#------------------------------------------------------------------------------
#$Date: 2016-03-25 13:41:51 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179858 $
#$URL: svn://www.crystallography.net/cod/cif/7/01/54/7015492.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7015492
loop_
_publ_author_name
'Xu, Hai-Bing'
'Li, Jia'
'Shi, Lin-Xi'
'Chen, Zhong-Ning'
_publ_section_title
;
 Sensitized luminescence in dinuclear lanthanide(iii) complexes of
 bridging 8-hydroxyquinoline derivatives with different electronic
 properties.
;
_journal_issue                   20
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              5549
_journal_page_last               5556
_journal_paper_doi               10.1039/c0dt01663b
_journal_volume                  40
_journal_year                    2011
_chemical_formula_sum            'C62 H40 Eu2 F36 N2 O18'
_chemical_formula_weight         2088.88
_chemical_name_systematic
;
?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 106.683(5)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   13.951(5)
_cell_length_b                   18.353(5)
_cell_length_c                   15.516(5)
_cell_measurement_reflns_used    11613
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      27.4855
_cell_measurement_theta_min      1.7322
_cell_volume                     3806(2)
_computing_cell_refinement       'Bruker XSCANS'
_computing_data_collection       'Bruker XSCANS'
_computing_data_reduction        'Bruker SHELXTL'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_detector_area_resol_mean 28.5714
_diffrn_measured_fraction_theta_full 0.977
_diffrn_measured_fraction_theta_max 0.977
_diffrn_measurement_device_type  'RIGAKU MERCURY CCD/AFC'
_diffrn_measurement_method       CCD_Profile_fitting
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0660
_diffrn_reflns_av_sigmaI/netI    0.0783
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            25742
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         1.73
_diffrn_standards_number         8970
_exptl_absorpt_coefficient_mu    1.788
_exptl_absorpt_correction_T_max  1.0000
_exptl_absorpt_correction_T_min  0.5648
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
R.H. Blessing, Acta Cryst. (1995), A51, 33-38
;
_exptl_crystal_colour            Yellow
_exptl_crystal_density_diffrn    1.823
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Prism
_exptl_crystal_F_000             2040
_exptl_crystal_size_max          0.24
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.15
_refine_diff_density_max         1.500
_refine_diff_density_min         -2.398
_refine_diff_density_rms         0.431
_refine_ls_extinction_coef       0.0093(9)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.167
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     650
_refine_ls_number_reflns         6560
_refine_ls_number_restraints     255
_refine_ls_restrained_S_all      1.167
_refine_ls_R_factor_all          0.0860
_refine_ls_R_factor_gt           0.0618
_refine_ls_shift/su_max          0.038
_refine_ls_shift/su_mean         0.004
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1409P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1594
_refine_ls_wR_factor_ref         0.2387
_reflns_number_gt                5474
_reflns_number_total             6560
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c0dt01663b.txt
_cod_data_source_block           x
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from
2010-06-29.

'_exptl_absorpt_correction_type' value 'Multi-scan' changed
to 'multi-scan' according to
'/home/saulius/struct/CIF-dictionaries/cif_core.dic' dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1555 2011-01-17 13:19:09Z saulius 
;
_cod_original_sg_symbol_H-M      P2(1)/n
_cod_database_code               7015492
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.93587(3) 1.02908(2) 0.09787(2) 0.0313(3) Uani 1 1 d . . .
O1 O 0.7886(5) 0.9488(4) 0.0587(5) 0.0492(16) Uani 1 1 d . . .
O2 O 0.9425(5) 0.9430(4) 0.2173(4) 0.0480(16) Uani 1 1 d . . .
O3 O 0.8101(5) 1.0730(4) -0.0332(4) 0.0439(15) Uani 1 1 d . . .
O4 O 0.8026(5) 1.0772(4) 0.1515(5) 0.0492(16) Uani 1 1 d . . .
O5 O 0.9364(4) 1.1634(4) 0.0931(4) 0.0449(17) Uani 1 1 d . . .
O6 O 1.0195(5) 1.0830(3) 0.2436(4) 0.0470(16) Uani 1 1 d . . .
O7 O 0.9635(4) 0.9310(3) -0.0008(4) 0.0313(12) Uani 1 1 d . . .
O8 O 1.1172(5) 0.9907(4) 0.1615(4) 0.0392(14) Uani 1 1 d . . .
O9 O 0.1614(7) 0.9475(6) 0.3340(6) 0.082(3) Uani 1 1 d U . .
C1 C 0.6886(10) 0.8945(8) -0.2765(9) 0.095(6) Uani 1 1 d . . .
H1B H 0.7228 0.9405 -0.2671 0.142 Uiso 1 1 calc R . .
H1C H 0.6197 0.9016 -0.2792 0.142 Uiso 1 1 calc R . .
H1D H 0.6928 0.8735 -0.3320 0.142 Uiso 1 1 calc R . .
C2 C 0.7370(8) 0.8436(6) -0.1995(7) 0.056(3) Uani 1 1 d . . .
C3 C 0.7037(9) 0.7721(6) -0.1922(8) 0.069(3) Uani 1 1 d . . .
H3A H 0.6499 0.7540 -0.2376 0.082 Uiso 1 1 calc R . .
C4 C 0.7476(8) 0.7288(6) -0.1209(7) 0.053(3) Uani 1 1 d . . .
H4A H 0.7270 0.6807 -0.1193 0.063 Uiso 1 1 calc R . .
C5 C 0.8243(6) 0.7575(5) -0.0496(6) 0.0399(19) Uani 1 1 d . . .
C6 C 0.8739(7) 0.7178(5) 0.0322(6) 0.043(2) Uani 1 1 d . . .
C7 C 0.8428(7) 0.6380(5) 0.0421(6) 0.045(2) Uani 1 1 d . . .
C8 C 0.7434(10) 0.6226(6) 0.0454(7) 0.061(3) Uani 1 1 d . . .
H8A H 0.6959 0.6595 0.0371 0.074 Uiso 1 1 calc R . .
C9 C 0.7206(11) 0.5552(8) 0.0607(8) 0.075(4) Uani 1 1 d . . .
H9A H 0.6582 0.5465 0.0690 0.090 Uiso 1 1 calc R . .
C10 C 0.7840(11) 0.4962(7) 0.0649(9) 0.077(4) Uani 1 1 d . . .
H10A H 0.7631 0.4488 0.0706 0.093 Uiso 1 1 calc R . .
C11 C 0.8769(15) 0.5104(8) 0.0606(12) 0.099(5) Uani 1 1 d . . .
H11B H 0.9221 0.4725 0.0643 0.119 Uiso 1 1 calc R . .
C12 C 0.9066(10) 0.5839(6) 0.0502(10) 0.071(3) Uani 1 1 d . . .
H12A H 0.9718 0.5935 0.0492 0.085 Uiso 1 1 calc R . .
C13 C 0.9478(8) 0.7506(6) 0.0935(6) 0.047(2) Uani 1 1 d . . .
H13A H 0.9791 0.7249 0.1456 0.056 Uiso 1 1 calc R . .
C14 C 0.9809(6) 0.8194(5) 0.0850(5) 0.0376(19) Uani 1 1 d . . .
H14A H 1.0345 0.8375 0.1305 0.045 Uiso 1 1 calc R . .
C15 C 0.9381(6) 0.8635(5) 0.0113(6) 0.0364(18) Uani 1 1 d . . .
C16 C 0.8578(6) 0.8300(5) -0.0563(5) 0.0323(17) Uani 1 1 d . . .
N1 N 0.8107(6) 0.8703(4) -0.1308(5) 0.0444(18) Uani 1 1 d . . .
C101 C 0.6435(8) 0.8838(6) 0.0525(8) 0.078(4) Uani 1 1 d D . .
F1 F 0.6243(16) 0.8911(13) -0.0355(9) 0.115(6) Uani 0.50 1 d PDU A 2
F2 F 0.5748(14) 0.9232(12) 0.0727(16) 0.117(6) Uani 0.50 1 d PDU A 2
F3 F 0.6220(15) 0.8156(7) 0.0656(16) 0.124(7) Uani 0.50 1 d PDU A 2
F1A F 0.6400(15) 0.8458(11) -0.0202(11) 0.114(6) Uani 0.50 1 d PDU A 1
F2A F 0.5838(13) 0.9397(9) 0.0224(15) 0.107(6) Uani 0.50 1 d PDU A 1
F3A F 0.5964(15) 0.8448(11) 0.0992(14) 0.117(6) Uani 0.50 1 d PDU A 1
C102 C 0.7498(8) 0.9071(6) 0.1039(9) 0.061(3) Uani 1 1 d . A .
C103 C 0.7870(9) 0.8828(7) 0.1894(8) 0.061(3) Uani 1 1 d . . .
H10C H 0.7481 0.8528 0.2141 0.073 Uiso 1 1 calc R A .
C104 C 0.8844(9) 0.9023(5) 0.2415(7) 0.051(3) Uani 1 1 d . A .
C105 C 0.9230(11) 0.8700(8) 0.3336(9) 0.075(4) Uani 1 1 d . . .
F4 F 0.8578(7) 0.8364(6) 0.3646(6) 0.114(3) Uani 1 1 d . A 1
F5 F 0.9683(10) 0.9186(6) 0.3947(5) 0.128(4) Uani 1 1 d . A 1
F6 F 0.9939(7) 0.8212(6) 0.3339(6) 0.115(3) Uani 1 1 d . A 1
C106 C 0.6713(8) 1.1203(8) -0.1371(8) 0.095(5) Uani 1 1 d D . .
F7 F 0.6824(18) 1.0799(14) -0.2033(11) 0.135(8) Uani 0.50 1 d PDU B 2
F8 F 0.5737(9) 1.1295(13) -0.1567(17) 0.113(7) Uani 0.50 1 d PDU B 2
F9 F 0.7031(18) 1.1858(11) -0.1545(16) 0.160(9) Uani 0.50 1 d PDU B 2
F7A F 0.6305(17) 1.0596(9) -0.1788(13) 0.133(7) Uani 0.50 1 d PDU B 1
F8A F 0.5965(14) 1.1659(12) -0.153(2) 0.140(9) Uani 0.50 1 d PDU B 1
F9A F 0.7270(14) 1.1423(15) -0.1876(13) 0.126(8) Uani 0.50 1 d PDU B 1
C107 C 0.7248(8) 1.1011(7) -0.0432(8) 0.062(3) Uani 1 1 d . B .
C108 C 0.6803(9) 1.1184(7) 0.0227(7) 0.062(3) Uani 1 1 d . . .
H10B H 0.6182 1.1412 0.0046 0.074 Uiso 1 1 calc R B .
C109 C 0.7196(8) 1.1049(6) 0.1118(7) 0.050(2) Uani 1 1 d . B .
C110 C 0.6569(10) 1.1232(8) 0.1764(8) 0.071(4) Uani 1 1 d . . .
F10 F 0.5729(6) 1.1623(7) 0.1356(6) 0.120(4) Uani 1 1 d . B 1
F11 F 0.7098(7) 1.1712(8) 0.2383(6) 0.140(5) Uani 1 1 d . B 1
F12 F 0.6363(10) 1.0719(7) 0.2161(8) 0.143(5) Uani 1 1 d . B 1
C111 C 0.9054(7) 1.2863(6) 0.1111(6) 0.065(3) Uani 1 1 d DU . .
F13 F 0.8159(13) 1.2859(10) 0.0517(14) 0.152(11) Uani 0.50 1 d PDU C 2
F14 F 0.9651(17) 1.3183(9) 0.0725(17) 0.119(8) Uani 0.50 1 d PDU C 2
F15 F 0.8925(16) 1.3343(7) 0.1712(10) 0.083(6) Uani 0.50 1 d PDU C 2
F13A F 0.8715(19) 1.2882(9) 0.0233(7) 0.124(9) Uani 0.50 1 d PDU C 1
F14A F 0.9843(13) 1.3314(8) 0.1278(14) 0.113(7) Uani 0.50 1 d PDU C 1
F15A F 0.8416(16) 1.3209(10) 0.1429(15) 0.118(9) Uani 0.50 1 d PDU C 1
C112 C 0.9365(7) 1.2131(5) 0.1488(6) 0.049(2) Uani 1 1 d DU C .
C113 C 0.9677(9) 1.2052(6) 0.2420(7) 0.059(3) Uani 1 1 d . . .
H11A H 0.9600 1.2441 0.2780 0.070 Uiso 1 1 calc R C .
C114 C 1.0100(8) 1.1405(6) 0.2825(7) 0.053(3) Uani 1 1 d . C .
C115 C 1.0520(8) 1.1409(5) 0.3839(8) 0.078(4) Uani 1 1 d D . .
F16 F 0.9949(14) 1.1815(12) 0.4190(15) 0.101(8) Uani 0.50 1 d PDU C 2
F17 F 1.1418(12) 1.1704(14) 0.408(2) 0.161(12) Uani 0.50 1 d PDU C 2
F18 F 1.0595(19) 1.0762(8) 0.4218(18) 0.100(9) Uani 0.50 1 d PDU C 2
F16A F 1.0370(17) 1.1974(13) 0.4305(17) 0.115(10) Uani 0.50 1 d PDU C 1
F17A F 1.1501(10) 1.1298(14) 0.4085(17) 0.115(8) Uani 0.50 1 d PDU C 1
F18A F 1.013(2) 1.0835(12) 0.413(2) 0.117(11) Uani 0.50 1 d PDU C 1
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O3 Eu1 O4 73.9(2) . . ?
O3 Eu1 O2 136.3(2) . . ?
O4 Eu1 O2 80.7(2) . . ?
O3 Eu1 O6 133.3(2) . . ?
O4 Eu1 O6 75.1(2) . . ?
O2 Eu1 O6 69.6(2) . . ?
O3 Eu1 O7 77.8(2) . 3_775 ?
O4 Eu1 O7 137.6(2) . 3_775 ?
O2 Eu1 O7 139.9(2) . 3_775 ?
O6 Eu1 O7 104.1(2) . 3_775 ?
O3 Eu1 O1 68.8(2) . . ?
O4 Eu1 O1 68.4(2) . . ?
O2 Eu1 O1 69.1(2) . . ?
O6 Eu1 O1 128.0(2) . . ?
O7 Eu1 O1 127.8(2) 3_775 . ?
O3 Eu1 O7 85.8(2) . . ?
O4 Eu1 O7 139.1(2) . . ?
O2 Eu1 O7 91.2(2) . . ?
O6 Eu1 O7 139.0(2) . . ?
O7 Eu1 O7 67.4(2) 3_775 . ?
O1 Eu1 O7 71.2(2) . . ?
O3 Eu1 O5 69.4(2) . . ?
O4 Eu1 O5 69.7(2) . . ?
O2 Eu1 O5 132.6(2) . . ?
O6 Eu1 O5 67.5(2) . . ?
O7 Eu1 O5 71.06(19) 3_775 . ?
O1 Eu1 O5 127.0(2) . . ?
O7 Eu1 O5 135.16(18) . . ?
O3 Eu1 O8 145.5(2) . . ?
O4 Eu1 O8 138.5(2) . . ?
O2 Eu1 O8 72.9(2) . . ?
O6 Eu1 O8 66.0(2) . . ?
O7 Eu1 O8 68.82(19) 3_775 . ?
O1 Eu1 O8 126.8(2) . . ?
O7 Eu1 O8 73.87(19) . . ?
O5 Eu1 O8 106.2(2) . . ?
O3 Eu1 Eu1 80.11(15) . 3_775 ?
O4 Eu1 Eu1 153.87(16) . 3_775 ?
O2 Eu1 Eu1 118.11(17) . 3_775 ?
O6 Eu1 Eu1 126.92(17) . 3_775 ?
O7 Eu1 Eu1 33.84(13) 3_775 3_775 ?
O1 Eu1 Eu1 99.96(17) . 3_775 ?
O7 Eu1 Eu1 33.59(13) . 3_775 ?
O5 Eu1 Eu1 103.48(13) . 3_775 ?
O8 Eu1 Eu1 67.41(14) . 3_775 ?
C102 O1 Eu1 133.5(7) . . ?
C104 O2 Eu1 138.0(7) . . ?
C107 O3 Eu1 132.2(7) . . ?
C109 O4 Eu1 132.4(6) . . ?
C112 O5 Eu1 134.7(6) . . ?
C114 O6 Eu1 134.9(6) . . ?
C15 O7 Eu1 126.5(5) . 3_775 ?
C15 O7 Eu1 120.2(5) . . ?
Eu1 O7 Eu1 112.6(2) 3_775 . ?
N1 C2 C3 118.2(9) . . ?
N1 C2 C1 117.9(9) . . ?
C3 C2 C1 123.7(9) . . ?
C4 C3 C2 122.0(10) . . ?
C3 C4 C5 119.1(9) . . ?
C4 C5 C16 119.1(8) . . ?
C4 C5 C6 124.3(9) . . ?
C16 C5 C6 116.6(8) . . ?
C13 C6 C5 118.3(8) . . ?
C13 C6 C7 122.7(8) . . ?
C5 C6 C7 118.9(8) . . ?
C12 C7 C8 119.0(10) . . ?
C12 C7 C6 121.4(9) . . ?
C8 C7 C6 119.5(9) . . ?
C9 C8 C7 118.6(12) . . ?
C8 C9 C10 124.0(13) . . ?
C11 C10 C9 117.2(12) . . ?
C10 C11 C12 120.2(15) . . ?
C7 C12 C11 120.7(13) . . ?
C6 C13 C14 124.4(9) . . ?
C13 C14 C15 122.8(8) . . ?
O7 C15 C14 126.6(7) . . ?
O7 C15 C16 119.0(7) . . ?
C14 C15 C16 114.4(7) . . ?
N1 C16 C5 118.5(7) . . ?
N1 C16 C15 118.0(8) . . ?
C5 C16 C15 123.5(7) . . ?
C2 N1 C16 123.0(8) . . ?
F2 C101 F1A 130.4(18) . . ?
F2 C101 F3 105.8(11) . . ?
F1A C101 F3 71.0(12) . . ?
F2 C101 F2A 39.1(11) . . ?
F1A C101 F2A 104.1(12) . . ?
F3 C101 F2A 130.2(16) . . ?
F2 C101 F3A 69.8(12) . . ?
F1A C101 F3A 106.4(11) . . ?
F3 C101 F3A 39.5(11) . . ?
F2A C101 F3A 104.7(11) . . ?
F2 C101 F1 104.3(12) . . ?
F1A C101 F1 38.7(11) . . ?
F3 C101 F1 105.6(11) . . ?
F2A C101 F1 68.6(12) . . ?
F3A C101 F1 129.6(17) . . ?
F2 C101 C102 112.9(13) . . ?
F1A C101 C102 112.8(12) . . ?
F3 C101 C102 114.5(13) . . ?
F2A C101 C102 112.7(12) . . ?
F3A C101 C102 115.2(14) . . ?
F1 C101 C102 112.9(12) . . ?
O1 C102 C103 129.8(10) . . ?
O1 C102 C101 112.8(11) . . ?
C103 C102 C101 117.4(10) . . ?
C102 C103 C104 120.9(10) . . ?
O2 C104 C103 125.8(10) . . ?
O2 C104 C105 116.2(10) . . ?
C103 C104 C105 118.0(10) . . ?
F4 C105 F5 107.2(12) . . ?
F4 C105 F6 106.1(11) . . ?
F5 C105 F6 104.4(13) . . ?
F4 C105 C104 116.3(12) . . ?
F5 C105 C104 112.6(11) . . ?
F6 C105 C104 109.4(11) . . ?
F8A C106 F7 119(2) . . ?
F8A C106 F9A 105.6(12) . . ?
F7 C106 F9A 59.0(12) . . ?
F8A C106 F8 32.5(15) . . ?
F7 C106 F8 103.8(12) . . ?
F9A C106 F8 124.9(19) . . ?
F8A C106 F7A 103.7(13) . . ?
F7 C106 F7A 43.6(12) . . ?
F9A C106 F7A 102.2(12) . . ?
F8 C106 F7A 74.1(13) . . ?
F8A C106 F9 71.2(14) . . ?
F7 C106 F9 103.4(12) . . ?
F9A C106 F9 46.9(12) . . ?
F8 C106 F9 102.7(12) . . ?
F7A C106 F9 140.9(16) . . ?
F8A C106 C107 119.3(16) . . ?
F7 C106 C107 119.8(13) . . ?
F9A C106 C107 116.3(12) . . ?
F8 C106 C107 116.9(15) . . ?
F7A C106 C107 107.7(14) . . ?
F9 C106 C107 108.2(14) . . ?
O3 C107 C108 127.7(10) . . ?
O3 C107 C106 114.2(9) . . ?
C108 C107 C106 118.1(9) . . ?
C109 C108 C107 125.4(10) . . ?
O4 C109 C108 128.4(9) . . ?
O4 C109 C110 112.6(9) . . ?
C108 C109 C110 118.9(10) . . ?
F12 C110 F11 107.9(13) . . ?
F12 C110 F10 110.4(13) . . ?
F11 C110 F10 102.0(11) . . ?
F12 C110 C109 115.2(11) . . ?
F11 C110 C109 107.8(11) . . ?
F10 C110 C109 112.6(10) . . ?
F14 C111 F15A 123.6(15) . . ?
F14 C111 F13A 66.1(13) . . ?
F15A C111 F13A 107.4(11) . . ?
F14 C111 F13 106.5(12) . . ?
F15A C111 F13 69.8(13) . . ?
F13A C111 F13 44.5(13) . . ?
F14 C111 F15 104.9(11) . . ?
F15A C111 F15 33.5(12) . . ?
F13A C111 F15 129.0(14) . . ?
F13 C111 F15 101.6(11) . . ?
F14 C111 F14A 37.8(11) . . ?
F15A C111 F14A 103.8(11) . . ?
F13A C111 F14A 102.5(11) . . ?
F13 C111 F14A 134.1(15) . . ?
F15 C111 F14A 74.0(12) . . ?
F14 C111 C112 116.1(10) . . ?
F15A C111 C112 116.6(10) . . ?
F13A C111 C112 114.4(9) . . ?
F13 C111 C112 112.4(10) . . ?
F15 C111 C112 114.1(9) . . ?
F14A C111 C112 110.7(10) . . ?
O5 C112 C113 125.4(10) . . ?
O5 C112 C111 116.4(8) . . ?
C113 C112 C111 118.2(8) . . ?
C112 C113 C114 121.4(10) . . ?
O6 C114 C113 126.6(10) . . ?
O6 C114 C115 116.5(9) . . ?
C113 C114 C115 116.8(9) . . ?
F16A C115 F18 118(3) . . ?
F16A C115 F16 27.9(15) . . ?
F18 C115 F16 107.8(12) . . ?
F16A C115 F17 79.2(16) . . ?
F18 C115 F17 107.4(13) . . ?
F16 C115 F17 107.0(12) . . ?
F16A C115 F18A 107.1(13) . . ?
F18 C115 F18A 27.9(17) . . ?
F16 C115 F18A 87(2) . . ?
F17 C115 F18A 133(2) . . ?
F16A C115 F17A 106.2(11) . . ?
F18 C115 F17A 77.8(16) . . ?
F16 C115 F17A 131.7(16) . . ?
F17 C115 F17A 33.1(14) . . ?
F18A C115 F17A 105.7(12) . . ?
F16A C115 C114 120.1(15) . . ?
F18 C115 C114 114.6(15) . . ?
F16 C115 C114 109.4(13) . . ?
F17 C115 C114 110.3(17) . . ?
F18A C115 C114 105.9(15) . . ?
F17A C115 C114 111.0(14) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O3 2.411(6) . ?
Eu1 O4 2.412(6) . ?
Eu1 O2 2.417(6) . ?
Eu1 O6 2.436(6) . ?
Eu1 O7 2.447(6) 3_775 ?
Eu1 O1 2.459(7) . ?
Eu1 O7 2.464(6) . ?
Eu1 O5 2.467(7) . ?
Eu1 O8 2.538(6) . ?
Eu1 Eu1 4.0849(12) 3_775 ?
O1 C102 1.260(13) . ?
O2 C104 1.237(12) . ?
O3 C107 1.265(12) . ?
O4 C109 1.252(12) . ?
O5 C112 1.256(11) . ?
O6 C114 1.242(12) . ?
O7 C15 1.317(10) . ?
O7 Eu1 2.447(6) 3_775 ?
C1 C2 1.514(15) . ?
C2 N1 1.342(12) . ?
C2 C3 1.408(15) . ?
C3 C4 1.357(15) . ?
C4 C5 1.403(13) . ?
C5 C16 1.423(12) . ?
C5 C6 1.456(12) . ?
C6 C13 1.329(14) . ?
C6 C7 1.548(12) . ?
C7 C12 1.315(15) . ?
C7 C8 1.430(16) . ?
C8 C9 1.316(16) . ?
C9 C10 1.39(2) . ?
C10 C11 1.34(2) . ?
C11 C12 1.434(18) . ?
C13 C14 1.364(14) . ?
C14 C15 1.388(12) . ?
C15 C16 1.435(11) . ?
C16 N1 1.372(11) . ?
C101 F2 1.308(9) . ?
C101 F1A 1.316(9) . ?
C101 F3 1.317(9) . ?
C101 F2A 1.319(9) . ?
C101 F3A 1.320(9) . ?
C101 F1 1.321(9) . ?
C101 C102 1.529(15) . ?
C102 C103 1.353(17) . ?
C103 C104 1.413(16) . ?
C104 C105 1.497(16) . ?
C105 F4 1.300(14) . ?
C105 F5 1.323(17) . ?
C105 F6 1.334(15) . ?
C106 F8A 1.305(10) . ?
C106 F7 1.311(9) . ?
C106 F9A 1.315(9) . ?
C106 F8 1.319(10) . ?
C106 F7A 1.332(10) . ?
C106 F9 1.335(10) . ?
C106 C107 1.476(15) . ?
C107 C108 1.377(15) . ?
C108 C109 1.356(15) . ?
C109 C110 1.544(14) . ?
C110 F12 1.205(17) . ?
C110 F11 1.356(17) . ?
C110 F10 1.364(14) . ?
C111 F14 1.297(9) . ?
C111 F15A 1.301(9) . ?
C111 F13A 1.308(9) . ?
C111 F13 1.323(9) . ?
C111 F15 1.332(9) . ?
C111 F14A 1.341(9) . ?
C111 C112 1.480(14) . ?
C112 C113 1.393(14) . ?
C113 C114 1.394(14) . ?
C114 C115 1.514(15) . ?
C115 F16A 1.314(10) . ?
C115 F18 1.316(10) . ?
C115 F16 1.316(10) . ?
C115 F17 1.316(10) . ?
C115 F18A 1.322(10) . ?
C115 F17A 1.327(10) . ?
