si3 -96.4(4) . . . . ?
Cl1 Bi1 C1 Si3 167.4(3) . . . . ?
C15 Si5 C11 Si6 -37.3(7) . . . . ?
C16 Si5 C11 Si6 80.1(6) . . . . ?
C17 Si5 C11 Si6 -160.1(6) . . . . ?
C15 Si5 C11 Si4 -163.7(6) . . . . ?
C16 Si5 C11 Si4 -46.3(7) . . . . ?
C17 Si5 C11 Si4 73.5(7) . . . . ?
C15 Si5 C11 Bi2 76.0(6) . . . . ?
C16 Si5 C11 Bi2 -166.5(5) . . . . ?
C17 Si5 C11 Bi2 -46.8(7) . . . . ?
C13 Si6 C11 Si5 -163.4(5) . . . . ?
C14 Si6 C11 Si5 -42.6(7) . . . . ?
C12 Si6 C11 Si5 79.9(6) . . . . ?
Bi2 Si6 C11 Si5 122.3(6) . . . . ?
C13 Si6 C11 Si4 -37.3(6) . . . . ?
C14 Si6 C11 Si4 83.5(6) . . . . ?
C12 Si6 C11 Si4 -154.0(5) . . . . ?
Bi2 Si6 C11 Si4 -111.6(5) . . . . ?
C13 Si6 C11 Bi2 74.4(5) . . . . ?
C14 Si6 C11 Bi2 -164.9(5) . . . . ?
C12 Si6 C11 Bi2 -42.4(5) . . . . ?
C20 Si4 C11 Si5 -158.2(6) . . . . ?
C19 Si4 C11 Si5 -38.8(7) . . . . ?
C18 Si4 C11 Si5 82.8(7) . . . . ?
C20 Si4 C11 Si6 75.4(7) . . . . ?
C19 Si4 C11 Si6 -165.3(5) . . . . ?
C18 Si4 C11 Si6 -43.7(6) . . . . ?
C20 Si4 C11 Bi2 -32.6(7) . . . . ?
C19 Si4 C11 Bi2 86.7(6) . . . . ?
C18 Si4 C11 Bi2 -151.7(5) . . . . ?
Cl3 Bi2 C11 Si5 70.4(4) . . . . ?
Cl4 Bi2 C11 Si5 -24.8(5) . . . . ?
Si6 Bi2 C11 Si5 -120.2(6) . . . . ?
Cl3 Bi2 C11 Si6 -169.4(3) . . . . ?
Cl4 Bi2 C11 Si6 95.4(3) . . . . ?
Cl3 Bi2 C11 Si4 -53.0(4) . . . . ?
Cl4 Bi2 C11 Si4 -148.2(4) . . . . ?
Si6 Bi2 C11 Si4 116.4(6) . . . . ?
